KR20040080665A - Bubble concrete mortar composition and its manufacturing process - Google Patents

Bubble concrete mortar composition and its manufacturing process Download PDF

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KR20040080665A
KR20040080665A KR1020030015543A KR20030015543A KR20040080665A KR 20040080665 A KR20040080665 A KR 20040080665A KR 1020030015543 A KR1020030015543 A KR 1020030015543A KR 20030015543 A KR20030015543 A KR 20030015543A KR 20040080665 A KR20040080665 A KR 20040080665A
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weight
insulation
cement
mortar composition
heat
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KR100547951B1 (en
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안기주
김동수
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안기주
안용호
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/0445Synthetic gypsum, e.g. phosphogypsum
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • C04B20/04Heat treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/06Oxides, Hydroxides
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/06Oxides, Hydroxides
    • C04B22/062Oxides, Hydroxides of the alkali or alkaline-earth metals
    • C04B22/064Oxides, Hydroxides of the alkali or alkaline-earth metals of the alkaline-earth metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/08Acids or salts thereof
    • C04B22/10Acids or salts thereof containing carbon in the anion
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/38Polysaccharides or derivatives thereof
    • C04B24/383Cellulose or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/02Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/52Sound-insulating materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

PURPOSE: Provided is a preparation method of foam concrete mortar composition with incombustibility, heat insulation, and sound absorption and insulation by using phosphogypsum as a main material. CONSTITUTION: The foam concrete mortar composition is prepared by dry-mixing 30-70wt.% of phosphogypsum as a main material and auxiliary materials. The phosphogypsum, generated after fertilizer production, for use as a main material is dried at 150-800deg.C for 30-40min to remove moisture and harmful materials. The auxiliary materials comprise 20-40wt.% of cement, 2-20wt.% of yellow earth, kaolin or feldspar, 0.01-0.5wt.% of foaming material such as Al2O3 or Zn, 2-5wt.% of foaming catalysts such as CaO and carbonate, 0.01-5wt.% of separation inhibitor such as methyl cellulose, wood powder or rice hull, 0.5-3wt.% of concrete strength-reinforcing material, and 3-15wt.% of tensile strength-reinforcing material such as sepiolite. The resultant mortar is easily applied in the construction field by mixing with water.

Description

불연, 단열, 보온, 흡 . 차음 기능을 갖는 기포 콘크리트 몰타르 조성물 및 이의 제조방법{Bubble concrete mortar composition and its manufacturing process}Non-combustible, heat insulation, heat insulation, absorption. Bubble concrete mortar composition and its manufacturing process

본 발명은 불연, 단열, 보온, 흡 . 차음 기능을 갖는 기포 콘크리트 몰타르 조성물 및 이의 제조방법에 관한 것으로서, 더욱 상세하게는 수분제거와 함침된 미량의 공해물질을 안정화시키기 위해 150℃ ~ 800℃의 조건에서 고온 열처리된 인산석고 30 ~ 70중량%를 주재료로 하고, 부재료로써 시멘트 20 ~ 40중량%, 황토 또는 고령토, 장석분말 2 ~ 20중량%, 기포발포제(알루미나 분말 또는 아연 분말) 0.01 ~ 0.5중량%, 발포촉매제(생석회, 탄산염) 2 ~ 5중량%, 분리방지 안정제(메틸셀룰로오스, 목분 또는 왕겨) 0.01 ~ 5중량%, 콘크리트 강도 강화제 0.5 ~ 3중량%, 인장력 강화제(해포석) 3 ~ 15중량%를 건식 혼화시킴으로써 고층의 주거 건축물 등의 층간 또는 벽체에 충격, 소음을 차단함과 아울러 불연성, 단열성, 보온성 기능을 가지도록 한 불연, 단열, 보온, 흡 . 차음 기능을 갖는 기포 콘크리트 몰타르 조성물 및 이의 제조방법에 관한 것이다.The present invention is non-combustible, heat insulation, heat insulation, absorption. The present invention relates to a foamed concrete mortar composition having a sound insulation function and a method of manufacturing the same, and more particularly, to hydrated plaster and high temperature heat-treated at 150 ° C. to 800 ° C. to stabilize trace amounts of pollutants. % As main material, 20-40% by weight of cement, loess or kaolin, 2-20% by weight of feldspar powder, 0.01-0.5% by weight of foam foaming agent (alumina powder or zinc powder), foaming catalyst (quick lime, carbonate) 2 ~ 5% by weight, dry anti-separation stabilizer (methylcellulose, wood flour or rice husk) 0.01 ~ 5% by weight, concrete strength reinforcement 0.5 ~ 3% by weight, tensile strength reinforcement (calculated stone) by dry blending high-rise residential buildings, etc. Non-combustible, heat-insulated, heat-insulated, and non-combustible to prevent shock, noise, and non-flammability, heat insulation, and heat insulation. It relates to a foamed concrete mortar composition having a sound insulation function and a method for producing the same.

