DE60133005T2 - DURABLE COSMETIC COMPOSITION CONTAINING A PARTICULAR ADHESIVE MATERIAL - Google Patents

Abstract

The invention concerns a composition, in particular cosmetic and/or physiological, for skin or skin appendage make-up and/or care comprising at least a specific pro-adhesive material. Said composition exhibits remarkable non-transfer and/or long lasting properties. The invention also concerns the use of a pro-adhesive material in such a composition.

Description

The The present invention relates to a make-up kit containing a composition containing a pro-adhesive. In particular, it relates the invention to a kit for make-up of the facial skin as well the body skin and / or the skin appendages with great durability and without transmission.

cosmetic Compositions, especially those for make-up, such as lipsticks, Make-up, body make-up products, Products against dark circles, eye shadow or powder generally contain Fatty substances such as oils and / or waxes and a particular phase which generally out fillers and pigments. So can in the form of an anhydrous gel, as a crayon or pencil or in the form of a soft paste, for example as certain Make-up compositions, eye shadows or lipsticks. You can also in the form of a powder, for example, loose, compacted or pressed. The makeup compositions may further Contain water or a hydrophilic phase and therefore in particular in the form of an oil-in-water emulsion, a water-in-oil emulsion or a multiple emulsion, especially if it is a make-up, a tinted one Cream, a care cream or a sunscreen product. nail polishes usually lie in the form of a solution in an organic solvent in front.

From the document EP-A-600445 are known cosmetic makeup compositions, which have a high resistance to water, oils and sebum and are present as a water-in-oil emulsion containing 1 to 54 wt .-% of an outer phase-soluble resin and a dye in the contains inner phase.

If on the skin, on the mucous membranes or the semi-mucous membranes are applied, these compositions do not always have one high resistance on. Because you have found that certain compounds tend to be in the Interior of the wrinkles and / or skin wrinkles, as is the case with make-up is, in the case of lipsticks in the wrinkles that surround the lips, in the case of eyeshadows in the eyelid crease. It was also found that especially in the case of eyeshadow strips in the make-up form due to the movement of the eyelids. As well may be the original color to change with time. In the case of nail polishes, the product may be cracked will, flake off or be sensitive to friction.

Furthermore some make-up products have the disadvantage of transferring themselves. By this one understands that the composition tends to become at least in part on certain carriers with whom they are in contact is brought, such as a glass, a piece of clothing or the skin, deposit.

If she deposits, leaves the composition is a residue on the carrier. As a result, insufficient durability of the composition results on the skin or mucous membranes, which is why it is necessary to renew them by regular application.

Furthermore can cause the appearance of unacceptable marks on certain garments and especially on blouse collars To discourage some women from using make-up of this type.

All these phenomena produce an unaesthetic Effect, of course like to avoid.

It There is therefore a need for products, especially a make-up, which show a good hold and at the same time good cosmetic properties own, in particular sliding properties when applying, as well Properties of softness, hydration and comfort after the make-up.

The Applicant has completely surprising found that by using a particular Pro-adhesive in a cosmetic or physiological composition a make-up with a very good hold that does not transmit in the least and the resistant to water is, can be obtained, whereby the composition beyond easily split off.

• – i°) eine kombinierbar genannte Zusammensetzung, die in einem kosmetisch akzeptablen Träger zumindest ein Pro-Adhäsiv enthält, das die folgende Bedingung erfüllt: – 10⁸ Pa ≥ G'(35°C) ≥ 2·10⁴ Pa bei jeder Frequenz von 2·10^–2 bis 2 Hz, vorzugsweise: – 10⁷ Pa ≥ G'(35°C) ≥ 2·10⁴ Pa bei jeder Frequenz von 2·10^–2 bis 2 Hz, wobei: – G'(35°C) der elastische Speichermodul des Pro-Adhäsivs, gemessen bei 35°C, ist, und das Pro-Adhäsiv unter den Polyisobutylenen ausgewählt ist, und
• – ii°) eine «kombinierte Zusammensetzung», die in einem kosmetisch akzeptablen Träger zumindest eine diffundierende Verbindung, die unter den Ölen mit einer Molmasse kleiner oder gleich 20000 ausgewählt ist, enthält, so dass das haftende System «Pro-Adhäsiv + diffundierende Verbindung» die folgende Bedingungen erfüllt: – G'_SA(2 Hz, 35°C) ≥ 10³ Pa, – 10⁸ Pa ≥ G'_SA(35°C), vorzugsweise 10⁷ Pa ≥ G'_SA(35°C), und – G'_SA(2·10^–2 Hz, 35°C) ≤ 3·10⁵ Pa, wobei: – G'_SA(2 Hz, 35°C) der elastische Speichermodul des haftenden Systems ist, der bei einer Frequenz von 2 Hz und einer Temperatur von 35°C gemessen wird, – G'_SA(35°C) der elastische Speichermodul des haftenden Systems bei einer Temperatur von 35°C und jeder Frequenz von 2·10^–2 bis 2 Hz ist, – G'_SA(2·10^–2 Hz, 35°C) der elastische Speichermodul des haftenden Systems ist, der bei einer Frequenz von 2·10^–2 Hz und einer Temperatur von 35°C gemessen wird.

A first subject of the invention is a make-up kit containing:

• - i °) a composition which may be combined and which contains in a cosmetically acceptable carrier at least one pro-adhesive which satisfies the following condition: - 10 ⁸ Pa ≥ G '(35 ° C) ≥ 2 · 10 ⁴ Pa at each frequency of 2 × 10 ^-2 to 2 Hz, preferably: - 10 ⁷ Pa ≥ G '(35 ° C) ≥ 2 x 10 ⁴ Pa at each frequency of 2 x 10 ^-2 to 2 Hz, where: - G' (35 ° C) is the elastic memory modulus of the pro-adhesive measured at 35 ° C, and the pro-adhesive is selected from polyisobutylenes, and
• - ii °) a "combined composition" containing, in a cosmetically acceptable carrier, at least one diffusing compound chosen from oils of molecular weights less than or equal to 20000, so that the adhesive system "Pro-adhesive + diffusing compound" satisfies the following conditions: G ' _SA (2 Hz, 35 ° C) ≥ 10 ³ Pa, - 10 ⁸ Pa ≥ G' _SA (35 ° C), preferably 10 ⁷ Pa ≥ G ' _SA (35 ° C), and - G ' _SA (2 x 10 ^-2 Hz, 35 ° C) ≤ 3 x 10 ⁵ Pa, where: - G' _SA (2 Hz, 35 ° C) is the adherent system elastic storage modulus operating at one frequency of 2 Hz and a temperature of 35 ° C, - G ' _SA (35 ° C) is the elastic storage modulus of the adhesive system at a temperature of 35 ° C and at any frequency from 2 x 10 ^-2 to 2 Hz, G ' _SA (2 x 10 ^-2 Hz, 35 ° C) is the adherent system elastic storage modulus measured at a frequency of 2 x 10 ^-2 Hz and a temperature of 35 ° C.

