KR20010067070A - A Printing Ink composition and Film for a Patterned Wood Using the Same - Google Patents

A Printing Ink composition and Film for a Patterned Wood Using the Same Download PDF

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Publication number
KR20010067070A
KR20010067070A KR1020000046523A KR20000046523A KR20010067070A KR 20010067070 A KR20010067070 A KR 20010067070A KR 1020000046523 A KR1020000046523 A KR 1020000046523A KR 20000046523 A KR20000046523 A KR 20000046523A KR 20010067070 A KR20010067070 A KR 20010067070A
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South Korea
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parts
weight
printing ink
resin
film
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KR1020000046523A
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Korean (ko)
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황성배
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황성배
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Priority claimed from KR2019990027494U external-priority patent/KR200183141Y1/en
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Priority to KR1020000046523A priority Critical patent/KR20010067070A/en
Publication of KR20010067070A publication Critical patent/KR20010067070A/en

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C08J2323/12—Polypropene

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

PURPOSE: Provided are a printing ink composition and film for grained timber by using the same, which have excellent in printability by adding an acrylic resin, an urethane resin and a vinyl resin. CONSTITUTION: The composition is characterized by mixing printing ink I with printing ink II in a ratio of 6:4-7:3, wherein, the printing ink I contains i) 10.0-15.0pts.wt. of vinyl-based resin; ii) 2.0-4.0pts.wt. of ethylenevinylacetate copolymer; iii) 1.0-3.0pts.wt. of maleic acid resin; iv) 20.0-30.0pts.wt. of titanium; v)0.1-2.0pts.wt. of polyethylene wax; vi) 2.0-5.0pts.wt. of chloro-substituted polypropylene; vii) 3.0-7.0pts.wt. of silica; and viii) 45.0-49.0pts.wt. of a solvent, and the printing ink II contains ix) 5.0-10.0pts.wt. of acrylic-based resin; x) 20.0-25.0pts.wt. of vinyl-based resin; xi) 5.0-10.0pts.wt. of polyurethane resin; xii) 2.0-5.0pts.wt. of ethylenevinylacetate copolymer; xiii) 12.0-15.0pts.wt. of chloro-substituted polypropylene; 14) 5.0-10.0pts.wt. of a hardening agent; and 15) 3.0-38.0pts.wt. of a solvent.

Description

인쇄잉크 조성물 및 이를 이용하여 제조되는 무늬목용 필름{A Printing Ink composition and Film for a Patterned Wood Using the Same}A printing ink composition and film for a patterned wood using the same

본 발명은 무늬목용 필름의 무늬목을 인쇄하기 위해 사용하는 인쇄잉크에 관한 것으로 보다 상세하게는 아크릴계수지, 우레탄계 수지 및 비닐계 수지를 첨가하여 우수한 인쇄성을 갖는 인쇄잉크 조성물을 제조하고 PP필름의 이면에 본발명의 인쇄잉크를 사용하여 무늬목을 인쇄하고 무늬목이 인쇄된 PP필름을 접착층이 형성되어 있는 화장판과 냉압 프레스 또는 가열로라 프레스를 사용하여 부착함으로서 투명 PP무광필름층과 인쇄층 및/또는 인쇄층과 화장판이 박리가 되지 않으면서 표면코팅 등의 별도의 후가공 없이 무늬목을 제작할 수 있는 무늬목용 필름에 관한 것이다.The present invention relates to a printing ink used to print a veneer of a veneer film, and more particularly, to a printing ink composition having excellent printability by adding an acrylic resin, a urethane resin, and a vinyl resin. The printed PP film using the printing ink of the present invention is applied to the transparent PP matt film layer and the printing layer and / or by attaching the PP film on which the veneer is printed using a decorative plate having an adhesive layer and a cold press or a heating roller press. It relates to a film for veneer that can produce veneer without separate post-processing such as surface coating without peeling the printing layer and the makeup plate.

경제의 발전에 따라, 현대의 가구산업과 실내장식분야는 괄목할만한 성장을 보이며, 화학 제품보다 천연 소재를 많이 요구하고 있다. 그러나 천연소재 중에서 목재의 경우, 고갈되어 가는 산림자원, 기후의 변화 등으로 인하여 동일한 무늬와 색상을 가진 결점이 없는 목재와 자연 무늬목을 원하는 만큼 공급받기가 어려운 실정이며, 적기에 공급받기는 갈수록 어려워지는 것이 현실이다. 그래서 합판이나 수지판을 원목을 대신하여 사용하는 예가 증가하고 있으며, 이러한 합판이나 수지판을 원목대신 사용할 때 그 표면에 무늬목 인쇄종이나 무늬목 필름을 부착하여 원목무늬 효과를 얻고 있다.As the economy develops, the modern furniture and upholstery sectors have seen remarkable growth, requiring more natural materials than chemicals. However, in the case of wood among natural materials, it is difficult to supply as many woods and natural veneers with the same pattern and color as they want due to depleted forest resources and climate change. Losing is a reality. Thus, the use of plywood or resin boards in place of wood is increasing, and when using the plywood or resin boards instead of wood, the woodwork effect is obtained by attaching a veneer print species or a wood film on the surface.