일반적으로 현대사회를 살아가는 모든 사람들은 급속도로 주거 문화의 변화속에서 좀 더 나은 주거 공간을 추구하며, 살아온 과정에서 주거 용지의 부족과 건축 기술의 발달로 주거용 건축물은 날로 고층화되고 있는 시점에서 쾌적하고 온화하며, 조용한 자기만의 주거공간을 소유하고자 노력하고 있으며, 그 속에서 자기 가족의 행복 추구권리를 만끽하고자 하는 것이 모든 인간들의 바람이라 할 것이다.In general, all people living in modern society rapidly seek better living spaces in the change of residential culture, and in the process of living, residential buildings are pleasant at the time of high rise due to lack of residential land and development of building technology. It is the desire of all human beings that they are trying to own their own, quiet and quiet living space, and enjoy the right to pursue their own happiness.

그로 인하여 가장 중시되고 있는 부분은 주거 공간내의 난방부문과 계층간에서 발생되어질 수 있는 불쾌한 충격음과 소음이라 할 것이다.Therefore, the most important part is the unpleasant impact sound and noise that can be generated between the heating sector and the class in the living space.

그로 인하여 가장 친밀하고 가깝게 살아야 할 층간 이웃끼리의 끊이지 않는 불협화음 및 민원발생으로 급기야 정부에서는 2002년 11월 아파트 바닥충격소음기준을 정하고 이를 입법예고하는 지경에 이르렀다.As a result, due to the constant dissonance and complaints between the neighbors who are most intimate and close to each other, the government has set the standard for floor impact noise in November 2002 and predicted legislation.

이러한 상황을 발마추어 많은 연구가들에 의해 단열층을 갖는 경량 콘크리트 및 이의 제조방법 등이 많이 제시되어 왔으나 실용화에 있어 그 효용성이 의문시되었다.In light of this situation, many researchers have suggested a lot of lightweight concrete with a heat insulating layer and a method of manufacturing the same, but its utility has been questioned in practical use.

종래의 기술사상과 문제점에 대해 살펴보면 다음과 같다.Looking at the conventional technical thoughts and problems are as follows.

단열층으로써 주로 적용되는 경량 기포 콘크리트는 전 시멘트만을 사용물과 혼합 슬러리화 과정에서 기포군을 섞어서 타설하기 때문에 과다한 시멘트가 서요되어 경제적 낭비와 시멘트의 높은 비중으로 건축물의 중량의 부담과 아울러 양생과정에서 수축이 심하여 크랙 발생 등이 문제점을 안고 있으며, 또한 비중이 높은 시멘트만을 고체상으로 사용함으로써 경화체내 적정 포아(pore)를 얻고자 할 경우 높은 비중, 크랙발생 슬러리의 고정도화 등의 문제로 인하여 적용이 불가능하고 단지 비중이 낮은 상태로만 시공이 되어 강도 부실과 경화체의 침전등 많은 하자 발생 요인이 된다.Lightweight foam concrete, which is mainly applied as a heat insulating layer, mixes all the cement with air bubbles in the process of slurrying and mixes the cement. Excessive cement is required, resulting in economic waste and high weight of cement. There is a problem of cracking due to severe shrinkage, and in case of obtaining proper pore in hardened body by using only cement with high specific gravity, it is difficult to apply due to problems such as high specific gravity and high precision of cracking slurry. It is impossible to do it, and it can be constructed only with low specific gravity, which causes many defects such as poor strength and precipitation of hardened body.

