KR101350100B1 - Fiber highly cool to touch - Google Patents

Abstract

The present invention provides a dough, medical and underwear having excellent contact cooling feeling made of fibers which can prevent unpleasant feelings when wet and have excellent texture of texture and feel and excellent contact cooling feeling, and fibers having excellent contact cooling feeling. For the purpose of The present invention is a fiber excellent in contact cooling feeling containing a thermoplastic elastomer and an inorganic filler.

Description

Fiber superior in contact cooling feeling {FIBER HIGHLY COOL TO TOUCH}

The present invention is capable of preventing unpleasant feelings when wet, and is excellent in greige and medical treatment, which is made of fibers having excellent contact cooling feeling excellent in texture and feel, and fibers having excellent contact cooling feeling. ) And underwear.

In recent years, the use of the fiber which is excellent in the cold feeling of contact which gives a cool feeling at the time of wearing as a summer underwear and gives a refreshing feeling is studied.

As a method of obtaining the fiber excellent in such a feeling of contact cooling, the method of improving the water absorption of a fiber, the heat conductivity of a fiber, etc. was performed conventionally, for example.

As a fiber which improved water absorption, the fiber etc. which consist of resin which introduce | transduced hydrophilic groups, such as a carboxyl group and a hydroxyl group, are mentioned, for example.

As a fiber which improved the thermal conductivity, the fiber which consists of resin containing the filler with high thermal conductivity, the fiber which plated the surface, etc. are mentioned, for example.

However, when such a fiber is used, it can certainly be expected to obtain a feeling of contact cooling in theory, but when a sensory test by a human is actually carried out, it is almost the same as that of untreated, and the feeling of contact cooling could not be realized.

Patent Literature 1 discloses a fiber having a contact cooling effect formed by gripping porous inorganic powder particles containing an absorbent polymer into a fiber. This fiber has a level of contact cooling feeling that can be reliably realized. However, in order to obtain sufficient contact cooling feeling, it is necessary to contain a large amount of porous inorganic powder particles, and as a result, adverse effects occur in texture and feel, and they cannot be used in underwear or the like.

Patent Document 1: Japanese Unexamined Patent Publication No. 2002-235278

The present invention provides a feeling of sufficient contact cooling feeling at a sensory level, excellent texture and feel, and excellent contact cooling feeling that can be preferably used in underwear and the like, and a contact cooling feeling using a fiber having excellent contact cooling feeling. The aim is to provide excellent dough, medical care and underwear.

The present invention is a fiber containing a thermoplastic elastomer and an inorganic filler.

This invention is explained in full detail below.

MEANS TO SOLVE THE PROBLEM As a result of earnestly examining, the present inventors discovered that the fiber obtained by spinning the thermoplastic elastomer is excellent in contact cooling feeling when it uses for medical use. However, when the fiber containing the thermoplastic elastomer is used in medicine, the contact feeling is excellent, but when wetted by sweat or the like, it sticks or deteriorates the touch, and especially when used in the medicine directly touching the skin such as underwear. There is a new problem that causes discomfort. Therefore, the inventors of the present invention have conducted a thorough study, and by adding an inorganic filler to the fiber containing the thermoplastic elastomer, when used in medical treatment, it is possible to prevent discomfort during wetness and to provide excellent texture and feel. Since it can be done, it discovered especially that it can use suitably for medical care, such as underwear, and came to complete this invention.

According to the present invention, it is possible to prevent unpleasant feeling when wet, and furthermore, to provide dough, medical and underwear having excellent contact cooling feeling, which is made of a fiber having excellent contact cooling feeling with excellent texture and feel, and a fiber having excellent contact cooling feeling. can do.

FIG.1 (a) is a schematic diagram which shows an example of the medical which was excellent in the cold feeling of contact of this invention.
FIG.1 (b) is a schematic diagram which shows an example of the medical which was excellent in the cold feeling of contact of this invention.
FIG.2 (a) is a schematic diagram which shows an example of the medical which was excellent in the cold feeling of contact of this invention.
FIG.2 (b) is a schematic diagram which shows an example of the medical which was excellent in the cold feeling of contact of this invention.
3 is a schematic diagram showing the flow of heat and water vapor emitted from the skin when wearing sensation medicine.
4 is an organization chart showing a letter of a reversible structure knitted in Example 14;
Fig. 5 is an organization chart showing a letter of reversible structure organized in Example 15;
6 is a graph showing the evaluation results in the artificial vapor phase chamber carried out in the examples.
7 is a graph showing the results of sensory evaluation 1 performed in the examples.
8 is a graph showing the results of sensory evaluation 2 performed in the examples.

The thermoplastic elastomer is not particularly limited, but polyamide elastomers and / or polyester elastomers are preferable.

It does not specifically limit as said polyamide-type elastomer, For example, a polyether blockamide copolymer, a polyetheramide copolymer, a polyesteramide copolymer, etc. are mentioned. These may be used independently and 2 or more types may be used together.

As what is marketed among these polyamide-type elastomers, For example, Pebox (made by Arkema), UBE nylon (made by Ube Heungsan), Glylon ELX, Grillamide ELY (above, is manufactured by MMS Showa Electric Co., Ltd.). ), Diamide, bestamid (above, produced by Daicel Dexa Co.) and the like.

It does not specifically limit as said polyester-type elastomer, For example, a polyether ester copolymer, a polyester ester copolymer, etc. are mentioned.

These may be used independently and 2 or more types may be used together.

Commercially available among these polyester-based elastomers include, for example, Glylax (manufactured by Dainippon Ink and Chemicals Co., Ltd.), Nuberan (manufactured by Teijin Kasei Co., Ltd.), Pelfurene (manufactured by Toyo Boseki Co., Ltd.), Hytrel ( Toray Dupont Co., Ltd., Primero (made by Mitsubishi Chemical Corporation), etc. are mentioned.

Among these thermoplastic elastomers, the polyetherblockamide copolymer represented by the following formula (1) is characterized in that fibers which give a very good contact cooling feeling are obtained, excellent in radioactivity, light weight, light dough, medical care, underwear, etc. It is especially preferable at the point which the fiber which can manufacture can be obtained. As what is marketed among these polyether blockamide copolymers, Pebox (made by Arkema) etc. is mentioned, for example.

[Formula 1]

In formula (1), PA represents a polyamide and PE represents a polyether.

Although the said thermoplastic elastomer may be sufficient as the resin component contained in the fiber excellent in the cold feeling of contact of this invention, the fiber containing only a thermoplastic elastomer as a resin component generally has a feeling of sticking and it may become difficult to spin. In addition, you may use together with other resins other than the said thermoplastic elastomer.

The fiber excellent in the cold feeling of contact of this invention contains an inorganic filler further.

When the inorganic filler is contained, minute unevenness is formed on the surface of the fiber, and the surface of the fiber is modified. Therefore, the sticking feeling during the wetness, which is a characteristic of the thermoplastic elastomer, can be prevented, and when used in medical care. It can greatly improve the touch when it touches the skin and the detachment from the skin at the time of desorption. In addition, since the sticking of the fibers can be reduced, the spinning property when producing the yarn can be improved.

