KR102353526B1 - Composition for 1 step hairdye shampoo - Google Patents

Abstract

The present invention relates to a hairdye shampoo composition containing a mixed extract of mulberry fruit, Morus alba L. bark, Morus alba L. leaf, and biotite as an active ingredient. The hairdye shampoo containing the active ingredient of the present invention can be continuously used without damage to the scalp and hair, and a repeated use thereof can further increasing a dyeing effect. In addition, a conventional hairdye is used in such a manner that first and second agents are mixed just before use. However, when the hairdye shampoo composition of the present invention was used in a conventional shampooing method without a need for mixing two separate agents, only one step agent showed an excellent hair dyeing effect, as well as a scalp cleaning effect and a hair improvement effect. In addition, when the conventional hair dye is stored in a pumping container, which is often used as a shampoo container, oxidation proceeds in two to three days after being opened, and thus the hair is not dyed. However, the hairdye shampoo composition of the present invention has the effect of maintaining the quality related to dyeing and washing without any product change in six months after being opened, as long as the composition is stored in the same container, or for up to two years from the date of container filling when unopened.

Description

One-part hair dye shampoo composition {Composition for 1 step hairdye shampoo}

The present invention relates to a hair dye shampoo composition comprising a mixed extract of mulberry fruit, sangbaekpi, upper leaf and biotite as an active ingredient.

Gray hair, which occurs one by one with environmental factors or aging, acts as a considerable stress. In particular, gray hairs are particularly prominent, which is a factor that irritates the nerves. However, because of gray hair, it is cumbersome to visit a hairdresser and dye it every time, and frequent dyeing causes damage to the hair and scalp.

Hair dyes can be classified into three types: temporary hair dye, semi-permanent hair dye, and permanent hair dye, which are classified according to the location of the hair dyeing agent.

Semi-permanent hair dye is applied to the surface of the hair and penetrates the epidermis at the same time, but does not change the basic molecular structure of the hair. In general, after applying to the hair, leave it for 15 to 20 minutes, or heat it and then cool it. One dye lasts for 4-6 weeks, but each time you shampoo, the color fades, and the more you use it, the shorter the duration.

Most commonly used hair dyes are oxidation-type hair dyes, which allow the oxidation-type dye to penetrate the epidermis of the hair to deposit the dye molecules in the cortex, and to develop color while discoloring the hair by the addition of an oxidizing agent. These dyes are synthetic organisms derived from aniline and are known to have the best dyeing power and durability among hair dyes.

Oxidation-type hair dyes, which are usually formulated to be separately prescribed as one agent and two agents, have an oxidation dye and an alkali agent in the first agent, and hydrogen peroxide as an oxidizing agent in the second agent. The alkali agent of the first agent promotes the activity of the hydrogen peroxide agent of the second agent, thereby helping the dyeing of the oxidation dye by color development and swelling of the hair.

Oxidation dyes that have penetrated into the hair undergo a polymerization reaction and increase in molecular size, so they cannot come out of the epidermis, so the color persistence is excellent. However, in terms of hair damage, alkalis and hydrogen peroxide can have a bad effect, and oxidation dyes can cause irritation, such as hypersensitivity reactions of the scalp, in addition to hair damage. side effects are likely to occur.

In addition, the existing oxidized hair dye has a problem of damaging the hair by dissolving the hair component as it uses a strong acid or alkali component. In addition, existing oxidized hair dyes are dyed by oxidative polymerization inside the hair, so there are cases where the hair loses its gloss and gloss and the hair is severely damaged, resulting in unnatural color and poor texture. .

On the other hand, in the case of a non-oxidizing hair dye, there is a disadvantage in that color expression is lower than that of an oxidizing hair dye. For example, a commercially available non-oxidizing hair dye containing pyrogallol as a main component has a disadvantage in that the initial hair color is dark indigo with a lot of blue added, and is dyed in an unnatural color.

Accordingly, there is a demand for the development of a composition that has little damage to hair and scalp, is easy to use, has high stability in formulation, and has excellent hair dyeing power.

On the other hand, Korean Patent No. 2016584 discloses a composition for hair dye containing dogwood extract as an active ingredient, and Korean Patent No. 2227533 discloses a shampoo composition using herbal herbal medicines and a method for manufacturing the same, but this There is no disclosure regarding the hair dye shampoo composition containing the mixed extract of mulberry fruit, sangbaekpi, upper leaf and biotite of the present invention as an active ingredient.

