KR102037782B1 - 2,3,3,3-테트라플루오로프로펜 및 1,1,1,2-테트라플루오로에탄을 포함하는 조성물, 이를 함유하는 칠러, 및 그 안에 냉각을 생성하는 방법 - Google Patents
2,3,3,3-테트라플루오로프로펜 및 1,1,1,2-테트라플루오로에탄을 포함하는 조성물, 이를 함유하는 칠러, 및 그 안에 냉각을 생성하는 방법 Download PDFInfo
- Publication number
- KR102037782B1 KR102037782B1 KR1020187006578A KR20187006578A KR102037782B1 KR 102037782 B1 KR102037782 B1 KR 102037782B1 KR 1020187006578 A KR1020187006578 A KR 1020187006578A KR 20187006578 A KR20187006578 A KR 20187006578A KR 102037782 B1 KR102037782 B1 KR 102037782B1
- Authority
- KR
- South Korea
- Prior art keywords
- refrigerant
- tetrafluoroethane
- tetrafluoropropene
- composition
- chiller
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
- F25B9/002—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
- F25B9/006—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant the refrigerant containing more than one component
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/126—Unsaturated fluorinated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/22—All components of a mixture being fluoro compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/40—Replacement mixtures
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/40—Replacement mixtures
- C09K2205/42—Type R12
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2400/00—General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
- F25B2400/18—Refrigerant conversion
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US32498410P | 2010-04-16 | 2010-04-16 | |
| US61/324,984 | 2010-04-16 | ||
| PCT/US2011/032072 WO2011130237A1 (en) | 2010-04-16 | 2011-04-12 | Composition comprising 2,3,3,3-tetrafluoropropene and 1,1,1,2-tetrafluoroethane, chillers containing same and methods of producing cooling therein |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020127029921A Division KR20130051943A (ko) | 2010-04-16 | 2011-04-12 | 2,3,3,3-테트라플루오로프로펜 및 1,1,1,2-테트라플루오로에탄을 포함하는 조성물, 이를 함유하는 칠러, 및 그 안에 냉각을 생성하는 방법 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020197031107A Division KR20190122879A (ko) | 2010-04-16 | 2011-04-12 | 2,3,3,3-테트라플루오로프로펜 및 1,1,1,2-테트라플루오로에탄을 포함하는 조성물, 이를 함유하는 칠러, 및 그 안에 냉각을 생성하는 방법 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20180028552A KR20180028552A (ko) | 2018-03-16 |
| KR102037782B1 true KR102037782B1 (ko) | 2019-10-29 |
Family
ID=44166577
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020197031107A Ceased KR20190122879A (ko) | 2010-04-16 | 2011-04-12 | 2,3,3,3-테트라플루오로프로펜 및 1,1,1,2-테트라플루오로에탄을 포함하는 조성물, 이를 함유하는 칠러, 및 그 안에 냉각을 생성하는 방법 |
| KR1020187006578A Active KR102037782B1 (ko) | 2010-04-16 | 2011-04-12 | 2,3,3,3-테트라플루오로프로펜 및 1,1,1,2-테트라플루오로에탄을 포함하는 조성물, 이를 함유하는 칠러, 및 그 안에 냉각을 생성하는 방법 |
| KR1020127029921A Ceased KR20130051943A (ko) | 2010-04-16 | 2011-04-12 | 2,3,3,3-테트라플루오로프로펜 및 1,1,1,2-테트라플루오로에탄을 포함하는 조성물, 이를 함유하는 칠러, 및 그 안에 냉각을 생성하는 방법 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020197031107A Ceased KR20190122879A (ko) | 2010-04-16 | 2011-04-12 | 2,3,3,3-테트라플루오로프로펜 및 1,1,1,2-테트라플루오로에탄을 포함하는 조성물, 이를 함유하는 칠러, 및 그 안에 냉각을 생성하는 방법 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020127029921A Ceased KR20130051943A (ko) | 2010-04-16 | 2011-04-12 | 2,3,3,3-테트라플루오로프로펜 및 1,1,1,2-테트라플루오로에탄을 포함하는 조성물, 이를 함유하는 칠러, 및 그 안에 냉각을 생성하는 방법 |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US8765004B2 (enExample) |
