KR101345317B1 - 향상된 기질 중합체로 이루어진 필름을 함유하는 spd 광밸브와 그러한 기질 중합체의 제조 방법 - Google Patents
향상된 기질 중합체로 이루어진 필름을 함유하는 spd 광밸브와 그러한 기질 중합체의 제조 방법 Download PDFInfo
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- KR101345317B1 KR101345317B1 KR1020087020502A KR20087020502A KR101345317B1 KR 101345317 B1 KR101345317 B1 KR 101345317B1 KR 1020087020502 A KR1020087020502 A KR 1020087020502A KR 20087020502 A KR20087020502 A KR 20087020502A KR 101345317 B1 KR101345317 B1 KR 101345317B1
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- 229920000642 polymer Polymers 0.000 title claims abstract description 130
- 239000011159 matrix material Substances 0.000 title claims abstract description 59
- 238000000034 method Methods 0.000 title claims description 31
- 239000000178 monomer Substances 0.000 claims abstract description 93
- 239000000758 substrate Substances 0.000 claims abstract description 89
- 239000002245 particle Substances 0.000 claims abstract description 46
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 32
- 239000000725 suspension Substances 0.000 claims abstract description 31
- 239000007788 liquid Substances 0.000 claims abstract description 27
- 229920001577 copolymer Polymers 0.000 claims abstract description 26
- 239000010703 silicon Substances 0.000 claims abstract description 23
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- 125000000524 functional group Chemical group 0.000 claims description 6
- 150000007513 acids Chemical class 0.000 claims description 4
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- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- 238000010894 electron beam technology Methods 0.000 claims description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- 229920000307 polymer substrate Polymers 0.000 claims 7
- 239000006194 liquid suspension Substances 0.000 abstract description 25
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 34
- 238000006243 chemical reaction Methods 0.000 description 29
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 27
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- MCDBEBOBROAQSH-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propyl prop-2-enoate Chemical compound CO[Si](C)(OC)CCCOC(=O)C=C MCDBEBOBROAQSH-UHFFFAOYSA-N 0.000 description 19
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical compound [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 18
- 238000004821 distillation Methods 0.000 description 18
- 229920000139 polyethylene terephthalate Polymers 0.000 description 18
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- 238000006460 hydrolysis reaction Methods 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- 230000007062 hydrolysis Effects 0.000 description 12
- WHGNXNCOTZPEEK-UHFFFAOYSA-N dimethoxy-methyl-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical group CO[Si](C)(OC)CCCOCC1CO1 WHGNXNCOTZPEEK-UHFFFAOYSA-N 0.000 description 11
- POPACFLNWGUDSR-UHFFFAOYSA-N methoxy(trimethyl)silane Chemical compound CO[Si](C)(C)C POPACFLNWGUDSR-UHFFFAOYSA-N 0.000 description 11
- 238000003756 stirring Methods 0.000 description 11
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- 239000003381 stabilizer Substances 0.000 description 8
- BOZRCGLDOHDZBP-UHFFFAOYSA-N 2-ethylhexanoic acid;tin Chemical compound [Sn].CCCCC(CC)C(O)=O BOZRCGLDOHDZBP-UHFFFAOYSA-N 0.000 description 7
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- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 6
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- 101000911390 Homo sapiens Coagulation factor VIII Proteins 0.000 description 4
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- 238000000576 coating method Methods 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- PKTOVQRKCNPVKY-UHFFFAOYSA-N dimethoxy(methyl)silicon Chemical compound CO[Si](C)OC PKTOVQRKCNPVKY-UHFFFAOYSA-N 0.000 description 4
- 230000005684 electric field Effects 0.000 description 4
- 229940117955 isoamyl acetate Drugs 0.000 description 4
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- KCIKCCHXZMLVDE-UHFFFAOYSA-N silanediol Chemical compound O[SiH2]O KCIKCCHXZMLVDE-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000005160 1H NMR spectroscopy Methods 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- 210000002421 cell wall Anatomy 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 230000032798 delamination Effects 0.000 description 3
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- 239000002243 precursor Substances 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- PMBXCGGQNSVESQ-UHFFFAOYSA-N 1-Hexanethiol Chemical compound CCCCCCS PMBXCGGQNSVESQ-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 2
