KR101246213B1 - Method for predicting dissolved oxygen quantity in vacuum degassing process - Google Patents

Abstract

The present invention relates to a method for predicting dissolved oxygen in a vacuum degassing process that can accurately predict the dissolved oxygen amount before deoxidation in order to improve the cleanliness of molten steel in a vacuum degassing process. Calculating a reduced carbon amount reduced by the decarburization reaction by subtracting the threshold carbon value calculated from the estimated carbon amount, and multiplying the reduced carbon amount by the oxygen coefficient participating in the decarburization reaction to reduce the oxygen content to be reduced during decarburization. Comprising a step of calculating the amount of oxygen increase to increase due to TOB to the reduced oxygen amount to calculate the change oxygen, and subtracting the change oxygen amount from the measured initial oxygen amount to predict the amount of oxygen before deoxidation.

Description

METHODS FOR PREDICTING DISSOLVED OXYGEN QUANTITY IN VACUUM DEGASSING PROCESS}

The present invention relates to a method for predicting dissolved oxygen in a vacuum degassing process that can accurately predict the amount of dissolved oxygen before deoxidation in order to improve cleanliness of molten steel in a vacuum degassing process.

Molten steel is manufactured through a first refining process to remove impurities in the molten iron by sequentially performing delineation, decarburization, and deoxidation in molten iron in the form of iron ore. After the impurities are removed, the molten steel is moved to the continuous casting process after the secondary refining process is completed to control the fine components in the molten steel.

After that, the semi-finished product is formed through a continuous casting process, and the final product is manufactured into a product to be finally obtained through a final molding process such as rolling.

An object of the present invention is to accurately predict the amount of oxygen before deoxidation in a vacuum degassing process, so that the amount of coolant, TOB, and deoxidizer (aluminum) can be adjusted appropriately so that the cleanliness of molten steel can be improved. It is to provide a method for predicting dissolved oxygen amount in.

The technical problems to be achieved by the present invention are not limited to the technical problems mentioned above.

In the dissolved oxygen amount prediction method of the present invention for realizing the above object, the amount of carbon reduced by decarburization is calculated by calculating an expected carbon amount at the time of temperature measurement of molten steel and subtracting the threshold carbon value set to the calculated estimated carbon amount. Calculating; Calculating a reduced oxygen amount to be reduced during decarburization by multiplying the reduced carbon amount by an oxygen coefficient participating in the reaction during decarburization; Calculating a change oxygen amount by adding an increase oxygen amount to increase due to TOB to the decrease oxygen amount; And subtracting the changed oxygen amount from the measured initial oxygen amount to predict the amount of oxygen before deoxidation.

Specifically, the estimated carbon amount is obtained by calculating the temperature measurement time and a predetermined relational constant and then multiplying the measured initial carbon amount, and the relational constant is the actual carbon amount and the initial carbon amount based on the operation performance at the temperature measurement. It may be a value derived by correlation between the two.

The threshold carbon value may be set to a value between 10 and 20 as the amount of carbon reduced by the decarburization reaction.

The oxygen coefficient is a reaction ratio of oxygen to carbon reduced by the decarburization reaction, and may be set to a value between 0.5 and 0.6.

The increase oxygen amount is obtained by multiplying the increase coefficient of oxygen increased in the molten steel when blowing gas gas and the amount of TOB blown, the increase coefficient may be set to 2.

As described above, according to the present invention, by predicting the amount of oxygen contained in the molten steel before the deoxidation process, the amount of coolant or TOB and the amount of deoxidizer (aluminum) added in the vacuum degassing process can be properly adjusted, thereby improving the cleanliness of the molten steel. There is an advantage to obtain a way to manufacture ultra-low carbon steel.

1 is a view showing a vacuum degassing apparatus to which the present invention is applied.
2 is a view showing the dissolved oxygen amount prediction apparatus according to an embodiment of the present invention.
3 is a flowchart illustrating a process of predicting dissolved oxygen in a vacuum degassing process according to an embodiment of the present invention.

Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. Like elements in the figures are denoted by the same reference numerals wherever possible. In the following description, well-known functions or constructions are not described in detail since they would obscure the invention in unnecessary detail.

1 is a view showing a vacuum degassing apparatus to which the present invention is applied, and includes a vacuum chamber 10 and a ladle 50.

