KR101814271B1 - A manufacturing method of a bubble cement board and a bubble cement board foam made thereby - Google Patents

A manufacturing method of a bubble cement board and a bubble cement board foam made thereby Download PDF

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Publication number
KR101814271B1
KR101814271B1 KR1020160025011A KR20160025011A KR101814271B1 KR 101814271 B1 KR101814271 B1 KR 101814271B1 KR 1020160025011 A KR1020160025011 A KR 1020160025011A KR 20160025011 A KR20160025011 A KR 20160025011A KR 101814271 B1 KR101814271 B1 KR 101814271B1
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KR
South Korea
Prior art keywords
weight
cement
mixture
cement board
room temperature
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KR1020160025011A
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Korean (ko)
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KR20170102646A (en
Inventor
한경환
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한경환
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Priority to KR1020160025011A priority Critical patent/KR101814271B1/en
Publication of KR20170102646A publication Critical patent/KR20170102646A/en
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Publication of KR101814271B1 publication Critical patent/KR101814271B1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/02Cellulosic materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04Macromolecular compounds
    • C04B16/06Macromolecular compounds fibrous
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • C04B28/065Calcium aluminosulfate cements, e.g. cements hydrating into ettringite
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/76Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
    • E04B1/78Heat insulating elements
    • E04B1/80Heat insulating elements slab-shaped
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/30Water reducers, plasticisers, air-entrainers, flow improvers

Abstract

The present invention relates to a cement composition comprising 75 to 80% by weight of Portland cement, 7 to 10% by weight of CSA cement, 3 to 5% by weight of Selenite, 0.5 to 1% by weight of hydrogen peroxide, 1 to 5% by weight of lithium carbonate, Citric acid, 0.1 to 0.7 wt% of fiber, 0.5 to 1 wt% of calcium stearate, 1 to 3 wt% of hydroxyethyl cellulose, 1 to 3 wt% of ammonium phosphate ) And 3 to 5% by weight of a water reducing agent; Mixing 40 to 50% by weight of water with respect to the total weight of the mixture, and kneading the mixture at room temperature; And a step of putting the kneaded product into a mold and aging the kneaded product at room temperature. The present invention also provides a method for producing a porous lightweight foam and a bubble cement board manufactured by the method.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a bubble cement board and a bubble cement board produced by the bubble cement board,

The present invention relates to a method of manufacturing a bubble cement board and a bubble cement board manufactured by the method, and more particularly, to a method of manufacturing a bubble cement board excellent in heat insulation, soundproofing and nonflammability, and a bubble cement board .

Generally, in order to prevent the heat loss in the building and to increase the insulation effect, the insulation is applied during the building construction. Such a heat insulating material is a glass surface, vermiculite, perlite, airgel or the like for flame retardancy in addition to the adiabatic effect.

However, since the glass surface has a sealed air layer formed between the glass fibers, it is excellent in heat insulation, nonflammability, sound absorption, etc. However, there is a fear of reduction in effective thickness due to compression or settlement and deterioration of heat insulation due to function. There is a problem that it is necessary. Further, there is a problem that high energy of 1,000 DEG C or more is required for foaming of minerals such as vermiculite or perlite. In the case of aerogels, the structures with a thickness of one tenth of a hair are entangled like cotton candy, and the air holes occupy 95% of the total volume, which is advantageous in terms of insulation and soundproofing. However, due to the disadvantage of relatively high cost, And the like.

For this reason, recently, ALC (Autoclaved Lightweight Concrete) is attracting attention. It is a type of lightweight foamed concrete in which cement and foaming agent are added to lime and the mixture made porous by foam system is steam cured at high temperature and high pressure.

However, since such lightweight foamed concrete is cured in a high-temperature and high-pressure reactor, it is expensive to install the facility and requires a long time to cure the cement. Particularly, when lightweight foamed concrete is directly applied without curing, the curing time is several days or more, so that the bond between the foamed cement particles and the particles is broken, and the compressive strength after curing is remarkably decreased.

