KR101880654B1 - Cosmetic composition containing functional ceramic ball - Google Patents

Abstract

The present invention relates to a cosmetic composition, wherein the cosmetic composition contains a ceramic ball containing a ceramic material, wherein the ceramic ball has the size of 1 to 10 mm. According to at least one of the embodiments of the present invention, far-infrared rays emitted from the functional ceramics are absorbed into the human body, vibrations of water molecules constituting the human body become larger and cellular tissues are activated, thereby increasing the skin temperature of a subcutaneous layer, enlarging blood vessels, promoting blood circulation, promoting metabolism and the like.

Description

TECHNICAL FIELD [0001] The present invention relates to a cosmetic composition containing a functional ceramic ball,

The present invention relates to a cosmetic composition containing a ball-shaped functional ceramics for enhancing the function and effect of a cosmetic composition applied to the skin.

To date, compositions have been developed that incorporate a variety of materials to produce highly effective or newer cosmetics. As a general method, it is applied to a product which is grafted with a new plant or an animal material, and a material of a heterogeneous industry is applied to a cosmetic product in order to apply a more various materials and techniques to a cosmetic product. In the field of heterogeneous industry, food and pharmaceutical materials have been mainly used. In addition, materials of various industries have been used in cosmetics.

(Korean Patent Application No. 2000-60176), which contains ceramics that emit far-infrared rays to improve health, Korean Patent Application No. 2002-15538, which contains ceramics and emits far- , And mats for poultices containing ceramics (Korean Patent Application No. 2000-58021) have been developed by using far-infrared rays emitted from ceramics.

However, research and development on the use of ceramics in cosmetic compositions has not yet been conducted. In order to increase the efficacy, a variety of techniques for developing materials that are combined with cosmetics have been continuously studied.

The present invention is directed to solving the above-mentioned problems and other problems. Another object is to provide a cosmetic composition comprising a functional ceramic ball.

According to an aspect of the present invention, there is provided a cosmetic composition comprising a ceramic ball containing a ceramic material.

According to an aspect of the present invention, the ceramic ball may have a size of 1 to 10 mm.

According to an aspect of the present invention, the ceramic ball may be composed of 40 to 50% of SiO2, 10 to 22% of Al2O3, and the balance of other ceramic materials.

According to an aspect of the present invention, the ceramic ball may further contain 5 to 15% by weight of Fe 2 O 3.

According to an aspect of the present invention, the ceramic ball may further contain 30 to 40% by weight of ZrO2.

According to an aspect of the present invention, the ceramic ball may have a bulk density of 0.5 to 1.5 g / cm 3.

According to one aspect of the present invention, a cosmetic composition comprises a water-like material, and the water-based material is a mineral water containing calcium (Ca), potassium (K), magnesium (Mg) ).

The effects of the cosmetic composition according to the present invention will be described below.

According to at least one of the embodiments of the present invention, the far infrared ray emitted from the functional ceramics is absorbed into the human body, the water molecule vibration constituting the human body becomes larger, and the cell tissue is activated, thereby increasing the skin temperature of the subcutaneous layer, , Promotion of metabolism and so on.

According to at least one of the embodiments of the present invention, waste materials and harmful components are effectively discharged due to the sweating action of the ceramic, and the exercise ability of the human constituent molecules is activated, thereby exhibiting various beneficial effects on the skin.

According to at least one of the embodiments of the present invention, the functional ceramic composition is effective in promoting the metabolism of the human body, removing chlorine and organic substances, removing this hobby, removing fungi and bacteria, activating plants and animals, And the like.

According to at least one of the embodiments of the present invention, the mineral water rich in Ca, K, Mg, and Na contained in the composition is closely related to the constituents of the skin, thereby improving the skin such as moisturizing and skin barrier improvement ≪ / RTI >

Further scope of applicability of the present invention will become apparent from the following detailed description. It should be understood, however, that the detailed description and specific examples, such as the preferred embodiments of the invention, are given by way of illustration only, since various changes and modifications within the spirit and scope of the invention will become apparent to those skilled in the art.

1 is a far infrared ray emissivity graph according to the size of a ceramic ball according to an embodiment of the present invention.
FIG. 2 is a graph of far-infrared radiation energy according to the size of a ceramic ball according to an embodiment of the present invention.

Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings, wherein like or similar components are denoted by the same reference numerals, and redundant explanations thereof will be omitted. The suffix "part" for the constituent elements used in the following description is to be given or mixed with consideration only for ease of specification, and does not have a meaning or role that distinguishes itself. In the following description of the embodiments of the present invention, a detailed description of related arts will be omitted when it is determined that the gist of the embodiments disclosed herein may be blurred. It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory and are intended to provide further explanation of the invention as claimed. , ≪ / RTI > equivalents, and alternatives.