In general, in order to manufacture ultra low carbon steel having a carbon content of 70 ppm or less, the molten steel M is refined using a vacuum degassing facility (hereinafter, also referred to as 'RH') as shown in FIG. 1.

In the RH refining, when the molten steel (M), which is stepped out of the converter (not shown) and reaches the vacuum chamber 10, is first blown with argon gas (Ar gas) from a predetermined reflux gas supplier (not shown). While immersing the immersion pipe (11, 15) in the molten steel (M) received in the ladle 50, at the same time by operating the vacuum pump 20 to decompress the interior of the vacuum chamber 10 to several to several tens of Torr (Torr) Let's do it. At this time, the molten steel (M) in the ladle 50 is further raised to the interior of the vacuum chamber 10 by the pressure difference between the atmosphere and the interior of the vacuum chamber 10, the molten steel (M) in the reaction The decarburization reaction proceeds. As the decarburization reaction proceeds, the carbon content in the molten steel (M) decreases.

Scheme 1

C + O = CO (gas) ↑

In addition, in order to improve the reactivity, the stirring force should be increased so that the circulation of the molten steel M between the ladle 50 and the vacuum chamber 10 is faster. Circulation of the molten steel (M) is carried out through the ascending pipe 11 and the down pipe 15 arranged annularly in the lower portion of the vacuum chamber 10, the inert gas (Ar) as a reflux gas is blown up ( 11) The direction of the arrow (8) due to the difference in specific gravity from the molten steel (M) of the downcomer 15 having a relatively high specific gravity by lowering the specific gravity of the molten steel (M) by embedding gas bubbles in the molten steel (M) inside. The molten steel M is configured to circulate.

In the case of refining molten steel M using the vacuum chamber 10 shown in FIG. 1, it takes more than 15 minutes to reduce the carbon content to 70 ppm or less in the vacuum chamber 10 and the molten steel temperature during decarburization of the molten steel. It lowers more than 1.5 degreeC per minute, and the temperature of molten steel falls.

Meanwhile, in order to shorten the decarburization time of the ultra low carbon steel, a gas oxygen blowing lance 30 is installed on the ceiling of the vacuum chamber 10 and the inside of the vacuum chamber 10 through the lance 30 during decarburization of the molten steel M. Gas oxygen is sprayed at high speed on the molten steel (M).

In such a steelmaking process, the production process of ultra low carbon steel is produced by decarburizing molten steel (M) which has not been deoxidized from the converter in a vacuum degassing facility (RH). Although the entire process from pretreatment to secondary refining is an important process for improving cleanliness, the operating parameters of RH process, which is the last process of secondary refining, have a great influence on the cleanliness control of molten steel (M). When producing ultra-low carbon steel, the work in RH shows that the decarburization molten steel (M) is refluxed in the vacuum chamber 10 to reduce carbon in the molten steel (M), and the addition of aluminum (Al) to oxygen The deoxidation process to reduce the and a separation process for floating separation of the resulting alumina inclusions (Al ₂ O ₃ ).

At this time, if the amount of dissolved oxygen before deoxidation is not accurately predicted, the temperature after deoxidation is excessive or insufficient, and thus temperature adjustment of molten steel M is additionally performed. Adding coolant or Top of Blowing (TOB) for further temperature adjustment makes the molten steel M extremely inferior. Therefore, in order to improve the cleanliness of the molten steel (M), a method for accurately predicting the amount of dissolved oxygen before deoxidation is needed.

In the present invention will be described a method for refining ultra-low carbon steel that can accurately predict the amount of oxygen before deoxidation to improve the cleanliness of molten steel (M).

2 is a view showing a dissolved oxygen amount prediction apparatus in a vacuum degassing apparatus according to an embodiment of the present invention, the oxygen prediction apparatus 100 is a temperature measuring means 110, oxygen measuring means 120, memory 130, The input unit 140, the display unit 150, and the controller 160 are configured to be included.

Temperature measuring means 110 is immersed in the molten steel (M) of the ladle 50 to measure the temperature of the molten steel (M). Here, the temperature measuring means 110 may be a thermocouple and a temperature sensor.

Oxygen measuring means 120 is immersed in the molten steel (M) of the ladle 50 is composed of a probe for measuring the amount of oxygen in the molten steel (M). Here, the principle of the acidic measurement can determine the amount of oxygen in the molten steel (M) by measuring the amount of current flowing through the probe in the molten steel (M). The temperature measurement and the measurement may be performed at about 3 minutes after the start of the vacuum of the RH.