지금까지 많은 연구와 노력을 경주해 왔지만 단열층 문제만이라도 완벽하게 해결할만한 대안이 제시되지 못하고 있을 뿐만 아니라 단열층의 모든 문제와 흡 · 차음 성능을 갖춘 경량성 몰타르는 개발되지 못했다.Although much research and efforts have been made so far, not only an alternative solution to the insulation layer problem has been proposed, but a lightweight mortar with all the problems of the insulation layer and sound absorption and sound insulation has not been developed.

보다 구체적으로 기술하면, 대한민국 특허출원공개 제86-8958호의 불연성 콤프렉스 포옴 경량 콘크리트 제조방법에서는 단지 필라(filler)로써 플라이에쉬나 카바이트를 사용했기 때문에 기존의 크랙이나 강도 부실의 문제를 전혀 개선하지 못한 채 단지 시멘트의 일부를 골재로 대체하는 역할밖에 제시하지 못하였고, 또한 대한민국 특허출원공개 제92-2287호의 경량 단열 콘크리트 제조방법에서는 시멘트와 함께 스티로폼 입자, 화산재, 퍼라이트, 팝스톤, 고로슬래그, 질석 등의 경량 골재를 사용하는 시공법을 제시하였으나 이러한 물질들은 시멘트에 골재를 투입하여 배합을 조정하는 역할뿐이어서, 앞서 기술한 대한민국 특허출원공개 제86-8958호의 불연성 콘크리트 포옴, 경량 콘크리트 제조방법과 거의 대동소이하다 할 수 있다. 이는 시공시 블리딩(bleeding)과 입도분리 시공시간 경과에 따라 시공기계 내부에 경화등의 작동제한 등과 같은 문제를 발생시키면서 경량 기포 콘크리트의 근본문제를 해결하지 못하였다.More specifically, the method of manufacturing non-combustible complex foam lightweight concrete of Korean Patent Application Publication No. 86-8958 does not improve the problem of crack or strength failure at all because only fly ash or carbide is used as a filler. In addition, only a part of cement is replaced by aggregate, and in the method of manufacturing lightweight insulating concrete of Korean Patent Application Publication No. 92-2287, cement together with styrofoam particles, volcanic ash, perlite, popstone, blast furnace slag, Although construction methods using lightweight aggregates such as vermiculite have been proposed, these materials have only the role of adjusting aggregates by adding aggregates to cement. Thus, the method of manufacturing non-combustible concrete foams and lightweight concretes described in Korean Patent Application Publication No. 86-8958 described above. It can be almost the same. This did not solve the fundamental problem of lightweight foamed concrete while causing problems such as bleeding and particle size separation during construction, such as operating limitations such as hardening in the construction machine.

그 외에, 문제점을 해결하기 위한 방안으로 제시된 기술이 경량골재나 폐플라스틱을 골재로 사용하여 단열층을 구성하는 공법에 관한 것으로 대한민국 특허출원공개 제94-2202호 기포 콘크리트 제조방법과 대한민국 특허공개 제95-3216호 경량 단열 콘크리트 제조방법이 제시되었다. 이 방법에 따르면 폴리우레탄, E.V.A 스티로폼 등의 경량 골재를 적용하여 단열성을 높이고자 하였으나, 이들의 물질은 초경량으로써 시멘트 슬러리와 혼합하여 타설할 시 초경량 골재인 상기 혼화제 등이 부유하는 현상이 발생되어 유기물과 무기물의 층분리로 인하여 분리층간의 열팽창계수와 건조, 수축차이가 발생하여 하자 위험성이 유발된다. 특히 심각한 경우 입주후 난방개시 시 단열층이 박리현상을 일으켜 바닥을 재시공해야 하는 경우도 발생된다. 즉 마감층까지도 영향을 주게 된다는 결론이다. 이런 단점을 보완하기 위해 대한민국 특허공개 2000-14685호 경화성 및 수축 안정성이 강화된 단열 몰탈 조성물에 기포군들을 혼화제로 사용, 슬러리를 만들어 단열층 및 축열층의 시공용 몰탈 조성물에 관한 시공법이 제시되었으나, 이 역시 시멘트의 사용량이 너무 많아 초경량화를 이루지 못할 뿐만 아니라 단열 및 축열효과는 얻을 수 있으나 흡 · 차음의 효과는 극히 미미하다 할 것이다.In addition, the technology proposed as a solution to the problem relates to a method for constructing an insulating layer using lightweight aggregate or waste plastic as aggregate, and Korean Patent Application Publication No. 94-2202 Method for manufacturing aerated concrete and Korean Patent Publication No. 95 A method for manufacturing lightweight insulated concrete has been proposed. According to this method, it was intended to increase the thermal insulation by applying lightweight aggregates such as polyurethane and EVA styrofoam, but these materials are very light weight when mixed with cement slurry and poured into the admixture, which is the ultra-light aggregate, resulting in floating organic matter. Thermal separation coefficient and drying and shrinkage difference between the separation layer due to the separation of the inorganic material and inorganic material causes a risk of defects. In particularly serious cases, when the heating starts after moving in, the insulation layer may be peeled off and the floor must be rebuilt. In other words, it will affect the finishing layer. In order to make up for this drawback, the method of applying the mortar composition for the construction of the insulating layer and the heat storage layer was proposed by using a bubble group as a admixture in the insulating mortar composition having enhanced hardenability and shrinkage stability. In addition, the amount of cement used is too high to achieve ultra-light weight, and thermal insulation and heat storage effects can be obtained, but the effects of sound absorption and sound insulation will be extremely small.