In addition, in the fiber excellent in the contact cooling feeling of the present invention, a large amount of inorganic filler is added in order not to impart contact cooling property but to prevent sticking feeling when wet, and to add an inorganic filler. It does not need to be added, and even when used for medical purposes, no adverse effects occur on texture or feel.

It does not specifically limit as said inorganic filler, For example, magnesium carbonate, such as calcium carbonate, such as hard calcium carbonate and heavy calcium carbonate, a barium carbonate, basic magnesium carbonate, calcium sulfate, barium sulfate, titanium dioxide, iron oxide, tin oxide Diatomaceous earth, calcium silicate, aluminum silicate, magnesium silicate, amorphous silica, amorphous synthetic silica, such as titanium oxide, zinc oxide, magnesium oxide, ferrite powder, zinc sulfide, zinc carbonate, aluminum nitride, silicon nitride, satin white, calcined diatomaceous earth, Silica such as colloidal silica, colloidal alumina, pseudo boehmite, aluminum hydroxide, magnesium hydroxide, alumina, alumina hydrate, littphone, zeolite, hydrolyzate, clay, hydrotalcite, aluminosilicate, talc, pyrophyll Light, saponite, hectorite, soconite, stevensite, montmorillonite, Smectite, vermiculite, gold mica, biotite, zinnwaldite, dolomite, paragonite, ceradite, hematite, such as ideolite, nontronite, cinnamon, chamosite, nimite , Phenanthite, waterite, tonbasite, clintonite, margarite, sprite, antigorite, lizardite, chrysotile, mecite, crossteite, vachelin, greenite, garniite, kaolinite Kaolin such as decite, nacrite, halosite, deramikaolin, calcined kaolin, sepiolite, parigoscarite, imogolite, arofen, hiscinegerite, penwysite, activated clay, bentonite, cerasite, etc. Mineral pigments; and the like. These may be used independently and 2 or more types may be used together.

Among these, titanium oxide, zinc oxide, barium sulfate and silica are preferable.

Moreover, as a shape of the said inorganic filler, it does not specifically limit, Shaped objects, such as spherical shape, needle shape, and plate shape, or amorphous shape are mentioned.

The minimum with preferable average particle diameter of the said inorganic filler is 0.20 micrometer, and a preferable upper limit is 3.00 micrometer. If the thickness is less than 0.20 µm, the effect of improving unpleasant feeling such as sticking during wetting may be insufficient. If the thickness is more than 3.00 µm, the texture or texture may be impaired or the strength of the fiber may be reduced in medical treatment. have.

The minimum with preferable content of the said inorganic filler is 2 weight%, and a preferable upper limit is 30 weight%. A more preferable upper limit is 7 weight%. If it is less than 2 weight%, the effect of improving unpleasant feelings, such as sticking at the time of wetness, may become inadequate, and when it exceeds 30 weight%, the strength of a fiber may fall. Moreover, radioactivity may worsen.

Although the fiber excellent in the contact cooling feeling of this invention may consist only of the fiber containing the said thermoplastic elastomer and an inorganic filler, it aims at improving the requirements for underwear, such as a touch, in the range which does not impair the objective of this invention. It is also possible to use alternating fibers. Although it does not specifically limit as such other fibers, For example, Polyamide resin, such as nylon 6 and nylon 12; Polyester, cotton, rayon, etc. are mentioned.

The fiber excellent contact feeling of cold of the present invention, the preferable lower limit of the q _max value is 0.20J / sec / ㎠. When q _max value is less than 0.20 J / sec / cm <2>, most people do not feel a cold feeling even if it carries out a sensory test. The minimum with more preferable is 0.21 J / sec / cm <2>, and still more preferable is 0.22 J / sec / cm <2>.

In addition, in this specification, _qmax value is the peak value of the amount of heat flow which accumulates predetermined | prescribed heat | fever in the hotplate of a fixed area and a fixed mass, and this accumulated heat amount moves to the sample of low temperature side immediately after this contact | connects a sample surface. . q _max value, when a garment is considered to simulate the body temperature deprived of the sample, the higher the q _max value increases the temperature at the time of deprived garment, it is believed this high contact feeling of cold.

As for the fiber excellent in the contact cooling feeling of this invention, the preferable minimum of thermal conductivity is 1 * 10 <^-3> C / W * m <2>. The thermal conductivity is also considered to be one of the important parameters corresponding to the cooling of the contact. When thermal conductivity is less than 1 * 10 <^-3> degreeC / W * m <2>, most people may not feel contact cold feeling even if it carries out a sensory test.

In addition, in this specification, a heat conductivity measures the heat loss rate after superposing | superposing a hotplate on the sample put on the sample stage, and stabilized the temperature of a hotplate to predetermined temperature, and is computed by following formula (2). Can be.

Thermal Conductivity (W / cm / ℃) = W / D / A / ΔT (2)

W: Heat flow rate (J / sec)

D: thickness of the sample (cm)

A: hot plate area (㎠)

ΔT: The temperature difference between the sample bed and the hot plate (℃)

As for the fiber excellent in the contact cooling feeling of this invention, the preferable minimum of a wet slip start angle is 20 degrees, and a preferable upper limit is 25 degrees. When it is less than 20 degrees, a texture and a touch may worsen, and when it exceeds 25 degrees, desorption from skin may fall when used for underwear. In addition, the said wet slip start angle can be calculated | required by measuring the slip start angle according to the inclination method according to JIS P 8147.

As for the fiber excellent in the contact cooling feeling of this invention, the preferable minimum of a wet slip resistance value is 1.28 CN / cm <2>, and a preferable upper limit is 1.58 CN / cm <2>. When it is less than 1.28 CN / cm <2>, a texture and a touch may worsen, and when it exceeds 1.58 CN / cm <2>, desorption property from the skin at the time of wet may fall. In addition, the said wet slip resistance value refers to the static frictional resistance value at the time of wetness, and can be measured by the inclination method according to JISP 8147.

The fiber excellent in the contact cooling feeling of this invention may be used as a composite fiber which consists of the said thermoplastic elastomer and another resin, and especially has a core / sheath structure, and contains the core part and thermoplastic elastomer resin containing a chlorinated resin. It is preferable that the thickness of the initial portion is 20 µm or less (hereinafter also referred to as a deep sheath composite fiber).

The fiber excellent in the contact cooling feeling of this invention uses the resin which can be dyed as such a core part, and has the contact cooling feeling at the beginning, and uses the thermoplastic elastomer which is excellent in flexibility, and ensures the outstanding performance of the thermoplastic elastomer called contact cooling sensitivity. In addition, it can be set as the fiber which has a favorable poncho structure.

