KR101547922B1 - Method for producing a sulfur-functional rice prepared using Admiral sulfur and Uses - Google Patents

Method for producing a sulfur-functional rice prepared using Admiral sulfur and Uses Download PDF

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KR101547922B1
KR101547922B1 KR1020140143018A KR20140143018A KR101547922B1 KR 101547922 B1 KR101547922 B1 KR 101547922B1 KR 1020140143018 A KR1020140143018 A KR 1020140143018A KR 20140143018 A KR20140143018 A KR 20140143018A KR 101547922 B1 KR101547922 B1 KR 101547922B1
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sulfur
rice
producing
hours
solid
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이상종
김미희
이승협
이혜현
최도영
권선화
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농업회사법인 주식회사 엘바이오텍
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/196Products in which the original granular shape is maintained, e.g. parboiled rice
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/16Inorganic salts, minerals or trace elements
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/17Amino acids, peptides or proteins
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/104Fermentation of farinaceous cereal or cereal material; Addition of enzymes or microorganisms
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/02Preparation of sulfur; Purification
    • C01B17/027Recovery of sulfur from material containing elemental sulfur, e.g. luxmasses or sulfur containing ores; Purification of the recovered sulfur

Abstract

The present invention relates to a method for manufacturing sulfur rice with high contents of a sulfur compound by spraying detoxified sulfur on the soil through liquefying, and stem and leaf treating before planting rice, and particularly, to a manufacturing method of sulfur rice which is beneficial to health with significantly good rice taste and grain quality since minerals comprising essential amino acids in a sulfur compound of rice contain a large amount of various nutrients good for human body, and to rice manufactured by the manufacturing method.

Description

제독유황을 이용하여 제조된 기능성 유황쌀의 제조방법 및 용도 {Method for producing a sulfur-functional rice prepared using Admiral sulfur and Uses}TECHNICAL FIELD The present invention relates to a sulfur-containing functional sulfur-containing rice,

본 발명은 제독된 유황을 모내기전 토양에 살포하고 액상화하여 경옆처리하여 유황화합물이 높은 유황 쌀의 생산제조방법에 관한 것으로, 특히 쌀의 유황화합물에 들어있는 필수아미노산을 포함한 미네랄은 우리몸에 좋은 각종 영양소들을 다량으로 함유하고 있어 건강에 유익하고 밥맛과 미질이 월등히 좋은 유황쌀의 제조방법 및 이러한 제조방법에 의하여 제조된 쌀에 관한 것이다.The present invention relates to a method for producing sulfur-rich rice with high sulfur content by spraying, decolorizing and liquefying decontaminated sulfur to the soil before cultivation. In particular, the minerals containing essential amino acids contained in the sulfur compounds of rice are suitable for the body The present invention relates to a method for producing sulfur-containing rice, which is rich in various nutrients and which is beneficial for health, and which has much better taste and taste, and rice produced by such a manufacturing method.

벼는 화본과 작물로써 주로 답(沓)에서 재배되고, 그 열매인 나락을 도정한 것을 쌀이라 하여 밥짓는데에 주로 쓰인다. 쌀의 성분은 대체로 탄수화물 70 내지 85%, 단백질 6.5% 내지 8.0%, 지방 1.0 내지 2.0%, 칼슘 24.23mg/kg이며 쌀 100g의 열량은 360cal 정도이다.Rice is cultivated mainly as an anthropomorphic crop and as a crop, and it is mainly used to cook rice, which is the fruit of Narak, which is a fruit. The components of rice are generally 70 to 85% of carbohydrate, 6.5 to 8.0% of protein, 1.0 to 2.0% of fat, 24.23 mg / kg of calcium, and the calories of 100 g of rice are about 360 calories.

이중 유황화합물은 우리몸의 뼈를 구성하는데 꼭 필요할 뿐 아니라, 특히 암 환자나 성장기에 있는 어린이, 생리적인 현상으로 유황화합물과 미네랄손실이 많은 폐경기 이후 여성, 임산부 및 수유부여성, 많은 스트레스와 불규칙적인 식습관으로 유황과 미네랄이이 부족하기 쉬운 직장인, 노인들에게는 영양소의 고른 섭취와 더불어 많은 유황화합물과 미네랄 섭취가 반드시 필요하다. In addition to being essential for the formation of bones in our body, the double sulfur compounds are particularly important for cancer patients and children in their growing stages, postmenopausal women who are physiologically symptomatic and have a high loss of sulfur compounds and minerals, pregnant and lactating women, For the elderly, who are likely to have a lack of sulfur and minerals in their eating habits, it is essential that they have plenty of sulfur compounds and minerals in addition to their regular intake of nutrients.

