KR20010052881A - Plasma display panel with superior light-emitting characteristics, and method and apparatus for producing the plasma display panel - Google Patents

Abstract

PDP with excellent luminescence properties and color reproduction sets the chromaticity coordinate y (CIE color designation) of the light to 0.08 or less, more preferably 0.07 or less, or 0.06 or less, and the color temperature of the light is 7,000 K or more, 8,000 K or more, 9,000 K. Or by setting it to at least 10,000 K. PDP is manufactured by a method in which a fluorescent material heating process such as a fluorescent material firing process, a temporary material for sealing material, an adhesion process, and a discharge process are performed in a dry gas atmosphere or an atmosphere in which dry gas is circulated at a pressure below atmospheric pressure. The PDP also provides a method of initiating a process of discharging gas from the interior space between these panels after adhering the front and rear panels when the panel is not cooled to room temperature; Or by temporarily firing the front and rear panels and then starting the panel bonding process when the panel is not cooled to room temperature. This reduces the time and energy required for heating, thereby reducing the manufacturing cost.

Description

Plasma display panel excellent in luminescence, its manufacturing method and apparatus for manufacturing the same {PLASMA DISPLAY PANEL WITH SUPERIOR LIGHT-EMITTING CHARACTERISTICS, AND METHOD AND APPARATUS FOR PRODUCING THE PLASMA DISPLAY PANEL}

In recent years, plasma display panels (PDPs) have attracted attention as large, thin and lightweight displays used in computers and televisions, and the demand for high definition PDPs is increasing.

29 is a sectional view showing a general AC PDP.

In the drawing, the front glass substrate 101 is covered with the stacked display electrode 102, the dielectric glass layer 103, and the dielectric protective layer 104, and the dielectric protective layer 104 is made of magnesium oxide (e.g., See Japanese Patent Laid-Open No. 5-342991).

The address electrode 106 and the partition wall 107 are formed on the rear glass substrate 105. The fluorescent material layers 110-112 of each color (red, green, and blue) are formed in the space between the partition walls 107.

The front glass substrate 101 is placed on the partition wall 107 on the rear glass substrate 105, thereby creating a space. Exhaust gas is discharged into the space to form the discharge space 109.

In the PDP of such a structure, vacuum ultraviolet (main wavelength is 147 nm) is emitted as electrical discharge occurs in the discharge space 109. The fluorescent material layers 110-112 of each color are excited by the emitted vacuum ultraviolet rays to form a color display.

The PDP is manufactured according to the following process.

The display electrode 102 is manufactured by applying a silver paste on the surface of the front glass substrate 101 and firing the applied silver paste. The dielectric glass layer 103 is formed by applying a dielectric glass paste on the surface of the layers and firing the applied dielectric glass paste. The protective layer 104 is formed over the dielectric glass layer 103.

The address electrode 22 is produced by applying a silver paste onto the rear glass substrate 105 and firing the applied silver paste. The partition wall 107 is formed by apply | coating a glass paste to a layer surface in the column direction with a fixed pitch, and baking the apply | coated glass paste. The phosphor layers 110-112 are formed by applying phosphor pastes of each color in the spaces between the partition walls and firing the applied paste at about 500 DEG C to remove resin and other elements from the paste.

After firing the fluorescent material, the sealing glass raw material is applied to the outer region of the rear glass substrate 105, and then the applied sealing glass raw material is fired at about 350 DEG C to remove the resin and other elements from the applied sealing glass raw material. (Glass raw material temporary firing process).

The front glass substrate 101 and the rear glass substrate 105 are assembled so that the display electrode 102 is perpendicular to the address electrode 106 so that the electrode 102 faces the electrode 106. Next, the substrate is heated and bonded to a temperature higher than the softening point of the sealing glass (about 450 ° C.) (adhesion step).

The glass is discharged from the interior space between the substrates (the space formed between the front and back substrates where the phosphors are in contact with the space) while the bonded panel is heated to about 350 ° C. (emission process). After the discharge process is completed, the discharge gas is supplied to the internal space at a constant pressure (typically between 300 Torr and 500 Torr).

The problem with the fabricated PDP is how to improve the luminance and other luminous properties.

To solve this problem, the fluorescent material itself was improved. However, it is desirable that the light emitting property of the PDP be further improved.

Many PDPs are further manufactured using the above manufacturing method. However, PDP manufacturing costs are significantly higher than CRTs. As a result, another problem with PDP is to reduce manufacturing costs.

One of the many possible solutions to reduce costs is to reduce the energy and effort (time required for the work) consumed in some processes required by the heating process.

TECHNICAL FIELD The present invention relates to a plasma display panel used as a display such as a color television receiver and a manufacturing method thereof.

1 is a sectional view of a main part of the AC discharge PDP of the specific example 1. FIG.

FIG. 2 shows a PDP display device made of the PDP shown in FIG. 1 and an activation circuit connected to the PDP.

3 shows a belt-conveyor type heating device used in embodiment 1. FIG.

Figure 4 shows the structure of the heating device for sealing used in Example 1.

Fig. 5 shows the results of measuring the relative luminous intensity emitted from the firing of the blue fluorescent material in air having different partial pressures of vapor contained in the air.

FIG. 6 shows measurement results of chromaticity coordinates y emitted from the firing of a blue fluorescent material in air having different partial pressures of steam contained in the air.

7A to 7C show measurement results of the number of molecules in H ₂ O gas desorbed from a blue fluorescent substance.

8 to 16 show the air outlet position on the rear glass substrate; And a specific embodiment of Format 2 related to which the sealing glass raw material is applied.

17 and 18 show that the luminescence recovery effect once deteriorated depends on the partial pressure of the vapor which is calcined again in air after the blue phosphor layer is deteriorated once.

FIG. 19 shows the bonding apparatus structure used in the bonding process of Embodiment 5. FIG.

20 is a perspective view showing the internal structure of the heating furnace of the bonding apparatus shown in FIG.

21A-21C show the bonding device operation in the preliminary heating process and the bonding process.

22 shows the results of the experiment in Example 5 in which the amount of vapor released from the MgO layer was measured over time.

23 shows a variation of the bonding apparatus of embodiment 5. FIG.

24A-24C show operations performed with other variations of the bonding apparatus of embodiment 5. FIG.

25 shows the spectrum emitted from only the blue cells in the PDP of Example 5. FIG.

FIG. 26 is a CIE chromaticity diagram showing a color reproduction area around a blue color for the PDP and the comparative PDP of Embodiment 5. FIG.

27A, 27B and 27C show the operation performed in the temporary firing process through the discharging process using the bonding apparatus of embodiment 6. FIG.

FIG. 28 shows the temperature profiles used in the temporary firing process, the bonding process and the discharging process in the panel preparation of embodiment 6.

Fig. 29 is a sectional view of a general AC PDP.

Summary of the Invention

Accordingly, it is an object of the present invention to provide a PDP having high luminous efficiency and excellent color reproduction. Another object of the present invention is to provide a PDP manufacturing method that reduces the manufacturing cost by lowering the energy consumption while performing the temporary firing process, the bonding process and the discharge process in a shorter time.

The first purpose is achieved by setting the color temperature of the light to at least 7,000 K, more preferably at least 8,000 K, at least 9,000 K, or at least 10,000 K when light is emitted from all cells.

In order to increase the color temperature in the white background, it is important to increase the chromaticity emitted from the blue phosphor layer. This is achieved by setting the chromaticity coordinate y (CIE color designation) of the light to 0.8 or less, more preferably 0.07 or less or 0.06 or less when light is emitted from the blue cell only or vacuum ultraviolet light is emitted from the blue cell to excite the blue phosphor. do. Alternatively, this is achieved by setting the peak wavelength of the light spectrum to 455 nm or less, more preferably 453 nm or less, or 451 nm or less when light is emitted from the blue cell or only the light is emitted from the blue cell.

Color reproduction is also improved when the chromaticity emitted from the blue phosphor layer is improved.

The PDP, which has improved light chromaticity emitted from the blue fluorescent material layer, is characterized in that a fluorescent material heating process (e.g., a fluorescent material firing process, a sealing material temporary firing process, an adhesion process and a discharge process) is carried out in a dry gas atmosphere, or It is prepared by the PDP manufacturing method carried out under an atmosphere circulated at a pressure below atmospheric pressure.

The inventors of the present invention have known the manufacturing process according to the conventional PDP manufacturing method in which the blue fluorescent material is decomposed by heat when the fluorescent material is heated during the process and the emission intensity and chromaticity are reduced due to the decomposition. The present inventors provide the above PDP manufacturing method of the present invention and prevent the blue fluorescent material from being decomposed by heat.

In the text, “dry gas” means a vapor containing gas having a partial pressure below the typical partial pressure. It is preferable to use the treated air after drying (dry air).

The vapor partial pressure in the dry gas atmosphere is preferably set to 15 Torr or less, more preferably 10 Torr or less, 5 Torr or less, 1 Torr or less, or 0.1 Torr or less. The dew point temperature in the dry gas is preferably set to 20 ° C or lower, more preferably 10 ° C or lower, 0 ° C or lower, -20 ° C or lower, or -40 ° C or lower.

The PDP whose chromaticity emitted from the blue phosphor layer is improved is temporarily fired when the space between the front and rear panels facing their sides is opened; The front and rear panels are glued when the dry gas is circulated to the internal space between the panels; Or by a PDP manufacturing method in which the front and rear panels are preliminarily heated and then glued together when the space between their opposing sides is opened.

After both the first and second objects of the present invention seal and bond together the material between the front panel and the back panel by maintaining the adhesion temperature, the discharge process starts when the panel is not cooled to room temperature at the adhesion temperature, Gas is discharged from the internal spaces between the panels; Or after the temporary firing of the front panel and the rear panel in which the sealing material is inserted by temporarily maintaining the bonding temperature, the bonding process is achieved by starting when the panel is not cooled to the room temperature at the bonding temperature.

In actual manufacturing, each such heating process is carried out using a furnace. Conventionally, the sealing material temporary firing process, the bonding process and the discharge process are performed separately, and the panel is cooled to room temperature at intervals between the processes. Such a structure takes a long time and consumes a lot of energy for the panels to be heated in each process. In contrast, the present invention is carried out in these processes without reducing the temperature to room temperature. This reduces the time and energy required for heating.

<Specific example 1>

Fig. 1 is a sectional view of the main part of the AC discharge PDP in this embodiment. This figure shows a display area located in the center of the PDP.

The PDP has a front panel consisting of a front glass substrate 11 having a display electrode 12 (classified as a scanning electrode 12a and a sustain electrode 12b), a dielectric layer 13 and a protective layer 14 formed thereon. 10; And a rear panel 20 having a rear glass substrate 21 having an address electrode 22 and a dielectric layer 23 formed thereon. The front panel 10 and the rear panel 20 are disposed such that the display electrode 12 and the address electrode 22 face each other. The space between the front panel 10 and the rear panel 20 is divided into a plurality of discharge spaces 30 by partition walls 24 formed in the column direction. Each discharge space is filled with exhaust gas.

The fluorescent material layer 25 is formed on the rear panel 20 so that each of the discharge spaces 30 has a fluorescent material layer of one color of red, green, and blue, and the fluorescent material layers are repeatedly arranged in color order. .

In the panel, the display electrode 12 and the address electrode 22 are each formed in a column direction, the display electrode 12 is perpendicular to the partition wall 24, and the address electrode 22 is parallel to the partition wall 24. Cells having one of red, green and blue colors are formed at each intersection of the display electrode 12 and the address electrode 22.

The address electrode 22 is made of metal (eg, silver or Cr-Cu-Cr). In order to keep the resistance of the display electrode low and to enlarge the discharge area in the cell, each display electrode 12 is narrowly stacked on a wide transparent electrode made of a conductive metal oxide such as ITO, SnO ₂ and ZnO. It is preferable to consist of a some bus electrode (made of silver or Cr-Cu-Cr). However, the display electrode 12 may be made of an address electrode 22 such as silver.

The dielectric layer 13, which is a layer made of a dielectric material, covers the entire surface of one side of the front glass substrate 11 including the display electrode 12. The dielectric layer may be made of bismuth low melting glass or laminated lead low melting glass and bismuth low melting glass, but is typically made of lead low melting glass.

The protective layer 14 made of magnesium oxide is a thin layer covering the entire surface of the dielectric layer 13.

The dielectric layer 23 is similar to the dielectric layer 13 but further mixed with TiO ₂ particles to function as a visible light reflecting layer.

The partition wall 24 made of glass is formed to protect the entire surface of the dielectric layer 23 of the back panel 20.

The following are the fluorescent materials used in this embodiment:

Blue phosphor BaMgAl ₁₀ O ₁₇ : Eu

Green phosphor Zn ₂ SiO ₄ : Mn

Red phosphor Y ₂ O ₃ : Eu.

These phosphor compositions are the same as the conventional materials used for PDPs. However, compared with the conventional materials, the fluorescent material of this embodiment emits light with more vivid color. This is because the fluorescent material is degraded by the heat applied in the manufacturing process. Luminescent light emission means that the chromaticity coordinate y emitted from the blue cell is small (i.e., the peak wavelength of the emitted blue light is short), and the color reproduction range near blue is wide.

In a conventional PDP, when only the blue cell emits light, the chromaticity coordinate y (CIE color designation) emitted from the blue cell is 0.085 or more (that is, the peak wavelength of the emitted light spectrum is 456 nm or more), and there is no color correction. The color temperature at the white background (light is emitted from all of the blue, red and green cells resulting in a white display) is about 6,000 K.

As a technique for improving the color temperature on a white background, a technique is known in which only the width (pitch of a partition) of a blue cell is set to a large value and the blue cell region is set to a larger value than a red or green cell. However, in order to set the color temperature above 7,000 K according to the above technique, the blue cell area must be 1.3 times larger than the red or green cell.

In contrast, in the PDP of the present embodiment, the chromaticity coordinate y emitted from the blue cell when only the blue cell emits light is 0.08 or less, and the peak wavelength of the emitted light spectrum is 455 nm or less. Under these conditions, it is possible to increase the color temperature to 7,000 K or more on a white background without color correction. Furthermore, depending on the conditions in the manufacturing process, it is possible to further reduce the chromaticity coordinate y or to increase the color temperature to 10,000 K or more on a white background without color correction.

As described above, since the chromaticity coordinate y of the blue cell becomes small, the peak wavelength of the emitted blue light becomes short. This is described later in Example 3 and Example 5.

These embodiments also explain why the color reproduction region grows as the chromaticity coordinates y of the blue cells decrease, and how the chromaticity coordinates y of the light emitted from the blue cells relates to the color temperature on a white background without color correction. .

In this embodiment, assuming that the present PDP is used for a 40-inch high definition TV, the thickness of the dielectric layer 13 is about 20 mu m and the thickness of the protective layer 14 is about 0.5 mu m. In addition, the height of the partition wall 24 is 0.1 mm to 0.15 mm, the pitch of the partition wall is 0.15 mm to 0.3 mm and the thickness of the fluorescent material layer 25 is 5 ㎛ to 50 ㎛. The exhaust gas is Ne-Xe gas, with Xe accounting for 50% by volume. The discharge pressure is set to 500 Torr to 800 Torr.

PDP is activated by the following process. As shown in FIG. 2, the panel activation circuit 100 is connected to the PDP. The address discharge is generated by applying a constant voltage to the area between the display electrode 12 and the address electrode 22 of the cell and dimming. The sustain discharge is then generated by applying a pulse voltage to the region between the display electrodes 12a and 12b. The cell emits ultraviolet rays as the discharge proceeds. The emitted ultraviolet rays are converted into visible light by the fluorescent material layer 31. As the cell dims through the above process, an image is displayed on the PDP.

PDP manufacturing process

Next, a process of manufacturing the PDP having the above structure will be described.

Front panel manufacturers

The front panel 10 is manufactured by forming the display electrode 12 on the front glass substrate 11, covering it with the dielectric layer 13, and then forming the protective layer 14 on the dielectric layer 13.

The display electrode 12 is manufactured by applying a silver paste to the front glass substrate 11 surface by a screen manufacturing method and then baking the applied silver paste. The dielectric layer 13 is coated with a lead glass material (e.g., 70 wt% lead oxide (PbO), 15 wt% boron oxide (B ₂ O ₃ ), and 15 wt% silicon oxide (SiO ₂ ) mixed material). It is produced by firing the applied material. The protective layer 14 made of magnesium oxide (MgO) is formed on the dielectric layer 13 by vacuum deposition or the like.

Rear panel manufacturers

The rear panel 20 is manufactured by forming the address electrode 22 on the rear glass substrate 21, covering the dielectric layer 23 (visible light reflecting layer), and then forming the partition 30 on the surface of the dielectric layer 23. do.

The address electrode 22 is produced by applying a silver paste to the surface of the rear glass substrate 21 by a screen manufacturing method and then firing the applied silver paste. The dielectric layer 23 is produced by applying a paste containing TiO ₂ particles and dielectric glass particles to the surface of the address electrode 22 and then firing the applied paste. The partition 30 is formed by repeatedly applying a paste containing glass particles having a constant pitch by screen printing and then firing it.

