KR102158887B1 - 흡열 반응들을 위한 방법 및 장치 - Google Patents
흡열 반응들을 위한 방법 및 장치 Download PDFInfo
- Publication number
- KR102158887B1 KR102158887B1 KR1020157003640A KR20157003640A KR102158887B1 KR 102158887 B1 KR102158887 B1 KR 102158887B1 KR 1020157003640 A KR1020157003640 A KR 1020157003640A KR 20157003640 A KR20157003640 A KR 20157003640A KR 102158887 B1 KR102158887 B1 KR 102158887B1
- Authority
- KR
- South Korea
- Prior art keywords
- furnace
- burners
- tubes
- endothermic process
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims abstract description 52
- 230000008569 process Effects 0.000 title claims abstract description 26
- 238000006243 chemical reaction Methods 0.000 title description 12
- 239000003054 catalyst Substances 0.000 claims abstract description 28
- 230000005855 radiation Effects 0.000 claims description 14
- 238000005516 engineering process Methods 0.000 claims description 6
- 238000002347 injection Methods 0.000 claims description 6
- 239000007924 injection Substances 0.000 claims description 6
- 239000000919 ceramic Substances 0.000 claims description 5
- 239000006260 foam Substances 0.000 claims description 5
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 5
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 238000000629 steam reforming Methods 0.000 claims description 4
- 238000002485 combustion reaction Methods 0.000 description 25
- 230000004907 flux Effects 0.000 description 14
- 239000007789 gas Substances 0.000 description 13
- 238000005452 bending Methods 0.000 description 11
- 239000003546 flue gas Substances 0.000 description 10
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 9
- 239000000446 fuel Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- 230000009970 fire resistant effect Effects 0.000 description 7
- 238000010276 construction Methods 0.000 description 6
- 239000012530 fluid Substances 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 238000013021 overheating Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000001991 steam methane reforming Methods 0.000 description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 239000007943 implant Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- -1 methane Chemical class 0.000 description 1
- 229910003465 moissanite Inorganic materials 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006057 reforming reaction Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/062—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes being installed in a furnace
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/067—Heating or cooling the reactor
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C5/00—Disposition of burners with respect to the combustion chamber or to one another; Mounting of burners in combustion apparatus
- F23C5/08—Disposition of burners
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D1/00—Casings; Linings; Walls; Roofs
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D7/00—Forming, maintaining or circulating atmospheres in heating chambers
- F27D7/02—Supplying steam, vapour, gases or liquids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
- C01B2203/0816—Heating by flames
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C13/00—Apparatus in which combustion takes place in the presence of catalytic material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2900/00—Special features of, or arrangements for combustion apparatus using fluid fuels or solid fuels suspended in air; Combustion processes therefor
- F23C2900/03002—Combustion apparatus adapted for incorporating a fuel reforming device