The associative composition of the kit of the invention has excellent Properties re adhesion to the skin and "non-transference". It adheres well to the skin. It resists friction, sweat, Sebum, water. She lets split off easily. It allows a temporally homogeneous depot on the skin and a uniform Makeup. Once applied to the skin, it does not migrate and keeps the color is very good over the time. The composition is easy to distribute and is very nice. It is pleasant to apply and all day long long comfortable to wear. She is not greasy and starts with the Time not to shine. she feels creamy and pleasant.

One Another object of the invention is the use of at least one Pro-adhesive, as defined above, in or for the manufacture of a cosmetic or physiological, powdery composition, to reduce the transfer and / or the migration or even eliminate, and / or the resistance the composition on the lips and / or skin of the human across from a carrier, that comes in contact with it, to improve.

One Another object of the invention is the use of at least one Pro-adhesive, as defined above, in or for the manufacture of a cosmetic or physiological, powdery Composition to the long-term stability of the color of the composition to improve.

The Invention has in addition a non-therapeutic method for applying make-up to the skin, mucous membranes, the semi-mucous membranes and / or the skin appendages of the human being in the subject exists, the combined composition before or after the so-called combinable composition of the kit on the skin, the mucous membranes, the semi-mucous membranes and / or human skin appendages.

Under a powdery one Composition or a composition in powder form is understood according to the invention a composition containing at least one powdery compound. The powdered compounds can among the pigments and / or pearlescent pigments and / or fillers and / or their mixtures, usually be used in cosmetic compositions. Advantageously, the pulverulent compounds are in one Content of 60 to 99.9% by weight, preferably 80 to 99.9% by weight, based on the total weight of the composition.

Under a physiological composition is understood according to the invention a physiologically acceptable composition that is non-toxic is and for an application on the skin, the appendages and the lips of the human being is suitable. Under a cosmetic composition is understood within the meaning of the invention, a composition with a pleasant appearance and smell, which feels pleasant.

To a particular embodiment of the invention the combinable composition at least 80% powdered compounds. You get So a product with a special texture in rubber form, d. H. in the form of a solid product that is under its own weight not deformed.

Furthermore contains the combinable composition of the kit according to the invention at least a pro-adhesive Material. Under material is understood in the sense of the present Invention, a polymer or a polymer system, preferably at least is partially uncrosslinked, even better is virtually uncrosslinked, which may comprise one or more polymers of different nature. Under pro-adhesive is understood in the sense of the present invention, the ability generally by interaction with an added diffusing one Compound or to become attached to biological exudates. Under Adhesive understands For the purposes of the present invention, adhering to a surface, d. H. that after having the index finger the surface of the Composition containing the material has touched, a feeling of sticking on the surface to feel is, as soon as you release the contact with her, by pointing the index finger raises, just as it for example after a contact with the Sticky side of an adhesive tape is felt. In contact with the Skin generally adheres to the combinable composition with the Pro-Adhesive the skin and thus has a good adhesion, it can also be at one so-called combined composition with at least one diffusing Compound before and / or after the combinable composition of the kit according to the invention is applied, adhere; this will be the result on the skin cosmetic product generally be non-sticky on the surface, d. that is, when you touch the surface of the product with your index finger no feeling gluing on the surface to feel, when you make contact with her, by raising the index finger.

The Pro-Adhesive according to the invention can may be used alone have a certain adhesive power. After applying the combinable Composition of the kit according to the invention on the skin, especially on the face, is obtained because of the interactions with biological secretions that can evolve over time, one Composition with a very good hold. Biological secretions are general body fluids and skin secretions, especially sebum, sweat, tears and saliva. The expert White, that dependent from the body site the extent and the nature of these secretions fluctuate throughout the day.

The Proadhesive is used in combination with a diffusing compound, which by diffusion through the polymer network of the Pro-Adhesive this in comparison with the original one Pro-adhesive one greater adhesion lends: So receives a system "Pro-adhesive + diffusing Connection", which has adhesive properties. The diffusing compound can for example sebum or sweat, which over time the skin is excreted. The stop of a composition that the pro-adhesive according to the invention contains improved Consequently, with time and the release of sebum or sweat through the skin.

The diffusing compound is in a second composition which combined in the following and throughout this application Called composition and separated from and combined with the invention Pro-adhesive containing Composition used. The combined composition can without distinction before or after the combinable composition of the kit according to the invention be applied to the skin and / or the skin appendages.

For the kits according to the invention There is a particularly interesting application in the field of make-up the skin, the mucous membranes, the semi-mucous membranes, the skin appendages. Under mucous membrane is understood in particular the inner part of the lower eyelid; Under Semi-adhesive skins understands especially the lips; Under skin appendages understands eyelashes, eyebrows, hair and nails. Therefore exists for the invention a very special application in the field of makeup products for the lips and the skin, such as make-up creams, masking sticks, eyeshadows, Powder, body make-up products, Lipsticks, and in the field of makeup products for skin appendages (or their substitutes like false nails or false eyelashes), as well as mascara, nail polishes.

• – dem elastischen Speichermodul, der das elastische Verhalten eines Materials für eine gegebene Frequenz angibt und den man üblicherweise mit G' bezeichnet,
• – dem viskosen Verlustmodul, der das viskose Verhalten eines Materials für eine gegebene Frequenz angibt und den man üblicherweise mit G'' bezeichnet.

The viscoelastic properties of a material are usually defined by means of two characteristic values, namely:

• The elastic storage modulus, which indicates the elastic behavior of a material for a given frequency, usually denoted by G ',
• The viscous loss modulus, which indicates the viscous behavior of a material for a given frequency, commonly referred to as G ".

These quantities are defined in particular in the "Handbook of Pressure Sensitive Adhesive Technology" 3 ^rd edition, D. Satas, chapter 9, pages 155 to 157.

The measurement of these viscoelastic properties is carried out by dynamic experiments under si small-amplitude (low-strain) n-shaped stresses performed at 35 ° C. within a frequency range of 2 × 10 ^-2 to 20 Hz with a rheometer (for example, Haake RS50 or RS75 type) under torsional / shear stress, for example, conical - plane geometry (for example with a cone angle of 1 °).

