KR102426439B1 - Method of manufacturing multi-layer textile using polylactide sea/island type composite yarn with stereo-complex crystal structure and high heat-resisting property - Google Patents
Method of manufacturing multi-layer textile using polylactide sea/island type composite yarn with stereo-complex crystal structure and high heat-resisting property Download PDFInfo
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D11/00—Double or multi-ply fabrics not otherwise provided for
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
- D01D10/02—Heat treatment
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/34—Core-skin structure; Spinnerette packs therefor
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/06—Load-responsive characteristics
- D10B2401/063—Load-responsive characteristics high strength
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/12—Physical properties biodegradable
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/14—Dyeability
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
- D10B2501/04—Outerwear; Protective garments
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2505/00—Industrial
- D10B2505/10—Packaging, e.g. bags
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2505/00—Industrial
- D10B2505/18—Outdoor fabrics, e.g. tents, tarpaulins
Abstract
본 발명은 폴리-L-락틱 애시드(PLLA)와 폴리-DL-락틱 애시드(PDLA)를 해도형 복합섬유 방사용 구금을 통해 복합방사하여 스트레오-컴플렉스(Stereo-complex) 결정 구조를 갖는 고내열성 폴리락타이드 해도형 복합섬유를 제조한 후, 이를 경사 및/또는 위사로 사용하여 다중직 텍스타일을 제직한 후, 다단 콜드 패드 배치에서 순차적으로 정련, 염색 및 숙성하여 친환경적 이면서도 내열성이 특히 우수한 다중직 텍스타일을 제조한다.
본 발명으로 제조된 다중직 텍스타일은 고내열성 폴리락타이드 섬유로 제조되어 생분해성이 뛰어나 친환경적임과 동시에 내열성 등의 기계적 물성이 우수하다.
또한, 본 발명으로 제조된 다중직 텍스타일은 공기투과도가 낮아 다운자켓제조용 원단 등으로 사용시 다운 충진제가 빠져나오는 현상을 효과적으로 방지할 수 있고, 강력 및 내구성이 뛰어나고, 양호한 보온성, 터치감 및 심색성 및 염색내구성을 구현할 수 있다.
그로 인해, 본 발명으로 제조된 복합 기능성 다중직 텍스타일은 다운자켓, 텐트, 침낭 및 백팩(가방) 제조용 텍스타일로 유용하다.The present invention is a high heat-resistant poly having a stereo-complex crystal structure by compound spinning poly-L-lactic acid (PLLA) and poly-DL-lactic acid (PDLA) through a sea-island type composite fiber spinning spinneret. After manufacturing the lactide sea-island type composite fiber, using it as warp and/or weft yarns to weave a multi-woven textile, it is sequentially scoured, dyed and aged in a multi-stage cold pad batch to make a multi-woven textile that is environmentally friendly and has particularly excellent heat resistance. to manufacture
The multi-woven textile produced by the present invention is made of high heat-resistant polylactide fiber, so it has excellent biodegradability, is environmentally friendly, and has excellent mechanical properties such as heat resistance.
In addition, the multi-woven textile manufactured by the present invention has low air permeability and can effectively prevent the down filler from escaping when used as a fabric for down jacket manufacturing, has excellent strength and durability, good heat retention, touch and deep color, and Dyeing durability can be realized.
Therefore, the composite functional multi-woven textile manufactured by the present invention is useful as a textile for manufacturing down jackets, tents, sleeping bags and backpacks (bags).
Description
본 발명은 스트레오-컴플렉스(Stereo-complex) 결정 구조를 갖는 고내열성 폴리락타이드(이하 "SC-PLA" 라고 한다)로 구성된 해도형 복합섬유(이하 "SC-PLA 해도형 복합섬유" 라고 한다)를 이용하여 생분해성으로 친환경적임과 동시에 내열성이 우수하고 공기투과도가 낮고, 강력, 내구성, 보온성 및 터치감 등이 양호한 다중직 텍스타일의 제조방법에 관한 것이다.The present invention relates to a sea-island type composite fiber (hereinafter referred to as "SC-PLA sea-island type composite fiber") composed of high heat-resistant polylactide (hereinafter referred to as "SC-PLA") having a stereo-complex crystal structure. It relates to a method of manufacturing a multi-woven textile that is biodegradable, eco-friendly, has excellent heat resistance, low air permeability, and has good strength, durability, warmth and touch.
