CN102307830B - 使用醌甲基化物/烷基羟胺组合的乙烯基芳族单体的聚合物抑制 - Google Patents

使用醌甲基化物/烷基羟胺组合的乙烯基芳族单体的聚合物抑制 Download PDF

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Publication number
CN102307830B
CN102307830B CN201080006847.0A CN201080006847A CN102307830B CN 102307830 B CN102307830 B CN 102307830B CN 201080006847 A CN201080006847 A CN 201080006847A CN 102307830 B CN102307830 B CN 102307830B
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China
Prior art keywords
inhibitor
monomer
delayed
action activator
quinone methides
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CN201080006847.0A
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English (en)
Chinese (zh)
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CN102307830A (zh
Inventor
文森特·E·莱维斯
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ChampionX LLC
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Nalco Co LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/40—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/06—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen
    • C09K15/08—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen containing a phenol or quinone moiety

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Materials Engineering (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201080006847.0A 2009-02-05 2010-02-03 使用醌甲基化物/烷基羟胺组合的乙烯基芳族单体的聚合物抑制 Active CN102307830B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/366,154 US7651635B1 (en) 2009-02-05 2009-02-05 Polymer inhibition of vinyl aromatic monomers using a quinone methide/alkyl hydroxylamine combination
US12/366,154 2009-02-05
PCT/US2010/022977 WO2010091040A1 (en) 2009-02-05 2010-02-03 Polymer inhibition of vinyl aromatic monomers using a quinone methide/alkyl hydroxomine combination

Publications (2)

Publication Number Publication Date
CN102307830A CN102307830A (zh) 2012-01-04
CN102307830B true CN102307830B (zh) 2014-10-22

Family

ID=41559765

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201080006847.0A Active CN102307830B (zh) 2009-02-05 2010-02-03 使用醌甲基化物/烷基羟胺组合的乙烯基芳族单体的聚合物抑制

Country Status (11)

Country Link
US (1) US7651635B1 (https=)
EP (1) EP2393765B1 (https=)
JP (1) JP5536106B2 (https=)
KR (1) KR101613760B1 (https=)
CN (1) CN102307830B (https=)
BR (1) BRPI1005420B1 (https=)
CA (1) CA2750187C (https=)
ES (1) ES2398053T3 (https=)
SG (1) SG173564A1 (https=)
TW (1) TWI461406B (https=)
WO (1) WO2010091040A1 (https=)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8691994B2 (en) 2011-02-03 2014-04-08 Nalco Company Multi-component polymerization inhibitors for ethylenically unsaturated monomers
US9090526B2 (en) * 2011-06-13 2015-07-28 Nalco Company Synergistic combination for inhibiting polymerization of vinyl monomers
US8884038B2 (en) * 2011-06-13 2014-11-11 Nalco Company Synthesis of 7-acetyleno quinone methide derivatives and their application as vinylic polymerization retarders
BR112014004284B1 (pt) 2011-08-26 2020-05-05 Dorf Ketal Chemicals (I) Private Limited processo de preparação de uma composição aromática contendo vanilina e etilvanilina
CA2858755C (en) * 2011-12-09 2016-08-23 Dorf Ketal Chemicals (India) Private Limited Additive composition for control and inhibition of polymerization of aromatic vinyl monomers, and method of use thereof
WO2013102930A1 (en) * 2011-12-26 2013-07-11 Dorf Ketal Chemicals (India) Private Limited Improved amine based additive composition for control and inhibition of polymerization of aromatic vinyl monomers, and method of use thereof
ES2686127T3 (es) * 2012-08-24 2018-10-16 Dorf Ketal Chemicals (India) Private Limited Composición de derivados de métido de quinona y aminas para el control y la inhibición de la polimerización de monómeros, y procedimiento de preparación y uso de la misma
US9944577B2 (en) 2012-10-25 2018-04-17 Baker Hughes, A Ge Company, Llc Hydroquinone compounds for inhibiting monomer polymerization
US9611336B2 (en) 2012-10-25 2017-04-04 Baker Hughes Incorporated Quinone compounds for inhibiting monomer polymerization
IN2013MU01165A (https=) * 2013-03-26 2015-04-24 Dorf Ketal Chemicals India Private Ltd
US9399622B2 (en) 2013-12-03 2016-07-26 Ecolab Usa Inc. Nitroxide hydroxylamine and phenylenediamine combinations as polymerization inhibitors for ethylenically unsaturated monomer processes
PL3414217T3 (pl) * 2016-02-13 2020-10-19 Dorf Ketal Chemicals (India) Private Limited Kompozycje do kontroli i hamowania polimeryzacji monomerów winyloaromatycznych oraz sposoby ich stosowania
TW202005938A (zh) 2018-07-13 2020-02-01 美商藝康美國公司 具有胺穩定劑之聚合抑制劑及阻滯劑組合物
KR102763208B1 (ko) * 2018-07-13 2025-02-04 에코랍 유에스에이 인코퍼레이티드 비닐계 단량체에 대한 항파울런트로서의 산소화 아민 및 퀴논 메티드의 조성물
TWI880966B (zh) * 2019-10-11 2025-04-21 美商藝康美國公司 醌甲基化物及銨鹽抗聚合劑組合物及方法
WO2025217595A1 (en) * 2024-04-12 2025-10-16 Bl Technologies, Inc. Boosted styrene polymerization retarder and method of use