In general, since the thermoplastic elastomer does not have a dyeing seat necessary for dyeing, or even if it has a dyeing seat, it is difficult to dye using an acid dye or a cationic dye. For this problem, Japanese Patent Laid-Open No. 2003-247177 discloses a method of dyeing thermoplastic elastomers such as polyurethane using a disperse dye. Moreover, the method of salting by introducing a salted seat in a thermoplastic elastomer resin, the method of coloring by containing the inorganic pigment etc. in the pellet of a thermoplastic elastomer resin, and making it colored, and polyamide to the polyamide elastomer resin as a thermoplastic elastomer resin Various methods, such as a method of salting by blending system resin, are examined. However, none of these methods sufficiently solved the problem of staining.

On the other hand, when dyeing is carried out using the above-described sheath type composite fiber, the dye passes through the sheath containing the thermoplastic elastomer having almost no dye seat, and the heart portion containing the salting resin is dyed. As a result, when the dyeing is carried out using the above-described sheath type composite fiber, dyeing can be preferably performed even with dyes such as acid dyes and cationic dyes, and moreover, compared with the fiber using a thermoplastic elastomer alone, Excellent dyeing can be exhibited.

It is preferable that the said deep seaweed type | mold composite fiber contains a chlorinated resin in a core part.

The above-mentioned chlorinated resin is not particularly limited as long as it can be dyed and can be used as a fiber. For example, polyamide resin such as nylon 6, nylon 66, nylon 12, poly such as PET, PBT, PTT, etc. Ester resin, other rayon, acryl, etc. are mentioned. In these, polyamide resin is preferable. These may be used alone or in combination of two or more.

Although the content of the said chlorinated resin in a core part changes with the resin to be used for the said core sheath composite fiber, a preferable minimum is 5 weight%. If it is less than 5 weight%, dyeability may fall.

The core sheath composite fiber may contain various additives in addition to the salting resin in the core portion as necessary. It does not specifically limit as said additive, For example, antioxidant, antiseptic | preservative, antistatic agent, stabilizer, antioxidant, gloss remover, light resistant agent, a lubricating agent, a fragrance | flavor, a plasticizer, surfactant, a flame retardant, etc. are mentioned.

It is preferable that the said deep sheath composite fiber contains the said thermoplastic elastomer and an inorganic filler at the edge part.

Although the content of the said thermoplastic elastomer in a sheath part changes with resin to be used, in the said deep sheath composite fiber, a preferable minimum is 15 weight%. If it is less than 15 weight%, contact cooling sensitivity may fall.

The core sheath composite fiber may contain various additives in addition to the thermoplastic elastomer at the beginning. It does not specifically limit as said additive, For example, antioxidant, antiseptic | preservative, antistatic agent, stabilizer, antioxidant, gloss remover, light resistant agent, a lubricating agent, a fragrance | flavor, a plasticizer, surfactant, a flame retardant, etc. are mentioned.

It does not specifically limit as a shape of the said deep sheath composite fiber, For example, the cross-sectional shape at the time of cut | disconnected perpendicularly to the longitudinal direction of a fiber may be a round shape, or an ellipse etc. may be sufficient as it. Moreover, the fiber which has a concentric eccentric structure formed concentrically and the said core part and a sheath part may be sufficient as you, and the fiber which has an eccentric heart sheath structure in which the said core part and the sheath part were formed eccentrically may be sufficient as it. The structure may be such that a plurality of core portions exist when the fibers are cut perpendicular to the longitudinal direction of the fiber.

In the above-mentioned core sheath composite fiber, it is preferable that the upper limit of the thickness of the said sheath part is 20 micrometers. When it exceeds 20 micrometers, dye may not pass through a sheath well at the time of dyeing, and dyeability may become inadequate. Moreover, the minimum with preferable thickness of the said begin part is 2 micrometers. If it is less than 2 micrometers, a sheath may be too thin and a contact cooling effect may not be exhibited.

In the case where the core portion and the sheath portion of the heart sheath composite fiber have a concentric heart sheath structure formed in a concentric manner, the preferred lower limit of the ratio of the diameter of the core portion to the thickness of the sheath portion (core portion / second portion) is 5/20, and the preferred upper limit is 46 /. 2 If it is less than 5/20, the ratio of the initial part may be large, and dyeability may become inadequate, and when it exceeds 46/2, contact cooling sensitivity and flexibility may fall.

The lower limit of the q _max value of the deep sheath composite fiber is preferably 0.17 J / sec / cm 2. When q _max value is less than 0.17 J / sec / cm <2>, it is the level equivalent to polyester and nylon, and even if a sensory test is performed, most people may not feel the outstanding contact cold feeling. The minimum with more preferable is 0.18 J / sec / cm <2>, and still more preferable 0.1 gJ / sec / cm <2>.

The preferable minimum of the said thermal conductivity of the said deep seaweed composite fiber is 0.9 * 10 <^-3> degreeC / W * m <2>. When the thermal conductivity is less than 0.9 × 10 ⁻³ ° C / W · m 2, most people may not feel the cold feeling of contact even when performing a sensory test.

It does not specifically limit as a method of manufacturing the fiber excellent in the contact cooling feeling of this invention, For example, after manufacturing resin pellets containing a thermoplastic elastomer and an inorganic filler, using the obtained resin pellets and performing melt spinning Conventionally well-known methods, such as a manufacturing method, can be used.

In addition, the above-mentioned core sheath-type composite fiber can be manufactured by the method of throwing resin pellets containing a chlorinated resin, a thermoplastic elastomer, and an inorganic filler into a composite spinning apparatus, and melt spinning.

The fiber excellent in the cold feeling of contact of this invention can be used as raw materials, such as a knitted fabric, a woven fabric, a nonwoven fabric. The raw material which is excellent in the cold contact feeling which uses the fiber excellent in the cold contact feeling of this invention is also one of this invention.

Although the dough which is excellent in the contact cooling feeling of this invention may consist only of the fiber which is excellent in the contact cooling feeling of this invention, in order not to impair the objective of this invention, it is another fiber for the purpose of improving the requirements required for underwear etc., such as a touch. It does not matter even if it intersects with. Although it does not specifically limit as such other fibers, For example, Polyamide resin, such as nylon 6 and nylon 12; Polyester, cotton, rayon, etc. are mentioned.

By using the fiber which is excellent in the contact cooling feeling of this invention and the dough which is excellent in the contact cooling feeling of this invention, it can prevent the discomfort at the time of wetness, and it can be set as the medical which was excellent in a texture and a touch. Medical which is excellent in such a cold feeling is also one of this invention.

The medical which is excellent in the cold feeling of contact of this invention contains a thermoplastic elastomer, and can produce a cool feeling at the time of wearing, and can give a refreshing feeling. Moreover, by containing an inorganic filler, there is no stickiness at the time of wetness, it is excellent also in touch and a texture, and it can use suitably also for underwear.

