KR102139538B1 - Hair shampoo compositions - Google Patents

Abstract

The present invention relates to a hair shampoo composition. According to the present invention, the hair shampoo composition comprises: 10 to 15 parts by weight of a shungite extract; 4 to 8 parts by weight of a fermented horseradish liquid; 3 to 7 parts by weight of an inorganic extract; 1 to 5 parts by weight of tea tree oil; 0.2 to 0.6 parts by weight of cystamine dimaleate; and 3 to 7 parts by weight of a Houttuynia cordata extract. According to the present invention, the hair shampoo composition reinforces fiber tissue inside a user′s hair to restore healthy hair, soothes the scalp and mitigates dermatitis to enhance health of the scalp.

Description

Hair shampoo composition {HAIR SHAMPOO COMPOSITIONS}

The present invention relates to a hair shampoo composition, and more specifically, by constructing a shampoo composition including natural ingredients, strengthens the internal fiber tissue of the hair to restore healthy hair, soothes the scalp, relieves skin inflammation, and improves scalp health. It relates to a hair shampoo composition that can be improved.

In general, the scalp of the human body is stained by sweat and sebum caused by metabolism. In addition, in modern industrialized society, the hair is more unclean and the appearance is not good due to dust and external stimuli caused by various pollution. Therefore, if your hair gets dirty, it is inevitable to regularly shampoo regularly. In particular, in the modern society where the standard of living has improved, unlike before, it became a habit to shampoo almost every day.

Shampoo is used to decontaminate the scalp and hair and keep the hair clean and beautiful. In addition to the purpose of cleaning, ease of combing, softness, smoothness, shine and friction reduction on the surface of the hair, prevention of static electricity, protection of hair, etc. It is used for additional purposes.

Hair is damaged by various external factors such as shampoo, drying, styling, and the surrounding environment. Also, when washing with shampoo, the hair remains dry or rough and shiny due to excessive friction of the scalp or removal of natural moisturizing ingredients. Is done.

Hair is composed of cuticle, cortex and medula, of which cortex occupies more than 80%, showing a great influence on the properties of hair. The cortex is divided into a crystalline region and an amorphous region, and is a fibrous layer composed of fibrous keratin proteins, and its physical and chemical properties are determined according to the manner in which keratin molecules are combined or the amount of sulfur (S) contained is small and large.

At this time, hard keratin, which is a fibrous tissue, forms a crystalline region, and an interstitial substance is located between the fibrous tissues as an amorphous region. This layer of insecticide consists of soft keratin and lipids, that is, cholesterol and its derivatives, fatty alcohols, fatty acids, ceramides, etc., and a small amount of phospholipid, And polysaccharides.

It is known that this part is largely lost in damaged hair, because the amorphous region made of insecticide is more susceptible to various stimuli than the part that is tightly bound to the fibrous material, and thus is easily lost.

Therefore, it is important to fundamentally protect or restore these amorphous regions in hair conditioning such as softness, flexibility, gloss, antistatic, and ease of combing of hair.

In order to improve this problem, fats and oils such as alcohol, glyceride, and paraffin have been used, but they act as a cause of re-pollution by imparting excessive lubricity to the hair, and it is also difficult to maintain a visually transparent shape. There is this.

Therefore, there is a need to develop a shampoo composition that can protect the scalp and hair and effectively maintain the conditioning feeling of the hair, thereby strengthening the internal fiber tissue of the hair to restore healthy hair.

Domestic registered patent No. 10-1033307 (registered on April 28, 2011) Domestic registered patent No. 10-0657380 (registered on December 07, 2006) Domestic registered patent No. 10-2052262 (registered on November 28, 2019)

The present invention is to provide a hair shampoo composition capable of improving the scalp health by constituting the shampoo composition containing natural ingredients, strengthening the internal fiber tissue of the hair to restore healthy hair, soothe the scalp and relieve skin inflammation. .

The various problems to be solved by the present invention are not limited to the problems mentioned above, and other problems not mentioned will be clearly understood by those skilled in the art from the following description.

The hair shampoo composition according to the present invention includes 10 to 15 parts by weight of pure Jjit extract, 4 to 8 parts by weight of horseradish fermentation solution, 3 to 7 parts by weight of inorganic extract, 1 to 5 parts by weight of tea tree oil, cystamine dimaleate (Cystamine dimaleate) 0.2 to 0.6 parts by weight and 3 to 7 parts by weight of Eoseongcho extract.

In addition to the pure water extract, horseradish fermentation liquid, inorganic extract, tea tree oil, cystamine dimaleate and fish vinegar extract, mineral water, amino acid surfactant (Sodium N-(2-Dodecyl Succinoyl) l-Glutamate), amphoteric surfactant (Cocobetainamido amphopropionate), nonionic surfactant (decyl glucoside), nonionic surfactant (coco-glucoside), lauric acid, myristylic acid ( Myristic Acid, Citric Acid, Glycerin, Tocopheryl acetate, Hydroxyethyl Cellulose, Panthenyl Triacetate, Persea Giratissima (Avocado) Oil , Placental protein, Pantothenic acid, Biotin, Vividin, Methionine, Allantion, Cetyl alcohol, Vites Trifolia Fruit Extract, Rehmannia Chinensis Extract, Thuja Orientalis Root Extract, Morus Alba Bark Extract, Pineus sylvestris bark Extract, Cimicifuga racemosa root Extract, Chlorella Extract, Dietary Sulfur (Methyl sulfonylmethane), Brewer's yeast Extract and Mandarin Extract (Citrus nobilis (Mandarin Oran) ge) fruit Extract).

The inorganic extract is 5 to 10 parts by weight of mica extract, 1 to 5 parts by weight of biotite extract, 3 to 7 parts by weight of ocher stone extract, 2 to 6 parts by weight of diatomaceous earth extract, 3 to 7 parts by weight of jade extract and 4 to 8 parts of illite extract It may be included in a weight ratio of parts by weight.

The inorganic extract, after preparing the mica, biotite, ocher stone, diatomaceous earth, jade and illite, pulverize the mica, biotite, ocher stone, diatomaceous earth, jade and illite, and pulverized the mica, biotite, ocher, diatomaceous earth, jade, and Heat treatment by heating the illite at a temperature of 1500 to 1700°C for 50 to 100 minutes, and washing the heated muscovite, biotite, ocher stone, diatomaceous earth, jade and illite with purified water at 50 to 60°C to obtain the biotite, biotite, After removing combustion residues generated during heat treatment attached to the surface of ocher stone, diatomaceous earth, jade, and illite, the temperature of 60 to 65° C. for 100 parts by weight of the washed silk, biotite, ocher, diatomaceous earth, jade, and illite After mixing 300 to 500 parts by weight of purified water, aged by sealing and storing for 3 to 6 days, aged mica, biotite, ocher stone, diatomaceous earth, jade, illite and purified water from a mixture of mica, biotite, ocher stone, diatomaceous earth , After removing and removing jade and illite, by centrifuging the purified water, the lower layer solution in which fine particles of sericite, biotite, ocher stone, diatomaceous earth, jade and illite are located, and the middle layer solution located above the lower layer solution and It can be separated by locational separation into the supernatant, and after separating the supernatant and the supernatant of the centrifuged purified water, heated to a heat source at a temperature of 150 to 170°C to remove moisture.

