KR20010072738A - Solid aqueous gel comprising a hydrophilic gelling agent and particular fillers - Google Patents

Abstract

The present invention relates to a solid aqueous gel containing i) at least one hydrophilic gelling agent and ii) at least one filler with deformable particles, wherein the hydrophilic gelling agent is at most 20% by weight relative to the total weight of the gel. Present in the gel in an amount of. It also relates to a solid composition of a continuous aqueous phase containing the gel.

The gel may be used in the form of a stick or compact (water compact) and may constitute a product for the makeup of the skin and / or mucous membranes and / or keratinous fibers. The water has a hardness that allows for both effective partitioning of the product and effective adhesion of the stick. The gel, or composition containing it, can be applied directly to the skin or using a sponge and has very good cosmetic properties (comfort and softness).

Description

SOLID AQUEOUS GEL COMPRISING A HYDROPHILIC GELLING AGENT AND PARTICULAR FILLERS}

The present invention relates to solid aqueous gels, solid compositions of a continuous aqueous phase containing said gels, and to the use of said substances in the cosmetic field, in particular for the makeup of skin and / or mucous membranes and / or keratin fibres.

Products provided in solid form are known in the cosmetic industry. What may be referred to as products of this type include, for example, lipsticks, foundations or eyeshadow sticks in the field of cosmetics; In the field of skin care or lip care, lip correction pencils and depigmentation, cosmetic removal or moisturizing sticks; And, in the field of hygiene, deodorant sticks and foaming sticks or bars for shaving or skin cleaning.

The actual available product in the form of a stick is particularly useful because the product is very convenient to use and can be easily carried without the risk of the product flowing.

Cosmetics are also very commonly formulated primarily in the fat phase for comfort and softness, and in the finely divided phase which provides the second intended color. The finely divided phase may contain pigments and / or fillers and / or pearlescent agents. The fatty phase generally contains wax and / or oil and / or paste-like compounds.

However, sticks formulated on wax bases have certain disadvantages; The water has a greasy property that users do not like and lacks freshness in application. In addition, it is difficult to introduce active hydrophilic materials into the material.

Thus, as an increasing trend, attempts have been made to produce cosmetic sticks containing the aqueous phase in as high a concentration as possible. Like deodorant sticks, the production of nonfat sticks is of course known, but they contain little pigment or pearlescent.

However, it is known that the presence of pigments or pearlescent agents in aqueous sticks causes problems of product partitioning, ie product application; Indeed, such pigments and / or pearlescent agents, which are essential for providing color to cosmetics, are solid particles that do not dissolve in the final composition. For this reason, they are likely to interfere with the stability of the composition.

In addition, the preconditions of cosmetics in particular are those that can be optimally applied, i.e. by using fingers or sponges or directly on the body's skin, for example, simply not appropriately (not too much so as not to waste the product) of the product. However, it is not only possible to take an amount sufficient to provide a cosmetic effect, but also to maintain the integrity of the product at the point of application: what is needed is not breaking the product due to shearing, but instead, if present, With the pigments and / or pearlescents and / or fillers it provides, the whole component of the product is applied. If the above conditions are obtained, it is possible to apply the product uniformly and to obtain a make-up of a constant application.

Stable solid aqueous gels containing pigments are also known: however, these products are generally indelible; They are often fragile and therefore cannot apply the product to fingers or sponges. The product cannot be buried in a uniform film on the skin.

There is also a splitting product, but it is too soft to break down during repeated use, or to show condensation over time, ie the liquid part is soaked out and consumed and the product appears in two phases: non-dividing Solid and liquid. Since the pigment cannot be removed on the finger or sponge, the product can no longer fulfill its function, namely make-up function.

Hard aqueous gels are also described in the specification of WO-A-97 / 17055. However, such gels require the use of certain high concentration gelling agents or the use of specific manufacturing techniques, which are extrusion techniques. In addition, the sticks lack freshness and softness in skin application due to the high concentration of the gelling agent.