이러한 화장판에 원목무늬의 효과를 낼 수 있는 종래의 기술에는 물체에 의도하는 모양을 인쇄하는 방법으로 일본특허공고 소화 제52-41682호에 의한 전사하는 방법을 개시하고 있다. 그러나 이 방법은 전기 박질막을 물체 표면에서 제거하였기 때문에 패턴인쇄를 행하는 박질막이 오브라이트의 모양으로 팽윤성, 즉 전개성이 양호한 것과 유연성 연화성이 큰 것이 바람직하고, 특히 소개 표면의 요철이 복잡한 경우에는 박질막이 펼쳐진 요철면에 밀착하는 것이 요구되었다. 따라서 이와 같은 특수한 박질막을 수면에 띄우는 경우, 그 위에 인쇄한 패턴은 전사 이전에이미 현저히 확장되어 변형되어 버리기 때문에 물체의 표면에 인쇄를 통하여 패턴을 얻으려는 소기의 목적을 달성할 수 없었다.The prior art which can produce the effect of a wooden pattern on such a decorative board discloses the method of transferring by Japanese Patent Laid-Open No. 52-41682 by printing an intended shape on an object. However, in this method, since the thin film is removed from the surface of the object, it is preferable that the thin film to be printed on the pattern is in the shape of an ore, which has good swelling property, that is, good development and high softening softness. It was required to adhere to the uneven surface on which the thin film was unfolded. Therefore, when such a special thin film floats on the water surface, the pattern printed thereon is already significantly expanded and deformed before the transfer, and thus the desired purpose of obtaining the pattern through printing on the surface of the object cannot be achieved.

무늬목을 인쇄하는 방법으로는 도2에 도시한 바와 같이 종이(11)의 표면에 나무결 무늬의 인쇄면(12)을 구비하고, 그 인쇄면(12) 위에 아크릴, 호마이카, 불포화수지 등의 멜라민계 코팅층(13)을 형성함으로서 구성하였으나, 이는 기초재질이 종이(11)이므로 쉽게 찢어지는 등의 문제점이 있었을 뿐만 아니라, 코팅층(13)이 갖는 광택으로 인하여 제품의 질이 저하되는 문제점도 있었다.As a method of printing a veneer, as shown in Fig. 2, the surface of the paper 11 is provided with a wood-coated printing surface 12, and on the printing surface 12, a melamine-based resin such as acrylic, homica, and unsaturated resins. It was configured by forming the coating layer 13, but this is because the base material is a paper 11, there was a problem such as easy tearing, there is also a problem that the quality of the product is degraded due to the gloss of the coating layer (13).

또한 종래의 무늬목 필름은 도3에 도시한 바와 같이 불투명 PVC필름(21) 표면에 나무결 무늬의 인쇄면(22)을 구비하고, 그 인쇄면(22)의 위에 다시 투명 PVC필름(23)을 코팅하는 것으로 구성되었으나, 이는 코팅된 투명 PVC필름(23)이 갖는 고유한 광택으로 인하여 제품의 질이 저하되는 문제점이 있었다.In addition, the conventional veneer film has a wood-coated printing surface 22 on the surface of the opaque PVC film 21 as shown in FIG. 3, and the transparent PVC film 23 is coated on the printing surface 22 again. It was configured to, but this was a problem that the quality of the product is degraded due to the inherent gloss of the coated transparent PVC film 23.

특히 상기의 무늬목 인쇄지나 무늬목 필름은 나무결 무늬를 인쇄한 후 그 위에 코팅작업을 하면 위면으로 노출되는 인쇄면(12)(22)을 보호하는 후가공이 필요한 것이므로 작업성이 저하되는 문제점이 있었다.In particular, the above-mentioned veneer printing paper or veneer film has a problem in that workability is deteriorated because it requires post-processing to protect the printed surfaces 12 and 22 exposed to the upper surface when the wood work pattern is printed and coated thereon.

또한 종래의 인쇄잉크를 사용하여 PVC필름에 무늬목을 인쇄한 후 그 무늬목이 인쇄된 층과 기판과의 접착하였을 경우 PVC필름층과 무늬목 인쇄층 및/또는 접착층과 기판층이 박리가 발생하여 무늬목용 필름의 질을 저하시키는 문제가 있었다.In addition, when the veneer is printed on a PVC film using a conventional printing ink, when the veneer is bonded to the printed layer and the substrate, the PVC film layer and the veneer printed layer and / or the adhesive layer and the substrate layer are peeled off. There was a problem of degrading the quality of the film.