The memory 130 includes setting values for various parameters such as the initial carbon amount in the molten steel M and the relational constants (A, B), the oxygen coefficient (Co), the increase coefficient (Cio), etc. The prediction algorithm is stored.

The input unit 140 receives various setting values from the outside and stores them in the memory 130. The input unit 140 may be configured as a keyboard or a GUI screen.

The display unit 150 displays the measured temperature, initial oxygen amount, and dissolved oxygen amount before deoxidation of the molten steel M in a text or graph form under the control of the controller 160.

The control unit 160 calculates the change oxygen amount by calculating the decrease oxygen amount to decrease during the decarburization process of molten steel M at the time of temperature measurement, and then add the increase oxygen amount to be increased by the TOB, and calculate the calculated change oxygen amount. Subtract from the initial oxygen amount to calculate and predict the amount of oxygen before deoxidation.

That is, when calculating the reduced oxygen amount, the control unit 160 calculates the estimated carbon amount at the time of temperature measurement of the molten steel M, and then subtracts the threshold carbon value preset in the memory 130 to the calculated carbon amount to decarburize the reaction. The amount of reduced carbon reduced by is calculated and the amount of reduced oxygen to be reduced during decarburization is calculated by multiplying the calculated reduced carbon amount by the oxygen coefficient participating in the reaction during decarburization.

The controller 160 calculates the change oxygen amount by adding the increase oxygen amount to be increased due to TOB to the decrease oxygen amount, and predicts the oxygen amount before deoxidation by subtracting the calculated change oxygen amount from the initial oxygen amount.

Specifically, the expected carbon amount may be calculated by Equation 1 below. In Equation 1, the initial carbon amount may be a carbon amount calculated by analyzing molten carbon components after sampling molten steel during the RH refining process or RH refining.

Equation 1

Here, the measurement time point is the elapsed time [min] from the start of the vacuum to the measurement time point, A and B are constants derived by the correlation between the actual carbon amount and the initial carbon amount based on the operation performance at the temperature measurement, The initial carbon amount is the amount of carbon in molten steel [ppm] during RH refining.

In the above, the temperature measurement time point may be approximately 3 minutes after the vacuum is started. At this point the amount of carbon will be slightly lower than the amount of carbon before vacuum is applied, as some decarburization has occurred for three minutes. That is, the amount of carbon at the time of temperature measurement will vary depending on the time point (at a few minutes) at temperature measured at the amount of carbon before vacuum is applied. For example, the later the temperature is measured after the vacuum is started, the more carbon will be reduced in the molten steel.

In addition, the constant A calculated at the time of temperature measurement may be set to a number smaller than B. The constant A may be set to a value of 0.1 to 0.2, and B may be set to a value of 1 to 2. Preferably the constant A may be 0.15 and the constant B may be 1.3.

The threshold carbon value may be set to a value between 10 and 20 as the amount of carbon reduced by the decarburization reaction. Subtracting the marginal carbon amount from the expected carbon amount means the amount of carbon reduced by the decarburization reaction during the decarburization reaction. That is, it can be said that the amount of carbon reduced during the decarburization reaction. In general, no matter how long the decarburization time is increased, it is difficult to theoretically reach a carbon value below the threshold carbon value, and thus it can be set to a value between 10 and 20 as a finally reached limit carbon value. The marginal carbon value may preferably be 10.

The oxygen coefficient multiplied by the reduced carbon amount when calculating the reduced oxygen amount may be set to a value between 0.5 and 0.6 as a reaction ratio of oxygen to carbon reduced by the decarburization reaction.

In addition, when calculating the increased oxygen amount due to TOB, the increased oxygen amount is obtained by multiplying the amount of TOB blown and the increase coefficient of oxygen increased in molten steel when blowing gas gas. Here, the increase coefficient may be set to two. When oxygen is supplied to molten steel, oxygen is supplied to molten steel using a top lance. At this time, if the oxygen of molten steel is to be increased, theoretically, gaseous oxygen of 22.4 Nm ³ may be blown. That is, 100 ppm of oxygen in molten steel is equivalent to 32 kg of oxygen on the basis of 320 tons of molten steel, and 32 kg of oxygen (O ₂ ) is equivalent to 1000 moles, which is 22.4 Nm ³ . However, analysis of the actual operation results, in order to increase the oxygen in the molten steel was found to 100ppm as the oxygen gas in ³ 22.4Nm be blown into the gaseous oxygen of 50Nm ^3. Due to this, the increase factor was set to '2' (100 ppm / 50 Nm ³ ), which means that 2 ppm of oxygen increases when gaseous oxygen 1 Nm ³ is injected.