Although the thing which used the fiber excellent in contact cooling feeling as a whole may be used for the medical which is excellent in contact cooling feeling of this invention, Especially, it is the medicine which is excellent in the feeling of feeling which consists of letters of reversible structure, It is preferable to use what the 30-70% is a loop which consists of a fiber excellent in contact cooling feeling, and the loop which consists of a fiber excellent in contact cooling feeling is arrange | positioned only on the skin side (henceforth a sensation medicine).

The medical treatment which is excellent in the contact cooling feeling of this invention WHEREIN: The medical treatment which consists of a letter of reversible structure WHEREIN: The ratio of the number of loops which consists of a fiber which is excellent in contact cooling feeling is made into a fixed range, and the loop which consists of a fiber which is excellent in contact cooling feeling is directly connected with skin. By arrange | positioning only to the skin side which touches, it can be set as the medicine which has the effect of preventing the unpleasant feeling which arises due to high sweating.

In recent years, various medical treatments have been developed that have been developed to improve the function as underwear to be worn during sweating during summers and sports, and as such functional medical treatments, medical treatments made of hydrophobic fibers such as polyester have been proposed. . In addition, a method of increasing the air permeability by using cotton in combination with hydrophobic fibers, a method of increasing the air permeability by making the structure of the dough into a mesh structure, or making a bruise by changing tissues of the sheeting piece and the thin piece is examined. Japanese Unexamined Patent Publication No. 2003-155669 discloses a cloth modified by attaching a hydrophilic chemical to the surface of the hydrophobic fibers constituting the cloth. However, in medical treatments made of such hydrophobic fibers, the heat of production can be efficiently dissipated. However, when the skin and clothing are wetted by sweating, the dough is easily attached to the skin and the discomfort is felt. There was a problem that is difficult to win.

On the other hand, when the said sensation medicine consists of the letter of such a reversible structure, the ratio of the number of loops which consists of a fiber which is excellent in contact cooling feeling is within a predetermined range, and it gives a cool feeling and a refreshing feeling at the time of sweating, It is possible to prevent adhesion of the dough to the skin due to the discomfort caused by the dampness and deterioration of the detachment from the skin. Moreover, by arranging the loop which consists of the fiber which is excellent in contact cooling feeling only on the skin side, the fiber which is excellent in contact cooling feeling and skin contact directly, and it can be set as the medical which was excellent in a refreshing feeling and a feeling of cold contact.

In the said sensation medicine, the minimum with preferable ratio of the loop which consists of a fiber excellent in contact cooling feeling is 30% of a total loop number, and a preferable upper limit is 70%. If it is less than 30%, the effect of causing a refreshing feeling and cold feeling of contact may be insufficient. If it exceeds 70%, the sweat is hard to move because it feels unpleasant due to moistness, and the dough is easily attached to the skin. You may lose. The minimum with more preferable is 33% and a more preferable upper limit is 67%.

When the skin side of the sensation medicine is composed of only loops made of fibers having excellent contact cooling feeling, the lower limit of the ratio of loops made of fibers having excellent contact cooling feeling is 50% of the total number of loops, and the upper limit is preferably 70%. When the skin side is composed of fibers having excellent contact cooling feeling and hydrophobic fibers, the lower limit of the ratio of the loops made of fibers having excellent contact cooling feeling is 30%, and the upper limit thereof is preferably 50%.

Moreover, in the said sensation medicine, it is preferable that the fiber which is excellent in the said contact cooling feeling has a q _max value of 0.07 J / m <2> / scc or more.

It is preferable that the said sensation medicine contains the said thermoplastic elastomer and an inorganic filler.

In this case, among the fibers containing the thermoplastic elastomer, polyamide-based elastomer A in which hard segment is polyamide 12 and soft segment is polyethylene glycol, and polyamide in which hard segment is polyamide 12 and soft segment is polytetramethylene glycol. The fiber containing the mixed resin with Elastomer B is preferable in that it gives very excellent contact cooling feeling and is also excellent in moisture absorption and moisture absorption characteristics and diffusion characteristics. In addition, as the fiber containing the thermoplastic elastomer, a content of Pebox 1014SA01 (manufactured by Atpina Japan), which is a polyetherblockamide copolymer, is 60% by weight or more, porous, and the surface is subjected to a hydrophilization treatment. The fiber etc. which added 1-5 weight% of inorganic substances, such as a titanium oxide, to synthetic fiber, such as a fiber and polyester and nylon, and improved contact cooling property are preferable.

In the said sensation medicine, the fiber excellent in the said contact cooling feeling may use together another fiber suitably when it is going to make thickness of a dough as thin as possible. In this case, the minimum with preferable content of the said thermoplastic elastomer in the fiber excellent in the said contact cooling feeling is 50 weight%. If it is less than 50 weight%, sufficient contact cooling feeling may not be exhibited.

In the said sensation medicine, it is preferable that the loop which consists of a fiber excellent in the said cold feeling is arrange | positioned only at the skin side. In this arrangement, when the sensitizing medicine is worn, a loop composed mainly of fibers having excellent contact cooling sensation can come into contact with the skin, causing a cold feeling of cooling or a refreshing feeling, and a loop made of hydrophobic fibers described below is disposed outside. As a result, it is possible to improve the diffusibility and the transpiration of heat and water emitted from the skin.

In the said sensation medicine, it is preferable that loops other than the loop of the fiber excellent in the said contact cooling feeling are a loop which consists of hydrophobic fiber.

In the sensation medicine, as described above, the loop made of the hydrophobic fiber is mainly arranged on the outside in that the loop made of the fiber having excellent contact cooling feeling is disposed only on the skin side. Thereby, transpiration of sweat can be accelerated | stimulated and it can efficiently dissipate fever.

In the present specification, the hydrophobic fiber refers to chemical fiber having a process moisture content of 5.0% or less, and specifically, for example, polypropylene (process moisture content: 0%), polyester (0.4%), acrylic resin (2.0%) And fibers made of nylon (4.5%), vinylon (5.0%) and the like. These may be used alone or in combination of two or more. In addition, a process moisture content means the moisture content in 20 degreeC and 65% RH.

The said sensation medicine may contain the fiber which is excellent in contact cooling feeling, fibers other than hydrophobic fiber, for example, natural fiber which consists of cotton, hemp, etc., semisynthetic fiber, such as rayon and acetate, as needed.

1 schematically shows an example of the sensation medicine. 1 (a) is a plan view when the said sensation medicine is seen from the skin side, and FIG. 1 (b) is sectional drawing when the outer side is upper and the skin side is lower.

As shown in FIG. 1, the sensation medicine 11 is knitted by the fiber which was comprised from the part 12 knitted by the fiber which was excellent in contact cooling feeling, and the part 13 knitted by the hydrophobic fiber, and was excellent in contact cooling feeling. The part 12 has become a shape which has a rectangular part mutually different linearly. In addition, the part knitted by the fiber excellent in contact cooling feeling means the part which has a loop which consists of a fiber excellent in contact cooling feeling, and the part knitted by hydrophobic fiber does not have a loop which consists of a fiber excellent in contact cooling feeling, and is hydrophobic Refers to a part having only a loop made of fibers.