본 발명은 상기와 같은 종래 기술의 문제점을 해결하기 위해 안출된 것으로The present invention has been made to solve the problems of the prior art as described above

본 발명자들은 투명 PP무광필름층과 인쇄층 및/또는 인쇄층과 화장판 사이가 박리가 되지 않으면서 인쇄성이 우수한 인쇄잉크를 개발하기 위해 예의 연구 노력한 결과, 아크릴계수지, 우레탄계 수지 및 비닐계 수지를 첨가하여 우수한 인쇄성과 투명 PP무광필름층과 인쇄층 및/또는 인쇄층과 화장판 사이가 박리 되지 않는 인쇄잉크를 개발하는데 성공하였다.The present inventors have diligently researched to develop a printing ink having excellent printability without peeling between the transparent PP matt film layer and the printing layer and / or the printing layer and the decorative plate, and thus, acrylic resins, urethane resins and vinyl resins. The addition of s (2) was successful in developing a printing ink which is excellent in printability and does not peel off between the transparent PP matt film layer and the printing layer and / or the printing layer and the decorative plate.

또한, 투명 PP무광필름의 이면에 본 발명의 인쇄잉크를 사용하여 무늬목을 인쇄한 후 접착층이 형성되어 있는 화장판과 냉압 프레스 또는 가열로라 프레스를 사용하여 표면코팅 등의 별도의 후가공 없이 무늬목을 제작할 수 있는 우수한 품질의 무늬목용 필름을 형성할 수 있음을 확인하고 본 발명을 완성하게 되었다.In addition, after printing the veneer using the printing ink of the present invention on the back side of the transparent PP matte film, it is possible to produce veneer without a separate post-processing such as surface coating using a decorative plate and a cold press or a heating roller press having an adhesive layer formed thereon. It was confirmed that it is possible to form a film for veneer of good quality and completed the present invention.

결국, 본 발명의 목적은 투명 PP무광필름층과 인쇄층 및/또는 인쇄층과 화장판이 박리가 되지 않으면서 인쇄성이 개선된 인쇄잉크 조성물을 제공하는 것이다.After all, it is an object of the present invention to provide a printing ink composition having improved printability without peeling off the transparent PP matt film layer and the print layer and / or the print layer and the decorative plate.

본 발명의 다른 목적은 상기의 인쇄잉크 조성물을 이용하여 제조하는 무늬목용 필름을 제공하는 것이다.Another object of the present invention is to provide a film for veneer to be produced using the printing ink composition.

도1은 본 발명의 인쇄잉크 조성물을 사용한 무늬목 필름을 보인 단면도1 is a cross-sectional view showing a veneer film using the printing ink composition of the present invention

도2는 종래의 무늬목 인쇄지를 보인 단면도Figure 2 is a cross-sectional view showing a conventional veneer printing paper

도3은 종래의 무늬목 필름을 보인 단면도Figure 3 is a cross-sectional view showing a conventional veneer film

*도면의 주요 부분에 대한 부호의 설명** Description of the symbols for the main parts of the drawings *

1: 투명 PP무광필름층 2: 무늬목 인쇄층1: transparent PP matt film layer 2: veneer printed layer

3: 접착층 4: 화장판3: adhesive layer 4: decorative plate

11: 종이 12: 인쇄면11: paper 12: printing surface

13: 코팅층 21: 불투명PVC필름13: coating layer 21: opaque PVC film

22: 인쇄면 23: 투명PVC필름22: print side 23: transparent PVC film

이하, 본 발명을 보다 구체적으로 설명하기로 한다.Hereinafter, the present invention will be described in more detail.

본 발명의 목적을 달성하기 위한 인쇄잉크는 무늬목용 필름의 투명 PP무광필름층(1)과 인쇄층(2) 및 인쇄층(2)과 화장판(4)이 박리되지 않는 인쇄층(2)의 무늬목을 형성하는 인쇄잉크에 관한 것으로 10.0∼15.0중량부의 비닐계수지, 2.0∼4.0중량부의 에틸렌비닐아세테이트 공중합체, 1.0∼3.0중량부의 말레인산 수지, 20.0∼30.0중량부의 타이타늄, 0.1∼2.0중량부의 폴리에틸렌왁스, 2.0∼5.0중량부의 염소가 치환된 폴리프로필렌, 3.0∼7.0중량부의 실리카 및 45.0∼49.0중량부의 용매를 혼합하여 제조하는 인쇄잉크I에 5.0∼10.0중량부의 아크릴계 수지, 20.0∼25.0중량부의 비닐계수지, 5.0∼10.0중량부의 폴리우레탄 수지, 2.0∼5.0중량부의 에틸렌비닐아세테이트 공중합체, 12.0∼15.0중량부의 염소가 치환된 폴리프로필렌, 5.0∼10.0중량부의 경화제 및 30.0∼38.0중량부의 용매를 혼합한 인쇄잉크II를 배합하여 제조되는 것을 특징으로 한다.The printing ink for achieving the object of the present invention is a transparent PP matt film layer (1) and the print layer (2) of the veneer film (2) and the print layer (2) and the decorative plate (4) is not peeled off 10.0-15.0 parts by weight of vinyl resin, 2.0-4.0 parts by weight of ethylene vinyl acetate copolymer, 1.0-3.0 parts by weight of maleic acid resin, 20.0-30.0 parts by weight of titanium, 0.1-2.0 parts by weight 5.0-10.0 parts by weight of acrylic resin, 20.0-25.0 parts by weight of printing ink I prepared by mixing polyethylene wax, polypropylene substituted with 2.0 to 5.0 parts by weight of chlorine, 3.0 to 7.0 parts by weight of silica, and 45.0 to 49.0 parts by weight of solvent. Vinyl resin, 5.0-10.0 parts by weight of polyurethane resin, 2.0-5.0 parts by weight of ethylene vinyl acetate copolymer, 12.0-15.0 parts by weight of chlorine-substituted polypropylene, 5.0-10.0 parts by weight of curing agent and 30.0-38.0 parts by weight of solvent It is characterized in that it is prepared by mixing the mixed printing ink II.