If the materials are too cohesive to be characterized by a person skilled in the art using a Haake RS50 or RS75 rheometer as described above (eg G ' _SA (2 x 10 ^-2 Hz, 35 ° C)> 10 ⁸ Pa) , the measurement of the viscoelastic properties of the materials by dynamic experiments under low amplitude sinusoidal stress (small deformations), carried out at 35 ° C within a frequency range of 2 · 10 ^-2 to 20 Hz with a viscoelastometer, for example of type DMA 2980 of TA Instruments by means of film traction. For this purpose, the materials are dissolved in a suitable volatile solvent (for example in a concentration of 10%), then applied as a film on a teflon matrix; then they are dried at 35 ° C to remove the solvent and to obtain a film of this material. In this case, the elastic storage modulus E 'and the viscous loss modulus E "are determined under tensile stress and the values for G' and G" determined therefrom by the equations G '= E' / 3 and G "= E" / third

• – 10⁸ Pa ≥ G'(35°C) ≥ 2·10⁴ [Pa], vorzugsweise 10⁷ Pa ≥ G'(35°C) ≥ 2·10⁴ Pa bei jeder Frequenz von 2·10^–2 bis 2 Hz, wobei:
• – G'(35°C) der elastische Speichermodul des Pro-Adhäsivs, gemessen bei 35°C, ist.

The pro-adhesive materials usable according to the invention satisfy the following condition:

• - 10 ⁸ Pa ≥ G '(35 ° C) ≥ 2 x 10 ⁴ [Pa], preferably 10 ⁷ Pa ≥ G' (35 ° C) ≥ 2 x 10 ⁴ Pa at each frequency of 2 x 10 ^-2 to 2 Hz, where:
• - G '(35 ° C) is the elastic storage modulus of the Pro-Adhesive measured at 35 ° C.

The pro-adhesive materials of the present invention may be selected from "Pressure Sensitive Adhesives" type adhesives, for example, those listed in "Handbook of Pressure Sensitive Adhesive Technology" ^3d edition, D. Satas.

The inventive pro-adhesive materials Preferably, adhesive polymers are selected from block copolymers or random copolymers containing at least one monomer or a Combination of monomers, the resulting polymer a glass transition temperature below room temperature (25 ° C) owns, can these monomers or combinations of monomers with butadiene, Ethylene, propylene, isoprene, isobutylene, a silicone and their Selected mixtures become. examples for such materials are block polymers of the styrene-butadiene-styrene type, Styrene- (ethylene-butylene) -styrene, styrene-isoprene-styrene, such as the under the trade name "Kraton" by Shell Chemical Co. or "Vector" from Exxon sold products.

The pro-adhesive Materials according to the invention are adhesive polymers selected from polyisobutylenes.

In a particularly advantageous embodiment of the invention, the pro-adhesive materials are selected from polyisobutylenes having a relative molecular weight M _V greater than or equal to 150,000.

This relative molecular weight M _V can be evaluated by its viscosity average, which is calculated according to the formula J ₀ = 3.06 × 10 ^-2 M _V ^0.65 , where J _{0 is} the Staudinger index (in cm ³ / g). This index is calculated from the flow time of a polyisobutylene solution in isooctane at a concentration of C = 0.01 g / cm ³ through a capillary of a Ubbelhode viscometer at 20 ° C according to the ISO 1628 standard.

The relative molecular weight M _V can also be determined by means of GPC (gel permeation chromatography) according to the following procedure: 200 μL of a 0.5% polymer solution (adhesive material) are pumped using a "Waters 600 A" pump, throughput 1 ml / min injected at room temperature, with the eluent being a 100% THF solution, through eight columns in series: μstyragel 500 Å + 10 ⁴ Å + 2 × 10 ³ Å + styragel HR 0.5 + 2 × HR 1 + HR5E (300 × 7.8 mm). Detection is carried out by means of a «Waters 410» refractometer and by means of a «Waters 490» UV detector at a wavelength of 254 nm.

Commercial products which are particularly suitable for the present invention are the polyisobutylenes having relative molecular weights greater than 150,000 of the product range Oppanol from BASF, in particular polyisobutylenes having the relative molecular weights of 200,000, 400,000 and 110,000, respectively, sold under the trade names Oppanol B 30 Sold by the company BASF, Polyisobutylene having relative molecular weights M _V from 900 000 to 2 200 000, the Exxon under the Han delsnamen «Vistanex MM» are sold, as well as their mixtures.

The pro-adhesive Materials are preferably in the combinable composition with a content of 0.1 to 99 wt .-% before, preferably from 0.1 to 30 wt .-% and more preferably from 0.1 to 10 wt .-%, based on the total weight of the composition.

Next the above-defined Pro-adhesive can the combinable invention Composition containing any cosmetically acceptable carrier. Under a cosmetically acceptable carrier one understands a medium, which with every keratinische substance, like the skin, the nails, the hair, the eyelashes and eyebrows, the mucous membranes and the semi-mucous membranes and every other skin area of the body and of the face, as well as any substitute of these carriers like false nails, false ones Eyelashes and hairstyles, compatible is.

This carrier can any water-soluble, water-dispersible, fat-soluble or in oil dispersible, cosmetically acceptable and usually in cosmetics used compound include. Therefore, the carrier can be in shape a pulverizable composition, an anhydrous fatty phase (Gel or solution), in Form of an aqueous Phase (gel or solution), in the form of a dispersion, a solution in an organic solvent, an O / W or a W / O emulsion, a multiple emulsion, optionally by a or more organized systems can be stabilized.

Under Organized systems are understood in the sense of the present invention inverse micelles or «lyotropic Liquid crystal "structure, which at room temperature by the mixing of several surface-active Substances or surface-active Sub punch with polar solvents or of several polar solvents form, the polar solvents for example, under water, glycerol, panthenol, propylene glycol, Butylene glycol and / or mixtures thereof are selected. The liquid crystalline Condition is an intermediate state between the solid and the liquid state. It is often referred to as the mesomorphic state. These organized Systems are thermodynamically stable.

Depending on of its kind, the inventive per-adhesive can be solubilized or dispersed in an aqueous or in an aqueous phase in the carrier. The pro-adhesive according to the invention can so as watery Particle dispersion or as a particle dispersion in oil.