따라서 본 발명은 상기의 제반문제를 해결하기 위해 창출된 것으로서 그 목적은 고층의 주거 건축물 등의 층간 또는 벽체에 충격, 소음을 차단함과 아울러 불연성, 단열성, 보온성 기능을 가지도록 한 초경량의 기포 콘크리트 몰타르 조성물과 그 제조방법을 제공함에 있다.Therefore, the present invention was created in order to solve the above problems, and its purpose is to prevent shock and noise on the floors or walls of high-rise residential buildings, etc., as well as ultra-light foam concrete to have a non-combustible, insulating, and insulating function. It is to provide a mortar composition and a method of manufacturing the same.

보다 상세하게는 상기의 우수한 기능을 가진 초경량 기포 시멘트 몰타르의 주요 조성물을 인산 비료 공장에서 필연적으로 생성되는 인산석고를 주조성물로 하되 인산석고에 함유되어 있는 환경 유해물질을 150℃ ~ 800℃의 조건에서 연속적으로 수분을 제거시키고 조직을 안정시켜 불연성, 단열성, 보온성 및 흡 . 차음기능을 가지도록 한 초경량 기포 시멘트 몰타르 조성물을 얻고자 하는 것이며, 폐적치 및 투리되는 폐자재를 대량 재활용하는 방법을 제공함에 있는 것이며,More specifically, the main composition of the ultra-light foam cement mortar having the above excellent function is made of phosphate gypsum, which is inevitably produced in a phosphate fertilizer plant, but the environmentally harmful substances contained in the phosphate gypsum are 150 ° C. to 800 ° C. Remove water continuously and stabilize the tissue to prevent inflammability, heat insulation, warmth and absorption. To obtain an ultra-light foam cement mortar composition having a sound insulation function, and to provide a method for mass recycling of waste material deposited and dumped waste material,

아울러 본 발명은 상기의 조성물과 이의 제조방법에 있어, 혼화제로 황토를 투여 혼화함으로써, 원적외선 방사효과와 탈취효과, 적정습도 조정 등의 쾌적한 주거 공간을 위한 조성물 및 이의 제조방법을 제공함에 있다.In addition, the present invention provides a composition and a method for producing the same for a comfortable living space, such as far-infrared radiation effect, deodorizing effect, adjustment of the appropriate humidity by admixing the ocher with the admixture in the composition and its preparation method.

도 1 은 본 발명의 제조 공정도.1 is a manufacturing process diagram of the present invention.

