CA2640630C - Spd light valves incorporating films comprising improved matrix polymers and methods for making such matrix polymers - Google Patents
Spd light valves incorporating films comprising improved matrix polymers and methods for making such matrix polymers Download PDFInfo
- Publication number
- CA2640630C CA2640630C CA2640630A CA2640630A CA2640630C CA 2640630 C CA2640630 C CA 2640630C CA 2640630 A CA2640630 A CA 2640630A CA 2640630 A CA2640630 A CA 2640630A CA 2640630 C CA2640630 C CA 2640630C
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- Prior art keywords
- polymer
- cross
- film
- matrix
- monomer
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- 229920000642 polymer Polymers 0.000 title claims abstract description 133
- 239000011159 matrix material Substances 0.000 title claims abstract description 125
- 238000000034 method Methods 0.000 title claims abstract description 39
- 239000000178 monomer Substances 0.000 claims abstract description 96
- 239000007788 liquid Substances 0.000 claims abstract description 44
- 239000002245 particle Substances 0.000 claims abstract description 43
- 239000000758 substrate Substances 0.000 claims abstract description 34
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 32
- 239000000725 suspension Substances 0.000 claims abstract description 31
- 229920001577 copolymer Polymers 0.000 claims abstract description 25
- 239000010703 silicon Substances 0.000 claims abstract description 23
- 238000004132 cross linking Methods 0.000 claims abstract description 19
- 229920006037 cross link polymer Polymers 0.000 claims abstract description 7
- 239000000839 emulsion Substances 0.000 claims description 39
- 239000003054 catalyst Substances 0.000 claims description 13
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 13
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 13
- 125000003545 alkoxy group Chemical group 0.000 claims description 9
- 230000005855 radiation Effects 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 8
- 239000002253 acid Chemical group 0.000 claims description 6
- 230000003301 hydrolyzing effect Effects 0.000 claims description 4
- 239000004593 Epoxy Chemical group 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- 238000010894 electron beam technology Methods 0.000 claims description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 34
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 27
- 238000006243 chemical reaction Methods 0.000 description 27
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 24
- MCDBEBOBROAQSH-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propyl prop-2-enoate Chemical compound CO[Si](C)(OC)CCCOC(=O)C=C MCDBEBOBROAQSH-UHFFFAOYSA-N 0.000 description 19
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical compound [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 18
- 229920000139 polyethylene terephthalate Polymers 0.000 description 17
- 239000005020 polyethylene terephthalate Substances 0.000 description 17
- 230000007062 hydrolysis Effects 0.000 description 14
- 238000006460 hydrolysis reaction Methods 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 238000002390 rotary evaporation Methods 0.000 description 13
- 238000000526 short-path distillation Methods 0.000 description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- WHGNXNCOTZPEEK-UHFFFAOYSA-N dimethoxy-methyl-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](C)(OC)CCCOCC1CO1 WHGNXNCOTZPEEK-UHFFFAOYSA-N 0.000 description 11
- 239000000203 mixture Substances 0.000 description 10
- 238000006116 polymerization reaction Methods 0.000 description 10
- 239000011541 reaction mixture Substances 0.000 description 10
- 238000010992 reflux Methods 0.000 description 10
- 238000006482 condensation reaction Methods 0.000 description 9
- POPACFLNWGUDSR-UHFFFAOYSA-N methoxy(trimethyl)silane Chemical compound CO[Si](C)(C)C POPACFLNWGUDSR-UHFFFAOYSA-N 0.000 description 9