다운자켓, 텐트, 침낭 및 가방(백팩) 제조용 원단의 경우에는 다운 충진제가 밖으로 빠져나오는 것을 효과적으로 방지할 수 있는 고밀도와 함께 우수한 강력 및 내구성과 양호한 보온성, 터치감 및 심색성이 동시에 요구되고 있다.In the case of down jackets, tents, sleeping bags, and bags (backpacks) manufacturing, high density that can effectively prevent down fillers from leaking out, as well as excellent strength and durability, good heat retention, touch and deep color are required at the same time.
다운자켓을 제조하는 종래기술로서, 대한민국 등록특허 제10-0915959호에서는 겉감과 안감 사이에 다운이 투입된 부분판들을 연결하여 다운자켓을 제조할 때, 부분판을 형성하는 겉감과 안감 사이에 고밀도 원단 테이프를 위치시킨 후 상기 겉감과 안감을 함께 봉제하여 다운 격실을 형성하는 방법을 게재하고 있으나, 상기 종래기술은 다운 충진제가 외부로 빠져나오는 것을 방지하기 위한 제조공정이 복잡한 문제가 있었다.As a prior art for manufacturing a down jacket, Korean Patent Registration No. 10-0915959 discloses a high-density fabric between the outer and lining forming a partial plate when manufacturing a down jacket by connecting partial plates to which down is inserted between the outer and lining. Although a method of forming a down compartment by sewing together the outer and inner linings after positioning the tape is disclosed, the prior art has a complicated manufacturing process for preventing the down filler from escaping to the outside.
다운자켓을 제조하는 또 다른 종래기술로서, 대한민국 공개특허 제10-2012-0032528호에서는 직물 상에 수지가 01~5g/㎡의 도포량으로 코팅되어 있는 박막코팅 직물을 사용하여 다운 충진제가 외부로 빠져나오는 것을 방지하는 방법이 게재되어 있으나, 상기 종래기술은 코팅원단 사용으로 터치감이 저하되는 문제가 있었다.As another prior art for manufacturing a down jacket, in Korean Patent Application Laid-Open No. 10-2012-0032528, a thin-film coated fabric in which a resin is coated on the fabric at an application amount of 01 to 5 g/
한편, 이중직 원단에 대한 종래기술로서, 대한민국 등록특허 제10-0317115호에서는 경사 및 위사가 폴리에스터 멀티필라멘트 표리 양면 지조직과 비스코스 인견 멀티필라멘트의 파일로 구성되어 번 아웃트 벨벳과 같은 효과를 갖는 파일 이중직의 편물을 하고 있고, 대한민국 등록특허 제10-1566634호에서는 온도 적응성이 우수한 이중직 환편물을 게재하고 있으나, 상기의 이중직 편물 또는 이중직 환편물은 밀도가 낮아 다운 자켓 제조용 직물로 사용시 다운 충진제가 외부로 쉽게 빠져 나가는 문제와 강도 및 내구성이 떨어지고, 터치감 및 심색성도 불량한 문제가 있었다.On the other hand, as a prior art for a double weave fabric, in Korean Patent Registration No. 10-0317115, the warp and weft yarns are composed of polyester multifilament front and back both sides paper tissue and viscose pull multifilament pile, which has the same effect as burnout velvet. A pile double weave is knitted, and Korean Patent No. 10-1566634 discloses a double weave circular knitted fabric with excellent temperature adaptability, but the double weave knitted or double weave circular knitted fabric has a low density, so when used as a fabric for manufacturing down jackets, down filler is There was a problem of easily escaping to the outside, poor strength and durability, and poor touch and deep color.
한편, 대한민국 등록특허 제10-2053234호에서는 다단연신된 가염성 폴리에스테르 멀티필라멘트를 경사 및/또는 위사로 사용하여 다중직 텍스타일을 제조하는 방법을 게재하고 있으나, 상기 방법으로 제조한 다중직 텍스타일은 기존의 종래 다중직 텍스타일들과 같이 생분해되지 않아 친환경적이지 못한 문제가 있었다.On the other hand, Korean Patent Registration No. 10-2053234 discloses a method of manufacturing a multi-woven textile using multi-stage stretched dyeable polyester multifilaments as warp and/or weft yarns, but the multi-woven textile manufactured by the method is There was a problem that it was not eco-friendly because it was not biodegradable like the conventional multi-woven textiles.