Specific details of other embodiments are included in the detailed description.

The hair shampoo composition according to the present invention can improve the scalp health by strengthening the internal fiber tissue of the hair to restore healthy hair, soothe the scalp and relieve skin inflammation.

It will be fully understood that embodiments of the technical idea of the present invention can provide various effects not specifically mentioned.

1A, 2A, and 3A are photographs showing the condition of the scalp before a subject uses the shampoo composition prepared according to Example 1.
1B, 2B, and 3B are photographs showing the condition of the scalp after a subject uses the shampoo composition prepared according to Example 1 once a day for 4 months.
4, 5, and 6 are before the subject uses the shampoo composition prepared according to Example 1 (left photograph in FIGS. 4, 5, and 6), and the shampoo composition prepared by the subject according to Example 1 It is a photograph showing the hair condition after using for 5 months once a day (pictures on the right in FIGS. 4, 5, and 6).

Advantages and features of the present invention, and methods for achieving them will be clarified with reference to embodiments described below in detail. However, the present invention is not limited to the embodiments described herein and may be embodied in other forms. Rather, the embodiments introduced herein are provided to ensure that the disclosed contents are thorough and complete and that the spirit of the present invention is sufficiently conveyed to those skilled in the art.

The terms used in this application are only used to describe specific embodiments, and are not intended to limit the present invention. Singular expressions include plural expressions unless the context clearly indicates otherwise.

Unless defined otherwise, all terms used herein, including technical or scientific terms, have the same meaning as commonly understood by a person skilled in the art to which the present invention pertains. Terms such as those defined in a commonly used dictionary should be interpreted as having meanings consistent with meanings in the context of related technologies, and should not be interpreted as ideal or excessively formal meanings unless explicitly defined in the present application. Does not.

Hereinafter, the hair shampoo composition according to the present invention will be described in more detail with reference to the accompanying drawings.

The hair shampoo composition according to the present invention may include as an active ingredient a pure water extract, horseradish fermentation liquid, inorganic extract, tea tree oil, cystamine dimaleate, and eoseongcho extract.

In addition, the hair shampoo composition according to the present invention is 10 to 15 parts by weight of pure water extract, 4 to 8 parts by weight of horseradish fermentation solution, 3 to 7 parts by weight of inorganic extract, 1 to 5 parts by weight of tea tree oil, cystamine dimaleate (Cystamine dimaleate) 0.2 to 0.6 parts by weight and eoseongcho extract 3 to 7 parts by weight may be included in a weight ratio.

In addition, the hair shampoo composition according to the present invention, in addition to the pure water extract, horseradish fermentation liquid, inorganic extract, tea tree oil, cystamine dimaleate and eoseongcho extract, thickener, surfactant, viscosity modifier, moisturizer, A conventional composition used when preparing a shampoo, such as a pH adjusting agent and a solvent, may be further included.

For example, the hair shampoo composition according to the present invention, in addition to the above pure water extract, horseradish fermentation liquid, inorganic extract, zinc gluconate, cystamine dimaleate and fish vinegar extract, mineral water (mineral water) water), amino acid surfactant (Sodium N-(2-Dodecyl Succinoyl)l-Glutamate), amphoteric surfactant (Cocobetainamido amphopropionate), nonionic surfactant (decyl glucoside), nonionic surfactant (cocoglucoside; Coco-Glucoside, Lauric Acid, Myristic Acid, Citric Acid, Glycerin, Tocopheryl acetate, Hydroxyethyl Cellulose, Panthenyl Tri Acetyl Triacetate, Persea Giratissima (Avocado) Oil, Placental Protein, Pantothenic Acid, Biotin, Vividin, Methionine, Allantoin , Cetyl alcohol, Vites Trifolia Fruit Extract, Rehmannia Chinensis Extract, Thuja Orientalis Root Extract, Morus Alba Bark Extract, Pine Bark Extract (Pinus sylvestris bark Extract), Cimicifuga racemosa root Extract, Chlorella Extract, Methyl sulfonylmethane, Brewer's yeast Extract ) And mandarin extract (Citrus nobilis (Mandarin Orange) fruit Extract).

Among the above compositions, citric acid is used as a pH adjusting agent, tocopheryl acetate is used as an antioxidant as vitamin E, Hydroxyethyl Cellulose is used as a thickener, and panthenyl triacetate ) Acts as a hair conditioning agent, antistatic agent, active ingredient, and therapeutic agent, and Persea Giratissima (Avocado) Oil can exert a skin soothing effect.

In addition, the placental protein (Placental protein) is an amino acid that helps to prevent hair loss and activate cells, and pantothenic acid helps to repair damaged hair and prevent hair loss, and Biotin supplies nutrition to hair. , Vividin helps to prevent hair loss, allantoin helps to soothe skin, activates cells, and cetyl alcohol can act as a water-soluble thickener.

The shunite extract may be an extract prepared using shungite. The shunite is a material mainly composed of SiO ₂ (silicate) and C ₆₀ (fullerene), which contains natural fullerene. Means a substance. A pure sheet containing 90% or more of fullerene is called Elite shungite or a Noble Shungite, and a pure sheet containing 60% or less of fullerene is called Normal shungite.

Representative functions of the sunjit are antioxidant function, electromagnetic wave shielding function, pollutant purification and decomposition function, and sterilization and antibacterial function. SunJit is a powerful natural antioxidant that enhances human immunity to numerous diseases, adsorbs pollutants, purifies water and air, and has the ability to self-decompose adsorbed pollutants.

In addition, the pure sheet has antibacterial and sterilizing properties, and thus has a function of removing more than 99% of E. coli, Pseudomonas aeruginosa, Staphylococcus aureus, and harmful bacteria, and blocks harmful electromagnetic waves and emits a large amount of far infrared rays.

In the present invention, the sunjit extract may be used as the sunjit extract prepared as follows.

First, after preparing a pure sheet mineral, it can be pulverized using a ball milling device.

In the above step, the particle size of the pure zigzag mineral may be pulverized to have a range of 10 to 300 µm. When the pulverized pure zircite mineral has a particle diameter of 10 µm or less, the pulverization time is delayed and work is performed by dust or fine powder. A problem of poor sex may occur, and when it exceeds 300 μm, a problem that the active ingredients contained in the pulverized pure sulphate mineral may not be easily extracted in a later process.

Next, the pulverized pure sheet may be heated to heat treatment.

In the above step, the impurities remaining in the crushed pure paper may be removed by heating the crushed pure paper to heat, and the heat treatment of the crushed pure paper may be performed for 1 to 20 minutes at a temperature of 1200 to 1600°C. Can.

