KR20160040791A - Manufacturing process and 3D[Three-Dimensional] make-up cosmetic composition of powder cosmetic - Google Patents

Abstract

The present invention relates to a three-dimensional makeup cosmetic composition comprising an aqueous phase containing carrageenan, an oil-containing oil phase and a powder phase, and a process for producing the same, which comprises dissolving a water phase containing carrageenan and uniformly dispersing the oil phase and the powder phase Dimensional solid make-up cosmetics as a powdered cosmetic product by separating the contents and a tray when the contents of the slurry state are poured into a mold, that is, a tray, and then gradually evaporating moisture and completely drying the contents.
According to the present invention, the three-dimensional makeup cosmetic composition and the method for producing the same can advantageously express various three-dimensional stereoscopic designs of the makeup cosmetic composition, improve the dusting and improve the adhesion.

Description

[0001] The present invention relates to a three-dimensional make-up cosmetic composition and a method for manufacturing the same,

More particularly, the present invention relates to a three-dimensional makeup cosmetic composition comprising an aqueous phase containing carrageenan, an oil phase containing oil, and a powder phase, .

The present invention is a manufacturing method for realizing a variety of three-dimensional stereoscopic design of powder cosmetic materials in cosmetics for color tones and surface gloss. Consumer interest in two - dimensional design is gradually decreasing, and powder formulations are diversifying due to the launch of three - dimensional solid design products. The present invention is particularly directed to a method for improving various three dimensional appearance of such formulations and feeling without feeling of dustiness.

Conventional three-dimensional stereoscopic color cosmetics have been developed in the form of a dome, square pillar, etc. in a kneaded state by mixing O / W emulsion formulations, waxes and the like with coloring matters, pearlescent pigments and extender pigments. Such kneaded cosmetics have a limitation in expressing a three-dimensional design such as fine waves and fine letters, and have disadvantages such as dusting.

The 'powder extender pigment' includes all of the powder-type pigments added to the cosmetic to impart color, texture or texture, and improves the stability of the powder product and serves as a diluent. Typically, the powder extender pigment is interpreted as further comprising a pearl luster pigment (pearl) and pigment in the form of powders, including talc, mica, silica, titanium dioxide, zinc oxide and boron nitride .

Carrageenan (Carrageenan) is a natural macromolecule material produced from red algae, stone scabbard and the like. Carrageenan is a complex polysaccharide extracted from red algae grown in clean waters and is used as a dispersant, emulsifier, swelling agent, thickener, binder, dietary fiber, crystallization inhibitor and gelling agent in food applications. In addition to food, applications are expected in medicine, cosmetics and other fields. In general, carrageenan is an anionic polymer having a sulfate group that exhibits strong hydrophilic properties, and can be classified into kappa-, kappa-, lambda-, lambda-, iota-, and iota- -), mu- (mu-, mu-) - furcellaran, and they are commercialized either singly or in combination. Usually, three types of carrageenans, such as kappa, lambda, and iota-type, are mainly used. One of the characteristics of these carrageenans is that they are easily gelled by the cations of the gel former and are excellent in film forming ability. Particularly, the present invention utilizes the characteristic that carrageenan is dissolved in water at 70 to 90 占 폚 and a gel is formed slowly at 60 占 폚 or less.

Accordingly, the present inventors have made intensive efforts to overcome the problems of the prior art. As a result, in the case of a three-dimensional makeup cosmetic composition comprising an aqueous phase containing carrageenan, an oil phase containing oil, and a powder phase, It is possible to produce a cosmetic composition capable of expressing the design, improving the dusting of the powder and improving the feeling of adhesion, and completed the present invention.

Accordingly, it is a main object of the present invention to provide a three-dimensional makeup cosmetic composition as a powder cosmetic composition capable of expressing various three-dimensional stereoscopic designs, improved flour spreading and improved adhesion.

Another object of the present invention is to provide a method for producing a three-dimensional makeup cosmetic as a powder cosmetic using the three-dimensional makeup cosmetic composition as the powder cosmetic.