| EP (3) | EP3929265B1 (enExample) |
| JP (2) | JP2013527273A (enExample) |
| KR (3) | KR20190122879A (enExample) |
| CN (1) | CN102844400B (enExample) |
| AR (1) | AR084380A1 (enExample) |
| AU (1) | AU2011240740B2 (enExample) |
| CA (1) | CA2796051C (enExample) |
| DE (1) | DE202011111049U1 (enExample) |
| ES (3) | ES2886149T3 (enExample) |
| FI (1) | FI3929265T3 (enExample) |
| MX (1) | MX346315B (enExample) |
| MY (1) | MY156787A (enExample) |
| PL (2) | PL3929265T3 (enExample) |
| PT (2) | PT3406688T (enExample) |
| RU (1) | RU2012148719A (enExample) |
| SA (1) | SA111320376B1 (enExample) |
| SG (1) | SG184453A1 (enExample) |
| TW (1) | TWI540117B (enExample) |
| WO (1) | WO2011130237A1 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8463441B2 (en) | 2002-12-09 | 2013-06-11 | Hudson Technologies, Inc. | Method and apparatus for optimizing refrigeration systems |
| US9546311B2 (en) | 2008-08-19 | 2017-01-17 | Honeywell International Inc. | Azeotrope-like compositions of 1,1,1,2-tetrafluoropropene and 1,1,1,2-tetrafluoroethane |
| AU2011343821B2 (en) | 2010-12-14 | 2015-12-24 | The Chemours Company Fc, Llc. | Use of refrigerants comprising E-1,3,3,3-tetrafluoropropene and at least one tetrafluoroethane for cooling |
| JP2015500897A (ja) * | 2011-12-01 | 2015-01-08 | ソルヴェイ(ソシエテ アノニム) | HFC−134aとHFO−1234yfとを含む組成物の新規な用途及びその共沸性組成物 |
| EP4112700A1 (en) * | 2013-11-22 | 2023-01-04 | The Chemours Company FC, LLC | Use of compositions comprising tetrafluoropropene and tetrafluoroethane in power cycles and power cycle apparatus |
| WO2015199855A1 (en) * | 2014-06-26 | 2015-12-30 | The Chemours Company Fc, Llc | Application of 1-chloro-3,3,3-trifluoropropene and 1,1,1,2,3-pentafluoro- propane mixtures in chillers having a screw-type compressor |
| US10648702B2 (en) | 2015-08-11 | 2020-05-12 | Carrier Corporation | Low capacity, low-GWP, HVAC system |
| CN108595761B (zh) * | 2018-03-23 | 2021-11-16 | 中国科学院理化技术研究所 | 基于体积最小化的翘式换热器设计方法及装置 |
| BR112021022059A2 (pt) | 2018-10-26 | 2021-12-28 | Chemours Co Fc Llc | Composições de fluoropropeno, métodos de produção de uma mistura e de resfriamento, processos para transferência de calor, para tratamento de uma superfície e para formação de uma composição, sistema de refrigeração, aparelhos de refrigeração, uso da composição de fluoropropeno e método para substituição de um refrigerante |
| US11209196B2 (en) | 2018-10-26 | 2021-12-28 | The Chemours Company Fc, Llc | HFO-1234ZE, HFO-1225ZC and HFO-1234YF compositions and processes for producing and using the compositions |
| MY202072A (en) | 2018-10-26 | 2024-04-02 | Chemours Co Fc Llc | Hfo-1234ze and hfo-1234yf compositions and processes for producing and using the compositions |
| DK4079831T3 (da) | 2020-01-31 | 2024-12-16 | Daikin Ind Ltd | Fremgangsmåde til udskiftning af kølemiddel i køleenhed |
| CN112054262A (zh) * | 2020-08-28 | 2020-12-08 | 甘肃电气装备集团生物科技工程有限公司 | 适用于退役锂电池中电解液的浸取溶剂以及利用其从退役锂电池中分离回收电解液的方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010002020A1 (en) * | 2008-07-01 | 2010-01-07 | Daikin Industries, Ltd. | REFRIGERANT COMPOSITION COMPRISING 1,1,1,2-TETRAFLUOROETHANE (HFC134a) AND 2,3,3,3-TETRAFLUOROPROPENE (HFO1234yf) |