When the heat treatment in the step is performed at a temperature of 1200°C or less than 1 minute, a problem that impurities remaining in the pulverized pure paper may not be sufficiently removed, and when the temperature exceeds 1600°C or 20 minutes. Problems may arise where it is difficult to expect further increase in effectiveness.

Next, after washing the heat-treated sunjit to remove the combustion residue adhered to the surface of the sunjit, the washed sunjit and baked salt solution may be mixed and aged.

Washing of the pure heat treated in the step may wash the surface of the heat treated pure paper using distilled water or purified water, for example, washing of the heat treated pure paper with purified water of 30 to 50 ℃ This can be done by washing the surface of the heat treated pure sheet.

In addition, in the above step, after mixing in a weight ratio of 500 to 1000 parts by weight of the roasted salt solution at a concentration of 5 to 7% by weight based on 100 parts by weight of the total content of the washed pure paper, 3 to 7 days at a temperature of 60 to 70°C By storing and aging for a while, the active ingredients contained in the pure sheet can be sufficiently leached.

Subsequently, the pure salt immersed in the baked salt solution is separated and removed, and then the baked salt solution in which the active component of the pure salt is leached can be centrifuged.

In the above step, in the baked salt solution from which the pure paper is removed, active ingredients of pure paper are leached. By centrifuging the baked salt solution in which the active ingredients of the pure paper are leached, lower-layer baked salt in which the pure paper particles are located The solution may be divided into locations, separated by a middle layer baked salt solution and an upper layer baked salt solution located above the lower layer baked salt solution.

Next, by heating the centrifuged middle layer and the upper layer of the salt solution to remove moisture can be prepared a pure sujit extract.

In the above step, after separating the centrifuged middle layer and the upper layer baked salt solution, heating to a temperature of 110 to 130° C. to remove moisture, thereby producing a pure gel extract of gel form formed by leaching the active ingredients of SunJit. have.

The horseradish fermentation broth may be prepared using wasabi, and the horseradish fermentation broth may be used in the following manufacturing method.

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To prepare the wasabi fermentation broth, first, wasabi was prepared and then washed clean in water.

The horseradish (Wasabia koreana, Wasabia japonica) is an evergreen, perennial ripened semi-perennial plant belonging to the cruciferaceae family, sinigrin, allylisothiocyanate, vitamin C, vitamin C, glucose, It contains KHSO ₄ and is known to be a material that can be used for anti-corruption, antibacterial and edible spices.

Next, the washed horseradish can be steamed.

In the above step, the steaming may be performed by steaming the washed horseradish for 10 minutes to 60 minutes with water vapor. If steaming of the horseradish is performed below the above-mentioned lower limit, sufficient steaming is not achieved. In this case, when it is performed in excess of the above-described upper limit range, a difference in effect according to an increase in steaming time may be insignificant.

Next, the steamed horseradish may be washed with any one or more acids of acetic acid or citric acid, and the washing of the steamed wasabi was washed with any one or more acids of acetic acid or citric acid. By doing so, there is an effect of improving flavor, color, and the like of the wasabi fermentation liquid.

Subsequently, the washed horseradish may be sprayed with a culture medium and a culture medium consisting of lactic acid bacteria.

As the lactic acid bacteria, any one or more known lactic acid bacteria selected from the group consisting of Lactobacillales , Streptococcus thermophiles , and Bifidobacterium longum can be used, and the culture solution is peptone. , Malt extract, sodium citrate, potassium phosphate dibasic, glucose and distilled water, the culture solution is 20 to 30 parts by weight of peptone, 10 to 20 parts of malt extract Weight parts, 1 to 2 parts by weight of sodium citrate, 0.1 to 0.3 parts by weight of potassium diphosphate, 1.5 to 3.5 parts by weight of glucose and 100 to 200 parts by weight of distilled water may be mixed.

In the lactic acid bacteria culture solution, the peptone is a nitrogen source that supplies proteins, and supplies proteins necessary for the growth of microorganisms, and the malt extract contains various minerals, vitamin B groups, and amino acids, which can help with microorganism growth, and citric acid Sodium is a mineral that regulates the pH of the culture medium to maintain an optimized state for the growth of microorganisms, and can supply nutrients, and the glucose can function as an important component that lactic acid bacteria metabolize sugars to produce organic acids.

Subsequently, the lactic acid bacteria fermentation broth may be prepared by fermenting horseradish sprayed with the lactic acid bacteria culture solution.

The lactic acid bacteria fermentation broth may be prepared by storing horseradish sprayed with the lactic acid bacteria culture solution in a storage container maintaining a temperature of 50 to 55°C and a humidity of 55 to 60% for 1 to 3 days.

Next, a mixed solution may be prepared by mixing the deep seawater solution with wasabi on which the lactic acid bacteria culture solution was sprayed, wherein the mixed solution is 50 to 150 wt. It can be prepared by mixing in parts by weight.

Next, after fermenting the mixed solution in a container at a temperature of 20 to 30° C. for 2 to 6 days, fermentation of wasabi can be prepared by separating only the supernatant of the mixed solution stored in the container.

In addition, the deep ocean water solution may be a deep ocean water solution prepared by the following manufacturing method.

First, deep ocean water can be prepared, and the deep ocean water is usually referred to as deep ocean water having a depth of 200 m or less, and unlike surface ocean water, plankton and living organisms multiply because sunlight does not reach. Because it does not have high concentration of nutrient salts and there is no contaminant present in the surface seawater because it is not mixed with the surface seawater due to the density difference according to the water temperature, low temperature stability, contaminants, harmful bacteria or organic matter are very low compared to the surface seawater. Small cleanliness, mineral balance characteristics that are rich in inorganic nutrients rich in eutrophication and various mineral components, which are very important for plant growth, and small group of water molecules cluster over a long period of time under high pressure and low temperature It has characteristics such as aging, which is aged with water with good surface permeability and low surface tension.

In particular, salt containing a large amount of mineral components produced in deep sea water contains various mineral components such as calcium (Ca), magnesium (Mg), iron (Fe), and zinc (Zn) necessary for the growth of basophilic fermenting microorganisms. Containing, in particular, the concentration of nutrient salts such as nitrate, phosphate, and silicate is high because the organism does not live at low temperature without sunlight, and does not contain contaminants because it is not mixed at all with the density difference from contaminated surface seawater. There is this.

Next, the water of the deep ocean water can be evaporated.

The evaporation of the water in the deep ocean water can be performed until the deep ocean water is naturally dried by leaving the deep ocean water at a temperature of 20 to 35° C., until 5/5 to 3/5 of the mass of the deep ocean water is evaporated. It is possible to reduce the cost by evaporating the moisture contained in and to easily increase the salinity of the deep ocean water.

Subsequently, the deep-water of the evaporated water can be frozen to crystallize.

In the above step, after the deep water of the evaporated water is introduced into the freeze-concentration device, the temperature of the freeze-concentration device is lowered to freeze the temperature of the deep-sea water to form an ice crystal.