- 239000003381 stabilizer Substances 0.000 description 9
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 description 8
- 239000006194 liquid suspension Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- 238000000576 coating method Methods 0.000 description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- 239000002985 plastic film Substances 0.000 description 7
- -1 polyethylene terephthalate Polymers 0.000 description 7
- 239000013049 sediment Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000013019 agitation Methods 0.000 description 6
- 239000004305 biphenyl Substances 0.000 description 6
- 235000010290 biphenyl Nutrition 0.000 description 6
- 125000006267 biphenyl group Chemical group 0.000 description 6
- 210000004027 cell Anatomy 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 6
- 238000009833 condensation Methods 0.000 description 6
- 230000005494 condensation Effects 0.000 description 6
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 6
- GKOZKEKDBJADSV-UHFFFAOYSA-N disilanol Chemical compound O[SiH2][SiH3] GKOZKEKDBJADSV-UHFFFAOYSA-N 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 238000012544 monitoring process Methods 0.000 description 6
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 125000005372 silanol group Chemical group 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000000020 Nitrocellulose Substances 0.000 description 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000012141 concentrate Substances 0.000 description 5
- 230000007812 deficiency Effects 0.000 description 5
- 229920001220 nitrocellulos Polymers 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 229920006255 plastic film Polymers 0.000 description 5
- 229910000077 silane Inorganic materials 0.000 description 5
- KCIKCCHXZMLVDE-UHFFFAOYSA-N silanediol Chemical compound O[SiH2]O KCIKCCHXZMLVDE-UHFFFAOYSA-N 0.000 description 5
- 239000006228 supernatant Substances 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- SHZIWNPUGXLXDT-UHFFFAOYSA-N caproic acid ethyl ester Natural products CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- YQGOWXYZDLJBFL-UHFFFAOYSA-N dimethoxysilane Chemical class CO[SiH2]OC YQGOWXYZDLJBFL-UHFFFAOYSA-N 0.000 description 4
- 230000005684 electric field Effects 0.000 description 4
- 229940117955 isoamyl acetate Drugs 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- BOZRCGLDOHDZBP-UHFFFAOYSA-N 2-ethylhexanoic acid;tin Chemical compound [Sn].CCCCC(CC)C(O)=O BOZRCGLDOHDZBP-UHFFFAOYSA-N 0.000 description 3
- 101150041968 CDC13 gene Proteins 0.000 description 3
- 102100026735 Coagulation factor VIII Human genes 0.000 description 3
- 101000911390 Homo sapiens Coagulation factor VIII Proteins 0.000 description 3
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 3
- HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 210000002421 cell wall Anatomy 0.000 description 3
- 230000032798 delamination Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 230000006353 environmental stress Effects 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 239000011369 resultant mixture Substances 0.000 description 3
- 230000002194 synthesizing effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- PMBXCGGQNSVESQ-UHFFFAOYSA-N 1-Hexanethiol Chemical compound CCCCCCS PMBXCGGQNSVESQ-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UNMYWSMUMWPJLR-UHFFFAOYSA-L Calcium iodide Chemical compound [Ca+2].[I-].[I-] UNMYWSMUMWPJLR-UHFFFAOYSA-L 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 125000001891 dimethoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- 238000003760 magnetic stirring Methods 0.000 description 2
- 238000012643 polycondensation polymerization Methods 0.000 description 2
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 2