상기에서 인쇄잉크I과 인쇄잉크II의 혼합비율은 6:4 내지 7:3의 중량비율로 구성되는 것이 바람직하고, 인쇄잉크I과 인쇄잉크II에 사용하는 용매는 메틸에테르케톤, 에틸아세테이트, 톨루엔 및 아세톤에서 선택된 일종 이상의 것을 사용하는 것이 바람직하다.The mixing ratio of the printing ink I and the printing ink II is preferably composed of a weight ratio of 6: 4 to 7: 3, and the solvent used for the printing ink I and the printing ink II is methyl ether ketone, ethyl acetate, toluene. And at least one selected from acetone.

또한, 투명 PP무광필름의 이면에 상기의 인쇄잉크I과 인쇄잉크II의 혼합에 의한 인쇄잉크를 사용하여 무늬목을 인쇄한 후 접착층(3)이 형성되어 있는 화장판(4)과 냉압 프레스 또는 가열로라 프레스로 접착하여 무늬목용 필름을 제조하는 것을 특징으로 한다.In addition, after printing the veneer using the printing ink by mixing the printing ink I and the printing ink II on the back side of the transparent PP matt film, the decorative plate 4 having the adhesive layer 3 formed thereon and cold press or heating It is characterized by producing a film for veneer by adhering with a roller press.

본 발명에서 사용하는 비닐계 수지인 VAGH 또는 VMCH는 미국의 유니온 카바이드사(UNION CARBIDE CO., LTD)의 제품을 사용하였고 흰색의 미세한 분말로 자연발화점이 390℃이며 분자량이 5,000∼30,000인 것을 사용하며 인쇄잉크의 작업성을 용이하게 위해서 점도를 조절하기 위해서는 15,000∼25,000인 것을 사용하는 것이 보다 바람직하다.VAGH or VMCH, a vinyl resin used in the present invention, is a product of Union Carbide Co., Ltd. of the United States. The white powder is a fine powder having a natural ignition point of 390 ° C. and a molecular weight of 5,000 to 30,000. In order to adjust the viscosity to facilitate the workability of the printing ink, it is more preferable to use 15,000 to 25,000.

왁스성분의 폴리에틸렌 왁스인 LUWAX A는 바스프사(BASF CO., LTD)의 제품을사용하였고 녹는점은 98∼108℃이고 밀도는 0.91∼0.93g/cm3이고 물이나 유기용매에 모두 잘 녹는다.A polyethylene wax of the wax component A LUWAX the BASF Corporation (BASF CO., LTD) was used of the product melting point of 98~108 ℃ and density 0.91~0.93g / cm 3 and melt all well in water or an organic solvent.

에틸렌비닐아세테이트공중합체인 EVAFLEX는 순한 에스테르 냄새가 나는 고체 펠렛 형태로 되어 있다.EVAFLEX, an ethylene vinyl acetate copolymer, is in the form of a solid pellet with a mild ester odor.

염소가 치환된 폴리프로필렌인 HARDREN 13LP-P 및 HARDREN 16LP-P 토요 카세이 코교 사(TOYO KASEI KOGYO CO., LTD) 제품으로 바인더 수지로 사용되며 냄새가 없는 백색의 알갱이이다.HARDREN 13LP-P and HARDREN 16LP-P, a chlorine-substituted polypropylene, are manufactured by TOYO KASEI KOGYO CO., LTD. And used as binder resin.

또한 바인더 수지로 사용되는 폴리에스터 폴리올은 NIPPOLLAN 1004는 일본 폴리우레탄 산업사(NIPPON POLYURETHANE IND CO., LTD) 제품으로 노란색의 투명한 액체로 냄새가 없고 비중은 1. 16이고, 점도는 750cps이다.The polyester polyol used as the binder resin is NIPPOLLAN 1004, a product made by Nippon Polyurethane Industries Co., Ltd., a yellow transparent liquid, odorless, specific gravity of 1.16, and viscosity of 750 cps.