한편, 생분해성인 통상의 폴리락타이드 원사로 다중 텍스타일을 제조하는 방법도 일부 시도되어 왔으나, 통상의 폴리락타이드 원사의 용융온도가 낮기 때문에 제조된 다중 텍스타일의 내열성이 크게 저하되는 문제가 있었다.On the other hand, some methods for producing multi-textiles from biodegradable conventional polylactide yarns have been tried, but there is a problem in that the heat resistance of the multi-textiles produced is greatly reduced because the melting temperature of the conventional polylactide yarns is low.
본 발명의 과제는 생분해성을 구비하여 친환경적임과 동시에 내열성도 우수하고, 공기투과도가 낮아 다운자켓 제조용 원단 등으로 사용시 다운 충진제가 빠져나오는 현상을 효과적으로 방지할 수 있고, 양호한 보온성, 터치감, 강력 및 내구성을 구현할 수 있는 다중직 텍스타일을 제조하는 방법을 제공하는 것이다.The object of the present invention is to have biodegradability, so it is environmentally friendly and has excellent heat resistance, and its low air permeability can effectively prevent the down filler from leaking out when used as a fabric for down jacket manufacturing. And to provide a method of manufacturing a multi-woven textile that can implement durability.
이와 같은 과제를 해결하기 위해서, 본 발명에서는 폴리-L-락틱 애시드(PLLA)와 폴리-DL-락틱 애시드(PDLA)를 해도형 복합섬유 방사용 구금을 통해 복합방사하여 스트레오-컴플렉스(Stereo-complex) 결정 구조를 갖는 고내열성 폴리락타이드 해도형 복합섬유를 제조한 후, 이를 경사 및/또는 위사로 사용하여 다중직 텍스타일을 제직한 후, 다단 콜드 패드 배치에서 순차적으로 정련, 염색 및 숙성하여 친환경적 이면서도 내열성이 특히 우수한 다중직 텍스타일을 제조한다.In order to solve the above problems, in the present invention, poly-L-lactic acid (PLLA) and poly-DL-lactic acid (PDLA) are compound-spun through a sea-island-type composite fiber spinning spinneret, and stereo-complex (Stereo-complex) ) After manufacturing high heat-resistant polylactide sea-island composite fiber having a crystal structure, weaving a multi-woven textile using warp and/or weft yarns, and sequentially scouring, dyeing and maturing in a multi-stage cold pad arrangement, so as to be environmentally friendly It produces a multi-woven textile with particularly excellent heat resistance.
본 발명으로 제조된 다중직 텍스타일은 고내열성 폴리락타이드 섬유로 제조되어 생분해성이 뛰어나 친환경적임과 동시에 내열성 등의 기계적 물성이 우수하다.The multi-woven textile produced by the present invention is made of high heat-resistant polylactide fiber, so it has excellent biodegradability, is environmentally friendly, and has excellent mechanical properties such as heat resistance.
또한, 본 발명으로 제조된 다중직 텍스타일은 공기투과도가 낮아 다운자켓제조용 원단 등으로 사용시 다운 충진제가 빠져나오는 현상을 효과적으로 방지할 수 있고, 강력 및 내구성이 뛰어나고, 양호한 보온성, 터치감 및 심색성 및 염색내구성을 구현할 수 있다.In addition, the multi-woven textile manufactured by the present invention has low air permeability and can effectively prevent the down filler from leaking out when used as a fabric for manufacturing a down jacket, has excellent strength and durability, good heat retention, touch and deep color and Dyeing durability can be realized.
그로 인해, 본 발명으로 제조된 복합 기능성 다중직 텍스타일은 다운자켓, 텐트, 침낭 및 백팩(가방) 제조용 텍스타일로 유용하다.Therefore, the composite functional multi-woven textile manufactured by the present invention is useful as a textile for manufacturing down jackets, tents, sleeping bags and backpacks (bags).
도 1은 이중직 직물의 단면 구조를 나타내는 모식도.
