KR102332575B1 - Manufacturing process and 3D[Three-Dimensional] make-up cosmetic composition of powder cosmetic - Google Patents

Abstract

The present invention provides a three-dimensional three-dimensional makeup cosmetic composition comprising an aqueous phase containing carrageenan, an oil phase containing oil, and a powder phase, and a method for preparing the same, wherein the aqueous phase containing carrageenan is dissolved, and the oil phase and the powder phase are uniformly dispersed It relates to a method of manufacturing a three-dimensional three-dimensional makeup cosmetic as a powder cosmetic by pouring the contents in a slurry state into a mold, that is, after pouring the contents into a tray, evaporating moisture slowly, and then separating the tray from the contents when it is completely dried.
According to the present invention, the three-dimensional three-dimensional makeup cosmetic composition and its manufacturing method have the advantage of being able to express various three-dimensional three-dimensional designs of the makeup cosmetic composition, improving powdering and improving adhesion.

Description

A three-dimensional three-dimensional makeup cosmetic composition as a powder cosmetic, and a method for manufacturing the same

The present invention relates to a three-dimensional three-dimensional makeup cosmetic composition as a powder cosmetic and a manufacturing method thereof, and more particularly, to a three-dimensional three-dimensional makeup cosmetic composition comprising an aqueous phase containing carrageenan, an oil phase containing oil, and a powder phase. .

The present invention is a manufacturing method for realizing the diversity of three-dimensional three-dimensional design and surface gloss of powder cosmetics among color cosmetics. Consumer interest in two-dimensional design is on the decline, and powder formulations are being diversified with the release of three-dimensional design products. In particular, the present invention is a method for improving the feeling of use without the expression of various three-dimensional appearance of such formulations and powder flying.

Existing three-dimensional three-dimensional color cosmetics have been developed by mixing O/W emulsion formulations, waxes, etc. with pigments, pearlescent pigments, and extender pigments to form a dome, square pillar, etc. in a kneaded state. These kneaded cosmetics have a limitation in expressing three-dimensional designs such as fine waves and detailed characters, and there is a disadvantage in that powders appear.

The 'powder extender pigment' includes all pigments in powder form added to cosmetics to impart color, texture, or texture, and improves the stability of powder products and serves as a diluent. In general, the powder extender pigment includes talc, mica, silica, titanium dioxide, zinc oxide, and boron nitride, but in the present specification, it is interpreted to further include a pearlescent pigment (pearl) and pigment, which are colored pigments in powder form. .

Carrageenan (Carrageenan) is a natural high molecular substance produced in the red algae snail hair, stone kelp, etc. Carrageenan is a complex polysaccharide extracted from red algae that grows in clean seas, and is used as a dispersant, emulsion stabilizer, swelling agent, thickener, binder, dietary fiber, anti-crystallizer, and gelling agent in food applications. In addition to food, applications are expected in pharmaceuticals, cosmetics and other fields. In general, carrageenan is an anionic polymer with sulfuric acid groups exhibiting strong hydrophilicity, and depending on the content and position of sulfate groups, kappa-(kappa-,κ-), lambda-(lambda-,λ-), iota-(iota-,ι) -), mu-(mu-, μ-)-furcellaran (-furcellaran) form, and is commercialized alone or mixed with each other. In general, three types of carrageenans of kappa-, lambda-, and iota-form are mainly used. One of the characteristics of these carrageenans is that they are easily gelled by cations of the gel-forming agent and have excellent film-forming ability. In particular, in the present invention, carrageenan is dissolved in water at 70 ~ 90 ℃ and a gel is gradually formed at 60 ℃ or less was used.

Accordingly, the present inventors have made intensive research efforts to overcome the problems of the prior art. As a result, in the case of a three-dimensional three-dimensional makeup cosmetic composition comprising an aqueous phase containing carrageenan, an oil phase containing oil, and a powder phase, various three-dimensional three-dimensional It was confirmed that it is possible to express a design, and a cosmetic composition with improved powder flying and improved adhesion can be prepared, and the present invention has been completed.

Accordingly, the main object of the present invention is to provide a three-dimensional three-dimensional makeup cosmetic composition as a powder cosmetic that can express various three-dimensional designs and has improved powdering and improved adhesion.