After the rear panel 20 is manufactured, red, green, and blue phosphor pastes are prepared and applied to the spaces between the partitions by screen printing. The fluorescent material layer 25 is formed by baking the applied paste as described later.

Fluorescent paste of each color is prepared by the following procedure.

Blue phosphor (BaMgAl ₁₀ O ₁₇ : Eu) is obtained through the following steps. First, materials, ie, barium carbonate (BaCO ₃ ), magnesium carbonate (MgCO ₃ ) and aluminum oxide (α-Al ₂ O ₃ ), are prepared in a mixture such that the atomic ratio of Ba: Mg: Al is 1: 1: 10. . Next, an amount of europium oxide (Eu ₂ O ₃ ) is added to the mixture. The appropriate amount of flax (AlF ₂ , BaCl ₂ ) is mixed with the mixture in a ball mill. The resulting mixture is calcined under reduced atmosphere (H ₂ , N ₂ ) at 1400 ° C. to 1650 ° C. for a period of time (eg 0.5 hour).

Red phosphor (Y ₂ O ₃ : Eu) is obtained through the following steps. First, a certain amount of europium oxide (Eu ₂ O ₃₎ is added to yttrium hydroxide _{(Y 2 (OH) 3)} . The appropriate amount of flex is mixed with this mixture in a ball mill. The resulting mixture is calcined in air at 1200 ° C. to 1450 ° C. for a period of time (eg 1 hour).

Green phosphor (Zn ₂ SiO ₄ : Mn) is obtained through the following steps. First, the materials, ie zinc oxide (ZnO) and silicon oxide (SiO ₂ ), are prepared in a mixture so that the atomic ratio of Zn: Si is 2: 1. Next, an amount of manganese oxide (Mn ₂ O ₃ ) is added to the mixture. The appropriate amount of flex is mixed with the mixture in a ball mill. The resulting mixture is calcined in air at 1200 ° C. to 1350 ° C. for a period of time (eg 0.5 hour).

The fluorescent material of each color produced above is pulverized and sieved to obtain particles for each color having a constant particle size distribution. Each color fluorescent paste is obtained by mixing the particles with an adhesive and a solvent.

The fluorescent material layer 25 may be formed by a method other than screen printing. For example, the fluorescent material layer may be sprayed with a fluorescent nozzle with a moving nozzle, or a photosensitive resin sheet containing the fluorescent material may be prepared and attached to the surface of the rear glass substrate 21 on the side of the partition wall 24. It can be formed by applying a photolithography pattern and then developing the attached sheet to remove unnecessary portions of the attached sheet.

Front and back panel bonding, vacuuming and exhaust filling

The sealing glass layer is formed by applying the sealing glass raw material to any one or both of the manufactured front panel 10 and rear panel 20. The sealing glass layer is temporarily baked to remove other elements from the resin and glass raw materials described below. The front panel 10 and the rear panel 20 are assembled together with the display electrode 12 and the address electrode 22 facing each other and perpendicular to each other. The front panel 10 and the back panel 20 are heated and bonded together with the softened sealing glass layer. This will be described later.

The bonded panels are fired (for 3 hours at 350 ° C.) and the air is evacuated from the space between the bonded panels to make a vacuum. The PDP is completed after filling the exhaust gas of the composition into the space between the bonded panels at a constant pressure.

Detail of Fluorescent Material Firing, Temporary Firing of Sealing Glass Raw Material and Adhesion of Front Panel and Rear Panel

It describes the firing process of phosphors, the temporary firing process for sealing glass materials, and the bonding of front and back panels.

Figure 3 shows a belt-conveyor type heating apparatus used to fire fluorescent materials and to temporarily fire glass raw materials.

The heating device 40 includes a heating furnace 41 for heating a substrate, a transport belt 42 for carrying the substrate inside the heating furnace 41, and a gas guide pipe 43 for guiding the atmospheric gas to the heating furnace 41. There is. The heating furnace 41 is provided with a some heating apparatus (not shown) along the heating belt.

The substrate is heated to an ambient temperature profile by adjusting the temperature near a plurality of heaters located along the belt between the inlet 44 and the outlet 45. In addition, the heating furnace may be filled with the atmosphere gas injected through the gas guide pipe 43.

Dry air can be used as the atmosphere gas. Dry air is produced by condensing steam in the cooled air by passing through a gas dryer (not shown) that cools the air to a low temperature (-10 ° C). The amount of steam in the cooled air (partial pressure) is reduced through this process and the dry air is finally obtained.

In order to fire the fluorescent material, the rear glass substrate 21 on which the fluorescent material layer 25 is formed is fired in the heating device 40 in dry air (at a peak temperature of 520 ° C. for 10 minutes). As can be seen from the above, deterioration due to steam and heat in the atmosphere during the firing process of the fluorescent material is reduced by firing the fluorescent material in the dry air.

The lower the partial pressure of the steam in the dry air, the greater the effect of reducing the deterioration of the fluorescent substance by heat. As a result, the partial pressure of steam is preferably 15 Torr or less. The effect is more pronounced when the vapor partial pressure is set to a low value such as 10 Torr or less, 5 Torr or less, 1 Torr or less, 0.1 Torr or less.

There is a relationship between the partial pressure of steam and the dew point temperature. As a result, the technique can be described again by replacing the steam partial pressure with dew point temperature. That is, the lower the dew point temperature is, the greater the effect of reducing the deterioration phenomenon of the fluorescent substance by heat. Therefore, it is preferable that the dew point temperature of dry gas shall be 20 degrees C or less. The above effects are further remarkable when the dew point temperature of the dry gas is set at a low value such as 0 ° C. or lower, −20 ° C. or lower, or −40 ° C. or lower.

In order to temporarily fire the sealing glass raw material, the front glass substrate 11 or the rear glass substrate 21 on which the sealing glass layer is formed is fired by the heating device 40 in dry air (30 minutes at a peak temperature of 30 ° C). During).

In this temporary firing step, as in the firing step, the vapor partial pressure is preferably 15 Torr or less. Moreover, the effect becomes more remarkable when the steam partial pressure is set to a low value such as 10 Torr or less, 5 Torr or less, 1 Torr or less, or 0.1 Torr or less. That is, it is preferable that the dew point temperature of a dry gas is 20 degrees C or less, and it is still more preferable to set temperature to low values, such as 0 degrees C or less, -20 degrees C or less, and -40 degrees C or less.

4 shows the structure of a heating device for sealing.

The heating device for sealing 50 includes a heating furnace 51 for heating a substrate (in this embodiment, the front panel 10 and the rear panel 20), and an atmosphere gas from the outside of the heating furnace 51. Pipe 52a for guiding the space between the rear panel 20 and the space 52 between the front panel 10 and the rear panel 20 and for discharging the atmosphere gas to the outside of the heating furnace 51. There is. The pipe 52a is connected to the gas supply source 53 which supplies dry air as atmospheric gas. The pipe 52b is connected to the vacuum pump 54. Adjustment valves 55a and 55b are attached to pipes 52a and 52b, respectively, to regulate the gas flow rate through the pipes.

The front panel and the rear panel are bonded as described below using the sealing heating device 50 of the above structure.

The rear panel is provided with air outlets 21a and 21b in the outer area surrounding the display area. Glass pipes 26a and 26b are attached to air outlets 21a and 21b, respectively. Note that the partition and fluorescent material that should be on the rear panel 20 are omitted in FIG. 4.

The front panel 10 and the rear panel 20 are suitably positioned with the sealing glass layer therebetween and then placed in the furnace 51. In doing so, the positioned front panel 10 and rear panel 20 are tightened with a clamp or the like to prevent them from moving.

Air is exhausted from the space between the panels using the vacuum pump 54 to vacuum the space. The dry air is then sent to the space through the pipe 52a at a constant flow rate without using the vacuum pump 54. Dry air is exhausted from the pipe 52b. This means that dry air flows through the space between the panels.

The front panel 10 and rear panel 20 are then heated (for 30 minutes at a peak temperature of 450 ° C.) and dry air flows through the spaces between the panels. In this process, the front panel 10 and the back panel 20 are bonded together with the soft sealing glass layer 15.

After the adhesion is completed, one of the glass pipes 26a and 26b is blocked and the vacuum pump is connected to the other glass pipe. The heating device for sealing is used in the next process, vacuum discharge process. In the exhaust gas filling process, the cylinder containing the exhaust gas is connected to another glass pipe and the exhaust gas is filled into the space between the panels for operating the exhaust device.

Effect of the method shown in this embodiment

The method shown in this embodiment of adhering the front and rear panels has the unique effect described below.

In general, gases such as steam are retained by adsorption on the surfaces of the front and back panels. The adsorbed gas is released when the panel is heated.

In the conventional method, in the bonding process after the temporary firing process, the front panel and the rear panel are first assembled at room temperature and then heated and bonded. In the bonding process, gases retained by adsorption on the front panel and rear panel surfaces are released. A certain amount of gas is released through the temporary firing process, but before the bonding process begins, the gas is again retained by adsorption when the panel is in air at room temperature and the gas is released in the bonding process. The released gas is confined to the space between the panels. At this stage the partial pressure of steam in the space is typically measured to be at least 20 Torr.

At this time, the fluorescent material layer 25 in contact with the space tends to be deteriorated by heat and gas (particularly, vapor emitted from the protective layer 14) and the gas confined to the space. Deterioration of the phosphor layer reduces the luminescence intensity of the layer (especially the blue phosphor layer).

On the other hand, according to the method shown in this embodiment, deterioration is reduced because dry air flows through the space when the panel is heated and steam is discharged from the space.

In this bonding process, such as the fluorescent material firing process, the partial pressure of steam is preferably 15 Torr or less. In addition, the deterioration of the fluorescent material is further reduced when the partial pressure of the vapor is set to a low value such as 10 Torr or less, 5 Torr or less, 1 Torr or less, 0.1 Torr. That is, it is preferable that the dew point temperature of dry air is set to 20 degreeC, and it is still more preferable to set it as low values, such as 0 degrees C or less, -20 degrees C or less, and -40 degrees C or less.

Study on steam partial pressure in atmospheric gas

Experiments confirmed that deterioration of the blue phosphor due to heating can be prevented by reducing the partial pressure of the vapor in the atmosphere gas.

5 and 6 show the relative emission intensity and the chromaticity coordinate y of the light emitted from the blue phosphor (BaMgAl ₁₀ O ₁₇ : Eu), respectively. These values were measured after firing the blue phosphor in air by varying the partial pressure of the vapor. The blue phosphor was calcined at a peak temperature of 450 ° C. for 20 minutes.

The relative luminescence intensity value shown in FIG. 5 is a relative value when the luminescence intensity of the blue fluorescent substance measured before firing is 100 as the standard value.

To obtain the emission intensity, the emission spectrum of the phosphor layer is first measured using a spectrophotometer, and then the chromaticity coordinate y is calculated from the measured emission spectrum, so that the emission intensity is calculated from the calculated chromaticity coordinate y and the measured luminance. Obtained from the equation (luminescence intensity = luminance / chromatic coordinate y).

Note that the chromaticity coordinate y of the blue fluorescent substance before firing is 0.052.

From the results shown in FIGS. 5 and 6, it can be seen that there is no change in chromaticity when the luminescence intensity is not reduced by heat and the partial pressure of steam is about 0 Torr. However, it is noted that as the partial pressure of the vapor increases, the relative emission intensity of the blue phosphor decreases and the chromaticity coordinate y of the blue phosphor increases.

The blue phosphor (BaMgAl ₁₀ O ₁₇ : Eu) is conventionally thought to have a reduced luminescence intensity and an increase in chromaticity coordinate y when oxidized through heating and converted to Eu ³⁺ ions due to the activator Eu ²⁺ ion (S. Oshio). , T. Matsoka, S. Tanaka, and H. Kobayashi, Mechanism of Luminance Decrease in BaMgAl ₁₀ O ₁₇ : Eu ²⁺ Phosphor by Oxidation, J. Electrochem. Soc., Vol. 145, No. 11, November 1988, pp 3903-3907). However, from the fact that the chromaticity coordinate y of the blue phosphor depends on the partial pressure of the vapor in the atmosphere, Eu ²⁺ ions do not react directly with oxygen in the atmosphere gas (e.g. air), but the vapor in the atmosphere gas is deteriorated. It is thought to promote the reaction involved.

For comparison, the decrease in luminescence intensity and change in chromaticity coordinate y of the blue phosphor (BaMgAl ₁₀ O ₁₇ : Eu) were measured for various heating temperatures. The measurement result shows that the decrease in luminescence intensity increases as the heating temperature increases in the range of 300 ° C. to 600 ° C., and the decrease in luminescence intensity increases as the partial pressure of steam increases at the heating temperature. On the other hand, the measurement results show a tendency that the change in chromaticity coordinate y increases as the partial pressure of steam increases, but the measurement result does not show a tendency that the change in chromaticity coordinate y depends on the heating temperature.

In addition, the amount of vapor emitted during heating is determined by the front glass substrate 11, the display electrode 12, the dielectric layer 13, the protective layer 14, the rear glass substrate 21, the address electrode 22, and the dielectric layer 23. (Visible light reflecting layer), the partition 24 and the fluorescent material layer 25 was measured for each material. According to the measurement result, MgO, which is the material of the protective layer 14, among other materials, releases the maximum amount of vapor. From this result it is assumed that the deterioration of the phosphor layer 25 by heat during adhesion of the layer is mainly caused by the vapor released from the protective layer 14.

Variation of This Embodiment

In this embodiment, a certain amount of dry air flows into the space between the panels during the bonding process. However, it is possible to alternately repeat the air discharge from the internal space and the injection of dry air to be a vacuum. By this operation, the vapor is effectively discharged from the internal space and the deterioration of the phosphor layer by heat can be reduced.

In addition, not all of the fluorescent material layer firing process, temporary firing process and bonding process are carried out in an atmosphere dry gas. It is possible to achieve the same effect by only one or two of these processes being carried out in atmospheric dry gas.

In this embodiment, dry air as the atmospheric gas flows into the space between the panels during the bonding process. However, it is possible to obtain a certain effect by flowing an inert gas such as nitrogen whose low partial pressure in the vapor does not react with the phosphor layer.

In this embodiment, dry air is forcibly injected into the space between the panels 10 and 20 through the glass pipe 26a in the bonding process. However, the panels 10 and 20 can be glued together in the atmosphere of dry air using the heating device 40 shown in FIG. Also in this case, since a small amount of dry gas flows into the internal space through the air outlets 21a and 21b, a constant effect is obtained.

Although not described in this embodiment, the water retained by adsorption on the surface of the protective layer is reduced in amount when the front panel 10 having the protective layer 14 formed on the surface is calcined under an atmospheric dry gas. do. When only this is done, the deterioration of the blue phosphor layer is limited to some extent. The effect is expected to be further increased by combining this method of firing the front panel 10 with the manufacturing method of the present embodiment.

PDP prepared according to the method of this embodiment has the effect that abnormal emission is reduced during PDP activation because the phosphor contains a small amount of water.

Example 1

In Table 1, panels 1 to 4 are PDPs prepared according to this embodiment. Panels 1 to 4 were prepared under different partial pressures of steam in dry air flowing during the phosphor layer firing process, glass material temporary firing process and bonding process, and the partial pressures of the steam were in the range of 0 Torr to 12 Torr.

Panel 5 is a PDP prepared for comparison. Panel 5 was manufactured in non-dry air (vapor partial pressure of 20 Torr) through a fluorescence layer firing process, a glass material temporary firing process, and a bonding process.

In each of panels 1 to 5, the phosphor layer thickness was 30 μm and the exhaust gas Ne (95%)-Xe (5%) was charged to a filling pressure of 500 Torr.

Luminescent Properties Test and Results

For each panel 1 to 5, the color temperature and panel brightness on a white background without color correction (color temperature when light is emitted from all blue, red and green cells to reproduce a white display). And panel luminance) and the peak intensity ratio of the spectrum emitted from the blue cell to the green cell were measured as luminescence properties.

The test results are shown in Table 1.

Each prepared PDP was decomposed and vacuum ultraviolet light (center wavelength 146 nm) was irradiated with a blue phosphor layer on the rear panel using a Krypton excimer lamp. The color intensity when light is emitted from all blue, red and green cells and the peak intensity ratio of the light spectrum emitted from the blue to green cells were measured. The result was the same as described above because no color filter or the like was used in the manufactured front panel.

Blue phosphor was extracted from the panel. The number of molecules contained in 1 g of H ₂ O gas desorbed from the blue phosphor was measured by TDS (thermal desorption) analysis. In addition, the ratio of c-axis length to a-axis length of the blue phosphor crystal was also measured by X-ray analysis.