- 238000000527 sonication Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- QYCPVKMFWNBDPV-UHFFFAOYSA-N 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluorooctanedioic acid Chemical compound OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(O)=O QYCPVKMFWNBDPV-UHFFFAOYSA-N 0.000 description 1
- RIOVTDYYGZVCSA-UHFFFAOYSA-N 3-[dihydroxy(methyl)silyl]propyl prop-2-enoate Chemical compound C[Si](O)(O)CCCOC(=O)C=C RIOVTDYYGZVCSA-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229940042776 anhydrous calcium iodide Drugs 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 229910001640 calcium iodide Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- DLAWWWHBMVKBLT-UHFFFAOYSA-N dihydroxy-methyl-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound C[Si](O)(O)CCCOCC1CO1 DLAWWWHBMVKBLT-UHFFFAOYSA-N 0.000 description 1
- PKTOVQRKCNPVKY-UHFFFAOYSA-N dimethoxy(methyl)silicon Chemical compound CO[Si](C)OC PKTOVQRKCNPVKY-UHFFFAOYSA-N 0.000 description 1
- 239000012799 electrically-conductive coating Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- NYMPGSQKHIOWIO-UHFFFAOYSA-N hydroxy(diphenyl)silicon Chemical compound C=1C=CC=CC=1[Si](O)C1=CC=CC=C1 NYMPGSQKHIOWIO-UHFFFAOYSA-N 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- GVEVNOSZLMMBOR-UHFFFAOYSA-N pyrazine-2,5-dicarboxylic acid;dihydrate Chemical compound O.O.OC(=O)C1=CN=C(C(O)=O)C=N1 GVEVNOSZLMMBOR-UHFFFAOYSA-N 0.000 description 1
- 238000012113 quantitative test Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
- FJFYFBRNDHRTHL-UHFFFAOYSA-N tris(8-methylnonyl) benzene-1,2,4-tricarboxylate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC(C)C)C(C(=O)OCCCCCCCC(C)C)=C1 FJFYFBRNDHRTHL-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 210000000635 valve cell Anatomy 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B26/00—Optical devices or arrangements for the control of light using movable or deformable optical elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/06—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/17—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on variable-absorption elements not provided for in groups G02F1/015 - G02F1/169
- G02F1/172—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on variable-absorption elements not provided for in groups G02F1/015 - G02F1/169 based on a suspension of orientable dipolar particles, e.g. suspended particles displays
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- General Chemical & Material Sciences (AREA)
- Silicon Polymers (AREA)
- Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US77506206P | 2006-02-21 | 2006-02-21 | |
| US60/775,062 | 2006-02-21 | ||
| US11/559,537 US7791788B2 (en) | 2006-02-21 | 2006-11-14 | SPD light valves incorporating films comprising improved matrix polymers and methods for making such matrix polymers |
| US11/559,537 | 2006-11-14 | ||
| PCT/US2006/045574 WO2007097796A2 (en) | 2006-02-21 | 2006-11-29 | Spd light valves incorporating films comprising improved matrix polymers and methods for making such matrix polymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2640630A1 CA2640630A1 (en) | 2007-08-30 |
| CA2640630C true CA2640630C (en) | 2013-10-01 |
Family
ID=38438677
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2640630A Active CA2640630C (en) | 2006-02-21 | 2006-11-29 | Spd light valves incorporating films comprising improved matrix polymers and methods for making such matrix polymers |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7791788B2 (enExample) |
| EP (1) | EP2005236B1 (enExample) |
| JP (1) | JP5346591B2 (enExample) |
| KR (1) | KR101345317B1 (enExample) |
| CN (1) | CN101517451B (enExample) |
| AU (1) | AU2006338614B2 (enExample) |
| BR (1) | BRPI0621348B1 (enExample) |
| CA (1) | CA2640630C (enExample) |
| WO (1) | WO2007097796A2 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2008331875C1 (en) * | 2007-12-06 | 2015-08-20 | Research Frontiers Incorporated | SPD films and light valves incorporating overcoatings |