그러나 칼슘은 전형적인 2가 양이온 금속이어서, 벼 재배과정중 토양속의 음이온성분이나 쌀의 쌀겨층으로 인하여 쌀에 축적되는 것이 쉽지 않고, 또한 질소·인산 등의 미량원소와의 불용성 결합이 자주 일어나 실질적인 축적율이 떨어지며, 작물에서의 이동이 쉽지 않아 지속적인 축적이 어렵다.However, since calcium is a typical divalent cation metal, it is not easy to accumulate in the rice due to the anion component in the soil or the rice bran layer of the rice during the rice growing process. Insoluble bonds with trace elements such as nitrogen and phosphoric acid occur frequently, It is difficult to accumulate because the rate is low and it is difficult to move from crops.

따라서 일반재배법으로 벼를 재배하여서는 생산되는 쌀의 유황화합물과 미네랄 함량을 높이는 데에 한계가 있었다.Therefore, cultivation of rice with the general cultivation method has limitations in raising the sulfur content and mineral content of the produced rice.

일반재배법으로 벼를 재배함에 있어 생산되는 쌀의 유황화합물과 미네랄 함량을 높이는 기능성 쌀 생산에 한계를 가진다.There is a limit to the production of functional rice, which increases the sulfur content and minerals content of rice produced in the cultivation of rice by the general cultivation method.

본 발명의 목적은 상기한 문제점을 해결하기 위하여 벼 재배시 유황화합물과 미네랄이 토양속의 성분과 결합함을 융용하여 유황화합물과 미네랄 흡수를 증가시키고, 유황화합물과 미네랄이 벼에 최대로 흡수되는 조건으로유황화합물과 미네랄을 제공함으로써, 유황을 포함한 몸에 좋은 각종 영양소들을 다량으로 함유한 쌀을 생산하기 위한 유황화합물과 미네랄 쌀의 제조방법을 제공하는 것에 목적을 가진다.It is an object of the present invention to solve the above-mentioned problems, and it is an object of the present invention to improve the absorption of sulfur compounds and minerals by melting sulfur compounds and minerals bound to components in the soil during rice cultivation, To provide a method for producing sulfur compounds and mineral rice for producing rice containing a large amount of nutrients that are good for the body including sulfur, by providing sulfur compounds and minerals.

본 발명의 또 다른 목적은 유황화합물과 미네랄을 포함한 몸에 좋은 각종 영양소들을 다량으로 함유하게 되는 쌀을 제공하는데에 있다.Another object of the present invention is to provide rice which contains a large amount of nutrients that are good for the body including sulfur compounds and minerals.

본 발명에 따라 생산된유황화합물과 미네랄 쌀은 기존의 쌀보다 월등히 높은 유황화합물이 쌀에 고루 함유되어 있므로, 식생활에서 유황화합물과 미네랄을 포함한 영양과 밥맛 모두에서 소비자의 욕구를 확실히 충족시키면서 영양도 충족 되어 양 보다 질을 추구하는 소비자들의 쌀 소비를 진작시킬수 있는 유황화합물과 미네랄효과의 쌀 생산 발명효과가 있다.Since the sulfur compounds and mineral rice produced according to the present invention contain sulfur compounds which are much higher than the conventional rice in the rice, it is possible to satisfy the consumers' needs in both nutrition and taste including the sulfur compounds and minerals in the diet, Has also been invented to produce rice with sulfur compounds and minerals that can boost rice consumption by consumers seeking quality rather than quantity.

도 1. 유황쌀 재배 단지 사진
도 2. 유황쌀의 뿌리 발근 차이점
도 3. 토양계량제나 경옆처리제로 활용 가능한 천연유황수
Figure 1. Sulfur rice cultivation complex photo
Figure 2. Root rooting difference of sulfur rice
Figure 3. Natural sulfur water that can be used as a soil weighing agent or light-

일반 독성유황은 물과의 혼합은 몇 십년이 가도 두 물질이 혼용되지않고 식물이 흡수할수 없는 것이 일반 유황의 단점이었다 하지만 유황제독특허 제 10-1334157호로 제독된 유황은 물과의 혼합이 바로 이어지고 식물 또한 바로 흡수할수 있어서 기능설 쌀과 밭과 식물 재배에 효과적이라 할 수 있다.General toxic sulfur is a disadvantage of general sulfur which can not be absorbed by plants because the two substances are not mixed with water even after several decades. However, the sulfur which is decontaminated with sulfur admiral patent No. 10-1334157 immediately follows the mixing with water Plants can also be absorbed directly, so they can be effective in cultivating functional rice paddies and fields and plants.