In order to overcome these splitting problems, it has been proposed to inject fillers of certain chemical properties into the gel, such as silica or nylon. However, the product thus obtained has remarkably inadequate cosmetic properties: the water is rough to apply and gives an uncomfortable feeling such as drying or pulling when the product is applied to the skin. In addition, the substance is difficult to apply in the presence of a pigment.

Therefore, there is a need for a solid aqueous gel that does not have the disadvantages of the prior art.

Applicants may unexpectedly combine a hydrophilic gelling agent with a particular filler, i.e. a filler with deformable particles, to make a solid aqueous gel that optionally contains pigments and / or pearlescent agents, wherein the gel is on a finger or sponge, or It has been found that it is easily relieved directly on the skin of the face or body and has excellent cosmetic properties.

The present invention thus provides a solid aqueous gel consisting of a finely divided phase comprising i) at least one hydrophilic gelling agent and ii) at least one filler with deformable particles, wherein the hydrophilic gelling agent is 20% by weight of the total weight of the gel. It is present in the gel in an amount of up to%.

The gels of the present invention exhibit excellent partitioning and applicability. In particular, by the combination according to the invention, at equal hardness, a higher degree of splitting than known sticks is obtained. The product is easy to apply and can be applied directly to the body or by finger or sponge while applying a sufficient amount of the product, which is therefore easy to apply to the skin in a uniform manner without requiring pre-wetting. The gel spreads easily on the skin. The makeup obtained is constant and uniform.

The gel exhibits excellent cosmetic properties: improved comfort and softness of the membrane after skin drying. The membrane is not dry and does not give a feeling of pulling on drying.

The gel is stable over time and against temperature. Thus, after two months of storage at ambient temperature or 45 ° C., there is no adsorption (extrusion) or phase separation phenomenon; The appearance and hardness of the product do not change.

The gels according to the invention do not exudate, even at low gelling contents, and do not obligate the use of specific preparation techniques. In application, the water provides excellent cosmetic properties, in particular softness while maintaining excellent freshness.

The present invention additionally provides a solid composition of a continuous aqueous phase containing a gel as defined above.

The present invention also provides a cosmetic product for skin or keratinous fibers, containing the gel and / or composition as defined above.

The present invention additionally provides a cosmetic method of skin and / or mucous membranes and / or keratinous fibers, consisting of applying the solid aqueous gel and / or solid composition and / or cosmetic product as defined above.

In the context of the present invention, a solid composition or gel penetrates a stainless steel carrier having a diameter of 2 mm at a depth of 1 mm at a rate of 1 mm / s into the matrix of the gel or composition and the carrier is subjected to 2 in the matrix of the gel or composition. By recovering at a rate of mm / s, it is meant a gel or composition having a hardness defined as the maximum force before break in the range of 5 to 50 grams at ambient temperature (20-25 ° C.), the maximum force before breakage being Leo (RHEO) It is measured by a texture analyzer of type "TAXT2".

More preferably, the maximum force before breakage is in the range of 7 to 40 g.

The gel according to the invention contains a hydrophilic gelling agent. By gelling agent is meant a compound which, in the presence of a solvent, forms many or few strong macromolecular bonds and thus forms a three dimensional network which can trap the solvent.

The hydrophilic gelling agent may be selected from polysaccharides, protein derivatives, synthetic or semisynthetic gels of polyester type, polyacrylates or polymethacrylates and derivatives of the above.

Among the polysaccharides, the following may be mentioned:

Agar, carrageenan (iota, kappa, lambda) (carragheenans, iota, kappa, lambda), alginates, in particular seaweed extracts such as sodium alginate or calcium alginate;

Exudates of microorganisms, such as gellan, a product sold under the trade name "Rheosan" by the company Rhodia Chimie, such as xanthan gum and derivatives thereof;

Fruit extracts such as pectin;

Gelling agents derived from animals such as protein derivatives, in particular gelatin of cattle or fish, and caseinates;

Polysaccharides having side chains and six neutral sugars, as described in the specification of FR-A-2759377;

And mixtures of the above.

Preferably, the hydrophilic gelling agent is selected from polysaccharides, and more preferably, the hydrophilic gelling agent is gellan.

