KR101781989B1 - Glass Circuit Board and method of manufacturing the same - Google Patents
Glass Circuit Board and method of manufacturing the same Download PDFInfo
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- KR101781989B1 KR101781989B1 KR1020150173569A KR20150173569A KR101781989B1 KR 101781989 B1 KR101781989 B1 KR 101781989B1 KR 1020150173569 A KR1020150173569 A KR 1020150173569A KR 20150173569 A KR20150173569 A KR 20150173569A KR 101781989 B1 KR101781989 B1 KR 101781989B1
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- glass
- glass core
- core
- circuit board
- manufacturing
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4602—Manufacturing multilayer circuits characterized by a special circuit board as base or central core whereon additional circuit layers are built or additional circuit boards are laminated
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0306—Inorganic insulating substrates, e.g. ceramic, glass
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/10—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern
- H05K3/20—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern by affixing prefabricated conductor pattern
- H05K3/202—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern by affixing prefabricated conductor pattern using self-supporting metal foil pattern
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/40—Forming printed elements for providing electric connections to or between printed circuits
- H05K3/42—Plated through-holes or plated via connections
- H05K3/429—Plated through-holes specially for multilayer circuits, e.g. having connections to inner circuit layers
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4611—Manufacturing multilayer circuits by laminating two or more circuit boards
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- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Production Of Multi-Layered Print Wiring Board (AREA)
Abstract
In a method of manufacturing a glass circuit board according to an embodiment, a base substrate including a glass core and an insulating frame disposed so as to surround an outer frame portion of the glass core is prepared. The glass core is processed to form a through glass via hole. Through glass vias filling the inside of the through glass via holes and first and second circuit pattern layers disposed on both sides of the glass core are formed. The first and second insulating layers covering the first and second circuit pattern layers are formed. The glass core including the through glass vias and the first and second circuit pattern layers is separated from the insulating frame.
Description
The present invention relates to a glass circuit board and a method of manufacturing the same.
BACKGROUND ART [0002] With the trend toward miniaturization and multifunctionality of electronic devices, electronic components are becoming more sophisticated and more compact. Due to the advancement of digital networks, portable information terminal devices such as mobile phones and portable computers are becoming more sophisticated, versatile and highly functional, and various functions are being fused into one device to be combined.
As described above, it has been demanded that the thickness of the printed circuit board is also reduced in accordance with the thinning and shortening of electronic devices. As the thickness of the printed circuit board is reduced, the problem of warpage of the target substrate during the manufacture of the printed circuit board continues to arise. The above-mentioned bending problem causes breakage of the original plate or process failure, which leads to reduction in the yield, and therefore, a method for overcoming this problem is being demanded.
In order to solve such a bending problem, Korean Patent Laid-Open Publication No. 2015-0047880 entitled " Insulating Resin Composition for Printed Circuit Boards and Products Using the Same "
SUMMARY OF THE INVENTION It is an object of the present invention to provide a manufacturing method for suppressing the occurrence of defects such as cracks in a glass core by applying a glass core to a printed circuit board in order to improve a deflection problem of the substrate.
A problem to be solved by the present invention is to provide a new method for manufacturing a glass circuit board with improved defectiveness described above more reliably.
A manufacturing method of a glass circuit board according to one aspect is disclosed. In the method of manufacturing the glass circuit board, a base substrate including a glass core and an insulating frame arranged to surround an outer frame portion of the glass core is prepared. The glass core is processed to form a through glass via hole. Through glass vias filling the inside of the through glass via holes and first and second circuit pattern layers disposed on both sides of the glass core are formed. The first and second insulating layers covering the first and second circuit pattern layers are formed. The glass core including the through glass vias and the first and second circuit pattern layers is separated from the insulating frame.
A manufacturing method of a glass circuit board according to another aspect is disclosed. In the above method of manufacturing a glass circuit board, a base substrate including a glass core having a through glass via hole and an insulating frame arranged to surround an outer frame portion of the glass core is prepared. Through glass vias filling the inside of the through glass via holes and first and second circuit pattern layers disposed on both sides of the glass core are formed. The first and second insulating layers covering the first and second circuit pattern layers are formed. The glass core including the through glass vias and the first and second circuit pattern layers is separated from the insulating frame.