본 발명의 목적을 달성하기 위하여, 벼 재배시 유황화합물과 건운모를 용융하여 제조된 유기태 액상 미네랄이 토양속의 성분과 함께 황화합물과 미네랄 흡수를 증가시키고, 유황화합물과 미네랄이 벼에 최대로 흡수되는 조건으로 유황화합물과 미네랄을 제공함으로써, 유황을 포함한 몸에 좋은 각종 영양소들을 다량으로 함유한 쌀을 생산하기 위한 유황화합물과 미네랄 쌀의 제조방법을 제공한다. In order to achieve the object of the present invention, an organic liquid mineral prepared by melting sulfur compounds and dry mica at the time of growing rice, together with the components in the soil, increases the absorption of sulfur compounds and minerals and maximizes the absorption of sulfur compounds and minerals into rice The present invention provides a method for producing sulfur compounds and mineral rice for producing rice containing a large amount of nutrients suitable for the body including sulfur, by providing sulfur compounds and minerals as a condition.

본 발명의 일 구현예에 있어서, 상기 유황을 포함한 몸에 좋은 각종 영양소들을 다량으로 함유한 쌀은 쌀의 종류에 상관없이 살포 가능하고, 이에 제한되지 않는다.In one embodiment of the present invention, rice containing a large amount of various nutrients that are good for the body including sulfur can be sprayed regardless of the kind of rice, and is not limited thereto.

이하, 본 발명을 실시예에 의해 상세히 설명한다. 단, 하기 실시예는 본 발명을 예시하는 것일 뿐, 본 발명의 내용이 하기 실시예에 한정되는 것은 아니다.Hereinafter, the present invention will be described in detail with reference to examples. However, the following examples are illustrative of the present invention, and the present invention is not limited to the following examples.

