KR102472476B1 - 실리카를 포함하는 천연 고무 배합물 및 타이어에 대한 용도 - Google Patents

실리카를 포함하는 천연 고무 배합물 및 타이어에 대한 용도 Download PDF

Info

Publication number
KR102472476B1
KR102472476B1 KR1020177022644A KR20177022644A KR102472476B1 KR 102472476 B1 KR102472476 B1 KR 102472476B1 KR 1020177022644 A KR1020177022644 A KR 1020177022644A KR 20177022644 A KR20177022644 A KR 20177022644A KR 102472476 B1 KR102472476 B1 KR 102472476B1
Authority
KR
South Korea
Prior art keywords
rubber
silica
delete delete
phr
guayul
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020177022644A
Other languages
English (en)
Korean (ko)
Other versions
KR20170103954A (ko
Inventor
하워드 에이. 콜빈
Original Assignee
쿠퍼 타이어 앤드 러버 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 쿠퍼 타이어 앤드 러버 캄파니 filed Critical 쿠퍼 타이어 앤드 러버 캄파니
Publication of KR20170103954A publication Critical patent/KR20170103954A/ko
Application granted granted Critical
Publication of KR102472476B1 publication Critical patent/KR102472476B1/ko
Assigned to 더 굿이어 타이어 앤드 러버 캄파니 reassignment 더 굿이어 타이어 앤드 러버 캄파니 권리의 전부이전등록 Assignors: 쿠퍼 타이어 앤드 러버 캄파니
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/25—Incorporating silicon atoms into the molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016—Compositions of the tread
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0025—Compositions of the sidewalls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C4/00—Treatment of rubber before vulcanisation, not provided for in groups C08C1/00 - C08C3/02
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1515—Three-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/548—Silicon-containing compounds containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06—Copolymers with styrene
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
    • C12N9/88—Lyases (4.)
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12Y—ENZYMES
    • C12Y402/00—Carbon-oxygen lyases (4.2)
    • C12Y402/01—Hydro-lyases (4.2.1)
    • C12Y402/01092—Hydroperoxide dehydratase (4.2.1.92)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C2001/005—Compositions of the bead portions, e.g. clinch or chafer rubber or cushion rubber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C2001/005—Compositions of the bead portions, e.g. clinch or chafer rubber or cushion rubber
    • B60C2001/0058—Compositions of the bead apexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C2200/00—Tyres specially adapted for particular applications
    • B60C2200/02—Tyres specially adapted for particular applications for aircrafts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/006—Additives being defined by their surface area
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Genetics & Genomics (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Biochemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Tires In General (AREA)
  • Molecular Biology (AREA)
  • Biomedical Technology (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
KR1020177022644A 2015-01-12 2016-01-12 실리카를 포함하는 천연 고무 배합물 및 타이어에 대한 용도 Active KR102472476B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562102211P 2015-01-12 2015-01-12
US62/102,211 2015-01-12
PCT/US2016/013043 WO2016115132A1 (en) 2015-01-12 2016-01-12 Natural rubber compounds with silica and use with tires

Publications (2)

Publication Number Publication Date
KR20170103954A KR20170103954A (ko) 2017-09-13
KR102472476B1 true KR102472476B1 (ko) 2022-11-29

Family

ID=56406291

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020177022644A Active KR102472476B1 (ko) 2015-01-12 2016-01-12 실리카를 포함하는 천연 고무 배합물 및 타이어에 대한 용도

Country Status (9)

