CA2880132C - Process and apparatus for endothermic reactions - Google Patents

Process and apparatus for endothermic reactions Download PDF

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Publication number
CA2880132C
CA2880132C CA2880132A CA2880132A CA2880132C CA 2880132 C CA2880132 C CA 2880132C CA 2880132 A CA2880132 A CA 2880132A CA 2880132 A CA2880132 A CA 2880132A CA 2880132 C CA2880132 C CA 2880132C
Authority
CA
Canada
Prior art keywords
furnace
burners
tubes
tube
roof
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2880132A
Other languages
English (en)
French (fr)
Other versions
CA2880132A1 (en
Inventor
Julien CANCES
Frederic Camy-Peyret
Bernard Labegorre
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Publication of CA2880132A1 publication Critical patent/CA2880132A1/en
Application granted granted Critical
Publication of CA2880132C publication Critical patent/CA2880132C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/062—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes being installed in a furnace
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts with external heating of the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067—Heating or cooling the reactor
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C13/00—Apparatus in which combustion takes place in the presence of catalytic material
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C5/00—Disposition of burners with respect to the combustion chamber or to one another; Mounting of burners in combustion apparatus
    • F23C5/08—Disposition of burners
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D1/00—Casings; Linings; Walls; Roofs
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D7/00—Forming, maintaining or circulating atmospheres in heating chambers
    • F27D7/02—Supplying steam, vapour, gases or liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0816—Heating by flames
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2900/00—Special features of, or arrangements for combustion apparatus using fluid fuels or solid fuels suspended in air; Combustion processes therefor
    • F23C2900/03002—Combustion apparatus adapted for incorporating a fuel reforming device

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
CA2880132A 2012-09-13 2013-08-14 Process and apparatus for endothermic reactions Active CA2880132C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12184303.1 2012-09-13
EP12184303.1A EP2708812B1 (en) 2012-09-13 2012-09-13 Process and apparatus for endothermic reactions
PCT/EP2013/066998 WO2014040815A1 (en) 2012-09-13 2013-08-14 Process and apparatus for endothermic reactions

Publications (2)

Publication Number Publication Date
CA2880132A1 CA2880132A1 (en) 2014-03-20
CA2880132C true CA2880132C (en) 2020-03-31

Family

ID=46939579

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2880132A Active CA2880132C (en) 2012-09-13 2013-08-14 Process and apparatus for endothermic reactions

Country Status (15)