In the above step, as the temperature of the freeze-concentrating device is lowered, the deep ocean water contained in the freeze-concentration device may be partially frozen. The deep-sea water received in the freeze-concentration device is in direct contact with the inside of the freeze-concentration device. The pure water component may be frozen around the outer circumferential surface or crystal nuclei formed in the deep ocean water to form ice particles with large particles.

In the step, the internal temperature of the freeze-concentration device containing the deep ocean water is maintained at a temperature of -12 to -10°C for 10 to 20 hours, until 10 to 20% by weight of the initial weight of the filtered seawater is frozen. Can proceed.

Subsequently, the ice crystals formed in the frozen deep ocean water may be removed.

In the above step, by removing the ice crystals in which pure water (solvent) components are frozen, deep ocean water having a high salt concentration can be prepared.

Next, after re-injecting the deep sea water from which the ice crystal has been removed into the freeze concentrator, the temperature of the freeze concentration device is lowered to recrystallize the deep sea water from which the ice crystal is removed to recrystallize to form an ice crystal. .

In the above step, the internal temperature of the freeze-concentration device in which the deep sea water from which the ice crystal is removed is accommodated is maintained at a temperature of -15 to -13°C for 10 to 30 hours, and the deep sea water from which the ice crystal is removed can be re-frozen.

In the above step, as the temperature of the freeze-concentrating device is lowered, the deep-sea water contained in the freeze-concentration device may be partially frozen once again. Pure water components may be frozen around the outer circumferential surface in direct contact or the crystal nuclei formed in the deep ocean water to form ice crystals with large particles.

Next, the highly frozen marine deep water solution can be prepared by separating and removing the re-frozen ice crystals.

In the above step, once the ice crystals are removed from the re-consolidated deep ocean water once again, a high salinity deep ocean water solution can be prepared. For example, the salinity of the deep ocean water solution after the above process is 10 to 13%. It can be done.

The inorganic extract may be an extract prepared by using a material having far-infrared radiation, antibacterial effect, etc., wherein the inorganic extract is an inorganic extract consisting of silkworm extract, biotite extract, ocher stone extract, diatomaceous earth extract, jade extract and illite extract Can be used.

In addition, the inorganic extract is 5 to 10 parts by weight of the mica extract, 1 to 5 parts by weight of the biotite extract, 3 to 7 parts by weight of the loess stone extract, 2 to 6 parts by weight of the diatomaceous earth extract, 3 to 7 parts by weight of the jade extract and 4 of the illite extract It may be included in a weight ratio of 8 to 8 parts by weight, preferably, the inorganic extract is 8 parts by weight of mica extract, 3 parts by weight of biotite extract, 5 parts by weight of ocher stone extract, 4 parts by weight of diatomaceous earth extract, 5 parts by weight of jade extract and illite It may be included in a weight ratio of 6 parts by weight of the extract.

The silkworm extract can be extracted from the silkworm, which is also called sericite, belongs to the monoclinic system, and has a white or grayish-white pearl luster. Originally referred to as the main component mineral of crystalline schist, especially sericite schist, today it refers to a fine muscovite shaped like clay produced by hydrothermal action. The chemical composition is almost the same as that of muscovite, but in general potassium (K) is less than muscovite and the moisture H ₂ O is somewhat higher. It is produced as a secondary metamorphic material such as feldspar, cordierite, and red stone, and is the most common constituent mineral of phyllite or phyllite, which has undergone light power metamorphism. Doseok (陶石) is caused by the deterioration of volcanic rocks, and consists of quartz (70%) and sericite (30%). The serpentine is used as a material for mixing ceramics and refractory bricks, and has a variety of other uses such as paints, electrical insulators, lubricating materials, and cosmetics.

The biotite extract may be extracted from biotite. The biotite is a mineral belonging to a monoclinic system and has a chemical composition of K(Mg, Fe) ₃ (OH) ₂ AlSi ₃ O ₁₂ . When forming a plate or impression (鱗狀), it often represents a hexagonal or rhombohedral. The cleavage is complete on the underside, and the flakes have elasticity and are small compared to the mica. It has black, brown, green, etc. , The split surface has pearl luster, and sometimes has a metallic luster, the hardness is 25 to 30, and the specific gravity is 27 to 31. The distribution is very wide and is produced in many igneous and metamorphic rocks, and is rarely calculated in sedimentary rocks. It is known that huge biotite crystals can be obtained.

The biotite purifies the soil and facilitates the supply of oxygen by ion exchange, thereby activating crop growth, enhancing the vitality of the soil, preventing acidification of the soil, and adsorbing harmful gases to prevent soil contamination, and excellent purification ability It has the property of neutralizing acidified land.

The loess stone extract can be extracted from loess stone, the far infrared rays from the loess penetrate deep into the subcutaneous layer 80 times deeper than normal heat and shake the cells finely 2,000 times per minute to make the cell tissue vital activity more vigorous. And promotes blood circulation, discharges waste and heavy metals from the body and prevents stress, adult diseases, and gynecological diseases. Natural ocher stone is porous and breathes, so it has excellent humidity control ability and excellent antibacterial performance. Cool and warm in winter.

Ocher stone is a natural stone that retains the ancient primitive nature formed by high pressure after being deposited for more than 300 million years, and is a natural ocher stone that has little impurities such as heavy metals, not calcined or processed soil. Ocher stone has good far-infrared emissivity and is good for health. Excellent deodorizing effect and antibacterial. It has excellent anti-mildew performance, and is particularly porous sedimentary rock, so it has excellent humidity control ability, and ordinary stone is cold, so if it sits directly on the floor, cold air invades, but natural ocher stone has the components of loess, so it has the effect of blocking cold air. .

The diatomaceous earth extract may be extracted from the diatomaceous earth, and the diatomaceous earth (硅藻土) is a collection of fossil soils in which the debris of a single-celled plant is deposited on the seabed or on the bottom.

The diatomaceous earth has the ability to extract its silica from the aquatic environment to construct its own solid skeletal structure. Most of the diatomaceous earth sedimentary rocks formed by hardening of sediment of the diatom skeleton are made of hydrous amorphous silica, and the particle size is It shows 3-10㎛, oil absorption 18-25cc/g, specific surface area 400-600m ² /g. Although it has similar properties to general mineral silica, diatomaceous earth is a type in which various shapes, such as plate shape, needle shape, and spherical shape, are mixed, while mineral silica has a spherical shape. Because of this, the malleability is relatively inferior, but it maintains high oil absorption and improves skin adhesion and alleviates powderiness.

The jade extract may be extracted from jade, and the jade functions to soften and soften the skin texture and effectively deliver nutrients to the skin, thereby improving a moisturizing effect. Jade is divided into jadeite and purgatory, and jadeite is a lead pyrite mineral belonging to the Huiseok family, and is a monoclinic material composed of silicate, aluminum oxide, and soda. Hardness is a dense lump like crystal, and light is black, cyan, green, transparent or translucent, and jade is commonly referred to as jadeite.