The singular expressions include plural expressions unless the context clearly dictates otherwise.

In the present application, the terms "comprises", "having", and the like are used to specify that a feature, a number, a step, an operation, an element, a component, But do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, or combinations thereof.

In one embodiment of the present invention, there is provided a composition for solving various skin problems using functional ceramic materials and minerals used in high-tech products and environmental products.

To this end, in one embodiment of the present invention, a ceramic ball formed into a spherical shape is used so that it can be realized to be free from loss of far-infrared rays and anions without being mixed with the contents of the shape, and mineral water water) is used to maximize the effect on the skin.

Far-infrared ray means that the wavelength of infrared rays is long. Generally, light has a good reflection when its wavelength is short, and it has a property of being absorbed when it reaches an object if its wavelength is long, and it is strong when it penetrates, so that a human body gets warm when it receives far infrared ray. This heat helps to eliminate germs that cause various diseases, and it enlarges the capillaries and helps blood circulation and cell tissue formation. It is effective in prevention of various diseases such as anti-aging, metabolism promotion, chronic fatigue and so on.

For example, a far-infrared ray having a wavelength range of about 4 to 100 탆 has the longest wavelength in the ultraviolet region, and the intermolecular intermolecular bonding or intermolecular bonding formed in the molecule is formed in a form such as stretching or scissoring As shown in Fig.

In one embodiment of the present invention, a technique relating to a cosmetic composition comprising a water-containing mineral and a ceramic ball having a size of 1 to 10 mm is disclosed, wherein the cosmetic composition comprises a water- In addition to the ball, it may further include an ethanol phase or an oil phase. At this time, the water phase may contain various components such as mineral water, disodium iodide, adenosine, niacinamide, glycerin, butylene glycol and the like.

The cosmetic composition according to one embodiment of the present invention contains a ball-shaped functional ceramic emitting far-infrared rays and anions. By utilizing the far-infrared rays and anions emitted by the ceramic material, skin temperature rise of the subcutaneous layer, vasodilation, Promoting, promoting metabolism, moisturizing, relieving troubles, removing chlorine and organic matter, removing this hobby, removing fungi and bacteria.

For this purpose, the size of the ceramic ball in the embodiment of the present invention is limited to 1 to 10 mm. If the size of the ceramic ball is smaller than 1 mm, the ceramic used in the cosmetic composition is almost in the form of powder, It is possible to easily cause a phenomenon in which the color changes or the odor is formed or the stability of the formulation is largely decreased or the physical property is changed. Furthermore, when applied to transparent liquid formulations, various problems may occur, such as that the contents may become cloudy or precipitate may occur. On the other hand, when the size of the ceramic ball is larger than 10 mm, it may be limited to use in various types of cosmetic compositions, and the amount of far-infrared radiation per unit area may be reduced. In this embodiment, To 10 mm. By using a ceramic ball having a size within the above range, it is possible to realize a highly stable composition without any abnormal phenomenon such as discoloration, peeling, phase separation in the stability of the formulation.

FIG. 1 is a far infrared ray emissivity graph according to the size of a ceramic ball according to an embodiment of the present invention, and FIG. 2 is a far infrared ray emission energy graph according to the size of a ceramic ball according to an embodiment of the present invention.

Referring to FIGS. 1 and 2, the emissivity and radiant energy of the far infrared ray are high, the maximum value of the emissivity is 0.926, and the maximum value of the radiant energy is 357 W / m ²占 퐉 when the size of the ceramic ball is 1 to 10 mm.

In this case, the ceramic ball in the embodiment of the present invention has a spherical ball shape composed of SiO2, Al2O3, Fe2O3, ZrO2, CaO, etc. and has a diameter of 1 to 10 mm (preferably 3 to 5 mm) And can be used in various forms of cosmetic composition. Far infrared radiation energy is about 366 W / m ²占 퐉 at 40 占 폚, and anion has 880 ion / cc, so that it can effectively impart skin effect. May include at least one ceramic material such as SiO2, Al2O3, Fe2O3, ZrO2, and CaO. In one embodiment of the present invention, SiO2 and Al2O3 are limited to the basic components. However, the present invention is not limited to this, and it is also within the scope of the present invention to perform any one of SiO 2, Al 2 O 3, Fe 2 O 3, ZrO 2 and CaO in the range described below.

The ceramic ball according to an embodiment of the present invention may include 40 to 50% by weight of SiO2 and 10 to 22% by weight of Al2O3. If the content of SiO2 is less than 40% by weight, the expansion ratio becomes large and weakens due to heat change. Therefore, the strength and durability of the ceramic ball are weakened and the amount of far-infrared radiation energy generated is decreased. And the amorphous property may be broken and the weight may be slightly changed depending on the humidity. Therefore, in one embodiment of the present invention, SiO 2 is limited to 40 to 50 wt%.