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12184303.1A EP2708812B1 (en) | 2012-09-13 | 2012-09-13 | Process and apparatus for endothermic reactions |
| EP12184303.1 | 2012-09-13 | ||
| PCT/EP2013/066998 WO2014040815A1 (en) | 2012-09-13 | 2013-08-14 | Process and apparatus for endothermic reactions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20150054766A KR20150054766A (ko) | 2015-05-20 |
| KR102158887B1 true KR102158887B1 (ko) | 2020-09-22 |
Family
ID=46939579
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020157003640A Active KR102158887B1 (ko) | 2012-09-13 | 2013-08-14 | 흡열 반응들을 위한 방법 및 장치 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US9533275B2 (enExample) |
| EP (1) | EP2708812B1 (enExample) |
| KR (1) | KR102158887B1 (enExample) |
| CN (1) | CN104620050B (enExample) |
| BR (1) | BR112015004134B1 (enExample) |
| CA (1) | CA2880132C (enExample) |
| ES (1) | ES2642139T3 (enExample) |
| IN (1) | IN2015MN00126A (enExample) |
| MX (1) | MX356160B (enExample) |
| MY (1) | MY181002A (enExample) |
| PL (1) | PL2708812T3 (enExample) |
| RU (1) | RU2643734C2 (enExample) |
| SA (1) | SA515360132B1 (enExample) |
| WO (1) | WO2014040815A1 (enExample) |
| ZA (1) | ZA201500563B (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9272905B2 (en) * | 2014-02-27 | 2016-03-01 | Honeywell International, Inc. | Method for optimizing down fired reforming furnaces |
| EP3153465B1 (de) * | 2015-10-05 | 2020-01-01 | L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Reformer zur erzeugung von synthesegas |
| ES2752674T3 (es) * | 2015-10-05 | 2020-04-06 | Air Liquide | Reformador de vapor para la producción de gas de síntesis |
| FR3043185B1 (fr) * | 2015-11-02 | 2019-07-12 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Methode pour ameliorer l'efficacite thermique d'un four de reformage |
| EP3182003B1 (en) * | 2015-12-15 | 2021-04-07 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Apparatus for endothermic process with improved burners arrangement |
| EP3411329B1 (en) * | 2016-02-04 | 2020-04-15 | Technip France | Method for reducing temperature spread in reformer |
| EP3279561B1 (en) * | 2016-08-02 | 2019-06-26 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Apparatus for endothermic process with improved tubes arrangement |
| CN109996760B (zh) * | 2016-10-25 | 2022-09-02 | 法国德西尼布 | 用于重整的催化剂管 |
| KR20180078364A (ko) * | 2016-12-29 | 2018-07-10 | 주식회사 효성 | 파이어 히터 |
| CN110720014A (zh) * | 2017-06-14 | 2020-01-21 | 乔治洛德方法研究和开发液化空气有限公司 | 具有改进的外燃烧器布置的用于吸热过程的设备 |
| US11806705B2 (en) | 2018-06-28 | 2023-11-07 | Haldor Topsøe A/S | Catalytic reactor comprising metal radiation surfaces |
| PL3647658T3 (pl) | 2018-11-01 | 2021-11-22 | L'air Liquide, Société Anonyme pour l'Étude et l'Exploitation des Procédés Georges Claude | Piec do procesu endotermicznego i sposób działania pieca z ulepszonym układem palników |
| WO2020260589A1 (en) | 2019-06-28 | 2020-12-30 | Technip France | Method of loading a tubular reactor with a catalyst tube assembly, and a catalyst tube assembly for a tubular reactor |
| ES2926691T3 (es) * | 2019-10-28 | 2022-10-27 | Air Liquide | Método para mejorar la homogeneización de las temperaturas en un reformador de metano con vapor mediante el ajuste de la distribución de potencia |
| US11110424B2 (en) * | 2019-11-18 | 2021-09-07 | Praxair Technology, Inc. | Reformer box with reformer tunnel including tunnel port |
| EP3838397B1 (de) * | 2019-12-19 | 2024-09-04 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Reformerofen und dessen verwendung zur dampfreformierung |