- 229910002808 Si–O–Si Inorganic materials 0.000 description 2
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- 230000005540 biological transmission Effects 0.000 description 2
- DLAWWWHBMVKBLT-UHFFFAOYSA-N dihydroxy-methyl-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound C[Si](O)(O)CCCOCC1CO1 DLAWWWHBMVKBLT-UHFFFAOYSA-N 0.000 description 2
- 125000001891 dimethoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 2
- 239000012799 electrically-conductive coating Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
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- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
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- 238000010907 mechanical stirring Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- RIOVTDYYGZVCSA-UHFFFAOYSA-N 3-[dihydroxy(methyl)silyl]propyl prop-2-enoate Chemical compound C[Si](O)(O)CCCOC(=O)C=C RIOVTDYYGZVCSA-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 1
- 230000005653 Brownian motion process Effects 0.000 description 1
- UNMYWSMUMWPJLR-UHFFFAOYSA-L Calcium iodide Chemical compound [Ca+2].[I-].[I-] UNMYWSMUMWPJLR-UHFFFAOYSA-L 0.000 description 1
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- 206010037660 Pyrexia Diseases 0.000 description 1
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- 238000000149 argon plasma sintering Methods 0.000 description 1
- LFYJSSARVMHQJB-QIXNEVBVSA-N bakuchiol Chemical compound CC(C)=CCC[C@@](C)(C=C)\C=C\C1=CC=C(O)C=C1 LFYJSSARVMHQJB-QIXNEVBVSA-N 0.000 description 1
- 238000005537 brownian motion Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- SLFDDMXEAUAENU-UHFFFAOYSA-N dimethyl 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluorooctanedioate Chemical compound COC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(=O)OC SLFDDMXEAUAENU-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
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- 230000002706 hydrostatic effect Effects 0.000 description 1
- HVKDCVWOBDEWMI-UHFFFAOYSA-N hydroxy(methoxy)silane Chemical compound CO[SiH2]O HVKDCVWOBDEWMI-UHFFFAOYSA-N 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
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- 150000002632 lipids Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- GVEVNOSZLMMBOR-UHFFFAOYSA-N pyrazine-2,5-dicarboxylic acid;dihydrate Chemical compound O.O.OC(=O)C1=CN=C(C(O)=O)C=N1 GVEVNOSZLMMBOR-UHFFFAOYSA-N 0.000 description 1
- 238000012113 quantitative test Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- FJFYFBRNDHRTHL-UHFFFAOYSA-N tris(8-methylnonyl) benzene-1,2,4-tricarboxylate Chemical group CC(C)CCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC(C)C)C(C(=O)OCCCCCCCC(C)C)=C1 FJFYFBRNDHRTHL-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 210000000635 valve cell Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B26/00—Optical devices or arrangements for the control of light using movable or deformable optical elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/06—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/17—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on variable-absorption elements not provided for in groups G02F1/015 - G02F1/169
- G02F1/172—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on variable-absorption elements not provided for in groups G02F1/015 - G02F1/169 based on a suspension of orientable dipolar particles, e.g. suspended particles displays
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- General Chemical & Material Sciences (AREA)
- Silicon Polymers (AREA)
- Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US77506206P | 2006-02-21 | 2006-02-21 | |
| US60/775,062 | 2006-02-21 | ||
| US11/559,537 US7791788B2 (en) | 2006-02-21 | 2006-11-14 | SPD light valves incorporating films comprising improved matrix polymers and methods for making such matrix polymers |
| US11/559,537 | 2006-11-14 | ||
| PCT/US2006/045574 WO2007097796A2 (en) | 2006-02-21 | 2006-11-29 | Spd light valves incorporating films comprising improved matrix polymers and methods for making such matrix polymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20080106195A KR20080106195A (ko) | 2008-12-04 |
| KR101345317B1 true KR101345317B1 (ko) | 2013-12-27 |
Family
ID=38438677
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020087020502A Active KR101345317B1 (ko) | 2006-02-21 | 2006-11-29 | 향상된 기질 중합체로 이루어진 필름을 함유하는 spd 광밸브와 그러한 기질 중합체의 제조 방법 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7791788B2 (enExample) |
| EP (1) | EP2005236B1 (enExample) |
| JP (1) | JP5346591B2 (enExample) |
| KR (1) | KR101345317B1 (enExample) |
| CN (1) | CN101517451B (enExample) |
| AU (1) | AU2006338614B2 (enExample) |