Korean Patent Publication No. 10-2000-0060707

It is an object of the present invention to solve the above-mentioned problems, and it is an object of the present invention to reduce the cost by using ordinary Portland cement and to reduce the energy cost by foaming and curing more uniformly and rapidly at room temperature without using a separate foaming agent Soundproofing, sound-absorbing property, and nonflammability, while maintaining the required compressive strength, and a bubble cement board manufactured by this manufacturing method.

According to an aspect of the present invention, there is provided a cement paste composition comprising 75 to 80 wt% of Portland cement, 7 to 10 wt% of CSA cement, 3 to 5 wt% of Selenite, 0.5 to 1 wt% of hydrogen peroxide, 1 to 5 wt% of lithium carbonate 0.1 to 0.5% by weight of citric acid, 0.1 to 0.7% by weight of fibers, 0.5 to 1% by weight of calcium stearate, 1 to 3% by weight of hydroxyethyl cellulose, 1 to 3% by weight of ammonium (Ammonium Phosphate) and 3 to 5% by weight of a water reducing agent; Mixing 40 to 50% by weight of water with respect to the total weight of the mixture, and kneading the mixture at room temperature; And aging the kneaded product at room temperature by injecting the kneaded product into a mold.

According to another aspect of the present invention, there is provided a method of manufacturing a bubble cement board, wherein the CSA cement has a plurality of pores formed by firing at 800 ° C or higher and quenched.

According to another aspect of the present invention, there is provided a bubble cement board, which is manufactured by the above-described manufacturing method.

As described above, according to the present invention, it is possible to provide a bubble cement board in which a foamed structure is formed at room temperature without using a foaming agent, so that it is light in weight and low in cost and does not require a production facility like a conventional reactor, The cost is reduced. The bubble cement board is more uniform and stabilized in foamed structure by hydroxyethyl cellulose, so that it maintains a certain compressive strength and is excellent in sound insulation and sound absorption as well as in heat insulation, has a short curing time, Do. On the other hand, since CSA cement as a raw material of the bubble cement board is quenched and quenched to form a plurality of pores as compared with the prior art, sound insulation and sound absorption are more excellent, so that the interlayer noise of a building can be more effectively solved to provide a pleasant living space And it is excellent in nonflammability, so that even if fire is generated by other interior materials, toxic gas is not generated, safety is improved, environmentally friendly, and damage scale can be reduced.

The objects, features and advantages of the present invention will become more apparent from the following detailed description. Hereinafter, preferred embodiments of the present invention will be described.

A method of manufacturing a foamed cement board according to an embodiment of the present invention includes a process of making a mixture, a process of kneading the mixture with water, and a process of putting the kneaded material into a mold and aging the mixture. Hereinafter, the mixture will be described first.

Herein, the mixture may be selected from conventional Portland cement, CSA cement, gypsum, hydrogen peroxide, lithium carbonate, citric acid, fiber, calcium stearate, hydroxyethyl cellulose, ammonium phosphate (Ammonium Phosphate), and a water reducing agent.

Cement is divided into air hard cement which is categorized largely by air, hard cement which is hardened in air and water, and special cement which is cured in air. Portland cement which is called general cement is hydraulic cement. At this time, it is preferable to add 75 to 80% by weight of the Portland cement into the mixture.

The above-mentioned CSA (Calcium Sulfo-Aluminate) cement is known to be made of lime, gypsum and bauxite materials, and is known as ultra fast cement and expansion cement. It has a characteristic that the coagulation time and intensity development speed are much faster than other general cements .

Unlike the conventional CSA cement, the present invention is characterized in that the CSA cement is produced by sintering the material at approximately 800 캜 and quenched. That is, the conventional CSA cement is manufactured by calcining the material and then cooling the material. However, in the present invention, a plurality of pores are retained without being bubbled by rapidly cooling the material in a state where a plurality of pores are formed. It is preferable to add 7 to 10 wt% of the CSA cement into the mixture. At this time, the input amount of the Portland cement and CSA cement is determined in consideration of the optimized state due to the physical properties and mixing ratio of the remaining raw materials of the mixture.