The measurement was performed using an infrared heating TDS analyzer manufactured by ULVAC JAPAN Ltd. as follows. Each of the phosphor samples contained in the tantalum plate was filled in the prepared exhaust chamber and the gas was removed from the chamber at about 10 ⁻⁴ Pa. The test sample was then filled into the measuring chamber and the gas was withdrawn from the chamber on the order of 10 ⁻⁷ Pa. The number of H ₂ O molecules (mass number 18) desorbed from the fluorescent material was measured in the scan mode at the 15 second measurement interval and the test sample was heated using an infrared heater from room temperature to 1,100 ° C. at a heating rate of 10 ° C./min. 7A, 7B and 7C show test results for blue phosphors extracted from panels 2, 4 and 5, respectively.

As observed in the figure, the number of H ₂ O molecules desorbed from the blue phosphor has peaks at about 100 ° C. to 200 ° C. and about 400 ° C. to 600 ° C. It is believed that the peak at about 100 ° C. to 200 ° C. is due to the desorption of the physical adsorption gas and the peak at about 400 ° C. to 600 ° C. is due to the desorption of the chemical adsorption gas.

Table 1 shows the peak value of the number of H ₂ O molecules desorbed at 200 ° C. or higher, that is, the number of H ₂ O molecules desorbed at about 400 ° C. to 600 ° C., and the ratio of c-axis length to a-axis length of the blue phosphor crystal. .

Research

By studying the results shown in Table 1, it can be seen that panels 1 to 4 of the present embodiment are superior to panel 5 (comparative example) in terms of light emission characteristics. That is, panels 1 to 4 have higher panel brightness and color temperature.

In panels 1 to 4, the light emission characteristics increase in the order of panels 1, 2, 3, and 4.

From this result, it can be seen that the luminescence properties (panel luminance and color temperature) are excellent as the partial pressure of steam is lowered in the fluorescent material layer firing step, the glass material temporary firing step and the bonding step.

It is thought that this phenomenon is because when the vapor partial pressure decreases, the deterioration of the blue fluorescent substance (BaMgAl ₁₀ O ₁₇ : Eu) layer is prevented and the chromaticity coordinate y value becomes small.

In the case of the panel of this embodiment, the peak number of molecules contained in 1 g of H ₂ O gas desorbed from the blue phosphor at 200 ° C. or higher is 1 × 10 ¹⁶ or less, and the c-axis length of the blue phosphor crystal versus the a-axis The ratio of lengths is 4.0218 or less. In contrast, the corresponding values of the comparison panel are both greater than the above values.

<Specific example 2>

The PDP of this embodiment has the same structure as that of the first embodiment.

The manufacturing method of the PDP is the same as that of Embodiment 1 except for the air outlet position in the outer region of the rear glass substrate 21 and the format in which the sealing glass raw material is applied. During the bonding process, the phosphor layer is degraded by worse heat during the phosphor layer firing process and the glass material temporary firing process, in which the vapor containing gas is generated from the protective layer, the phosphor layer and the sealing of the front panel. This is because the molten glass is each limited to a small internal space divided by the partition wall at the time of heating. In consideration of this, in this embodiment, the dry air injected into the inner space can be constantly flowed through the space between the partition walls in the bonding process, and the gas generated in the space between the partition walls is effectively disposed. This increases the effect of preventing degradation of the phosphor layer by heat.

8-16 show specific embodiments relating to the air outlet position in the outer region of the rear glass substrate 21 and the format in which the sealing glass material is applied. The rear panel 20 is provided with partitions 24 in a column direction over the actual entire image display area, but FIGS. 8 to 16 show only a few columns of the partitions 24 for both sides with the center omitted. Indicates.

In these figures, the frame-shaped sealing glass region 60 (the region where the sealing glass layer 15 is formed) is located in the outer region of the rear glass substrate 21. The sealing glass region 60 is a pair of vertical sealing regions 61 extending along the outermost partition wall 24 and a pair of horizontal sealing regions 62 extending perpendicular to the partition wall (in the width direction of the partition wall). consist of.

When the panels are bonded, dry air flows through the gaps between the partition walls 24.

The characteristics of this embodiment are described with reference to the drawings.

As shown in Figs. 8 to 12, the air outlets 21a and 21b are formed at a diagonal position inside the sealing glass region 60. Figs. When the panel is bonded, the dry air guided through the air outlet 21a as shown in FIG. 4 passes through the gap 63a between the partition end 24a and the horizontal sealing area 62 to partition the partition 24. Is divided into gaps 65). The dry air then passes through the gap 65 and passes through the gap 63b between the partition end 24d and the horizontal sealing region 62 and is discharged from the air outlet 21b.

In the embodiment shown in FIG. 8, each gap 63a and 63b has a wider width than each gap 64a and 64b between the vertical sealing region 61 and the adjacent partition wall 24 (thus D1, D2). > D1, d2 are satisfied, where D1, D2, d1 and d2 represent the minimum widths of the gaps 63a, 63b, 64a and 64b, respectively).

With such a structure, for the dry air supplied through the air outlet 21a, the resistance to the gas flow in the gap 65 between the partition walls 24 becomes lower than the gaps 64a and 64b. As a result, a large amount of dry air passes through the gaps 63a and 63b rather than the gaps 64a and 64b, and the dry air is uniformly distributed into the gaps 65, so that the dry air flows in the gaps 65 constantly.

With this arrangement, the gas generated in each gap 65 is effectively discharged and the effect of preventing the deterioration of the phosphor layer in the bonding process is increased.

Further, the partition wall 24 is set so that the minimum widths D1 and D2 of the gaps 63a and 63b are set to larger values, such as two or three times the minimum widths d1 and d2 of the gaps 64a and 64b. The resistance to gas flow in the gap 65 between them becomes smaller and the effect becomes greater as the dry air flows through each gap 65 more uniformly.

In the embodiment shown in FIG. 9, the vertical sealing region 61 is connected at its central part to the adjacent partition 24. Therefore, the minimum widths d1 and d2 of the gaps 64a and 64b are respectively 0 near the center. In this case, since the dry air does not flow through the gaps 64a and 64b, the dry air flows more uniformly through each gap 65.

10 to 16, the flow preventing wall 70 is formed to be in direct contact with the inner sealing glass region 60. The flow preventing wall 70 is composed of a pair of vertical walls 71 extending along the vertical sealing region 61 and a pair of horizontal walls 72 extending along the horizontal sealing region 62. Air outlets 21a and 21b are adjacent to the flow barrier wall 70. In the embodiment shown in FIG. 12 only horizontal walls 72 are formed.

The flow preventing wall 70 is made of the same material and in the same shape as the partition wall 24. As a result, it can be manufactured in the same process.

The flow preventing wall 70 prevents the sealing glass of the sealing glass region 60 from flowing to the display region located at the center of the panel when the sealing glass region 60 is softened by heat.

In the embodiment shown in FIG. 10, as in the case shown in FIG. 8, each gap 63a and 63b is wider than each gap 64a and 64b between the vertical sealing region 61 and the adjacent partition wall 24. It is large (D1, D2 &gt; d1, d2), thereby providing the same effect as in the case shown in FIG.

In the embodiment shown in FIG. 11, the partitions 73a and 73b are formed near the center of the gaps 64a and 64b respectively between the vertical wall 71 and the adjacent partition 24. The minimum widths d1 and d2 of the gaps 64a and 64b are respectively 0 near the center as in the case shown in FIG. Therefore, this case also provides the same effect as the case shown in FIG.

In the embodiment shown in FIG. 12, the center portion of the vertical sealing region 61 is connected to the adjacent partition wall 24. The minimum widths d1 and d2 of the gaps 64a and 64b are respectively 0 near the center as shown in FIG. Therefore, this case also provides the same effect as the case shown in FIG.

In the embodiment shown in FIG. 13, air outlets 21a and 21b are formed in the center, not in the diagonal position of the gaps 64a and 64b between the vertical wall 71 and the adjacent partition 24. The partitions 73a and 73b are formed at the ends of the gaps 64a and 64b, respectively. This case thus provides the same effects as the case shown in FIG.

In the embodiment shown in Fig. 14, two gas outlets 21a are formed as gas inlets and two gas outlets 21b are formed as gas outlets, and the middle partition walls 27 among the partition walls 24 have horizontal walls at both ends. Extends to connect 72. The panel is almost identical to that shown in FIG. In this case, dry air flows in each area separated by the central partition 27. However, each gap 63a and 63b is wider than each gap 64a and 64b, and this case also provides the same effect as the case shown in FIG. Moreover, in the embodiment shown in FIG. 14, it is possible to adjust the flow rate of the dry air for each area separated by the heavy bulkhead 27.

Variation of This Embodiment

In this embodiment, as in embodiment 1, the steam partial pressure is preferably 15 Torr or less (or the dew point temperature of the dry air is 20 ° C. or less), and the partial pressure in steam is not reacted with the fluorescent material layer instead of dry air. The same effect can be obtained by flowing an inert gas such as low nitrogen.

This embodiment describes the case where the partition wall is formed in the rear panel. However, the partitions may be formed in the front panel in the same way to achieve the same effect.

Example 2

Panel 6 is a PDP prepared according to FIG. 10 of this embodiment, wherein the steam partial pressure in the dry air flowing during the bonding process is 2 Torr (the dew point temperature of the dry air is −10 ° C.).

Panel 7 is a PDP partially fabricated in accordance with FIG. 15 of this embodiment, wherein each gap 63a and 63b is narrower than each gap 64a and 64b between the vertical sealing region 61 and the adjacent partition wall 24 ( D1, D2 <d1, d2). The panel is also manufactured according to FIG. 10. When panel 7 is manufactured, the panels are bonded together under the same conditions as panel 6.

Panel 8 is a PDP prepared for comparison. Panel 8 has one air outlet 21a on back panel 20 as shown in FIG. During the bonding process, the front panel 10 and the back panel 20 are assembled together and then heated and bonded together without flowing dry air.

Panels 6-8 were manufactured under the same conditions except for the bonding process. Panels 6-8 have the same panel structure except for the air outlet and the flow barrier. In each of PDP Nos. 6 to 8, the phosphor layer thickness was 20 μm and the exhaust gas Ne (95%)-Xe (5%) was charged to a filling pressure of 500 Torr.

Test for Luminescent Properties

For each PDP No. 6 to 8, the color temperature and panel brightness on the white background without color correction, and the peak intensity ratio of the spectrum emitted from the blue cell to the green cell were measured as the luminescence properties.

The test results are shown in Table 2.

Each prepared PDP was disassembled and vacuum ultraviolet rays were irradiated with a blue phosphor layer on the rear panel using a krypton excimer lamp. The color temperature when light is emitted from all blue, red and green cells and the peak intensity ratio of the spectrum emitted from the blue cell to the green cell were measured. The results were the same as above.

Blue phosphor was extracted from the panel. The number of molecules contained in 1 g of H ₂ O gas desorbed from the blue phosphor was measured by TDS analysis. In addition, the c-axis length to a-axis length ratio of the blue phosphor crystal was also measured by X-ray analysis. This result is also shown in Table 2.

Research

By studying the results shown in Table 2, it can be seen that panel 6 of the present embodiment shows the best luminescence properties among the three panels. The light emission characteristic of panel 6 is better than panel 7. This is because during the bonding process of panel 6, dry air flows uniformly through the gap between the partition walls, and the generated gas is effectively discharged, while during the bonding process of panel 7, most of the guided inwards through the air outlet 21a. After the dry air passes through the gaps 63a and 63b, it is discharged to the outside through the air outlet 21b. In the case of panel 7, because a small amount of dry gas flows through the gap 65 between the partition walls, the gap 65 This is because the gas generated from) is not effectively discharged.

The luminescence properties of panel 8 are poor compared to others. This is considered to be because the gas generated in the gap 65 is not effectively discharged because a small amount of dry gas flows through the gap 65 between the partition walls.

The PDP in this embodiment is manufactured according to FIG. However, it was confirmed that the PDP prepared according to FIGS. 10 to 16 similarly exhibited excellent light emission characteristics.

<Specific example 3>

The PDP of this embodiment has the same structure as that of the first embodiment.

The manufacturing method of PDP is the same as that of Example 1 except that when the front panel 10 and the back panel 20 are bonded together in the bonding process, the panel is heated and the dry air flows by adjusting the pressure of the internal space below atmospheric pressure. Do.

In this embodiment, the sealing glass material is first applied to one or both of the front panel 10 and the rear panel 20. The applied sealing glass raw material is temporarily fired. The panels 10 and 20 are assembled and placed in the heating furnace 51 of the sealing heating device 50. Pipes 52a and 52b are connected to glass pipes 26a and 26b, respectively. The pressure in the interior space between the panels is reduced by using the vacuum pump 54 to exhaust air from the space through the pipe 52b. At the same time, dry air is supplied from the gas supply source 53 to the internal space through the pipe 52a at a constant flow rate. At this time, the adjustment valves 55a and 55b are adjusted so that the pressure in the internal space is kept below atmospheric pressure.

As described above, while the panels 10 and 20 are heated at a sealing temperature (peak temperature of 450 ° C.) for 30 minutes, dry air is supplied to the internal spaces between the panels under reduced pressure so that the sealing glass layer 15 is softened and the panel ( 10 and 20 are bonded together by a soft sealing glass.

The bonded panels are fired (for 3 hours at 350 ° C.) and the air is evacuated from the interior spaces between the panels to become a vacuum. Filling the exhaust gas of the composition into the space at a constant pressure to complete the PDP.

Effect of this embodiment

During the bonding process of this embodiment, the panels are bonded as dry air flows into the interior spaces between the panels as in embodiment 1. Therefore, as described above, deterioration of the fluorescent material due to contact with the steam is limited.

As in Embodiment 1, the partial pressure of the steam in the dry air is preferably 15 Torr or less. The deterioration limiting effect becomes more pronounced when the partial pressure of steam is set to 10 Torr or less, 5 Torr or less, 1 Torr or less, 0.1 Torr or less. The dew point temperature of the dry gas is preferably 20 ° C. or lower, more preferably 0 ° C. or lower, −20 ° C. or lower, or −40 ° C. or lower.

Moreover, in this embodiment, the steam generated in the inner space is more effectively discharged to the outside than in the embodiment 1 because the panels are glued together when the pressure in the inner space is kept below atmospheric pressure. Since the dry air is supplied to the space when the pressure in the internal space is kept below atmospheric pressure, the internal spaces between the panels do not expand during the bonding process so that the bonded panels 10 and 20 are in direct contact.

The lower the pressure in the interior space, the easier the partial pressure of the steam is adjusted. This is preferable because the panels are brought into direct contact with each other. Therefore, the pressure in the internal spaces between the panels is preferably 500 Torr or less, more preferably 300 Torr or less.

On the other hand, when the dry gas is supplied to the internal space between the panels and its partial pressure is very low, the partial pressure of oxygen in the atmospheric gas is lowered. For this reason, defects such as oxygen deficiency occur when oxide fluorescent materials such as BaMgAl ₁₀ O ₁₇ : Eu, Zn ₂ SiO ₄ : Mn, and Y ₂ O ₃ : Eu, which are often used in PDPs, are heated under an oxygen-free atmosphere. This reduces the luminous efficiency. Therefore, from this point of view, it is preferable to set the pressure of the internal space to 300 Torr or more.

Variation of This Embodiment

In this embodiment, the dry air is supplied as the atmosphere gas to the interior space between the panels in the bonding process. However, instead of dry air, the same effect can be obtained by flowing an inert gas such as nitrogen having a low partial pressure in the vapor without reacting with the phosphor layer. It can be seen that it is preferable to supply an atmosphere gas containing oxygen in terms of limiting deterioration of luminance.

In this embodiment, the pressure in the interior space is reduced even when the temperature is too low to soften the sealing glass. In this case, however, gas can flow from the furnace 51 into the interior space through the gap between the front panel 10 and the rear panel 20. As a result, the dry air is preferably supplied to or charged from the heating furnace 51.

Alternatively, to prevent gas from flowing from the furnace 51 into the interior space between the panels, the temperature of the interior space is reduced so that dry gas is not discharged from the interior space when the temperature is still low and the sealing glass is not softened. It can be maintained near atmospheric pressure and then the temperature is increased above a certain temperature so that the pressure in the internal space decreases below atmospheric pressure and then the dry gas can be forced out of the internal space. In this case, the temperature at which the dry gas is forcibly discharged is preferably set above the temperature at which the sealing glass starts to soften. The temperature at which the dry gas is forcibly discharged is preferably 300 ° C. or higher, more preferably 350 ° C. or higher, even more preferably 400 ° C. or higher.

This embodiment describes the case where panels 10 and 20 are heated while supplying dry air to the internal space under reduced pressure during the bonding process. However, the firing process of the fluorescent material or the temporary firing process of the sealing glass material may be carried out under an atmosphere in which dry air is supplied under reduced pressure. This gives a similar effect.

The panel structure described in Embodiment 2 is applied to this embodiment to obtain other effects.

Example 3

Table 3 shows the various conditions under which the panel is bonded for each PDP, including the PDP according to this embodiment and the comparative PDP.