Moreover, the part 12 knitted by the fiber which was excellent in contact cooling feeling is arrange | positioned only in the skin side (lower side), and when the said sensation medicine is worn, the part 12 which was knitted mainly by the fiber excellent in contact cooling feeling. It is a structure like contact with this skin.

FIG. 2: is another example of the said sensation medicine, FIG. 2 (a) is a top view when it sees from the skin side, and FIG.

As shown in FIG. 2, the sensation medicine 21 is comprised from the part 22 knitted with the fiber excellent in contact cooling feeling, and the part 23 knitted with the hydrophobic fiber. Moreover, the part 22 knitted by the fiber which was excellent in contact cooling feeling is arrange | positioned only in the skin side (lower side), and when the said sensation medicine is worn, the part 22 which was knitted mainly by the fiber which was excellent in contact cooling feeling. It is a structure like contact with this skin.

3 is a schematic diagram showing the flow of heat and water vapor emitted from the skin when the sensation medicine is worn.

As shown in FIG. 3, heat and water vapor emitted from the skin first pass through the portion 12 knitted by the fiber having excellent contact cooling feeling, and are absorbed and absorbed by the fiber having excellent contact cooling feeling at this time. Then, the heat and moisture not absorbed and absorbed by the fiber having excellent contact cooling feeling are diffused by passing through the portion 13 knitted by the hydrophobic fiber, and then radiated and evaporated to the outside. In addition, in FIG. 3, although only the part which has both the part knitted by the fiber excellent in contact cooling feeling and the part knitted by the hydrophobic fiber was shown, in the part which consists only of the part knitted by hydrophobic fiber, Heat and water vapor diffuse and then radiate and transpire to the outside.

In said sensation medicine, since the ratio of the part which has both the part knitted by the fiber excellent in contact cooling feeling and the part knitted by the hydrophobic fiber becomes a suitable range, it gives a cool feeling and a refreshing feeling at the time of wearing, It is possible to prevent adhesion of the dough to the skin due to the discomfort caused by the sweating and the deterioration of detachment from the skin.

In the said sensation medicine, the minimum with preferable air permeability is 200 cm <3> / cm <2> / sec, and a preferable upper limit is 500 cm <3> / cm <2> / sec. If it is less than 200 cm 3 / cm 2 / sec, the air permeability is poor, and heat dissipation and sweat evaporation from the skin may be inhibited, and if it exceeds 500 cm 3 / cm 2 / sec, the heat or moisture is sufficiently transferred through medical treatment. There is a case where it is not carried out and, on the contrary, enters the outside air.

In addition, the said air permeability can be measured in accordance with the method based on JISL1096A method using a plastic-type air permeability tester.

In the said sensation medicine, the minimum with preferable weight per unit area is 90 g / m <2>, and a preferable upper limit is 200 g / m <2>. If it is less than 90 g / m 2, heat and moisture do not move easily, and the sensation effect may be lowered. If it exceeds 200 g / m 2, the sensibility may decrease with an increase in weight or heat transfer resistance.

The letter of the reversible structure can be produced by adjusting the amount of knitting when knitting a loop using a piece knitting machine or the like. Specifically, it can manufacture by the method of knitting as 30 to 70% of the number of the knitting needles which can knit the loop which consists of a fiber excellent in contact cooling feeling.

It does not specifically limit as a method of manufacturing the medical which was excellent in the cold feeling of contact of this invention, For example, conventionally well-known methods, such as a method of manufacturing a medical | medical art, by making it knit using the fiber excellent in the cold contact feeling of this invention. Can be used.

Moreover, the said sensation medicine can be manufactured by using the conventionally well-known method of sewing, cutting, etc. using the letter of the reversible structure obtained as mentioned above, for example.

The underwear excellent in contact cooling feeling can be manufactured using the fiber excellent in contact cooling feeling of this invention, or the dough excellent in contact cooling feeling of this invention. Moreover, the medical which was excellent in the cold feeling of contact of this invention can be used as underwear.

The underwear excellent in the cold feeling of contact obtained in this way is also one of this invention.

The underwear having excellent contact cooling feeling of the present invention can produce a cool feeling at the time of wearing in that it contains a thermoplastic elastomer, and can give a refreshing feeling. Moreover, by containing an inorganic filler, there is no sticking at the time of moisture, and it is excellent also in a touch and a texture. Underwear excellent in the cold feeling of contact of the present invention has a particularly excellent effect in direct contact with the skin.

By using the fiber excellent in the contact cooling feeling of this invention or the dough excellent in the contact cooling feeling of this invention, stockings, gloves, a face mask, a muffler etc. can be manufactured besides the underwear excellent in the contact cooling feeling of this invention. They have a particularly good effect in direct contact with the skin.

Effects of the Invention

According to the present invention, it is possible to prevent unpleasant feeling when wet, and furthermore, to provide dough, medical and underwear having excellent contact cooling feeling, which is made of a fiber having excellent contact cooling feeling with excellent texture and feel, and a fiber having excellent contact cooling feeling. can do.

Carrying out the invention  Best form for

Although an Example is given to the following and this invention is demonstrated in more detail, this invention is not limited only to these Examples.

[ Example ]

* (Example 1)

2 weight% of titanium oxide (made by Sakai Chemical Co., Ltd., "D918", average particle diameter 0.26 micrometer) with respect to 98 weight% of polyether blockamide copolymers which are thermoplastic polyamide-type elastomers (made by Arkema, "Pebox 1041SA01") After addition, melt mixing was performed and resin pellets were prepared using a pelletizer.

Next, using the obtained resin pellets, weaving was carried out by melt spinning to obtain a yarn.

Knit was performed using the obtained yarn to prepare dough.

(Example 2)

The addition amount of the polyetherblockamide copolymer (made by Arkema, "Pebox 1041SA01) was 96 weight%, and the addition amount of the titanium oxide (made by Sakai Chemical Co., Ltd.," D918 ", average particle diameter 0.26 micrometer) was 4 weight%. A dough was produced in the same manner as in Example 1 except for the above.

(Example 3)

94 wt% of the polyetherblockamide copolymer (Archema Co., Ltd., "Pebox 1041 SA0") and 6 wt% of the titanium oxide (Skai Chemical Co., Ltd., "D918", average particle diameter 0.26㎛) Dough was produced in the same manner as in Example 1 except for the one.

(Example 4)

Titanium oxide ("D918", Sakai Chemical Co., Ltd. product, "D918", average particle diameter 0.26 micrometer) with respect to 98 weight% of polyether ester copolymers which are thermoplastic polyester elastomers (made by Toray Dupont, "Hytrirel 8171") 2 After the weight% was added, melt pelletization was carried out using a pelletizer to prepare a resin pellet.

Next, using the obtained resin pellets, weaving was carried out by melt spinning to obtain a yarn.

Knit was performed using the obtained yarn to prepare dough.