If the combinable composition contains a fatty phase, then it may preferably be at least one cosmetically or physiologically acceptable oil containing, in particular, mineral or hydrocarbon oils, vegetable or synthetic origin and mixtures thereof, as far as these for the intended use are suitable.

Further can be hydrocarbon oils list, like paraffin oil or Vaseline, mink oil, Turtle oil, soybean oil, perhydrosqualene, Sweet almond oil, calophyllum oil, palm oil, grape seed oil, sesame oil, corn oil, parleam oil, arara oil, rapeseed oil, sunflower oil, cottonseed oil, apricot kernel oil, castor oil, avocado oil, jojoba oil, olive oil or cereal germ oils; ester of lanolin, oleic, lauric, stearic; Fatty acid esters like Isopropyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, Diisopropyl adipate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-hexyldecyl laurate, 2-octyldecyl palmitate, 2-octyldecyl myristate or 2-octyldecyl lactate, 2-diethylhexylsuccinate, Diisostearyl malate, glyceryl triisostearate or diglyceryl triisostearate, higher Fatty acids like myristic, palmitic acid, stearic acid, Behen acid, oleic acid, linoleic acid, linolenic acid or isostearic; higher Fatty alcohols such as cetanol, stearyl alcohol, oleyl alcohol, linoleyl or linolenyl alcohol, Isostearyl alcohol or octyldodecanol; Silicone oils such as polydimethylsiloxane (PDMS), which may be phenylated, such as phenyltrimethicone, or possibly with aliphatic or aromatic radicals, or with functional Groups such as hydroxy, thiol and / or Amine groups are substituted; with fatty acids, fatty alcohols or polyoxyalkylenes modified polysiloxanes and mixtures thereof.

advantageously, At least one volatile at room temperature oil can be used. Under a understand volatile oil an oil, which is capable of settling in less than an hour at room temperature to evaporate. Preferably, the volatile oil has a viscosity of 0.5 at 25 ° C to 25 centistokes. After volatilization these oils receives a particle deposit that does not adhere to the skin or mucous membranes. They are preferably oils used, their flashpoint for a use in formulations is high enough. These volatile oils facilitate about that addition, the application of the composition on the skin.

These oils may be hydrocarbon or silicone oils, eventually with alkyl or alkoxy radicals at the end the silicone or hydrocarbon chain.

According to the invention suitable volatile silicone oils are, for example, linear or cyclic silicones of 2 to 7 Silicon atoms, these silicones having alkyl or alkoxy radicals May have 1 to 10 carbon atoms. Therefore, in particular Octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, hexadecamethylcyclohexasiloxane, Heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane and / or their mixtures are listed become.

When volatile Hydrocarbon oil Isoparaffins can be carried out with C8-C16, such as isododecane, isodecane, Heptane, isohexadecane and / or mixtures thereof.

These volatile oils can in from 0.1 to 99% by weight, preferably from 0.1 to 60% by weight and more preferably from 0.1 to 40% by weight, based on the total weight the composition to be present in the composition. Preferably is the weight ratio of volatile oil and of Pro-adhesive according to the invention 1 to 20, better 1 to 10 and even better from 2 to 4.

The Fat phase may further comprise at least one wax, at least one gum and / or at least one pasty one Fats vegetable, animal, mineral or synthetic Of origin, even silicone-based, and containing their mixtures.

From the solid at room temperature waxes which are suitable in the composition according to the invention can be used listed hydrocarbon waxes, such as beeswax, carnauba wax, Candelilla wax, ouricoury wax, japan wax, cork fiber wax, sugarcane wax, paraffin waxes, Lignite wax, microcrystalline waxes, lanolin wax, montan wax, Ozokerite, polyethylene waxes, Fischer-Tropsch paraffins, hydrogenated oil, fatty acid esters and at 25 ° C solid glycerides. It is also possible to use silicone waxes, of which alkyl, alkoxypolymethylsiloxanes and / or polymethylsiloxane esters listed can be. The waxes can exist as stable dispersions of colloidal wax particles, as they can be prepared by known methods, such as those from "micro-emulsions Theory and Practice ", L.M. Prince Ed., Academic Press (1977), 21-32. When a liquid at room temperature Wax can be jojoba oil to be named.

The Waxes can in a proportion of 0.1 to 50 wt .-%, based on the total weight of the composition.

• – eine Viskosität von 0,1 bis 40 Pa·s (1 bis 400 Poise), vorzugsweise 0,5 bis 25 Pa·s, gemessen bei 40°C mit einem Rotationsviskosimeter CONTRAVES TV ausgestattet mit einem beweglichen Teil MS-r3 oder MS-r4 bei einer Frequenz von 240 Umdrehungen/min.
• – ein Schmelzpunkt von 25–70°C, vorzugsweise von 25–55°C.

Pasty fat compounds can be defined by at least one of the following physico-chemical properties:

• A viscosity of 0.1 to 40 Pa.s (1 to 400 poise), preferably 0.5 to 25 Pa.s, measured at 40 ° C with a CONTRAVES TV viscometer equipped with a moving part MS-r3 or MS- r4 at a frequency of 240 revolutions / min.
• A melting point of 25-70 ° C, preferably 25-55 ° C.

Further can the compositions of the invention contain at least one alkyl, alkoxy or phenyl dimethicone, such as the product named "Abil wax 2440", produced by the company GOLDSCHMIDT is sold.

Furthermore, the compositions according to the invention may contain at least one silicone resin which contains a combination of R ₃ SiO _1/2 , R ₂ SiO _2/2 , RSiO _3/2 and SiO _4/2 units, where R is an alkyl radical with 1 to 6 carbon atoms.

In addition, can the fat phase contain at least one fat-soluble dye. This fat-soluble dye is, for example, Sudan red, DC Red 17, DC Green 6, β-carotene, Soybean oil, DC Yellow 11, DC Violet 2, DC Orange 5, Quinoline yellow or theirs Mixtures. You can 0.01 to 20%, preferably 0.1 to 6%, of the total weight of the composition represent.

The Fat phase can be 0.01 to 99.9 wt .-%, based on the total weight the finished composition. If the combinable Composition is a powder, for example, a face powder, then the fatty phase is preferably in a content of 0.1 to 30 Wt .-%, based on the total weight of the composition, before.

The combinable composition according to the invention may comprise at least one organic solvent contain medium phase, especially if the composition is a nail polish.

