KR101384694B1 - Complex finishing process method by loess and persimmon tannin of dyed fibers - Google Patents

Abstract

The purpose of the present invention is to provide a functional product for health beneficial to human bodies by primarily dyeing fabric such as cotton fabric or clothes and bedclothes using cotton fabric, and conducting the complex post processing of the primarily dyed fabric using loess and persimmon juice. To solve the above-mentioned problem, the present invention post processes the dyed fabric by a cationization process for obtaining the primarily dyed fabric in the process of dyeing the fabric to be post processed, and improving the adsorptive property of loess in the process of giving an ionic property to the primarily dyed fabric using a cationizing agent; a loess adsorption process for primarily post processing the dyed fabric by soaking the dyed fabric in loess water having loess mixed therein using a dyeing machine; and a persimmon juice adsorption process for forming a persimmon juice membrane layer on the surface of the loess adsorbed to fibers by secondarily post processing the dyed fabric in the process of soaking the dyed fabric in persimmon juice using the dyeing machine again. [Reference numerals] (AA) Cotton fabric; (BB) Products made of cotton fabric; (S1) Fabric dyeing process; (S10) Singeing process; (S11,S20) Desizing process; (S12) Refining and bleaching process; (S13) Reactive dye dyeing process; (S2) Cationization process; (S21) Pigment dyeing process; (S22) Binder treating process; (S23) Biological treatment process; (S3) Loess adsorption process; (S4) Persimmon juice adsorption process

Description

COMPOSITE FINISHING PROCESS METHOD BY LOESS AND PERSIMMON TANNIN OF DYED FIBERS}

The present invention is intended to provide a health functional product that is beneficial to the human body by primary dyeing of the dyeing material such as clothing, bedding, etc., using cotton fabric or cotton fabric, in turn after the complexing of the primary dyeing dyeing using ocher and persimmon .

In general, natural dyeing is a dye that is obtained from nature using dyes obtained from nature, and dyes with natural materials obtained from nature without using chemicals that are harmful to the human body. It is a trend.

Natural dyeing is mostly carried out by manual labor, which makes it difficult to mass-produce, economically and productive, inefficient, very difficult to work on, and staining easily occurs according to the skill of the operator. There was a difficulty in repeat production.

As a means to solve these problems, a means of using natural dyeing rather than manual dyeing machine has been provided.

Patent Registration No. 290316 "Cold Pad Dyeing Method of Natural Fiber and Knitted Fabrics Using Loess and Tidal Flats" (Patent Document 1) and Patent Registration No. 535320 "Dyeing Method of Fabrics Using Natural Dyes" (Patent Document 2) And Patent No. 1152909 "Ocher natural dyeing method using a dyeing machine" (Patent Document 3) and the like have been provided.

Examining the technical contents of the patent document 1, the pretreatment step of refining, bleaching, neutralizing and washing natural fibers, diluting the ocher and mudflat in water, filtering the fine particles, and then diluting with water in a ratio of 1: 2 to 1:20. Dyeing step, immersing the fiber fabric of the salt solution and padding at room temperature using a pressing roller, repeating the dyeing step until a desired color concentration is obtained, washing the dyed fabric and then adsorbing the adsorbed ocher particles Dyeing is done in a post-treatment step.

When reviewing the technical contents of Patent Document 2, in order to give an electrostatic function to the fabric that has undergone the refining bleaching and sealing process, the reaction is performed at 40 to 80 ° C. for 10 to 30 minutes after adding DMSIP or SIPEG at 0.5 to 5.0% by weight relative to the liquid ratio. To give the functionality of the fiber, and adjust the liquid ratio to 1: 20 to 40 by dissolving 0.5 to 5.0% by weight of the anionic natural dyes relative to the liquid ratio and dyed for 20 minutes at the initial dyeing temperature 30 ℃, 80 ℃ Dyeing by heating and drying for 60 minutes and adding 0.5-5.0% by weight of ultrafine colloidal TiO ₂ in the processing process to fabrics which have been embedded, washed, washed, dehydrated and dried in the process of drying will be.

In addition, by reviewing the technical contents of Patent Literature 3, pre-treating the fabric to be dyed, preparing the ocher dye, putting the dye and the ocher dye into a dyeing machine, and dyeing the glacial acetic acid at a concentration of 0.2% in the dyed fabric. Including a step, the first washing the dyed fabric, drying, washing the dried fabric and the second drying the washed fabric, the step of preparing the ocher dye is ocher particles Removing the foreign matter in the fine powder, step of mixing the fine powdered ocher with water in a weight ratio of 1: 6, and dyeing by mixing the salt solution of the 8% concentration.