토양계량제 제조 하기 표 1에 기재된 성분들을 계량한 후 증류수에 각 성분들을 용해시켜 토양계량제를 제조하여 1차 살포액으로 사용하였다. 유황분말은 하기 방법을 이용하여 제조한다.
(a) 탄소원으로 녹차 잎 및 광나무 잎이 6.5~7.5:2.5~3.5의 중량비로 포함된 혼합 배지를 23~35℃에서 43~48일간 발효시키는 단계;
(b) 상기 (a) 단계의 발효시킨 혼합 배지에 고온멸균시킨 2~3%(w/v) 당밀 희석액을 첨가한 후, 유용미생물을 접종하여 23~35℃에서 92~140시간 동안 배양하는 단계;
(c) 상기 (b)단계의 유용미생물 배양액에 독성유황 분말을 25~35%(w/v)의 비율로 첨가한 후, 25~35℃에서 22~26시간 동안 1차 발효분해시키는 단계;
(d) 상기 (c)단계의 1차 발효분해물을 습식 콜로이드밀로 파쇄하는 단계;
(e) 상기 (d)단계의 파쇄된 1차 발효분해물을 고액 분리하고, 분리된 침전물에 상기 (b)단계의 유용미생물 배양액을 첨가한 후, 25~35℃에서 22~26시간 동안 2차 발효분해시키는 단계; 및
(f) 상기 (e)단계의 2차 제독유황 발효분해물을 고액 분리하고, 분리된 고체를 75~85℃에서 건조시켜 제독유황 발효 분말을 제조하는 단계를 포함하는 유용 미생물을 이용한 제독유황의 제조방법을 제공한다.
본 발명의 일 구현 예에 따른 제조방법에서, 상기 (a) 단계의 혼합배지는 녹차 잎 및 광나무 잎이 6.5~7.5:2.5~3.5의 중량비로 포함된 탄소원 혼합물에 미네랄 혼합물 100 중량부 기준으로 이온화된 미네랄 1.5~2.5 중량부, 천연과즙 8~12 중량부, 천연식초 2.7~3.3 중량부, 소금 4.5~5.5 중량부, 감미성분 2.7~3.3 중량부 및 당밀 74~84 중량부가 혼합된 미네랄 혼합물을 첨가하여 제조된 pH 4.8~5.2의 혼합배지일 수 있고, 바람직하게는 녹차 잎 및 광나무 잎이 6.5~7.5:2.5~3.5의 중량비로 포함된 탄소원 혼합물에 미네랄 혼합물 100 중량부 기준으로 이온화된 미네랄 2 중량부, 천연과즙 10 중량부, 천연식초 3 중량부, 소금 5 중량부, 감미성분 3 중량부 및 당밀 77 중량부가 혼합된 미네랄 혼합물을 첨가하여 제조된 pH 4.8~5.2의 혼합배지일 수 있으나, 이에 제한되지 않는다.
본 발명의 일 구현 예에 따른 제조방법에서, 상기 (a) 단계의 유용미생물은 유산균 및 효모로 이루어진 혼합 미생물일 수 있고, 바람직하게는 락토바실러스 파라파라기니스(Lactobacillus parafarraginis), 락토바실러스 파라카제이 (Lactobacillus paracasei), 락토바실러스 톨러란스(Lactobacillus tolerans), 락토바실러스 부츠네리(Lactobacillus buchneri), 락토바실러스 하르비넨시스(Lactobacillus harbinensis), 락토바실러스 페로렌스(Lactobacillus perolens), 락토바실러스 람노서스(Lactobacillus rhamnosus), 락토바실러스 벡시노스테르쿠스(Lactobacillus vaccinostercus), 아세토박터 로바니엔시스(Acetobacter lovaniensis), 아세토박터 페록시단스(Acetobacter peroxydans), 피키아 퍼멘탄스(Pichia fermentans), 칸디다 에탄올리카(Candida ethanolica) 및 사카로미콥시스 스코에니(Saccharomycopsis schoenii)로 이루어진 12종의 유용미생물 혼합물일 수 있으나, 이에 제한되지 않는다.
또한, 본 발명은 더욱 구체적으로
(a) 탄소원으로 녹차 잎 및 광나무 잎이 6.5~7.5:2.5~3.5의 중량비로 포함된 혼합 배지를 23~35℃에서 43~48일간 발효시키는 단계;
(b) 상기 (a) 단계의 발효시킨 혼합 배지에 고온멸균시킨 2~3%(w/v) 당밀 희석액을 0.5~0.7%(v/v)의 비율로 첨가한 후, pH 3.2~3.7로 적정하여 유용미생물을 접종하여 23~35℃에서 92~140시간 동안 배양하는 단계;
(c) 상기 (b)단계의 유용미생물 배양액에 독성유황 분말을 25~35%(w/v)의 비율로 첨가한 후, 25~35℃에서 22~26시간 동안 1차 발효분해시키는 단계;
(d) 상기 (c)단계의 1차 발효분해물을 습식 콜로이드밀로 46~52시간 동안 파쇄하는 단계;
(e) 상기 (d)단계의 파쇄된 1차 발효분해물을 고액 분리하고, 분리된 침전물에 상기 (b)단계의 유용미생물 대량 배양액을 2~3배(v/w)의 비율로 첨가한 후, 25~35℃에서 22~26시간 동안 2차 발효분해시키는 단계; 및
(f) 상기 (e)단계의 2차 제독유황 발효분해물을 고액 분리하고, 분리된 고체를 75~85℃에서 8~12시간 동안 건조시켜 제독유황 발효 분말을 제조하는 단계를 포함하는 유용 미생물을 이용한 제독유황의 제조방법을 제공한다.
상기 제조방법으로 제도된 제독유황분말은 총 1톤을 혼합하여, 25℃에서 72시간 발효하여 과립상으로 제조한 토양계량제를 제조하고, 200평당 15~20kg을 살포한다.
Preparation of soil metering agent The ingredients listed in Table 1 were weighed and dissolved in distilled water to prepare a soil metering agent and used as a primary spraying solution. Sulfur powder is prepared by the following method.
(a) fermenting a mixed medium containing green tea leaves and camphor leaves at a weight ratio of 6.5 to 7.5: 2.5 to 3.5 as a carbon source at 23 to 35 ° C for 43 to 48 days;
(b) adding a 2 to 3% (w / v) molasses dilution to a fermented mixed medium of step (a) by high temperature sterilization, and then inoculating the useful microorganism and culturing at 23 to 35 ° C for 92 to 140 hours step;
(c) adding 25 to 35% (w / v) of a toxic sulfur powder to the useful microorganism culture of step (b), and then performing primary fermentation decomposition at 25 to 35 ° C for 22 to 26 hours;
(d) disrupting the primary fermentation broth of step (c) with a wet colloid mill;
(e) separating the pulverized primary fermentation broth of step (d) by solid-liquid separation, adding the culture medium of the useful microorganism in step (b) to the separated precipitate, Fermenting and decomposing; And