Country Link
US (1) US9533275B2 (enExample)
EP (1) EP2708812B1 (enExample)
KR (1) KR102158887B1 (enExample)
CN (1) CN104620050B (enExample)
BR (1) BR112015004134B1 (enExample)
CA (1) CA2880132C (enExample)
ES (1) ES2642139T3 (enExample)
IN (1) IN2015MN00126A (enExample)
MX (1) MX356160B (enExample)
MY (1) MY181002A (enExample)
PL (1) PL2708812T3 (enExample)
RU (1) RU2643734C2 (enExample)
SA (1) SA515360132B1 (enExample)
WO (1) WO2014040815A1 (enExample)
ZA (1) ZA201500563B (enExample)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9272905B2 (en) * 2014-02-27 2016-03-01 Honeywell International, Inc. Method for optimizing down fired reforming furnaces
PL3153464T3 (pl) * 2015-10-05 2020-03-31 L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Reformer parowy do wytwarzania gazu syntezowego
EP3153465B1 (de) * 2015-10-05 2020-01-01 L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Reformer zur erzeugung von synthesegas
FR3043185B1 (fr) * 2015-11-02 2019-07-12 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Methode pour ameliorer l'efficacite thermique d'un four de reformage
PL3182003T3 (pl) * 2015-12-15 2021-10-25 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Urządzenie do procesu endotermicznego z ulepszonym układem palników
US11117110B2 (en) * 2016-02-04 2021-09-14 Technip France Method for reducing temperature spread in reformer
ES2738389T3 (es) * 2016-08-02 2020-01-22 Air Liquide Aparato para proceso endotérmico con disposición mejorada de los tubos
RU2750041C2 (ru) * 2016-10-25 2021-06-21 Текнип Франс Катализаторная трубка для риформинга
KR20180078364A (ko) * 2016-12-29 2018-07-10 주식회사 효성 파이어 히터
US11686471B2 (en) 2017-06-14 2023-06-27 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Apparatus for endothermic process with improved outer burners arrangement
US11806705B2 (en) 2018-06-28 2023-11-07 Haldor Topsøe A/S Catalytic reactor comprising metal radiation surfaces
EP3647658B1 (en) 2018-11-01 2021-04-14 L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude Furnace for endothermic process and process for operating a furnace with improved burner arrangement
EP3990164A1 (en) 2019-06-28 2022-05-04 Technip Energies France Method of loading a tubular reactor with a catalyst tube assembly, and a catalyst tube assembly for a tubular reactor
EP3816513B1 (en) * 2019-10-28 2022-06-22 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method for improving the homogenization of the temperatures in a steam methane reformer by adjusting the power distribution
US11110424B2 (en) * 2019-11-18 2021-09-07 Praxair Technology, Inc. Reformer box with reformer tunnel including tunnel port
ES2998583T3 (en) * 2019-12-19 2025-02-20 Air Liquide Reformer furnace and its use for steam reforming
CN113847821B (zh) * 2020-06-28 2023-10-17 宝山钢铁股份有限公司 一种加热炉烧嘴的脉冲控制方法及脉冲炉的炉温控制方法
WO2022106058A1 (en) * 2020-11-19 2022-05-27 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Reforming reactor comprising reformer tubes with enlarged outer surface area and structured catalyst
DE102020214918A1 (de) * 2020-11-27 2022-06-02 Thyssenkrupp Ag Verfahren zur Minimierung der Stickoxidemission einer Dampfreformierungsanlage sowie Dampfreformierungsanlage dafür
FR3137847B1 (fr) 2022-07-18 2026-05-08 Air Liquide Four pour mettre en œuvre un procédé endothermique
US12583743B2 (en) * 2022-09-23 2026-03-24 Praxair Technology, Inc. Method for carbon formation free operation of reformers

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1078193A1 (ru) * 1968-02-26 1984-03-07 Kucherov Aleksandr S Парогенератор
JPH05332509A (ja) * 1992-05-29 1993-12-14 Kuwahara Seisakusho:Kk 炉内排ガス循環型低ｎｏｘバーナ
RU2135891C1 (ru) * 1997-12-23 1999-08-27 Дзержинская ТЭЦ АО "Нижновэнерго" Топка
DE10333854A1 (de) 2003-07-24 2005-02-17 Uhde Gmbh Röhrenspaltofen
DE10357064A1 (de) 2003-12-04 2005-07-07 Uhde Gmbh Syntheseofen
KR100590401B1 (ko) * 2004-03-15 2006-06-19 주식회사 경동세라텍 팽창퍼라이트 소성로
US7686611B2 (en) * 2005-11-03 2010-03-30 Air Products And Chemicals, Inc. Flame straightening in a furnace
MY160806A (en) * 2009-06-24 2017-03-31 Thyssenkrupp Uhde Gmbh Primary reformer for reduced nitric oxide formation
US8545213B2 (en) 2010-03-09 2013-10-01 Air Products And Chemicals, Inc. Reformer and method of operating the reformer

Also Published As

Publication number Publication date
MY181002A (en) 2020-12-15
KR20150054766A (ko) 2015-05-20
CN104620050A (zh) 2015-05-13
US20150217250A1 (en) 2015-08-06
WO2014040815A1 (en) 2014-03-20
SA515360132B1 (ar) 2017-02-22
CA2880132A1 (en) 2014-03-20
RU2643734C2 (ru) 2018-02-05
MX2015003184A (es) 2015-09-25
ES2642139T3 (es) 2017-11-15
BR112015004134A2 (pt) 2017-07-04
EP2708812A1 (en) 2014-03-19
US9533275B2 (en) 2017-01-03
IN2015MN00126A (enExample) 2015-10-16
MX356160B (es) 2018-05-16
PL2708812T3 (pl) 2017-12-29
CN104620050B (zh) 2017-06-13
BR112015004134B1 (pt) 2021-05-04
EP2708812B1 (en) 2017-08-02
ZA201500563B (en) 2016-10-26
KR102158887B1 (ko) 2020-09-22
RU2015113308A (ru) 2016-11-10

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