Particularly suitable products for the present invention are gellan rubber sold under the trade name "Kelcogel F" by NUTRASWEET-KELCO or iota-carragheenan sold under the trade names "Seaspen PF 357" or "Viscarin SD 389" by FMC. May be mentioned.

The hydrophilic gelling agent is present in the gel according to the invention at a concentration of less than 20% by weight, preferably in the range of 0.2 to 10% by weight relative to the total weight of the gel. This concentration allows the water to obtain hardness and firmness suitable for ideal cleavage.

The gel according to the invention further comprises a finely divided phase containing at least one filler with deformable particles.

The term fillers refers to white or colorless, mineral or synthetic, spherical or non-spherical particles for imparting shape or strength to the composition and / or providing softness, matte and uniformity to the makeup.

In the context of the present invention, fillers with deformable particles are spherical such that, when the product is associated with a stick, its hardness is sufficiently low that the water can be deformed during use by rubbing the composition onto a finger or sponge or directly onto the skin. Or non-spherical particles. In particular, the term "deformable" is intended to indicate that the particles are flexible and stretchable: after being pressed down, the particles regain their initial form.

The particles can be any chemical species. Preferably, the water has an average particle size in the range of 0.1 to 500 microns, and preferably 1 to 100 microns. The water may be hollow or hollow.

Examples of solid deformable particles that may be mentioned are particles of crosslinked organosiloxane or particles of “silicone rubber powder” such as those described in the specification of JP 10 175816, whose JIS A hardness is below 80 and preferably below 65. There is. The particles can be coated with a surfactant or fine organic powder. The water may also contain uncrosslinked silicone or hydrocarbon oils that can be exuded from the "silicone rubber powder".

Reference may be made to the silicone rubber powder, a 63% concentration of aqueous dispersion, marketed under the trade name Dow Corning under the trade name "BY29-119", "BY-29-122". Can be.

The solid deformable particles usable in accordance with the invention preferably have a density in the range from 0.8 to 4, more preferably in the range from 0.8 to 1.5.

If the deformable particles are hollow or filled with gas or air, the water advantageously has a density in the range of 0.015 to 0.2 and, more preferably, greater than 0.04 and / or less than 0.1, and especially in the range 0.06 to 0.08. Indicates.

For example, a copolymer containing the following may be used: a unit derived from vinylidene chloride, which is 1% by weight to 60% by weight based on the total weight of the copolymer, 20% by weight to 90% by weight of the copolymer. The sum of the units derived from acrylonitrile, which is 1% by weight to 50% by weight relative to the total weight of the copolymer, by weight percent phosphorus, the acrylonitrile, equals 100. Acrylic monomers are, for example, methyl methacrylate or acrylate, and in particular, methacrylate. The particles are particularly present in a dried or hydrated state.

The copolymer is nontoxic and not irritating to the skin.

Preferably, the hollow particles are in the form of microspheres and have an average size or granule meter in the range of 10 μm to 60 μm.

The hollow particles of the present invention are, for example, according to the methods of patents and patent applications EP-56 219, EP-348372, EP-486 080, EP-320 473, EP-112 807 and US-3 615 972, Can be obtained.

The inner steel of the particles contains a gas which can basically be air, nitrogen or a hydrocarbon such as isobutane or isopentane.

Hollow particles that can be used in the invention include, in particular, Expanel 551 DE 20 having a particle size of 27 μm and a density of about 0.052, Expancel 551 D 80 having a particle size of 50 μm and a density of about 0.045. DE 80), Expancell 051 DE with particle size 30 μm and density about 0.056, Expancell 461 DE with particle size 30 μm and density about 0.058, Particle size 17 μm and density about 0.07 Such as the "W" series of Expancell products such as Expancel 551 DE 12, or Expancel 551 W 20 with a particle size of 27 μm and a density of about 0.033. And those sold under the trade name Expanel of Casco Nobel.