(f) solid-liquid separation of the secondary fermented sulfurized fermentation broth of step (e), and drying the separated solid at 75 to 85 ° C. to prepare a fermented powder of virgin sulfur fermentation. ≪ / RTI >
In the preparation method according to one embodiment of the present invention, the mixed medium of step (a) is prepared by ionizing (i) 100 parts by weight of a mineral mixture to a carbon source mixture containing green tea leaves and camphor leaves at a weight ratio of 6.5 to 7.5: 2.5 to 3.5 1.5 to 2.5 parts by weight of the mineral minerals, 8 to 12 parts by weight of the natural juice, 2.7 to 3.3 parts by weight of the natural vinegar, 4.5 to 5.5 parts by weight of the salt, 2.7 to 3.3 parts by weight of the sweetener component and 74 to 84 parts by weight of the molasses. And a pH of 4.8-5.2 prepared by the addition of carbonic anhydride. Preferably, green tea leaves and mineral fiber leaves are mixed in a carbon source mixture in a weight ratio of 6.5-7.5: 2.5-3.5 to mineralized 2 A mixed medium of pH 4.8-5.2 prepared by adding a mineral mixture mixed with 10 parts by weight of natural juice, 3 parts by weight of natural vinegar, 5 parts by weight of salt, 3 parts by weight of sweetening ingredient and 77 parts by weight of molasses, But is not limited thereto.
In the production method according to an embodiment of the present invention, the useful microorganism of step (a) may be a mixed microorganism consisting of lactic acid bacteria and yeast, and preferably Lactobacillus parafarrhinis, Lactobacillus paracase, Lactobacillus paracasei, Lactobacillus tolerans, Lactobacillus buchneri, Lactobacillus harbinensis, Lactobacillus perolens, Lactobacillus rhamnosus, Lactobacillus spp. , Lactobacillus vaccinostercus, Acetobacter lovaniensis, Acetobacter peroxydans, Pichia fermentans, Candida ethanolica, and Sakae Twelve kinds of usefulness of Saccharomycopsis schoenii It is a mixture of water, but is not limited thereto.
Further, the present invention is more specifically
(a) fermenting a mixed medium containing green tea leaves and camphor leaves at a weight ratio of 6.5 to 7.5: 2.5 to 3.5 as a carbon source at 23 to 35 ° C for 43 to 48 days;
(b) 0.5 to 0.7% (v / v) of a 2 to 3% (w / v) molasses dilution prepared by sterilization at high temperature in the fermented mixed medium of step (a) Cultivating the useful microorganism at 23-35 ° C for 92-140 hours;
(c) adding 25 to 35% (w / v) of a toxic sulfur powder to the useful microorganism culture of step (b), and then performing primary fermentation decomposition at 25 to 35 ° C for 22 to 26 hours;
(d) breaking the primary fermentation broth of step (c) with a wet colloid mill for 46 to 52 hours;
(e) separating the pulverized primary fermentation broth of step (d) by solid-liquid separation, adding a large amount of the useful microorganism mass of step (b) to the separated precipitate in a ratio of 2 to 3 times (v / w) , Secondary fermentation decomposition at 25 to 35 ° C for 22 to 26 hours; And
(f) solid-liquid separation of the secondary fermented sulfurized fermentation broth of step (e), and drying the separated solid at 75 to 85 ° C. for 8 to 12 hours to prepare a fermented broth of fermented sulfur, And a method for producing the virgin sulfur.
A total of 1 ton of the virgin sulfur powder prepared by the above-described method is mixed and fermented at 25 ° C for 72 hours to prepare a granular soil metering agent and spray 15 to 20 kg per 200 square meters.