The present invention has been derived from the above needs, and provides a hair dye shampoo composition containing a mixed extract of mulberry fruit, sangbaekpi, upper leaf and biotite as an active ingredient, and the scalp cleaning effect of the shampoo composition, the scalp by continuous use, and The present invention was completed by checking the degree of hair damage, the dyeing effect according to repeated use, the degree of fading, the hair dyeing power according to the biotite content, and the product stability (oxidative stability) according to the presence or absence of biotite addition.

In order to solve the above problems, the present invention provides a hair dye shampoo composition comprising a mixed extract of mulberry fruit, sangbaekpi, sangyeop and biotite as an active ingredient.

In addition, the present invention provides a hair dye shampoo comprising the composition as an active ingredient.

The present invention relates to a hair dye shampoo composition comprising a mixed extract of mulberry fruit, sagebrush, upper leaf and biotite as an active ingredient. After using it for 2 minutes at a time, for a total of 2 weeks, damage to the scalp and hair did not appear, but rather had the effect of improving the degree of damage to the hair. In addition, the dyeing effect was further increased by repeated use, and the fading effect by general shampoo washing was insignificant.

As a result of checking the hair dyeing power according to the biotite content, the hair dyeing power was excellent as the biotite content increased. As a result of comparing the degree of oxidation of the product depending on whether or not biotite was added, the group without biotite oxidized after opening the container and the container was dyed. It was confirmed that the product quality was maintained even after 6 months of opening in the biotite-added group, while the product stability was reduced. When the conventional hair dye is stored in a pumping container, which is often used as a shampoo container, oxidation proceeds after 2-3 days and does not dye the hair. The quality for dyeing and cleaning was maintained without any change in the product from the day of work to 2 years.

Conventional hair dye is a method used by mixing the first agent and the second agent immediately before use, but the hair dye shampoo composition of the present invention can exhibit a dyeing effect simply with only one agent without the need to mix two separate agents, and use a conventional shampoo When used in this method, there was no dyeing on the skin and nails except for the hair, and only the hair showed an excellent hair dyeing effect.

1 is a photograph comparing the scalp keratin condition before and after using the hair dye shampoo of the present invention (use once for 2 minutes). The keratin was expressed in white.
2 is a photograph confirming the degree of damage to the scalp after using the hair dye shampoo of the present invention for 2 weeks, immediately after using it once for 2 minutes, and once a day for 2 minutes.
3 is a photograph confirming the degree of damage to the hair before and after using the hair dye shampoo of the present invention continuously (used for 2 minutes once a day for a total of 2 weeks).
4 is a result confirming the dyeing effect according to the repeated use of the hair dye shampoo of the present invention. After applying the shampoo of the present invention to the white cloth for testing and the bleached hair for 2 minutes, the process of rinsing with water and drying with a hair dryer was repeated 5 to 15 times.
5 is a result of examining the dyeing lasting effect of the hair dye shampoo of the present invention. After applying the shampoo of the present invention to the white cloth for testing and the bleached hair for 2 minutes, rinse with water and dry with a hair dryer 15 times. It was repeated ~30 times.
6 is a result of confirming the hair dyeing power of the hair dye shampoo of the present invention according to the biotite (biotite) content. After applying to bleached hair for 2 minutes, rinse with water and dry with a dryer 15 times.
7 is a result of comparing the degree of oxidation of a product according to the presence or absence of biotite (biotite) included.

In order to achieve the object of the present invention, the present invention provides a hair dye shampoo composition containing a mixed extract of mulberry fruit, sangbaekpi, sangyeop and biotite as an active ingredient.

As used herein, the term 'hair dye' refers to a dyeing product that permanently or semi-permanently changes the hair color by using the chemical properties of the hair through natural or synthetic dyes. There is this.