• – bei Raumtemperatur flüssige Ketone wie Methylethylketon, Methylisobutylketon, Diisobutylketon, Isophoron, Cyclohexanon, Aceton;
• – bei Raumtemperatur flüssige Alkohole wie Ethanol, Isopropanol, Diacetonalkohol, 2-Butoxyethanol, Cyclohexanol;
• – bei Raumtemperatur flüssige Glycole wie Ethylenglycol, Propylenglycol, Pentylenglycol, Glycerin;
• – bei Raumtemperatur flüssige Propylenglycolether wie Propylenglycolmonomethylether, Propylenglycolmonomethyletheracetat, Dipropylenglycolmono-n-butylether;
• – kurzkettige Ester (mit insgesamt 3 bis 8 Kohlenstoffatomen) wie Ethylacetat, Methylacetat, Propylacetat, n-Butylacetat, Isopentylacetat;
• – bei Raumtemperatur flüssige Ether wie Diethylether, Dimethylether oder Dichlordiethylether;
• – bei Raumtemperatur flüssige Alkane wie Decan, Heptan, Dodecan, Cyclohexan;
• – bei Raumtemperatur flüssige cyclische aromatische Verbindungen wie Toluol und Xylol;
• – bei Raumtemperatur flüssige Aldehyde wie Benzaldehyd, Acetaldehyd;
• – Gemische daraus.

As the organic solvent usable for the invention, there can be mentioned:

• - At room temperature liquid ketones such as methyl ethyl ketone, methyl isobutyl ketone, diisobutyl ketone, isophorone, cyclohexanone, acetone;
• - Alcohols at room temperature, such as ethanol, isopropanol, diacetone alcohol, 2-butoxyethanol, cyclohexanol;
• - liquid at room temperature glycols such as ethylene glycol, propylene glycol, pentylene glycol, glycerol;
• Propylene glycol ethers which are liquid at room temperature, such as propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate, dipropylene glycol mono-n-butyl ether;
• Short chain esters (having a total of 3 to 8 carbon atoms) such as ethyl acetate, methyl acetate, propyl acetate, n-butyl acetate, isopentyl acetate;
• - Ether at room temperature, such as diethyl ether, dimethyl ether or dichlorodiethyl ether;
• Alkane at room temperature, such as decane, heptane, dodecane, cyclohexane;
• - At room temperature, liquid cyclic aromatic compounds such as toluene and xylene;
• - Aldehydes which are liquid at room temperature, such as benzaldehyde, acetaldehyde;
• - mixtures thereof.

The organic solvents can in the composition of the invention in an amount of 0.01 to 99% by weight, preferably 50 to 99% by weight for an application as nail polish, based on the total weight of Composition, be present.

Contains the combinable Composition a water phase, then this water, a hydrolate like cornflower water and / or a mineral water like water from Vittel, LUCAS or LA ROCHE POSAY and / or thermal water included.

Further, the water phase may contain solvents other than water, such as primary alcohols such as ethanol or isopropanol, glycols such as propylene glycol, butylene glycol, dipropylene glycol, diethylene glycol, glycol ethers such as mono-, di-, or tripropylene glycol alkyl (C ₁ -C ₄ ) ethers and theirs mixtures.

Further the water phase may contain at least one water-soluble dye, which is selected from among the common dyes in this field, such as the disodium salt of Ponceau, the disodium salt of alizarin green, quinoline yellow, the trisodium salt of amaranth, the monosodium salt of a rhodamine, the disodium salt of fuchsin, xanthophyll and their mixtures.

Further can the watery Phase each with an aqueous one Phase compatible (water soluble or hydrodispersible) compound, such as gelling agent, polymeric film formers, thickeners, surfactants, preservatives, Dispersions and pigments.

If the combinable composition is a nail varnish, then the aqueous phase may consist essentially of water or a water-alcohol mixture which contains in particular monoalcohols with C ₁ -C ₅ or glycols with C ₂ -C ₈ .

Preferably lies the watery Phase in the compositions of the invention in a content of 0.01 to 99 wt .-% before, preferably from 0.1 to 80 wt .-%, based on the total weight of the composition. Is the composition of the invention a powder, for example a face powder, then lies the aqueous phase preferably in a content of 0.01 to 30 wt .-%, based on the total weight of the composition, before.

Further the combinable composition may be at least one amphiphilic Containing compound, d. H. a connection that simultaneously has a lipophilic (apolar) and has a hydrophilic (polar) part and to a surface or to an interface can adsorb. Such compounds are, for example, emulsifiers or coemulsifiers.

The in the composition of the invention, when present as an emulsion, emulsifiers and coemulsifiers used are chosen among those the usual used in the field of cosmetics and dermatology. The emulsifier and the coemulgator can in the composition in a proportion of preferably 0.3 to 30 wt .-% and better from 0.5 to 20 wt .-%, based on the total weight of the composition.

When surfactant Substance W / O can be listed in particular (CTFA): Cetearylglucoside, PEG-40 Stearate, sorbitan tristearate, sorbitan stearate, polysorbate 60, a Mixture of sorbitan stearate / coconut fatty acid sucrose ester, a mixture of glyceryl stearate / PEG-100 stearate, PEG-400, glyceryl stearate, a mixture from PEG-6 / PEG-32 / glycol stearate. As surface-active In particular, the substance O / W can be the mixture polyglyceryl-4 isostearate / cetyldimethicone copolyol / hexyl laurate and the mixture mineral oil / petrolatum / ozokerite / glyceryl oleate / lanolin alcohol list.

In addition, can the combinable composition moreover at least one powdery compound contain. The powdery Connections can among the pigments and / or pearlescent pigments and / or fillers and / or mixtures thereof, usually in cosmetic compositions to be used become. Advantageously, the powdery compounds 0.1 to 99.9 wt .-%, preferably 60 to 99.9 wt .-%, based on the total weight of the composition. If the composition of the invention is a powder, For example, a face powder, then put the powdery compounds preferably 80 to 99.9 wt .-%, based on the total weight of Composition, dar.

The Pigments can white or be colored, inorganic and / or organic. Among the inorganic Pigments can be listed: possibly surface treated Titanium dioxide, zirconium or cerium oxides, as well as iron or chromium oxides, Manganese violet, ultramarine pigments, chromium hydroxide and iron blue pigments. Among the organic pigments can be listed: carbon black, D & C pigments and Carmine-barium, strontium, calcium, aluminum-based paints.

The Pearlescent pigments can among the white ones Pearlescent pigments as coated with titanium or bismuth oxychloride Mica pigments, the colored pearlescent pigments, such as titanium dioxide iron oxide mica pigments, Titanium dioxide-mica pigments, in particular with iron-blue pigments or chromium oxide pigments, with an organic pigment of the above mentioned type, as well as the pearlescent pigments based on Bismuth oxychloride selected be.