Another object of the present invention is to provide a three-dimensional three-dimensional makeup cosmetic manufacturing method as a powder cosmetic using the three-dimensional three-dimensional makeup cosmetic composition as the powder cosmetic.

According to one aspect of the present invention, the present invention provides a three-dimensional three-dimensional makeup cosmetic composition comprising an aqueous phase containing carrageenan, an oil phase containing oil, and a powder phase.

As a conventional three-dimensional three-dimensional cosmetic, a composition in the form of a dough made by mixing an oil-in-water emulsion formulation and waxes with a powder phase had limitations in expressing three-dimensional designs such as fine waves and detailed characters, and the problem of powder flying. there was Accordingly, the present inventors made a three-dimensional three-dimensional cosmetic composition in the form of a slurry prepared by adding a powder phase after making an oil-in-water binder using carrageenan (a water-soluble gelling agent), making it possible to express a three-dimensional design and flying It was confirmed that the problems are improved and the adhesion is improved, and the present invention has been completed.

In the present invention, the water phase part is characterized in that it is composed of carrageenan, a moisturizing agent, a surfactant, a gel-forming agent and water. What can be used as the humectant may be any humectant component conventionally used in cosmetic compositions, preferably propylene glycol, isoprene glycol, 1,2-pentanediol, 1,3-butylene glycol, dipropylene glycol, hexane. glycols such as diol, polyethylene glycol glycerin, glycerin, diglycerin, triglycerin, polyglycerin, neopentyl glycol, sorbitol, erythritol, pentaerythritol, glucose, galactose, etc. Any surfactant used in the composition may be used, and polysorbate, sorbitan stearate, glyceryl stearate PEG-100 stearate, C12-20 acid PEG-8 ester, etc. may be used. In addition, calcium chloride, potassium chloride, etc. may be used as the gel-forming agent.

According to the experimental example of the present invention, the composition containing carrageenan was able to confirm a uniform release state under various drying temperature conditions than the composition containing other water-soluble gelling agents (xanthan gum). From these results, it can be seen that the carrageenan of the present invention is an important composition for three-dimensional design by playing an important role in releasing the silicone tray and contents as a film film forming agent (see Experimental Example 1).

In the present invention, the oily part may be an ester-based oil or a hydrocarbon-based oil, preferably hexyl laurate, dicaprylyl carbonate, diisostearylmalate, butylene glycol. Lycol dicaprylate / dicaprate (Butylene glycol dicaprylate / dicaprate), Cetyl ethylhexanoate (Cetyl ethylhexanoate), Cetearyl Ethylhexanoate (Cetearyl Ethylhexanoate), Triethylhexanoin (Triethylhexanoin), Dice Dicetearyl dimer dilinoleate, Caprylic/Capric Triglyceride, Polyglyceryl-2 Triisostearate, Pentaerythrityltetraisostearate ester oils such as (Pentaerythrityl Tetraisostearate); A mixture of one or more of hydrocarbon-based oils such as polybutene, hydrogenated polyisobutene, and vegetable squalane may be used, and the type of oil is not limited thereto.

In the present invention, the powder phase is characterized in that talc, mica, sericite, spherical silicon, plastic powder, titanium dioxide, boron nitrite, pearlescent pigment (pearl) and pigment.

In the present invention, the carrageenan is characterized in that it contains 0.1 to 1.0% by weight based on the total weight of the composition. When the content of carrageenan is less than 0.1% by weight, the release from the tray becomes non-uniform or when it exceeds 1.0% by weight, even if the release is uniform, there is a problem in that it does not apply well to the skin when applied to the skin.

In the present invention, the aqueous phase part is characterized in that it contains 35 to 55% by weight based on the total weight of the composition. If the water phase is less than 35% by weight, the fluidity of the content is lowered, so it may be difficult to mix and implement a detailed design. If it exceeds 55% by weight, there is a problem in that the drying speed is slow.

In the present invention, the oily portion is characterized in that it contains 5 to 15% by weight based on the total weight of the composition. When the oil phase is less than 5% by weight, powdering is severe, and when it is more than 15% by weight, the spreadability is deteriorated.

