KR102088445B1 - 중합체 형성이 감소된 올레핀 화합물의 올리고머화 - Google Patents

중합체 형성이 감소된 올레핀 화합물의 올리고머화 Download PDF

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KR102088445B1
KR102088445B1 KR1020147034293A KR20147034293A KR102088445B1 KR 102088445 B1 KR102088445 B1 KR 102088445B1 KR 1020147034293 A KR1020147034293 A KR 1020147034293A KR 20147034293 A KR20147034293 A KR 20147034293A KR 102088445 B1 KR102088445 B1 KR 102088445B1
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containing additive
catalyst
metallic oxygen
oxygen
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KR20150006474A (ko
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마틴 존 한톤
데이비드 메튜 스미쓰
윌리엄 풀러드 가브리엘리
스티븐 존 에반스
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사솔 테크날러지 (프로프라이어터리) 리미티드
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/78—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from chromium, molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/30—Inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
    • C07C2531/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24 of chromium, molybdenum or tungsten

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
KR1020147034293A 2012-05-09 2013-05-08 중합체 형성이 감소된 올레핀 화합물의 올리고머화 Active KR102088445B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261644733P 2012-05-09 2012-05-09
US61/644,733 2012-05-09
PCT/IB2013/053693 WO2013168103A1 (en) 2012-05-09 2013-05-08 Oligomerisation of olefinic compounds with reduced polymer formation

Publications (2)

Publication Number Publication Date
KR20150006474A KR20150006474A (ko) 2015-01-16
KR102088445B1 true KR102088445B1 (ko) 2020-03-13

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Country Link
US (1) US9447202B2 (https=)
EP (1) EP2847149B1 (https=)
KR (1) KR102088445B1 (https=)
CN (1) CN104271537B (https=)
BR (1) BR112014027793B1 (https=)
CA (1) CA2866971C (https=)
ES (1) ES2904662T3 (https=)
IN (1) IN2014DN10415A (https=)
MX (1) MX352923B (https=)
MY (1) MY164153A (https=)
SG (1) SG11201407140SA (https=)
WO (1) WO2013168103A1 (https=)
ZA (1) ZA201406072B (https=)

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KR101607214B1 (ko) 2014-06-18 2016-03-29 주식회사 엘지화학 올레핀 올리고머의 제조 방법
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KR20160134464A (ko) 2015-05-15 2016-11-23 주식회사 엘지화학 혼성 담지 촉매계, 및 이를 이용한 폴리올레핀의 제조방법
KR102058142B1 (ko) * 2015-09-02 2019-12-20 주식회사 엘지화학 리간드 화합물, 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법
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CN112262147A (zh) * 2018-06-07 2021-01-22 亚洲大学校产学协力团 双膦配体化合物、铬化合物、乙烯低聚催化体系以及乙烯低聚物的制备方法
KR102087994B1 (ko) * 2018-06-07 2020-03-12 아주대학교산학협력단 에틸렌 사량화 촉매 시스템 제조 방법, 에틸렌 사량화 촉매 시스템, 에틸렌 사량체 제조 방법, 및 비스포스핀 리간드 화합물
WO2022060108A1 (ko) * 2020-09-15 2022-03-24 주식회사 엘지화학 리간드 화합물, 유기 크롬 화합물 및 이를 포함하는 촉매 시스템
AR124332A1 (es) * 2020-12-15 2023-03-15 Shell Int Research UN PROCESO PARA PRODUCIR a-OLEFINAS
CN114160199B (zh) * 2021-11-02 2024-01-16 浙江智英石化技术有限公司 乙烯选择性三聚和四聚的催化体系及其应用
KR20230134931A (ko) * 2022-03-15 2023-09-22 한화토탈에너지스 주식회사 에틸렌 올리고머화 방법 및 그 에틸렌 올리고머
JP7813628B2 (ja) * 2022-03-24 2026-02-13 三井化学株式会社 オレフィン多量化用触媒およびその触媒存在下で行うオレフィン多量体の製造方法
CN115028509B (zh) * 2022-07-01 2024-02-02 万华化学集团股份有限公司 反应活性提升和聚合物形成降低的乙烯齐聚工艺
KR20240154822A (ko) * 2023-04-19 2024-10-28 주식회사 엘지화학 리간드 화합물, 유기 크롬 화합물 및 이를 포함하는 촉매 조성물
KR20240154821A (ko) * 2023-04-19 2024-10-28 주식회사 엘지화학 리간드 화합물, 유기 크롬 화합물 및 이를 포함하는 촉매 조성물
KR102864902B1 (ko) * 2023-05-19 2025-09-26 한화토탈에너지스 주식회사 고분자 생성 저감 및 생산성이 향상된 에틸렌 올리고머화 방법
KR20250110054A (ko) * 2024-01-11 2025-07-18 주식회사 엘지화학 리간드 화합물, 유기 크롬 화합물 및 이를 포함하는 촉매 조성물

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MY164153A (en) 2017-11-30
MX352923B (es) 2017-12-14
ZA201406072B (en) 2015-11-25
CA2866971A1 (en) 2013-11-14
IN2014DN10415A (https=) 2015-08-14
CA2866971C (en) 2020-07-07
SG11201407140SA (en) 2014-11-27
US20150152200A1 (en) 2015-06-04
WO2013168103A1 (en) 2013-11-14
US9447202B2 (en) 2016-09-20
BR112014027793A2 (pt) 2017-07-18
EP2847149A1 (en) 2015-03-18
KR20150006474A (ko) 2015-01-16
ES2904662T3 (es) 2022-04-05
EP2847149B1 (en) 2022-01-12
CN104271537A (zh) 2015-01-07
BR112014027793B1 (pt) 2021-11-09
CN104271537B (zh) 2017-03-08
MX2014011595A (es) 2014-11-21

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