The gypsum is added for the purpose of producing etringite as is well known. Anhydrous gypsum is used for such gypsum, and it is preferable to add 3 to 5 wt% to the mixture. When the amount of gypsum is less than 3% by weight, the amount of etrinzite is small and the initial strength of the present invention deteriorates. When the amount of gypsum is more than 5% by weight, the length of etinzite is shortened and the strength development is inhibited.

The hydrogen peroxide is mixed with Portland cement to generate air bubbles, and it is preferable to add 0.5 to 1 wt% of the hydrogen peroxide into the mixture. If the amount of hydrogen peroxide is less than 0.5 wt%, the effect of hydrogen peroxide is insignificant. If the amount of hydrogen peroxide is more than 1 wt%, the effect of hydrogen peroxide on the increase of the amount of input is hardly obtained.

Lithium carbonate (CRC) helps to cure the cement rapidly to improve initial strength and ensure initial fluidity. Such lithium carbonate is preferably added in an amount of 1 to 5 wt% in the mixture. If the amount of lithium carbonate is less than 1% by weight, it is difficult to obtain a controlled effect. If the amount of lithium carbonate is more than 5% by weight, the coagulation time may be excessively delayed or skewed.

Citric acid is a known retarder for delaying the condensation of concrete by suppressing the hydration reaction of cement, and is for controlling the time when the lightweight foam is injected into the mold and foamed. Such citric acid is preferably added in an amount of 0.1 to 0.5 wt% in the mixture. When the content of citric acid is less than 0.1% by weight, the effect of citric acid is insignificant. If the content exceeds 0.5% by weight, proper mixing with other raw materials may be impaired and the physical properties may be deteriorated.

The fibers prevent cracking of the foamed cement board according to the present invention, and both plant fiber and chemical fiber can be used. It is preferable that 0.1 to 0.7% by weight of the fiber is added to the mixture. If the fiber content is less than 0.1% by weight, it is easily broken by a small impact or the like. If the fiber content exceeds 0.7% by weight, some fibers are not smoothly mixed and aggregated.

The calcium stearate is a well-known waterproof material for preventing the penetration of water into the pores of the cement, and it is preferable to add 0.5 to 1% by weight of the calcium stearate into the mixture. If the amount of calcium stearate is less than 0.5% by weight, the water repellency is insignificant. If the amount of calcium stearate is more than 1% by weight, water repellency is good, but mixing with water is difficult and workability is deteriorated.

Hydroxyethyl cellulose (Hydroxyethyl Cellulose) allows the bubbles generated when the water is mixed with the mixture to be stably and uniformly dispersed. It also disperses the fibers substantially evenly within the mixture. Such hydroxyethyl cellulose is added in an appropriate amount depending on the interaction with other components of the mixture, and preferably 1 to 3 wt% is added.

The ammonium phosphate promotes the curing of the cement at room temperature, and monoammonium phosphate is preferably used. Such ammonium phosphate is preferably added in an amount of 1 to 3% by weight in the mixture. When the amount of ammonium phosphate is less than 1% by weight, it is difficult to secure an initial high strength. When the amount is more than 3% by weight, sufficient time for foaming can not be secured.

The water reducing agent is an admixture which improves the strength and durability by reducing the amount of water required for mixing the mixture and promoting the coagulation. As is well known, a polycarboxylic acid type, melamine type, amino sulfonic acid type or naphthalene type water reducing agent can be used. However, in the present invention, it is preferable to use a high-performance water reducing agent (Superplasticizer) having a better dispersing effect than a general water reducing agent. Such a water reducing agent is preferably added in an amount of 3 to 5 wt% in the mixture.

Then, water is added to the mixture in which the raw materials are mixed and kneaded. The amount of water is preferably 40 to 50% by weight based on the total weight of the mixture, and the mixture is kneaded at room temperature for a certain period of time. If the amount of water is less than 40% by weight, the effect of accelerating the curing of the CSA cement hardly occurs. If the amount of water exceeds 50% by weight, the curing of the CSA cement proceeds rapidly, but the foamed structure is not uniformly formed. Then, the kneaded product is put into a mold of a predetermined type and aged at a room temperature for a certain period of time. At this time, the completed product may be cut and subjected to plastic working in various molds.