이하 실시예에 의하여 본 발명을 보다 구체적으로 설명하고자 한다. 이들 실시예는 오로지 본 발명을 설명하기 위한 것으로, 본 발명의 요지에 따라 본 발명의 범위가 이들 실시예에 국한되지 않는다는 것은 당업계에서 통상의 지식을 가진 자에게 자명할 것이다.Hereinafter, the present invention will be described in more detail with reference to the following examples. These examples are only for illustrating the present invention, and it will be apparent to those skilled in the art that the scope of the present invention is not limited to these examples according to the gist of the present invention.

다음의 표1에는 본 발명에서 사용하는 성분의 상품명을 나타내었다.Table 1 below shows the trade names of the components used in the present invention.

[실시예1] 10.0중량부의 비닐계수지, 2.0중량부의 에틸렌비닐아세테이트 공중합체, 1.0중량부의 말레인산 수지, 20.0중량부의 타이타늄, 1.0중량부의 폴리에틸렌왁스, 2.0중량부의 염소가 치환된 폴리프로필렌, 3.0중량부의 실리카 및 45.0중량부의 용매를 혼합하여 인쇄잉크I을 제조하였고 5.0중량부의 아크릴계 수지, 20.0중량부의 비닐계수지, 5.0중량부의 폴리우레탄 수지, 2.0중량부의 에틸렌비닐아세테이트 공중합체, 12.0중량부의 염소가 치환된 폴리프로필렌, 5.0중량부의 경화제 및 35.0중량부의 용매를 혼합한 인쇄잉크II를 제조하였다. 인쇄잉크I과 인쇄잉크II를 6:4의 중량비로 혼합하여 본 발명에서 사용할 최종 인쇄잉크를 제조하였다.Example 1 10.0 parts by weight of vinyl resin, 2.0 parts by weight of ethylene vinyl acetate copolymer, 1.0 parts by weight of maleic acid resin, 20.0 parts by weight of titanium, 1.0 parts by weight of polyethylene wax, 2.0 parts by weight of propylene substituted polypropylene, 3.0 parts by weight Printing ink I was prepared by mixing parts of silica and 45.0 parts by weight of solvent, and 5.0 parts by weight of acrylic resin, 20.0 parts by weight of vinyl resin, 5.0 parts of polyurethane resin, 2.0 parts by weight of ethylene vinyl acetate copolymer, 12.0 parts by weight of chlorine Printing Ink II was prepared by mixing substituted polypropylene, 5.0 parts by weight of curing agent and 35.0 parts by weight of solvent. Print Ink I and Print Ink II were mixed at a weight ratio of 6: 4 to prepare a final printing ink for use in the present invention.

[실시예2] 10.0중량부의 비닐계수지, 2.0중량부의 에틸렌비닐아세테이트 공중합체, 1.0중량부의 말레인산 수지, 22.0중량부의 타이타늄, 1.0중량부의 폴리에틸렌왁스, 3.0중량부의 염소가 치환된 폴리프로필렌, 4.0중량부의 실리카 및 45.0중량부의 용매를 혼합하여 인쇄잉크I을 제조하였고 7.0중량부의 아크릴계 수지, 22.0중량부의 비닐계수지, 7.0중량부의 폴리우레탄 수지, 3.0중량부의 에틸렌비닐아세테이트 공중합체, 12.0중량부의 염소가 치환된 폴리프로필렌, 6.0중량부의 경화제 및 35.0중량부의 용매를 혼합한 인쇄잉크II를 제조하였다. 인쇄잉크I과 인쇄잉크II를 6:4의 중량비로 혼합하여 본 발명에서 사용할 최종 인쇄잉크를 제조하였다.Example 2 10.0 parts by weight of vinyl resin, 2.0 parts by weight of ethylene vinyl acetate copolymer, 1.0 parts by weight of maleic acid resin, 22.0 parts by weight of titanium, 1.0 parts by weight of polyethylene wax, 3.0 parts by weight of propylene substituted polypropylene, 4.0 parts by weight Printing ink I was prepared by mixing parts silica and 45.0 parts by weight of solvent, and 7.0 parts by weight of acrylic resin, 22.0 parts by weight of vinyl resin, 7.0 parts by weight of polyurethane resin, 3.0 parts by weight of ethylene vinyl acetate copolymer, 12.0 parts by weight of chlorine Printing Ink II was prepared by mixing substituted polypropylene, 6.0 parts by weight of curing agent and 35.0 parts by weight of solvent. Print Ink I and Print Ink II were mixed at a weight ratio of 6: 4 to prepare a final printing ink for use in the present invention.

