KR101230793B1 - surface treatment material - Google Patents

Abstract

The present invention relates to a metal surface coating agent using an effective microorganism (EM), and in particular, 75 to 90% by weight of the first substance obtained by mixing a useful microorganism stock solution and lactic acid and a liquid detergent for washing acidic acid and lactic acid. And 10 to 25% by weight of the second material obtained by mixing citric acid are obtained by stirring and mixing, and a non-toxic coating agent having excellent anti-rusting property, adhesion and rust removal effect.
Specifically, the first material, characterized in that formed by stirring the mixture of useful microbial stock solution 80 ~ 90 weight% and lactic acid (10 to 20% by weight).
In addition, the second material is formed by mixing 45 to 65% by weight of a strong acidic washing liquid detergent, 20 to 30% by weight of lactic acid and 15 to 35% by weight of citric acid, wherein the strong acidic washing liquid detergent is vegetable 64 to 85% by weight of surfactant, 4 to 15% by weight of herbal fermentation products, 5 to 15% by weight of citrus oil fermentation extract and 0.5 to 6% by weight of Jeju citrus oil mixture, the herbal fermentation product is, 10 ~ 25% by weight of the useful microbial stock solution, 60 to 85% by weight aqueous solution of lacquer water, 5 to 15% by weight of citric acid and herbal components, the citrus oil fermentation extract, 20 to 35% by weight of useful microorganisms It is formed from a mixture of natural ingredients, including a group stock solution, 65-80% by weight aqueous solution of lacquer water and Jeju citrus oil, wherein the Jeju citrus oil mixture is useful in 90-99% by weight of Jeju citrus oil and 1-3% by weight Mixed microbial stock solution Characterized in that air is formed.

Description

Surface treatment material

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a metal surface coating agent prepared using an effective organism (EM), and specifically, to a first substance obtained by mixing a useful microorganism stock solution and lactic acid and a liquid detergent for strong acid washing, lactic acid and citric acid. It relates to a non-toxic coating agent excellent in the rust-preventing and de-rusting effects obtained by stirring and mixing the second substance obtained by mixing.

In a painting operation in which the surface of the object is coated for the protection and aesthetics of an object such as a metal in the related art, rust and dust remaining on the surface when the paint is applied directly without any treatment to the surface of the object Such contaminants make it impossible to obtain the durability of the coating and the adhesion of the coating.

Therefore, there is a need to degrease and decontaminate the surface of an object prior to painting on the surface. In order to improve the adhesion between the surface and the coating and the rust prevention effect, a surface cleaning and anodizing treatment, generally referred to as coating pretreatment, is performed.

In the prior art, the surface cleaning process and the encapsulation treatment process are sequentially performed before coating, and each process will be described in detail as follows.

1. Surface clean process

 (1) Degreasing, Cleaning and Cleaning

To clean the surface of the material, it is first subjected to a degreasing step. The degreasing step is a step for removing oils and the like remaining on the metal surface and other contaminants such as dust and metal powder, and tri-chromethylene (CHCl: CCl ₂ Solvent degreasing to clean the surface using solvents such as 100PPM), di-chloroethylene (Cl ₂ C: CCl ₂ 200PPM) or tri-chloroethane (CH ₃ CCl ₃ 500PPM), and saponification in oils on metal surfaces There are an alkali degreasing method for cleaning surfaces using animal and vegetable oils for oils and fats, and mineral degreasing oils, and a surfactant degreasing method using a degreasing agent using a combination of the above solvent degreasing method and a surfactant.

After the degreasing, a solvent, soap alkali, a surfactant and the like remain on the degreasing metal surface according to the degreasing method. To remove this residue, the metal surface is washed with water or acidic liquid.

 (2) Degreasing (rust removal) and washing

After the degreasing and washing step, a degreasing operation is performed to remove rust or scale on the metal surface. The degreasing method is classified into physical degreasing method of removing black skin or red blue color using a manpower or a machine, and chemical degreasing method of removing rust, that is, oxide layer, of the metal surface using an acidic solution.

In particular, the chemical degreasing method is also commonly referred to as pickling, and hydrochloric acid or sulfuric acid is used.

After degreasing by the chemical degreasing method, the metal surface is washed with hot water or the like to remove acidic solutions or acidic components remaining on the descaled metal surface. The washing with the hot water must proceed immediately after the pickling.

After the degreasing and washing steps are completed, if foreign matter such as dust remains on the metal surface, the cloth is removed using a rag or the like, and the film forming process is performed on the metal surface.

2. Encapsulation Treatment Process

 (1) Surface adjustment and cleaning

After adjusting the surface of the metal or the like through the surface adjustment liquid for the film formation, which is described later, the surface adjustment liquid is washed with water.