When Al 2 O 3 is less than 10% by weight, it can be weakened by acid and alkali. Therefore, it should be limitedly applied to various cosmetic compositions such as foam cleansing with high alkalinity and high-pH skin exfoliating agent. If it exceeds 22% by weight, the crystallinity may be deteriorated and the aluminum may be broken, and some excess aluminum may be adsorbed at the time of production and the composition may be irregularly produced. Therefore, in one embodiment of the present invention, Al2O3 is limited to 10 to 22 wt%.

If Fe2O3 is less than 5% by weight, it may become unstable in sunlight and heat, and there is room for change of physical properties at high temperature, and the ionicity is decreased and the amount of generated negative ions is irregular If it exceeds 15% by weight, it may be partially oxidized in the storage condition or composition, and the color may change or become weak to moisture.

If ZrO2 is less than 10% by weight, the aesthetics may decrease and the surface may appear irregular, the strength and durability may be lowered, and the amount of far-infrared radiation energy may be remarkably lowered And when it exceeds 22% by weight, the hardness is greatly increased, making it difficult to manufacture and process a ball shape in a general manufacturing facility.

In addition, the bulk density of the ceramic balls in the embodiment of the present invention is limited to 0.5 to 1.5 g / cm 3. If the bulk density of the ceramic balls is less than 0.5 g / cm 3, the ceramic ball is broken or weakened, Or a fine powder may be generated. When it exceeds 1.5 g / cm 3, the hardness becomes high and processing is difficult, and the manufacturing cost and other costs may be increased.

In one embodiment of the present invention, the mineral water contains calcium (Ca), potassium (K), magnesium (Mg), sodium (Na) and the like so as to exhibit excellent efficacy in moisturizing and skin barrier improvement.

Hereinafter, embodiments of the present invention will be described in more detail.

≪ Example 1 >

First, a ceramic ball made of 45% by weight of SiO2, 33% by weight of ZrO2, 13% by weight of Al2O3, and other ceramics was manufactured according to an embodiment of the present invention.

The far-infrared emissivity measured by the FT-IR spectrometer at 37 ° C was about 0.926 in the range of 5 to 20 mm, and the maximum radiant energy of far infrared rays of the ceramic ball was 357 W / m ² · ㎛.

Further, the amount of anions emitted from 20 g of the ceramic balls was measured under the conditions of a room temperature of 21 ° C, a humidity of 34%, and an ion concentration of 102 ions / cc using an electric charge particle measuring apparatus. As a result, the number of negative ions was 880 ion / cc.

Hereinafter, the process for preparing a cosmetic composition according to one embodiment of the present invention will be described.

≪ Example 2 >

First, a mixture of 0.02 g of disodium iodide, 0.05 g of dipotassium glycyrrhizate, 0.04 g of adenosine, 2.00 g of niacinamide, 1.30 g of betaine, 1.50 g of glycerin, 2.50 g of butylene glycol, 0.70 g of methylethyldimethylsilane and the aqueous phase containing the mineral water is completely dissolved by stirring at a speed of 20 to 30 rpm for 10 to 15 minutes.

Thereafter, the ethanol phase containing 3.50 g of ethanol, 0.25 g of Pigment-60 hydrogenated castor oil and 0.05 g of fragrance was heated to 40 ° C and stirred until completely dissolved. The dissolved ethanol phase is slowly added to the aqueous phase and solubilized at a rate of 20 to 30 rpm. Thereafter, when the introduction of the ethanol phase is completed, the mixture is stirred at a speed of 20 to 30 rpm for 3 to 5 minutes, and then the transparency is confirmed.

Then, additives such as a preservative, a coloring agent, an extract and the like were added and the transparency was confirmed. Then, the ceramic ball prepared in Example 1 was washed with purified water and dried in a thermostat, and then 20.00 g of a ceramic ball was further added.

At this time, the additive and the mineral water are added in an appropriate amount so that the total weight of the cosmetic composition is 100 g.

The cosmetic composition according to one embodiment of the present invention produced by the above process contains a ceramic ball which emits far-infrared rays and anions. The cosmetic composition may be a liquid containing an aqueous phase, for example, a skin, lotion, essence, hair tonic, hair liquid, or perfume, but the scope of the present invention is not limited thereto. For example, the ceramic ball may be used in the form of a cream, a lotion, or the like, which is an emulsified product. Thus, the cosmetic composition according to one embodiment of the present invention can be used in all cosmetic formulations.