The foamed cement board according to one embodiment of the present invention produced by mixing hydrogen peroxide with Portland cement generates bubbles and pores formed in the CSA cement are added to form a foamed structure having a larger number of pores, The foamed structure is more uniformly formed by the ethyl cellulose, and the foamed structure is complemented and stabilized by the above-mentioned mixtures, and the foamed structure is more stabilized by the ammonium phosphate particularly at room temperature.

As a result, the foamed structure having a plurality of pores in a short time is more uniformly cured, and the foamed structure is uniformly formed without being broken. Therefore, it is light in weight, maintains proper strength, and is excellent in heat insulation and sound absorption effect. Therefore, it is possible to reduce the noise level of the building by installing it as the insulation wall of the building, so that it can create a comfortable living environment and it is excellent in the incombustibility, so that even if a fire occurs through other interior materials, toxic gas is not emitted, It is environmentally friendly and has a long lifetime because of its excellent bonding strength between foamed tissues. Since it is manufactured at room temperature, facilities such as a reactor are not required as in the prior art, and production equipment costs are reduced.

It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit or scope of the inventions. It will be apparent to those of ordinary skill in the art.

Claims (3)

7 to 10% by weight of CSA cement having a large number of pores formed by sintering at a temperature of 800 ° C or higher after 75 to 80% by weight of Portland cement, 800 ° C or more, 3 to 5% by weight of gypsum, 0.5 to 1% by weight of hydrogen peroxide, 1 to 5% by weight of lithium carbonate, 0.1 to 0.5% by weight of citric acid, 0.1 to 0.7% by weight of fibers, 0.5 to 1% by weight of calcium stearate, 0.5 to 1% by weight of hydroxyethyl cellulose, 1 to 3% by weight of ammonium phosphate, 1 to 3% by weight of ammonium phosphate, and 3 to 5% by weight of a water reducing agent;
Mixing 40 to 50% by weight of water with respect to the total weight of the mixture, and kneading the mixture at room temperature; And
And aging the kneaded product at room temperature by injecting the kneaded product into a mold.
delete 7 to 10% by weight of CSA cement having a large number of pores formed by sintering at a temperature of 800 ° C or higher after 75 to 80% by weight of Portland cement, 800 ° C or more, 3 to 5% by weight of gypsum, 0.5 to 1% by weight of hydrogen peroxide, 1 to 5% by weight of lithium carbonate, 0.1 to 0.5% by weight of citric acid, 0.1 to 0.7% by weight of fibers, 0.5 to 1% by weight of calcium stearate, 0.5 to 1% by weight of hydroxyethyl cellulose, 1 to 3% by weight of ammonium phosphate, 1 to 3% by weight of ammonium phosphate, and 3 to 5% by weight of a water reducing agent;
Mixing 40 to 50% by weight of water with respect to the total weight of the mixture, and kneading the mixture at room temperature; And
And then aging the kneaded product at room temperature by injecting the kneaded product into a mold.
KR1020160025011A 2016-03-02 2016-03-02 A manufacturing method of a bubble cement board and a bubble cement board foam made thereby KR101814271B1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102032130B1 (en) * 2019-06-24 2019-11-08 곽장해 Manufacturing method of ultra light weight bubble cement board and the ultra light weight bubble cement board foam made by the same
CN112898043B (en) * 2021-03-19 2022-06-24 北京中科原创节能环保科技有限公司 High-temperature-resistant energy-saving insulation board for industrial furnace and preparation method
CN113149581B (en) * 2021-05-12 2022-04-15 山东鲁泰建材科技集团有限公司 Concrete companion plate and preparation process thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100594712B1 (en) * 1998-01-16 2006-07-03 세나드 테크니크베통 아베 Method for injecting of foamed concrete and a foamed concrete
KR101360261B1 (en) * 2013-11-19 2014-02-11 임성호 Manufacturing method of light weight bubble cement using composition of light weight bubble cement

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100594712B1 (en) * 1998-01-16 2006-07-03 세나드 테크니크베통 아베 Method for injecting of foamed concrete and a foamed concrete
KR101360261B1 (en) * 2013-11-19 2014-02-11 임성호 Manufacturing method of light weight bubble cement using composition of light weight bubble cement

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