 (2) chemical film treatment and cleaning

After the surface adjustment step, a chemical conversion coating process is performed to produce a film by a chemical method in order to provide corrosion resistance and rust resistance to metal surfaces such as iron, nonferrous metals and alloys on the adjusted surface.

Such a chemical film treatment method is a spraying method for spraying a coating agent (film agent) on the upper surface of the surface by spraying or the like for the chemical conversion film on the adjusted surface, and the metal or the like in a container containing the coating agent. Immersion Various methods, such as a brushing method in which a human or a machine applies the coating agent directly to the surface through a brush or the like, have been conventionally used.

The coating agent may be a coating agent having various chemical components, such as a pure substance or a mixture of FeHPO 4, Fe ₂ O ₃ , H ₃ PO ₄ , H ₂ O, Zn0, and / or HNO ₃ , and in general, the coating agent Depends on the type of metal and the like.

After the film treatment is completed on the metal surface using the coating agent, the surface of the surface is washed with water such as hot water to remove unreacted residual coating agent formed on the metal surface and remaining on the coated film. After the washing step to proceed to the post-treatment step.

3. Post Treatment and Washing

After the chemical conversion treatment step, the porous chemical conversion film is sealed (sealed) and then subjected to post-treatment in order to improve rust prevention ability. In the post-treatment process, the metal material is immersed in a dilute solution (about 0.03%) mainly containing chromic acid at about 60 to 90 ° C. for about 30 to 60 seconds.

After the post-treatment, washing with water is generally performed to remove the remaining after-treatment liquid. The washing step may be omitted to maintain the rust preventive effect, but is often post-treated to completely remove the unreacted components of the post-treatment.

4. Drying

After all the processes are completed, the surface of the material is dried by hot air drying or steam drying to remove moisture remaining on the surface of the coated material.

When the drying is completed, the painting operation is performed on the surface of the material to coat a metal surface or the like.

The conventional pretreatment process for rust prevention, adhesion increase and residual rust removal before surface coating of a substance has a problem of having to go through a number of steps to give the surface the effect of rust prevention, adhesion increase and derusting as described above. The coating agent may not only impair the safety of the operator as a substance having a strong toxicity, but also may cause water pollution by mixing the water treatment agent with the toxic in the cleaning process with water can be discharged to the outside. There were a lot of problems.

In addition, since the coating agent had to use a separate coating agent according to whether the metal material to form the coating is iron or non-ferrous metal, there was a problem that a separate coating agent should be provided.

The technical problem to be achieved by the present invention was devised to solve the above-mentioned conventional problems, and at the same time to remove the rust remaining on the surface to be painted, such as metal by having a function of rust prevention and rust removal in the coating operation and At the same time, an object of the present invention is to provide a coating treatment agent capable of preventing the formation of rust and giving the same effect as in the prior art in a few steps.

In addition, unlike conventional coating treatment agent, unlike the coating treatment agent, it does not emit much pollutants in the working environment, it is harmless to workers, and it does not emit water pollutants in the process of washing with water, thus providing a coating treatment agent that does not cause environmental pollution. For other purposes.

In addition, by providing a coating treatment agent having a variety of additional functions, such as anti-rusting and adhesion of the coating surface, coating treatment of the metal surface, anti-aging of the surface and strong sterilization on the metal surface, oil and water separation function and cleaning function addition of the coating treatment agent Maximizing efficacy is another goal.

The present invention has been made to solve the above problems, and provides a coating agent, characterized in that formed by stirring and mixing 75 to 90% by weight of the first material and 10 to 25% by weight of the second material.

The first substance is characterized in that formed 80 to 90% by weight of the useful microbial stock solution and 10 to 20% by weight of lactic acid is formed by stirring and mixing.

The second material is characterized by being formed by mixing 45 to 65% by weight of the strong acidic laundry liquid detergent, 20 to 30% by weight of lactic acid and 15 to 35% by weight of citric acid.

The strong acidic laundry liquid detergent used in the second material is 64 to 85% by weight of vegetable surfactant, 4 to 15% by weight of herbal fermented products, 5 to 15% by weight of citrus oil fermented extract and 0.5 to 6 of Jeju citrus oil mixture It is a mixed liquid formed by mixing by weight.

Specifically, the herbal fermented processed product is formed of a mixture of 10 to 25% by weight of a useful microbial stock solution, 60 to 85% by weight of a lacquer water solution, 5 to 15% by weight of citric acid and herbal components, and the citrus oil fermented extract Silver, 20 to 35% by weight of the useful microbial stock solution, 65 to 80% by weight aqueous solution of lactose and Jeju citrus oil is formed by a mixture of natural components, the Jeju citrus oil mixture, 90 to 99% by weight of Jeju Citrus oil and 1-3% by weight of useful microbial stock solution is characterized in that it is formed by mixing.