Preferably, the filler with deformable particles is present in the gel according to the invention in an amount ranging from 0.1 to 50% by weight relative to the total weight of the gel. The amount can vary, in particular depending on the density of the filler with deformable particles. Thus, when the filler has a density in the range of 0.015 to 0.2, the water is preferably present in an amount ranging from 0.1 to 10% by weight, relative to the total weight of the gel. If the filler has a density in the range from 0.8 to 4, the water is preferably present in an amount ranging from 1 to 50% by weight, relative to the total weight of the gel.

For example, for hollow deformable particles, such as the aforementioned Expancells, the amount is generally from 0.1% to 10% by weight, more preferably from 0.3% to 5% by weight, based on the total weight of the gel. %, And even more preferably, in the range of 0.3% to 2% by weight.

In addition to the abovementioned fillers with deformable particles, the finely divided phase may contain other fillers which may be mineral or synthetic, lamellar or non-lamellae, and also pigments and / or pearlescent agents.

Other fillers include talc, mica, silica, kaolin, nylon powder, polyethylene, teflon, lauroyl-lysine, starch, boron nitride, bismuth oxychloride, tetrafluoroethylene polymer powder, polymethyl methacrylate powder, polyurethane Powder, polystyrene powder, polyester powder, synthetic hollow microspheres, non-deformable silicone resin microbeads, zinc oxide and titanium oxide, zirconium oxide or cerium oxide, precipitated calcium carbonate, magnesium carbonate and basic magnesium carbonate, hydroxyapatite 8 to 22 carbon atoms, preferably 12 to 18, such as hollow silica microspheres, glass or ceramic microcapsules, zinc stearate, magnesium stearate or lithium stearate, zinc laurate and magnesium myristate Derived from organic carboxylic acids with two carbon atoms Mention may be made of soaps, compounds SiO ₂ / TiO ₂ / SiO ₂ , TiO ₂ / CeO ₂ / SiO ₂ , or TiO ₂ / ZnO / Talc, and polyethylene terephthalate / polymethacrylate polymers in the form of flakes.

The filler may be present in the composition in a proportion of 0.1-60% by weight, preferably 0.1-40% by weight, more preferably 1-20% by weight relative to the total weight of the composition.

The term pigment is to be understood as meaning white or colored, mineral or organic particles that are not soluble in the medium, ie in the gel, for coloring and / or opacity of the composition.

The pigment may be present in a proportion of 0-40% by weight, preferably in a proportion of 0.1 to 30% by weight and more preferably in a proportion of 1-20% by weight relative to the total weight of the composition. The water may be of conventional size or nanometers, white or colored, mineral and / or organic. The nanometer size refers to pigments whose average particle size is in the range of 5 to 100 nm.

Among the mineral pigments and nanopigments, mention may be made of titanium dioxide, zirconium dioxide or cerium dioxide, and also zinc oxide, iron oxide or chromium oxide, nanotitanium, and blue iron. Among the organic pigments, black carbon, and calcium salts of barium salts, aluminum salts or zirconium salts, azo pigments or anthraquinoid pigments of acidic pigments such as haloic acid pigments are commonly used to impart a cosmetic effect to lips and skin. Lake pigments may be mentioned.

Pigments may in particular be coated with silicone compounds such as PDMSs and / or polymers such as polyethylene, or with fluorinated compounds. Thus mention may be made of Maprecos SA pigments or Myoshi PI pigments.

The term pearlescent is intended to include pearly particles which reflect light and do not melt in the medium, ie in the gel.

Pearlescent agents may be present in the composition at a rate of 0-40% by weight, preferably at a rate of 0.1 to 30% by weight, and more preferably at a rate of 1-20% by weight.

Among the pearlescent agents contemplated, mention may be made of natural pearl clams, titanium oxide, iron oxide, mica covered with natural pigments or bismuth oxychloride, and colored titanium mica.

Generally, the finely divided phase contains a sufficient amount of pigment and / or pearlescent agent to provide the intended cosmetic effect. Preferably, the finely divided phase contains at least one pigment and / or pearlescent agent. Thus, preferably, the aqueous gel according to the invention is not transparent, ie the letters of the newspaper page cannot be seen through the gel. More preferably, the gel is not translucent, ie does not allow the passage of light.