Panels 11-21 are PDPs prepared according to this embodiment. Panels 11 to 21 are the partial pressures of the vapor in the dry gas flowing into the interior spaces between the panels during the bonding process; Gas pressure in the interior space between the panels; The temperature at which the pressure in the internal space begins to decrease below atmospheric pressure; And under different conditions such as dry gas type.

Panel 22 is a PDP prepared according to embodiment 1 in which dry gas is supplied to the interior space but no gas is forced out of the space during the bonding process.

Panel 23 is a PDP designed for comparison. Panel 23 was manufactured according to the conventional method without supplying dry air to the internal space between the panels.

In each of panels 11 to 23, the phosphor layer thickness was 30 μm and the exhaust gas, Ne (95%)-Xe (5%), was charged to a filling pressure of 500 Torr.

Test for Luminescent Properties

For each panel 11-23, the relative emission intensity of emitted blue light, chromaticity coordinate y of emitted blue light, peak wavelength of emitted blue light, color temperature on white background without color correction, and blue to green cells The peak intensity ratio of the spectrum emitted from the light was measured as the light emission characteristic.

Among the above characteristics, the relative emission intensity of blue light, chromaticity coordinate y of blue light, and color temperature on a white background without color correction were measured in the same manner as in Example 1. The peak wavelength of emitted blue light was measured by measuring only the emission light of emitted blue light by irradiating only blue light. The test results are shown in Table 3.

The relative light emission intensity value with respect to the blue light shown in Table 3 is a relative value when the measured light emission intensity of panel 23 as a comparative example is set to 100 as a standard value.

Each of the prepared PDPs was decomposed and vacuum ultraviolet rays were irradiated with a blue phosphor layer on the rear panel using a krypton excimer lamp. The chromaticity coordinate y of the blue light, the color temperature when the light is emitted from all blue, red and green cells and the peak intensity ratio of the spectrum emitted from the blue cell to the green cell were measured. The results were the same as above.

Blue phosphor was extracted from the panel. The number of molecules contained in 1 g of H ₂ O gas desorbed from the blue phosphor was measured by TDS analysis. In addition, the c-axis length to a-axis length ratio of the blue phosphor crystal was also measured by X-ray analysis. This result is also shown in Table 3.

Research

By studying the results shown in Table 3, it can be seen that panels 11 to 21 of the present embodiment have better luminescence properties than the comparative example (Panel 23) (high luminescence intensity of blue light and high color temperature on a white background). ).

Panels 14 and 22 have the same value for luminescence properties. This indicates that the same effect (luminescence property) is obtained if the partial pressure of steam in the dry air flowing in the inner space is the same regardless of whether the pressure in the inner space is equal to or lower than atmospheric pressure.

However, among the samples of panel 22, some samples were observed to have a gap between the partition and the front panel. This is considered to be because the internal space is slightly expanded due to the dry gas supplied during the bonding process.

By comparing the light emission characteristics of the panels 11 to 14, it can be seen that the emission intensity of the blue light is increased and the chromaticity coordinate y of the emitted blue light is decreased in the order of the panels 11, 12, 13, and 14. This indicates that the emission intensity of the emitted blue light increases and the chromaticity coordinate y of the emitted blue light decreases as the partial pressure in the dry air decreases. This is considered to be because deterioration of the blue phosphor is prevented by reducing the partial pressure of steam.

By comparing the light emission characteristics of panels 14-16, it can be seen that the panel has the same value for the chromaticity coordinate y of the emitted blue light. This indicates that the chromaticity coordinate y of the emitted blue light is not affected by the pressure in the interior space between the panels. In addition, it can be seen that the relative emission intensity with respect to blue light decreases in the order of panel 14, 15, 16. This indicates that the luminescence intensity of the emitted blue light decreases as the partial pressure of oxygen in the atmosphere gas decreases and defects such as oxygen deficiency occur in the fluorescent material.

By comparing the light emission characteristics of panels 14, 20 and 21, it can be seen that the panel has the same value for the chromaticity coordinate y of the emitted blue light. This indicates that the chromaticity coordinate y of the emitted blue light is not affected by the type of dry gas flowing into the interior space between the panels. In addition, it can be seen that the relative light emission intensity with respect to the blue light of panel 20 and 21 is less than panel 14. This indicates that when a non-oxygen nitrogen or gas such as Ne (95%)-Xe (5%) is used as the dry gas, the emission intensity of the emitted blue light decreases because defects such as oxygen deficiency occur in the phosphor. Indicates.

By comparing the light emission characteristics of panels 14 and 17 to 19, it can be seen that the emission intensity of blue light increases and the chromaticity coordinate y of emitted blue light decreases in the order of panels 17, 18, 14 and 19. . This indicates that the emission intensity of the emitted blue light increases and the chromaticity coordinate y of the emitted blue light decreases as the temperature at which the gas starts to be discharged from the internal space is set high so that the pressure in the internal space decreases below atmospheric pressure. This is considered to be because the discharge start temperature is set high to prevent the atmosphere gas around the panel from flowing into the internal space between the panels.

Note that the relationship between the chromaticity coordinate y of emitted blue light and the peak wavelength of emitted blue light for each panel provided in Table 3 shows that the peak wavelength also becomes shorter as chromaticity coordinate y decreases. This indicates that they are proportional to each other.

<Specific example 4>

The PDP of this embodiment has the same structure as that of the first embodiment.

The manufacturing method of the PDP is the same as the conventional method up to the bonding process (that is, during the bonding process, the front panel 10 and the rear panel 20 are heated without supplying dry air to the internal space between these panels). . However, in the exhaust process, the panel is heated when the dry gas is supplied to the internal space between the panels (hereinafter referred to as the dry gas process), and then the gas is evacuated and vacuumed (vacuum discharge). fair). This returns the luminescence properties of the blue phosphor layer to the level before deterioration through the process up to the adhesion process.

The following is a description of the discharge process of this embodiment.

In the discharge process of this embodiment, the sealing heating device shown in Fig. 4 is used and Fig. 4 is mentioned in the description.

First, each of the glass pipes 26a and 26b is attached to the air outlets 21a and 21b of the rear panel 20. Pipes 52a and 52b are connected to glass pipes 26a and 26b, respectively. The gas is discharged from the internal space between the panels via the pipe 52b using the vacuum pump 54 to temporarily vacuum the internal space. Next, dry air is supplied to the internal space at a constant flow rate through the pipe 52a without using the vacuum pump 54. This allows dry air to flow through the interior space between panels 10 and 20. Dry air is discharged to the outside through the pipe (52b).

The panels 10 and 20 are heated to a constant temperature when the dry air is supplied to the internal space.

The supply of dry air is then stopped. Then, the air is discharged from the internal space between the panels using the vacuum pump 54 while maintaining the temperature at a certain degree to discharge the gas retained by the adsorption in the internal space.

After the discharge process, the discharge gas is filled into the cell and then the PDP is completed.

Effect of this embodiment

The discharge process of this embodiment has the effect of preventing deterioration of the phosphor layer from occurring during this process.

In addition, the discharge process has the effect of returning the luminescence properties of the phosphor layer (particularly, the blue phosphor layer) to a level before deterioration through the initial process. The phosphor layer (particularly the blue phosphor layer) is likely to be degraded by heat during the phosphor layer firing process, the temporary firing process and the bonding process. The discharge process of this embodiment restores its luminescent properties if the phosphor layer deteriorates during the process.

The reason for the effect is as follows.

When heating panels bonded together during the bonding process, gases (especially steam) are released in the interior spaces between the panels. For example, when the bonded panel is in air, water is retained by adsorption in the interior space. Therefore, steam is released in the internal space between the panels when the panels in this state are heated. According to the discharge process of this embodiment, such vapor is effectively discharged to the outside because the dry gas flows through the internal space and heats the panel before the vacuum discharge process is started. Thus, in comparison with the conventional discharge process of simply discharging the gas without supplying dry gas, the fluorescent material is less degraded by heat during the discharge process of the present embodiment.

In addition, in the gas discharge process using dry gas, luminescence characteristics are restored because a reverse reaction occurs due to heat deterioration.

As can be seen from the above description, this embodiment provides a practically significant effect that the once deteriorated luminescent properties of the blue phosphor can be recovered in the discharge process, which is the final heating process.

It is preferable to satisfy the following conditions in order to increase the effect of restoring the light emission characteristic of the blue fluorescent substance once deteriorated.

The higher the temperature in the discharging process (i.e., the higher the temperature at which the panel is heated when the dry gas is supplied and the higher the temperature at which the gas is discharged to become a vacuum), the greater the effect of recovering the deteriorated light emission characteristics.

In order to sufficiently obtain this effect, the peak temperature is preferably set to a high degree such as 300 ° C or higher, more preferably 360 ° C or higher, 380 ° C or higher and 400 ° C or higher. However, the temperature is not set to such a high degree that the sealing glass flows softly.

It is preferable to set the temperature at which the panel is heated while the dry gas is supplied to be higher than the temperature at which the gas is discharged to become a vacuum. This is diminished by the gas (especially vapor) released from the panel into the interior space during the vacuum evacuation process when the temperature is set in reverse; This is because when the temperature is set as described above, less gas is discharged from the panel into the internal space during the vacuum discharge process than in the above case, whereby the effect is obtained.

It is preferable that the partial pressure of the steam in the supplied dry gas is set to a value as low as possible. This is because as the partial pressure of the steam in the dry air is lowered, the recovery effect of the light emission characteristic of the blue fluorescent substance once deteriorated increases, and this effect becomes remarkable even when the partial pressure of the steam is 15 Torr or less, compared with the conventional vacuum discharge process. .

The following experiment shows that it is possible to restore the once deteriorated luminescence properties of the blue phosphor.

17 and 18 show how the recovery effect of the deteriorated luminescence properties depends on the partial pressure of the vapor, and the blue phosphor layer (BaMgAl ₁₀ O ₁₇ : Eu) is once deteriorated and then fired again in air. The measuring method is mentioned later.

The blue phosphor (chromatic coordinate y = 0.052) was calcined in air having a partial pressure of 30 Torr in steam (20 minutes at a peak temperature of 450 ° C.) and the blue phosphor deteriorated by heat. In the deteriorated blue fluorescent substance, the chromaticity coordinate y was 0.092, and the relative emission intensity (the value when the emission intensity of the blue fluorescent substance measured before firing was set to 100 as a standard value) was 85.

The degraded blue phosphor was calcined again at some peak temperature in air with different partial pressures in the vapor (350 ° C. and 450 ° C. held for 30 minutes). Relative emission intensity and chromaticity coordinate y of the blue phosphor fired were measured.

Fig. 17 shows the relationship between the partial pressure of steam in the air upon firing again and the relative luminous intensity measured after firing again. Fig. 18 shows the relationship between the partial pressure of steam in the air upon firing again and the chromaticity coordinate y measured after firing again.

17 and 18, the relative emission intensity of blue light is high and the chromaticity coordinate y of blue light is high when the partial pressure of air vapor during refirement is in the range of 0 Torr to 30 Torr, regardless of whether the refire temperature is 350 ° C or 450 ° C. small. This indicates that even if the fluorescent material is calcined in an atmosphere containing a large amount of steam and the luminescent properties deteriorate, the luminescent properties are restored when the fluorescent material is calcined again in an atmosphere having a low partial pressure in the vapor. That is, this result shows that the degradation of the blue fluorescent substance by heat is a reversible reaction.

In addition, it can be seen from FIGS. 17 and 18 that the effect of restoring the deteriorated light emission characteristics increases as the partial pressure of the vapor in the air during refiring decreases or the refiring temperature increases.

Measurements are not described in detail in the text, but similar measurements were made during various times during which the peak temperature was maintained. This result indicates that as the time for which the peak temperature is maintained increases, the effect of restoring the deteriorated light emission characteristic increases.

Variation of This Embodiment

In this embodiment, dry air is used when the panel is heated in the exhaust process. However, an inert gas such as nitrogen or argon can be used in place of dry air and the effect can be obtained equally.

In the discharge process of this embodiment, the panel is heated while supplying dry air to the spaces between the panels before starting the vacuum discharge process. However, by setting the temperature to a degree higher than normal (ie, 360 ° C. or higher) during the vacuum discharge process, the luminescence properties of the fluorescent material can be restored to a certain degree by performing only the vacuum discharge process. Also in this case, the higher the discharge temperature, the greater the effect of recovering the luminescence property.

However, the discharging process of this embodiment has a larger luminescent property recovery effect than the above modification. This is considered to be because, in the case of the above modification, the internal space between the panels is small so that a sufficient amount of steam is not discharged out of the panel in the vacuum discharge process.

It is expected that the panel structure described in Embodiment 2 is applied to this embodiment to increase the gas discharge effect when the panel is heated while the dry gas is supplied.

Example 4

Panels 21-29 are PDPs produced according to this embodiment. Panels 21 to 29 were manufactured at different heating or discharging temperatures when heating the panel while supplying dry gas to the internal space. In this process, a constant heating temperature was maintained for 30 minutes while supplying dry gas to the internal space, and the constant discharge temperature was maintained for 2 hours in the next vacuum discharge process.

Panels 30 to 32 are PDPs produced according to variations of this embodiment. Panels 30 to 32 were manufactured by performing a vacuum discharge process at 360 ° C or higher without a dry gas process.

Panel 33 is a PDP manufactured according to a conventional method. Panel 33 was manufactured by vacuum discharge process above 350 ℃ without dry gas process.

In each of PDP Nos. 21 to 33, the phosphor layer thickness was 30 μm, and the exhaust gas Ne (95%)-Xe (5%) was charged with a filling pressure of 500 Torr.

Test for Luminescent Properties

For each of PDPs 21 to 33, the relative emission intensity of blue light and the chromaticity coordinate y of blue light were measured as light emission characteristics.

<Test Results and Research>

The test results are shown in Table 4. It can be seen that the relative luminous intensity value with respect to the blue light shown in Table 4 is a relative value when the measured luminous intensity of Comparative Panel No. 33 is set to 100 as the standard value.

From Table 4, each panel 21 to 28 has a higher luminous intensity than panel 33 and a chromaticity coordinate y smaller than that. This indicates that the luminescence properties of the PDP are improved by adopting the discharging step of the present embodiment when producing the PDP.

By comparing the light emission characteristics of panels 21 to 24, it can be seen that the light emission characteristics are improved in the order of panels 21, 22, 23 and 24 (luminescence intensity increases and chromaticity coordinate y decreases). This indicates that the higher the heating temperature of the dry gas process, the greater the effect of recovering the luminescence properties of the blue fluorescent material layer.

By comparing the light emission characteristics of the panels 24 to 26, it can be seen that the light emission characteristics are improved in the order of panel 26, 25 and 24. This indicates that as the heating temperature of the dry gas process is higher than the discharge temperature of the vacuum discharge process, the effect of recovering the luminescence properties of the blue fluorescent material layer is increased.

By comparing the light emission characteristics of panels 24 and 27 to 29, it can be seen that the light emission characteristics are improved in the order of panels 27, 28, 24 and 29. This indicates that the smaller the partial pressure value of the vapor in the dry gas process, the greater the effect of restoring the luminescence property of the blue fluorescent material layer.

Each panel 30 to 32 has a higher emission intensity than panel 33 and a chromaticity coordinate y smaller than that. This indicates that the light emitting characteristics of the PDP are improved by adopting a discharge process, which is a variation of the present embodiment, when producing the PDP.

Each panel 30 to 32 has a lower luminous property than panel 21. This indicates that the effect of restoring the luminescence properties of the blue mold material layer is greater when the dry gas process of this embodiment is adopted.

<Specific example 5>

The PDP of this embodiment has the same structure as that of the first embodiment.

The PDP manufacturing method of the present embodiment is the same as that of the first embodiment until the temporary firing step. However, in the bonding step, the panels are preliminarily heated with spaces formed between the opposing panels, and then the heated panels are assembled and bonded.

In the PDP of this embodiment, when the light is only emitted from the blue cell, the chromaticity coordinate y of the light emitted from the blue cell is 0.08 or less, and the peak wavelength of the spectrum of the emitted light is 455 nm or less, on a white background without color correction. Color temperature is over 7,000 K. Furthermore, by setting the chromaticity coordinate y of the blue light to 0.06 or less, it is possible to increase the color temperature to about 11,000 K on a white background without color correction depending on the manufacturing conditions.

The adhesion process of this embodiment is now described in detail.

19 shows the bonding apparatus structure used in the bonding process.

The bonding apparatus 80 includes a heating furnace 81 for heating the front panel 10 and the rear panel 20, a gas supply valve 82 for adjusting the amount of atmospheric gas supplied to the heating furnace 81, and a heating furnace 81. There is a gas discharge valve 83 for adjusting the amount of gas discharged from

The inside of the furnace 81 may be heated to a high temperature by a heater (not shown). Atmospheric gas (eg, dry air) may be supplied to the heating furnace 81 through the gas supply valve 82, and the atmosphere gas forms an atmosphere in which the panel is heated. A gas may be discharged from the heating furnace 81 through the gas discharge valve 83 using a vacuum pump (not shown) to vacuum the inside of the heating furnace 81. The degree of vacuum in the furnace 81 can be adjusted with the gas supply valve 82 and the gas discharge valve 83.