The mixed extract of mulberry fruit, sangbaekpi, upper leaf and biotite

1) obtaining a primary extract by first extracting a mixture of mulberry fruit, sagebrush, and upper leaf; and

2) adding biotite to the primary extract obtained in step 1) to perform secondary extraction; may be obtained by a manufacturing method comprising;

preferably

_{1) Add 5-10L of water, C 1} ~ C ₄ lower alcohol or a mixture thereof to a mixture of 200~300g of mulberry fruit, 100~200g of sagebrush and 270~370g of upper leaf, and then add 5~10L at 30~70℃ for 10~24. After primary extraction for a period of time, filtration to obtain a primary extract; and

2) adding 100 to 500 g of biotite to the primary extract obtained in step 1), performing secondary extraction at 60 to 100 ° C. for 6 to 24 hours, and then filtering; may be obtained by a manufacturing method comprising there is,

more preferably

1) To a mixture of 250-270 g of mulberry, 160-180 g of sagebrush, and 310-330 g of upper leaves, _{add 5-8 L of water, C 1} to C ₄ lower alcohol or a mixture thereof, After primary extraction for a period of time, filtration to obtain a primary extract; and

2) adding 100 to 500 g of biotite to the primary extract obtained in step 1), followed by secondary extraction at 70 to 90° C. for 10 to 14 hours, followed by filtering there is,

most preferably

_{1) 6L of water, C 1} ~ C ₄ lower alcohol or a mixture thereof is added to a mixture of 260 g of mulberry fruit, 170 g of sagebrush, and 320 g of upper leaf, and primary extraction is performed at 50° C. for 16 hours, followed by filtration and primary extract obtaining a; and

2) adding 100 to 500 g of biotite to the primary extract obtained in step 1), performing secondary extraction at 80° C. for 12 hours, followed by filtration; may be obtained by a manufacturing method comprising; it's not going to be

In one embodiment of the present invention, the biotite is

1) 100 parts by weight of silicon dioxide (SiO _{2 ), 10 to 20 parts by weight of aluminum oxide (Al 2} O ₃ ), 3 to 10 parts by weight of potassium hydroxide (KOH), magnesium oxide (magnesium oxide, MgO) 3-10 parts by weight, boric acid (H ₃ BO ₃ ) 30-70 parts by weight, manganese oxide (MnO) 3-10 parts by weight, ferrous oxide (FeO) Mixing 2-6 parts by weight and 2-6 parts by weight of ferric tetraoxide (Red oxide, Fe ₃ O _{4 );}

2) obtaining a molten mixture by putting the mixture of step 1) into a glass melting furnace at 1350 to 1550° C. and melting it for 15 to 25 hours; and

3) putting the molten mixture of step 2) into cooling water and pulverizing the decomposed glassy particles to an average particle size of 1 to 100 nm; may be obtained by a manufacturing method comprising;

preferably

1) Based on 100 parts by weight of _{silicon dioxide (SiO 2 ), 16 to 19 parts by weight of aluminum oxide (Al 2} O ₃ ), 5 to 8 parts by weight of potassium hydroxide (KOH), magnesium oxide (magnesium oxide, MgO) 5-8 parts by weight, boric acid (H ₃ BO ₃ ) 50-60 parts by weight, manganese oxide (MnO) 5-8 parts by weight, ferrous oxide (FeO) 3 to 5 parts by weight and 3 to 5 parts by weight of triiron tetraoxide (Red oxide, Fe ₃ O ₄ );

2) obtaining a molten mixture by putting the mixture of step 1) into a glass melting furnace at 1350 to 1550° C. and melting it for 19 to 21 hours; and

3) putting the molten mixture of step 2) into cooling water and pulverizing the decomposed glassy particles to an average particle size of 1 to 100 nm; may be obtained by a manufacturing method comprising;

more preferably

1) With respect to 100 parts by weight of silicon dioxide (SiO _{2 ), aluminum oxide (Al 2} O ₃ ) 17.8 parts by weight, potassium hydroxide (KOH) 6.7 parts by weight, magnesium oxide, MgO) 6.7 parts by weight, boric acid (H ₃ BO ₃ ) 55.6 parts by weight, manganese oxide (MnO) 6.7 parts by weight, ferrous oxide (FeO) 4.4 parts by weight, and red oxide, Fe ₃ O ₄ ) mixing 4.4 parts by weight;

2) obtaining a molten mixture by putting the mixture of step 1) into a glass melting furnace at 1350 to 1550° C. and melting it for 19 to 21 hours; and

3) Putting the molten mixture of step 2) into cooling water and pulverizing the decomposed glassy particles to an average particle diameter of 1 to 100 nm.

In one embodiment of the present invention, the composition may further include a colorant, and the colorant may include all dyes that can be conventionally used in the field of hair dye.