[실시예3] 13.0중량부의 비닐계수지, 2.0중량부의 에틸렌비닐아세테이트 공중합체, 1.0중량부의 말레인산 수지, 25.0중량부의 타이타늄, 1.0중량부의 폴리에틸렌왁스, 3.0중량부의 염소가 치환된 폴리프로필렌, 5.0중량부의 실리카 및 45.0중량부의 용매를 혼합하여 인쇄잉크I을 제조하였고 7.0중량부의 아크릴계 수지, 23.0중량부의 비닐계수지, 8.0중량부의 폴리우레탄 수지, 3.0중량부의 에틸렌비닐아세테이트 공중합체, 13.0중량부의 염소가 치환된 폴리프로필렌, 7.0중량부의 경화제 및 35.0중량부의 용매를 혼합한 인쇄잉크II를 제조하였다. 인쇄잉크I과 인쇄잉크II를 7:3의 중량비로 혼합하여 본 발명에서 사용할 최종 인쇄잉크를 제조하였다.Example 3 13.0 parts vinyl resin, 2.0 parts ethylene vinyl acetate copolymer, 1.0 parts maleic acid resin, 25.0 parts titanium, 1.0 parts polyethylene wax, 3.0 parts chlorine substituted polypropylene, 5.0 parts Printing ink I was prepared by mixing parts silica and 45.0 parts by weight of solvent, and 7.0 parts by weight of acrylic resin, 23.0 parts by weight of vinyl resin, 8.0 parts by weight of polyurethane resin, 3.0 parts by weight of ethylene vinyl acetate copolymer, 13.0 parts by weight of chlorine Printing Ink II was prepared by mixing substituted polypropylene, 7.0 parts by weight of curing agent and 35.0 parts by weight of solvent. Print Ink I and Print Ink II were mixed at a weight ratio of 7: 3 to prepare a final printing ink for use in the present invention.

[실시예4] 15.0중량부의 비닐계수지, 4.0중량부의 에틸렌비닐아세테이트 공중합체, 1.0중량부의 말레인산 수지, 28.0중량부의 타이타늄, 1.0중량부의 폴리에틸렌왁스, 4.0중량부의 염소가 치환된 폴리프로필렌, 6.0중량부의 실리카 및 45.0중량부의 용매를 혼합하여 인쇄잉크I을 제조하였고 8.0중량부의 아크릴계 수지, 24.0중량부의 비닐계수지, 9.0중량부의 폴리우레탄 수지, 4.0중량부의 에틸렌비닐아세테이트 공중합체, 13.0중량부의 염소가 치환된 폴리프로필렌, 8.0중량부의 경화제 및 35.0중량부의 용매를 혼합한 인쇄잉크II를 제조하였다. 인쇄잉크I과 인쇄잉크II를 7:3의 중량비로 혼합하여 본 발명에서 사용할 최종 인쇄잉크를 제조하였다.EXAMPLE 4 15.0 parts by weight of vinyl resin, 4.0 parts by weight of ethylene vinyl acetate copolymer, 1.0 parts by weight of maleic acid resin, 28.0 parts by weight of titanium, 1.0 parts by weight of polyethylene wax, 4.0 parts by weight of propylene substituted polypropylene, 6.0 parts by weight Printing ink I was prepared by mixing a part of silica and 45.0 parts by weight of a solvent. 8.0 parts by weight of acrylic resin, 24.0 parts by weight of vinyl resin, 9.0 parts by weight of polyurethane resin, 4.0 parts by weight of ethylene vinyl acetate copolymer, 13.0 parts by weight of chlorine Printing Ink II was prepared by mixing substituted polypropylene, 8.0 parts by weight of curing agent and 35.0 parts by weight of solvent. Print Ink I and Print Ink II were mixed at a weight ratio of 7: 3 to prepare a final printing ink for use in the present invention.

[실시예5] 15.0중량부의 비닐계수지, 4.0중량부의 에틸렌비닐아세테이트 공중합체, 1.0중량부의 말레인산 수지, 30.0중량부의 타이타늄, 1.0중량부의 폴리에틸렌왁스, 5.0중량부의 염소가 치환된 폴리프로필렌, 7.0중량부의 실리카 및 45.0중량부의 용매를 혼합하여 인쇄잉크I을 제조하였고 10.0중량부의 아크릴계 수지, 25.0중량부의 비닐계수지, 10.0중량부의 폴리우레탄 수지, 5.0중량부의 에틸렌비닐아세테이트 공중합체, 15.0중량부의 염소가 치환된 폴리프로필렌, 10.0중량부의 경화제 및 35.0중량부의 용매를 혼합한 인쇄잉크II를 제조하였다. 인쇄잉크I과 인쇄잉크II를 7:3의 중량비로 혼합하여 본 발명에서 사용할 최종 인쇄잉크를 제조하였다.Example 5 15.0 parts vinyl resin, 4.0 parts ethylene vinyl acetate copolymer, 1.0 parts maleic acid resin, 30.0 parts titanium, 1.0 parts polyethylene wax, 5.0 parts chlorine substituted polypropylene, 7.0 parts Printing ink I was prepared by mixing parts silica and 45.0 parts by weight of solvent, and 10.0 parts by weight of acrylic resin, 25.0 parts by weight of vinyl resin, 10.0 parts by weight of polyurethane resin, 5.0 parts by weight of ethylene vinyl acetate copolymer, 15.0 parts by weight of chlorine Printing Ink II was prepared by mixing substituted polypropylene, 10.0 parts by weight of curing agent and 35.0 parts by weight of solvent. Print Ink I and Print Ink II were mixed at a weight ratio of 7: 3 to prepare a final printing ink for use in the present invention.