The natural ingredients mixed in the citrus oil fermented extract will be described later.

Meanwhile, preferably, each of the coating agent formed by mixing the first material, the second material, and the first material and the second material has an acidity of pH 2.5 or less for effective rust prevention, rust removal, and coating. can do.

More preferably, each of the coating agent formed by the mixing of the first material, the second material and the first material and the second material may be carried out after each mixing step to remove impurities that may be generated after mixing. It may be characterized by using a micro filter having a filtration performance of 100 ㎛ or less.

In the present invention, the coating agent obtained as described above is provided with a rust prevention function and a rust removal function at the time of painting, thereby removing rust remaining on the surface to be coated such as metal and preventing generation of rust. It is possible to provide the effect at the same time.

In addition, the coating agent is formed by a mixture of environmentally friendly materials that are harmless to the human body, unlike the conventional toxic coating agent does not discharge a lot of pollutants in the working environment is harmless to the operator, water pollutants are discharged even during the process of washing It does not cause environmental pollution.

In the coating treatment on the surface to be coated after degreasing work and antirust treatment using the coating agent, the coating agent increases the rust resistance of the surface to be coated while removing rust or scale remaining even after the antirust treatment. It is possible to prevent the occurrence of rust due to oxidation in advance, and unlike the conventional film treatment technology, the surface adjustment and drying process without going through surface adjustment, washing, coating conversion treatment, post treatment, washing, drying and powder removal It is possible to obtain an advantage that the coating can be easily performed alone. Therefore, the time and cost consumed in the coating process can be reduced.

In addition, the coating agent enhances the adhesion of the surface to be coated to enable a more stable coating of the paint on the surface, and by coating the surface of the metal to be coated to smooth and smooth the metal surface, the metal surface It is also possible to obtain an effect of forming a film between the paint for painting and blocking direct contact between the metal and the paint to prevent aging of the coating.

In addition, the coating agent also provides an effect of imparting an excellent oil / water separation function and a strong cleaning function to the surface to be coated.

In addition, unlike the conventional use of a separate coating agent according to the iron, non-ferrous metals, etc. provides a coating agent that can be used simultaneously for all kinds of metals.

Hereinafter, preferred embodiments of the present invention will be described with reference to the accompanying drawings so that those skilled in the art may easily implement the present invention. However, in the following description of the present invention, the drawings are not intended to limit the scope of the present invention but merely represent an embodiment of the invention.

Hereinafter, a useful microbial stock solution used in one embodiment of the present invention may be a commercially available useful microbial stock solution. The useful microorganisms symbiotic in the useful microbial group stock solution are known and those skilled in the art can easily obtain the microorganisms.

According to an embodiment of the present invention, a first material obtained by mixing a useful microbial stock solution and lactic acid, a strong acid laundry liquid detergent, a second material obtained by mixing lactic acid and citric acid, and the first material and the second material are stirred and mixed. It relates to a coating treatment agent obtained by.

Hereinafter, the coating agent including the first material and the coating agent including the second material according to one embodiment of the present invention will be described, and then the coating agent obtained by mixing the first material and the second material will be described. I will explain.

Hereinafter, the coating agent including the first substance in one embodiment of the present invention will be described.

In one embodiment of the present invention, the coating agent, characterized in that it comprises a first material formed by stirring and mixing 80 to 90 weight% of useful microbial stock solution and 10 to 20% by weight lactic acid.

In one embodiment of the present invention, preferably, when the useful microbial stock solution and lactic acid are mixed as described above, an acidity may be formed at a pH of 4.5 or less to show acidity. More preferably, the first material may have an acidity of ph 2.5 or less, and may have a strongly acidic property. This is to enhance the rust and derust effect of the first material.

In addition, in one embodiment of the present invention, the first material is obtained by mixing the useful microbial stock solution and the lactic acid, and then filtering the mixed solution formed by the mixing using a micro filter of 100 μm or less. Can be. This is to remove impurities and the like that may be generated by the mixing.

The first material formed through the above method, the black surface treatment of the coating surface to increase the rust resistance of the coating surface, and prevents the aging of the coating film by the metal by intermittently blocking the reaction between the metal and the paint. It also has the effect of increasing the adhesion of the painted surface and coating treatment to smooth the metal surface.

The lactic acid contained in a large amount in the first substance can maintain the coating treatment agent of the present invention in an acidic manner, and is fermented by yeasts symbiotic with the useful microbial stock solution to produce a substance having effects such as oil and water separation and scale removal. The film treatment agent can provide a variety of functions, such as rust removal, scale, oil-water separation.