도 2는 삼중직 직물의 단면 구조를 나타내는 모식도.
도 3은 본 발명에 사용되는 해도형 복합섬유 방사용 구금의 저면도.1 is a schematic view showing the cross-sectional structure of a double weave fabric.
2 is a schematic diagram showing the cross-sectional structure of a triple woven fabric.
Figure 3 is a bottom view of the sea-island-type composite fiber spinning spinneret used in the present invention.
이하, 첨부한 도면 등을 통하여 본 발명을 상세하게 설명한다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.
본 발명은 (ⅰ) 폴리-L-락틱 애시드(Poly-L-lactic acid : PLLA) 및 폴리-DL-락틱 애시드(Poly-DL-lactic acid : PDLA)중에서 선택된 1종의 폴리머를 해도형 복합섬유 방사용 구금의 도성분 형성부(1)에 공급하고, 나머지 1종의 폴리머를 해도형 복합섬유 방사용 구금의 해성분 형성부(2)에 공급하여 상기 폴리-L-락틱 애시드(PLLA)와 폴리-DL-락틱 애시드(PDLA)를 서로 분리된 상태로 열처리하면서 복합방사하여 스트레오-컴플렉스(Stereo-complex) 결정 구조를 갖는 고내열성 폴리락타이드 해도형 복합섬유를 제조하는 공정; (ⅱ) 상기 스트레오-컴플렉스(Stereo-complex) 결정 구조를 갖는 고내열성 폴리락타이드 해도형 복합섬유를 경사 및 위사의 전부 또는 일부로 사용하여 다중직 텍스타일을 제직하는 공정; 및 (ⅲ) 제직된 다중직 텍스타일을 다단 콜드 패드 배치(Cold pad bath)에서 순차적으로 연속해서 정련, 염색 및 숙성하는 공정;을 포함한다.(i) Poly-L-lactic acid (PLLA) and poly-DL-lactic acid (PDLA) of one type of polymer selected from the group consisting of a sea-island composite fiber The poly-L-lactic acid (PLLA) and A process of manufacturing high heat-resistant polylactide sea-island composite fibers having a stereo-complex crystal structure by compound spinning poly-DL-lactic acid (PDLA) while heat-treating them in a separated state; (ii) a step of weaving a multi-woven textile using the high heat-resistant polylactide sea-island composite fiber having the stereo-complex crystal structure as all or part of warp and weft yarns; and (iii) a process of sequentially and continuously scouring, dyeing and aging the woven multi-woven textile in a multi-stage cold pad bath.
구체적으로, 본 발명은 먼저 (ⅰ) 폴리-L-락틱 애시드(Poly-L-lactic acid : PLLA) 및 폴리-DL-락틱 애시드(Poly-DL-lactic acid : PDLA)중에서 선택된 1종의 폴리머를 해도형 복합섬유 방사용 구금의 도성분 형성부(1)에 공급하고, 나머지 1종의 폴리머를 해도형 복합섬유 방사용 구금의 해성분 형성부(2)에 공급하여 상기 폴리-L-락틱 애시드(PLLA)와 폴리-DL-락틱 애시드(PDLA)를 서로 분리된 상태로 열처리하면서 복합방사하여 스트레오-컴플렉스(Stereo-complex) 결정 구조를 갖는 고내열성 폴리락타이드 해도형 복합섬유를 제조한다.Specifically, the present invention provides first (i) one polymer selected from poly-L-lactic acid (PLLA) and poly-DL-lactic acid (PDLA). The poly-L-lactic acid is supplied to the island component forming unit (1) of the spinneret for spinning a sea-island type composite fiber, and the remaining one type of polymer is supplied to the sea component forming unit (2) of the spinneret for spinning a sea-island type composite fiber. (PLLA) and poly-DL-lactic acid (PDLA) are heat-treated while separated from each other and composite spinning to prepare a high heat-resistant polylactide sea-island composite fiber having a stereo-complex crystal structure.