(Example 5)

Regarding the polyetherblockamide copolymer (manufactured by Arkema, "Pebox 1041SA01") that is a thermoplastic polyamide-based elastomer, barium sulfate (manufactured by Sakai Chemical Co., Ltd., "B-30NC", average particle diameter of 0.3 µm) 2 After the weight% was added, melt pelletization was carried out using a pelletizer to prepare a resin pellet.

Next, using the obtained resin pellets, weaving was carried out by melt spinning to obtain a yarn. Knit was performed using the obtained yarn to prepare dough.

(Example 6)

To 98% by weight of a polyetherblockamide copolymer (manufactured by Arkema Co., Ltd., "Pebox 1041SA01") which is a thermoplastic polyamide elastomer, zinc oxide (manufactured by Long Chemical Co., Ltd. ) 2% by weight was added, followed by melt mixing using a pelletizer to prepare a resin pellet.

Next, using the obtained resin pellets, weaving was carried out by melt spinning to obtain a yarn. Knit was performed using the obtained yarn to prepare dough.

(Example 7)

To 98% by weight of a polyetherblockamide copolymer (Archema Co., Ltd., "Pebox 1041SA01") which is a thermoplastic polyamide-based elastomer, silica particles (Tekyama Co., Ltd. product, "Equerica SH-03", average particle diameter of 0.2 µm) ) 2% by weight was added, followed by melt mixing to prepare resin pellets using a pelletizer.

Next, using the obtained resin pellets, weaving was carried out by melt spinning to obtain a yarn. Knit was performed using the obtained yarn to prepare dough.

(Example 8)

To 70% by weight of a polyetherblockamide copolymer (Archema Co., Ltd., "Pebox 1041SA01") that is a thermoplastic polyamide elastomer, 30% by weight of ferrite powder (average particle diameter 0.88 µm) is added, followed by melt mixing. Resin pellets were prepared using a pelletizer.

Next, using the obtained resin pellets, weaving was carried out by melt spinning to obtain a yarn.

Knit was performed using the obtained yarn to prepare dough.

(Comparative Example 1)

The yarn was obtained by melt spinning using the pellet of the polyether block amide copolymer (Archema Co., Ltd. make, "Pebox 1041SA01") which is a thermoplastic polyamide-type elastomer, and obtained the yarn. Knit was performed using the obtained yarn to prepare dough.

(evaluation)

About the dough obtained in Examples 1-8 and Comparative Example 1, it evaluated by the following method. The results are shown in Table 1.

(1) measurement of wet slip start angle

The slip start angle according to the tilting method was measured by a method based on JIS P 8147. Specifically, the ascending speed of the slide was 2 ° / sec and the weight was 93.37 g. The tilt angle was measured by tilting the slide to determine the additional movement of the wet specimen.

(2) Measurement of wet slip resistance

The slip start angle according to the tilting method was measured by a method based on JIS P 8147. Specifically, the rising speed of the slide was 2 ° / sec, the weight was 93.37 g, and the static frictional resistance value at the instant when the weight to which the wet test piece was attached began to move by tilting the slide was measured.

(3) Measurement of q _max value

Each dough was placed on a sample table set at a temperature of 20.5 ° C., and immediately after the low heat plate warmed to a temperature of 32.5 ° C. was overlapped with a contact pressure of 0.098 N / cm 2 on the dough, the accumulated heat amount was lower than the sample on the low temperature side. The peak value of the amount of heat moving to was measured. Samorabo type II rapid rapid thermal measurement apparatus (manufactured by Katotech Co., Ltd.) was used for the measurement.

(4) measurement of thermal conductivity

Each dough was placed on a sample table set at a temperature of 20.5 ° C, the hot plate was superimposed on the dough at a contact pressure of 0.059 N / cm 2, and the temperature of the hot plate was adjusted to a temperature of 32.5 ° C. to stabilize. The heat loss rate when the temperature of the hot plate was stabilized to a predetermined temperature was measured using a Samorabo II type rapid rapid thermal property measuring apparatus (manufactured by Katotech Co., Ltd.), and the thermal conductivity was measured from this value.

(5) Radioactive

The number of breaks of the filaments in the extrusion step, the stretching step, and the heat set step when the resin pellets used in the examples and the comparative examples were continuously melt spun for 24 hours was counted, and the evaluation was made according to the following criteria.

◎: Number of broken filaments is 0

(Circle): The number of times a filament breaks is 1-3 times

△: Filament breaks more than 4 times

(6) sensory test

Ten subjects were subjected to the sensory test for the feeling of contact coldness at the time of contacting each dough and the detachment from the skin of the dough when the dough was slipped on the skin, and evaluated according to the following criteria. In the case of ◎, 3 points, ○ were 2 points, △ was 1 point, × was 0, and the total of 10 persons was obtained, which was used as the evaluation point.

(Double-circle): It is cold, and desorption property from the skin of dough is good also at the time of drying and wet.

(Circle): It is cold, but desorption from the skin of dough is common at the time of drying, wet

(Triangle | delta): Although it is cold, the detachment | desorption property from the skin of the dough at the time of wet is bad.

X: cold, but desorption from skin is bad

As shown in Table 1, the dough using the yarn containing the thermoplastic elastomer and inorganic filler produced in Examples 1 to 8 is excellent in contact cooling feeling in terms of high q _max value and thermal conductivity, and furthermore, wet slip resistance. When the value was not too high, it was found that, when used as a medical, desorption property from the skin at the time of moistening was good.

On the other hand, the dough using the yarn manufactured in Comparative Example 1 has excellent contact cooling feeling in terms of high q _max value and thermal conductivity, but wet skin when used as a medical treatment in that wet slip resistance value is too high. It was found that the detachment from the deteriorated.

(Example 9)

85 weight% of nylon 12 ("UBESTA 3014U", product made by Ube Heungsan Co., Ltd.) which is a polyamide resin as core part resin, and 5 weight% of titanium oxide ("D918", manufactured by Sakai Chemical Co., Ltd., average particle diameter 0.26 mu m) were used as resin for second part. 15 weight% of the containing polyetherblockamide copolymer ("Pebox 1041SA01" by Arkema Co., Ltd.) was put into a composite spinning device, and the yam was composited by melt spinning to obtain a deep sheath-type composite yarn having a diameter of 50 µm.

Moreover, it was 2 micrometers when the cross section of the obtained deep vinegar composite yarn was image | photographed using the electron microscope, and the thickness of a sheath part was measured.

Kneading was carried out using the obtained myocardial composite yarn.

(Example 10)

65 weight% of nylon 12 ("UBESTA 3014U", product made by Ube Heungsan Co., Ltd.) which is a polyamide resin as core part resin, and 5 weight% of titanium oxide ("D918", Sakai Chemical Co., Ltd. make, average particle diameter 0.26 micrometer) are 5 weight% as a resin for super parts. 35 weight% of the containing polyetherblockamide copolymer ("Pebox 1041SA01" by Arkema Co., Ltd.) was put into the composite spinning device, and the yam was composited by melt spinning to obtain a vinegar composite yarn having a diameter of 50 µm. Moreover, it was 5 micrometers when the cross section of the obtained myocardial composite yarn was image | photographed using the electron microscope, and the thickness of a sheath part was measured. Kneading was carried out using the obtained myocardial composite yarn.

