KR101613760B1 - 퀴논 메티드/알킬 히드록실아민 조합을 이용한 방향족 비닐 단량체의 중합 억제 - Google Patents

퀴논 메티드/알킬 히드록실아민 조합을 이용한 방향족 비닐 단량체의 중합 억제 Download PDF

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KR101613760B1
KR101613760B1 KR1020117018201A KR20117018201A KR101613760B1 KR 101613760 B1 KR101613760 B1 KR 101613760B1 KR 1020117018201 A KR1020117018201 A KR 1020117018201A KR 20117018201 A KR20117018201 A KR 20117018201A KR 101613760 B1 KR101613760 B1 KR 101613760B1
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inhibitor
monomer
retarder
combination
composition
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KR20110122111A (ko
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빈센트 이. 루이스
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날코 컴퍼니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/40—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/06—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen
    • C09K15/08—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen containing a phenol or quinone moiety

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Materials Engineering (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
KR1020117018201A 2009-02-05 2010-02-03 퀴논 메티드/알킬 히드록실아민 조합을 이용한 방향족 비닐 단량체의 중합 억제 Active KR101613760B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/366,154 US7651635B1 (en) 2009-02-05 2009-02-05 Polymer inhibition of vinyl aromatic monomers using a quinone methide/alkyl hydroxylamine combination
US12/366,154 2009-02-05

Publications (2)

Publication Number Publication Date
KR20110122111A KR20110122111A (ko) 2011-11-09
KR101613760B1 true KR101613760B1 (ko) 2016-04-19

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ID=41559765

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KR1020117018201A Active KR101613760B1 (ko) 2009-02-05 2010-02-03 퀴논 메티드/알킬 히드록실아민 조합을 이용한 방향족 비닐 단량체의 중합 억제

Country Status (11)

Country Link
US (1) US7651635B1 (https=)
EP (1) EP2393765B1 (https=)
JP (1) JP5536106B2 (https=)
KR (1) KR101613760B1 (https=)
CN (1) CN102307830B (https=)
BR (1) BRPI1005420B1 (https=)
CA (1) CA2750187C (https=)
ES (1) ES2398053T3 (https=)
SG (1) SG173564A1 (https=)
TW (1) TWI461406B (https=)
WO (1) WO2010091040A1 (https=)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8691994B2 (en) 2011-02-03 2014-04-08 Nalco Company Multi-component polymerization inhibitors for ethylenically unsaturated monomers
US8884038B2 (en) 2011-06-13 2014-11-11 Nalco Company Synthesis of 7-acetyleno quinone methide derivatives and their application as vinylic polymerization retarders
US9090526B2 (en) * 2011-06-13 2015-07-28 Nalco Company Synergistic combination for inhibiting polymerization of vinyl monomers
KR101812624B1 (ko) 2011-08-26 2017-12-27 도르프 케탈 케미칼즈 (인디아) 프라이비트 리미티드 스타이렌의 중합화의 제어 및 억제를 위한 첨가제 조성물, 및 그의 제조와 사용 방법
BR112014013855B1 (pt) * 2011-12-09 2020-11-17 Dorf Ketal Chemicals (I) Private Limited composição aditiva para o controle e inibição de polimerização de monômeros vinil aromáticos e método de utilização da mesma
ES2547893T3 (es) * 2011-12-26 2015-10-09 Dorf Ketal Chemicals (India) Private Limited Composición de aditivo mejorada a base de amina para el control y la inhibición de la polimerización de monómeros aromáticos de vinilo, y procedimiento para su uso
US9234057B2 (en) * 2012-08-24 2016-01-12 Dorf Ketal Chemicals (India) Private Limited Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof
US9611336B2 (en) * 2012-10-25 2017-04-04 Baker Hughes Incorporated Quinone compounds for inhibiting monomer polymerization
US9944577B2 (en) 2012-10-25 2018-04-17 Baker Hughes, A Ge Company, Llc Hydroquinone compounds for inhibiting monomer polymerization
IN2013MU01165A (https=) * 2013-03-26 2015-04-24 Dorf Ketal Chemicals India Private Ltd
US9399622B2 (en) 2013-12-03 2016-07-26 Ecolab Usa Inc. Nitroxide hydroxylamine and phenylenediamine combinations as polymerization inhibitors for ethylenically unsaturated monomer processes
CN108884004B (zh) * 2016-02-13 2020-02-25 多尔夫凯塔尔化学制品（I）私人有限公司 用于控制和抑制乙烯基芳族单体聚合的组合物，及其使用方法
EP3820836A1 (en) 2018-07-13 2021-05-19 Ecolab USA, Inc. Compositions of oxygenated amines and quinone methides as antifoulants for vinylic monomers
US11180578B2 (en) 2018-07-13 2021-11-23 Ecolab Usa Inc. Polymerization inhibitor and retarder compositions with amine stabilizer
TWI880966B (zh) * 2019-10-11 2025-04-21 美商藝康美國公司 醌甲基化物及銨鹽抗聚合劑組合物及方法
WO2025217595A1 (en) * 2024-04-12 2025-10-16 Bl Technologies, Inc. Boosted styrene polymerization retarder and method of use