In the present invention, the powder phase is characterized in that it contains 40 to 50% by weight based on the total weight of the composition. When the powder phase is less than 40% by weight, the drying rate is slowed and the color development power is lowered because the amount of the aqueous phase is relatively increased. On the other hand, in the case of more than 50% by weight, the fluidity of the contents is lowered, so it may be difficult to mix and implement a detailed design.

In the present invention, the cosmetic composition is characterized in that it is a blush, highlighter or eye shadow formulation.

According to the experimental example of the present invention, the three-dimensional three-dimensional eye shadow prepared according to the composition and composition ratio of the present invention showed excellent feeling of use in spreadability, powdering, adhesion and spreadability. From these results, it can be seen that the three-dimensional cosmetic composition of the present invention is suitable as a composition for powder cosmetics such as blusher, highlighter or eye shadow (see Experimental Example 2).

According to another aspect of the present invention, the present invention provides a three-dimensional three-dimensional makeup cosmetic manufacturing method as a powder cosmetic comprising the following steps.

a) preparing a mixture by mixing an aqueous phase containing carrageenan at 70 to 90° C. for 5 to 15 minutes;

b) adding the oil phase to the mixture of step a) and mixing at 70 to 90° C. for 5 to 15 minutes to prepare a mixture of the aqueous phase and the oil phase;

c) homogeneously mixing the powder phase with the mixture of step b);

d) defoaming the bubbles generated in the mixture of step c) in which the powder phase is homogeneously mixed;

e) pouring the mixture containing the powder phase of step d) into a silicone tray at 80 to 85° C.;

f) cooling the tray containing the mixture of step d) at -10 to 0° C. for 5 to 10 minutes, followed by drying at 55 to 75° C.; and

g) Remove the silicone tray after complete drying.

In the present invention, the term 'wet' refers to a state in which the powder is completely wetted with the liquid.

In the present invention, the term 'de-foaming' refers to the removal of air bubbles in the mixture.

Specifically, the conventional cosmetic composition had a two-dimensional design or a simple three-dimensional design, and had the disadvantage of flying powder, but in the present invention, carrageenan and the like are dissolved in water at 70 to 90 ° C. After dispersing, pour the contents of the slurry state into the mold, that is, the tray, and after evaporating the moisture slowly at a temperature of 60 ° C or less, when it is completely dried, the contents and the tray are separated to make a three-dimensional design formulation. In particular, in the present invention, carrageenan is dissolved in water at 70 ~ 90 ℃ and a gel is gradually formed at 60 ℃ or less was used.

As described above, according to the present invention, it is possible to prepare a make-up cosmetic composition having various 3D three-dimensional designs with glossiness by controlling the type and content of the water-soluble gelling agent during the preparation of the cosmetic composition, and the prepared cosmetic composition is powdered on the skin. There is no slipping, and the adhesion is excellent.

Hereinafter, the present invention will be described in more detail through examples. These examples are only for illustrating the present invention, and therefore, the scope of the present invention should not be construed as being limited by these examples.

Example 1 to 3: cosmetics composition ( eye shadow ) Produce

The present inventors prepared eye shadows using the aqueous phase part, oil phase part, and powder phase of the ingredients shown in Table 1 below. The aqueous phase consists of carrageenan (a water-soluble thickener), a moisturizing agent such as glycerin, a surfactant, a gel-forming agent, and a preservative. The oil phase consists of ester oil, and the powder phase consists of mica, sericite, spherical silicone, plastic powder, titanium dioxide, pearlescent pigment (pearl), boron nitride powder, and pigment. Specific content is shown in Table 2.

ingredient Content (wt %) Awards Distilled water, water-soluble thickener, glycerin, surfactant, gel-forming agent, preservative 35 to 60 paid Ester oil, hydrocarbon oil 5 to 15 powder Talc, mica, sericite, spherical silicon, plastic powder, titanium dioxide, pearlescent pigment (pearl), boron nitride powder and pigment 35 to 50

comparative example 1 to 3: cosmetics composition ( eye shadow ) Produce

The raw materials for manufacturing the eye shadow are the same as Table 1 of Examples 1 to 3, and the water-soluble thickener in the aqueous phase was prepared using xanthan gum, not carrageenan.