(Example 11)

50% by weight of nylon 12 (`` UBESTA 3014U '', manufactured by Ube Heungsan Co., Ltd.), which is a polyamide resin, and 5% by weight of titanium oxide (`` D918 '', manufactured by Sakai Chemical Co., Ltd., average particle diameter 0.26 µm) were used as the core resin. 50 weight% of the containing polyetherblockamide copolymer ("Box 1041SA01", manufactured by Arkema Co., Ltd.) was charged into a composite spinning device, and the yam was manufactured by melt spinning to obtain a deep sheath-type composite yarn having a diameter of 50 µm.

Moreover, it was 7 micrometers when the cross section of the obtained cardiac composite yarn was image | photographed using the electron microscope, and the thickness of a sheath part was measured.

Kneading was carried out using the obtained myocardial composite yarn.

(Example 12)

35 weight% of nylon 12 ("UBESTA 3014U", product made by Ube Heungsan Co., Ltd.) which is a polyamide resin as core part resin, and 5 weight% of titanium oxide ("D918", manufactured by Sakai Chemical Co., Ltd., average particle diameter 0.26 mu m) were used as resin for second part. 65 weight% of the containing polyetherblockamide copolymer ("Pebox 1041SA01" by Arkema Co., Ltd.) was put into the composite spinning apparatus, and the spinning was carried out by melt spinning to obtain a core sheath composite yarn having a diameter of 50 µm.

Moreover, it was 10 micrometers when the cross section of the obtained myocardial composite yarn was image | photographed using the electron microscope, and the thickness of a sheath part was measured.

Kneading was carried out using the obtained myocardial composite yarn.

(Example 13)

5% by weight of polyamide resin nylon 12 (`` UBESTA 3014U '', manufactured by Ube Heungsan Co., Ltd.) as the core part resin, and 5% by weight of titanium oxide (`` D918 '', manufactured by Sakai Chemical Co., Ltd., average particle diameter 0.26 µm) as the base part resin 95 weight% of the containing polyetherblockamide copolymer ("Pebox 1041SA01" by Arkema Co., Ltd.) was put into the composite spinning apparatus, and the spinning was carried out by melt spinning to obtain a core sheath composite yarn having a diameter of 50 µm.

Moreover, it was 20 micrometers when the cross section of the obtained myocardial composite yarn was image | photographed using the electron microscope, and the thickness of a sheath part was measured.

Kneading was carried out using the obtained myocardial composite yarn.

Hereinafter, in order to make it clear that the vinegar-type composite yarn obtained in Examples 9-13 has predetermined | prescribed vinegar structure, and obtains the dough excellent in dyeing property, it is a fiber which is excellent in the contact cooling feeling of this invention, but does not have a predetermined vinegar structure. It shows as a test example about the dough which uses a fiber.

(Experimental Example 1)

The preparation was carried out by melt spinning using a polyetherblockamide copolymer (Archema Co., Ltd., "Pebox 1041 SA0") containing 5% by weight of titanium oxide (`` D918 '', manufactured by Sakai Chemical Co., Ltd., with an average particle diameter of 0.26 µm). It carried out and obtained the yarn.

* Kneading was obtained using the obtained yarn.

(Experimental Example 2)

3% by weight of nylon 12 (`` UBESTA 3014U '', manufactured by Ube Heungsan Co., Ltd.), which is a polyamide resin, and 5% by weight of titanium oxide (`` D918 '', manufactured by Sakai Chemical Co., Ltd., average particle diameter 0.26 µm) as the core resin 97 wt% of the polyetherblockamide copolymer ("Pebox 1041SA01", manufactured by Arkema Co., Ltd.) was added to the composite spinning apparatus, and the spinning was carried out by melt spinning to obtain a core sheath-type composite yarn having a diameter of 60 µm.

* Moreover, the cross section of the obtained myocardial composite yarn was image | photographed using the electron microscope, and the thickness of the sheath part was measured, and it was 25 micrometers.

Kneading was carried out using the obtained myocardial composite yarn.

(evaluation)

The dough obtained in Examples 9-13 and Experimental Examples 1 and 2 was dyed using an acid dye (Nylosan, manufactured by Clariant Japan), and evaluated by the following method. The results are shown in Table 2.

(1) dyeability

About the dough after staining, the sharpness was compared by visual evaluation by five subjects. The results were comprehensively evaluated and evaluated in four stages as follows.

(Double-circle): Sharpness and uniformity are very good.

○: The sharpness is good.

(Triangle | delta): It is inferior to sharpness.

X: The sharpness is bad.

(2) Measurement of q _max value

Each dough is placed on a sample table set at a temperature of 20.5 ° C., and immediately after the low heat plate warmed to a temperature of 32.5 ° C. is overlapped with a contact pressure of 0.098 N / cm 2 on the dough, the accumulated heat is transferred to the sample on the low temperature side. The peak value of calories was measured. Samorabo type II rapid rapid thermal measurement apparatus (manufactured by Katotech Co., Ltd.) was used for the measurement.

(3) measurement of thermal conductivity

Each dough was placed on a sample table set at a temperature of 20.5 ° C, the hot plate was superimposed on the dough at a contact pressure of 0.059 N / cm 2, and the temperature of the hot plate was adjusted to a temperature of 32.5 ° C. to stabilize. The heat loss rate when the temperature of the hot plate was stabilized at a predetermined temperature was measured using a Samorabo II type rapid rapid thermal property measuring apparatus (manufactured by Catotech Co., Ltd.), and the thermal conductivity was measured from this value.

(Example 14)

A polyetherblockamide copolymer (manufactured by Atpina Japan, "Pebox 1041SA01"), which is a thermoplastic polyamide elastomer, and titanium oxide ("D918", manufactured by Sakai Chemical, Inc., having an average particle diameter of 0.26 µm) as inorganic fillers A fiber having excellent contact cooling feeling is disposed only on the skin side, and a polyester fiber (Asahi Kasei Co., Ltd., Technofine), which is a hydrophobic fiber, is mainly disposed on the outside and is reversible according to the structure diagram 1 shown in FIG. Letter was used to make a T-shirt.

In the obtained T-shirt, the number of loops made of fibers excellent in contact cooling feeling was 50% of the total number of loops, and the number of loops made of hydrophobic fibers was 50% of the total number of loops. Moreover, the ratio of the loop which consists of hydrophobic fiber was 100% in the outer side of the T-shirt, and the ratio of the loop which consists of fiber which was excellent in contact cooling feeling was 100% in the skin side.

In addition, the weight per unit area of the obtained T-shirt was 184g / m <2>.