Purgatory is an inosilicate monoclinic whisperite mineral that is divided into purgatory and serpentine superbasic purgatory among high-grade surrogate rocks, and their quality is a fine structure with a fine structure, that is, open-cut summit-positive crystals are composed of quick-drying and fiber. It is determined to a degree, and it is known that the finer the fiber, the better the quality.

The illite extract may be extracted from illite, which is defined as a porous mica mineral as a representative natural clay mineral, and has a flexibility and elasticity due to its sheer structure and has elasticity and elasticity. It has superior properties to other adsorbents.

The main components of illite mineral are 57.5% of silicon oxide (SiO ₂ ), which removes waste and fruit sebum in the pores, 23.3% of aluminum oxide (Al ₂ O ₃ ), which promotes blood circulation, and collagen binding action. Iron oxide (Fe ₂ O ₃ ) 6.76%, calcium oxide (C ₂ O) 0.1%, sodium oxide (Na ₂ O) to provide osmotic pressure regulation and moisture control, It contains 0.38% of magnesium oxide (MgO), 6.43% of potassium oxide (K ₂ O), 4.32% of titanium dioxide (TiO ₂ ), MnO, Li, Cr, Zn, Sr, etc. Is adsorbed and has negative ions, causing flocculation and precipitation by floating neutralization of cations and electrical neutralization, and it has excellent water purification, adsorption/decomposition ability for certain radioactive materials, and various heavy metals and toxic gases in water/soil/atmosphere Desorbs deodorizes, activates cells, enhances immunity, releases a large amount of dissolved oxygen in water, activates water molecules, generates a large amount of anions in illite itself, and produces 93% of far infrared rays at 40°C. It is known to be excellent in adhesion by spinning, adsorbing and decomposing various heavy metals/organic substances/toxic substances on the skin, bacteriostatic action of viruses/bacteria/fungi, etc.

For the inorganic extract, for example, an inorganic extract prepared by the following method may be used.

First, after preparing the mica, biotite, ocher stone, diatomaceous earth, jade and illite, the mica, biotite, ocher stone, diatomaceous earth, jade and illite can be crushed to a certain particle size.

In this step, the mica, biotite, ocher, diatomaceous earth, jade, and illite may be pulverized using a known grinder such as a ball milling device.

Next, the crushed silk, biotite, ocher, diatomaceous earth, jade and illite may be heated to heat treatment.

In the step, impurities and residual organic matter contained in the mica, biotite, ocher, diatomaceous earth, jade and illite may be removed by heating the crushed silk, biotite, ocher, diatomaceous earth, jade and illite. Heating of the mica, biotite, ocher, diatomaceous earth, jade and illite may be carried out at a temperature of 1500 to 1700°C for 50 to 100 minutes.

Next, the heated muscovite, biotite, ocher, diatomaceous earth, jade and illite are washed to remove combustion residues generated during heat treatment attached to the surface of the mica, biotite, diatomaceous earth, jade and illite. Thereafter, the washed silkworm mica, biotite, ocher stone, diatomaceous earth, jade, and illite may be aged by dipping them in purified water.

In the step, washing of the muscovite, biotite, ocher stone, diatomaceous earth, jade, and illite may be performed by washing the surfaces of the mica, biotite, ocher, diatomaceous earth, jade, and illite with purified water at 50 to 60° C. After aging of the biotite, ocher stone, diatomaceous earth, jade and illite, after mixing 300 to 500 parts by weight of purified water at a temperature of 60 to 65° C. for 100 parts by weight of the washed mica, biotite, ocher, diatomaceous earth, jade and illite, This can be done by sealing and storing for 3-6 days.

Subsequently, after separating and removing the silkworm, biotite, diatomaceous earth, diatomaceous earth, jade, and illite from a mixture of the aged silkworm, biotite, ocher, diatomaceous earth, jade, illite and purified water, the purified water may be centrifuged.

In the above step, the purified water contains active ingredients of mica, biotite, ocher, diatomaceous earth, jade, and illite, and by centrifuging the purified water, fine particles of silk, biotite, ocher, diatomaceous earth, jade, and illite are located. It can be separated into the lower layer liquid, and the middle layer liquid and the upper layer liquid located on top of the lower layer liquid.

Next, after separating the supernatant and the supernatant of the centrifuged purified water, by heating the supernatant and supernatant, mica extract, biotite extract, ocher stone extract, diatomaceous earth extract, jade extract and inorganic extract consisting of illite extract Can be produced.

In the above step, after separating the supernatant and the supernatant of the centrifuged purified water, by heating with a heat source at a temperature of 150 to 170°C to remove moisture, mica extract, biotite extract, ocher stone extract, diatomaceous earth extract, jade extract and illite An inorganic extract composed of an extract can be prepared.

The teatree oil is used as a skin conditioning agent, and is effective in inflammatory acne due to its antiviral properties. In addition, the zinc gluconate is effective in calming irritated scalp and relieving itching of the skin.

The cystamine dimaleate exhibits the following characteristics, wherein the cystamine dimaleate provides disulfide-binding material of damaged hair due to frequent dyeing, discoloration, and perm treatment, thereby providing hair. Can prevent damage and strengthen the internal fiber tissue of hair to restore healthy hair.

That is, in general, due to frequent dyeing, discoloration, and perm treatment, the disulfide bond (-SS-) of the hair is cut to damage the hair, and the thiol (-SH) residue increases in the damaged hair. The cystamine dimaleate may restore damaged hair by restoring disulfide bonds of damaged hair as described above.

Cystamine dimaleate

(1) Chemical formula: C ₁₂ H ₂₀ N ₂ O ₈ S ₂ (MW=384.43)

(2) Appearance: Light yellow crystalline powder

(3) Structural formula:

Cystamine dimaleate damage hair restoration principle

The Eoseongcho extract is prepared by extracting Eoseongcho, and Eoseongcho (Houttuynia cordata thunb) is an outpost of medicinal wheat, a plant of the saururaceae family, and inhabits Southeast Asia, particularly Japan and Korea. Said Eoseongcho is also called ten pills because it has ten medicinal effects, and the stem is like sweet potato leaves, and when it touches raw leaves, fishy fishy is derived from the bad smell and is sometimes called Eoseongcho. Eoseongcho is also available for medicinal and edible purposes, and is classified as an animal or plant that can use only the minimum amount as a subsidiary ingredient in food ingredients classification before food, and is widely known as having strong, diuretic, antibacterial, detoxifying and anticancer effects. Is used as a cosmetic and health functional food that helps detoxification and beauty.

The Eoseongcho extract may be used as an Eoseongcho extract prepared by the following manufacturing method.

First, Eoseongcho can be prepared and washed.

Next, the washed Eoseongcho can be steamed.

In the above step, the steaming may be performed by heating the washed fish roots at a temperature of 130 to 150° C. and a pressure of 3 to 5 kgf/cm ² with water vapor for 10 to 30 minutes.

Next, the steamed eoseongcho can be dried.

In the above step, the drying is dried for 30 to 60 hours at a temperature of 18 to 22° C. and a humidity of 55 to 60% in order to prevent chlorophyll of the fish vinegar from being destroyed and useful components volatilized during sunlight drying. can do.

