KR101918408B1 - 고온강도가 우수한 오스테나이트강 - Google Patents
고온강도가 우수한 오스테나이트강 Download PDFInfo
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- KR101918408B1 KR101918408B1 KR1020170093482A KR20170093482A KR101918408B1 KR 101918408 B1 KR101918408 B1 KR 101918408B1 KR 1020170093482 A KR1020170093482 A KR 1020170093482A KR 20170093482 A KR20170093482 A KR 20170093482A KR 101918408 B1 KR101918408 B1 KR 101918408B1
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- high temperature
- nickel
- temperature strength
- austenitic steel
- manganese
- Prior art date
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 38
- 239000010959 steel Substances 0.000 title claims abstract description 38
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 81
- 239000011572 manganese Substances 0.000 claims abstract description 53
- 239000011651 chromium Substances 0.000 claims abstract description 34
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 26
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 25
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910001566 austenite Inorganic materials 0.000 claims abstract description 19
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 17
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 16
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000011733 molybdenum Substances 0.000 claims abstract description 15
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000010703 silicon Substances 0.000 claims abstract description 14
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 13
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 13
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000012535 impurity Substances 0.000 claims abstract description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 7
- 229910052758 niobium Inorganic materials 0.000 claims description 7
- 229910052721 tungsten Inorganic materials 0.000 claims description 7
- 238000005275 alloying Methods 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 abstract description 28
- 239000000956 alloy Substances 0.000 abstract description 28
- 229910001220 stainless steel Inorganic materials 0.000 abstract description 7
- 239000010935 stainless steel Substances 0.000 abstract description 4
- 230000000704 physical effect Effects 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 32
- 239000012071 phase Substances 0.000 description 25
- 229910000859 α-Fe Inorganic materials 0.000 description 22
- 230000000694 effects Effects 0.000 description 11
- 239000010955 niobium Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 9
- 230000000087 stabilizing effect Effects 0.000 description 8
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 235000012907 honey Nutrition 0.000 description 6
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 5
- 239000010937 tungsten Substances 0.000 description 5
- 238000002441 X-ray diffraction Methods 0.000 description 4
- 238000001887 electron backscatter diffraction Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 238000009864 tensile test Methods 0.000 description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 229910001208 Crucible steel Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- -1 and at the same time Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
Abstract
본 발명에 따른 오스테나이트강은, 탄소(C): 0.35~0.5중량%, 실리콘(Si): 1.0~2.0중량%, 망간(Mn): 6.0~9.0중량%, 니켈(Ni): 13.5~15.5중량%, 크롬(Cr): 23~26중량%, 몰리브덴(Mo): 1.5~4.5중량%, 나머지 철(Fe) 및 불가피한 불순물을 포함하며, 상기 합금원소 중 니켈(Ni) 함량에 대한 망간(Mn) 함량의 비율, CMn/CNi이 0.4~0.65 범위를 유지하는 것을 특징으로 한다.
Description
도 2는 비교예 1~3에 따른 오스테나이트강의 XRD 분석 결과를 나타낸 것이다.
도 3은 본 발명의 실시예 1과 비교예 1에 따른 오스테나이트강의 미세조직 사진이다.