A manufacturing method of a glass circuit substrate according to another aspect is disclosed. In the method of manufacturing the glass circuit board, a base substrate including a glass core and an insulating frame arranged to surround an outer frame portion of the glass core is prepared. At this time, the glass core includes through glass vias passing through the glass core, and first and second circuit pattern layers connected to the through glass vias and disposed on both sides of the glass core. Forming first and second insulating layers respectively covering the first and second circuit pattern layers; separating the glass core including the through glass vias and the first and second circuit pattern layers from the insulating frame.
A glass circuit board according to another aspect is disclosed. Wherein the glass circuit board comprises a glass core having glass through vias and having first and second circuit pattern layers on both sides connected to the glass through vias; First and second insulating layers covering the first and second circuit pattern layers on the glass core; First and second blind vias disposed in the first and second insulating layers and connected to the first and second circuit pattern layers; And third and fourth circuit pattern layers disposed on the first and second insulating layers and connected to the first and second blind vias.
According to one embodiment, a glass circuit board can be manufactured by disposing a glass core in a frame structure using a copper clad laminate (CCL) or a prepreg substrate. Specifically, a frame structure in which a cavity is formed in the copper-clad substrate or the prepreg substrate is provided to overcome the fact that the glass core is relatively vulnerable to edge impact. After the glass core is inserted into the cavity and the glass core is coupled with the frame structure, the glass core is subjected to a printed circuit board manufacturing process. By removing the frame structure after the printed circuit board manufacturing process is completed, the glass circuit board can be reliably manufactured.
As described above, the glass core can be protected from the impact of the outer frame by advancing the printed circuit board manufacturing process while the outer frame of the glass core is protected by the frame structure. Thus, it is possible to easily manufacture a glass circuit board having a higher elastic modulus and stiffness and a lower coefficient of thermal expansion than conventional copper-clad laminated boards or prepreg boards.
1 is a flowchart schematically showing a method of manufacturing a glass circuit board according to an embodiment of the present invention.
2 to 16 are sectional views schematically showing a method of manufacturing a glass circuit board according to an embodiment of the present invention.
17 is a cross-sectional view schematically showing one step of a method of manufacturing a glass circuit board according to another embodiment of the present invention.
18 to 21 are sectional views schematically showing a method of manufacturing a glass circuit board according to still another embodiment of the present invention.
22 is a cross-sectional view schematically showing a step of a method of manufacturing a glass circuit board according to still another embodiment of the present invention.
23 is a plan view schematically showing a glass core according to an embodiment of the present invention.
24 is a plan view schematically showing a glass core according to another embodiment of the present invention.
25 is a flowchart schematically showing a method of manufacturing a glass circuit board according to another embodiment of the present invention.
26 is a plan view schematically showing a glass core according to another embodiment of the present invention.
27 is a flowchart schematically showing a method of manufacturing a glass circuit board according to still another embodiment of the present invention.
28 to 31 are sectional views schematically showing a method of manufacturing a glass circuit board according to still another embodiment of the present invention.
Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings. However, the techniques disclosed in the present invention are not limited to the embodiments described herein but may be embodied in other forms. It should be understood, however, that the embodiments disclosed herein are provided so that this disclosure will be thorough and complete, and will fully convey the concept of this disclosure to those skilled in the art. In the drawings, the width, thickness, and the like of the components are enlarged in order to clearly illustrate the components of each device. It is to be understood that when an element is described as being located on another element, it is meant that the element is directly on top of the other element or that additional elements can be interposed between the elements .
Like numbers refer to like elements throughout the several views. It is to be understood that the singular forms "a", "an", and "the" include plural referents unless the context clearly dictates otherwise, and the terms "comprise" Or combinations thereof, and does not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, or combinations thereof.
Further, in carrying out the method or the manufacturing method, the respective steps of the method may take place differently from the stated order unless clearly specified in the context. That is, each process may occur in the same order as described, may be performed substantially concurrently, or may be performed in the opposite order.
As used herein, the term " top surface " or " bottom " of a substrate or device chip is a relative concept observed at an observer's viewpoint. Therefore, one of the two surfaces except the side of the substrate or the element chip may be referred to as an 'upper surface' or 'lower surface', and the other surface may be referred to as 'lower surface' or 'upper surface' correspondingly. Likewise, in the present specification, the concept of 'upper', 'upper' or 'lower' and 'lower' can be used as a relative concept as well.
In the embodiments of the present invention, a method of using a glass core instead of a conventional copper laminate (CCL) substrate or a prepreg substrate as a base material for a printed circuit board is proposed. The glass core has a higher elastic modulus and rigidity and a lower coefficient of thermal expansion on the material side than the conventional copper laminated board or prepreg substrate. This makes it possible to effectively suppress the warpage of the original plate caused by the stress between the upper and lower layers stacked and the lack of rigidity of the material during the printing circuit process.