The fillers can inorganic or organic, lamellar or spherical. You can list the following: talk, Mica, pebble earth, kaolin, nylon powder (orgasol from Atochem or Nylon 12), poly-β-alanine powder and polyethylene powder, teflon, bismuth oxychloride, lauroyl lysine, Strength, Boron nitride, powder of tetrafluoroethylene polymers, hollow microspheres, like Expancel (Nobel Industry), Polytrap (Dow Corning) and Microspheres silicone resin (for example Tospearls from Toshiba), precipitated calcium carbonate, Magnesium carbonate and magnesium bicarbonate, hydroxyapatite, Silica hollow spheres (SILICA BEADS from MAPRECOS), Microcapsules made of glass or ceramics, metal soaps by one organic carboxylic acid having from 8 to 22 carbon atoms, preferably from 12 to 18 carbon atoms, For example, zinc, magnesium or lithium stearate, zinc laurate, magnesium myristate.

The In addition, any combinable composition can be any of these Compositions usually used compound such as thickener, antioxidant, Perfumes, preservatives, surfactants, active ingredients.

When cosmetic, dermatological, hygienic agents used in the Composition of the invention can be used, the following can be mentioned: Hydrating agents, vitamins, essential fatty acids, sphingolipids, Sunscreens. These agents are present in quantities such as she generally for the powders are used. They are in particular in one share from 0.001 to 20% of the total weight of the composition.

Of the Specialist becomes natural these optionally added compound (s) and / or their How to choose quantity that the advantageous properties of the composition according to the invention are not or not materially affected by the intended addition.

The compositions according to the invention can be prepared by a person skilled in the art in a customary manner. They may be in the form of a loose powder or compact powder, anhydrous or hydrous gel, a W / O or O / W emulsion or a multiple emulsion. They can be in the form of a stick, for example in the form of a stick or as a small bowl, the contents of which are taken with the fingers or with a sponge: they are mainly used as blush, cheek blush, eye shadow, lip powder, facial or body powder or as deodorant Powder, lipstick, tint primer, mascara, eye-liner, masking product applied. They may also be in the form of a loose powder, in particular as cheek powder, as a face or body make-up or as a deodorizing powder. she may also be present as a solution or dispersion and applied as a nail varnish.

These Compositions for topical application may in particular be a cosmetic, a hygienic and protective Composition, a composition for treatment or care the face, the neck, the hands, the skin appendages or body (for example, an anhydrous perfumed or not perfumed Care powder, a sun powder), a makeup composition (for Example, a make-up gel) or a composition for artificial skin tanning be.

In a preferred embodiment of the invention the combinable invention Composition of at least 80% of powdered compounds. So you get a product with a special texture in rubber form, d. H. in shape a solid product that does not deform under its own weight.

Lies the combinable composition in the form of a gum, then can this gum in a small bowl present and used as an exfoliating composition and / or make-up become. The product is preferably applied by finger, by running your finger over the surface several times Rubber drives: In this way triggers You take small rolls of rubber, which you then apply to the skin can. By rubbing off the skin with these little rollers, removes from her the dead cells and massaging them without any irritating Effect. The composition of the invention is therefore used because of their peeling properties. Through this Hand movement are also those in the composition of the invention evenly distributed dye particles. That's how the skin gets at the same time soft and stained. Accordingly, the composition according to the invention is also for makeup the skin used. Finally, remove the firm little ones Rolling, simply by running your hand over the skin, causing you get a soft and painted skin at the same time. It stays no sticky or greasy feeling on the skin.

The Compositions of the invention can individually for use on the body or facial skin. These compositions possess a good grip and very good properties, without looking after the Apply to transfer. About that In addition, the sebum or sweat, which excreted from the skin, interacts be, with the pro-adhesive, what the hold of the combinable composition and its property, not to transfer even stronger.

In another embodiment The invention relates to the combinable composition individually and in combination with a combined composition containing a contains diffusing compound, used.

These diffusing compound forms in combination with the pro-adhesive System with adhesive properties, which in the following and the whole Login «Adhesive Called system becomes. The diffusing compound enhances the adhesion of the pro-adhesive by: it from the time of application on the skin through the polymer mesh this pro-adhesive diffused to the desired to achieve cosmetic effect. It is important that the pro-adhesive and the diffusing compound not before application within the confectioning be brought into contact with each other so no sticky feeling when touching is caused. For a powdered combinable composition, which contains the Pro-Adhesive exists additionally the risk of instability the composition, that is, that at a contact between the pro-adhesive and the diffusing Link the powders higher risk to agglomerate.

• – G'_SA(2 Hz, 35°C) ≥ 10³ Pa,
• – 10⁸ Pa ≥ G'_SA(35°C), vorzugsweise 10⁷ Pa ≥ G'_SA(35°C), und
• – G'_SA(2·10^–2 Hz, 35°C) ≤ 3·10⁵ Pa, wobei:
• – G'_SA(2 Hz, 35°C) der elastische Speichermodul des haftenden Systems ist, der bei einer Frequenz von 2 Hz und einer Temperatur von 35°C gemessen wird,
• – G'_SA(35°C) der elastische Speichermodul des haftenden Systems bei einer Temperatur von 35°C ist,
• – G'_SA(2·10-² Hz, 35°C) der elastische Speichermodul des haftenden Systems ist, der bei einer Frequenz von 2·10^–2 Hz und einer Temperatur von 35°C gemessen wird.

The "sticking system" fulfills the following conditions:

• - G ' _SA (2 Hz, 35 ° C) ≥ 10 ³ Pa,
• - 10 ⁸ Pa ≥ G ' _SA (35 ° C), preferably 10 ⁷ Pa ≥ G' _SA (35 ° C), and
• G ' _SA (2 x 10 ^-2 Hz, 35 ° C) ≤ 3 x 10 ⁵ Pa, where:
• - G ' _SA (2 Hz, 35 ° C) is the elastic storage modulus of the adhesive system measured at a frequency of 2 Hz and a temperature of 35 ° C,
• G ' _SA (35 ° C) is the elastic storage modulus of the adhesive system at a temperature of 35 ° C,
• - G ' _SA (2 x 10- ² Hz, 35 ° C) is the adherent system elastic storage modulus measured at a frequency of 2 x 10 ^-2 Hz and a temperature of 35 ° C.