According to one aspect of the present invention, there is provided a three-dimensional makeup cosmetic composition comprising an aqueous phase comprising carrageenan, an oily phase comprising oil, and a powder phase.

As a conventional three-dimensional cosmetic cosmetic, a dough-like composition prepared by mixing an emulsion formulation of water type, wax, and the like with a powder phase has limitations in expressing a three-dimensional design such as fine waves and fine characters, . Accordingly, the present inventors have made it possible to express a three-dimensional stereoscopic design in a slurry-type three-dimensional cosmetic composition prepared by preparing a binder of an underwater type using a carrageenan (a water-soluble gelling agent) And the adhesion is improved. Thus, the present invention has been completed.

In the present invention, the water receiving portion is characterized by comprising carrageenan, a moisturizing agent, a surfactant, a gel-forming agent, and water. Any moisturizing agent conventionally used in the cosmetic composition may be used as the moisturizing agent, and preferable examples thereof include propylene glycol, isoprene glycol, 1,2-pentanediol, 1,3-butylene glycol, dipropylene glycol, Glycols such as polyethylene glycol glycerin, glycerin, diglycerin, triglycerin, polyglycerin, neopentyl glycol, sorbitol, erythritol, pentaerythritol, glucose and galactose, and the like. Any surfactant used in the composition may be used, and preferred are polysorbate, sorbitan stearate, glyceryl stearate phage-100 stearate, C12-20 acid phage-8 ester, and the like. In addition, there are calcium chloride, potassium chloride and the like which can be used as the above gel forming agent.

According to the experimental example of the present invention, the composition containing carrageenan was able to confirm a uniform release state at various drying temperature conditions than the composition containing other water-soluble gelling agent (xanthan gum). From these results, it can be seen that the carrageenan of the present invention plays an important role in releasing the silicon tray and the contents as a film-forming agent, and is an important composition for three-dimensional stereoscopic design (see Experimental Example 1).

In the present invention, the oil phase may be an ester-based oil or a hydrocarbon-based oil, and is preferably selected from the group consisting of hexyl laurate, Dicaprylyl carbonate, Diisostearylmalate, Butylene glycol dicaprylate / dicaprate, Cetyl ethylhexanoate, Cetearyl Ethylhexanoate, Triethylhexanoin, Polyglyceryl-2-triisostearate, pentaerythritol tetraisostearate, polyglyceryl dimer dilinoleate, caprylic / capric triglyceride, polyglyceryl-2 triisostearate, (Pentaerythrityl tetraisostearate); A mixture of at least one hydrocarbon-based oil such as polybutene, hydrogenated polyisobutene, and phytosqualane may be used, and the kind of oil is not limited thereto.

In the present invention, the powder phase is characterized by being talc, mica, sericite, spherical silicon, plastic powder, titanium dioxide, boron nitride, pearl luster pigment (pearl) and dye.

In the present invention, the carrageenan is characterized by containing 0.1 to 1.0% by weight based on the total weight of the composition. When carrageenan is contained in an amount of less than 0.1% by weight, if the release from the tray becomes non-uniform or exceeds 1.0% by weight, even if the release is uniform, the carrageenan may not be able to swell well on the skin.

In the present invention, the water receiving portion is characterized by containing 35 to 55% by weight based on the total weight of the composition. When the water phase portion is less than 35% by weight, the fluidity of the contents is lowered, which makes it difficult to carry out the mixing process, and it may be difficult to realize a detailed design, and when it exceeds 55% by weight, the drying speed is slow.

In the present invention, the oil phase part is characterized by containing 5 to 15% by weight based on the total weight of the composition. If the oil phase portion is less than 5% by weight, the powdery fly becomes worse, and when it is more than 15% by weight, the spreadability is lowered.

In the present invention, the powder phase is characterized by containing 40 to 50% by weight based on the total weight of the composition. When the powder phase is less than 40% by weight, the amount of the water phase is relatively increased, so that the drying speed is slowed and the coloring power is lowered. On the other hand, when the content is more than 50% by weight, the fluidity of the content is lowered, which makes it difficult to carry out a mixing process and it may be difficult to realize detailed design.