As shown in Equation 2 below, the overall equation for the prediction of oxygen amount (Op) before deoxidation is represented.

Equation 2

Here, the initial oxygen amount is the acid value at the time of temperature measurement, the initial carbon amount is the amount of carbon in molten steel [ppm] during RH refining, Co is the oxygen coefficient, and Cio is the increase coefficient.

3 is a flowchart illustrating a process of predicting dissolved oxygen according to an embodiment of the present invention, with reference to the accompanying drawings.

First, in the memory 130 of the oxygen predicting apparatus 100, various types of initial carbon in molten steel, relation coefficients (A, B), oxygen coefficients (Co), increase coefficients (Cio), and the like, for predicting the amount of oxygen before deoxidation are obtained. The parameter is stored (S11). The initial carbon amount is a value obtained by analyzing molten steel during the RH refining process or the RH refining process, which can be determined by analyzing a component analyzer after collecting a portion of the molten steel by immersing the sampler in the molten steel.

Subsequently, the controller 160 stores the molten steel temperature and the initial oxygen amount measured by the temperature measuring means 110 and the oxygen measuring means 120 at a time point at which a predetermined time elapses after the RH vacuum (hereinafter, referred to as a temperature measurement time point). Each is stored in the 130 (S12). Here, the temperature measurement time point may be approximately 3 minutes after the vacuum is started.

The control unit 160 calculates the temperature measurement time [min] and the preset relation constants (A, B) at the time of temperature measurement, and then multiplies the initial carbon amount stored in the memory 130 at the temperature measurement time. Calculate the expected carbon amount (S13). The constant A multiplied by the temperature measurement time is a negative value between -0.1 and -0.2, and the constant B added by the temperature measurement time may be set to a value between 1 and 2 as a positive number. Preferably the constant A may be -0.15 and the constant B may be 1.3. The constant A multiplied by the temperature measurement time becomes negative since the amount of carbon in the molten steel will be further reduced as the temperature measurement time is delayed.

After obtaining the estimated carbon amount, the controller 160 calculates the reduced carbon amount reduced by the decarburization reaction by subtracting the threshold carbon value preset in the memory 130 to the calculated estimated carbon amount (S14). The threshold carbon value may be set to a value between 10 and 20 as the amount of carbon reduced by the decarburization reaction. That is, subtracting the marginal carbon amount from the expected carbon amount means the amount of carbon reduced by the decarburization reaction during the decarburization reaction. That is, it can be said that the amount of carbon reduced during the decarburization reaction. In general, no matter how long the decarburization time is increased, it is difficult to theoretically reach a carbon value below the threshold carbon value, and thus it can be set to a value between 10 and 20 as a finally reached limit carbon value. The marginal carbon value may preferably be 10.

Subsequently, the controller 160 calculates the reduced oxygen amount to be reduced during decarburization by multiplying the calculated reduced carbon amount by the oxygen coefficient Co participating in the reaction during decarburization (S15). The oxygen coefficient Co is a reaction ratio of oxygen to carbon reduced by the decarburization reaction, and may be set to a value between 0.5 and 0.6. The stoichiometric ratio of carbon and oxygen participating in the decarburization reaction is 1: 1.33 depending on the atomic weight of carbon and oxygen, but it can be seen that the reaction occurs at a ratio of 1: 0.55 according to the analysis of the actual operation results. This can be seen as a result of the oxygen participating in the decarburization reaction participates in not only dissolved oxygen but also oxygen present in slag and refractory materials. Eventually, the decreasing amount of oxygen during decarburization is obtained by multiplying the decreasing amount of carbon during decarburization by the oxygen coefficient Co, for example, 0.55.

The controller 160 calculates the change oxygen amount by adding the increase oxygen amount to increase due to the TOB to the decrease oxygen amount (S16). Here, the increased oxygen amount is obtained by multiplying the increase coefficient (Cio) of oxygen that is increased in molten steel upon blowing of gaseous oxygen and the amount of TOB blown. Herein, the increase coefficient Cio may be set to two. The value '2' set as the increase coefficient Cio means that 2 ppm of oxygen increases when gaseous oxygen 1Nm ³ is charged.