The fine powder phase preferably contains from 0.1 to 40% by weight, more preferably from 0.1 to 20% by weight of pigment and / or pearlescent agent relative to the total weight of the gel.

The gels of the present invention are cosmetically or physiologically acceptable media, i.e. media compatible with all keratin materials, such as skin, nails, hair, eyebrows and eyebrows, mucous membranes and mucous membranes, and other stratum corneum layers of the skin and body. It contains more.

Gels according to the present invention can be used in plant waters such as cornflower water and / or mineral waters and / or hot spring waters such as VITTEL water, LUCAS water or LA ROCHE POSAY water, ponshu disodium salt, alizarin green disodium salt, quinoline yellow, amarane It may contain a water-soluble dye selected from the general dyes in the field under consideration, such as tritrium salt, tarrazine disodium salt, rhodamine monosodium salt, puccicin disodium salt and xanthophyll.

Preferably, the gel according to the invention contains less than 99.8% by weight, preferably 20 to 99% by weight of water, relative to the total weight of the gel.

The gels according to the invention are, for example, mono-, di- or tripropylene glycols such as primary alcohols such as ethanol and isopropanol, propylene glycol, butylene glycol, dipropylene glycol and diethylene glycol, mono-, di- or tripropylene glycol. It may further contain a solvent other than water, such as a glycol ether, such as a C ₁ -C ₄ alkyl ether of di- or triethylene glycol, and a mixture of these.

The strength of the gel according to the invention can be modified by mixing the above with one or more salts which will increase its strength. The salts may be selected from mono-, di-, or trivalent metal salts, and more preferably alkali metal salts and alkaline earth metal salts, and in particular sodium, calcium or magnesium salts. The ions constituting the salts are, for example, carbonates, bicarbonates, sulfates, glycerophosphates, borates, chlorides, nitrates, acetates, hydroxides, pulsulfates and alpha-hydroxy acids. Salts (citrate, tartrate, lactate, malate) or salts of fruit acids, or salts of amino acids (aspartate, alginate, glycocholate, fumarate). The amount of salt may range from 0.01 to 2% and preferably 0.1 to 1% by weight of the total weight of the gel.

Preferably, the salt is calcium nitrate, magnesium nitrate or strontium nitrate, calcium borate or magnesium borate, calcium chloride, sodium chloride, magnesium chloride, strontium chloride, neodymium chloride or manganese chloride, magnesium sulfate or calcium sulfate, calcium acetate or magnesium acetate, and Selected from mixtures of the above. More preferably, the salt is magnesium chloride.

The gel of the present invention may be injected into the cosmetic composition, constituting the persistent phase of the above. The composition may also comprise a fatty phase, which may contain, for example, an oil.

Among the oils that can be used are liquid paraffin, vaseline, perhydrosqualene, apricot oil, wheat seed oil, sweet almond oil, crimson oil, sesame oil, macadamia oil, grapeseed oil, rapeseed oil, copra oil, peanut oil, palm oil, castor oil, Oils derived from animals, plants or minerals such as avocado oil, jojoba oil, olive oil or grain seed oil; Esters of fatty acids and polyols, in particular liquid triglycerides; Alcohol; Acetylglycerides; Octanoate, decanoate or ricinoleate of alcohols or polyalcohols; triglycerides of fatty acids; Glycerides, fluorinated oils and perfluorinated oils; Synthetic oils such as fatty esters; Mention may be made of volatile silicone oils, polymethylsiloxanes, polymethylphenylsiloxanes, silicone oils such as polysiloxanes modified with fatty acids, fatty alcohols or polyalkylenes, fluorinated silicones and perfluorinated oils.

The fatty phase of the composition according to the invention may further contain other fatty substances which, based on the knowledge of the skilled person, may be chosen to give the final composition the desired properties, for example in terms of persistence, texture and / or delivery. Can be. The additional fatty substances may be waxes of the animal origin, plant origin, mineral origin or synthetic origin, rubber and / or paste fatty substances, and mixtures of these.