In the present invention, the cosmetic composition is characterized by being a blusher, a highlighter or an eye shadow formulation.

According to the experimental example of the present invention, the three-dimensional stereoscopic eye shadow produced according to the composition and the composition ratio of the present invention exhibited excellent feeling in spreading, dusting, adhesion and spreadability. From these results, it can be seen that the three-dimensional solid cosmetic composition of the present invention is suitable as a powder cosmetic composition such as a blusher, a highlighter or an eye shadow (see Experimental Example 2).

According to another aspect of the present invention, there is provided a method for producing a three-dimensional makeup cosmetic as a powder cosmetic comprising the following steps.

a) mixing the water phase containing carrageenan at 70 to 90 DEG C for 5 to 15 minutes to prepare a mixture;

b) adding an oil phase to the mixture of step a) and mixing the mixture at 70 to 90 DEG C for 5 to 15 minutes to prepare a mixture of water and oil phase;

c) wetting the powder phase with the mixture of step b) and homogeneously mixing;

d) defoaming the bubble formed in the mixture of step c) in which the powder phase is homogeneously mixed;

e) pouring the mixture comprising the powder phase of step d) into a silicon tray at 80 to 85 占 폚;

f) cooling the tray containing the mixture of step d) at -10 to 0 占 폚 for 5 to 10 minutes and then drying at 55 to 75 占 폚; And

g) releasing the silicon tray after complete drying.

In the present invention, the term " wet " means that the powder is completely wetted with the liquid.

The term " defoaming " in the present invention means defoaming in a mixture.

In the present invention, carrageenan and the like are dissolved in water at 70 to 90 ° C, and the oil phase and the powder phase are uniformly dispersed in water And then the contents of the slurry are poured into a mold, that is, a tray, and then the water is gradually evaporated at a temperature of 60 ° C or lower. When the contents are completely dried, the contents and the tray are separated to form a three-dimensional solid design formulation. Particularly, the present invention utilizes the characteristic that carrageenan is dissolved in water at 70 to 90 占 폚 and a gel is formed slowly at 60 占 폚 or less.

INDUSTRIAL APPLICABILITY As described above, according to the present invention, it is possible to produce makeup cosmetic compositions of various 3D stereoscopic designs with shiny feel by controlling the kind and amount of the water-soluble gelling agent during the production of the cosmetic composition, It is free from wrinkles and has excellent adhesion.

Hereinafter, the present invention will be described in more detail with reference to Examples. These embodiments are only for illustrating the present invention, and thus the scope of the present invention is not construed as being limited by these embodiments.

Example  1 to 3: Cosmetics  Composition ( Eyeshadow ) Produce

The present inventors manufactured an eye shadow using the above-mentioned water component, oil phase and powder phase shown in Table 1 below. In the upper part, it is composed of carrageenan (water-soluble thickener), moisturizer such as glycerin, surfactant, gel-forming agent, preservative and the like. The oil phase is composed of ester oil. The powder is composed of mica, sericite, spherical silicone, plastic powder, titanium dioxide, pearl luster pigment (pearl), boron nitride powder and pigment. The specific contents are shown in Table 2.

ingredient Content (% by weight) Awards Distilled water, water-soluble thickener, glycerin, surfactant, gel-forming agent, preservative 35 to 60 Paid Ester-based oils, hydrocarbon-based oils 5 to 15 Powder phase Talc, mica, sericite, spherical silicon, plastic powder, titanium dioxide, pearl luster pigment (pearl), boron nitride powder and pigment 35 to 50

Comparative Example  1 to 3: Cosmetics  Composition ( Eyeshadow ) Produce

Raw materials for eye shadow production are the same as those in Table 1 of Examples 1 to 3 above, and the water-soluble thickening agent in the water-soluble portion was prepared using xanthan gum which is not carrageenan.