However, as a result of the inventors' research, it has been found that the glass core applied to the manufacturing process has a weak point that the outer portion is vulnerable to impact. Particularly, as the panel size of the glass core increases, it has been found that cracks due to the impact are easily generated at the outer portion of the glass core during the printed circuit manufacturing process. Cracks generated in the outer frame portion can easily propagate to the center of the core, thereby causing process defects and yield reduction.
In the embodiments of the present invention described below, in a method of manufacturing a printed circuit board to which a glass core is applied, it is possible to effectively suppress the occurrence of a crack due to an outer frame impact. This makes it possible to reliably manufacture the glass circuit board to which the glass core is applied.
1 is a flowchart schematically showing a method of manufacturing a glass circuit board according to an embodiment of the present invention. Referring to S110 of FIG. 1, a base substrate including a glass core and a frame structure arranged to surround the outer periphery of the glass core is prepared.
In step S120, the glass core is processed to form a through glass via hole.
In step S130, through glass vias filling the inside of the through glass via holes and first and second circuit pattern layers disposed on both sides of the glass core are formed.
In step S140, first and second insulating layers are formed to cover the first and second circuit pattern layers, respectively. Additionally, first and second blind vias disposed in the first and second insulating layers and connected to the first and second circuit pattern layers may be formed. Next, third and fourth circuit pattern layers, which are disposed on the first and second insulating layers and connected to the first and second blind vias, may be formed. Similarly, a multilayer interlayer insulating layer, a blind via, and a circuit pattern layer can be laminated on the third and fourth circuit pattern layers in the same manner.
In step S150, the glass core including the through glass vias and the first and second circuit pattern layers is separated from the frame structure. Thus, a glass circuit substrate having a via core and a circuit pattern layer formed on the glass core and the glass core can be manufactured.
A more specific process for manufacturing the glass circuit substrate will be described below.
2 to 16 are sectional views schematically showing a method of manufacturing a glass circuit board according to an embodiment of the present invention. Referring to FIG. 2, a copper clad
3, the copper clad
Referring to FIG. 4, the copper laminated
Next, a pair of sacrificial copper foils 130a and 130b are prepared and disposed on both sides of the
Referring to FIG. 5, a pair of sacrificial copper foils 130a and 130b, a
In some embodiments, the pair of sacrificial copper foils 130a, 130b may have an adhesive layer on the surface facing the
Referring to FIG. 6, a pair of sacrificial copper foils 130a and 130b may be selectively processed to expose both sides of the
Alternatively, both sides of the
Referring to FIG. 7, the exposed
8, the
9, an electrolytic plating method using a
As a result, the through
Referring to FIG. 10, the first and second insulating
11, blind via
12, the first and second
Referring to FIG. 13, third and fourth insulating
Referring to FIG. 14, the third and fourth insulating
Referring to FIG. 15, first and second solder resist
Referring to FIG. 16, through
By proceeding with the above-described processes, a glass circuit board according to an embodiment of the present invention can be manufactured.
2, a
Meanwhile, unlike the above-described embodiment, in some other embodiments, the
First, a process substantially the same as the process related to Figs. 2 to 9 is performed. Thus, the structure shown in Fig. 18 is formed. Referring to Fig. 19, the
Referring to FIG. 20, after the
On the other hand, in some other embodiments, the fifth and sixth circuit pattern layers 184a2 and 184b2 corresponding to the uppermost circuit pattern layer are formed on the third and fourth insulating
On the other hand, in the above-described manufacturing methods, the
Referring to FIG. 24, in step S210, a base substrate including a glass core having a through glass via hole and a frame structure arranged to surround the outer periphery of the glass core is prepared. In step S220, through glass vias filling the inside of the through glass via holes and first and second circuit pattern layers disposed on both sides of the glass core are formed. In step S230, first and second insulating layers are formed to cover the first and second circuit pattern layers, respectively. Additionally, first and second blind vias disposed in the first and second insulating layers and connected to the first and second circuit pattern layers may be formed. Next, third and fourth circuit pattern layers, which are disposed on the first and second insulating layers and connected to the first and second blind vias, may be formed. Similarly, a multilayer interlayer insulating layer, a blind via, and a circuit pattern layer can be laminated on the third and fourth circuit pattern layers in the same manner. In step S240, the glass core including the through glass vias and the first and second circuit pattern layers can be separated from the frame structure.