A dryer (not shown) is formed in the middle of the heating furnace 81 and the atmosphere gas supply source. The dryer removes the water in the atmosphere gas by cooling the atmosphere gas (several degrees below zero) and condensing the water in the gas. The atmospheric gas is transferred to the heating furnace 81 through the dryer to reduce the amount of steam (partial pressure of steam) in the atmospheric gas.

The base 84 is formed in the heating furnace 81. There is a front panel 10 and a back panel 20 on the base 84. A slide pin 85 is formed on the base 84 to move the rear panel 20 in parallel. Above base 84 is a compression mechanism 86 that compresses rear panel 20 downward.

20 is a perspective view showing the internal structure of the heating furnace 81.

In Figures 19 and 20, the rear panel 20 is positioned so that the bulkhead length appears as a horizontal line.

As shown in FIGS. 19 and 20, the length of the rear panel 20 is longer than the front panel 10, and both ends of the rear panel 20 extend longer than the front panel 10. An extended rear panel 20 is provided with lead connecting the address electrode 22 to the activation circuit. The slide pin 85 and compression mechanism 86 are located at four corners of the rear panel 20, with portions of the rear panel 20 extending therebetween.

Four slide pins 85 protruding from the base 84 can simultaneously move up and down with a pin winding and take-up mechanism (not shown).

Each of the four compression mechanisms 86 has a cylindrical support 86a fixed to the ceiling of the furnace 81, a slide rod 86b which can move up and down inside the support 86a and a support device. It consists of the spring 86c which compresses the slide rod 86b downward inside 86a. The pressure applied to the slide rod 86b causes the rear panel 20 to be compressed downward by the slide rod 86b.

21A to 21C show the operation of the bonding apparatus in the preliminary heating process and the bonding process.

Temporary firing processes, preliminary heating processes and bonding processes are described with reference to FIGS. 21A-21C.

Temporary firing process

An outer region of the front panel 10 on the side facing the rear panel 20 with a paste made of sealing glass (glass raw material); An outer region of the rear panel 20 on the side facing the front panel 10; And an outer region of the front panel 10 and the rear panel 20 on the side facing each other. The paste-coated panel is temporarily baked at about 350 ° C. for 10 to 30 minutes to form a sealing glass layer 15. In the figure, the sealing glass layer 15 is formed on the front panel 10.

Preliminary heating process

First, the front panel 10 and the rear panel 20 are properly positioned and then assembled. The panel is placed on the base 84 in a fixed position. Compression mechanism 86 is set to compress rear panel 20 (FIG. 21A).

Next, the atmospheric gas (dry air) is circulated in the heating furnace 81 while performing the next operation (or at the same time, the gas is discharged through the gas discharge valve 83 to be vacuum).

The slide pin 85 is rolled up and moved to a position where the rear panel 20 is parallel (FIG. 21B). This enlarges the space between the front panel 10 and the rear panel 20 so that the fluorescent material layer 25 on the rear panel 20 occupies a large space in the heating furnace 81.

The heating furnace 81 in this state is heated so that the panel releases gas. When the preset temperature (eg 400 ° C) is reached, the preliminary heating process is stopped.

Bonding process

The front and rear panels are reassembled by rolling up the slide pins 85. That is, the rear panel 20 is reset to an appropriate position on the front panel 10 (FIG. 21C).

When the inside of the furnace 81 reaches a constant adhesion temperature (about 450 ° C.) higher than the softening point of the sealing glass layer 15, the adhesion temperature is maintained for 10 to 20 minutes. During this time, the outer regions of the front panel 10 and the rear panel 20 are glued together by the soft sealing glass. The panel is bonded with high stability because the back panel 20 is compressed over the front panel 10 by the compression mechanism 86 during this bonding time.

After the adhesion is complete, the compression mechanism 86 is released and the bonded panel is moved.

The bonding process is carried out as described above, followed by the draining process.

In this embodiment, as shown in FIGS. 19 and 20, the air outlet 21a is formed in the outer region of the rear panel 20. Gas discharge is effected using a vacuum pump (not shown) connected to the glass pipe 26 attached to the air outlet 21a. After the discharge process, the discharge gas is filled through the glass pipe 26 into the interior space between the panels. The PDP is completed after the air outlet 21a is blocked and the glass pipe 26 is cut off.

Effect of the manufacturing method shown in this embodiment

The manufacturing method of this embodiment has the following effects which are not obtained by the conventional method.

As described in Embodiment 1, in a conventional manner, the phosphor layer 25 in contact with the internal spaces between the panels is limited to the gas confined to the space (among the gases, in particular the vapor emitted from the protective layer 14) and the heat. Tends to deteriorate. Deterioration of the phosphor layer decreases the emission intensity of the layer (especially the blue phosphor layer).

According to the method shown in this embodiment, even when the gas such as vapor retained by adsorption on the front and rear panels is released during the preliminary heating process, the gas is confined to the internal space because the panels are separated by a large distance therebetween It doesn't work. Moreover, since the panel is heated to bond immediately after the preliminary heating, water and the like cannot be retained by adsorption on the panel after the preliminary heating. Thus, less gas is released from the panels 10 and 20 during the bonding process to prevent the phosphor layer 25 from being degraded by heat.

In addition, in this embodiment, the preliminary heating process or the bonding process is carried out under an atmosphere in which dry air is circulated. Therefore, the phosphor layer 25 is not degraded by the steam and heat contained in the atmosphere gas.

Another advantage of this embodiment is that the processes can be carried out quickly and with low energy, since the preliminary heating process and the bonding process are carried out continuously in the same furnace 81.

In addition, by using the bonding apparatus of the above structure, it is possible for the front panel 10 and the rear panel 20 to be bonded at appropriately adjusted positions.

Study on panel assembly time and preliminary heating temperature

Heating the panel to as high a temperature as possible to prevent degradation of the phosphor layer 25 by heat and gases emitted from the panel (particularly vapor emitted from the protective layer 14) when the panel is bonded. It is considered desirable.

The following experiment was conducted to study this problem in detail.

The amount of vapor released from the MgO layer was measured using the TDS method for the time when the glass substrate on which the MgO layer was formed as the front panel 10 was gradually heated at a constant heating rate.

22 shows the results of the experiment, or the measured amount of steam released at each heating temperature up to 700 ° C.

In Figure 22, the first peak appears at about 200 ° C to 300 ° C and the second peak appears at about 450 ° C to 500 ° C.

It can be seen from the results shown in FIG. 22 that a large amount of steam is released at about 200 ° C. to 300 ° C. and about 450 ° C. to 500 ° C. when the protective layer 14 is gradually heated.

Thus, in order to prevent the vapor released from the protective layer 14 from confining to the interior space when the panel is heated during the bonding process, the temperature at the time of panel heating is about 200 ° C. or higher, preferably about 300 ° C. to 400 ° C. It is thought that the panels should be separated from each other until they are increased.

In addition, if the panel is bonded after being heated to a temperature higher than about 450 ° C. when the panel is separated, the release of gas from the panel is almost completely prevented. In this case, the panel changes over time after the panel is completed, which hardly degrades the phosphor layer as the panel adheres, and there is little chance for the vapor retained by adsorption to the panel to be gradually released during the discharge. Because.

However, since the phosphor layer and the MgO protective layer are generally formed at a firing temperature of about 520 ° C, it is not preferable that this temperature exceeds 520 ° C. As a result, the panel is more preferably heated to about 450 ° C. to 520 ° C. and then bonded.

On the other hand, the sealing glass flows out of its position when the panel is heated to a temperature exceeding the softening point of the sealing glass when the panel is separated. This may prevent the panel from sticking with high stability.

In order to adhere the panel with high stability from the viewpoint of preventing the deterioration of the phosphor layer by the gas emitted from the panel, the following conclusions (1) to (3) are reached.

(1) It is preferable to heat and heat the front and rear panels as much as possible under the softening point of the sealing glass used when the panels are separated from each other and then to assemble and bond them.

Thus, for example, when conventionally used conventional sealing glass having a softening point of about 400 ° C. is used, in order to reduce the adverse effects of the released gas on as many fluorescent materials as possible while maintaining adhesion stability, the best adhesion process Is to heat to about 400 ° C when the front and back panels are apart, then assemble the panels and heat them to temperatures above the softening point to bond them.

(2) The use of sealing glass with a high softening point increases the heating temperature and enhances the adhesive stability of the panel. Therefore, using such a high softening point sealing glass, the front and rear panels are heated to near the softening point, the panels are assembled and then heated to a temperature above the softening point to bond them so that the fluorescent substance of the emitted gas is maintained while maintaining the panel adhesion stability. The adverse effect on is also reduced.

(3) On the other hand, if the arrangement is made when the panel is separated, it is possible to bond the panel with high stability even when heated to a temperature exceeding the softening point of the sealing glass, and the sealing glass layer formed in the outer region of the front or rear panel is If softened, it does not flow out of position. For example, a partition may be formed between the sealing glass application area and the display area of the outer area of the front or rear panel to prevent the softened sealing glass from flowing out of the display area.

Thus, the gas released when the front and rear panels are heated to a high temperature above the softening point of the sealing glass and then assembled and glued together after such an arrangement to prevent the softened sealing glass from leaking out of the display. The adverse effect on the phosphor can be reduced while maintaining the stability of panel adhesion.

In this case, the front and rear panels are first assembled and bonded directly at high temperatures without heating. As a result, gas release from the panel after the panel is assembled can be almost completely prevented. This allows the panel to adhere without the phosphor deteriorating at all by heat.

Atmospheric gas and pressure

An oxygen containing gas such as air is preferably used as the atmospheric gas circulated in the heating furnace 81 during the bonding process. This is because, as described in Embodiment 1, oxide phosphors often used in PDPs tend to reduce the luminescence properties when heated in an oxygen-free atmosphere.

When the outside air is supplied as the atmospheric gas at atmospheric pressure, a certain effect can be obtained. However, in order to enhance the effect of preventing the deterioration of the fluorescent material, it is preferable to operate the furnace 81 while circulating dry gas such as dry air in the furnace 81 or releasing the gas into a vacuum. Do.

The reason why it is preferable to circulate the dry gas is that there is no worry that the fluorescent material is degraded by the steam and heat contained in the atmosphere gas. It is also preferable to discharge the gas from the heating furnace 81 to become a vacuum. This is because when the panels 10 and 20 are heated, the gas (steam or the like) emitted therefrom is effectively discharged to the outside.

When the dry gas is circulated as the atmospheric gas, the lower the vapor partial pressure contained in the gas, the more the blue fluorescent substance layer is prevented from being deteriorated by heat (see FIGS. 5 and 6 for the experimental results of the specific example 1). In order to obtain a sufficient effect, it is preferable to set the vapor partial pressure to 15 Torr or less. This effect becomes more pronounced when the partial pressure of the steam is set to a low value such as 10 Torr or less, 5 Torr or less, 1 Torr or less, 0.1 Torr or less.

Application of sealing glass

In the bonding process, the sealing glass is typically applied to only one of the two panels (typically only the back panel) before the panels are assembled.

On the other hand, in this embodiment, the back panel 20 is compressed to the front panel 10 by the compression mechanism 86 in the bonding apparatus 80. In this case, it is difficult to obtain such a strong pressure as generated by the clamp.

In such a case, when the sealing glass is only applied to the rear panel, there is a possibility that the panel may not be completely bonded if the suitability between the sealing glass and the front panel with respect to the adhesion is not good. This defect can be prevented if a sealing glass layer is formed on both the front and back panels. This increases the PDP production rate.

Note that the method of forming a sealing glass layer on both the front and back panels is effective in increasing the yield for the general bonding process in PDP fabrication.

Variation of This Embodiment

In this embodiment, the front panel 10 and rear panel 20 are assembled after being properly positioned before being heated. The slide pin 85 is rolled up to move the rear panel 20 upward and to separate the panel. However, the panels 10 and 20 can be separated from each other in other ways.

For example, FIG. 23 shows another way of lifting the rear panel 20. In the figure, the front panel 10 is surrounded by a frame 87 and fits the front panel 10 to the frame 87. The rods 88 attached to the frame 87 allow the frame 87 to move up and down and to move vertically. In such an arrangement, the back panel 20 lying on the frame 87 can also move up and down in parallel positions. That is, the rear panel 20 is separated from the front panel 10 when the frame 87 is moved upward, and the rear panel 20 is assembled with the front panel 10 when the frame 87 is moved downward.

There are other differences between the two mechanisms. In the bonding apparatus 80, when the back panel 20 is compressed to the front panel 10 by the compression mechanism 86, the weight 89 instead of the compression mechanism 86, as shown in the embodiment shown in FIG. Is placed on the rear panel 20. In this variant method, when the frame 87 is moved downward to the bottom, the weight 89 compresses the rear panel 20 to the front panel 10 by gravity.

24A-24C show operations performed during the bonding process according to another variant method.

In the embodiment shown in FIGS. 24A-24C, the rear panel 20 returns to its initial position some away from the front panel 10.

On base 84, as in the case shown in FIG. 20, four or one pair of pins 85a and one pair of pins 85b correspond to four corners of back panel 20. It is formed in. However, the pin 85a corresponding to one side of the rear panel 20 (left side in FIGS. 24A-24C) supports the rear panel 20 at four ends (eg, the ends of the fins 85a formed in a spherical shape). Is suitable for a spherical pit formed on the rear panel 20), the pins 85b corresponding to the other side of the rear panel 20 (right side in FIGS. 24A-24C) are movable up and down.

Front panel 10 and rear panel 20 are assembled and placed on base 84 as shown in FIG. 24A. The back panel 20 is rotated relative to the end of the pin 85a by moving the pin 85b upward as shown in FIG. 24B. This causes the rear panel 20 to be partially separated from the front panel 10. The rear panel 20 returns to its initial position by moving the pin 85b downward by rotating in reverse as shown in FIG. 24C. That is, panels 10 and 20 are in the same position as initially adjusted appropriately.

Panels 10 and 20 are in contact with pin 85a side in the step shown in FIG. 24B. However, the gas emitted from the panel is not limited to the interior space because the other side of the panel is open.

Example 5

Panels 41 to 50 are PDPs produced according to this embodiment. Panels 41-50 were fabricated under different conditions during the bonding process. That is, the panels were heated under various pressures and under various atmosphere gases, and assembled at various temperatures for various time periods.

Each panel was temporarily baked at 350 ° C.

For panels 41-46 and 48-50, dry gas with different partial pressures of steam in the range of 0 Torr to 12 Torr was used as the atmosphere gas. Panel 47 was heated while evacuating the gas.

For panels 43 to 47, the panels were heated at room temperature to 400 ° C. (below the softening point of the sealing glass) and then the panels were assembled. The panel was further heated to 450 ° C. (above the softening point of the sealing glass) and the temperature was maintained for 10 minutes and then reduced to 350 ° C. and the gas was vented while maintaining the temperature at 350 ° C.

For panels 41 and 42, the panels were bonded at low temperatures of 250 ° C. and 350 ° C., respectively.

For panel 48, the panels were heated to 450 ° C. and then assembled at this temperature. For panel 49, the panel was heated to 500 ° C. (peak temperature) and then assembled at this temperature.

For panel 50, the panel was heated to 450 ° C. following a peak temperature of 480 ° C. and the panel was assembled by bonding at 450 ° C.

Panel 51 is a PDP made according to the variation of embodiment 5 shown in FIGS. 24A-24C, wherein the panel was heated to 450 ° C. (peak temperature) and then assembled and bonded at this temperature.

Panel 52 is a comparative PDP produced by assembling the panel at room temperature and then bonding it by heating to 450 ° C. in dry air under atmospheric pressure.

In each of PDP Nos. 41 to 52, the phosphor layer thickness was 30 μm, and the exhaust gases Ne (95%)-Xe (5%) were charged at a packing pressure of 500 Torr, each having the same panel structure.

Test for Luminescent Properties

For each of PDPs 41-52, the relative luminescence intensity of emitted blue light, chromaticity coordinate y of emitted blue light, peak wavelength of emitted blue light, panel brightness and color temperature on white background without color correction and blue The peak intensity ratio of the spectrum of light emitted from the cell to the green cell was measured as luminescence properties.

Each of the prepared PDPs was decomposed and a vacuum ultraviolet ray (center wavelength 146 nm) was irradiated with a blue phosphor layer on the rear panel using a krypton excimer lamp. The chromaticity coordinate y of the blue light was measured.

The results are shown in Table 5. The relative light emission intensity value with respect to blue light shown in Table 5 is a relative value when the measured light emission intensity of panel 52 as a comparative example is set to 100 as a standard value.