In particular, mention may be made of:

-Silicone rubber,

Microcrystalline waxes, paraffins, petrolatum, petrolatum, ozokerite, montan waxes; Beeswax, lanolin and derivatives thereof; Waxes of animal, plant, mineral or synthetic origin, such as candelilla wax, ducky wax, carnauba wax, Japanese wax, cocoa butter, cork fiber wax or sugar cane wax; Hydrogenated oils solid at 25 ° C., ozokelets solid at 25 ° C., fatty esters and glycerides; Polyethylene waxes and waxes obtained by Fischer-Tropsch synthesis; Hydrogenated oils that are solid at 25 ° C .; lanolin; Fatty esters that are solid at 25 ° C .; Silicone waxes; Fluorinated waxes; Mixture of the above.

The fatty phase may be present in a proportion of the total weight of the composition, for example less than 30% by weight, preferably 0.1 to 20% by weight and, more preferably, 0.5 to 10% by weight, said ratio being in the selected application. It depends.

To ensure better spreadability, oils or waxes can be introduced into the aqueous phase in the presence of one or more surfactants.

The compositions according to the invention may thus also contain at least 8 ionic or nonionic O / W surfactants or cosurfactants of at least 8 HLB (hydrophilic / lipophilic controls), commonly used in the cosmetic field. If such water is present, the content of surfactant or cosurfactant is preferably in the range of 0.05 to 8% by weight of the total weight of the composition.

The composition may further contain any additional compound commonly used in the cosmetic field. Such additional compounds include antioxidants, essential oils, preservatives, active lipophilic or hydrophilic pharmacological or cosmetic ingredients, humectants, vitamins, essential fatty acids, sphingolipids, self-tanning compounds such as DHA, sunscreens, fragrances, and the like. May be selected from a mixture of water.

One skilled in the art will appreciate the content of any of the additional compound (s), and / or the foregoing so that the advantageous properties of the gels and / or compositions according to the invention are not adversely or significantly affected by the intended addition. Of course you have to be careful about your choices.

Gels and compositions with a continuous aqueous phase, according to the present invention, can be prepared according to conventional methods for making sticks, the method of which is already known to those skilled in the art.

The gels and compositions according to the invention may constitute products for the makeup or care of the skin, in particular the body, the face and / or scalp, or the keratin fibers, in particular the hair, nails, eyebrows and / or eyelashes, or the mucous membranes, in particular the lips. Can be. The water may therefore constitute a body cosmetic product, foundation, eye shadow, blusher, concealer, lipstick, lip liner pencil, mascara, eye liner pencil, and stick for hair dyeing or makeup.

The invention is illustrated in more detail in the following examples.

In the examples below, the amounts are given in weight percent relative to the total weight of the composition.

Example 1:

Applicant prepared an aqueous gel in the form of the following stick foundation:

0.5% by weight of gellan rubber sold under the trade name "Kelcogel F" (NUTRASWEET-KELCO).

0.1 wt% magnesium chloride

-Preservative appropriate

-7% by weight of pigments (iron oxide and titanium dioxide)

7% by weight of propylene glycol

-15% by weight of silicone rubber powder, 63% aqueous dispersion, sold under the trade name "BY29-119 (BY29-119)" (Dow Corning).

-100% water

The gel was prepared as follows: Water and preservatives were heated to 90 ° C. and then gellan was injected under stirring. After waiting for 15 minutes, the pigment paste, prepared by mixing the pigment and propylene glycol in advance, was injected. Next, silicon powder was injected.

The mixture was then poured into a vessel and cooled. The entire system was left at room temperature for 24 h.

The result is a stick that is very fresh in application, can be used as a dry or wet sponge, is easy to take out, and can be easily and uniformly applied to the skin.

The skin make-up using the stick has no greasy effect and shows a very soft, natural and clear result even after moisture evaporates.

The hardness of the gel, measured as described above, is 10 g.

Comparative Example 2:

Applicant prepared the following aqueous gel in the form of an eyeshadow stick.

0.5% by weight of gellan rubber sold under the trade name "Kelcogel F" (NUTRASWEET-KELCO).