| CN113847821B (zh) * | 2020-06-28 | 2023-10-17 | 宝山钢铁股份有限公司 | 一种加热炉烧嘴的脉冲控制方法及脉冲炉的炉温控制方法 |
| WO2022106058A1 (en) * | 2020-11-19 | 2022-05-27 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Reforming reactor comprising reformer tubes with enlarged outer surface area and structured catalyst |
| DE102020214918A1 (de) * | 2020-11-27 | 2022-06-02 | Thyssenkrupp Ag | Verfahren zur Minimierung der Stickoxidemission einer Dampfreformierungsanlage sowie Dampfreformierungsanlage dafür |
| US20240101418A1 (en) * | 2022-09-23 | 2024-03-28 | Tushar P. Vispute | Method for carbon formation free operation of reformers |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1078193A1 (ru) * | 1968-02-26 | 1984-03-07 | Kucherov Aleksandr S | Парогенератор |
| JPH05332509A (ja) * | 1992-05-29 | 1993-12-14 | Kuwahara Seisakusho:Kk | 炉内排ガス循環型低noxバーナ |
| RU2135891C1 (ru) * | 1997-12-23 | 1999-08-27 | Дзержинская ТЭЦ АО "Нижновэнерго" | Топка |
| DE10333854A1 (de) | 2003-07-24 | 2005-02-17 | Uhde Gmbh | Röhrenspaltofen |
| DE10357064A1 (de) | 2003-12-04 | 2005-07-07 | Uhde Gmbh | Syntheseofen |
| KR100590401B1 (ko) * | 2004-03-15 | 2006-06-19 | 주식회사 경동세라텍 | 팽창퍼라이트 소성로 |
| US7686611B2 (en) * | 2005-11-03 | 2010-03-30 | Air Products And Chemicals, Inc. | Flame straightening in a furnace |
| MX2011013913A (es) * | 2009-06-24 | 2012-02-23 | Thyssenkrupp Uhde Gmbh | Reformador primario para la formacion reducida de oxido nitrico. |
| US8545213B2 (en) | 2010-03-09 | 2013-10-01 | Air Products And Chemicals, Inc. | Reformer and method of operating the reformer |
-
2012
- 2012-09-13 PL PL12184303T patent/PL2708812T3/pl unknown
- 2012-09-13 EP EP12184303.1A patent/EP2708812B1/en active Active
- 2012-09-13 ES ES12184303.1T patent/ES2642139T3/es active Active
-
2013
- 2013-08-14 MX MX2015003184A patent/MX356160B/es active IP Right Grant
- 2013-08-14 CA CA2880132A patent/CA2880132C/en active Active
- 2013-08-14 KR KR1020157003640A patent/KR102158887B1/ko active Active
- 2013-08-14 US US14/426,027 patent/US9533275B2/en active Active
- 2013-08-14 WO PCT/EP2013/066998 patent/WO2014040815A1/en not_active Ceased
- 2013-08-14 IN IN126MUN2015 patent/IN2015MN00126A/en unknown
- 2013-08-14 BR BR112015004134-5A patent/BR112015004134B1/pt not_active IP Right Cessation
- 2013-08-14 CN CN201380047041.XA patent/CN104620050B/zh active Active
- 2013-08-14 MY MYPI2015700720A patent/MY181002A/en unknown
- 2013-08-14 RU RU2015113308A patent/RU2643734C2/ru active
-
2015
- 2015-01-26 ZA ZA2015/00563A patent/ZA201500563B/en unknown
- 2015-03-12 SA SA515360132A patent/SA515360132B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR112015004134A2 (pt) | 2017-07-04 |
| IN2015MN00126A (enExample) | 2015-10-16 |
| CA2880132A1 (en) | 2014-03-20 |
| RU2643734C2 (ru) | 2018-02-05 |
| CA2880132C (en) | 2020-03-31 |
| MY181002A (en) | 2020-12-15 |
| WO2014040815A1 (en) | 2014-03-20 |
| CN104620050B (zh) | 2017-06-13 |
| EP2708812A1 (en) | 2014-03-19 |
| PL2708812T3 (pl) | 2017-12-29 |
| US20150217250A1 (en) | 2015-08-06 |
| BR112015004134B1 (pt) | 2021-05-04 |
| MX2015003184A (es) | 2015-09-25 |
| CN104620050A (zh) | 2015-05-13 |
| ZA201500563B (en) | 2016-10-26 |
| SA515360132B1 (ar) | 2017-02-22 |
| US9533275B2 (en) | 2017-01-03 |
| MX356160B (es) | 2018-05-16 |
| KR20150054766A (ko) | 2015-05-20 |
| EP2708812B1 (en) | 2017-08-02 |
| ES2642139T3 (es) | 2017-11-15 |
| RU2015113308A (ru) | 2016-11-10 |
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Legal Events
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