In one embodiment of the present invention, the composition is p-nitro-o-phenylenediamine, nitro-p-phenylenediamine, 2-methyl-5-hydroxyethylaminophenol, 2-amino-4-nitrophenol , 2-amino-5-nitrophenol, 2-amino-3-hydroxypyridine, 5-amino-o-cresol, m-aminophenol, o-aminophenol, p-aminophenol, hydrochloric acid 2,4-dia Minophenoxyethanol, hydrochloric acid toluene-2,5-diamine, hydrochloric acid m-phenylenediamine, hydrochloric acid p-phenylenediamine, hydrochloric acid hydroxypropylbis(N-hydroxyethyl-p-phenylenediamine), toluene- 2,5-diamine, m-phenylenediamine, p-phenylenediamine, N-phenyl-p-phenylenediamine, picramic acid, sulfuric acid p-nitro-o-phenylenediamine, sulfuric acid p-methylaminophenol; 5-amino-o-cresol sulfate, m-aminophenol sulfate, o-aminophenol sulfate, p-aminophenol sulfate, toluene-2,5-diamine sulfate, m-phenylenediamine sulfate, p-phenylenediamine sulfate , sulfuric acid N,N-bis(2-hydroxyethyl)-p-phenylenediamine, 2,6-diaminopyridine, hydrochloric acid 2,4-diaminophenol, 1,5-dihydroxynaphthalene, picramine Sodium acid, 2-amino-5-nitrophenol sulfate, o-chloro-p-phenylenediamine sulfate, 1-hydroxyethyl-4,5-diaminopyrazole, hydroxybenzomorpholine, 6-hydroxy acid Oxyindole, α-naphthol, resorcinol, 2-methylresorcinol, gallic acid, catechol and pyrogallol may further include one or more coloring agents, preferably p-phenylenediamine, resorcinol , 2,4-diaminophenoxyethanol hydrochloric acid, and at least one colorant selected from m-aminophenol, but is not limited thereto.

In one embodiment of the present invention, the composition has the effect of improving dyeability and oxidative stability compared to that in which biotite is not added.

In addition, the present invention provides a hair dye shampoo comprising the composition as an active ingredient.

The hair dye shampoo further comprises a hair protectant, a chelating agent, a surfactant, a pH adjuster, an alkali agent, a moisturizing agent, a thickener, a preservative, an antioxidant, a bactericide, an anti-inflammatory agent, an antimicrobial agent, a solvent, a skin conditioning agent, a flavoring agent and a colorant. It may contain one or more components selected from the group, and preferably contains, but is not limited to, coloring agents, surfactants, skin conditioning agents, thickeners and flavoring agents.

The hair dye shampoo of the present invention may be provided in a packaged form in a container, tube or pouch, but is not limited thereto.

The material of the container, tube and pouch may be any material as long as it is made of a material used for general shampoo packaging.

In one embodiment of the present invention, the hair dye shampoo may contain 50 to 60% of the total weight of the mixed extract of mulberry fruit, sangbaekpi, upper leaf and biotite diluted by adding 8 to 10 times water, but is limited thereto no.

Hereinafter, the present invention will be described in more detail using Preparation Examples and Examples. These preparations and examples are only for illustrating the present invention in more detail, and it will be apparent to those of ordinary skill in the art that the scope of the present invention is not limited thereto.

Preparation Example 1. Preparation of biotite (biotite)

Biotite (biotite) of the present invention was prepared according to the method described in Korean Patent No. 0655152 and then used.

Specifically, with respect to silicon dioxide (SiO ₂ ) 100 parts by weight, aluminum oxide (Al ₂ O ₃ ) 17.8 parts by weight, potassium hydroxide (KOH) 6.7 parts by weight, magnesium oxide (magnesium oxide) , MgO) 6.7 parts by weight, boric acid (H ₃ BO ₃ ) 55.6 parts by weight, manganese oxide (MnO) 6.7 parts by weight, ferrous oxide (FeO) 4.4 parts by weight, and red oxide , Fe ₃ O ₄ ) After mixing 4.4 parts by weight, the mixture was put into a glass melting furnace at 1350 to 1550° C. and melted for 19 to 21 hours to obtain a molten mixture, and the obtained molten mixture was put in cooling water and decomposed The glassy particles were pulverized to have an average particle diameter of 1 to 100 nm to prepare biotite (biotite) of the present invention.