| WO2010022018A2 (en) * | 2008-08-19 | 2010-02-25 | Honeywell International Inc. | Azeotrope-like compositions of 1,1,1,2-tetrafluoropropene and 1,1,1,2-tetrafluoroethane |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6096932A (en) | 1999-07-27 | 2000-08-01 | E. I. Du Pont De Nemours And Company | Fluorocarbon manufacturing process |
| US9005467B2 (en) * | 2003-10-27 | 2015-04-14 | Honeywell International Inc. | Methods of replacing heat transfer fluids |
| US20040089839A1 (en) * | 2002-10-25 | 2004-05-13 | Honeywell International, Inc. | Fluorinated alkene refrigerant compositions |
| US7524805B2 (en) | 2004-04-29 | 2009-04-28 | Honeywell International Inc. | Azeotrope-like compositions of tetrafluoropropene and hydrofluorocarbons |
| US20060243944A1 (en) * | 2005-03-04 | 2006-11-02 | Minor Barbara H | Compositions comprising a fluoroolefin |
| US7569170B2 (en) * | 2005-03-04 | 2009-08-04 | E.I. Du Pont De Nemours And Company | Compositions comprising a fluoroolefin |
| TWI657070B (zh) * | 2005-06-24 | 2019-04-21 | 美商哈尼威爾國際公司 | 含有經氟取代之烯烴之組合物及其用途 |
| US8574451B2 (en) * | 2005-06-24 | 2013-11-05 | Honeywell International Inc. | Trans-chloro-3,3,3-trifluoropropene for use in chiller applications |
| US7708903B2 (en) * | 2005-11-01 | 2010-05-04 | E.I. Du Pont De Nemours And Company | Compositions comprising fluoroolefins and uses thereof |
| US7560602B2 (en) | 2005-11-03 | 2009-07-14 | Honeywell International Inc. | Process for manufacture of fluorinated olefins |
| US8974688B2 (en) | 2009-07-29 | 2015-03-10 | Honeywell International Inc. | Compositions and methods for refrigeration |
| KR20090049617A (ko) | 2006-09-01 | 2009-05-18 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 폐쇄 루프 사이클을 통한 선택된 열전달 유체의 순환 방법 |
| KR101513319B1 (ko) | 2007-05-11 | 2015-04-17 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 증기 압축 열전달 시스템에서의 열교환 방법 및 2열 증발기 또는 응축기를 갖는 중간 열교환기를 포함하는 증기 압축 열전달 시스템 |
| CN101688817A (zh) * | 2007-06-21 | 2010-03-31 | 纳幕尔杜邦公司 | 用于热传递系统的渗漏检测的方法 |
| EP2171012A1 (en) * | 2007-07-27 | 2010-04-07 | E. I. du Pont de Nemours and Company | Compositions comprising fluoroolefins and uses thereof |
| WO2009047535A2 (en) | 2007-10-12 | 2009-04-16 | Ineos Fluor Holdings Limited | Heat transfer compositions |
| JP2009257655A (ja) * | 2008-03-04 | 2009-11-05 | Daikin Ind Ltd | 冷凍装置 |
| US8038899B2 (en) * | 2008-04-28 | 2011-10-18 | Honeywell International Inc. | Refrigerant compositions having a siloxane solubilizing agent |
| FR2932492B1 (fr) * | 2008-06-11 | 2010-07-30 | Arkema France | Compositions a base d'hydrofluoroolefines |
| FR2932493B1 (fr) * | 2008-06-11 | 2010-07-30 | Arkema France | Compositions a base d'hydrofluoroolefines |
| KR101628421B1 (ko) | 2008-11-19 | 2016-06-08 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 테트라플루오로프로펜 조성물 및 그의 용도 |
| SI2427527T1 (sl) | 2009-05-08 | 2016-03-31 | Honeywell International Inc. | Sestavki in postopki za prenos toplote |
| GB0915004D0 (en) | 2009-08-28 | 2009-09-30 | Ineos Fluor Holdings Ltd | Heat transfer composition |
| FR2950068B1 (fr) * | 2009-09-11 | 2012-05-18 | Arkema France | Procede de transfert de chaleur |