-Preservative appropriate

-100% by weight of water

0.5 weight of expanded microspheres of vinylidene chloride / acrylonitrile / methyl methacrylate copolymer containing isobutane, sold under the trade name “Expancel 551 DE 20” (Casco Nobel). %

-5% by weight pearlescent

0.1 wt% magnesium chloride

The stick was prepared in the same manner as in Preparation Example 1.

The result is a stick that can be used directly on the skin, is easily stained, and has a powdery, dry feel.

The hardness of the stick, measured as described above, is 5.54 g.

Comparative Example 3:

Applicants prepared the following sticks in the same manner as in Preparation Example 1:

0.5 weight percent of gellan

0.1 wt% magnesium chloride

-Preservative appropriate

-7% by weight of pigments (iron oxide and titanium dioxide)

7% by weight of propylene glycol

3.15% by weight of pyrogenic silica sold under the trade name "Aerosil 200" (Degussa)

-100% water

The hardness of the stick, measured as described above, is 9.75 g.

A stick is obtained which is very inconvenient, lacks in ductility and cannot be applied uniformly.

Claims (30)

solid aqueous containing i) at least one hydrophilic gelling agent and ii) at least one filler with deformable particles, wherein the hydrophilic gelling agent is present in the gel in an amount of up to 20% by weight relative to the total weight of the gel. Gel. 2. Gel according to claim 1, characterized in that the hydrophilic gelling agent is selected from polysaccharides, protein derivatives, polyester type, especially sulfonic type, synthetic or semisynthetic gels, polyacrylates or polymethacrylates and derivatives of the above. . The gel of claim 2 wherein the hydrophilic gelling agent is a polysaccharide selected from: Seaweed extracts, such as agar, carrageenan, alginates, in particular sodium alginate or calcium alginate; Exudates of microorganisms, such as xanthan gum and derivatives thereof or gellan gum; Fruit extracts such as pectin; Gelling agents derived from animals such as protein derivatives, in particular gelatin of cattle or fish, and caseinates; Polysaccharides with side chains and six neutral sugars; And mixtures of the above. 4. The gel of claim 3 wherein the hydrophilic gelling agent is selected from gellan, carrageenin and mixtures of the foregoing. 5. The gel according to claim 1, wherein the hydrophilic gelling agent is present in a concentration ranging from 0.2 to 10% by weight relative to the total weight of the gel. 6. 6. The gel according to claim 1, wherein the filler with deformable particles has an average particle size in the range of 0.1 to 500 microns, preferably 1 to 100 microns. 7. The gel according to claim 1, wherein the filler with deformable particles is present at a concentration in the range of 0.1 to 50% by weight relative to the total weight of the gel. 8. The gel according to claim 1, wherein the filler with deformable particles is hollow and has a density in the range from 0.8 to 4, more preferably in the range from 0.8 to 1.5. 9. 9. A gel according to claim 8, wherein the particles are present in an amount ranging from 1 to 50% by weight relative to the total weight of the gel. 10. The gel according to claim 8 or 9, wherein the hollow particles are particles of crosslinked organosiloxane. The gel according to claim 1, wherein the filler with deformable particles is hollow and has a density in the range of 0.015 to 0.2, more preferably in the range of 0.06 to 0.08. 12. The gel of claim 11, wherein the particles are present in an amount in the range of 0.1 to 10 weight percent, relative to the total weight of the gel. The unit derived from vinylidene chloride, wherein the hollow particles are from 1% to 60% by weight relative to the total weight of the copolymer, from 20% to 90% by weight relative to the total weight of the copolymer. A unit comprising a unit derived from acrylonitrile, and a unit derived from an acrylic monomer, which is 1% by weight to 50% by weight relative to the total weight of the copolymer, and the sum of the weight% is 100. The gel of claim 13, wherein the particles contain air or a gas selected from nitrogen, isobutane or isopentane. 