상기 목적을 달성하기 위한 본 발명은, 수분제거와 함침된 미량의 공해물질을 안정화시키기 위해 150℃ ~ 800℃의 조건에서 고온 열처리된 인산석고 30 ~ 70중량%를 주재료로 하고, 부재료로써 시멘트 20 ~ 40중량%, 황토 또는 고령토, 장석분말 2 ~ 20중량%, 기포발포제(알루미나 분말 또는 아연 분말) 0.01 ~ 0.5중량%, 발포촉매제(생석회, 탄산염) 2 ~ 5중량%, 분리방지 안정제(메틸셀룰로오스, 목분 또는 왕겨) 0.01 ~ 5중량%, 콘크리트 강도 강화제 0.5 ~ 3중량%, 인장력 강화제(해포석) 3 ~ 15중량%를 건식 혼화 제조되는 특징을 갖는다.The present invention for achieving the above object, 30 to 70% by weight of a high temperature heat-treated gypsum phosphate gypsum in a condition of 150 ℃ to 800 ℃ in order to stabilize the removal of pollutants impregnated with moisture, as a main material, cement 20 ~ 40% by weight, ocher or kaolin, feldspar 2-20% by weight, foaming agent (alumina powder or zinc powder) 0.01 ~ 0.5% by weight, foaming catalyst (quick lime, carbonate) 2 ~ 5% by weight, anti-separation stabilizer (methyl Cellulose, wood flour or rice hull) 0.01 to 5% by weight, 0.5 to 3% by weight of concrete strength enhancer, 3 to 15% by weight of tensile strength enhancer (gallbladder) is characterized by dry mixing.

이하 본 발명의 실시예를 첨부한 도면에 의거 보다 상세하게 설명한다.DETAILED DESCRIPTION Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.

도 1 은 본 발명의 제조 공정도이다.1 is a manufacturing process chart of the present invention.

본 발명의 구성을 설명하기 전에 인산석고의 생성과정과 그 처리방안에 대해 간단히 언급하면, 석고는 비료생산 과정에서 필연적으로 생성되는 인산석고 뿐만 아니라 발전소 및 화학공장의 탈황공정에서 생성되는 탈황석고 등 그 발생량이 증가하고 있는데, 필연적으로 생성된 석고의 일부는 석고보드나 시멘트 생산에 이용되고 있으나, 사용량보다 생성되는 양이 너무 많아 상당량의 석고가 적치되고 있으며, 적치장 관리에 많이 비용 등이 소진될 뿐만 아니라 바람에 날린 분진 등의 공해유발과 시각적 공해 또한 시급한 문제로써 대량의 재활용 방안이 시급히 요구되고 있다.Before briefly describing the composition of the present invention and the process of producing phosphate gypsum and its treatment method, gypsum is not only phosphate inevitably generated during fertilizer production but also desulfurized gypsum generated in desulfurization processes of power plants and chemical plants. The amount of gypsum is increasing, but some of the gypsum is inevitably used for the production of gypsum board or cement. However, the amount of gypsum is much higher than the amount of gypsum and the amount of gypsum is accumulated. In addition, pollution and visual pollution, such as dust blown by the wind is also an urgent problem, a large amount of recycling measures are urgently required.

이러한 상항에서 본 발명은 비료생산의 반대급부로 대량으로 양산되는 인산석고를 재활용한다는 측면이 본 발명의 핵심사항이다.In this context, the present invention is a key aspect of the present invention is to recycle the phosphate gypsum mass-produced in large quantities as a counterpart of the fertilizer production.

보다 구체적으로는, 상기 인산석고는 수분과 환경 유해물질이 소량 함유하고 있어 도 1 에서와 같이 로터리 킬른에서 연속적으로 150℃ ~ 800℃ 30분 ~ 40분 정도의 조건하에 건조 및 볶음 열처리하여 상기 인산석고에 포함되어 있는 유해물질을 안정화시키고, 또한 생성된 입도가 후술되는 시멘트, 황토 및 다른 혼화제와 거의 같고 모든 혼화제와 잘 혼합되며, 특히 발포 과정에서 기포발생시 기공의 고른 분포를 형성시키며, 고른 크기의 기포 형성의 안정화를 주며, 양생이후 강력한 고강도의 초경량 흡 . 차음재의 성능을 얻게 된다.More specifically, the phosphate gypsum contains a small amount of moisture and environmental harmful substances, and as shown in FIG. 1, the rotary phosphate is dried and roasted under a condition of about 150 ° C. to 800 ° C. for 30 minutes to 40 minutes, and the phosphoric acid Stabilizes the harmful substances contained in the gypsum, and the resulting particle size is almost the same as the cement, loess and other admixtures described below and blends well with all admixtures, creating an even distribution of pores during foaming, especially during foaming. It stabilizes the formation of bubbles and has a strong high strength ultra-light absorption after curing. You get the performance of sound insulation.