이때, 상기 고내열성 폴리락타이드 해도형 복합섬유를 구성하는 폴리-L-락틱 애시드(PLLA) 분자와 폴리-DL-락틱 애시드(PDLA) 분자간의 거리가 폴리-L-락틱 애시드(PLLA)의 결정 사이즈 및 폴리-DL-락틱 애시드(PDLA)의 결정 사이즈 보다 작게 조절해 준다.At this time, the distance between the poly-L-lactic acid (PLLA) molecules and the poly-DL-lactic acid (PDLA) molecules constituting the high heat-resistant polylactide sea-island composite fiber is determined by determining the poly-L-lactic acid (PLLA). It adjusts the size and the crystal size of poly-DL-lactic acid (PDLA) smaller than the crystal size.
다음으로는, 상기 스트레오-컴플렉스(Stereo-complex) 결정 구조를 갖는 고내열성 폴리락타이드 해도형 복합섬유를 경사 및 위사의 전부 또는 일부로 사용하여 다중직 텍스타일을 제직한다.Next, the stereo-complex (Stereo-complex) high heat-resistant polylactide sea-island type composite fiber having a crystal structure is used as all or part of warp and weft yarns to weave a multi-woven textile.
본 발명에서는 다중직 텍스타일 제직공정 이전에 상기 고내열성 폴리락티드 해도형 복합섬유(SC-PLA 해도형 복합섬유)를 인터레이싱 방법, 에어텍스츄어링 방법, 드로우 텍스츄어링 방법 또는 가연(False Twisting) 방법 등으로 사가공하는 공정을 추가로 포함할 수도 있다.In the present invention, an interlacing method, an air texturing method, a draw texturing method, or a false twisting method of the high heat-resistant polylactide sea-island composite fiber (SC-PLA sea-island composite fiber) before the multi-woven textile weaving process It may further include a process of sand processing, etc.
상기 다중직 텍스타일은 도 1에 도시된 이중직 직물일 수도 있고, 도 2에 도시된 삼중직 직물일 수도 있다.The multi-woven textile may be the double-woven fabric shown in FIG. 1 or the triple-woven fabric shown in FIG. 2 .
다중직 텍스타일 제직시 직밀도를 250~500T로 조절하는 것이 다운 충진제가 외부로 빠져나가는 것을 효과적으로 방지하는데 바람직하다.When weaving multi-woven textiles, it is preferable to adjust the weaving density to 250 to 500T to effectively prevent the down filler from escaping to the outside.
다중직 텍스타일을 제직시 사용되는 원사의 일부로, 경사 및/또는 위사의 일부로, 천연섬유 또는 재생섬유를 사용할 수도 있다.It is also possible to use natural fibers or regenerated fibers as part of the yarns used in weaving the multi-woven textile, warp and/or weft yarns.
다음으로는, 제직된 다중직 텍스타일을 다단 콜드 패드 배치(Cold pad bath)에서 순차적으로 연속해서 정련, 염색 및 숙성하여 다중직 텍스타일을 제조한다.Next, the woven multi-woven textile is sequentially and continuously scoured, dyed and aged in a multi-stage cold pad bath to prepare a multi-woven textile.
상기 염색 공정 중에 염료 침투성을 촉진하는 전처리 약제를 첨가해 주는 것이 심색성을 개선하는데 바람직하다.It is preferable to add a pretreatment agent that promotes dye permeability during the dyeing process to improve deep color properties.
본 발명으로 제조된 다중직 텍스타일은 고내열성 폴리락타이드 섬유로 제조되어 생분해성이 뛰어나 친환경적 이면서도 내열성 등의 기계적 물성이 우수하다.The multi-woven textile manufactured by the present invention is made of high heat-resistant polylactide fiber, so it has excellent biodegradability and is environmentally friendly and has excellent mechanical properties such as heat resistance.
또한, 본 발명으로 제조된 다중직 텍스타일은 공기투과도가 낮아 다운자켓제조용 원단 등으로 사용시 다운 충진제가 빠져나오는 현상을 효과적으로 방지할 수 있고, 강력 및 내구성이 뛰어나고, 양호한 보온성, 터치감 및 심색성 및 염색내구성을 구현할 수 있다.In addition, the multi-woven textile manufactured by the present invention has low air permeability and can effectively prevent the down filler from leaking out when used as a fabric for manufacturing a down jacket, has excellent strength and durability, good heat retention, touch and deep color and Dyeing durability can be realized.