Specific contents of the eyeshadow component materials according to the Examples and Comparative Examples are shown in Table 2 below.

division Comparative Example 1 Comparative Example 2 Comparative Example 3 Example 1 Example 2 Example 3 Awards Distilled water To 100 To 100 To 100 To 100 To 100 To 100 glycerin 2.00 2.00 2.00 2.00 2.00 2.00 Polysorbate 80 0.50 0.50 0.50 0.50 0.50 0.50 carrageenan - - - 0.30 0.40 0.50 xanthan gum 0.30 0.40 0.50 - - - calcium chloride - - - 0.10 0.10 0.10 antiseptic 0.50 0.50 0.50 0.50 0.50 0.50 paid triethylhexanoin 10.00 10.00 10.00 10.00 10.00 10.00 powder Mica (CI 77019) 5.00 5.00 5.00 5.00 5.00 5.00 Methyl methacrylate crosspolymer 5.00 5.00 5.00 5.00 5.00 5.00 Mica & Titanium Oxide & Red Iron Oxide 30.00 30.00 30.00 30.00 30.00 30.00

The preparation of the eye shadow using the above ingredients is as follows.

According to the content composition of the components, the raw materials of the aqueous phase were mixed at 80° C. for 10 minutes using an agi mixer. After that, the oil phase was put into the homomixer into which the aqueous phase was added, and after homogeneous mixing at 80° C. and 5000 rpm for 10 minutes, 40 to 50 wt % of the powder was added to the mixture of the aqueous phase and the oil phase and wetted. After completely wetted, the homomixer was homogeneously mixed at 80°C at 7000rpm for 10 minutes and then defoamed. The prepared contents were poured into a silicone tray at 80-85° C., cooled at -10 to 0° C. for 5 minutes, dried at 55 to 75° C., and separated from the silicone tray.

Example 4 to 5 and comparative example 4 to 5: cosmetics composition ( eye shadow ) Produce

The raw materials for manufacturing the eye shadow are the same as in Examples 1 to 3, the content of the ester oil as an oily component (Example 4, Comparative Examples 4-5) is different, and hydrocarbon oil is added instead of ester oil (Example 4, Comparative Example 4-5) Example 5) was prepared.

Specific contents of the eyeshadow component materials according to the Examples and Comparative Examples are shown in Table 3 below, and the eyeshadow using the following components was prepared in the same manner as above.

division Comparative Example 4 Example 4 Comparative Example 5 Example 5 Awards Distilled water To 100 To 100 To 100 To 100 glycerin 2.00 2.00 2.00 2.00 Polysorbate 80 0.50 0.50 0.50 0.50 carrageenan 0.30 0.30 0.30 0.30 calcium chloride 0.10 0.10 0.10 0.10 antiseptic 0.50 0.50 0.50 0.50 paid triethylhexanoin 3.00 10.00 20.00 8.00 vegetable squalane - - - 2.00 powder Mica (CI 77019) 5.00 5.00 5.00 5.00 Methyl methacrylate crosspolymer 5.00 5.00 5.00 5.00 Mica & Titanium Oxide & Red Iron Oxide 30.00 30.00 30.00 30.00

Experimental example 1: Evaluation of anomalies

The eye shadow was prepared with the components and component ratios shown in Tables 1 and 2, and the release state was evaluated whether it was uniform, partially released, or not released at all, and the release state according to the drying temperature was evaluated. The results are shown in Table 4 below.

drying temperature Comparative Example 1 Comparative Example 2 Comparative Example 3 Example 1 Example 2 Example 3 75℃ X X X △ △ ○ 65℃ X X △ △ △ ○ 55℃ X △ △ ○ ○ ○ ○: uniform release, △: partially heated, X: no release

As a result of the measurement, as shown in Table 4, the eyeshadow composition of Comparative Example 1 did not release at all, the compositions of Comparative Examples 2 to 3 showed a non-uniform release state, and the compositions of Examples 1 to 3 were The most uniform release state was exhibited when the drying temperature was 55° C., and in the case of Example 3, a uniform release state was exhibited even under various temperature conditions.

Experimental example 2: feeling evaluation

The eyeshadow was prepared with the ingredients and ingredient ratios shown in Tables 1 and 2 above, and the following samples were provided to each of the 25 panelists to measure the feeling of use. indicated.

The evaluation list of the feeling of use was determined as spreadability, powdering, adhesion, and spreadability, and the measurement results are shown in Tables 5 to 6.