Subsequently, the dried Eoseongcho can be heated to agitate and then cooled. The agitation is first performed at a temperature of 75 to 80° C. for 1 to 5 minutes after the dried Eoseongcho is put into a heating container, and the 1 The second aerated eoseongcho may be subjected to secondary agitation for 10 to 50 seconds at a temperature of 120 to 140° C., and the second aerated eoseongcho may be cooled at a temperature of 35 to 45° C. for 1 to 3 hours.

Next, mineral and lactic acid bacteria culture solution may be sprayed on the cooled eoseongcho to inoculate.

In the above step, 1 to 3 parts by weight of minerals and 5 to 10 parts by weight of lactic acid bacteria culture solution may be inoculated by spraying 100 parts by weight of the cooled eoseongcho, and the mineral and lactic acid bacteria culture solution is included below the lower limit. In the case, a problem in which sufficient fermentation is not achieved in a later process may occur, and when it is included in an amount exceeding the above-described upper limit range, a problem in which physical properties of the fish vinegar may be deteriorated by excessive fermentation may occur.

In the above step, the mineral refers to a mineral that is absorbed by the fish in the process during fermentation of the fish, etc. in a later process, and is a mineral that is a nutritional substance that is required in a relatively small amount for growth, maintenance, and reproduction of the human body, and includes calcium, phosphorus, potassium, magnesium, and manganese. , Any one or more selected from the group consisting of iodine, selenium, molybdenum, and cobalt may be used.

In addition, the lactic acid bacteria in the step may use a lactic acid strain isolated from fermented food kimchi, specifically, as the lactic acid strain Lactobacillus curvatus ( Lactobacillus curvatus ) , Visella viridescens ( Weissella viridescens ) , Lactobacillus plantarum and Any one or more known lactic acid strains selected from the group consisting of Leuconostoc lactis can be used.

For example, in the above step, the pH of the medium is adjusted to 2.8 to 3.2 using 1.2N HCl to prepare a lactic acid bacteria culture solution from kimchi, and then the lactic acid strain is separated from the kimchi, and the separated lactic acid strain is MRS broth (Oxoid , England), and incubated at 37~39°C for 20 to 25 hours, diluted to 1×1.0 ⁸ to 5×1.0 ⁸ CFU/mL, and then centrifuged at 10,000 to 15,000 rpm for 10 to 15 minutes to supernatant. Lactobacillus by separating only the supernatant, filtering the supernatant with a 0.45 µm syringe filter, and diluting it by mixing in a weight ratio of 1,000 to 2,000 parts by weight of sterilized distilled water to 100 parts by weight of the filtered supernatant Culture medium can be prepared.

Next, Eoseongcho inoculated with the mineral and lactic acid bacteria culture may be fermented.

In the above step, after the temperature of 38 to 42° C. and the humidity of 60 to 62% are maintained, the fermented vinegar inoculated with the mineral and lactic acid bacteria culture solution can be fermented for 3 to 5 days. When it is performed below the range, there may be a problem that the eochocho is not sufficiently fermented, and when it is performed above the above-described upper limit, there may be a problem that the physical properties of the fermented eochocho are lowered.

Subsequently, the fermented Eoseongcho can be extracted to prepare Eoseongcho extract.

In the above step, for example, after mixing the fermented fish vinegar with a solvent to prepare a mixture, it is introduced into an ultrasonic extractor to add ultrasonic waves to the mixture, and the solids contained in the mixture are known as a sieve. Eoseongcho extract can be prepared by removing it using a strainer, etc. As the solvent, any one or more solvents selected from water or an alcohol having 1 to 4 carbon atoms (C1 to C4) may be used.

In addition, in the step, the ultrasonic waves applied to the mixture under a temperature of 18 to 20° C. and a pressure of 0.5 to 1.0 kgf/cm ² output 150 to 300 watts for 150 to 200 minutes at a vibration frequency of 50 to 80 KHz. Eoseongcho extract can be prepared by extraction using.

Hereinafter, examples and comparative examples for the hair shampoo composition according to the present invention will be described in more detail.

Shampoos were prepared using the shampoo compositions according to Examples 1, 2, 3 and Comparative Examples 1, 2 so that the components as shown in Table 1 below were included.

Ingredient (parts by weight) Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Sunjit extract 12 14 10 - - Wasabi fermentation broth 6 7 4 - 6 Inorganic extract 5 3 7 5 - Tea tree oil One One 2 3 4 Cystamine Dimaliate 0.4 0.5 0.6 - 0.5 Eoseongcho Extract 5 3 6 5 - Panthenyl Triacetate 3 4 3 3 3 Decyl Glucoside, Coco-Glucoside 50 55 50 50 50 Vividin One One One One One glycerin 10 8 8 8 10 Citric acid 2 2 3 2 2 Hicell One One 2 One 2 Cetyl alcohol 7 7 6 6 8 Allantoin 3 3 2 2 4 Tocopheryl acetate 2 2 3 2 3 Biotin 2 2 3 2 3 Methionine One One One One One Mineral water 30 30 30 30 30

1. Stability test

Stability tests of the hair shampoos prepared according to Examples 1, 2, and 3 were performed.

The observation period was the same for one week, and stability was observed at various temperatures, and the results are shown in [Table 2].

Temperature Example 1 Example 2 Example 3 0℃ Good Good Good 40℃ Good Good Good -20℃ Good Good Good

Referring to [Table 2], it was confirmed that the hair shampoos prepared according to Examples 1, 2, and 3 had good formulation stability.

2. Hair conditioning effect test (sensory evaluation)

Using the Sampu prepared according to Examples 1, 2, 3 and Comparative Examples 1 and 2, a product evaluation group consisting of 20 people aged 20 to 40 years was allowed to use for 1 week, and then 5 points on the questionnaire item (very bad, bad) , Normal, good, very good) The quality was evaluated through a questionnaire and the results are shown in [Table 3].

Survey items Example Comparative example One 2 3 One 2 Bubbles are rich and soft 4.5 4.6 4.5 3.1 3.2 Clean rinse 4.5 4.4 4.5 3.1 3.0 Easy to comb when semi-drying 4.3 4.2 4.1 3.3 3.2 After drying, the hair is soft 4.4 4.2 4.3 3.2 3.1 After drying, the hair is moist 4.5 4.4 4.3 3.2 3.1 After drying, the hair feels glossy 4.5 4.3 4.4 2.9 3.1

3. Scalp irritation test

Stimulation clinical experiments on the shampoo prepared as in Example 1 were carried out as follows.

First, clinical trials were conducted on 20 healthy subjects (8 males and 12 females) between the ages of 10 and 50, and it was confirmed that other products such as steroids and antibiotics were not used until 2 weeks before the end of the experiment. .

In addition, for all test subjects, the scalp condition was observed 24 hours after shampooing, and qualitative evaluation was performed through the evaluation table as shown in [Table 4].