그로 인해, 본 발명으로 제조된 복합 기능성 다중직 텍스타일은 다운자켓, 텐트, 침낭 및 백팩(가방) 제조용 텍스타일로 유용하다.Therefore, the composite functional multi-woven textile manufactured by the present invention is useful as a textile for manufacturing down jackets, tents, sleeping bags and backpacks (bags).
이하, 실시예 및 비교실시예를 통하여 본 발명을 보다 구체적으로 살펴본다.Hereinafter, the present invention will be described in more detail through Examples and Comparative Examples.
그러나 본 발명의 보호범위는 하기 실시예만으로 한정되는 것으로 해석되어서는 안된다.However, the protection scope of the present invention should not be construed as being limited only to the following examples.
실시예 1Example 1
폴리-L-락틱 애시드(Poly-L-lactic acid : PLLA) 및 폴리-DL-락틱 애시드(Poly-DL-lactic acid : PDLA)중에서 선택된 1종의 폴리머를 해도형 복합섬유 방사용 구금의 도성분 형성부(1)에 공급하고, 나머지 1종의 폴리머를 해도형 복합섬유 방사용 구금의 해성분 형성부(2)에 공급하여 상기 폴리-L-락틱 애시드(PLLA)와 폴리-DL-락틱 애시드(PDLA)를 서로 분리된 상태로 열처리하면서 복합방사하여 섬도가 75데니어이며 스트레오-컴플렉스(Stereo-complex) 결정 구조를 갖는 고내열성 폴리락타이드 해도형 복합섬유(SC-PLA 해도형 복합섬유)를 제조하였다.One kind of polymer selected from poly-L-lactic acid (PLLA) and poly-DL-lactic acid (PDLA) is used as an island component of the sea-island type composite fiber spinneret. The poly-L-lactic acid (PLLA) and poly-DL-lactic acid are supplied to the forming unit (1), and the remaining one type of polymer is supplied to the sea component forming unit (2) of the spinneret for sea-island composite fiber spinning. High heat-resistant polylactide sea-island composite fiber (SC-PLA sea-island composite fiber) with a fineness of 75 denier and a stereo-complex crystal structure is produced prepared.
이때, 상기 고내열성 폴리락타이드 해도형 복합섬유를 구성하는 폴리-L-락틱 애시드(PLLA) 분자와 폴리-DL-락틱 애시드(PDLA) 분자간의 거리가 폴리-L-락틱 애시드(PLLA)의 결정 사이즈 및 폴리-DL-락틱 애시드(PDLA)의 결정 사이즈 보다 작게 조절하였다.At this time, the distance between the poly-L-lactic acid (PLLA) molecules and the poly-DL-lactic acid (PDLA) molecules constituting the high heat-resistant polylactide sea-island composite fiber is determined by determining the poly-L-lactic acid (PLLA). It was adjusted to be smaller than the size and crystal size of poly-DL-lactic acid (PDLA).
다음으로, 상기의 SC-PLA 해도형 복합섬유를 경사 및 위사의 전부로 사용하여 밀도가 350T이고 단위면적당 중량이 40g/㎡인 이중직 직물을 제조하였다.Next, a double weave fabric having a density of 350T and a weight per unit area of 40 g/
다음으로, 상기 이중직 직물을 다단 콜드 패드 배치(Cold Pad Bath)에서 순차적으로 연속해서 정련(열처리), 염색 및 숙성하여 이중직 염색직물(텍스타일)을 제조하였다.Next, the double weave fabric was sequentially and continuously scoured (heat treatment), dyed and aged in a multi-stage cold pad batch to prepare a double weave dyed fabric (textile).
상기와 같이 제조된 이중직 염색직물의 각종물성을 평가한 결과는 표 1과 같았다.The results of evaluating various physical properties of the double weave dyed fabric prepared as described above are shown in Table 1.
비교실시예 1Comparative Example 1
동일한 양의 L-락타이드와 D-락타이드가 공중합 되어 저 결정성의 랜덤 코폴리머인 라세미-폴리락틱애시드로 75데니어의 폴리락타이드 원사를 제조하였다.The same amount of L-lactide and D-lactide was copolymerized to prepare a 75 denier polylactide yarn with racemic-polylactic acid, a random copolymer of low crystallinity.
