KR102363246B1 - 이소시아네이트-종료된 프레폴리머를 함유하는 1-성분 구조 접착제 - Google Patents

이소시아네이트-종료된 프레폴리머를 함유하는 1-성분 구조 접착제 Download PDF

Info

Publication number
KR102363246B1
KR102363246B1 KR1020177003458A KR20177003458A KR102363246B1 KR 102363246 B1 KR102363246 B1 KR 102363246B1 KR 1020177003458 A KR1020177003458 A KR 1020177003458A KR 20177003458 A KR20177003458 A KR 20177003458A KR 102363246 B1 KR102363246 B1 KR 102363246B1
Authority
KR
South Korea
Prior art keywords
weight
prepolymer
isocyanate
component structural
structural adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020177003458A
Other languages
English (en)
Korean (ko)
Other versions
KR20170039186A (ko
Inventor
안드레아스 러츠
대니얼 슈나이더
Original Assignee
다우 글로벌 테크놀로지스 엘엘씨
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 다우 글로벌 테크놀로지스 엘엘씨 filed Critical 다우 글로벌 테크놀로지스 엘엘씨
Publication of KR20170039186A publication Critical patent/KR20170039186A/ko
Application granted granted Critical
Publication of KR102363246B1 publication Critical patent/KR102363246B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/08—Polyurethanes from polyethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4805—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
    • B29C65/483—Reactive adhesives, e.g. chemically curing adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4865—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding containing additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/52—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the way of applying the adhesive
    • B29C65/54—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the way of applying the adhesive between pre-assembled parts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/302—Water
    • C08G18/307—Atmospheric humidity
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4825—Polyethers containing two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C08G18/6677—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203 having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2170/00—Compositions for adhesives
    • C08G2170/40—Compositions for pressure-sensitive adhesives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Adhesives Or Adhesive Processes (AREA)
KR1020177003458A 2014-07-25 2015-07-14 이소시아네이트-종료된 프레폴리머를 함유하는 1-성분 구조 접착제 Active KR102363246B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462028825P 2014-07-25 2014-07-25
US62/028,825 2014-07-25
PCT/US2015/040361 WO2016014290A1 (en) 2014-07-25 2015-07-14 One-component structural adhesive containing isocyanate-terminated prepolymer

Publications (2)

Publication Number Publication Date
KR20170039186A KR20170039186A (ko) 2017-04-10
KR102363246B1 true KR102363246B1 (ko) 2022-02-16

Family

ID=53761548

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020177003458A Active KR102363246B1 (ko) 2014-07-25 2015-07-14 이소시아네이트-종료된 프레폴리머를 함유하는 1-성분 구조 접착제

Country Status (7)

Country Link
US (1) US10155891B2 (enExample)
EP (1) EP3172254B1 (enExample)
JP (1) JP6846335B2 (enExample)
KR (1) KR102363246B1 (enExample)
CN (1) CN106536586A (enExample)
BR (1) BR112017000946B1 (enExample)
WO (1) WO2016014290A1 (enExample)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110055026A (zh) * 2019-04-25 2019-07-26 王鹏 一种灌缝材料及其制备方法
US20260109804A1 (en) * 2024-10-21 2026-04-23 Rogers Corporation Process for making polyurethane