| FR2950071B1 (fr) * | 2009-09-11 | 2012-02-03 | Arkema France | Compositions ternaires pour refrigeration basse capacite |
| FR2950070B1 (fr) * | 2009-09-11 | 2011-10-28 | Arkema France | Compositions ternaires pour refrigeration haute capacite |
| FR2954342B1 (fr) | 2009-12-18 | 2012-03-16 | Arkema France | Fluides de transfert de chaleur a inflammabilite reduite |
| FR2957083B1 (fr) * | 2010-03-02 | 2015-12-11 | Arkema France | Fluide de transfert de chaleur pour compresseur centrifuge |
| FR2959997B1 (fr) * | 2010-05-11 | 2012-06-08 | Arkema France | Fluides de transfert de chaleur et leur utilisation dans des echangeurs de chaleur a contre-courant |
| FR2959998B1 (fr) * | 2010-05-11 | 2012-06-01 | Arkema France | Fluides de transfert de chaleur ternaires comprenant du difluoromethane, du pentafluoroethane et du tetrafluoropropene |
| JP2013529703A (ja) * | 2010-06-22 | 2013-07-22 | アーケマ・インコーポレイテッド | ヒドロフルオロカーボンとヒドロフルオロオレフィンの熱伝達組成物 |
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2011
- 2011-04-12 PL PL21185415.3T patent/PL3929265T3/pl unknown
- 2011-04-12 CA CA2796051A patent/CA2796051C/en active Active
- 2011-04-12 ES ES18181521T patent/ES2886149T3/es active Active
- 2011-04-12 AU AU2011240740A patent/AU2011240740B2/en active Active
- 2011-04-12 MY MYPI2012004441A patent/MY156787A/en unknown
- 2011-04-12 KR KR1020197031107A patent/KR20190122879A/ko not_active Ceased
- 2011-04-12 RU RU2012148719/05A patent/RU2012148719A/ru not_active Application Discontinuation
- 2011-04-12 EP EP21185415.3A patent/EP3929265B1/en active Active
- 2011-04-12 ES ES21185415T patent/ES2941409T3/es active Active
- 2011-04-12 US US13/640,650 patent/US8765004B2/en active Active
- 2011-04-12 EP EP11715644.8A patent/EP2558544B2/en active Active
- 2011-04-12 PT PT181815218T patent/PT3406688T/pt unknown
- 2011-04-12 KR KR1020187006578A patent/KR102037782B1/ko active Active
- 2011-04-12 DE DE202011111049.8U patent/DE202011111049U1/de not_active Expired - Lifetime
- 2011-04-12 JP JP2013505046A patent/JP2013527273A/ja active Pending
- 2011-04-12 CN CN201180019363.4A patent/CN102844400B/zh active Active
- 2011-04-12 SG SG2012073987A patent/SG184453A1/en unknown
- 2011-04-12 KR KR1020127029921A patent/KR20130051943A/ko not_active Ceased
- 2011-04-12 EP EP18181521.8A patent/EP3406688B1/en active Active
- 2011-04-12 FI FIEP21185415.3T patent/FI3929265T3/fi active
- 2011-04-12 ES ES11715644T patent/ES2698388T5/es active Active
- 2011-04-12 WO PCT/US2011/032072 patent/WO2011130237A1/en not_active Ceased
- 2011-04-12 MX MX2012012012A patent/MX346315B/es active IP Right Grant
- 2011-04-12 PT PT211854153T patent/PT3929265T/pt unknown
- 2011-04-12 PL PL18181521T patent/PL3406688T3/pl unknown
- 2011-04-15 TW TW100113268A patent/TWI540117B/zh active
- 2011-04-15 AR ARP110101305A patent/AR084380A1/es unknown
- 2011-04-16 SA SA111320376A patent/SA111320376B1/ar unknown
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2016
- 2016-04-01 JP JP2016074429A patent/JP6290959B2/ja active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010002020A1 (en) * | 2008-07-01 | 2010-01-07 | Daikin Industries, Ltd. | REFRIGERANT COMPOSITION COMPRISING 1,1,1,2-TETRAFLUOROETHANE (HFC134a) AND 2,3,3,3-TETRAFLUOROPROPENE (HFO1234yf) |
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