KR101648337B1 - 슬러리루프 중합에 의해 고분말밀도의 올레핀중합체를 제조하는 방법 - Google Patents
슬러리루프 중합에 의해 고분말밀도의 올레핀중합체를 제조하는 방법 Download PDFInfo
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- KR101648337B1 KR101648337B1 KR1020147019104A KR20147019104A KR101648337B1 KR 101648337 B1 KR101648337 B1 KR 101648337B1 KR 1020147019104 A KR1020147019104 A KR 1020147019104A KR 20147019104 A KR20147019104 A KR 20147019104A KR 101648337 B1 KR101648337 B1 KR 101648337B1
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- chromium
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- polymer
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- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 41
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- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000011651 chromium Substances 0.000 claims abstract description 23
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 21
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- 125000001424 substituent group Chemical group 0.000 description 3
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- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
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- 239000000010 aprotic solvent Substances 0.000 description 2
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- 239000013522 chelant Substances 0.000 description 2
- 150000001844 chromium Chemical class 0.000 description 2
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
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- 238000001035 drying Methods 0.000 description 2
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
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- 125000005843 halogen group Chemical group 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
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- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
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- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
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- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
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- 125000000590 4-methylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
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- 125000003358 C2-C20 alkenyl group Chemical group 0.000 description 1
- 125000000041 C6-C10 aryl group Chemical group 0.000 description 1
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- 238000007725 thermal activation Methods 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/14—Organic medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/22—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of chromium, molybdenum or tungsten
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11194421.1 | 2011-12-20 | ||
| EP11194421.1A EP2607389A1 (en) | 2011-12-20 | 2011-12-20 | Process for preparing olefin polymer by slurry loop polymerization having high powder density |
| PCT/EP2012/074303 WO2013092195A1 (en) | 2011-12-20 | 2012-12-04 | Process for preparing olefin polymer by slurry loop polymerization having high powder density |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20140101427A KR20140101427A (ko) | 2014-08-19 |
| KR101648337B1 true KR101648337B1 (ko) | 2016-08-17 |
Family
ID=45346366
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020147019104A Active KR101648337B1 (ko) | 2011-12-20 | 2012-12-04 | 슬러리루프 중합에 의해 고분말밀도의 올레핀중합체를 제조하는 방법 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9464147B2 (OSRAM) |
| EP (2) | EP2607389A1 (OSRAM) |
| JP (1) | JP5922794B2 (OSRAM) |
| KR (1) | KR101648337B1 (OSRAM) |
| CN (1) | CN104321351B (OSRAM) |
| BR (1) | BR112014014897B1 (OSRAM) |
| ES (1) | ES2559464T3 (OSRAM) |
| IN (1) | IN2014CN04465A (OSRAM) |
| WO (1) | WO2013092195A1 (OSRAM) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10300460B1 (en) | 2017-11-17 | 2019-05-28 | Chevron Phillips Chemical Company L.P. | Aqueous methods for titanating a chromium/silica catalyst |