| JP2009179677A (ja) * | 2008-01-30 | 2009-08-13 | Mitsubishi Chemicals Corp | 硬化性ポリシロキサン化合物、及びその製造方法、並びに、それを用いたポリシロキサン硬化物、光学部材、半導体発光装置、導光板、及び航空宇宙産業用部材 |
| US20090241424A1 (en) * | 2008-06-06 | 2009-10-01 | Msa Aircraft Products Ltd. | Modular Window For An Aircraft Including An SPD Lens And An Opaque Shade |
| US9539883B2 (en) | 2010-04-23 | 2017-01-10 | Magna Mirrors Of America, Inc. | Window with shade |
| WO2011133830A1 (en) | 2010-04-23 | 2011-10-27 | Magna Mirrors Of America, Inc. | Vehicle window with shade |
| CN104885001B (zh) * | 2012-02-10 | 2017-03-08 | 尖端研究公司 | 具有较暗的关态透光率和较亮的开态透光率的spd膜 |
| US10831071B2 (en) | 2017-05-04 | 2020-11-10 | Zhejiang Jingyi New Material Technology Co., Ltd | Copper-reduced graphene oxide core-shell transparent conductor for controlling light transmission and method of making the same |
| US11015028B2 (en) * | 2018-07-13 | 2021-05-25 | Zhejiang Jingyi New Material Technology Co., Ltd | Plastic articles containing suspended photochromic dye molecules |
| US20200031999A1 (en) * | 2018-07-27 | 2020-01-30 | 1-Material Inc. | Hybrid Organic-inorganic Polymeric Matrix in Light Valve Devices and Method for Making the Same |
| US12130535B2 (en) | 2019-07-02 | 2024-10-29 | Gauzy Ltd. | Suspended particle devices with improved adhesion between the active and conducting layers |
| KR102151969B1 (ko) | 2019-12-11 | 2020-09-04 | 주식회사 지투비 | 투과도 가변창의 제조방법 및 그에 의해 제조된 투과도 가변창 |
| KR20230009907A (ko) * | 2020-05-07 | 2023-01-17 | 다우 실리콘즈 코포레이션 | (메트)아크릴레이트 작용성 실리콘 및 이의 제조 및 사용 방법 |
| CN114114779B (zh) * | 2021-11-29 | 2025-10-21 | 浙江精一新材料科技有限公司 | 一种光阀及提高光阀抗压性能的方法 |
| KR20240170574A (ko) * | 2022-04-14 | 2024-12-03 | 저지앙 징이 뉴 머티리얼 테크놀로지 컴퍼니 리미티드 | 광 밸브 및 변색 유리 |
| CN116854914A (zh) * | 2023-04-11 | 2023-10-10 | 江苏集萃智能液晶科技有限公司 | 有机硅树脂、应用其的spd调光器件及制备方法 |
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|---|---|---|---|---|
| US5463492A (en) * | 1991-11-01 | 1995-10-31 | Research Frontiers Incorporated | Light modulating film of improved clarity for a light valve |
| US6839158B2 (en) * | 1997-08-28 | 2005-01-04 | E Ink Corporation | Encapsulated electrophoretic displays having a monolayer of capsules and materials and methods for making the same |
| US7256766B2 (en) * | 1998-08-27 | 2007-08-14 | E Ink Corporation | Electrophoretic display comprising optical biasing element |
| US5973044A (en) * | 1998-08-28 | 1999-10-26 | Dow Corning Corporation | Adhesion promoting organosilicon compositions |
| US6301040B1 (en) * | 2000-05-24 | 2001-10-09 | Research Frontiers Incorporated | SPD films having improved properties and light valves comprising same |
| US6416827B1 (en) * | 2000-10-27 | 2002-07-09 | Research Frontiers Incorporated | SPD films and light valves comprising same |
| EP1456251B1 (en) | 2001-12-18 | 2006-08-09 | Dow Corning Toray Silicone Company, Ltd. | Photocurable organic polymer composition |
| JP4524458B2 (ja) * | 2002-05-31 | 2010-08-18 | エルシコン・インコーポレーテッド | 光学配向層調製用分岐ハイブリッドポリマー材料 |
| US6900923B2 (en) | 2003-06-18 | 2005-05-31 | Research Frontiers Incorporated | Siloxane matrix polymers and SPD light valve films incorporating same |
| KR101138672B1 (ko) * | 2003-12-19 | 2012-04-24 | 닛산 가가쿠 고교 가부시키 가이샤 | 저굴절률 및 큰 수접촉각을 갖는 피막 |
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| CA2640630A1 (en) | 2007-08-30 |
| AU2006338614B2 (en) | 2011-09-22 |
| JP2009527621A (ja) | 2009-07-30 |
| EP2005236A4 (en) | 2009-12-23 |
| US7791788B2 (en) | 2010-09-07 |
| JP5346591B2 (ja) | 2013-11-20 |
| KR20080106195A (ko) | 2008-12-04 |
| WO2007097796A2 (en) | 2007-08-30 |
| AU2006338614A1 (en) | 2007-08-30 |
| EP2005236A2 (en) | 2008-12-24 |
| BRPI0621348B1 (pt) | 2018-04-03 |
| CN101517451B (zh) | 2011-12-21 |
| EP2005236B1 (en) | 2018-02-07 |
| US20070195401A1 (en) | 2007-08-23 |
| BRPI0621348A2 (pt) | 2011-12-06 |
| KR101345317B1 (ko) | 2013-12-27 |
| CN101517451A (zh) | 2009-08-26 |
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