부재료로써 시멘트 20 ~ 40중량%, 황토, 고령토 분말 또는 장석 분말 3 ~ 15 중량%, 기포 발포제(알루미나 분말, 아연 분말) 0.01 ~ 0.5 중량%, 기포 촉매제(생석회 및 탄산염) 2 ~ 5중량%, 분리방지 안정제(메틸셀룰로오스, 목분 분말, 왕겨 분말) 0.01 ~ 5중량%, 콘크리트 강도 강화제 0.5 ~ 3중량%, 인장력 강화제(해포석) 3 ~ 15중량%를 첨가하여 혼합하면 시공현장에서 시공시 적정량의 물만 혼화하면 초경량 흡 . 차음 효과를 얻게 된다.20 to 40% by weight of cement, 3 to 15% by weight of ocher, kaolin powder or feldspar, 0.01 to 0.5% by weight foaming agent (alumina powder, zinc powder), 2 to 5% by weight of foam catalyst (quick lime and carbonate), Anti-separation stabilizer (methyl cellulose, wood powder, rice husk powder) 0.01 ~ 5% by weight, concrete strength enhancer 0.5 ~ 3% by weight, tensile strength enhancer (hamyeoseok) by adding 3-15% by weight of the appropriate amount of construction at the construction site Ultralight absorption if mixed with water. You get sound insulation.

주변 온도와 환경에 얻고자 하는 기포 콘크리트의 높이에 따라 함수량을 조절하게 되는 것이 특징이다.It is characterized by controlling the water content according to the ambient temperature and the height of the bubble concrete to obtain to the environment.

이 경우 강력하고 고루 분포된 기공이 형성 조성물의 부피의 200 ~ 300%의 기포 콘크리트가 조성되어, 건조 경화시 70 ~ 120Kgf/cm의 압축강도를 얻을 수 있으며, 흡 . 차음 효과는 경량 58dB이하, 중량 50dB이하의 흡 . 차음효과를 얻는 초경량 시멘트 몰타르의 조성물을 얻게 된다.In this case, strong and evenly distributed pores are formed in the foam concrete of 200 ~ 300% of the volume of the forming composition, it can obtain a compressive strength of 70 ~ 120Kgf / cm when dry hardening. Sound insulation is less than 58dB light weight, less than 50dB weight. A composition of ultralight cement mortar having a sound insulation effect is obtained.

이상에서 설명한 본 발명은 전술한 실시예 및 첨부된 도면에 의해 한정되는 것이 아니고, 본 발명의 기술적 사상을 벗어나지 않는 범위 내에서 여러 가지 치환, 변형 및 변경이 가능하다는 것이 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자에게 있어 명백할 것이다.The present invention described above is not limited to the above-described embodiments and the accompanying drawings, and various substitutions, modifications, and changes are possible in the art without departing from the technical spirit of the present invention. It will be clear to those of ordinary knowledge.

이상과 같은 본 발명으로 인하여, 단열 및 축열층이나 흡차음층을 한꺼번에 한 공정으로 처리하지 못한 공동주택 등의 건축물 계층간의 불연성, 단열성, 보온성 기능을 갖춘 흡 . 차음재용 초경량 시멘트 몰타르 조성물과 제조방법을 통하여 경제성과 간편한 시공성, 완벽한 성능으로 조용하고 쾌적한 주거공간 등을 얻을 수 있는 효과가 있다.Due to the present invention as described above, the non-combustible, heat-insulating, heat-insulating function between building layers, such as multi-family housing that did not process the heat insulation and heat storage layer or sound absorbing and insulating layer at the same time. Ultra-light cement mortar composition for sound insulation and manufacturing method has the effect of obtaining a quiet and comfortable living space with economical efficiency, easy construction, and perfect performance.