On the other hand, the moisturizing power of the cosmetic composition prepared in Example 2 was measured. The skin moisturizing power in one embodiment of the present invention was determined by electric conductivity.

The experimental method is as follows.

First, the sides of the subject's left and right lower abdomen are lightly rinsed with water before the experiment, and then allowed to stand in a constant temperature and humidity condition (25 ° C, 40%) for at least 20 minutes to stabilize the skin condition. Draw 6 circles (3 each on the left and right) of the probe size of the Skicon-200EX to specify the measurement site. Each measurement site before the application of the sample was measured three times with Skicon-200EX and the average value was used as the measurement value before the sample application. 20 μl of each sample was applied to the measurement site, and the electrical conductivity was measured by the same method for 30 minutes, 1 hour, 2 hours and 4 hours, and the measured values were measured three times.

Moisture (electric conductivity) measurement result Example 2 Comparative Example 1 Comparative Example 2 Before application 52 52 52 30 minutes 183 122 159 1 hours 175 104 131 2 hours 159 87 123 4 hours 148 68 119

<Unit: μS / cm>

In Table 1, Comparative Example 1 is an experimental example in which ceramic balls are not added at all, and Comparative Example 2 is an experimental example in which 10 g of ceramic balls are added.

As can be seen from the above Table 1, the highest electric conductivity value was observed at 30 minutes after application, and the value tended to decrease with time. In Example 2, the highest electrical conductivity value was obtained, and Comparative Example 1 showed the smallest value. The decrease in the electrical conductivity with time shows that the electrical conductivity of Example 2 is the lowest even though the electrical conductivity is the highest, and the electrical conductivity of Comparative Example 1 is the greatest drop even though the electrical conductivity is the lowest.

As can be seen from the comparison between Comparative Example 1 and Example 2, it was found that the skin moisturizing effect of the cosmetic product was more excellent when the ceramic ball was added, and when comparing Comparative Example 2 and Example 2, It can be seen that the case of containing an appropriate amount is more effective than the case where the content is very small.

The following is the measurement result of transepidermal water loss (TEWL).

Percutaneous water loss refers to the amount of water lost through the skin. To measure this, the patient's face should be lightly washed with water before the test, and then allowed to stand for at least 20 minutes under constant temperature and humidity conditions (25 ° C, 40% do. The amount of transdermal water loss was measured three times using Tewameter TM 210 (C + K electronic GmbH, Germany) for 30 minutes, 1 hour, 2 hours, 4 hours and 6 hours, Respectively.

Results of transdermal water loss measurement Example 2 Comparative Example 1 Comparative Example 2 30 minutes 15.1 17.3 16.5 1 hours 13.7 15.8 14.3 2 hours 10.5 14.1 12.1 4 hours 8.3 12.8 9.8 6 hours 5.9 10.5 7.3

<Unit: g / m ² / h>

As can be seen from Table 2, the maximum amount of transdermal water loss is shown at 30 minutes after application, and the amount of loss tends to decrease with time. In Example 2, the transdermal water loss was the smallest, and in Comparative Example 1, the transdermal water loss was the largest. In addition, when the amount of transdermal water loss according to time is examined, it can be seen that the amount of percutaneous water loss is remarkably decreased in Example 2 over time, whereas the value of percutaneous water loss in Comparative Example 1 is much greater than in other experimental examples.

The efficacy of the cosmetic composition provided in one embodiment of the present invention shows effects such as improvement of skin texture, improvement of skin tone, increase of cell regeneration ability and skin soothing effect, and also shows excellent effects on skin safety.

The foregoing detailed description should not be construed in all aspects as limiting and should be considered illustrative. The scope of the present invention should be determined by rational interpretation of the appended claims, and all changes within the scope of equivalents of the present invention are included in the scope of the present invention.

Claims (7)

A ceramic ball comprising ceramic material,
Wherein the ceramic ball has a size of 1 to 10 mm and comprises 40 to 50% by weight of SiO2, 10 to 22% by weight of Al2O3, and the balance of other ceramics. delete delete The method according to claim 1,
Wherein the other ceramic material comprises Fe2O3, and the Fe2O3 is 5 to 15% by weight of the total weight of the ceramic balls. The method according to claim 1,
Wherein the other ceramic material comprises ZrO2, and the ZrO2 is 30 to 40% by weight of the total weight of the ceramic ball. The method according to claim 1,
Wherein the ceramic ball has a bulk density of 0.5 to 1.5 g / cm &lt; 3 &gt;. The method according to claim 1,
Wherein the cosmetic composition comprises a water phase and the water phase includes mineral water containing calcium (Ca), potassium (K), magnesium (Mg), and sodium (Na) / RTI &gt;

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