본 발명의 인쇄잉크 조성물을 다음의 표2와 같이 혼합 조제하였다.The printing ink composition of the present invention was prepared by mixing as shown in Table 2 below.

또한, 본 발명의 인쇄잉크를 사용한 무늬목용 필름을 제조하기 위해 사용되는 투명 PP무광필름의 다음의 표3과 같은 물리적 특성을 갖는 한국의 화승인더스트리 사의 제품을 사용하였다.In addition, a product of Hwaseung Industries Co., Ltd., Korea, which has the physical properties as shown in Table 3 below, was used for producing a veneer film using the printing ink of the present invention.

합판이나 수지판 등의 화장판(4) 표면에 부착되어 원목의 효과를 얻을 수 있도록 하는 무늬목 필름에 있어서, 상기의 표3의 특성을 갖는 투명 PP무광필름층(1)의 이면에 상기의 실시예에서 제조한 인쇄잉크를 사용하여 무늬목 인쇄층(2)을 형성하고 그 무늬목 인쇄층(2)을 상기 접착층(3)이 형성되어 있는 합판이나 수지판 등의 화장판(4)에 냉압 프레스 또는 가열로라 프레스로 부착하여 무늬목이 인쇄된 필름을 얻는다.In the veneer film which is attached to the surface of the decorative board 4 such as plywood or resin board to obtain the effect of solid wood, the above-described implementation is performed on the back surface of the transparent PP matt film layer 1 having the characteristics shown in Table 3 above. The veneer printed layer 2 is formed by using the printing ink manufactured in the example, and the veneer printed layer 2 is cold pressed or pressed onto a decorative board 4 such as plywood or resin plate on which the adhesive layer 3 is formed. It is attached by a heating roller press to obtain a film printed with veneer.

이와 같이 구성된 본 발명은 투명 PP무광필름(1)의 이면에 본 발명의 인쇄잉크를 사용하여 무늬목 인쇄층(2)을 형성하고, 그 인쇄층(2)을 합판이나 수지판 등의 화장판(4) 등에 부착함으로서 투명 PP무광필름(1)을 합판이나 수지판 등이 화장판(4)에 부착하면 인쇄층(2)의 위에 투명 PP무광필름(1)이 구비되므로 코팅작업과 같은 별도의 후가공작업이 필요 없게 되어 생산성을 향상시킬 수 있게 된다.According to the present invention configured as described above, the veneer printing layer 2 is formed on the back surface of the transparent PP matt film 1 by using the printing ink of the present invention, and the printing layer 2 is made of a decorative board such as plywood or resin plate ( 4) When the transparent PP matte film 1 is attached to the plywood or resin board to the decorative plate 4 by attaching it to the back, the transparent PP matte film 1 is provided on the printing layer 2, so that the separate This eliminates the need for post-processing and improves productivity.

또한, 광택이 없는 투명 PP무광필름을 사용함으로서 제품의 품질을 향상시킬 수 있을 뿐만 아니라, 인쇄층(2)의 무늬목 효과를 높일 수 있게 되는 것이다.In addition, by using a matte transparent PP matte film can not only improve the quality of the product, but also improve the veneer effect of the printing layer (2).

이상에서 살펴본 바와 같이 본 발명에 의한 인쇄잉크는 투명 PP무광필름의 이면에 본 발명의 인쇄잉크를 사용하여 무늬목 인쇄층을 형성하고, 그 무늬목이 인쇄된 인쇄층을 접착층이 형성되어 있는 합판이나 수지판 등의 화장판에 냉압 프레스 또는 가열로라 프레스를 사용하여 부착함으로서 투명 PP무광필름층과 인쇄층 및 인쇄층과 화장판이 박리가 되지 않으면서 인쇄층와 화장판의 접착을 용이하게 하여 생산성을 향상할 수 있고, 인쇄 무늬목이 품질을 향상시킬 수 있는 우수한 효과가 있다.As described above, the printing ink according to the present invention uses a printing ink of the present invention on the back side of the transparent PP matt film to form a plywood print layer, and the plywood or resin on which the adhesive layer is formed. By using cold press or heating roller press on the plate such as plate, it is possible to improve productivity by facilitating adhesion of the printed layer and the plate without peeling off the transparent PP matte film layer, printing layer, and printing layer. And the printing veneer has an excellent effect of improving the quality.