In addition, each of the manufactured PDPs was disassembled and vacuum ultraviolet rays were irradiated with a blue phosphor layer on the rear panel using a Krypton excimer lamp. The color temperature when light is emitted from all blue, red and green cells and the peak intensity ratio of the light spectrum emitted from the blue and green cells were measured. The results were the same as above.

FIG. 25 shows the light spectrum emitted from only the blue cells of PDPs in panels 45, 50 and 52. FIG.

Although not shown in Table 5, the chromaticity coordinates x and y of the light emitted from the red and green cells 41 to 53 were substantially the same: red (0.636, 0.350), green (0.251, 0.692). In the comparative PDP, the chromaticity coordinates x and y of the light emitted from the blue cell were (0.170, 0.090) and the peak wavelength in the emitted light spectrum was 458 nm.

Blue phosphor was extracted from the panel. The number of molecules contained in 1 g of H ₂ O gas desorbed from the blue phosphor was measured by TDS analysis. In addition, the c-axis length to a-axis length ratio of the blue phosphor crystal was measured by X-ray analysis. This result is also shown in Table 5.

Research

It can be seen that panels 41 to 51 have better luminescence properties than panel 52 (high emission intensity of blue light and small chromaticity coordinate y). This is thought to be because a small amount of gas is released from the interior spaces between the panels after the panels are adhered according to this embodiment rather than conventional methods.

In the PDP of panel 52, the chromaticity coordinate y of the light emitted from the blue cell is 0.088 and the color temperature on the white background without color correction is 5800 K. Conversely, in panels 41-51, the values are below 0.08 and above 6500 K, respectively. In particular, in panels 48 to 51 having a low chromaticity coordinate y of blue light, it can be seen that a high color temperature of about 11,000 K (in a white background without color correction) has been achieved.

Fig. 26 is a CIE chromaticity diagram showing the color reproduction area around blue in relation to the PDP of this embodiment and the comparative example.

In the figure, area (a) represents the color reproduction area near blue for the case where the chromaticity coordinate y of the blue light is about 0.09 (peak wavelength of the emitted light spectrum is 458 nm) (corresponding to panel 52). b) shows the color reproduction region near blue for the case where the chromaticity coordinate y of the blue light is about 0.08 (peak wavelength of the emitted light spectrum is 455 nm) (corresponding to panel 41), and the region (c) shows the blue light The color reproduction area near blue is shown for the case where the chromaticity coordinate y is about 0.052 (peak wavelength of the emitted light spectrum is 448 nm) (corresponding to panel 50).

From the figure, it can be seen that the color reproduction region near blue expands in the order of regions (a), (b), and (c). This indicates that the smaller the chromaticity coordinate y of the blue light (the shorter the peak wavelength of the emitted light spectrum) can produce a PDP in which the color reproduction region near blue is wider.

By comparing the light emission characteristics of panels 41, 42, 45, and 48 (partial pressure of the vapor in the dry gas is 2 Torr, respectively), the light emission characteristics were found in the order of panels 41, 42, 45 and 48. It can be seen that the light emission intensity increases (the chromaticity coordinate y decreases). This indicates that the higher the heating temperature at the time of bonding the front panel 10 and the back panel 20, the more the luminous characteristics of the PDP are improved.

This is because a small amount of gas is released from the internal space between panels after the panels are glued because when the panels are heated to a preliminary high temperature when they are separated from each other before the panels are glued, the gas released from the panels is sufficiently discharged. I think.

By comparing the light emission characteristics of panels 43 to 46 (having the same temperature profile in the bonding process), it can be seen that the light emission characteristics are improved in the order of panels 43, 44, 45, and 46 (chromaticity coordinate y). Decreases in the above order). This indicates that the lower the partial pressure of the vapor in the atmospheric gas, the more the luminescence properties of the PDP are improved.

By comparing the luminescent properties of panels 46 and 47 (with the same temperature profile in the bonding process), it can be seen that panel 46 is slightly better than panel 47.

This is considered to be because oxygen deficiency is caused in part 47 because some oxygen is released from an fluorescent substance which is an oxide and is preliminarily heated in an oxygen-free atmosphere, while panel 46 is preliminarily heated in an oxygen-containing atmosphere gas.

It can be seen that the light emission characteristics of panels 48 and 51 are almost the same. This indicates that there is little difference in the light emitting characteristics of the PDP between the case where the panels are preheated when the panels are completely separated from each other and when the panels are partially separated.

It can be seen from Table 5 that the chromaticity coordinate y values are almost the same regardless of the measurement by irradiating a vacuum ultraviolet ray to the blue phosphor layer or only emitting light from the blue phosphor layer.

Note that the relationship between the peak wavelength of the emitted blue light and the chromaticity coordinate y of the emitted blue light for each panel provided in Table 5 shows that the peak wavelength also becomes shorter as the chromaticity coordinate y becomes smaller. This indicates that they are proportional to each other.

<Specific example 6>

The PDP of this embodiment has the same structure as that of the first embodiment.

In the manufacturing method of the PDP, the sealing glass is applied to the at least one front panel 10 and the rear panel 20, and the temporary firing process, the bonding process and the discharge process are continuously performed in the heating furnace 81 of the bonding apparatus 80. It is the same as that of Example 5 except having implemented.

The temporary firing process, the bonding process and the discharging process of this embodiment are described in detail.

These processes are carried out using the bonding apparatus shown in FIGS. 19 and 20. However, in this embodiment, as shown in FIGS. 27A-27C, the pipe 90 is fitted from the outside of the furnace 81 and attached to the air outlet 21a of the rear panel 20. 26).

27A, 27B and 27C show operations performed in the temporary firing process or the discharging process using the bonding apparatus.

The temporary firing process, the bonding process and the discharging process are described with reference to these drawings.

Temporary firing process

An outer region of the front panel 10 on the side facing the sealing glass paste toward the rear panel 20; An outer region of the rear panel 20 on the side facing the front panel 10; And an outer region of the front panel 10 and the rear panel 20 on the side facing each other. In the figure, it can be seen that the sealing glass layer 15 is formed on the front panel 10.

The front panel 10 and the back panel 20 are properly positioned and then assembled. The panel is placed on base 84 in a fixed position. Compression mechanism 86 is set to compress rear panel 20 (FIG. 27A).

The following operation is performed while circulating the atmospheric gas (dry air) in the heating furnace 81 (or at the same time discharging the gas through the gas discharge valve 83 to become a vacuum).

The slide pin 85 is rolled up to move the rear panel 20 to a parallel position (FIG. 27B). This expands the space between the front panel 10 and the rear panel 20 so that the phosphor layer 25 on the rear panel 20 occupies a large space in the heating furnace 81.

The heating furnace 81 in this state is heated to a temporary firing temperature (about 350 ° C.), and then the panel is temporarily heated at that temperature for 10 to 30 minutes.

Preliminary heating process

Panels 10 and 20 are further heated to release the gas retained by adsorption to the panels. When the preset temperature (eg 400 ° C) is reached, the preliminary heating process is stopped.

Bonding process

Roll up the slide pins 85 so that the front and back panels are reassembled. That is, the rear panel 20 is reset to an appropriate position on the front panel 10 (FIG. 27C).

When the inside of the furnace 81 reaches a constant adhesion temperature (about 450 ° C.) higher than the softening point of the sealing glass layer 15, the adhesion temperature is maintained for 10 to 20 minutes. During this time, the outer regions of the front panel 10 and the rear panel 20 are glued together by the soft sealing glass. The panel is bonded with high stability because the back panel 20 is compressed over the front panel 10 by the compression mechanism 86 during this bonding time.

Discharge process

The inside of the furnace is cooled to a discharge temperature below the softening point of the sealing glass layer 15. The panel is baked at a temperature (eg, 1 hour at 350 ° C.). The gas is vented from the interior spaces between the bonded panels to a high vacuum (8 × 10 ⁻⁷ Torr). The discharge process is carried out using a vacuum pump (not shown) connected to the pipe 90.

The panel is then cooled to room temperature while maintaining the vacuum of the interior space. The exhaust gas is filled into the inner space through the glass pipe 26. The PDP is completed after the air outlet 21a is blocked and the glass pipe 26 is cut off.

Effect of the manufacturing method shown in this embodiment

The manufacturing method of this embodiment has the following effects which are not obtained by the conventional method.

Conventionally, the temporary firing process, the bonding process and the discharging process are carried out separately using a heating furnace, and the panels are cooled to room temperature at each interval between the processes. With such a structure, it takes a long time and consumes a lot of energy for the panels to be heated in each process. In contrast, in this embodiment, these processes are carried out continuously in the same furnace without lowering the temperature to room temperature. This reduces the time and energy required for heating.

In this embodiment, the temporary firing step and the preliminary heating step are carried out while the heating furnace 81 is heated to the temperature for the bonding step, so that the temporary firing step or the bonding step is carried out quickly and with less energy. Furthermore, in this embodiment, the discharging step is carried out while the panel is cooled to room temperature after the bonding step, so that the bonding step or the discharging step is carried out quickly and with low energy consumption.

Moreover, this embodiment has the same effect as Embodiment 5 compared to the conventional bonding method as described.

In general, gases such as steam are retained by adsorption on the surfaces of the front and back panels. The adsorbed gas is released when the panel is heated.

In the conventional method, in the bonding process following the temporary firing process, the front panel and the rear panel are first assembled at room temperature and then heat bonded. In the bonding process, gases retained by adsorption on the front panel and the back panel surfaces are released. Even if a certain amount of gas is released in the temporary firing process, if the panel is placed in air at room temperature before starting the bonding process, the gas is retained by adsorption again, and the gas is released in the bonding process. The released gas is confined to a small space between the panels. At this time, the phosphor layer tends to be deteriorated by heat and gas, in particular vapor emitted from the protective layer 14. Degradation of the phosphor layer reduces the luminescence intensity of the layer.

On the other hand, according to the manufacturing method shown in this embodiment, the gas discharged from the panel is not limited to the inner space because a wide gap is formed between the panels in the bonding step or the preliminary heating step. Further, since the panel is continuously heated in the bonding step following the preliminary heating step, water or the like is not retained by adsorption on the panel after the preliminary heating step. Therefore, a small amount of gas is released from the panel during the bonding process. This prevents the phosphor layer 25 from being degraded by heat.

It is also possible to first adjust the panel appropriately and then to heat it with the bonding apparatus 80 of this embodiment at a suitable position.

Furthermore, in this embodiment, the preliminary heating step or the bonding step is carried out in an atmosphere in which dry gas is circulated. This prevents the phosphor layer 25 from being deteriorated by steam and heat contained in the atmosphere gas.

Temperature at preliminary heating; Panel assembly time; Atmosphere gas type; Preferred conditions for this embodiment in terms of pressure and partial pressure of steam are the same as described in embodiment 5.

Variation of This Embodiment

In this embodiment, the temporary firing step, the preliminary heating step, the bonding step and the discharge step are carried out continuously in the same apparatus. However, the same effect can be obtained to some extent even if the preliminary heating step is omitted. In addition, even if the temporary firing process and the bonding process are carried out continuously in the same apparatus, or the bonding process and the discharge process are continuously performed in the same apparatus, the same effect is obtained to some extent.

In this embodiment, the inside of the furnace is cooled to a discharge temperature (350 ° C.) below the softening point of the sealing glass after the bonding process and the gas is discharged at that temperature. However, it is possible to discharge the gas at a high temperature as in the bonding process. In this case, the gas is sufficiently discharged in a short time. However, in order to do this, it is thought that some arrangement should not be made to flow out of the position (for example, the partition shown in Figs. 10 to 16) even if the sealing glass layer is softened.

In this embodiment, the temporary firing process and the preliminary heating process are performed when the front panel 10 and the rear panel 20 are separated from each other. However, the temporary firing process, the bonding process, and the discharging process are adopted by adopting the method of embodiment 3, in which the panel is properly positioned, then assembled, the pressure in the inner space is reduced, and the panel is heated and bonded while supplying dry air to the inner space. It is possible to carry out this continuously.

The method will be described. The sealing heating device 50 shown in FIG. 4 is used. First, the sealing glass is applied to one or both of the front panel 10 and the rear panel 20 to form the sealing glass layer 15. After the panels 10 and 20 are properly positioned, they are assembled without temporarily firing and placed in the heating furnace 51.

The pipe 52a is connected to a glass pipe 26a attached to the air outlet 21a of the rear panel 20. Gas is discharged from space through pipe 52b using a vacuum pump (not shown). At the same time, dry air is supplied to the internal space through a pipe 52b connected to the glass pipe 26b attached to the air outlet 21b of the rear panel 20. By doing so, the pressure in the interior space is reduced while flowing dry air through the interior space.

While maintaining the above state of the space between the panels 10 and 20, the inside of the furnace 51 is heated to a temporary firing temperature and the panel is temporarily baked (10 to 30 minutes at 350 ° C).

Since it is difficult to supply oxygen to the sealing glass layer, if the panels are simply fired after the panels are assembled, they are not fired sufficiently in the temporary firing process. However, when the panels are fired while flowing dry air through the internal spaces between the panels, they are sufficiently fired.

The temperature is increased to some adhesion temperature above the softening point of the sealing glass and the adhesion temperature is maintained for a period of time (eg, a peak temperature of 450 ° C. is maintained for 30 minutes). During this time, the front panel 10 and the back panel 20 are bonded by the soft sealing glass.

The inside of the furnace 51 is cooled to the discharge temperature below the softening point of the sealing glass. By maintaining the discharge temperature, the gas is discharged from the interior spaces between the bonded panels to become a high vacuum. After this discharge step, the panel is cooled to room temperature. The exhaust gas is filled into the inner space through the glass pipe 26. The PDP is completed after the air outlet 21a is blocked and the glass pipe 26 is cut off.

In this modified embodiment, as in the method of this embodiment, the temporary firing process, the bonding process and the discharging process are carried out continuously in the same bonding apparatus without reducing the temperature to room temperature. Therefore, these processes are carried out quickly and with low energy consumption.

In this modified embodiment, only the temporary firing process and the bonding process are continuously performed in the heating furnace 51, or only the bonding process and the discharging process are continuously performed in the heating furnace 51 to obtain the same effect to some extent.

Example 6

Panels 61-69 are PDPs produced according to this embodiment. Panels 61-69 were fabricated under different conditions during the bonding process. That is, the panels were heated under various pressures and under various atmosphere gases, and assembled at various temperatures for various time periods.

FIG. 28 shows temperature profiles used in the temporary firing process, the bonding process, and the discharging process in manufacturing panels 63 to 67. FIG.

For panels 61-66 and 68-69, dry gas with different partial pressures of steam in the range of 0 Torr to 12 Torr was used. For panel 70, non-drying gas was used. Panel 67 was heated while evacuating the gas.

For panels 63-67, the panels were heated to 350 ° C. at room temperature. The panels were temporarily baked by maintaining their temperature for 10 minutes. Next, the panel was heated to 400 ° C. (below the softening point of the sealing glass), and then the panel was assembled. The panel was heated to 450 ° C. (above the softening point of the sealing glass) and the temperature was maintained for 10 minutes and then reduced to 350 ° C. and the gas was vented while maintaining the temperature at 350 ° C.

For panels 61 and 62, the panels were bonded at low temperatures of 250 ° C and 350 ° C, respectively.

For panel 68, the panel was heated to 450 ° C. and then assembled at this temperature. For panel 69, the panel was heated to 450 ° C. following a peak temperature of 480 ° C. and the panel was assembled at 450 ° C. to bond.

Panel No. 70 is a comparative PDP produced according to a conventional method of temporarily firing a panel, assembling at room temperature, and heating to an adhesion temperature of 450 ° C. in air under atmospheric pressure. The panel was then once cooled to room temperature and again heated in a furnace to a discharge temperature of 350 ° C. The gas was discharged from the space by maintaining the temperature at 350 ° C.

In each of PDP Nos. 61 to 70, the phosphor layer thickness was 30 μm, and the exhaust gases Ne (95%)-Xe (5%) were charged with a filling pressure of 500 Torr, indicating that each had the same panel structure. Can be.

Test for Luminescent Properties

For each of PDPs 61-70, the relative emission intensity of emitted blue light, chromaticity coordinate y of emitted blue light, peak wavelength of emitted blue light, color temperature on white background without color correction, and blue cell vs. The peak intensity ratio of the spectrum of light emitted from the green cell was measured as the luminescence property.

The results are shown in Table 6. It can be seen that the relative luminous intensity value with respect to the blue light shown in Table 6 is a relative value when the measured luminous intensity of Panel No. 70 as a comparative example is set to 100 as a standard value.

Each manufactured PDP was disassembled and vacuum ultraviolet rays were irradiated with a blue phosphor layer on the rear panel using a krypton excimer lamp. The chromaticity coordinates y of the emitted blue light, the color temperature when the light is emitted from all blue, red and green cells, and the peak intensity ratio of the light spectrum emitted from the blue and green cells were measured. The results were the same as above.

Blue phosphor was extracted from the panel. The number of molecules contained in 1 g of H ₂ O gas desorbed from the blue phosphor was measured by TDS analysis. In addition, the ratio of c-axis length to a-axis length of the blue phosphor crystal was measured by X-ray analysis. This result is also shown in Table 6.