• – G''_SA/G'_SA(0,2 Hz, 35°C) ≥ 0,35, wobei:
• – G''_SA(0,2 Hz, 35°C) der viskose Schubmodul dieses haftenden Systems ist, der bei einer Frequenz von 0,2 Hz und einer Temperatur von 35°C gemessen wird,
• – G'_SA(0,2 Hz, 35°C) der elastische Speichermodul des haftenden Systems ist, der bei einer Frequenz von 0,2 Hz und einer Temperatur von 35°C gemessen wird.

In a preferred embodiment of the invention, the adhesive system further satisfies the following condition:

• - G " _SA / G ' _SA (0.2 Hz, 35 ° C) ≥ 0.35, where:
• - G " _SA (0.2 Hz, 35 ° C) is the viscous shear modulus of this adhesive system measured at a frequency of 0.2 Hz and a temperature of 35 ° C,
• - G ' _SA (0.2 Hz, 35 ° C) is the elastic storage modulus of the adhesive system measured at a frequency of 0.2 Hz and a temperature of 35 ° C.

• – G'_SA(2 Hz, 35°C) ≥ 10⁴ Pa.

In a preferred embodiment of the invention:

• - G ' _SA (2 Hz, 35 ° C) ≥ 10 ⁴ Pa.

• – G'_SA(2·10^–2 Hz, 35°C) ≤ 5·10⁴ Pa.

In another preferred embodiment of the invention:

• - G ' _SA (2 x 10 ^-2 Hz, 35 ° C) ≤ 5 x 10 ⁴ Pa.

• – G'_SA(2 Hz, 35°C) ≥ 10⁴ Pa, und
• – 10⁸ Pa ≥ G'_SA(35°C), vorzugsweise 10⁷ Pa ≥ G'_SA(35°C), und
• – G'_SA(2·10^–2 Hz, 35°C) ≤ 5·10⁵ Pa, und
• – G''_SA/G'_SA(0,2 Hz, 35°C)≥ 0,35.

It is even better if the adhesive systems according to the invention fulfill the four following conditions:

• - G ' _SA (2 Hz, 35 ° C) ≥ 10 ⁴ Pa, and
• - 10 ⁸ Pa ≥ G ' _SA (35 ° C), preferably 10 ⁷ Pa ≥ G' _SA (35 ° C), and
• - G ' _SA (2 x 10 ^-2 Hz, 35 ° C) ≤ 5 x 10 ⁵ Pa, and
• - G " _SA / G ' _SA (0.2 Hz, 35 ° C) ≥ 0.35.

The diffusing compound can be any low molecular weight oil for example, with a molecular weight less than or equal to 20,000 diffusing compound may be polyisobutylenes, Lanolins, aliphatic or aromatic hydrocarbon resins, terpene resins and theirs Mixtures, aliphatic or aromatic hydrocarbon resins of the type "sticking Resin »to be selected; it is at least partially compatible with the Pro-Adhesive.

you following, especially good for the present invention suitable diffusing compounds list: Polyisobutylenes with a relative molecular weight less than or equal to 10,000, such as the polyisobutylenes with a molecular weight of 455 to 2000, under the trade name «Napvis» from the Company BP Chemicals are sold, or the polyisobutylenes, the under the name "Parleam" by Ets B. Rossow et Cie be sold, or the polyisobutylenes, under the trade name «Vistanex LM »from the company Exxon are sold and their mixtures.

These Diffusing compounds are especially for a combination with the for the Invention preferred pro-adhesive Materials suitable, such as the polyisobutylenes having relative molecular weights greater than 150000 of the product range Oppanol from BASF, in particular the polyisobutylenes with the relative molar masses 200 000, 400 000 and 1 110 000, the under the trade names «Oppanol B 30 SF »,« Oppanol B 50 SF »and« Oppanol B 100 »from sold by BASF, the polyisobutylenes with a relative Molecular weight (viscosity agent) of 900 000 and 2 200 000 sold under the trade name "Vistanex MM »from the company Exxon and their mixtures.

Preferably is the weight ratio of the Pro-Adhesive and the diffusing compound 0.01 to 10, better 0.05 to 2 and even better 0.1 to 2.

Further can following for the present invention preferred combinations "Pro-adhesive + diffusing Connection »are listed: Block polymers of the type styrene-butadiene-styrene, styrene- (ethene-butene) -styrene, Styrene-isoprene-styrene, such as those sold under the trade names "Kraton" by Shell Chemical Co. or sold under the trade name "Vector" by Exxon, combined with aliphatic or aromatic tackifying Hydrocarbon resins, such as resins sold under the names "Piccotac", "Hercotac" by Hercules, or under the name "Escorez" by Exxon sold.

Next The diffusing compound can be the «combined composition» of each cosmetically acceptable carrier contained in the present invention for the combinable invention Composition was defined. It can also be used in all forms, Gels, emulsions, sticks are present in the present application already for the composition of the invention were defined.

The combination of the combinable with the combined composition provides a kit that can be used for every make-up cosmetic product. After application of the two together On the skin, a cosmetic product with very good hold and / or very good properties without transfer is obtained.

The Invention is illustrated in more detail in the following examples.

Example 1:

The Applicant has the following cosmetic base in the form of a Emulsion O / W produced:

Composition A:

Phase A: - sorbitan isostearate 4.2% - preservative 0.2% Phase B1: Hydrogenated isobutylene 12% Phase B2: Polyisobutylene with a molecular weight of 1 110 000, sold under the trade name "Oppanol B 100" by BASF (Pro-Adhesive) 2% - Isododecane 12% Phase C - Water 70.7% - magnesium sulfate 0.7% - preservative 0.2%

The polyisobutylene having the molecular weight of 1 110 000 of this composition has a value of G '(35 ° C) ≥ 6 × 10 ⁴ Pa at every frequency of 2 × 10 ^-2 to 2 Hz.

These Emulsion was mixed with a usual Method for producing O / W emulsions made. At first was Phase A produced by mixing. Then phase B1 became under stir and heating was added. Phase B2 is added after the Polyisobutylene has been dissolved with heating in isododecane. You get from it an oil phase, the for 5 min at 80 ° C heated becomes. This mixture is at 20 ° C cooled. All phase C compounds are mixed and then heated until the preservative has dissolved. Thereafter, phase C to 20 ° C chilled and then added slowly to the mixture A + B1 + B2.

The Applicant has also produced the following "combined composition" B, which is a face powder.