Preparation Example 2. Preparation of mixed extract of mulberry fruit, sagebrush, upper leaf and biotite

After adding 5 L of water and 1 L of alcohol (ethanol) to a mixture of 260 g of mulberry fruit, 170 g of sagebrush, and 320 g of upper leaf, primary extraction was performed at 50° C. for 16 hours, followed by filtration to obtain a primary extract. Thereafter, 450 g of biotite of Preparation Example 1 was added to the primary extract, followed by secondary extraction at 80° C. for 12 hours, followed by filtration to prepare a mixed extract of mulberry fruit, sangbaekpi, upper leaf and biotite.

A mixed extract of mulberry, sangbaekhui, upper leaf and biotite mixed extract diluted to 10% (v/v) by adding 900 mL of purified water to 100 mL of the mixed extract of mulberry berry, sangbaekpi, sangbaekpi, and biotite was used in the following shampoo preparation.

Preparation Example 3. Preparation of hair dye shampoo containing mixed extract of mulberry fruit, sangbaekpi, upper leaf and biotite as an active ingredient

A hair dye shampoo containing a mixed extract of mulberry fruit, sangbaekpi, upper leaf, and biotite as active ingredients was used by mixing at the mixing ratio (volume ratio) shown in Table 1 below.

ingredient content(%) Diluted mulberry fruit of Preparation Example 2, sangbaek skin, upper leaf and biotite mixed extract 50 to 60 coloring agent 0.1~5 Surfactants 2-40 skin conditioning agent 0.5 to 10 thickener 0.1~2 flavoring agent 0.1~1

Example 1. Scalp cleaning effect

The scalp cleaning effect was confirmed before and after using the hair dye shampoo of Preparation Example 3 for 2 minutes at a time. As a result, it was confirmed that dead skin cells were removed after using the hair dye shampoo of the present invention as shown in FIG. 1 .

Example 2. Confirmation of scalp damage according to continuous use

The degree of scalp damage caused by the continuous use of the hair dye shampoo of Preparation Example 3 was measured before shampooing, after shampooing once (used for 2 minutes), and after shampooing for 2 weeks (for 2 minutes once a day, for a total of 2 weeks). ) to confirm. As a result, as shown in FIG. 2 , it was confirmed that the hair dye shampoo of the present invention does not damage the scalp even with continuous use.

Example 3. Confirmation of hair damage according to continuous use

The degree of hair damage due to the continuous use of the hair dye shampoo of Preparation Example 3 was confirmed by dividing it into before shampoo use and after shampooing for 2 weeks (for 2 minutes once a day, for a total of 2 weeks). As a result, as shown in FIG. 3 , it was confirmed that the hair dye shampoo of the present invention did not damage the hair even after continuous use, but rather improved the damage to the hair.

Example 4. Dyeing effect according to repeated use

After applying the hair dye shampoo of Preparation Example 3 to white cloth or bleached hair for 2 minutes, rinsing with water and drying with a hair dryer, the process was repeated 5, 10, or 15 times, and then the dyeing effect according to repeated use was confirmed. As a result, as shown in FIG. 4 , the hair dye shampoo of the present invention increased the dyeing effect upon repeated use.

Example 5. Dyeing lasting effect

After applying the hair dye shampoo of Preparation Example 3 to white cloth or bleached hair for 2 minutes, rinsing with water and drying with a hair dryer 15 times, shampooing with general shampoo and drying with a hair dryer 15 times or 30 times Thus, the degree of discoloration was confirmed. As a result, as shown in FIG. 5 , the degree of fading was insignificant even after repeated use of the general shampoo 30 times.

Example 6. Hair dyeing power according to biotite (biotite) content

All the manufacturing methods are the same, but in Preparation Example 2, in order to check the hair dyeing power of the hair dye shampoo containing the extract prepared by varying the content of biotite (biotite) to 180, 310 or 450 g, the hair dye of the present invention for bleached hair After applying the shampoo for 2 minutes, the process of rinsing with water and drying with a dryer was repeated 15 times. As a result, as shown in FIG. 6 , as the content of biotite increased, the degree of dyeing was excellent.

Example 7. Comparison of the degree of oxidation according to whether or not biotite was added

In order to compare the degree of oxidation depending on whether or not biotite was added, all the manufacturing methods were the same as for the hair dye shampoo of Preparation Example 3 of the present invention, except that the process of secondary extraction by adding biotite in Preparation Example 2 was omitted and the prepared extract was used. After the hair dye shampoo containing the shampoo was packaged in a general pumping shampoo container, the degree of oxidation was checked before opening, immediately after opening, 1 month after opening, and 6 months after opening. As a result, as shown in FIG. 7 , in the hair dye shampoo of Preparation Example 3 of the present invention to which biotite was added, the quality of the product was maintained even after 6 months of opening. confirmed that it cannot.