Research

For each of panels 61 to 70, the emission intensity of emitted blue light, the chromaticity coordinate y of emitted blue light, the peak wavelength of emitted blue light, and the color temperature in the white background without color correction (power equal light) Color temperature when emitted from blue, red, and green cells having a color and displayed as white) was measured as the luminescence property.

<Test Results>

The test results are shown in Table 6. It can be seen that the relative light emission intensity value with respect to the blue light shown in Table 6 is a relative value when the measured light emission intensity of panel 70 is set to 100 as the standard value.

From Table 6, it can be seen that panels 61 to 69 have better emission characteristics than panel 70 (high emission intensity of blue light and small chromaticity coordinate y). This is considered to be because a small amount of gas is released from the internal space between the panels after the panels are adhered according to this embodiment rather than the conventional method.

In the PDP of panel 70, the chromaticity coordinate y of the light emitted from the blue cell is 0.090 and the color temperature on the white background without color correction is 5800 K. Conversely, in panels 61-69, the values are below 0.08 and above 6500 K, respectively. In particular, in panels 68 to 69 having a low chromaticity coordinate y of blue light, it can be seen that a high color temperature of about 11,000 K (in a white background without color correction) has been achieved.

By comparing the light emission characteristics of panels 61, 62, 65, 68 and 69 (partial pressure of vapor in dry gas is 2 Torr, respectively), the light emission characteristics of panels 61, 62, 65, It can be seen that in the order of 68, 69 (luminescence intensity increases and chromaticity coordinate y decreases). This indicates that the higher the heating temperature at the time of bonding the front panel 10 and the back panel 20, the more the luminous characteristics of the PDP are improved.

By comparing the light emission characteristics of panels 63 to 66 (having the same temperature profile in the bonding process), it can be seen that the light emission characteristics are improved in the order of panels 63, 64, 65 and 66 (chromatic coordinate y). Decreases in the above order). This indicates that the lower the partial pressure of the vapor in the atmospheric gas, the more the luminescence properties of the PDP are improved.

By comparing the light emission characteristics of panels 66 and 67 (having the same temperature profile in the bonding process), it can be seen that panel 66 is slightly better than panel 67.

It is thought that this is because oxygen deficiency is caused in part 67 because part of oxygen leaves the fluorescent material which is an oxide and is preliminarily heated in an oxygen-free atmosphere, while panel 66 is preliminarily heated in an oxygen-containing atmosphere gas.

Etc

In Examples 1 to 6, the fabrication case of the surface-emitting PDP was described. However, the present invention can be applied to the case of manufacturing the counter emission type PDP.

The present invention is achieved by using a fluorescent material generally used in PDP in addition to the fluorescent material having the composition shown in the above embodiment.

Typically, as shown in Examples 1 to 6, a fluorescent material layer is formed and then sealing glass is applied. However, these process sequences may be reversed.

The PDP and the PDP manufacturing method of the present invention are effective for the production of displays for computers or TVs, in particular for the production of large screen displays.

Claims (111)