벼를 심기전 모를 심기 위하여 관행농법대로 물대기 작업부터 시작해서 유기질비료를 살포하는 작업이까지 마무리 된 상태에서 200평당 15~20kg의 유황비료조성물 펠렛을 손으로 살포한다.In order to plant the rice before planting, spray the organic sulfur fertilizer pellets of 15 ~ 20kg per 200 ㎡ with the spraying of the organic fertilizer starting from the water standby work with the practice farming system.

토양계량제 조성Soil Metering 품 명Product Name 함량content 미강Rice bran 480kg480kg 유황분말Sulfur powder 250kg250kg 휴믹산Humic acid 20kg20kg 굴 패각Oyster shell 250kg250kg 합계Sum 1,000kg1,000kg

유황화합물 액상 경옆처리제의 제조하기 표 2에 기재된 성분을 계량한 후 증류수에 각 성분들을 용해시켜 유황화합물 액상 경옆처리제를 제조하여 2차 살포액으로 제조하였고, 벼의 성장 과정마다 30일에 1회를 경옆처리제를 4배희석하여 총 3-4회 살포한다. 살포시기는 벼 파종후 1차로 70일 전후로 1차 살포하며 2차로 25일에서 30일 주기로 3회 살포하고, 사용량은 천연유황수 500cc를 1.000배 물과 희석하여 농약 분무 방식으로 옆면 살포한다.Preparation of Liquid Phase Sulfur Treatment Agent of Sulfur Compound A liquid sulfur phase treatment agent was prepared by dissolving the components listed in Table 2 below in distilled water to prepare a secondary spray solution. And then sprayed with the light-treating agent four times and sprayed three to four times in total. The spraying time is first spraying around 70 days after rice seeding, 3 times spraying with 25 times 30 days cycle second time, and spraying side by side with spraying method of spraying 500cc of natural sulfur water with 1.000 times water.

살포한 재배단지의 사진은 도 1과 같으며, 일반벼와 유황벼의 비교 사진은 도2와 같다. 또한, 토양계량제나 경옆처리제로 활용 가능한 천연유황수는 도 3에 나타내었다.The photographs of the sprayed cultivation complex are shown in Fig. 1, and the comparative photographs of the general rice and the sulfur rice are shown in Fig. In addition, the natural sulfur water that can be used as a soil metering agent or light-side treatment agent is shown in FIG.

유황화합물 액상 경옆처리제의 조성Composition of sulfur compound liquid phase light treatment agent 품 명Product Name 함량content 유황분말Sulfur powder 250kg250kg 가성소다Caustic soda 200kg200kg 전복패각Abalone shell 10kg10kg 고막패각Cortical shell 5kg5kg 암염rock salt 15kg15kg 규산 나트륨Sodium silicate 20L20L 미생물배양액Microbial culture 810L810L

유황쌀의 조단백질, 조지방, 조회분 분석상기 재배방법으로 생산된 유황쌀의 조단백질, 조지방, 조회분 분석 결과는 표3에 나타내었다. Crude protein, crude fat, and crude analysis of sulfur rice The crude protein, crude fat, and crude analysis results of the sulfur rice produced by the above cultivation method are shown in Table 3.

유황쌀은 새누리조으로 상기 제조방법으로 제조된 도양계량제, 경옆처리제를 살포하였으며, 일반쌀은 화성를 대조구로 하였다. 유황쌀의 살포시기는 벼 파종후 1차로 70일 전후로 1차 살포하며 2차로 25일에서 30일 주기로 3회 살포하였고, 사용량은 천연유황수 500cc를 1.000배 물과 희석하여 농약 분무 방식으로 옆면 살포하였다. Sulfuric rice was sprayed with a light metering agent, light - treatment agent, which was prepared by the above - described method, and general rice was treated with Mars as a control. Sulfur rice was sprayed firstly for about 70 days after rice seeding, and second sprayed three times for 25 days to 30 days. Sulfuric acid was sprayed on the side by spraying with 500cc of natural sulfur water with 1.000 times water and pesticide spraying method .