Examining the dyeing means of Patent Documents 1 to 3, by using a natural dyeing machine by using a dyeing machine, by lowering the product price through mass production, excellent economic efficiency, convenient dyeing work, and color reproducibility It is an excellent effect.

However, by examining the dyeing means provided in the prior art, the fabric to be dyed is removed by staining or bleaching process to remove pigments possessed by other impurities and fibers, and then to ocher in a colorless state. Not only can not be obtained a variety of color dyeing, but also in functionality other than the functionality of the loess was not expected.

Patent registration No. 290316 "Cold pad dyeing method of natural fabric and knitted fabric using ocher and tidal flat" Patent registration No. 535320 "Dyeing method of fabrics using natural dye" Patent registration No. 1152909 "Oil natural dyeing method using dyeing machine"

The present invention is to solve the problems caused by the conventional dyeing method, while the primary dyeing of the dye in a variety of colors and at the same time to obtain a complex function of the natural material, in particular blood circulation and Promotes metabolism, removes toxins in the body, cools refreshing, antibacterial and odor removal, and provides high-quality cotton fiber products to prevent and treat skin diseases such as atopy and allergy. To meet the requirements.

As a means for solving the above problems, the present invention is to dye the chlorine to be post-processed to obtain a primary dye, and the primary dye to give ionicity by using a cationic agent Cationization process to improve the adsorption property, ocher adsorption process to immerse the chlorine in the ocher mixed with ocher, the first post-processing process, and second immersion in the persimmon using the dyeing machine again The post-treatment is a post-treatment of the dyeing of the dyeing through the permeation adsorption process to give the permeate coating layer on the surface of the loess adsorbed on the fiber.

The present invention is pretreated with a dyeing material of cotton material and then dyed with a dye of the desired color, and then cationic to the dyeing the dyeing dyeing, and then immersed in ocher, soaking ocher to cotton fiber, immersed in persimmon, cotton fiber By providing the permeable coating layer on the adsorbed ocher surface, it is possible to provide high quality cotton fabric products that satisfy the needs of consumers by improving the adhesion of the loess and simultaneously providing the functionality of the loess and persimmons. will be.

1: Post-processing process diagram of the present invention

Hereinafter, an embodiment of the present invention will be described in detail by process.

The present invention first dyeing the dyeing of the cotton fabric of cotton fibers, such as clothing and bedding products made of cotton fabrics in a desired color using a dyeing machine, and the first dyeing after the dyeing of the dyeing of the dyeing material with natural soil ocher After processing, the chlorinated material is secondly processed again to persimmon to obtain a product that meets both the functionality of the loess and the functionality of the persimmon.

The dyeing of the dye product produced by using the cotton fabric or cotton fabric, is dyed with a reactive dye, or dyed with a pigment, the dyeing process is a common operation commonly performed in domestic dyeing companies.

In the case where the chlorinated dye is cotton fabric, the dye is mainly dyed with a reactive dye, which is generally performed. Briefly, the dyeing process will be described first. Singeing process, the desizing process to hydrolyze and remove the squeeze applied to the inclination for smooth weaving of the chlorinated weaving, the scouring and bleaching process using the scouring agent and bleaching agent After the treatment, a scouring bleaching step of removing impurities, dyes, etc. of the cotton fibers is carried out sequentially, followed by washing with a reactive dye dyeing step of dyeing the dye using a reactive dye to finish dyeing the dyeing material of the cotton fabric.

In addition, when the dyeing product is a cotton fabric product such as clothing or bedding, pigment dyeing is generally performed, and the dyeing process is briefly described to describe the dye contained in the dyeing product of cotton fabric product. Pigmentation process by hydrolysis and removal, Pigmentation process which adds and treats the dyeing process to the dyeing solution filled with pigment and water in the proper ratio, and Pigment dyeing process using the preparation And the bio treatment process to remove the fuzz of cotton fibers with cellulase extracted by cultivating enzyme bio (cotton reducing enzyme), that is, yeast, in the bath. To finish dyeing the dyeing of cotton fabrics.

When the dyeing of the dyeing of the cotton fabric or cotton fabric product as described above is completed is subjected to the post-processing of the dyeing material using the natural material of the technical gist of the present invention.

In the case of post-treatment treatment, the post-treatment process is carried out using a dyeing machine regardless of the type of the dye.However, if the dye is cotton, the jigger dyeing machine is used, and if the dye is a cotton cloth product (clothing, bedding, etc.) It is preferable to use a rotary dyeing machine.

In the post-processing process, a cationization process, an ocher adsorption process, and a sensory adsorption process are sequentially performed, and the respective processes will be described in more detail.