The following steps can be followed in detail. First, as shown in FIG. 23, a
2 and 3, the
In some other embodiments, the
Referring to FIG. 26, in step S310, a base substrate including a glass core and a frame structure arranged to surround the outer periphery of the glass core is prepared. The glass core may include through glass vias formed to penetrate the glass core, and first and second circuit pattern layers connected to the through glass vias and disposed on both sides of the glass core. In step S320, the first and second insulating layers may be formed to cover the first and second circuit pattern layers, respectively. In step S330, the glass core including the through glass vias and the first and second circuit pattern layers can be separated from the frame structure.
The following steps can be followed in detail. First, as shown in FIG. 25, a
2 and 3, the
In some other embodiments, the process shown in Figs. 27 to 30 can be selectively applied to the manufacturing process of the glass circuit board. Referring to FIG. 27, a copper laminated
Referring to FIG. 28, the copper layered
Referring to FIG. 29, a
Referring to FIG. 30, the sacrificial copper foils 130a and 130b, the insulating
As described above, the glass circuit board manufactured by applying the manufacturing method of various embodiments is an example, and the structure can be explained using Fig. Referring to FIG. 16, the glass circuit board may include a
Referring to FIG. 16, first and second insulating
The third and fourth insulating
As some other embodiments, the glass circuit board shown in Fig. 17 can be provided. The illustrated glass circuit substrate is the same as the glass circuit board described above with reference to FIG. 16, except that a
As another embodiment, a glass circuit board shown in Fig. 21 can be provided. The illustrated glass circuit substrate has the same structure as that described with reference to Fig. 16 except that the fifth and sixth circuit pattern layers 184a and 184b are buried in the third and fourth insulating
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims. It can be understood that
10: cavity, 20: through glass via hole,
110: copper laminated substrate, 111: insulating core layer,
112: copper foil,
130a 130b: sacrificial copper foil, 144: through glass vias,
146a 146b: first and second circuit pattern layers,
150a 150b: first and second insulating layers,
162a 162b: first and second blind vias,
164a 164b: third and fourth circuit pattern layers,
170a 170b: third and fourth insulating layers,
182a 182b: third and fourth blind vias,
184a 184b 184a2 184b2: fifth and sixth circuit pattern layers,
190a 190b: first and second solder resist pattern layers,
200: glass core
1200a 1200b: insulating substrate layer.
Claims (21)
(b) processing the glass core to form a through glass via hole;
(c) forming through glass vias filling the inside of the through glass via holes and first and second circuit pattern layers respectively disposed on both sides of the glass core;
(d) forming first and second insulating layers on both surfaces of the base substrate, respectively, to cover the first and second circuit pattern layers, respectively;
(e) separating the glass core and the frame structure from each other to manufacture the glass core including the through glass vias, the first and second circuit pattern layers, and the first and second insulating layers doing
A method of manufacturing a glass circuit board.
(a)
(a1) preparing a substrate of at least one of a copper laminated substrate and a prepreg substrate;
(a2) forming a cavity through the circular plate by machining the circular plate;
(a3) preparing the glass core, and placing the glass core in the cavity;
(a4) preparing a pair of sacrificial copper foils, placing the glass core and the upper surface of the glass plate on both sides
(a5) pressing and bonding the pair of sacrificial copper foils, the disk and the glass core; And
(a6) selectively exposing the pair of sacrificial copper foils to expose both sides of the glass core
A method of manufacturing a glass circuit board.
Wherein the pair of sacrificial copper foils comprises an adhesive layer on a surface facing the glass core and the original plate.
In step (a6)
Wherein the pattern layer of the sacrificial copper foil remaining after the selective processing is positioned to cover at least a portion of the glass core
A method of manufacturing a glass circuit board.
(a)
(a1) preparing a copper laminated substrate;
(a2) forming a cavity through the copper-clad laminate by processing the copper-clad laminate;
(a3) preparing the glass core, and placing the glass core in the cavity;
(a4) preparing a pair of insulating substrate layers and a pair of sacrificial copper foils;
(a5) sequentially arranging the insulating base layer and the sacrificial copper foil on upper surfaces of the glass core and the copper laminated substrate;
(a5) pressing and bonding the sacrificial copper foil, the insulating base layer, the copper laminated substrate and the glass core; And
(a6) selectively exposing the pair of sacrificial copper foils to expose both sides of the glass core to which the insulating substrate layer is bonded
A method of manufacturing a glass circuit board.