When the conventional hair dye is stored in a pumping container often used as a shampoo container, oxidation proceeds after 2-3 days and does not dye the hair, but the hair dye shampoo of Preparation Example 3 of the present invention is opened in the same container 6 months after opening The quality related to dyeing and cleaning was maintained without any change in the product for up to 2 years from the date of filling the container.

Claims (9)

1) 100 parts by weight of silicon dioxide (SiO _{2 ), 10 to 20 parts by weight of aluminum oxide (Al 2} O ₃ ), 3 to 10 parts by weight of potassium hydroxide (KOH), magnesium oxide (magnesium oxide, MgO) 3-10 parts by weight, boric acid (H ₃ BO ₃ ) 30-70 parts by weight, manganese oxide (MnO) 3-10 parts by weight, ferrous oxide (FeO) Mixing 2-6 parts by weight and 2-6 parts by weight of ferric tetraoxide (Red oxide, Fe ₃ O _{4 );}
2) obtaining a molten mixture by putting the mixture of step 1) into a glass melting furnace at 1350 to 1550° C. and melting it for 15 to 25 hours;
3) adding the molten mixture of step 2) to cooling water and pulverizing the decomposed glassy particles to an average particle size of 1 to 100 nm to obtain biotite;
4) To a mixture of 200-300 g of mulberry fruit, 100-200 g of sagebrush and 270-370 g of upper leaves, _{add 5-10 L of water, C 1} to C ₄ lower alcohol or a mixture thereof, After primary extraction for a period of time, filtration to obtain a primary extract; and
5) adding 100 to 500 g of the biotite obtained in 3) to the primary extract obtained in step 4), followed by secondary extraction at 60 to 100° C. for 6 to 24 hours, followed by filtration; Manufacturing method comprising; A hair dye shampoo composition containing a mixed extract of mulberry fruit, sagebrush, upper leaf, and biotite obtained from delete delete delete The hair dye shampoo composition according to claim 1, wherein the composition further comprises a colorant, wherein dyeability and oxidative stability are improved compared to that without the addition of biotite. 6. The method of claim 5, wherein the colorant is p-nitro-o-phenylenediamine, nitro-p-phenylenediamine, 2-methyl-5-hydroxyethylaminophenol, 2-amino-4-nitrophenol, 2 -Amino-5-nitrophenol, 2-amino-3-hydroxypyridine, 5-amino-o-cresol, m-aminophenol, o-aminophenol, p-aminophenol, hydrochloric acid 2,4-diaminophenoxy Cyethanol, hydrochloric acid toluene-2,5-diamine, hydrochloric acid m-phenylenediamine, hydrochloric acid p-phenylenediamine, hydrochloric acid hydroxypropylbis(N-hydroxyethyl-p-phenylenediamine), toluene-2, 5-diamine, m-phenylenediamine, p-phenylenediamine, N-phenyl-p-phenylenediamine, picramic acid, sulfuric acid p-nitro-o-phenylenediamine, sulfuric acid p-methylaminophenol, sulfuric acid 5 -Amino-o-cresol, m-aminophenol sulfate, o-aminophenol sulfate, p-aminophenol sulfate, toluene-2,5-diamine sulfate, m-phenylenediamine sulfate, p-phenylenediamine sulfate, sulfuric acid N,N-bis(2-hydroxyethyl)-p-phenylenediamine, 2,6-diaminopyridine, hydrochloric acid 2,4-diaminophenol, 1,5-dihydroxynaphthalene, sodium picraminate , 2-amino-5-nitrophenol sulfate, o-chloro-p-phenylenediamine sulfate, 1-hydroxyethyl-4,5-diaminopyrazole sulfate, hydroxybenzomorpholine, 6-hydroxyindole , α-naphthol, resorcinol, 2-methylresorcinol, gallic acid, catechol and pyrogallol, characterized in that the dyeability and oxidation stability of the hair dye shampoo composition is improved compared to that without the addition of biotite, characterized in that. delete A hair dye shampoo comprising the composition of any one of claims 1 to 6 as an active ingredient. The hair dye shampoo according to claim 8, wherein the hair dye shampoo is provided in a packaged form in a container, tube or pouch.

Images