유황쌀의 조단백, 조지방, 조회분 분석결과Crude protein, crude fat, and crude analysis of sulfur rice 일반쌀Regular rice 유황쌀Sulfur rice 조단백Crude protein 6.56.5 6.566.56 조지방Crude fat 1.11.1 0.350.35 조회분Views min 0.280.28 0.270.27

유황쌀의 칼륨, 마그네슘, 칼슘, 비타민 B2 분석Analysis of Potassium, Magnesium, Calcium and Vitamin B2 in Sulfur Rice

상기 재배방법으로 생산된 유황쌀의 칼륨, 마그네슘, 칼슘, 비타민 B2 분석결과는 표4에 나타내었다. The results of analysis of potassium, magnesium, calcium and vitamin B2 of the sulfur rice produced by the cultivation method are shown in Table 4.

유황쌀의 칼륨, 마그네슘, 칼슘, 비타민 B2 분석결과Analysis of Potassium, Magnesium, Calcium and Vitamin B2 in Sulfur Rice 일반쌀Regular rice 유황쌀Sulfur rice 칼륨potassium 868.88mg/kg868.88 mg / kg 879.92mg/kg879.92 mg / kg 마그네슘magnesium 165.10mg/kg165.10 mg / kg 175.44mg/kg175.44 mg / kg 칼슘calcium 12.0%12.0% 16.28%16.28% 비타민 B2Vitamin B2 50mg%50 mg% 300mg%300 mg%

유황쌀의 필수 아미노산 분석Essential amino acid analysis of sulfur rice

상기 재배방법으로 생산된 유황쌀의 필수 아미노산 분석결과는 표5에 나타내었다. The essential amino acid analysis results of the sulfur rice produced by the cultivation method are shown in Table 5.

유황쌀의 필수 아미노산 분석Essential amino acid analysis of sulfur rice 일반쌀Regular rice 유황쌀Sulfur rice 메치오닌Methionine 119mg%119 mg% 148mg%148 mg% 트레오닌Threonine 164mg%164 mg% 240mg%240 mg% 알라닌Alanine 250mg%250 mg% 357mg%357 mg% 발 린Valin 251mg%251 mg% 327mg%327 mg% 이소루신Isoleucine 179mg%179 mg% 231mg%231 mg% 루 신Lu Shin 371mg%371 mg% 507mg%507 mg% 라이신Lysine 158mg%158 mg% 241mg%241 mg% 히스티딘Histidine 111mg%111 mg% 165mg%165 mg%

유황쌀의 비필수 아미노산 분석Non essential amino acid analysis of sulfur rice

상기 재배방법으로 생산된 유황쌀의 비필수 아미노산 분석결과는 표6에 나타내었다. The results of analysis of non-essential amino acids of the sulfur rice produced by the cultivation method are shown in Table 6.

유황쌀의 비필수 아미노산 분석Non essential amino acid analysis of sulfur rice 유황쌀(새누리, 4회살포)Sulfur rice (Saenuri, 4 times spraying) 시트테인Seattle 152mg%152 mg% 아스파르트산Aspartic acid 595mg%595 mg% 세 린Serine 333mg%333 mg% 글루탐산Glutamic acid 1097mg%1097 mg% 글리신Glycine 295mg%295 mg% 타이로신Tyrosine 252mg%252 mg% 아르기닌Arginine 523mg%523 mg% 프폴린Foflin 586mg%586 mg%

Claims (2)