Comparative Example 1 Comparative Example 2 Comparative Example 3 Example 1 Example 2 Example 3 spreadability 2 2 One 5 5 4 dusting 4 4 4 5 4 5 adhesion 3 3 3 5 4 5 spreadability One One One 4 4 3 * 5: Very good, 4: Somewhat good, 3: Moderate, 2: Moderately bad, 1: Very bad

As a result of the measurement, as shown in Table 5, the eyeshadow compositions of Comparative Examples 1 to 3 had disadvantages in that spreadability, powdering, adhesion, and spreadability were inferior to those of the eyeshadow compositions of Examples, and in particular, the spreadability was very poor. appeared as On the other hand, in the case of the eyeshadow compositions prepared according to Examples 1 to 3, good evaluation was obtained compared to Comparative Examples 1 to 3, and in particular, in the case of Example 1, there was less powder flying, and it was found that spreadability, adhesion, and spreadability were excellent. Based on the results of Experimental Examples 1 and 2, the following experiment was conducted under conditions of excellent feeling of use and uniform releasability.

Comparative Example 4 Example 4 Comparative Example 5 Example 5 spreadability 4 4 One 5 dusting One 4 4 4 adhesion One 5 4 4 spreadability 4 4 One 5 * 5: Very good, 4: Somewhat good, 3: Moderate, 2: Moderately bad, 1: Very bad

As a result of the measurement, as shown in Table 6, the eyeshadow compositions of Examples 4 and 5 showed better results in powdering and adhesion than the eyeshadow compositions of Comparative Example 4, and spreadability and spreadability than the eyeshadow composition of Comparative Example 5. This good result was confirmed. It was confirmed that the feeling of use can be improved by adjusting the oil phase.

Claims (10)

In the three-dimensional three-dimensional makeup cosmetic composition, characterized in that the aqueous phase part containing carrageenan, the oil phase part containing oil, and the cosmetic composition including the powder phase are completely dried so that no water remains and is separated from the tray, the aqueous phase part Carrageenan, a moisturizer, a gel-forming agent of calcium or potassium chloride, a surfactant, and water, wherein the oily part contains one or more oils selected from ester-based oils and hydrocarbon-based oils and does not contain silicone. Makeup cosmetic composition.
delete delete According to claim 1, wherein the powder phase is talc, mica, sericite, spherical silicone, plastic powder, titanium dioxide, pearlescent pigment (pearl), boron nitrite powder and a pigment, three-dimensional three-dimensional makeup cosmetic composition characterized in that.
The three-dimensional three-dimensional makeup cosmetic composition according to claim 1, wherein the carrageenan is contained in an amount of 0.1 to 1.0 wt% based on the total weight of the composition.
The three-dimensional three-dimensional makeup cosmetic composition according to claim 1, wherein the water-receiving part contains 35 to 60% by weight based on the total weight of the composition.
The three-dimensional three-dimensional makeup cosmetic composition according to claim 1, wherein the oily part contains 5 to 15% by weight based on the total weight of the composition.
The three-dimensional three-dimensional makeup cosmetic composition according to claim 1, wherein the powder phase contains 35 to 50% by weight based on the total weight of the composition.
The three-dimensional three-dimensional makeup cosmetic composition according to claim 1, wherein the cosmetic composition is a blush, highlighter, or eye shadow formulation.
A three-dimensional three-dimensional makeup cosmetic manufacturing method as a powder cosmetic comprising the following steps:
a) preparing a mixture by mixing an aqueous phase containing carrageenan at 70 to 90° C. for 5 to 15 minutes;
b) adding the oil phase to the mixture of step a) and mixing at 70 to 90° C. for 5 to 15 minutes to prepare a mixture of the aqueous phase and the oil phase;
c) homogeneously mixing the powder phase by wetting the mixture in step b);
d) defoaming the bubbles generated in the mixture of step c) in which the powder phase is homogeneously mixed;
e) pouring the mixture in a slurry state including the powder phase of step d) into a silicone tray at 80 to 85°C;
f) cooling the tray containing the mixture of step d) at -10 to 0° C. for 5 to 10 minutes without compression molding, followed by drying at 55 to 75° C.; and
g) Remove the silicone tray after complete drying.