Lastly, the control unit 160 subtracts the initial oxygen amount in the molten steel measured by the oxygen measuring means 120 at the temperature measurement time point as shown in Equation 2 to predict the oxygen amount before deoxidation (S17). .

Typically, the amount of oxygen before deoxidation is aimed at 300 ppm. For example, if the initial oxygen amount measured by the oxygen measuring means 120 is 250ppm, the amount of oxygen to be reduced during deoxidation may be calculated as described above. The amount of reduced oxygen at typical initial conditions is about 150 ppm. That is, it turns out that 300 = 250-150 + (Cio × TOB amount). If TOB is not carried out, the oxygen will only be about 100ppm before deoxidation, so it can be seen that 200ppm of oxygen is required to make 300ppm. As can be seen from the oxygen coefficient (Co), when 1Nm ³ of oxygen is injected, 2ppm of oxygen goes up, so it is understood that 100Nm ³ of gaseous oxygen needs to be injected to raise 200ppm of oxygen.

Thus, in the present invention, by predicting the amount of oxygen contained in the molten steel before the deoxidation process, the amount of coolant, deoxidizer (aluminum) input and TOB in the RH process can be adjusted appropriately, thereby improving the cleanness of the molten steel. Obtain a steel fabrication plan.

Such an oxygen prediction apparatus and method is not limited to the configuration and operation of the embodiments described above. The above embodiments may be configured such that various modifications may be made by selectively combining all or part of the embodiments.

10: vacuum chamber 11: rising tube
15: down pipe 20: vacuum motor
30: oxygen lance 50: ladle
100: prediction device 110: temperature measuring means
120: oxygen measuring means 130: memory
140: input unit 150: display unit
160:

Claims (10)

Calculating an expected carbon amount at the time of temperature measurement of the molten steel, and calculating a reduced carbon amount reduced by the decarburization reaction by subtracting a threshold carbon value set to the calculated expected carbon amount;
Calculating a reduced oxygen amount to be reduced during decarburization by multiplying the reduced carbon amount by an oxygen coefficient participating in the reaction during decarburization;
Calculating a change oxygen amount by adding an increase oxygen amount to increase due to TOB to the decrease oxygen amount; And
And subtracting the changed oxygen amount from the measured initial oxygen amount to predict the amount of oxygen before deoxidation.
The expected carbon amount is a dissolved oxygen amount prediction method in the vacuum degassing process is calculated by the following equation.
Equation

However, the temperature measurement time is the elapsed time [min] from the start of the vacuum to the temperature measurement time, A and B are constants derived by the correlation between the actual carbon amount and the initial carbon amount based on the operation performance at the temperature measurement, Initial carbon amount is carbon amount in molten steel [ppm].
Is a method of predicting dissolved oxygen in vacuum degassing process. The method according to claim 1,
The estimated carbon amount is a method for predicting dissolved oxygen in a vacuum degassing process obtained by multiplying an initial carbon amount measured after calculating a temperature-related time point and a predetermined relational constant. The method according to claim 2,
The relationship constant is a method for predicting dissolved oxygen in a vacuum degassing process, which is a value derived from a correlation between an actual carbon amount and an initial carbon amount based on an operation temperature at a temperature. delete The method according to claim 1,
The constant A is a dissolved oxygen amount prediction method in a vacuum degassing process is set to a number less than B. The method according to claim 1,
The constant A is a value between 0.1 and 0.2, B is set to a value between 1 and 2 dissolved oxygen amount prediction method in a vacuum degassing process. The method according to claim 1,
The threshold carbon value is the amount of carbon reduced by the decarburization reaction is set to a value between 10 to 20 dissolved oxygen amount in the vacuum degassing process. The method according to claim 1,
The oxygen coefficient is a reaction ratio of oxygen to carbon reduced by the decarburization reaction, it is set to a value between 0.5 to 0.6 dissolved oxygen amount in the vacuum degassing process. The method according to claim 1,
The increased oxygen amount is a dissolved oxygen amount prediction method in a vacuum degassing process is obtained by multiplying the amount of TOB blown and the increase coefficient of oxygen that is increased in the molten steel when blowing gas. The method according to claim 9,
The method of predicting the dissolved oxygen amount in the vacuum degassing process wherein the increase coefficient is set to '2'.

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