Experiment item Subjective score Evaluation results

Stimulation degree a: The skin is very red and itching is strong - b: The skin is slightly red and itchy - c: The skin becomes slightly red and irritated - d: Skin condition is unchanged, but slightly irritating - e: No irritation or changes in skin condition 20 people

Referring to [Table 4], it can be confirmed that the shampoo prepared according to Example 1 can be safely used because there is no scalp irritation or changes in skin condition.

4. Antibacterial effect

To confirm the antibacterial effect of the hair shampoos according to Examples 1, 2, 3 and Comparative Examples 1 and 2, microbiology guidelines of the Cosmetic, Toility and Fragrance Association, Inc. (hereinafter referred to as CTFA) ) Was used.

In addition, the bacteria used to confirm the antibacterial effect are Staphylococcus aureus ATCC 6538P as Gram-positive bacteria, Escherichia coli ATCC 8739 as Gram-negative bacteria, Pseudomonas aeruginosa ATCC 9027, and Candida albicans as yeast. (Candida albicans ATCC 10231), Aspergillus niger ATCC22343 was used.

In a vial containing 10 ｇ of each hair shampoo, a suspension of 3 bacteria (Ecoli, Paeruginosa, S aureus) and 2 fungi (C albicans, A niger) was mixed with 1 × 106 cfu/ｇ and 1 × 105, respectively. After inoculation to be cfu/ｇ, after storage at 25°C, samples of 1 g were taken under aseptic operation at 4 hour, 1 day, 2 day, 3 day, and 7 day intervals. Nutrient agar, Difco) and fungi were spread on a potato dextrose agar (Difoc) medium and incubated at 35°C and 25°C for 24 to 72 hours, respectively, to obtain a D-value through the measured number of bacteria.

ingredient Species D-value(Hr) Example 1 Germ 5.3 Fungi 5.4 Example 2 Germ 5.2 Fungi 5.3 Example 3 Germ 5.3 Fungi 5.2 Comparative Example 1 Germ 9.7 Fungi 9.8 Comparative Example 2 Germ 9.7 Fungi 9.6

* D-value: Time required to kill 90% of microorganisms

Referring to [Table 5], it was confirmed that the hair shampoos according to Examples 1, 2, and 3 had a very good antibacterial effect.

5. Scalp condition observation

The hair shampoo prepared according to Example 1 was washed once a day, and the scalp condition of the subject was observed after curing for a certain period.

1A, 2A, and 3A are photographs showing the state of the scalp before the subject uses the shampoo composition prepared according to Example 1, and FIGS. 1B, 2B, and 3B show the shampoo composition prepared by the subject according to Example 1 This picture shows the condition of the scalp after using it for 4 months once a day.

1A to 3B, the scalp state after a subject uses the shampoo composition prepared according to Example 1 (FIGS. 1B, 2B, and 3B) is the scalp condition before using the shampoo composition prepared according to Example 1 It can be seen that dandruff is removed, the scalp cleanliness is improved, and the hair is soft and shiny.

6. Hair condition observation

The hair shampoo prepared according to Example 1 was washed once a day, and after curing for a period of time, the subject's hair condition was observed.

4, 5, and 6 are before the subject uses the shampoo composition prepared according to Example 1 (left photograph in FIGS. 4, 5, and 6) and the shampoo composition prepared by the subject according to Example 1 It is a picture showing the hair condition after using for 5 months once a day (pictures on the right in FIGS. 4, 5 and 6).

4 to 6, after using the shampoo composition prepared according to Example 1, it was confirmed that the subject's hair was restored to a rich and healthy condition.

7. Antioxidant activity experiment

Using the shampoo compositions of Examples 1, 2, and 3 as samples, radical scavenging activity was measured.

The antioxidant activity of the sample (electron donation ability, EDA%) was measured by modifying the Blois method. After mixing 2 mL of a 0.2 mM DPPH (1,1-diphenyl-2-picryl hydrazyl) solution in 2 mL of the sample, allowed to stand for 30 minutes, and absorbance was measured at 517 nm.

The radical scavenging activity was expressed as the rate of decrease in absorbance between the sample-added and non-added spheres. The radical scavenging activity was calculated by the following equation, and the results are shown in Table 6 below. As a control sample, BHT (synthetic antioxidant) was used.

Radical scavenging activity (%) = (1-absorbance of sample addition/absorption of no addition)×100

division Radical scavenging activity Example 1 57.1 ± 0.5 Example 2 58.0 ± 0.4 Example 3 57.7 ± 0.5 Control 62.5 ± 0.4

Referring to [Table 6], the hair shampoos prepared according to Examples 1, 2, and 3 were found to have antioxidant activity, and had almost similar effects to the radical scavenging ability of the conventional synthetic antioxidant used as a control. Was confirmed.

Therefore, the hair shampoos prepared according to Examples 1, 2, and 3 are excellent in the antioxidant effect of protecting the scalp from free radicals and free radicals and are expected to greatly enhance the physiological activity of the scalp.

The preferred embodiments of the present invention have been described above with reference to the accompanying drawings, but those of ordinary skill in the art to which the present invention pertains may use the present invention in other specific forms without changing its technical spirit or essential features. It will be understood that it can be practiced. Therefore, it should be understood that the embodiment described above is illustrative in all respects and not limiting.

Claims (3)