(a) 탄소원으로 녹차 잎 및 광나무 잎이 6.5~7.5:2.5~3.5의 중량비로 포함된 혼합 배지를 23~35℃에서 43~48일간 발효시키는 단계;
(b) 상기 (a) 단계의 발효시킨 혼합 배지에 고온 멸균시킨 2~3%(w/v) 당밀 희석액을 첨가한 후, 유용미생물을 접종하여 23~35℃에서 92~140시간 동안 배양하는 단계;
(c) 상기 (b)단계의 배양한 유용미생물 배양액에 독성유황 분말을 25~35%(w/v)의 비율로 첨가한 후, 25~35℃에서 22~26시간 동안 1차 발효분해시키는 단계;
(d) 상기 (c)단계의 1차 발효분해한 발효분해물을 습식 콜로이드밀로 파쇄하는 단계;
(e) 상기 (d)단계의 파쇄된 1차 발효분해물을 고액 분리하고, 분리된 침전물에 상기 (b)단계의 유용미생물 배양액을 첨가한 후, 25~35℃에서 22~26시간 동안 2차 발효 분해시키는 단계;
(f) 상기 (e)단계의 2차 제독유황 발효분해물을 고액 분리하고, 분리된 고체를 75~85℃에서 건조시켜 제독유황 분말을 제조하는 단계; 및
(g) 상기 (f)단계에서 제조한 제독유황 분말 250kg과 휴믹산 20kg, 굴 패각250kg 및 미강 480kg으로 1톤을 혼합하여 25℃에서 72시간 발효하여 과립상으로 제조한 유황을 함유한 토양개량제를 제조하여 1차로 200평당 20kg을 살포하고, 2차로 상기 제조한 제독유황 분말 250kg, 가성소다 200kg, 전복패각 10kg, 고막패각 5kg, 암염15kg, 규산 나트륨 20 L 및 락토바실러스 파라파라지니스 배양액을 810 L로 구성성분으로 하는 유황화합물 액상 경엽처리제를 제조하여 벼의 성장 과정마다 30일에 1회씩 경엽처리제를 4배 희석하여 총 3~4회 살포하는 단계를 포함하는 것을 특징으로 하는 마그네슘, 이소루신 및 라이신 함량이 증진된 유황쌀을 제조하는 방법.
(a) fermenting a mixed medium containing green tea leaves and camphor leaves at a weight ratio of 6.5 to 7.5: 2.5 to 3.5 as a carbon source at 23 to 35 ° C for 43 to 48 days;
(b) adding a 2 to 3% (w / v) molasses dilution to a fermented mixed medium of step (a) by high temperature sterilization, and then inoculating the useful microorganism and culturing at 23 to 35 ° C for 92 to 140 hours step;
(c) adding toxic sulfur powder to the cultivated useful microorganism culture in step (b) at a rate of 25 to 35% (w / v), and then performing primary fermentation decomposition for 22 to 26 hours at 25 to 35 ° C step;
(d) disrupting the fermentation broth obtained by the first fermentation decomposition of step (c) with a wet colloid mill;
(e) separating the pulverized primary fermentation broth of step (d) by solid-liquid separation, adding the culture medium of the useful microorganism in step (b) to the separated precipitate, Fermenting and decomposing;
(f) solid-liquid separation of the second-order hydrolyzed sulfuric acid hydrolyzate of step (e) and drying the separated solid at 75 to 85 ° C to prepare a virgin sulfur powder; And
(g) One ton of the crude sulfur powder (250 kg), humic acid (20 kg), oyster shell (250 kg) and rice bran (480 kg) were fermented at 25 ° C for 72 hours to prepare a granular soymilk containing soil improving agent And 20 kg / 200 flats were sprayed firstly. Secondly, 250 kg of the above-described prepared virgin sulfur powder, 200 kg of caustic soda, 10 kg of abalone shell, 5 kg of cornea, 15 kg of rock salt, 20 L of sodium silicate and 810 L of Lactobacilli paraparialis culture The method for producing a sulfur compound liquid foliar treatment agent according to any one of claims 1 to 3, wherein the foliar treatment agent is diluted four times every 30 days for every three growing stages of rice, and sprayed three to four times in total. A method for producing sulfur rice with enhanced lysine content.
제1항의 방법에 의해 제조된 유황쌀.
The sulfur rice produced by the method of claim 1.
KR1020140143018A 2014-10-22 2014-10-22 Method for producing a sulfur-functional rice prepared using Admiral sulfur and Uses KR101547922B1 (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101719261B1 (en) * 2016-04-21 2017-03-27 농업회사법인 주식회사 엘바이오텍 Sulfur-cabbage
KR20180020480A (en) * 2016-08-18 2018-02-28 김흥일 Red ginseng and Ginseng Comprise Rice
KR102474511B1 (en) * 2022-03-21 2022-12-06 농업회사법인 주식회사 닛시 Beneficial sulfur that removed the toxicity of sulfur, Fertilizer, sterilization, pesticide using beneficial sulfur and manufacturing method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101719261B1 (en) * 2016-04-21 2017-03-27 농업회사법인 주식회사 엘바이오텍 Sulfur-cabbage
KR20180020480A (en) * 2016-08-18 2018-02-28 김흥일 Red ginseng and Ginseng Comprise Rice
KR101867454B1 (en) * 2016-08-18 2018-06-15 김흥일 Red ginseng and Ginseng Comprise Rice
KR102474511B1 (en) * 2022-03-21 2022-12-06 농업회사법인 주식회사 닛시 Beneficial sulfur that removed the toxicity of sulfur, Fertilizer, sterilization, pesticide using beneficial sulfur and manufacturing method thereof

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