Country Link
US (1) US10538600B2 (https=)
EP (1) EP3245250A4 (https=)
JP (1) JP6842426B2 (https=)
KR (1) KR102472476B1 (https=)
CN (1) CN107108957A (https=)
BR (1) BR112017014870B1 (https=)
CA (1) CA2972933C (https=)
MX (1) MX389436B (https=)
WO (1) WO2016115132A1 (https=)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT201600131325A1 (it) * 2016-12-27 2018-06-27 Pirelli Composizioni elastomeriche comprendenti gomme naturali da Guayule per componenti di pneumatici e pneumatici che le comprendono
US12514310B2 (en) 2017-01-24 2026-01-06 Smarterials Technology Gmbh Damage-resistant gloves with breach-indicator function
EP3573807B1 (en) 2017-01-24 2024-10-02 Smarterials Technology GmbH Damage-resistant gloves with breach-indicator function
MX2019009455A (es) * 2017-02-13 2019-11-05 Cooper Tire & Rubber Co Compuesto de banda de rodadura de neumaticos.
CA3052476A1 (en) * 2017-02-13 2018-08-16 Cooper Tire & Rubber Company Guayule tire tread compound
JP7243036B2 (ja) * 2018-04-24 2023-03-22 横浜ゴム株式会社 空気入りタイヤ
JP2021523261A (ja) 2018-05-04 2021-09-02 ブリヂストン アメリカズ タイヤ オペレーションズ、 エルエルシー タイヤトレッドゴム組成物
EP3781625A4 (en) 2018-05-04 2022-01-05 Bridgestone Americas Tire Operations, LLC RUBBER COMPOSITION FOR TIRE TREAD
US20210237510A1 (en) * 2018-05-04 2021-08-05 Bridgestone Americas Tire Operations, Llc Tire Tread Rubber Composition
JP2021523959A (ja) 2018-05-04 2021-09-09 ブリヂストン アメリカズ タイヤ オペレーションズ、 エルエルシー タイヤトレッドゴム組成物
EP3788101A4 (en) 2018-05-04 2022-01-12 Bridgestone Americas Tire Operations, LLC RUBBER COMPOSITION FOR TIRE TREAD
US12325797B2 (en) 2019-05-29 2025-06-10 Bridgestone Americas Tire Operations, Llc Tire tread rubber composition and related methods
WO2020243311A1 (en) 2019-05-29 2020-12-03 Bridgestone Americas Tire Operations, Llc Tire tread rubber composition and related methods
EP3976709A1 (en) 2019-05-29 2022-04-06 Bridgestone Americas Tire Operations, LLC Tire tread rubber composition and related methods
DE102019213148A1 (de) * 2019-08-30 2021-03-04 Continental Reifen Deutschland Gmbh Kautschukmischung für Zweiradreifenlaufstreifen
CN112608531B (zh) 2019-10-06 2025-01-28 希尔帕拉科技有限责任公司 功能性二氧化硅与天然橡胶的分子复合材料
JP7568861B2 (ja) * 2020-12-18 2024-10-16 株式会社ブリヂストン バガス含有グアユールゴムとシランとを組み合わせたゴム組成物及び関連する方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130253088A1 (en) 2012-03-06 2013-09-26 Bridgestone Corporation Cured guayule rubber containing compositions and method for preparing same
CN103772760A (zh) 2014-01-23 2014-05-07 怡维怡橡胶研究院有限公司 一种以天然橡胶/炭黑、合成聚异戊二烯橡胶/白炭黑为母胶的橡胶组合物及其加工工艺

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1004558B (it) 1972-08-31 1976-07-20 Ppg Industries Inc Agente copulante silanato per gomma
US3814160A (en) 1972-09-18 1974-06-04 Ppg Industries Inc Tread wear indicator
US4621118A (en) * 1985-03-21 1986-11-04 The Firestone Tire & Rubber Company Sulfurized guayule resin and rubber
JP4679312B2 (ja) * 2002-03-28 2011-04-27 株式会社ブリヂストン 天然ゴム、ゴム組成物及び空気入りタイヤ
AU2003246733A1 (en) 2002-08-03 2004-02-25 Degussa Ag Highly dispersible precipitated silica having a high surface area
US7259231B2 (en) 2004-10-12 2007-08-21 Yulex Corporation Extraction and fractionation of biopolymers and resins from plant materials
US7923039B2 (en) 2005-01-05 2011-04-12 Yulex Corporation Biopolymer extraction from plant materials
US7594528B2 (en) 2007-03-08 2009-09-29 The Goodyear Tire & Rubber Company Tire with sidewall comprised of emulsion styrene/butadiene rubber, cis 1,4-polyisoprene rubber and cis 1,4-polybutadiene rubber
MX2010013220A (es) 2008-07-24 2011-03-29 Ind Negromex S A De C V Procedimientos para elaborar silano, silice hidrofobizado, lote maestro de silice y productos de caucho.
JP5570153B2 (ja) * 2009-07-22 2014-08-13 株式会社ブリヂストン タイヤ
JP5545102B2 (ja) * 2010-07-30 2014-07-09 戸田工業株式会社 疎水性シリカ粒子粉末及びその製造法並びに該疎水性シリカ粒子粉末を用いたゴム組成物
US20130203940A1 (en) 2012-02-02 2013-08-08 Lion Copolymer, Llc Preparation of styrene butadiene rubber masterbatch using polyamide and an epoxidized silica
US9574055B2 (en) 2012-02-02 2017-02-21 Lion Copolymer Holdings, Llc Compatibilized silica with a plurality of silanes and a polymer silica-reinforced masterbatch
AU2013262725B2 (en) * 2012-05-16 2016-10-06 Bridgestone Corporation Compositions containing purified non-Hevea rubber and related purification methods
US8962759B2 (en) * 2013-05-30 2015-02-24 The Goodyear Tire & Rubber Company Functionalized elastomer
US9833037B2 (en) * 2013-11-11 2017-12-05 Nike, Inc. Natural rubber outsoles and footwear
US20150159001A1 (en) * 2013-12-05 2015-06-11 The Goodyear Tire & Rubber Company Rubber composition and pneumatic tire