(b)
Processing the glass core to penetrate the inside of the glass core so as to reach the other surface from one surface of the glass core or to process the glass core inward from both surfaces of the glass core
A method of manufacturing a glass circuit board.
(c)
(c1) forming a seed layer for plating on a surface of the glass core and an inner wall of the through-hole; And
(c2) a step of forming an electroplating process using the seed layer for plating to form a copper plating layer filling the through glass via holes and a plating pattern layer positioned on the surface of the glass core
A method of manufacturing a glass circuit board.
The step of forming the plating seed layer
Forming a copper layer by a sputtering method or an electroless plating method
A method of manufacturing a glass circuit board.
The step of forming the plating pattern layer
And is performed by any one of the processes selected from the group consisting of a tenting process, an additive process, a semi-additive process (SAP), and a modified semi-additive process (MSAP)
A method of manufacturing a glass circuit board.
Between step (c) and step (d)
Processing the glass core to form a glass core cavity penetrating the glass core;
Preparing a semiconductor device;
Disposing the semiconductor element in the glass core cavity; And
And forming a connecting circuit pattern layer on the electrode layer of the semiconductor element
A method of manufacturing a glass circuit board.
(d)
Preparing a pair of interlayer insulating materials;
Disposing the pair of interlayer insulating materials on both sides of the frame structure and the glass core; And
And pressing and bonding the pair of interlayer insulating materials, the frame structure and the glass core
A method of manufacturing a glass circuit board.
After step (d)
Forming a blind via hole selectively exposing the first and second circuit pattern layers by selectively processing the first and second insulating layers; And
Forming first and second blind via holes filling the blind via hole and third and fourth circuit pattern layers disposed on the first and second insulating layers,
A method of manufacturing a glass circuit board.
(e)
Removing the frame structure from the base substrate by applying a laser processing method
A method of manufacturing a glass circuit board.
(b) forming through glass vias filling the inside of the through glass via holes and first and second circuit pattern layers respectively disposed on both sides of the glass core;
(c) forming first and second insulating layers on both surfaces of the base substrate, respectively, to cover the first and second circuit pattern layers, respectively;
(d) separating the glass core and the frame structure from each other to manufacture the glass core including the through glass vias, the first and second circuit pattern layers, and the first and second insulating layers doing
A method of manufacturing a glass circuit board.
(a)
(a1) preparing a substrate of at least one of a copper laminated substrate and a prepreg substrate;
(a2) forming a cavity through the circular plate by machining the circular plate;
(a3) preparing a glass core and processing the glass core to form a through glass via hole penetrating the glass core;
(a4) disposing a glass core having the through-glass via hole in the cavity;
(a5) preparing a pair of sacrificial copper foils, and placing the sacrificial copper foil on both sides of the disk on which the glass core is disposed;
(a6) pressing and bonding the pair of sacrificial copper foils, the disk and the glass core; And
(a7) selectively exposing the pair of sacrificial copper foils to expose both sides of the glass core,
A method of manufacturing a glass circuit board.
(b) forming first and second insulating layers, respectively, on the base substrate to cover the first and second circuit pattern layers, respectively;
(c) separating the glass core and the frame structure from each other to manufacture the glass core including the through glass vias, the first and second circuit pattern layers, and the first and second insulating layers doing
A method of manufacturing a glass circuit board.
(a)
(a1) preparing a substrate of at least one of a copper laminated substrate and a prepreg substrate;
(a2) forming a cavity through the circular plate by machining the circular plate;
(a3) preparing a glass core and processing the glass core to form a through glass via hole penetrating the glass core;
(a4) forming through glass vias filling the inside of the through glass via holes and first and second circuit pattern layers disposed on both sides of the glass core;
(a5) disposing a glass core including the through glass via, the first and second circuit pattern layers in the cavity;
(a5) preparing a pair of sacrificial copper foils and disposing them on both sides of the glass core and the original plate;
(a6) pressing and bonding the pair of sacrificial copper foils, the disk and the glass core; And
(a7) selectively exposing the pair of sacrificial copper foils to expose both sides of the glass core,
A method of manufacturing a glass circuit board.
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KR20240005415A (en) | 2022-07-05 | 2024-01-12 | 주식회사 심텍 | Cavity-based glass substrate structure and manufacturing method thereof |
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KR102460870B1 (en) * | 2017-10-20 | 2022-10-31 | 삼성전기주식회사 | Printed circuit board |
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KR20240005415A (en) | 2022-07-05 | 2024-01-12 | 주식회사 심텍 | Cavity-based glass substrate structure and manufacturing method thereof |
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