The cationization process is to increase the adsorption rate of the yellow soil by modifying the surface of the anion with cations, and the preparation for the cationization process uses a cation agent used in the general dyeing process.

That is, 200 to 250 liters of water and 18 to 25 kg of cationic agent are added to the bath of the dyeing machine, and then sufficiently stirred at room temperature to obtain a solution of cationic treatment.

The solution is added to the cationic solution at a rate of 360 to 400 kg and treated at room temperature for about 40 to 50 minutes to modify the salt to cations, followed by washing at room temperature.

After the cationic treatment, the salt is subjected to an ocher adsorption process.

The ocher adsorption process is filled with the yellow soil in the ratio of 200 ~ 250ℓ of water, 20 ~ 25kg of ocher in the bath of the dyeing machine, and put the chlorine in the ocher to treat the soil for 40 to 50 minutes at room temperature The ocher adsorption process is completed by allowing the adsorbed fibers to sufficiently adsorb.

At this time, the salt is modified by cation through the cationic process, and the yellow soil fine particles bearing the anion are adsorbed firmly on the fiber surface.

The salts that have undergone the ocher adsorption process are subjected to the sensory adsorption process again.

The persimmon adsorption process fills the persimmon dilution water mixed in the ratio of 200 ~ 250ℓ of water and 36 ~ 40L persimmon stock solution (purchase use) in the tub of the dyeing machine, and the salted water that has completed the adsorbing process on the persimmon dilution water After 40 to 50 minutes at room temperature, the persimmon is adsorbed on the fiber surface to which ocher particles are adsorbed to form a coating layer.

The finished dye absorbing process is dried and processed to be commercialized.

As described above, the present invention is to dye the dyeing in a general manner, such as cotton fabrics, clothing or bedding made of cotton fabrics, and then cationized the dyed dyes and then ocher adsorption process, persimmon adsorption process By sequentially carrying out, it is possible to obtain a high-quality product that can satisfy the functionality of the loess and the functionality of the persimmon at the same time.

In reviewing the functionalities of the yellow soil recorded in the literature, it is effective in improving blood circulation and metabolism due to far-infrared radiation, removing toxins in the body, and changing the alkalinity of the constitution acidified by anion release. Examining it, it is reported that it is effective in preventing and treating various skin diseases such as atopy and allergy as well as cool refreshing feeling, antibacterial and odor removal.

Therefore, by post-processing secondary to the first dyed dyeing to provide a high-quality product that satisfies the functionality of loess and persimmon, it is possible to meet the needs of consumers.

(S1)-Stain dyeing process (S2)-Catification process
(S3)-Ocher adsorption process (S4)-Persimmon adsorption process
(S10)-Singing process (S11)-Calling process
(S12)-Refining and bleaching process (S13)-Reactive dye dyeing process
(S20)-Deposition Process (S21)-Pigment Dyeing Process
(S22)-Binder Process (S23)-Bio Process

Claims (3)

Dyeing the dyeing of cotton fiber to the desired color through the cotton fiber dyeing process, 200 ~ 250ℓ of water and 18 to 25 kg of cationic agent in the bath of the dyeing machine is added and stirred to obtain a cationization solution, to the cationization solution After the treatment for about 40 to 50 minutes at room temperature by the addition of the chlorine, the caking step (S2) and washing the filled ocher water at a ratio of 200 to 250 liters of water and 20 to 25 kg of ocher in the bath of the dyeing machine, the bath The ocher adsorption process (S3) in which the chlorine is added and treated at room temperature for 40 to 50 minutes to allow the ocher particles to be adsorbed to the fibers, and at a ratio of 36 to 40 l of the persimmon stock extracted from 200 to 250 l of water and persimmon in the bath of the dyeing machine. Filling the mixed persimmon dilution water, the chlorine is added to the persimmon dilution water, and treated at room temperature for 40 to 50 minutes by adsorbing the persimmon on the fiber surface adsorbed ocher particles to form a coating layer (S4) Dyed In the complex post-processing method of the loess and persimmons of the tainted substance, a desizing process (S20) for hydrolyzing and removing the scavenger contained in the tainted substance, and a pig which is fed and dyed to the dyeing tank filled with the pigment and water. Treatment dyeing step (S21), the color of the color adsorbed on the blood stains, and the coating process (S22), and the biotreatment process of removing the fuzz of cotton fibers with the cellulase cultivated and extracted the yeasts ( S23) and then the process of complex post-processing the ocher and persimmon of the dyed saline, characterized in that it is introduced into the cationic step (S2). delete delete

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