| US11186656B2 (en) | 2019-05-24 | 2021-11-30 | Chevron Phillips Chemical Company Lp | Preparation of large pore silicas and uses thereof in chromium catalysts for olefin polymerization |
| US11124586B1 (en) | 2020-11-09 | 2021-09-21 | Chevron Phillips Chemical Company Lp | Particle size control of metallocene catalyst systems in loop slurry polymerization reactors |
| WO2022125581A2 (en) * | 2020-12-08 | 2022-06-16 | Chevron Phillips Chemical Company Lp | Particle size control of supported chromium catalysts in loop slurry polymerization reactors |
| KR20250133456A (ko) | 2021-09-13 | 2025-09-05 | 셰브론 필립스 케미컬 컴퍼니 엘피 | 올레핀 중합에서 사용하기 위한 촉매 시스템 성분의 하이드로사이클론 개질 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008502760A (ja) | 2004-06-16 | 2008-01-31 | バーゼル・ポリオレフィン・ゲーエムベーハー | オレフィンの重合および／または共重合のためのクロムとジルコニウムとを含む触媒 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4182810A (en) | 1978-04-21 | 1980-01-08 | Phillips Petroleum Company | Prevention of fouling in polymerization reactors |
| DE3600610A1 (de) | 1986-01-11 | 1987-07-16 | Basf Ag | Einsatz von antistatika zur vermeidung von belagbildung bei der herstellung von ethylenpolymerisaten in gasphasenreaktoren |
| US5026795A (en) | 1987-02-24 | 1991-06-25 | Phillips Petroleum Co | Process for preventing fouling in a gas phase polymerization reactor |
| US5198400A (en) | 1987-05-20 | 1993-03-30 | Quantum Chemical Corporation | Mixed chromium catalysts and polymerizations utilizing same |
| US6239235B1 (en) | 1997-07-15 | 2001-05-29 | Phillips Petroleum Company | High solids slurry polymerization |
| DE19943206A1 (de) * | 1999-09-09 | 2001-03-15 | Elenac Gmbh | Verfahren zum Herstellen von Philips-Katalysatoren für die Polymerisation von Olefinen mit verbesserten Produktivitäten im Particle-Form-Verfahren |
| MY136330A (en) | 2001-12-12 | 2008-09-30 | Basell Poliolefine Spa | Process for the polymerization of olefins |
| SA04250276B1 (ar) | 2003-09-24 | 2009-02-07 | باسيل بوليوليفين جي ام بي اتش | عملية بلمرة لوسط معلق مع تركيزات عالية للمواد الصلبة خلال مفاعل حلقي |
| US7705097B2 (en) * | 2004-06-16 | 2010-04-27 | Basell Polyolefine Gmbh | Process for preparing a chromium-based catalyst for the polymerization and/or copolymerization of olefins |
| JP5409396B2 (ja) | 2007-03-02 | 2014-02-05 | ビーエーエスエフ ソシエタス・ヨーロピア | 非生物有機材料の帯電防止処理と導電性改善に適した添加剤組成物 |
-
2011
- 2011-12-20 EP EP11194421.1A patent/EP2607389A1/en not_active Withdrawn
-
2012
- 2012-12-04 IN IN4465CHN2014 patent/IN2014CN04465A/en unknown
- 2012-12-04 US US14/364,977 patent/US9464147B2/en active Active
- 2012-12-04 KR KR1020147019104A patent/KR101648337B1/ko active Active
- 2012-12-04 BR BR112014014897-0A patent/BR112014014897B1/pt active IP Right Grant
- 2012-12-04 CN CN201280059685.6A patent/CN104321351B/zh active Active
- 2012-12-04 WO PCT/EP2012/074303 patent/WO2013092195A1/en not_active Ceased
- 2012-12-04 JP JP2014546408A patent/JP5922794B2/ja active Active
- 2012-12-04 ES ES12794725.7T patent/ES2559464T3/es active Active
- 2012-12-04 EP EP12794725.7A patent/EP2794684B1/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008502760A (ja) | 2004-06-16 | 2008-01-31 | バーゼル・ポリオレフィン・ゲーエムベーハー | オレフィンの重合および／または共重合のためのクロムとジルコニウムとを含む触媒 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2794684B1 (en) | 2015-12-02 |
| EP2794684A1 (en) | 2014-10-29 |
| CN104321351A (zh) | 2015-01-28 |
| EP2607389A1 (en) | 2013-06-26 |
| JP2015500908A (ja) | 2015-01-08 |
| KR20140101427A (ko) | 2014-08-19 |
| BR112014014897A2 (pt) | 2017-06-13 |
| US9464147B2 (en) | 2016-10-11 |
| ES2559464T3 (es) | 2016-02-12 |
| JP5922794B2 (ja) | 2016-05-24 |
| IN2014CN04465A (OSRAM) | 2015-09-04 |
| WO2013092195A1 (en) | 2013-06-27 |
| BR112014014897B1 (pt) | 2020-09-15 |
| CN104321351B (zh) | 2016-08-24 |
| US20140316082A1 (en) | 2014-10-23 |
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