15. The gel according to any one of claims 11 to 14, wherein the hollow deformable particles are microspheres having an average size in the range of 10 μm to 60 μm. The method according to any one of claims 1 to 15, wherein the fine powder phase is talc, mica, silica, kaolin, nylon powder, polyethylene, Teflon, lauryl-lysine, starch, boron nitride, bismuth oxychloride, tetrafluoroethylene Polymer powder, polymethyl methacrylate powder, polyurethane powder, polystyrene powder, polyester powder, synthetic hollow microspheres, non-deformable silicone resin microbeads, zinc oxide and titanium oxide, zirconium oxide or cerium oxide, precipitated calcium carbonate, 8 to 8, such as magnesium carbonate and basic magnesium carbonate, hydroxyapatite, hollow silica microspheres, glass or ceramic microcapsules, zinc stearate, magnesium stearate or lithium stearate, zinc laurate and magnesium myrrate Organic with 22 carbon atoms, preferably 12 to 18 carbon atoms From metal soaps derived from carboxylic acids, compounds SiO ₂ / TiO ₂ / SiO ₂ , TiO ₂ / CeO ₂ / SiO ₂ , or TiO ₂ / ZnO / Talc, and polyethylene terephthalate / polymethacrylate polymers in flake form A gel, characterized in that it further contains a filler of choice. The fine powder phase according to any one of claims 1 to 16, wherein the fine powder is titanium dioxide, zirconium dioxide or cerium dioxide, zinc oxide, iron oxide or chromium oxide, nanotitanium, blue iron, carbon black, calcium salt, barium salt, aluminum salt. Or pigments coated with zirconium salts, acid dyes such as halo-acid dyes, azo dyes or anthraquinoid dyes, silicone compounds such as polydimethylsiloxane and / or polymers such as polyethylene, or fluorinated compounds, and / or the above Further comprising a pigment selected from the mixture. 18. The method according to any one of claims 1 to 17, wherein the fine powder phase further contains a pearlescent agent selected from natural pearl clam, titanium oxide, iron oxide, natural pigments or mica covered with bismuth oxychloride, and colored titanium mica. Characterized by gel. 19. The gel according to claim 17 or 18, wherein the fine powder contains 0.1 to 40% by weight, more preferably 0.1 to 20% by weight of pigment and / or pearlescent agent, relative to the total weight of the gel. 20. The gel according to any one of claims 1 to 19, wherein said water further contains a salt. The salt of claim 20 wherein the salt is calcium nitrate, magnesium nitrate or strontium nitrate, calcium borate or magnesium borate, calcium chloride, sodium chloride, magnesium chloride, strontium chloride, neodymium chloride or manganese chloride, magnesium sulfate or calcium sulfate, calcium acetate or magnesium acetate And a mixture of the foregoing. 22. The gel according to claim 21, wherein the salt is magnesium chloride. 23. The gel according to any one of claims 1 to 22, wherein said water further contains a cosmetically or physiologically acceptable medium. The gel according to any one of claims 1 to 23, wherein the water further contains a water-soluble pigment. The water according to any one of claims 1 to 24, wherein the water further contains a solvent selected from ethanol, isopropanol, propylene glycol, butylene glycol, dipropylene glycol, diethylene glycol, glycol ethers, and mixtures of the above. Gel, characterized in that. The compound according to claim 1, wherein the water is an antioxidant, essential oil, preservative, active lipophilic or hydrophilic pharmacological or cosmetic ingredient, humectant, vitamin, essential fatty acid, sphingolipid, self-tanning compound. And an additional compound selected from sunscreens, fragrances, and mixtures of the foregoing. 27. A solid composition having a continuous aqueous phase, characterized in that it contains a gel as defined in any of claims 1 to 26. A cosmetic product for skin or keratinous fibers, characterized in that it contains a gel as defined in any one of claims 1 to 26 and / or a composition as defined in claim 27. 29. The method of claim 28, wherein said water constitutes a body cosmetic product, foundation, eye shadow, blusher, concealer, lipstick, lip liner pencil, mascara, eye liner pencil, and stick for hair dyeing or makeup. Product. 27. The application of a gel as defined in any one of claims 1 to 26 and / or a composition as defined in claim 27 and / or a product as defined in claims 28 or 29 to skin and / or keratin fibres. A method of making up skin and / or keratinous fibers, comprising