Claims (4)

10.0∼15.0중량부의 비닐계수지, 2.0∼4.0중량부의 에틸렌비닐아세테이트 공중합체, 1.0∼3.0중량부의 말레인산 수지, 20.0∼30.0중량부의 타이타늄, 0.1∼2.0중량부의 폴리에틸렌왁스, 2.0∼5.0중량부의 염소가 치환된 폴리프로필렌, 3.0∼7.0중량부의 실리카 및 45.0∼49.0중량부의 용매를 혼합하여 제조하는 인쇄잉크I에 5.0∼10.0중량부의 아크릴계 수지, 20.0∼25.0중량부의 비닐계수지, 5.0∼10.0중량부의 폴리우레탄 수지, 2.0∼5.0중량부의 에틸렌비닐아세테이트 공중합체, 12.0∼15.0중량부의 염소가 치환된 폴리프로필렌, 5.0∼10.0중량부의 경화제 및 30.0∼38.0중량부의 용매를 혼합한 인쇄잉크II를 배합하여 무늬목용 필름의 인쇄층에 사용하는 것을 특징으로 하는 인쇄잉크.10.0 to 15.0 parts by weight of vinyl resin, 2.0 to 4.0 parts by weight of ethylene vinyl acetate copolymer, 1.0 to 3.0 parts by weight of maleic acid resin, 20.0 to 30.0 parts by weight of titanium, 0.1 to 2.0 parts by weight of polyethylene wax, 2.0 to 5.0 parts by weight of chlorine 5.0 to 10.0 parts by weight of acrylic resin, 20.0 to 25.0 parts by weight of vinyl resin, 5.0 to 10.0 parts by weight of polyvinyl substituted resin, printing ink I prepared by mixing 3.0 to 7.0 parts by weight of silica and 45.0 to 49.0 parts by weight of solvent Urethane resin, 2.0 to 5.0 parts by weight of ethylene vinyl acetate copolymer, 12.0 to 15.0 parts by weight of chlorine-substituted polypropylene, 5.0 to 10.0 parts by weight of curing agent, and 30.0 to 38.0 parts by weight of the mixed printing ink II for the veneer A printing ink, which is used for a printing layer of a film. 제1항에 있어서, 인쇄잉크I과 인쇄잉크II의 혼합비율은 6:4 내지 7:3의 중량비율로 배합하여 무늬목용 필름의 인쇄층에 사용하는 것을 특징으로 하는 인쇄잉크.The printing ink according to claim 1, wherein the mixing ratio of the printing ink I and the printing ink II is blended in a weight ratio of 6: 4 to 7: 3 and used for the printing layer of the veneer film. 제1항에 있어서, 인쇄잉크I과 인쇄잉크II에 사용하는 용매는 메틸에테르케톤, 에틸아세테이트, 톨루엔 및 아세톤 중에서 선택된 하나 또는 둘 이상을 혼합하여 무늬목용 필름의 인쇄층에 사용하는 것을 특징으로 하는 인쇄잉크.The method of claim 1, wherein the solvent used for the printing ink I and the printing ink II is mixed with one or two or more selected from methyl ether ketone, ethyl acetate, toluene and acetone is used for the printing layer of veneer film Printing ink. 제 1항 내지 제 3항의 인쇄잉크를 인쇄층으로 사용하는 무늬목 필름에 있어서, 투명 PP무광필름층의 이면에 무늬목 인쇄층을 형성하고 그 무늬목 인쇄층을 접착층이 형성되어 있는 합판이나 수지판 등의 화장판에 냉압프레스 또는 가열로라 프레스로 부착하여서 됨을 특징으로 하는 무늬목용 무광필름.In the veneer film using the printing ink of claim 1 as a printing layer, a veneer print layer is formed on the back side of the transparent PP matte film layer, and the veneer print layer is formed of a plywood or resin plate. The matte film for veneer, characterized in that attached to the decorative plate by a cold press or a heating roller press.
KR1020000046523A 1999-12-08 2000-08-11 A Printing Ink composition and Film for a Patterned Wood Using the Same KR20010067070A (en)

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KR2019990027494U KR200183141Y1 (en) 1999-12-08 1999-12-08 A dim film structure for a patterned wood
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115284762A (en) * 2022-09-14 2022-11-04 四川蓝剑金印股份有限公司 Holographic positioning screen printing wrinkle ink method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH045042A (en) * 1990-04-23 1992-01-09 Sakata Corp Laminate finishing and laminate-finished product
JPH04213375A (en) * 1990-12-11 1992-08-04 Dainippon Ink & Chem Inc Gravure ink for heat lamination
JP2000033675A (en) * 1998-07-16 2000-02-02 Dainippon Printing Co Ltd Decorative sheet
KR200183141Y1 (en) * 1999-12-08 2000-05-15 황성배 A dim film structure for a patterned wood
KR100305103B1 (en) * 1999-05-19 2001-10-18 유광선 UV-curing adhesive transfer ink

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH045042A (en) * 1990-04-23 1992-01-09 Sakata Corp Laminate finishing and laminate-finished product
JPH04213375A (en) * 1990-12-11 1992-08-04 Dainippon Ink & Chem Inc Gravure ink for heat lamination
JP2000033675A (en) * 1998-07-16 2000-02-02 Dainippon Printing Co Ltd Decorative sheet
KR100305103B1 (en) * 1999-05-19 2001-10-18 유광선 UV-curing adhesive transfer ink
KR200183141Y1 (en) * 1999-12-08 2000-05-15 황성배 A dim film structure for a patterned wood

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115284762A (en) * 2022-09-14 2022-11-04 四川蓝剑金印股份有限公司 Holographic positioning screen printing wrinkle ink method

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