The specific contents of the eye shadow component materials according to the above Examples and Comparative Examples are shown in Table 2 below.

division Comparative Example 1 Comparative Example 2 Comparative Example 3 Example 1 Example 2 Example 3 Awards Distilled water To 100 To 100 To 100 To 100 To 100 To 100 glycerin 2.00 2.00 2.00 2.00 2.00 2.00 Polysorbate 80 0.50 0.50 0.50 0.50 0.50 0.50 Carrageenan - - - 0.30 0.40 0.50 Xanthan gum 0.30 0.40 0.50 - - - Calcium chloride - - - 0.10 0.10 0.10 antiseptic 0.50 0.50 0.50 0.50 0.50 0.50 Paid Triethanolhexanone 10.00 10.00 10.00 10.00 10.00 10.00 Powder phase Mica (CI 77019) 5.00 5.00 5.00 5.00 5.00 5.00 Methyl methacrylate crosspolymer 5.00 5.00 5.00 5.00 5.00 5.00 Mica & Titanium Oxide & Red Oxide 30.00 30.00 30.00 30.00 30.00 30.00

The manufacture of eye shadow using the above components is as follows.

According to the content composition of the above components, the raw materials of the aqueous phase were mixed at 80 캜 for 10 minutes using an agi mixer. Then, the oil phase was charged into the homomixer to which the water phase was added, and homogenized at 80 DEG C and 5000 rpm for 10 minutes, and 40 to 50 wt% of the powder phase was added to the mixture of the water phase and the oil phase for wetting. After thoroughly wetting, the homomixer was homogeneously mixed and defoamed at 80 DEG C at 7000 rpm for 10 minutes. The prepared contents were poured into a silicon tray at 80 to 85 ° C, then cooled at -10 to 0 ° C for 5 minutes, then dried at 55 to 75 ° C, and the silicon tray was removed.

Example  4 to 5 and Comparative Example  4 to 5: Cosmetics  Composition ( Eyeshadow ) Produce

The raw materials for the production of eyeshadow are the same as those of Examples 1 to 3, except that the content of the ester-based oil (Example 4 and Comparative Example 4-5) was changed and the hydrocarbon-based oil was added instead of the ester-based oil Example 5).

The specific contents of the eye shadow component materials according to the examples and the comparative examples are shown in the following Table 3, and the production of the eye shadow using the following components was performed in the same manner as described above.

division Comparative Example 4 Example 4 Comparative Example 5 Example 5 Awards Distilled water To 100 To 100 To 100 To 100 glycerin 2.00 2.00 2.00 2.00 Polysorbate 80 0.50 0.50 0.50 0.50 Carrageenan 0.30 0.30 0.30 0.30 Calcium chloride 0.10 0.10 0.10 0.10 antiseptic 0.50 0.50 0.50 0.50 Paid Triethanolhexanone 3.00 10.00 20.00 8.00 Vegetable squalane - - - 2.00 Powder phase Mica (CI 77019) 5.00 5.00 5.00 5.00 Methyl methacrylate crosspolymer 5.00 5.00 5.00 5.00 Mica & Titanium Oxide & Red Oxide 30.00 30.00 30.00 30.00

Experimental Example  1: Evaluation of release status

Eyeshadow was manufactured by the ingredients and composition ratios shown in Tables 1 and 2, and the evaluation of the released state was evaluated as to whether the evaluation was uniform, partially or not at all, and the release state was evaluated according to the drying temperature. The results are shown in Table 4 below.

Drying temperature Comparative Example 1 Comparative Example 2 Comparative Example 3 Example 1 Example 2 Example 3 75 ℃ X X X △ △ ○ 65 ℃ X X △ △ △ ○ 55 ° C X △ △ ○ ○ ○ ?: Uniform release,?: Partial suspension,?: No release

As a result of the measurement, as shown in Table 4, the eye shadow composition of Comparative Example 1 was free from any mold release, the compositions of Comparative Examples 2 to 3 exhibited an unevenly dispersed state, and the compositions of Examples 1 to 3 The most uniform release state was observed when the drying temperature was 55 ° C, and in the case of Example 3, the uniform release state was exhibited even at various temperature conditions.

Experimental Example  2: Feeling  evaluation

Eyeshadow was prepared by the ingredients and composition ratios shown in Tables 1 and 2, and 25 sensory panels were selected for each of the following samples. Respectively.