도 4는 본 발명의 실시예 1, 2와 비교예 1~3에 따른 오스테나이트강의 900℃에서 고온 인장시험한 결과를 나타낸 것이다.
강종 | 조성 (중량%) | ||||||||
C | Si | Mn | P | S | Ni | Cr | Mo | Fe | |
비교예 1 | 0.40 | 1.2 | 10.2 | 0.04 | 0.04 | 12 | 25 | 4 | Bal. |
비교예 2 | 0.40 | 1.2 | 7.9 | 0.04 | 0.04 | 14 | 25 | 6 | Bal. |
비교예 3 | 0.40 | 1.2 | 5.6 | 0.04 | 0.04 | 16 | 25 | 2 | Bal. |
비교예 4 | 0.40 | 1.2 | 5.6 | 0.04 | 0.04 | 16 | 25 | 4 | Bal. |
실시예 1 | 0.40 | 1.2 | 7.9 | 0.04 | 0.04 | 14 | 25 | 2 | Bal. |
실시예 2 | 0.40 | 1.2 | 7.9 | 0.04 | 0.04 | 14 | 25 | 4 | Bal. |
강종 | 면적 분율 (%) | |
페라이트 | M7C3 | |
비교예 1 | ~3.3 | 14.1 ± 0.7 |
비교예 2 | ~1.3 | 17.7 ± 0.7 |
비교예 3 | - | 5.0 ± 0.5 |
비교예 4 | ~0.4 | 9.0 ± 0.3 |
실시예 1 | - | 7.3 ± 0.4 |
실시예 2 | ~0.4 | 13.1 ± 0.4 |
강종 | 고온 인장특성 | ||
항복강도 (MPa) |
인장강도 (MPa) |
연신율 (%) |
|
비교예 1 | 94 | 109 | 41.3 |
비교예 2 | 108 | 119 | 71.0 |
비교예 3 | 110 | 127 | 44.5 |
비교예 4 | 100 | 126 | 67.3 |
실시예 1 | 120 | 134 | 38.5 |
실시예 2 | 127 | 143 | 54.0 |
Claims (7)
- 탄소(C): 0.35~0.5중량%, 실리콘(Si): 1.0~2.0중량%, 망간(Mn): 6.0~9.0중량%, 니켈(Ni): 13.5~15.5중량%, 크롬(Cr): 23~26중량%, 몰리브덴(Mo): 1.5~4.5중량%, 나머지 철(Fe) 및 불가피한 불순물을 포함하며,
상기 합금원소 중 니켈(Ni) 함량에 대한 망간(Mn) 함량의 비율, CMn/CNi이 0.4~0.65 범위를 유지하는, 고온강도가 우수한 오스테나이트강 - 제1항에 있어서,
상기 불순물 중, P: 0.04중량% 이하, S: 0.04중량% 이하인, 고온강도가 우수한 오스테나이트강. - 제1항에 있어서,
900℃에서의 인장강도가 130MPa 이상인, 고온강도가 우수한 오스테나이트강. - 제1항에 있어서,
상기 오스테나이트강이 하기 [식 1]로 표시되는 Nieq가 31~33이고,
하기 [식 2]로 표시되는 Creq가 25~32인, 고온강도가 우수한 오스테나이트강.
[식 1]
Nieq = %Ni + 30%C + 0.87%Mn - 0.33%Cu + 30(%N-0.045)
[식 2]
Creq = %Cr + %Mo + %W + 1.5%Si + 0.5%Nb + 5%V + 3%Al - 제1항에 있어서,
상기 오스테나이트강에 포함되는 페라이트 조직은 면적비율로 1% 미만인, 고온강도가 우수한 오스테나이트강. - 제5항에 있어서,
상기 오스테나이트강에 포함되는 M7C3 상은 면적비율로 5~13%인, 고온강도가 우수한 오스테나이트강. - 제1항 내지 제6항 중 어느 한 항에 기재된 오스테나이트강으로 제조한 터보하우징.
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KR1020170093482A KR101918408B1 (ko) | 2017-07-24 | 2017-07-24 | 고온강도가 우수한 오스테나이트강 |
PCT/KR2018/008322 WO2019022460A1 (ko) | 2017-07-24 | 2018-07-24 | 고온강도가 우수한 오스테나이트강 |
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KR1020170093482A KR101918408B1 (ko) | 2017-07-24 | 2017-07-24 | 고온강도가 우수한 오스테나이트강 |
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US20210301379A1 (en) * | 2020-03-28 | 2021-09-30 | Garrett Transportation I Inc | Austenitic stainless steel alloys and turbocharger components formed from the stainless steel alloys |
GB2611819B (en) * | 2021-10-18 | 2024-09-18 | Alloyed Ltd | A heat-resistant austenitic stainless steel |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100428572B1 (ko) | 1999-12-09 | 2004-04-28 | 주식회사 포스코 | 내열강도 및 내산화성이 우수한 내열스테인레스강 |
KR100766251B1 (ko) | 2006-06-09 | 2007-10-12 | 주식회사 포스코 | 고온특성이 우수한 니켈 저감형 오스테나이트계 내열스테인레스강. |
JP2014208875A (ja) | 2013-03-22 | 2014-11-06 | トヨタ自動車株式会社 | オーステナイト系耐熱鋳鋼およびその製造方法 |
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JPH0770700A (ja) * | 1993-08-31 | 1995-03-14 | Nidatsuku Kk | 高耐力高耐食性オーステナイト系ステンレス鋳鋼 |
JP2010280950A (ja) * | 2009-06-04 | 2010-12-16 | Daido Steel Co Ltd | 排気バルブ用耐熱鋼及びその製造方法 |
KR101766039B1 (ko) * | 2015-09-18 | 2017-08-08 | 현대자동차주식회사 | 오스테나이트계 내열볼트 및 그 제조방법 |
US20170088910A1 (en) * | 2015-09-29 | 2017-03-30 | Exxonmobil Research And Engineering Company | Corrosion and cracking resistant high manganese austenitic steels containing passivating elements |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100428572B1 (ko) | 1999-12-09 | 2004-04-28 | 주식회사 포스코 | 내열강도 및 내산화성이 우수한 내열스테인레스강 |
KR100766251B1 (ko) | 2006-06-09 | 2007-10-12 | 주식회사 포스코 | 고온특성이 우수한 니켈 저감형 오스테나이트계 내열스테인레스강. |
JP2014208875A (ja) | 2013-03-22 | 2014-11-06 | トヨタ自動車株式会社 | オーステナイト系耐熱鋳鋼およびその製造方法 |
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