또한 본 발명의 조성물을 얻기 위한 주요 조성물이 비료공장의 생산과정에서 무한히 생성 폐기, 적치되는 인산석고의 대량 재활용 처리하여, 환경문제 해결에 일조하고 경제적인 효과까지 얻게 되는 효과가 있다.In addition, the main composition for obtaining the composition of the present invention is infinitely produced and discarded in the production process of the fertilizer plant, the mass recycling process of phosphate gypsum accumulated, there is an effect that helps to solve the environmental problems and economic effects.

Claims (2)

수분제거와 함침된 미량의 공해물질을 안정화시키기 위해 150℃ ~ 800℃의 조건에서 고온 열처리된 인산석고 30 ~ 70중량%를 주재료로 하고, 부재료로써 시멘트 20 ~ 40중량%, 황토 또는 고령토, 장석분말 2 ~ 10중량%, 기포발포제(알루미나 분말, 아연 분말) 0.01 ~ 0.5중량%, 발포촉매제(생석회 및 탄산염) 2 ~ 5중량%, 분리방지 안정제(메틸셀룰로오스, 목분 또는 왕겨분) 0.01 ~ 1중량%, 콘크리트 강도 강화제 0.5 ~ 3중량%, 인장력 강화제(해포석) 3 ~ 15중량%를 건식 혼화 제조됨을 특징으로 하는 불연, 단열, 보온, 흡 . 차음 기능을 갖는 기포 콘크리트 몰타르의 제조방법.In order to stabilize moisture removal and stabilization of small amounts of pollutants, 30 to 70% by weight of phosphate gypsum heated at a temperature of 150 ℃ to 800 ℃ is used as the main material, and 20 to 40% by weight of cement, loess or kaolin, feldspar 2 to 10% by weight of powder, foaming agent (alumina powder, zinc powder) 0.01 to 0.5% by weight, foaming catalyst (quick lime and carbonate) 2 to 5% by weight, anti-separation stabilizer (methylcellulose, wood flour or rice husk) 0.01 to 1 Non-flammable, heat insulation, insulation, moisture absorption, characterized in that dry mixing is prepared by weight%, concrete strength reinforcement 0.5-3% by weight, tensile strength reinforcement (calcite) 3-15% by weight. Method for producing foamed concrete mortar with sound insulation. 상기 청구항 1에 의한 제조방법에 의해 얻어지는 것을 특징으로 하는 불연, 단열, 보온, 흡 . 차음 기능을 갖는 기포 콘크리트 몰타르 조성물.Non-combustible, heat-insulating, heat-insulating, absorption is obtained by the manufacturing method according to claim 1. Foamed concrete mortar composition with sound insulation.
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100885852B1 (en) * 2007-12-26 2009-02-26 이영선 Method for preparing cement mixture using feldspar
KR101112758B1 (en) * 2010-01-19 2012-03-13 부경시멘트 주식회사 Cement admixture composite and manufacturing method for the same
CN110436870A (en) * 2019-08-14 2019-11-12 武汉理工大学 A kind of humidity conditioning function ardealite materials for wall and preparation method thereof suitable for assembled architecture
CN115849849A (en) * 2022-11-23 2023-03-28 河南城建学院 Light insulation board prepared from phosphogypsum and preparation method thereof
KR102585628B1 (en) * 2023-02-20 2023-10-05 이상혁 Lightweight cellular concrete composition, lightweight treated soil composition, construction method of lightweight cellular concrete composition, and lightweight treatred soil composition contruction method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100885852B1 (en) * 2007-12-26 2009-02-26 이영선 Method for preparing cement mixture using feldspar
KR101112758B1 (en) * 2010-01-19 2012-03-13 부경시멘트 주식회사 Cement admixture composite and manufacturing method for the same
CN110436870A (en) * 2019-08-14 2019-11-12 武汉理工大学 A kind of humidity conditioning function ardealite materials for wall and preparation method thereof suitable for assembled architecture
CN115849849A (en) * 2022-11-23 2023-03-28 河南城建学院 Light insulation board prepared from phosphogypsum and preparation method thereof
CN115849849B (en) * 2022-11-23 2024-02-09 河南城建学院 Light insulation board prepared from phosphogypsum and preparation method thereof
KR102585628B1 (en) * 2023-02-20 2023-10-05 이상혁 Lightweight cellular concrete composition, lightweight treated soil composition, construction method of lightweight cellular concrete composition, and lightweight treatred soil composition contruction method

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