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1061020A (zh) * 1990-09-17 1992-05-13 Ecp·恩尼化学聚合有限公司 乙烯基芳族单体的纯化方法
US5670692A (en) * 1995-04-14 1997-09-23 Ciba-Geigy Corporation 7-substituted quinone methides as inhibitors for unsaturated monomers
WO1999048996A1 (en) * 1998-03-25 1999-09-30 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
US20040097619A1 (en) * 2001-03-20 2004-05-20 Troutman Malisa V. Flame retardant compositions
CN1761638A (zh) * 2003-03-17 2006-04-19 伯东株式会社 芳香族乙烯基化合物的聚合抑制剂以及聚合抑制方法

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US3390198A (en) * 1965-12-16 1968-06-25 Koppers Co Inc Tertiary-butyl-5-methyl catechol as polymerization inhibitor for hot styrene
US4003800A (en) 1976-01-02 1977-01-18 Gulf Research & Development Company Styrene purification process
US4409408A (en) * 1982-09-24 1983-10-11 Atlantic Richfield Company Inhibiting polymerization of vinyl aromatic monomers
US5446220A (en) 1994-08-24 1995-08-29 Betz Laboratories, Inc. Methods for inhibiting vinyl aromatic monomer polymerization
KR100812038B1 (ko) 2000-10-16 2008-03-10 유니로얄 캐미칼 캄파니, 인크. 중합 억제제로서 퀴논 알키드와 니트록실 화합물의 블렌드물
US6685823B2 (en) * 2000-10-16 2004-02-03 Uniroyal Chemical Company, Inc. C-nitrosoaniline compounds and their blends as polymerization inhibitors
US6960279B2 (en) * 2002-05-06 2005-11-01 Fina Technology, Inc. Method for stabilizing vinyl aromatic monomers using selected polymerization inhibitors and polymers prepared therewith

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1061020A (zh) * 1990-09-17 1992-05-13 Ecp·恩尼化学聚合有限公司 乙烯基芳族单体的纯化方法
US5670692A (en) * 1995-04-14 1997-09-23 Ciba-Geigy Corporation 7-substituted quinone methides as inhibitors for unsaturated monomers
WO1999048996A1 (en) * 1998-03-25 1999-09-30 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
US20040097619A1 (en) * 2001-03-20 2004-05-20 Troutman Malisa V. Flame retardant compositions
CN1761638A (zh) * 2003-03-17 2006-04-19 伯东株式会社 芳香族乙烯基化合物的聚合抑制剂以及聚合抑制方法

Also Published As

Publication number Publication date
BRPI1005420B1 (pt) 2021-05-11
TW201035046A (en) 2010-10-01
US7651635B1 (en) 2010-01-26
JP5536106B2 (ja) 2014-07-02
EP2393765B1 (en) 2012-12-26
CN102307830A (zh) 2012-01-04
TWI461406B (zh) 2014-11-21
SG173564A1 (en) 2011-09-29
KR101613760B1 (ko) 2016-04-19
EP2393765A1 (en) 2011-12-14
CA2750187C (en) 2016-05-10
KR20110122111A (ko) 2011-11-09
ES2398053T3 (es) 2013-03-13
BRPI1005420A2 (pt) 2020-08-18
CA2750187A1 (en) 2010-08-12
JP2012516933A (ja) 2012-07-26
WO2010091040A1 (en) 2010-08-12

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