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3759778A (en) * 1971-07-22 1973-09-18 Monsanto Res Corp Polyurethane structural adhesive
US4876308A (en) * 1988-02-18 1989-10-24 Gencorp Inc. Polyurethane adhesive for a surface treatment-free fiber reinforced plastic
DE3827378A1 (de) * 1988-08-12 1990-02-22 Henkel Kgaa Haushaltsalleskleber auf polyurethanbasis
CA2039964A1 (en) * 1990-04-27 1991-10-28 Charles W. Stobbie, Iv Mixture of isocyanate-terminated polyurethane prepolymers
CA2041532C (en) 1991-04-30 2002-01-01 Hamdy Khalil Urethane sealant having improved sag properties
CA2095876A1 (en) 1992-06-05 1993-12-06 Nigel Barksby Isocyante-terminated prepolymers derived from polyether polyol mixtures having low monol content and their use in polyurethanes
US5698656A (en) 1994-12-07 1997-12-16 The Yokohama Rubber Co., Ltd. Moisture-curing urethane adhesive composition
KR100414602B1 (ko) * 1995-01-13 2004-02-18 에섹스 스페시얼티 프로덕츠, 인코오포레이티드 2-부분습윤경화성폴리우레탄접착제
JPH107757A (ja) * 1996-06-24 1998-01-13 Asahi Chem Ind Co Ltd 一液湿気硬化型ポリイソシアネート組成物
US6353057B1 (en) * 1999-02-10 2002-03-05 King Industries, Inc. Catalyzing cationic resin and blocked polyisocyanate with bismuth carboxylate
DE19961941A1 (de) 1999-12-22 2001-07-05 Henkel Kgaa Polyurethan-Zusammensetzungen auf der Basis von Polyether-Copolymeren
DE10013186A1 (de) * 2000-03-17 2001-09-20 Basf Ag Polyisocyanate
DE10028810A1 (de) 2000-06-10 2001-12-20 Henkel Kgaa Polyurethan-Zusammensetzungen auf der Basis von Polyester-Block-Copolymeren
US6866743B2 (en) * 2001-04-12 2005-03-15 Air Products And Chemicals, Inc. Controlled structure polyurethane prepolymers for polyurethane structural adhesives
JP4492787B2 (ja) * 2003-03-18 2010-06-30 東ソー株式会社 ポリウレタン樹脂製造用触媒組成物及びポリウレタン樹脂の製造方法
DE102004036146A1 (de) * 2004-07-26 2006-03-23 Basf Ag Vernetzte Polytetrahydrofuran-haltige Polyurethane
DE102004060284A1 (de) * 2004-12-15 2006-06-29 Bayer Materialscience Ag Reaktive Polyurethan-Prepolymere mit einem geringen Gehalt an monomeren Diisocyanaten
JP2009220480A (ja) * 2008-03-18 2009-10-01 Toray Ind Inc 切込シート基材の製造方法
US9579869B2 (en) * 2009-02-17 2017-02-28 Henkel IP & Holding GmbH Liquid moisture curable polyurethane adhesives for lamination and assembly
CN101993520B (zh) * 2009-08-24 2014-02-19 拜耳材料科技(中国)有限公司 异氰酸酯封端预聚物、及其制备方法和用途
DE102010001470A1 (de) 2010-02-02 2011-08-04 Henkel AG & Co. KGaA, 40589 Polyetherblockcopolymere und daraus erhältliche Zusammensetzungen
JP5638841B2 (ja) * 2010-06-01 2014-12-10 株式会社ダイフレックス コンクリート片及びタイルの剥落防止用一成分型ポリウレタン樹脂組成物及びこれを用いたコンクリート片及びタイルの剥落を防止する方法
EP2655516B1 (en) * 2010-12-26 2018-12-26 Dow Global Technologies LLC Structural epoxy resin adhesives containing chain-extended elastomeric tougheners capped with phenol, polyphenol or aminophenol compounds
CN103614108B (zh) * 2013-11-30 2015-06-10 江苏力合粘合剂有限公司 一种软包装复合树脂及其制备方法

Also Published As

Publication number Publication date
US20170130107A1 (en) 2017-05-11
JP6846335B2 (ja) 2021-03-24
EP3172254B1 (en) 2019-08-21
CN106536586A (zh) 2017-03-22
EP3172254A1 (en) 2017-05-31
WO2016014290A1 (en) 2016-01-28
US10155891B2 (en) 2018-12-18
JP2017528553A (ja) 2017-09-28
BR112017000946A2 (en) 2018-01-16
BR112017000946B1 (pt) 2021-10-13
KR20170039186A (ko) 2017-04-10

Similar Documents

Publication Publication Date Title
EP3310868B1 (en) Latent two-part polyurethane adhesives cured with infrared radiation
US8410213B2 (en) Primerless two-part polyurethane adhesive
US11643581B2 (en) Two-component polyurethane adhesive composition and bonding method thereof
EP1433802B1 (en) Polyurethane reactive composition
EP3562853B1 (en) Two-component polyurethane adhesive
JP6336381B2 (ja) 迅速な走行可能時間を提供する車輌窓装着において有用な接着剤
US6383324B1 (en) Polysulfide-based polyurethane sealant for insulating glass
US12134716B2 (en) Adhesive composition
JP5760691B2 (ja) ウレタン樹脂接着剤組成物
US10155891B2 (en) One-component structural adhesive containing isocyanate-terminated prepolymer
EP3027669B1 (en) Structural pu adhesive for composite bonding
EP1876197B1 (en) Polyurethane reactive composition
WO2014024262A1 (ja) ウレタン樹脂接着剤組成物
JP4689895B2 (ja) 二液硬化型ウレタン組成物およびその製造方法
JP5509919B2 (ja) 硬化性組成物およびその製造方法
EP1632515A2 (en) Polyurethane reactive composition

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

R18-X000 Changes to party contact information recorded

St.27 status event code: A-3-3-R10-R18-oth-X000

A201 Request for examination
PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-OTH-PR1001 (AS PROVIDED BY THE NATIONAL OFFICE)

Year of fee payment: 5