다음으로, 상기 폴리락타이드 원사를 경사 및 위사의 전부로 사용하여 밀도가 350T이고 단위면적당 중량이 40g/㎡인 이중직 직물을 제조하였다.Next, a double weave fabric having a density of 350T and a weight per unit area of 40 g/
다음으로, 상기 이중직 직물을 다단 콜드 패드 배치(Cold Pad Bath)에서 순차적으로 연속해서 정련(열처리), 염색 및 숙성하여 이중직 염색직물(텍스타일)을 제조하였다.Next, the double weave fabric was sequentially and continuously scoured (heat treatment), dyed and aged in a multi-stage cold pad batch to prepare a double weave dyed fabric (textile).
상기와 같이 제조된 이중직 염색직물의 각종물성을 평가한 결과는 표 1과 같았다.The results of evaluating various physical properties of the double weave dyed fabric prepared as described above are shown in Table 1.
(㎤/㎠/sec)air permeability
(㎤/㎠/sec)
표 1의 인열강도는 ASTM D 2261 방법으로 평가하였고, 세탁견뢰도는 AATCC 61 방법으로 평가하였고, 땀견뢰도는 AATCC 15 방법으로 평가하였고, 공기투과도는 KSK ISO 9237 방법으로 평가하였고, 마모강도 KS K ISO 12947-2 방법으로 평가하였고, 보온성은 다운 충진재 150g 충전 후에 KSK 0560 항온법(A법)으로 평가하였고, Melting point는 시차주사 열량분석(DSC)을 이용하여 평가하였다.The tear strength in Table 1 was evaluated by the ASTM D 2261 method, the washing fastness was evaluated by the AATCC 61 method, the sweat fastness was evaluated by the AATCC 15 method, the air permeability was evaluated by the KSK ISO 9237 method, and the abrasion strength was KS K It was evaluated by the ISO 12947-2 method, the thermal insulation was evaluated by the KSK 0560 constant temperature method (method A) after filling 150 g of the down filler, and the melting point was evaluated using differential scanning calorimetry (DSC).
1 : 해도형 복합섬유 방사용 구금 중 도성분 형성부
2 : 해도형 복합섬유 방사용 구금 중 해성분 형성부1: Island component forming part during detention for sea-island type composite fiber spinning
2: Sea component forming part in the detention for sea-island type composite fiber spinning
Claims (3)
(ⅱ) 상기 스트레오-컴플렉스(Stereo-complex) 결정 구조를 갖는 고내열성 폴리락타이드 해도형 복합섬유를 경사 및 위사의 전부 또는 일부로 사용하여 다중직 텍스타일을 제직하는 공정; 및
(ⅲ) 제직된 다중직 텍스타일을 다단 콜드 패드 배치(Cold pad bath)에서 순차적으로 연속해서 정련, 염색 및 숙성하는 공정;을 포함하는 것을 특징으로 하는 스트레오-컴플렉스(Stereo-complex) 결정 구조를 갖는 고내열성 폴리락타이드 해도형 복합섬유를 이용한 다중직 텍스타일의 제조방법.(i) One polymer selected from poly-L-lactic acid (PLLA) and poly-DL-lactic acid (PDLA) is detained for spinning sea-island composite fibers The poly-L-lactic acid (PLLA) and poly-DL are supplied to the island component forming unit (1) of - A process of manufacturing high heat-resistant polylactide sea-island composite fibers having a stereo-complex crystal structure by compound spinning while heat-treating lactic acid (PDLA) in a separate state;
(ii) a step of weaving a multi-woven textile using the high heat-resistant polylactide sea-island composite fiber having the stereo-complex crystal structure as all or part of warp and weft yarns; and
(iii) a step of sequentially and continuously refining, dyeing and aging the woven multi-woven textile in a multi-stage cold pad bath; stereo-complex comprising a crystal structure having a crystal structure A method for manufacturing a multi-woven textile using high heat-resistant polylactide sea-island composite fibers.
According to claim 1, wherein the multi-woven textile is a stereo-complex (Stereo-complex), characterized in that one selected from a double weave fabric and a triple weave fabric Multi-woven using a high heat-resistant polylactide sea-island composite fiber having a crystal structure A method for manufacturing textiles.
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| KR20220057973A (en) | 2022-05-09 |
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