Composition B

- Acetyltributyl citrate 8th% - iron oxide (red) 5% - Talk 79% - Polyisobutylene with molecular weight 455, sold under the trade name «Napvis D 07 »from the company BP Chemicals (diffusing compound) 8th%

• – G'_SA(2 Hz, 35°C) = 7·10³ Pa,
• – G'_SA(2·10^–2 Hz, 35°C) = 2·10³ Pa,
• – G''_SA/G'_SA(0,2 Hz, 35°C) = 0,35.

The adhesive system consisting of the Pro-Adhesive of Composition A and the diffusing compound of "Combined Composition" B in a ratio of 0.25 has the following properties:

• - G ' _SA (2 Hz, 35 ° C) = 7 x 10 ³ Pa,
• G ' _SA (2 x 10 ^-2 Hz, 35 ° C) = 2 x 10 ³ Pa,
• - G " _SA / G ' _SA (0.2 Hz, 35 ° C) = 0.35.

composition For example, A is applied to the face of a person. Then, to composition A, then composition B is applied. The resulting make-up product has a remarkable hold and transmits very much little.

Example 2:

• – eine Basis i°) für die Nägel, die das Pro-Adhäsiv enthält,
• – eine Nagellack-Zusammensetzung ii°), die die diffundierende Verbindung enthält.

Base i): – Polyisobutylen mit der Molmasse 1 110 000, verkauft unter dem Handelsnamen «Oppanol B 100» von der Firma BASF (Pro-Adhäsiv) 5% – Heptan qsp 100% Applicant has prepared the following kit comprising:

• A base i °) for the nails containing the pro-adhesive,
• A nail polish composition ii °) containing the diffusing compound.

Base i): Polyisobutylene with a molecular weight of 1 110 000, sold under the trade name "Oppanol B 100" by BASF (Pro-Adhesive) 5% - heptane qsp 100%

The polyisobutylene having a molecular weight of 1 110 000 of this composition has a value of G '(35 ° C.) ≥ 6 × 10 ⁴ Pa at each frequency of 2 × 10 ^-2 to 2 Hz. Nail varnish ii): - nitrocellulose 12% - N-ethyl-o, p-toluyl-sulfonamide 4% - Tributylacetyl citrate 4% - pigment 1% - hectorite 1.2% - isopropyl alcohol 5.1% Polyisobutylene of molecular weight 455, sold under the trade name "Napvis D 07" by BP Chemicals (diffusive compound) 10% - ethyl, butyl acetate qsp 100%

• – G'_SA(2 Hz, 35°C) = 3·10³ Pa,
• – G'_SA(2·10^–2 Hz, 35°C) ≤ 2·10³ Pa.

The adhesive system consisting of the Pro-Adhesive Base i °) and the diffusing compound of Nail Polish II °) ("combined composition" according to the invention) in a ratio of 0.5 has the following properties:

• G ' _SA (2 Hz, 35 ° C) = 3 x 10 ³ Pa,
• - G ' _SA (2 x 10 ^-2 Hz, 35 ° C) ≤ 2 x 10 ³ Pa.

The Base i °) gets on nails or false nails applied. Thereafter, the paint is applied ii °). The obtained Product has a remarkable hold.

Claims (11)

Make-up kit containing: - i °) a composition which may be combined and which contains in a cosmetically acceptable carrier at least one pro-adhesive which satisfies the following condition: - 10 ⁸ Pa ≥ G '(35 ° C) ≥ 2 · 10 ⁴ Pa at each frequency of 2 x 10 ^-2 to 2 Hz, preferably: - 10 ⁷ Pa ≥ G '(35 ° C) ≥ 2 x 10 ⁴ Pa at each frequency of 2 x 10 ^-2 to 2 Hz, where: - G' (35 ° C) is the elastic storage modulus of the pro-adhesive, measured at 35 ° C, and the pro-adhesive is selected from polyisobutylenes; and ii) a "combined composition" comprising, in a cosmetically acceptable carrier, at least one diffusing compound containing among the oils having a molecular weight less than or equal to 20000, so that the adhesive system "Pro-Adhesive + Diffusive Compound" satisfies the following conditions: - G ' _SA (2 Hz, 35 ° C) ≥ 10 ³ Pa, - 10 ⁸ Pa ≥ G ' _SA (35 ° C), preferably 10 ⁷ Pa ≥ G' _SA (35 ° C), and - G ' _SA (2 x 10 ^-2 Hz, 35 ° C) ≤ 3 · 10 ⁵ Pa, where: - G ' _SA (2 Hz, 35 ° C) is the elastic storage modulus of the adhesive system measured at a frequency of 2 Hz and a temperature of 35 ° C, - G' _SA ( 35 ° C), the elastic storage modulus of the adhesive system at a temperature of 35 ° C and at any frequency of 2 x 10 ^-2 to 2 Hz, - G ' _SA (2 x 10 ^-2 Hz, 35 ° C) is the elastic storage modulus of the adhesive system measured at a frequency of 2 × 10 ^-2 Hz and a temperature of 35 ° C. Kit according to claim 1, characterized in that the pro-adhesive is a polyisobutylene having a relative molecular weight M _V greater than or equal to 150,000. Kit according to claim 1 or 2, characterized in that Pro-adhesive is a polyisobutylene having a relative molecular weight M _V of 900,000 to 2,200,000. Kit according to one of the preceding claims, characterized characterized in that the diffusing compound is polyisobutylenes, Lanolins, aliphatic or aromatic hydrocarbon resins, Terpene resins, tackifying aliphatic or aromatic hydrocarbon resins and their mixtures selected is. Kit according to one of the preceding claims, characterized characterized in that the diffusing compound is among the polyisobutylenes selected is. Kit according to one of the preceding claims, characterized in that the diffusing compound is a polyisobutylene having a relative molecular weight M _V of 455 to 2000. Kit according to one of the preceding claims, characterized characterized in that the combinable and / or the combined Composition containing a volatile oil / contains. Kit according to one of the preceding claims, characterized characterized in that the combinable and / or the combined Composition containing an organic solvent phase / contains. Kit according to one of the preceding claims, characterized characterized in that the combinable and / or the combined Composition in addition a powdery Contains / contains compound those among the pigments and / or pearlescent pigments and / or fillers and / or mixtures thereof is. Non-therapeutic procedure for applying make-up Skin, mucous membranes, Semi-mucous membranes and / or the skin appendages of the human that consists in the combined Composition before or after the so-called combinable composition of the kit according to any one of the preceding claims on the skin, the mucous membranes, the semi-mucous membranes and / or human skin appendages. Use of the make-up kit of any one of claims 1 to 9 to form a make-up to get a good grip and / or without transmission.