Moreover, it was 326 cm <3> / cm <2> / sec as a result of measuring the air permeability of the obtained T-shirt in accordance with the method based on JISL1096A method using a plastic-type air permeability test machine (TEXTILE AIR PERMEABILITY TESTER made from Yamaguchi Corporation).

(Example 15)

Polyetherblockamide copolymers (manufactured by Atpina Japan, "Pebox 1041SA01"), which are thermoplastic polyamide elastomers, and titanium oxide ("D918", manufactured by Sakai Chemical, Inc., having an average particle diameter of 0.26 µm) as inorganic fillers The structure figure 2 shown in FIG. 5 by the fleece knitting machine is used for the fiber excellent in the contact cooling feeling which consists of a fiber which comprises the loop of a skin side, and polyester fiber (made by Asahi Kasei Co., Ltd., Technopine) as a fiber which comprises an outer loop. According to the letter of the reversible structure was knitted, using this to produce a T-shirt.

In the obtained T-shirt, the number of loops made of fibers excellent in contact cooling feeling was 33.3% of the total number of loops, and the number of loops made of hydrophobic fibers was 66.7% of the total number of loops. Moreover, the ratio of the loop which consists of hydrophobic fiber was 100% in the outer side of the T-shirt, and the ratio of the loop which consists of fiber which was excellent in contact cooling feeling was 50%, and the ratio of the loop which consists of hydrophobic fiber was 50%. In addition, the weight per unit area of the obtained T-shirt was 152g / m <2>.

Moreover, it was 397.6 cm <3> / cm <2> / sec when the air permeability of the obtained T-shirt was measured by the method similar to Example 14.

(Comparative Example 2)

The T-shirt (Mizuno Co., Ltd.) which was warped in the mesh shape by the hydrophilized polyester fiber (Kuraray Co., Sopista) was used for the commercially available surface.

(Comparative Example 3)

T-shirts knitted with cotton on the market were used.

(evaluation)

The T-shirts obtained in Examples 14 and 15 and Comparative Examples 2 and 3 were evaluated by the following method.

(1) Evaluation in artificial meteorological chamber

Assuming the early morning walking in the summer, and in the artificial meteorological room at a temperature of 28 ° C. × 65% RH, wearing the T-shirts obtained in Example 14 and Comparative Examples 2 and 3, after 15 minutes in a stable sitting position, After 30 minutes of walking with a treadmill while facing the wind of 1 m / sec, the temperature change in the clothes, the humidity change in the clothes, and the oxygen intake were measured when restoring postural stability sitting on the chair for 30 minutes. This result is shown in FIG.

In addition, the measurement was performed about six healthy adult males and the average value was shown. In FIG. 6, when the T-shirt manufactured in Example 14 was worn, it turned out that the rise of the temperature and humidity in a garment is suppressed compared with the case of wearing the T-shirt manufactured in Comparative Examples 2 and 3. FIG. Moreover, when wearing the T-shirt manufactured in Example 14, the oxygen intake during walking was also suppressed low compared with the case of wearing the T-shirt manufactured in Comparative Examples 2 and 3. This is because the T-shirt manufactured in Example 14 provides a comfortable in-clothing environment compared to the T-shirts manufactured in Comparative Examples 2 and 3, and therefore, the exercise load is reduced and the exercise can be performed with low energy consumption. do.

(2) sensory evaluation 1

In the family walking (hosted by the Kyoto Prefecture Walking Association) held in Kyoto City in July 2004, after walking with wearing the T-shirts obtained in Example 14 and Comparative Example 2, the T-shirts are usually worn. Sensory evaluation was carried out in response to the questionnaire. This result was shown in FIG. In addition, sensory evaluation was performed about nine adult males, and the average value was shown.

Moreover, rectal temperature and the temperature in clothes were measured about two of the people who performed the sensory evaluation. The result is shown in FIG.

In FIG. 7, the T-shirt manufactured in Example 14 is highly evaluated in comparison with the T-shirt normally worn in all items, and it can be seen that it is particularly mobile and excellent in touch. On the other hand, in the T-shirt manufactured in Comparative Example 2, poor evaluation was made in terms of sweat absorption, detachment from the skin at the time of sweating, and the like. In addition, when the T-shirt manufactured in Example 14 was worn, both the workplace temperature and the temperature in the garment showed lower values than when the T-shirt manufactured in Comparative Example 2 was worn.

(3) sensory evaluation 2

In November 2004, a male college student enrolled in the athletic department wears the T-shirts manufactured in Example 15 and Comparative Example 2 and runs, and then responds to the questionnaire based on the T-shirts she wears. Evaluated. This result is shown in FIG. In addition, sensory evaluation was performed about 29 people and the average value was shown.

In FIG. 8, the T-shirts manufactured in Example 15 obtained the highest scores in all 13 items, and 11 items were significantly higher than the T-shirts manufactured in Comparative Example 2. In particular, evaluation of the T-shirt manufactured in Example 15 was high in items such as stickiness, mobility, dough treatment, weight, touch and comfort.

According to the present invention, it is possible to provide a dough, medical and underwear having excellent contact cooling feeling, which is made of a fiber excellent in contact cooling feeling with excellent texture and feel, and a fiber excellent in contact cooling feeling. Can be.

11, 21: Yangyang Medical
12, 22: part knitted by the fiber excellent in contact cooling feeling
13, 23: portion knitted by hydrophobic fibers

Claims (7)

As a medical with excellent cool feeling composed of a reversible letter,
It has a loop which consists of a fiber excellent in contact cooling feeling containing a thermoplastic elastomer and an inorganic filler, and a loop which consists of hydrophobic fiber, and 30-70% of the total number of loops is a loop which consists of a fiber excellent in contact cooling feeling,
The loop made of the fiber having excellent contact cooling feeling is disposed only on the skin side,
In addition, the loop made of the hydrophobic fibers is disposed on the outside, when the medical wear is excellent in the cool feeling, the loop made of fibers having excellent contact cooling feeling is in contact with the skin, characterized in that the excellent cold feeling of medical care . The method of claim 1,
Thermoplastic elastomers are polyamide-based elastomers, polyester-based elastomers, or polyamide-based elastomers and polyester-based elastomers. 3. The method of claim 2,
Thermoplastic elastomer is a polyether block amide copolymer, characterized in that the excellent contact cooling feeling medical. The method of claim 1,
The inorganic filler is 0.20-3.00 micrometers in average particle diameter, The medical which was excellent in contact cooling feeling. The method of claim 1,
The fiber excellent in contact cooling feeling contains 50 weight% or more of thermoplastic elastomer, The medical excellent in contact cooling feeling characterized by the above-mentioned. The method of claim 1,
The fiber excellent in contact cooling feeling contains 2-30 weight% of inorganic fillers, The medical excellent in contact cooling feeling characterized by the above-mentioned. The underwear excellent in the cold feeling of contact is comprised using the medical which was excellent in the cold feeling of contact of Claim 1.

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