The evaluation list of feelings was determined as wettability, dustiness, adhesion, and spreadability, and the measurement results are shown in Tables 5 to 6.

Comparative Example 1 Comparative Example 2 Comparative Example 3 Example 1 Example 2 Example 3 Brittle 2 2 One 5 5 4 Dusting 4 4 4 5 4 5 Adhesion 3 3 3 5 4 5 Spreadability One One One 4 4 3 5: very good, 4: slightly better, 3: moderate, 2: slightly poor, 1: very poor

As a result of the measurement, as shown in Table 5, the eye shadow compositions of Comparative Examples 1 to 3 had drawbacks such as spreading, dusting, adhesion, and spreadability that were lower than those of the eye shadow compositions of the Examples, Respectively. On the other hand, in the case of the eye shadow composition prepared according to Examples 1 to 3, a good evaluation was obtained as compared with Comparative Examples 1 to 3. Particularly, in Example 1, powdery spots were less, and spreadability, adhesion and spreadability were superior. Based on the results of Experimental Examples 1 and 2, the following experiment was carried out under conditions that exhibit excellent feeling of use and uniform releasability.

Comparative Example 4 Example 4 Comparative Example 5 Example 5 Brittle  4  4  One 5 Dusting  One  4  4 4 Adhesion  One  5  4 4 Spreadability 4  4  One 5 5: very good, 4: slightly better, 3: moderate, 2: slightly poor, 1: very poor

As a result of the measurement, as shown in Table 6 above, the eye shadow compositions of Examples 4 and 5 showed better results than the eye shadow composition of Comparative Example 4 in terms of dustiness and adhesion, and the eye shadow composition of Comparative Example 5 had better wettability and spreadability We confirmed this good result. And it is confirmed that the feeling can be improved by controlling the oil phase.

Claims (10)

A three-dimensional makeup cosmetic composition comprising an aqueous phase comprising carrageenan, an oil-in-water emulsion and a powder phase.
2. The three-dimensional makeup cosmetic composition according to claim 1, wherein the water-soluble part is composed of carrageenan, a moisturizer, a gel-forming agent, a surfactant and water.
The three-dimensional makeup cosmetic composition according to claim 1, wherein the oil in the oil phase is an oil mixed with at least one ester-based oil or hydrocarbon-based oil.
The three-dimensional makeup cosmetic composition according to claim 1, wherein the powder phase is talc, mica, sericite, spherical silicone, plastic powder, titanium dioxide, pearl luster pigment (Pearl), boronite light powder and pigment.
The three-dimensional makeup cosmetic composition according to claim 1, wherein the carrageenan is contained in an amount of 0.1 to 1.0% by weight based on the total weight of the composition.
The three-dimensional makeup cosmetic composition according to claim 1, wherein the water-soluble part contains 35 to 60% by weight based on the total weight of the composition.
The three-dimensional make-up cosmetic composition according to claim 1, wherein the oily component is contained in an amount of 5 to 15% by weight based on the total weight of the composition.
The three-dimensional makeup cosmetic composition according to claim 1, wherein the powder phase contains 35 to 50% by weight based on the total weight of the composition.
The three-dimensional makeup cosmetic composition according to claim 1, wherein the cosmetic composition is a blusher, a highlighter, or an eye shadow formulation.
A method for producing a three-dimensional makeup cosmetic as a powder cosmetic comprising the steps of:
a) mixing the water phase containing carrageenan at 70 to 90 DEG C for 5 to 15 minutes to prepare a mixture;
b) adding an oil phase to the mixture of step a) and mixing the mixture at 70 to 90 DEG C for 5 to 15 minutes to prepare a mixture of water and oil phase;
c) wetting the powder phase with the mixture of step b) and homogeneously mixing;
d) defoaming the bubble formed in the mixture of step c) in which the powder phase is homogeneously mixed;
e) pouring the mixture comprising the powder phase of step d) into a silicon tray at 80 to 85 占 폚;
f) cooling the tray containing the mixture of step d) at -10 to 0 占 폚 for 5 to 10 minutes and then drying at 55 to 75 占 폚; And
g) releasing the silicon tray after complete drying.