In the PDP manufacturing method, Applying a fluorescent substance to at least one of a front panel surface facing the rear panel and a rear panel surface facing the front panel; And A heating step of heating any one or both of the front panel and the rear panel coated with the fluorescent material, The heating step is carried out when the applied fluorescent material is in contact with the dry gas. The method of claim 1, The heating step is a PDP manufacturing method, characterized in that acting as a fluorescent material firing step in which the fluorescent material applied in the fluorescent material applying step is fired. In the PDP manufacturing method, The fluorescent material and the sealing material are applied to at least one of the front panel surface facing the rear panel and the rear panel surface facing the front panel, and the front panel and the rear panel coated with the fluorescent material and the sealing material Or both are made of a temporary firing step of the sealing material for temporarily firing at a temporary firing temperature, Sealing material temporary firing step is characterized in that the PDP manufacturing method characterized in that it is carried out when the applied fluorescent material in contact with the dry gas. In the PDP manufacturing method, Applying a fluorescent material to one of a front panel surface facing the rear panel and a rear panel surface facing the front panel; A sealing material applying step of applying the sealing material to the other surface of the front panel and the rear panel to which the fluorescent material is not applied; And By the temporary firing temperature for the sealing material is made of the temporary material firing step for sealing the front panel and the rear panel temporarily, Sealing material temporary firing step is characterized in that the PDP manufacturing method characterized in that it is carried out when the applied fluorescent material in contact with the dry gas. In the PDP manufacturing method, Forming a fluorescent material layer on at least one of a front panel surface facing the rear panel and a rear panel surface facing the front panel; A sealing material layer forming step of forming a sealing material layer on at least one of a front panel surface facing the rear panel and a rear panel surface facing the front panel; And After the phosphor layer forming step and the sealing material layer forming step, the front panel is assembled by assembling these panels to form an internal space between the front panel and the rear panel and maintaining an adhesion temperature equal to or higher than the temperature at which the sealing material softens. It consists of a bonding step for bonding the panel and the back panel, The bonding step is performed when the fluorescent material layer is in contact with the dry gas. The method of claim 5, Bonding step is a PDP manufacturing method characterized in that is carried out when the dry gas is circulated in the inner space. The method of claim 5, The bonding step is carried out when the operation of filling the dry gas into the interior space and the operation of discharging the gas from the interior space is carried out alternately. In the PDP manufacturing method, Forming a fluorescent material layer on at least one of a front panel surface facing the rear panel and a rear panel surface facing the front panel; An adhesive step of assembling these panels and adhering the front panel and the rear panel so that an internal space is formed between the front panel and the rear panel after the phosphor layer forming step; And Method for producing a PDP characterized in that the heated front panel and the rear panel is heated to a temperature higher than room temperature when the dry gas is circulated in the inner space. In the PDP manufacturing method, Forming a fluorescent material layer on at least one of a front panel surface facing the rear panel and a rear panel surface facing the front panel; An adhesive step of assembling these panels and adhering the front panel and the rear panel so that an internal space is formed between the front panel and the rear panel after the phosphor layer forming step; And A discharge step of discharging gas from the interior space while maintaining the discharge temperature for the bonded panel higher than room temperature, Ejection step is characterized in that the PDP manufacturing method characterized in that is carried out when the contact with the dry gas. In the PDP manufacturing method, Forming an MgO layer on at least one of a front panel face facing the rear panel and a back panel face facing the front panel; A heating step of heating one or both of the front panel and the rear panel on which the MgO layer is formed, The heating step is carried out when the MgO layer is in contact with the dry gas. In the PDP manufacturing method, Forming a fluorescent material layer on at least one of a front panel surface facing the rear panel and a rear panel surface facing the front panel; Forming an MgO layer on at least one of a front panel face facing the back panel and a back panel face facing the front panel; And After the fluorescent material layer forming step and the MgO layer forming step of the heating step of heating the front panel and the rear panel, Heating step is carried out when the MgO layer and the phosphor layer is in contact with the dry gas. In the PDP manufacturing method, Forming a fluorescent material layer on at least one of a front panel surface facing the rear panel and a rear panel surface facing the front panel; Forming an MgO layer on at least one of a front panel face facing the back panel and a back panel face facing the front panel; A sealing material layer forming step of forming a sealing material layer on at least one of a front panel surface facing the rear panel and a rear panel surface facing the front panel; And After the phosphor layer forming step, the MgO layer forming step, and the sealing material layer forming step, these panels are assembled so that an internal space is formed between the front panel and the back panel, and the bonding temperature is equal to or higher than the temperature at which the sealing material is softened. It consists of a bonding step for bonding the front panel and the rear panel by maintaining the PDP manufacturing method characterized in that the bonding step is carried out when the dry gas is supplied to the internal space. The method of claim 6, The bonding step is performed when the dry gas is circulated in the inner space and the internal pressure of the inner space is maintained at a bonding pressure of less than atmospheric pressure. The method of claim 13, PDP manufacturing method characterized in that the bonding pressure is 500 Torr or less. The method of claim 13, PDP manufacturing method characterized in that the bonding pressure is 300 Torr or less. The method of claim 13, The front panel and the back panel are heated when the phosphor layer is at a pressure higher than the bonding pressure, and then the gas pressure in the inner space is reduced to the bonding pressure, and the bonding step is started in this state. . The method of claim 16, When the phosphor layer is at a pressure higher than the bonding pressure, the front panel and the rear panel are heated to a temperature equal to or higher than the softening point of the sealing material, and then the gas pressure in the inner space is reduced to the bonding pressure and in this state PDP manufacturing method characterized in that the bonding step is initiated. The method of claim 16, When the phosphor layer is at a pressure higher than the bonding pressure, the front panel and the rear panel are heated to 300 ° C. or higher, and then the gas pressure in the inner space is reduced to the bonding pressure and the bonding step is started in this state. PDP manufacturing method. The method of claim 16, When the phosphor layer is at a pressure higher than the bonding pressure, the front panel and the rear panel are heated to 350 ° C. or higher, and then the gas pressure in the inner space is reduced to the bonding pressure, and the bonding step is started in this state. PDP manufacturing method. The method of claim 16, When the phosphor layer is at a pressure higher than the bonding pressure, the front panel and the rear panel are heated to 400 ° C. or higher, and then the gas pressure in the inner space is reduced to the bonding pressure, and the bonding step is started in this state. PDP manufacturing method. The method of claim 13, PDP manufacturing method characterized in that the gas is forcibly discharged from the inner space in the bonding step. The method of claim 6, In the sealing material layer forming step, the sealing material layer is formed in a frame shape in the outer region of at least one of the front panel surface facing the rear panel and the rear panel surface facing the front panel, Prior to the bonding step, a plurality of partition walls are formed in a row direction on either of the front panel surface facing the rear panel and the rear panel surface facing the front panel such that the plurality of partition walls are in the sealing material layer and the pair of first A gap is formed between the end of the plurality of partition walls and the inner surface of the two sealing material layers, and the minimum width of the pair of first gaps is between the two outermost partition walls of the plurality of partition walls and the other sealing material layer. Is wider than the minimum width of the second gap of the pair, In the bonding step, the dry gas is moved from one side of the pair of the first gap to the other, characterized in that the PDP manufacturing method. The method of claim 6, In the sealing material layer forming step, the sealing material layer is formed in a frame shape in the outer region of at least one of the front panel surface facing the rear panel and the rear panel surface facing the front panel, Prior to the bonding step, a plurality of first partition walls are formed in a column direction on one of the front panel surface facing the rear panel and the rear panel surface facing the front panel so that the plurality of partition walls come into contact with the inside of the sealing material layer. In a second partition formed, a pair of first gaps are formed between the plurality of partition wall ends and two second partition inner surfaces, and the minimum width of the pair of first gaps is the two outermost of the plurality of partitions. Is wider than the minimum width of the pair of second gaps between the bulkhead and the other second bulkhead, In the bonding step, the dry gas is moved from one side of the pair of the first gap to the other, characterized in that the PDP manufacturing method. In the PDP manufacturing method, Forming a fluorescent material layer on at least one of a front panel surface facing the rear panel and a rear panel surface facing the front panel; A sealing material layer forming step of forming a sealing material layer on at least one of a front panel surface facing the rear panel and a rear panel surface facing the front panel; A preliminary heating step of heating the front panel and the rear panel when the space between the panel surfaces facing each other is opened after the fluorescent material layer forming step and the sealing material layer forming step; And An adhesive step of assembling the front panel and the rear panel by assembling these panels so that an inner space is formed between the front panel and the rear panel immediately after the preliminary heating step, and maintaining a bonding temperature equal to or higher than the softening point of the sealing material. PDP manufacturing method characterized in that. The method of claim 24, Wherein, in the preliminary heating step, the front panel and the back panel are heated to a temperature below the softening point of the sealing material, and in the bonding step, these panels are assembled and heated to the bonding temperature to which they are bonded. The method of claim 24, Wherein, in the preliminary heating step, the front panel and the back panel are heated to a temperature higher than the bonding temperature, and the bonding step is started after the front panel and the back panel are cooled to the bonding temperature. The method of claim 24, A preliminary heating step is carried out when the front panel and the rear panel is under pressure below atmospheric pressure. The method of claim 24, The preliminary heating step is characterized in that the front panel and the back panel is carried out when the atmosphere of the dry gas PDP manufacturing method. The method of claim 28, The preliminary heating step is characterized in that the front panel and the back panel is carried out when the dry gas is circulated in the manufacturing method of the PDP. The method of claim 24, The preliminary heating step is carried out while forcibly discharging the gas emitted from these panels to the outside when the front panel and the rear panel is heated. The method of claim 24, Separating the front panel and the back panel from each other by properly positioning the front panel and the back panel, assembling the panels and moving these panels along a certain path, further comprising a separation step performed before the preliminary heating step, , PDP manufacturing method comprising assembling the front panel and the rear panel by moving the panel as opposed to the movement along a constant path of the separation step. The method of claim 31, wherein In the separating step and the bonding step, PDP manufacturing method characterized in that to move the front panel and the rear panel to a parallel position respectively. The method of claim 24, PDP manufacturing method characterized in that the heating the front panel and the rear panel to 200 ℃ or more in the preliminary heating step. The method of claim 24, PDP manufacturing method characterized in that the front panel and the rear panel is heated to 300 ℃ or more in the preliminary heating step. The method of claim 24, Method for producing a PDP, characterized in that for heating the front panel and the rear panel to a temperature in the range of 300 ℃ to 400 ℃ in the preliminary heating step. The method of claim 24, PDP manufacturing method characterized in that the front panel and the rear panel is heated to 400 ℃ or more in the preliminary heating step. The method of claim 24, Method for producing a PDP, characterized in that for heating the front panel and the rear panel to a temperature in the range of 450 ℃ to 520 ℃ in the preliminary heating step. The method of claim 24, In the sealing material layer forming step, the sealing material layer is formed on both the front panel face facing the rear panel and the back panel face facing the front panel, and in the bonding step, the front panel and the back panel are used for sealing formed on these panels. PDP manufacturing method characterized by assembling the material layer to each other. In the PDP manufacturing method, A sealing material layer forming step of forming a sealing material layer on both the front panel surface facing the rear panel and the rear panel surface facing the front panel; And The front panel and the back panel are made of a PDP manufacturing method characterized in that the bonding step is bonded by matching the sealing material layer formed on these panels with each other In the PDP manufacturing method, Forming a fluorescent material layer on at least one of a front panel surface facing the rear panel and a rear panel surface facing the front panel; A sealing material applying step of applying a sealing material on at least one of a front panel surface facing the rear panel and a rear panel surface facing the front panel; After forming the phosphor layer and applying the sealing material, the front panel and the back panel are assembled by assembling these panels so that an internal space is formed between the front panel and the back panel and maintaining an adhesive temperature equal to or higher than the softening point of the sealing material. Adhering the adhesive; And A discharge step of discharging gas from the interior space while maintaining the discharge temperature for the bonded panel higher than room temperature, Discharge step is a PDP manufacturing method characterized in that the adhesive is initiated without cooling the front panel and the rear panel to the room temperature bonded in the bonding step. In the PDP manufacturing method, Forming a fluorescent material layer on at least one of a front panel surface facing the rear panel and a rear panel surface facing the front panel; A sealing material applying step of applying a sealing material to at least one of a front panel surface facing the rear panel and a rear panel surface facing the front panel; Sealing material temporary firing step of temporarily firing any one or both of the front panel and the rear panel to which the sealing material is applied by maintaining the temporary firing temperature; And After the phosphor layer forming step and the sealing material temporary firing step, the front panel and the rear panel are assembled by assembling these panels so that an internal space is formed between the front panel and the rear panel and maintaining an adhesive temperature equal to or higher than the softening point of the sealing material. It consists of a bonding step of bonding the panels, And the bonding step is initiated without cooling one or two panels of which the temporary firing temperature is maintained during the sealing material temporary firing step without cooling to room temperature. In the PDP manufacturing method, Forming a fluorescent material layer on at least one of a front panel surface facing the rear panel and a rear panel surface facing the front panel; A sealing material applying step of applying a sealing material to at least one of a front panel surface facing the rear panel and a rear panel surface facing the front panel; Sealing material temporary firing step of temporarily firing any one or both of the front panel and the rear panel to which the sealing material is applied by maintaining the temporary firing temperature; After the phosphor layer forming step and the sealing material temporary firing step, the front panel and the rear panel are assembled by assembling these panels so that an internal space is formed between the front panel and the rear panel and maintaining an adhesive temperature equal to or higher than the softening point of the sealing material. Adhering the panel; And A discharge step of discharging gas from the interior space while maintaining the discharge temperature for the bonded panel higher than room temperature, PDP manufacturing method characterized in that the front panel and the rear panel is maintained at a temperature higher than room temperature through all the steps of the sealing material temporary firing step to the discharge step. 43. The method of claim 41 or 42, The bonding step is initiated by heating one or two panels maintained at a temporary firing temperature during the sealing material temporary firing step to an adhesion temperature. 43. The method of claim 40 or 42 wherein The discharging step is started after the bonded front panel and the rear panel are cooled to the discharging temperature. 43. The method of claim 40 or 42 wherein The discharging step is initiated after the bonded front panel and rear panel are maintained at the bonding temperature. 43. The method of claim 41 or 42, The sealing material temporary firing step is carried out when the space between the panel surfaces facing each other is opened, between the sealing material temporary firing step and the bonding step, between these panel surfaces facing the front panel and the rear panel. PDP manufacturing method characterized in that it further comprises a preliminary heating step of heating when the space in the opening. The method of claim 46, In the preliminary heating step, the front panel and the rear panel is heated to a temperature higher than the temporary firing temperature. The method of claim 46, In the preliminary heating step, the front panel and the back panel are heated to a temperature higher than the temporary firing temperature, and then the bonding step is started after cooling the front panel and the back panel to the bonding temperature. . The method of claim 46, The preliminary heating step is a method for producing a PDP, characterized in that carried out under pressure below atmospheric pressure. The method of claim 46, The preliminary heating step is a PDP manufacturing method, characterized in that carried out in an atmosphere of dry gas. The method according to any one of claims 40 to 42, PDP manufacturing method characterized in that the bonding step is carried out when the dry gas is circulated in the inner space. 43. The method of claim 41 or 42, In the temporary firing step of the sealing material, these panels are assembled so that an inner space is formed between the front panel and the rear panel, and the temporary firing step of the sealing material is performed when dry gas is circulated in the inner space. Way. In the PDP manufacturing method, Bonding the front panel and the rear panel by assembling these panels so that an inner space is formed between the front panel and the rear panel and maintaining a bonding temperature equal to or higher than the softening point of the sealing material; And A discharge step of discharging gas from the interior space while maintaining the discharge temperature for the bonded panel higher than room temperature, PDP manufacturing method characterized in that the discharge temperature is 360 ℃ or more. In the PDP manufacturing method, Bonding the front panel and the rear panel by assembling these panels so that an inner space is formed between the front panel and the rear panel and maintaining a bonding temperature equal to or higher than the softening point of the sealing material; And A discharge step of discharging gas from the interior space while maintaining the discharge temperature for the bonded panel higher than room temperature, PDP manufacturing method characterized in that the discharge temperature is 380 ℃ or more. In the PDP manufacturing method, Bonding the front panel and the rear panel by assembling these panels so that an inner space is formed between the front panel and the rear panel and maintaining a bonding temperature equal to or higher than the softening point of the sealing material; And A discharge step of discharging gas from the interior space while maintaining the discharge temperature for the bonded panel higher than room temperature, PDP manufacturing method characterized in that the discharge temperature is 400 ℃ or more. In the PDP manufacturing method, Bonding the panels to the front panel and the rear panel by assembling these panels to form internal spaces between the rear panels and maintaining an adhesion temperature equal to or higher than the softening point of the sealing material; And A discharge step of discharging gas from the interior space while maintaining the discharge temperature for the bonded panel higher than room temperature, The bonded front panel and the rear panel are heated to a predetermined temperature when the dry gas is circulated in the internal space, and then the discharge step is initiated. The method of claim 56, wherein And a predetermined temperature is equal to or higher than the discharge temperature. The method of claim 56, wherein PDP manufacturing method, characterized in that at least one of the predetermined temperature and discharge temperature is 360 ℃ or more. The method of claim 56, wherein At least one of the predetermined temperature and the discharge temperature is at least 380 ℃ method for producing a PDP. The method of claim 56, wherein At least one of the predetermined temperature and the discharge temperature is 400 ℃ or more method. The method according to any one of claims 1 to 23, 28, 50, 51 and 56, Partial pressure of steam in the dry gas is a PDP manufacturing method, characterized in that less than 15 Torr under the atmosphere in which the dry gas is used. The method according to any one of claims 1 to 23, 28, 50, 51 and 56, PDP production method characterized in that the dew point temperature of the dry gas is 20 ℃ or less. 57. The method of any one of claims 1 to 23, 28, 50, 51, and 56, wherein the dry gas contains oxygen. The method according to any one of claims 1 to 23, 28, 50, 51 and 56, Dry gas is a PDP manufacturing method characterized in that the dry air. 61. A PDP prepared according to the PDP manufacturing method of any one of claims 1 to 42 and 52 to 60. A PDP comprising a blue cell formed between a pair of panels parallel to each other, each of which is formed with a blue phosphor layer, and comprising a plurality of cells filled with a gaseous medium, wherein the blue cell only when light is emitted from the blue cell. And a chromaticity coordinate y in the CIE color specification of the light emitted from the image is 0.08 or less. A PDP comprising a blue cell formed between a pair of panels parallel to each other, each of which is formed with a blue phosphor layer, and comprising a plurality of cells filled with a gaseous medium, wherein the blue cell only when light is emitted from the blue cell. And a chromaticity coordinate y in the CIE color specification of the light emitted from the PDP is 0.07 or less. A PDP comprising a blue cell formed between a pair of panels parallel to each other, each of which is formed with a blue phosphor layer, and comprising a plurality of cells filled with a gaseous medium, wherein the blue cell only when light is emitted from the blue cell. And a chromaticity coordinate y in the CIE color specification of the light emitted from the PDP is 0.06 or less. In a PDP comprising a blue cell formed between a pair of panels parallel to each other and a blue phosphor layer is formed, respectively, and a plurality of cells filled with a gas medium, vacuum ultraviolet rays are irradiated to the blue cell to produce a blue cell. And a chromaticity coordinate y in the CIE color specification of the light emitted from the blue cell when being excited is 0.08 or less. In a PDP comprising a blue cell formed between a pair of panels parallel to each other and a blue phosphor layer is formed, respectively, and a plurality of cells filled with a gas medium, vacuum ultraviolet rays are irradiated to the blue cell to produce a blue cell. And a chromaticity coordinate y in the CIE color specification of the light emitted from the blue cell when being excited is 0.07 or less. In a PDP comprising a blue cell formed between a pair of panels parallel to each other and a blue phosphor layer is formed, respectively, and a plurality of cells filled with a gas medium, vacuum ultraviolet rays are irradiated to the blue cell to produce a blue cell. And a chromaticity coordinate y in the CIE color specification of the light emitted from the blue cell at the time of excitation is 0.06 or less. A PDP comprising a blue cell formed between a pair of panels parallel to each other, each of which is formed with a blue phosphor layer, and comprising a plurality of cells filled with a gaseous medium, wherein the blue cell only when light is emitted from the blue cell. The peak wavelength of the spectrum of the light emitted from the PDP is characterized in that less than 455 nm. A PDP comprising a blue cell formed between a pair of panels parallel to each other, each of which is formed with a blue phosphor layer, and comprising a plurality of cells filled with a gaseous medium, wherein the blue cell only when light is emitted from the blue cell. The peak wavelength of the spectrum of the light emitted from the PDP is characterized in that 453 nm or less. A PDP comprising a blue cell formed between a pair of panels parallel to each other, each of which is formed with a blue phosphor layer, and comprising a plurality of cells filled with a gaseous medium, wherein the blue cell only when light is emitted from the blue cell. The peak wavelength of the spectrum of the light emitted from the PDP. A PDP comprising a blue cell formed between a pair of panels parallel to each other and each having a blue phosphor layer formed thereon and comprising a plurality of cells filled with a gas medium, wherein the light is emitted when the light is emitted from all the plurality of cells The color temperature of the light is 7,000 K or more PDP. In a PDP formed between a pair of panels parallel to each other and including a plurality of cells each containing a phosphor layer and filled with a gas medium, the plurality of cells when vacuum ultraviolet rays are irradiated to the phosphor layer and the plurality of cells PDP, characterized in that the color temperature of the light emitted from the 7,000K or more. A PDP comprising a plurality of cells formed between a pair of panels parallel to each other, each containing a blue cell formed with a blue phosphor layer, each containing a green cell formed with a green phosphor layer, and filled with a gaseous medium. Wherein the peak intensity ratio of the light spectrum emitted from the blue cell to the light spectrum emitted from the green cell is at least 0.8 and light is emitted from the blue and green cells under the same conditions. A PDP comprising a plurality of cells formed between a pair of panels parallel to each other, each containing a blue cell formed with a blue phosphor layer, each containing a green cell formed with a green phosphor layer, and filled with a gaseous medium. In which the blue phosphor layer in the blue cell is excited by vacuum ultraviolet light followed by the peak intensity of the light spectrum emitted from the blue cell versus the green phosphor layer in the green cell after being excited by vacuum ultraviolet light PDP, characterized in that the peak intensity ratio of the emitted light spectrum is 0.8 or more. 79. The method of any of claims 66-78, Wherein each of the plurality of cells corresponds to one of the plurality of colors, and the entire area of the cell corresponding to the color is 1.3 times or less with respect to the entire area of the cell corresponding to the other color. 79. The method of any of claims 66-78, The blue phosphor layer is made of BaMgAl ₁₀ O ₁₇ : Eu PDP. 81. The method of claim 80, The green phosphor layer is PDP, characterized in that made of Zn ₂ SiO ₄ . In a PDP comprising a blue cell formed between a pair of panels parallel to each other and each having a blue phosphor layer formed thereon and comprising a plurality of cells filled with a gas medium, the blue phosphor layer is BaMgAl ₁₀ O ₁₇ : Eu And a c-axis length to a-axis length ratio in the blue phosphor layer crystal, characterized in that not more than 4.0218. In a PDP comprising a blue cell formed between a pair of panels parallel to each other and each having a blue phosphor layer formed thereon and comprising a plurality of cells filled with a gas medium, the blue phosphor layer is BaMgAl ₁₀ O ₁₇ : Eu And a peak value of the number of molecules contained in H ₂ 0 desorbed from the blue phosphor layer at 200 ° C. or higher is 1 × 10 ¹⁶ / g or less as measured by TDS analysis. A pair of panels parallel to each other; A plurality of cells formed between the pair of panels; A plurality of partition walls formed between the pair of panels in a column direction to divide the plurality of cells; And A PDP comprising a sealing material layer formed between a pair of panels in a frame shape in an outer region of a pair of panels and adhering a pair of panels, The resistance to gas flowing through each gap between the plurality of partitions is greater than the resistance to gas flowing through each pair of gaps between the two outermost partitions of the plurality of partitions and the sealing material layer. PDP. A pair of panels parallel to each other; A plurality of cells formed between the pair of panels; A plurality of partition walls formed between the pair of panels in a column direction to divide the plurality of cells; And In a PDP comprising a sealing material layer formed between a pair of panels in a frame shape in an outer region between a pair of panels and adhering a pair of panels, A pair of first gaps is formed between the plurality of partition wall ends and two inner sealing material layers, and the minimum width of the pair of first gaps is for sealing the two outermost partitions and the other of the plurality of partitions. PDP wider than the minimum width of a pair of second gaps between material layers. 86. The method of claim 85, The minimum width of the pair of first gaps is at least twice the minimum width of the pair of second gaps PDP. 86. The method of claim 85, The minimum width of the pair of first gaps is at least three times the minimum width of the pair of second gaps. A pair of panels parallel to each other; A plurality of cells formed between the pair of panels; A plurality of partition walls formed between the pair of panels in a column direction to divide the plurality of cells; And A PDP comprising a sealing material layer formed between a pair of panels in a frame shape on an outer portion of a region between a pair of panels and adhering a pair of panels. A pair of first gaps are formed between the plurality of partition wall ends and two inner sealing material layers, and two outermost partition walls of each of the plurality of partition walls are at least partially in contact with the sealing material layer. PDP. A pair of panels parallel to each other; A plurality of cells formed between the pair of panels; A plurality of first partition walls formed between the pair of panels in a column direction and dividing the plurality of cells; A sealing material layer formed between the pair of panels in a frame shape on an outer portion of the area between the pair of panels and adhering the pair of panels; And A PDP comprising a second partition wall formed between a pair of panels and in contact with an inner sealing material layer, A pair of first gaps are formed between the plurality of first partition end portions and the two inner second partition walls, and the minimum width of the pair of first gaps is different from the two outermost partition walls of the plurality of partition walls. PDP wider than the minimum width of the pair of second gaps between the second partition wall. 92. The method of claim 89, The minimum width of the pair of first gaps is more than twice the minimum width of the pair of second gaps PDP. 92. The method of claim 89, And the minimum width of the pair of first gaps is three times greater than the minimum width of the pair of second gaps. A pair of panels parallel to each other; A plurality of cells formed between the pair of panels; A plurality of first partition walls formed between the pair of panels in a column direction and dividing the plurality of cells; A sealing material layer formed between the pair of panels in a frame shape on an outer portion of the area between the pair of panels and adhering the pair of panels; And A PDP comprising a second partition wall formed between a pair of panels and in contact with an inner sealing material layer, The pair of first gaps are formed between a plurality of first partition end portions and two inner second partition walls, and each of the two outermost partition walls of the plurality of first partition walls is at least partially in contact with the second partition wall. PDP. As a PDP manufacturing apparatus, A heating furnace for receiving a panel on which at least one phosphor layer and an MgO layer is formed and heating the panel; And An apparatus for producing a PDP comprising a dry gas supply mechanism for supplying dry gas to a heating furnace to form a dry gas atmosphere in a heating furnace. 94. The method of claim 93, And a discharge mechanism for discharging the gas from the furnace to reduce the pressure of the furnace to below atmospheric pressure. As a PDP manufacturing apparatus, At least one of a front panel face facing the rear panel and a rear panel face facing the front panel, the heating furnace for receiving the front panel and the rear panel assembled with the phosphor layer by itself and heating the front panel and the rear panel; And A PDP manufacturing apparatus comprising a dry gas supply mechanism for supplying dry gas to an interior space between a front panel and a rear panel. 97. The method of claim 95, The furnace further includes a discharge mechanism for accommodating a front panel and a rear panel assembled to form an inner space between the front panel and the rear panel, and for discharging gas from the inner space. 97. The method of any of claims 93-96, A partial pressure of steam in the dry gas supplied by the dry gas supply mechanism is 15 Torr or less in an atmosphere where dry gas is used. 97. The method of any of claims 93-96, Dry gas dew point temperature supplied by a dry gas supply mechanism is 20 ℃ or less apparatus. Assembling a phosphor layer formed on at least one of a front panel and a rear panel, a front panel surface facing the rear panel and a rear panel surface facing the front panel, and a sealing material formed between the front panel and the rear panel, In the PDP manufacturing apparatus which heats these panels, softens the sealing material, and bonds a panel so that internal space may be formed between these panels, A heating mechanism for heating the front panel and the back panel; And a moving mechanism for moving the assembled front panel and rear panel to separate the panels from each other along a predetermined path, and moving the panels in opposite directions to reassemble the front panel and the rear panel. The method of claim 99, wherein And a chamber in which the front panel and the rear panel are accommodated, and a discharge mechanism for discharging gas from the chamber. Assembling a phosphor layer formed on at least one of a front panel and a rear panel, a front panel surface facing the rear panel and a rear panel surface facing the front panel, and a sealing material formed between the front panel and the rear panel, In the PDP manufacturing apparatus which heats these panels, softens the sealing material, and bonds these panels, A chamber in which the front panel and the rear panel are accommodated; A discharge mechanism for discharging the gas from the chamber; And A PDP manufacturing apparatus comprising a heating mechanism for heating a front panel and a rear panel accommodated in a chamber. 102. The method of claim 101, wherein And a dry gas supply mechanism for supplying dry gas to the chamber. Assembling a phosphor layer formed on at least one of a front panel and a rear panel, a front panel surface facing the rear panel and a rear panel surface facing the front panel, and a sealing material formed between the front panel and the rear panel, In the PDP manufacturing apparatus which heats these panels, softens the sealing material, and bonds a panel so that internal space may be formed between these panels, A discharge mechanism for discharging the gas from the internal space; And A PDP manufacturing apparatus comprising a heating mechanism for heating a front panel and a rear panel. 103. The method of claim 103, And a dry gas supply mechanism for supplying dry gas to an internal space between the front panel and the rear panel. 105. The method of claim 102 or 104, A partial pressure of steam in dry gas supplied by a dry gas supply mechanism is 15 Torr or less in an atmosphere where dry gas is used. 105. The method of claim 102 or 104, The dew point temperature of the dry gas supplied by the dry gas supply mechanism is 20 ℃ or less apparatus. 105. The method of claim 102 or 104, The dry gas supplied by the dry gas supply mechanism contains oxygen. 105. The method of claim 102 or 104, The dry gas supplied by the dry gas supply mechanism is dry air. 61. A PDP produced by the PDP manufacturing method of any one of claims 1 to 42 and 53 to 60; And A PDP display device comprising an activation circuit for activating a PDP. 79. A PDP as claimed in any of claims 66 to 78; And A PDP display device comprising an activation circuit for activating a PDP. The PDP of claim 80; And A PDP display device comprising an activation circuit for activating a PDP.