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130253088A1 (en) 2012-03-06 2013-09-26 Bridgestone Corporation Cured guayule rubber containing compositions and method for preparing same
CN103772760A (zh) 2014-01-23 2014-05-07 怡维怡橡胶研究院有限公司 一种以天然橡胶/炭黑、合成聚异戊二烯橡胶/白炭黑为母胶的橡胶组合物及其加工工艺

Also Published As

Publication number Publication date
CN107108957A (zh) 2017-08-29
MX2017009165A (es) 2017-10-16
EP3245250A4 (en) 2018-07-25
KR20170103954A (ko) 2017-09-13
CA2972933C (en) 2023-03-14
EP3245250A1 (en) 2017-11-22
US10538600B2 (en) 2020-01-21
US20180265601A1 (en) 2018-09-20
BR112017014870B1 (pt) 2022-09-27
JP2018502980A (ja) 2018-02-01
BR112017014870A2 (pt) 2018-03-13
JP6842426B2 (ja) 2021-03-17
WO2016115132A1 (en) 2016-07-21
MX389436B (es) 2025-03-20
CA2972933A1 (en) 2016-07-21

Similar Documents

Publication Publication Date Title
KR102472476B1 (ko) 실리카를 포함하는 천연 고무 배합물 및 타이어에 대한 용도
US10273351B2 (en) Rubber mixture and vehicle tires
CN105579247B (zh) 硫可交联的橡胶共混物以及车辆轮胎
CN109562644B (zh) 硫可交联橡胶混合物以及车辆轮胎
CN109562642B (zh) 硫可交联橡胶混合物和车辆轮胎
CN105579513B (zh) 硫可交联的橡胶混合物以及机动车辆轮胎
CN109563181B (zh) 橡胶共混物、硫可交联橡胶混合物和车辆轮胎
EP3959086B1 (en) A rubber composition
CN109563182B (zh) 橡胶共混物、硫可交联的橡胶混合物以及车辆轮胎
JP2012117060A (ja) カルボキシル化スチレン／ブタジエンゴム含有トレッドを有するタイヤ
CN109562643B (zh) 硫可交联橡胶混合物以及车辆轮胎
CN111491998B (zh) 硫可交联的橡胶混合物、橡胶混合物的硫化橡胶和车辆轮胎
CN109641976B (zh) 硫可交联橡胶混合物以及车辆轮胎
US20220220288A1 (en) A rubber composition
EP4214279B1 (de) Vernetzungsfähige kautschukmischung und fahrzeugluftreifen

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

P22-X000 Classification modified

St.27 status event code: A-2-2-P10-P22-nap-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

PN2301 Change of applicant

St.27 status event code: A-5-5-R10-R11-asn-PN2301

PN2301 Change of applicant

St.27 status event code: A-5-5-R10-R14-asn-PN2301

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-OTH-PR1001 (AS PROVIDED BY THE NATIONAL OFFICE)

Year of fee payment: 4