Sunjit extract 10-15 parts by weight, horseradish fermentation broth 4-8 parts by weight, inorganic extracts 3-7 parts by weight, tea tree oil 1-5 parts by weight, cystamine dimaleate 0.2-0.6 parts by weight, and Eoseongcho extract is included in a weight ratio of 3 to 7 parts by weight,
In addition to the pure water extract, horseradish fermentation liquid, inorganic extract, zinc gluconate, cystamine dimaleate, and fish vinegar extract, mineral water, amino acid surfactant (Sodium N-(2) -Dodecyl Succinoyl)l-Glutamate), amphoteric surfactant (Cocobetainamido amphopropionate), nonionic surfactant (decyl glucoside), nonionic surfactant (coco-glucoside), lauric acid, Myristic Acid, Citric Acid, Glycerin, Tocopheryl acetate, Hydroxyethyl Cellulose, Panthenyl Triacetate, Avocado Oil (Persea Giratissima ( Avocado) Oil, Placental Protein, Pantothenic Acid, Biotin, Vividin, Methionine, Allantion, Cetyl Alcohol, Nettle Fruit Extracts (Vites Trifolia Fruit Extract), Rehmannia Chinensis Extract, Thuja Orientalis Root Extract, Morus Alba Bark Extract, Pineus sylvestris bark Extract, Cimicifuga racemosa root Extract, Chlorella Extract, Methyl sulfonylmethane, Brewer's yeast Extract and Mandarin Extract (Citrus n) obilis (Mandarin Orange) fruit extract),
The shunjit extract, after preparing the shunjit mineral, is pulverized to have a particle size of 10 to 300㎛ range using a ball milling device, and the pulverized shunjit at a temperature of 1200 to 1600 ℃ Heat treatment is performed by heating for 1 to 20 minutes, and after washing the heat-treated pure paper with purified water at 30 to 50°C to remove combustion residues attached to the surface of the pure paper, 100 parts by weight of the total content of the washed pure paper About 5 to 7% by weight of the mixed salt solution 500 to 1000 parts by weight of the weight ratio, and then aged for 3 to 7 days at a temperature of 60 to 70 ℃ storage, immersed in the baked salt solution After separating and removing the soil, centrifugation is performed to separate and separate the lower layer baked salt solution in which the pure jit particles are located, the middle layer baked salt solution located in the upper portion of the lower layer baked salt solution, and the upper layer baked salt solution. After separating the centrifuged middle layer and the upper layer roasted salt solution, using a gel-based Sunjit extract prepared through a process of removing moisture by heating to a temperature of 110 to 130°C,
The wasabi fermentation broth was prepared by washing wasabi in water, steaming the washed wasabi for 10 to 60 minutes with steam, and washing the boiled wasabi with one or more acids of acetic acid or citric acid. And spraying the acid-washed horseradish with culture medium and lactic acid bacteria culture medium consisting of lactic acid bacteria, wherein the lactic acid bacteria include Lactobacillales , Streptococcus thermophiles , and Bifidobacterium longum Any one or more lactic acid bacteria selected from the group consisting of is used, the culture medium is 20 to 30 parts by weight of peptone, 10 to 20 parts by weight of malt extract, 1 to 2 parts by weight of sodium citrate, 0.1 to 0.3 parts by weight of potassium diphosphate, glucose It is made by mixing at a weight ratio of 1.5 to 3.5 parts by weight and 100 to 200 parts by weight of distilled water, 1 to 1 in a storage container that maintains the temperature of 50 to 55°C and the humidity of 55 to 60% for wasabi sprayed with the lactic acid bacteria culture solution. The fermentation broth is stored for 3 days to prepare a lactic acid bacteria fermentation broth, and a mixed solution is prepared by mixing in a weight ratio of 50 to 150 parts by weight of the marine deep water solution with respect to 100 parts by weight of wasabi sprayed with the lactic acid bacteria culture solution, and the mixed solution is 20. It is prepared through fermentation by storing in a container for 2 to 6 days at a temperature of 30° C., and then separating only the supernatant of the mixed solution stored in the container,
The inorganic extract is 5 to 10 parts by weight of mica extract, 1 to 5 parts by weight of biotite extract, 3 to 7 parts by weight of ocher stone extract, 2 to 6 parts by weight of diatomaceous earth extract, 3 to 7 parts by weight of jade extract and 4 to 8 parts of illite extract Included in a weight ratio of parts by weight, the inorganic extract, mica, biotite, ocher, diatomaceous earth, jade and illite are prepared, and then the mica, biotite, ocher, diatomaceous earth, jade and illite are crushed, and the crushed silk, Heat treated by heating biotite, ocher stone, diatomaceous earth, jade and illite at a temperature of 1500 to 1700° C. for 50 to 100 minutes, and purified water of 50 to 60° C. of the heated mica, biotite, ocher, diatomaceous earth, jade and illite After removing the combustion residues generated during heat treatment attached to the surface of the muscovite, biotite, ocher, diatomaceous earth, jade, and illite, 100 weight of the washed muscovite, biotite, ocher, diatomaceous earth, jade, and illite After mixing 300 to 500 parts by weight of purified water at a temperature of 60 to 65° C. for parts, aged by sealing and storing for 3 to 6 days, a mixture of aged mica, biotite, ocher, diatomaceous earth, jade, illite and purified water After separating and removing the mica, biotite, ocher, diatomaceous earth, jade, and illite, and centrifuging the purified water, the lower layer liquid in which fine particles of mica, biotite, ocher, diatomaceous earth, jade, and illite are located, and the lower layer The process of separating and separating the middle layer liquid and the supernatant liquid located on the top of the liquid, separating the middle layer liquid and the supernatant of the centrifuged purified water, and heating the heat source at a temperature of 150 to 170°C to remove moisture. Manufactured through
The eoseongcho extract is prepared, washed after preparing eoseongcho, and steamed by heating the washed eoseongcho at a temperature of 130 to 150° C. and a pressure of 3 to 5 kgf/cm ² for 10 to 30 minutes with steam. After drying for 30 to 60 hours at a temperature of 22° C. and a humidity of 55 to 60%, the dried fish paste is heated to agitate and then cooled, but the agitation is 75 to 75 after the dried fish paste is introduced into a heating vessel. Primary agitation for 1 to 5 minutes at a temperature of 80° C., secondary aeration of the primary aerated primrose for 10 to 50 seconds at a temperature of 120 to 140° C., and 35 to 45° C. for the secondary aerated primrose. Cooling for 1 to 3 hours at a temperature of 1, 3 parts by weight of minerals with respect to 100 parts by weight of the cooled eoseongcho and 5 to 10 parts by weight of lactic acid bacteria culture medium by inoculation by spraying, the minerals Any one or more selected from the group consisting of calcium, phosphorus, potassium, magnesium, manganese, iodine, selenium, molybdenum, and cobalt is used, and the lactic acid bacteria use lactic acid strains separated from kimchi, and the lactic acid strain is Lactobacillus curva Lactobacillus curvatus , Weissella viridescens , Lactobacillus plantarum and Any one or more lactic acid strains selected from the group consisting of Leuconostoc lactis are used, and the lactic acid bacteria culture medium is adjusted to a pH of the medium to 2.8 to 3.2 using 1.2N HCl, and then the lactic acid strain is separated from kimchi. Then, the isolated lactic acid strains were incubated for 20-25 hours at 37~39°C using MRS broth (Oxoid, England), and then diluted to 1×1.0 ⁸ ~ 5×1.0 ⁸ CFU/mL, and then 10,000 After centrifugation at 15,000 rpm for 10 to 15 minutes, only the supernatant was separated, and the supernatant was filtered with a 0.45 μm syringe filter, and sterilized distilled water 1,000 with respect to 100 parts by weight of the filtered supernatant It is prepared through a process of diluting by mixing at a weight ratio of 2,000 to 2,000 parts by weight, and after maintaining the temperature of 38 to 42° C. and the humidity of 60 to 62%, the fish and vinegar inoculated with the mineral and lactic acid bacteria culture solution are maintained for 3 to 5 days. During fermentation, the fermented fish vinegar is mixed with a solvent to prepare a mixture, and then added to an ultrasonic extractor to which the ultrasonic wave is added to the mixture under a temperature of 18 to 20°C and a pressure of 0.5 to 1.0 kgf/cm ² , It is prepared through the process of removing the solids contained in, the solvent is water or any one or more solvents selected from alcohols having 1 to 4 carbon atoms (C1 to C4) is used, the ultrasonic waves applied to the mixture is 50 to 80KHz Hair shampoo composition characterized in that using the output of 150 to 300 watts (watt) for 150 to 200 minutes at the vibration frequency of. delete delete

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