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KR100402905B1 (ko) * 1995-04-14 2004-04-08 시바 스페셜티 케미칼스 홀딩 인크. 불포화단량체에대한억제제인7-치환된키논메티드

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US3390198A (en) * 1965-12-16 1968-06-25 Koppers Co Inc Tertiary-butyl-5-methyl catechol as polymerization inhibitor for hot styrene
US4003800A (en) 1976-01-02 1977-01-18 Gulf Research & Development Company Styrene purification process
US4409408A (en) * 1982-09-24 1983-10-11 Atlantic Richfield Company Inhibiting polymerization of vinyl aromatic monomers
IT1245845B (it) * 1990-09-17 1994-10-25 Montedipe Srl Processo per la depurazione di un monomero vinilaromatico.
US5446220A (en) 1994-08-24 1995-08-29 Betz Laboratories, Inc. Methods for inhibiting vinyl aromatic monomer polymerization
US6024894A (en) * 1998-03-25 2000-02-15 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
US6685823B2 (en) * 2000-10-16 2004-02-03 Uniroyal Chemical Company, Inc. C-nitrosoaniline compounds and their blends as polymerization inhibitors
US7045647B2 (en) 2000-10-16 2006-05-16 Uniroyal Chemical Company, Inc. Blends of quinone alkide and nitroxyl compounds and polymerization inhibitors
ES2247332T3 (es) * 2001-03-20 2006-03-01 Ciba Specialty Chemicals Holding Inc. Composiciones ignifugantes.
US6960279B2 (en) * 2002-05-06 2005-11-01 Fina Technology, Inc. Method for stabilizing vinyl aromatic monomers using selected polymerization inhibitors and polymers prepared therewith
WO2004083156A1 (ja) * 2003-03-17 2004-09-30 Hakuto Co., Ltd. 芳香族ビニル化合物の重合抑制剤および重合抑制方法

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KR100402905B1 (ko) * 1995-04-14 2004-04-08 시바 스페셜티 케미칼스 홀딩 인크. 불포화단량체에대한억제제인7-치환된키논메티드

Also Published As

Publication number Publication date
JP5536106B2 (ja) 2014-07-02
US7651635B1 (en) 2010-01-26
TW201035046A (en) 2010-10-01
WO2010091040A1 (en) 2010-08-12
TWI461406B (zh) 2014-11-21
EP2393765A1 (en) 2011-12-14
CN102307830A (zh) 2012-01-04
BRPI1005420A2 (pt) 2020-08-18
CA2750187A1 (en) 2010-08-12
EP2393765B1 (en) 2012-12-26
BRPI1005420B1 (pt) 2021-05-11
CA2750187C (en) 2016-05-10
KR20110122111A (ko) 2011-11-09
CN102307830B (zh) 2014-10-22
JP2012516933A (ja) 2012-07-26
SG173564A1 (en) 2011-09-29
ES2398053T3 (es) 2013-03-13

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