| BR (1) | BRPI0621348B1 (enExample) |
| CA (1) | CA2640630C (enExample) |
| WO (1) | WO2007097796A2 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2008331875C1 (en) * | 2007-12-06 | 2015-08-20 | Research Frontiers Incorporated | SPD films and light valves incorporating overcoatings |
| JP2009179677A (ja) * | 2008-01-30 | 2009-08-13 | Mitsubishi Chemicals Corp | 硬化性ポリシロキサン化合物、及びその製造方法、並びに、それを用いたポリシロキサン硬化物、光学部材、半導体発光装置、導光板、及び航空宇宙産業用部材 |
| US20090241424A1 (en) * | 2008-06-06 | 2009-10-01 | Msa Aircraft Products Ltd. | Modular Window For An Aircraft Including An SPD Lens And An Opaque Shade |
| US9539883B2 (en) | 2010-04-23 | 2017-01-10 | Magna Mirrors Of America, Inc. | Window with shade |
| WO2011133830A1 (en) | 2010-04-23 | 2011-10-27 | Magna Mirrors Of America, Inc. | Vehicle window with shade |
| CN104885001B (zh) * | 2012-02-10 | 2017-03-08 | 尖端研究公司 | 具有较暗的关态透光率和较亮的开态透光率的spd膜 |
| US10831071B2 (en) | 2017-05-04 | 2020-11-10 | Zhejiang Jingyi New Material Technology Co., Ltd | Copper-reduced graphene oxide core-shell transparent conductor for controlling light transmission and method of making the same |
| US11015028B2 (en) * | 2018-07-13 | 2021-05-25 | Zhejiang Jingyi New Material Technology Co., Ltd | Plastic articles containing suspended photochromic dye molecules |
| US20200031999A1 (en) * | 2018-07-27 | 2020-01-30 | 1-Material Inc. | Hybrid Organic-inorganic Polymeric Matrix in Light Valve Devices and Method for Making the Same |
| US12130535B2 (en) | 2019-07-02 | 2024-10-29 | Gauzy Ltd. | Suspended particle devices with improved adhesion between the active and conducting layers |
| KR102151969B1 (ko) | 2019-12-11 | 2020-09-04 | 주식회사 지투비 | 투과도 가변창의 제조방법 및 그에 의해 제조된 투과도 가변창 |
| KR20230009907A (ko) * | 2020-05-07 | 2023-01-17 | 다우 실리콘즈 코포레이션 | (메트)아크릴레이트 작용성 실리콘 및 이의 제조 및 사용 방법 |
| CN114114779B (zh) * | 2021-11-29 | 2025-10-21 | 浙江精一新材料科技有限公司 | 一种光阀及提高光阀抗压性能的方法 |
| KR20240170574A (ko) * | 2022-04-14 | 2024-12-03 | 저지앙 징이 뉴 머티리얼 테크놀로지 컴퍼니 리미티드 | 광 밸브 및 변색 유리 |
| CN116854914A (zh) * | 2023-04-11 | 2023-10-10 | 江苏集萃智能液晶科技有限公司 | 有机硅树脂、应用其的spd调光器件及制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6301040B1 (en) | 2000-05-24 | 2001-10-09 | Research Frontiers Incorporated | SPD films having improved properties and light valves comprising same |
| US20040257634A1 (en) | 2003-06-18 | 2004-12-23 | Research Frontiers Incorporated | Siloxane matrix polymers and SPD light valve films incorporating same |
| US20050090574A1 (en) | 2001-12-18 | 2005-04-28 | Osamu Mitani | Photocurable organic polymer composition |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5463492A (en) * | 1991-11-01 | 1995-10-31 | Research Frontiers Incorporated | Light modulating film of improved clarity for a light valve |
| US6839158B2 (en) * | 1997-08-28 | 2005-01-04 | E Ink Corporation | Encapsulated electrophoretic displays having a monolayer of capsules and materials and methods for making the same |
| US7256766B2 (en) * | 1998-08-27 | 2007-08-14 | E Ink Corporation | Electrophoretic display comprising optical biasing element |
| US5973044A (en) * | 1998-08-28 | 1999-10-26 | Dow Corning Corporation | Adhesion promoting organosilicon compositions |
| US6416827B1 (en) * | 2000-10-27 | 2002-07-09 | Research Frontiers Incorporated | SPD films and light valves comprising same |
| JP4524458B2 (ja) * | 2002-05-31 | 2010-08-18 | エルシコン・インコーポレーテッド | 光学配向層調製用分岐ハイブリッドポリマー材料 |
| KR101138672B1 (ko) * | 2003-12-19 | 2012-04-24 | 닛산 가가쿠 고교 가부시키 가이샤 | 저굴절률 및 큰 수접촉각을 갖는 피막 |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6301040B1 (en) | 2000-05-24 | 2001-10-09 | Research Frontiers Incorporated | SPD films having improved properties and light valves comprising same |
| US20050090574A1 (en) | 2001-12-18 | 2005-04-28 | Osamu Mitani | Photocurable organic polymer composition |
| US20040257634A1 (en) | 2003-06-18 | 2004-12-23 | Research Frontiers Incorporated | Siloxane matrix polymers and SPD light valve films incorporating same |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007097796A3 (en) | 2009-05-07 |
| CA2640630A1 (en) | 2007-08-30 |
| AU2006338614B2 (en) | 2011-09-22 |
| JP2009527621A (ja) | 2009-07-30 |
| EP2005236A4 (en) | 2009-12-23 |
| US7791788B2 (en) | 2010-09-07 |
| JP5346591B2 (ja) | 2013-11-20 |
| KR20080106195A (ko) | 2008-12-04 |
| WO2007097796A2 (en) | 2007-08-30 |
| AU2006338614A1 (en) | 2007-08-30 |
| EP2005236A2 (en) | 2008-12-24 |
| BRPI0621348B1 (pt) | 2018-04-03 |
| CN101517451B (zh) | 2011-12-21 |
| EP2005236B1 (en) | 2018-02-07 |
| US20070195401A1 (en) | 2007-08-23 |
| CA2640630C (en) | 2013-10-01 |
| BRPI0621348A2 (pt) | 2011-12-06 |
| CN101517451A (zh) | 2009-08-26 |
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