Hereinafter, the coating agent including the second material in one embodiment of the present invention will be described.

The second material is characterized by being formed by mixing 45 to 65% by weight of the strong acidic laundry liquid detergent, 20 to 30% by weight of lactic acid and 15 to 35% by weight of citric acid.

Here, the strong acid laundry liquid detergent is a strong acid laundry described in the previously filed 'strong acidic laundry liquid detergent containing fermentation material and a manufacturing method (application number 10-2010-0054701, filed June 10, 2010)' It refers to the liquid detergent for, specifically, it can be characterized by the mixture formed by mixing of the following components.

① 64 ~ 85% by weight of vegetable surfactant

② Herbal fermented processed product 4-15% by weight

③ 5 ~ 15% by weight of citrus oil fermented extract

④ 0.5 ~ 6 wt% of Jeju citrus oil mixture

In one embodiment of the present invention, the surfactant may be a conventional synthetic surfactant. Preferably it may be characterized in that it is a laundry vegetable surfactant that is harmless to the human body and does not cause environmental pollution.

In one example, the laundry vegetable surfactant may be an oil solution extracted by processing palm, coconut, and soybean, but the oil content may be 20% or more and less than 40%.

On the other hand, the herbal fermentation product is formed by adding a herbal component to a mixture formed by mixing 10 to 25% by weight of the useful microbial stock solution, 60 to 85% by weight of lacquer water solution, and 5 to 15% by weight of citric acid.

The herbal fermented processed product provides the effect of oil-water separation, scale removal, sterilization, etc. in the present invention.

The lacquer aqueous solution is used as an aqueous lacquer solution containing more than 5% of the lacquer concentrate except for purified water, and the citric acid is described above so that the acidity of the mixture of the useful microbial stock solution, the aqueous solution of the lacquer and the citric acid may be ph 3 or less Mix 5-15% by weight as one.

In order to obtain the optimum effect of the present invention, 15 to 20% by weight of the useful microbial stock solution, 70 to 75% by weight of the aqueous solution of lacquer water, and 5 to 15% by weight of citric acid are preferably mixed.

On the other hand, in the herbal fermented processed product, the herbal component is based on 20 L of the mixed solution of useful microorganism stock solution, aqueous solution of lacquer water and citric acid, gold: 5 to 25 g, ointment: 5 to 25 g, gold and silver: 5 to 25 g, peony: 5 to 5 20g, fruit room: 5-20g, country soup: 5-25g, green tea: 5-25g, quince: 5-20g, dermis: 50-100g or cheonnyeoncho: characterized in that it comprises one or more components selected from .

The herbal component contains a large amount of amino acid, organic acid and natural citric acid component to maintain the acidic strong acid laundry liquid detergent containing the fermentation material of the present invention, and is fermented by yeast, which is symbiotic to the useful microbial stock solution, and separated from oil and water. , Substances with the effect of descaling are produced.

On the other hand, in one embodiment of the present invention the method for producing the herbal fermented processed product is composed of the following steps.

(1) preparing an aqueous solution of EM lacquer containing citric acid by mixing 10 to 25 wt% of the useful microbial stock solution, 60 to 85 wt% of aqueous solution of lacquer, and 5 to 15 wt% of citric acid.

(2) mixing the herbal components in an EM lacquer aqueous solution containing the citric acid

(3) extracting the herbal extract of the general concentration by using the herbal extractor in an EM lacquer aqueous solution containing citric acid mixed with the herbal components

(4) filtering the herbal extract using a micro filter

(5) adjusting the acidity to pH 2.5 ~ 3 by adding lactic acid for food additives to the filtered herbal extracts and

(6) low-temperature vacuum distillation of the herbal extract with the acidity adjusted using a low-temperature vacuum distillation apparatus at a medium vacuum state of 10 ^-3 to 1 Torr and a temperature of 55 to 65 ° C.

Specifically, in the step (3), the herbal extractor in step (3) using a herbal extractor using a temperature of the hot water method or low temperature extraction method (40 ~ 90 ℃), so as to minimize the destruction of pharmacological components In the step (4), the micro filter may remove impurities using a 0.2 μm filtering equipment. On the other hand, step (6) is a low-temperature vacuum to remove impurities less than 0.2㎛ not filtered in step (4) as described above, to improve the odor, turbidity and chromaticity and to minimize the destruction of pharmacological components Low temperature vacuum distillation using distillation equipment. The description of other steps will be omitted because they have been described above or technically inferred by those skilled in the art.

The citrus oil fermentation extract is characterized in that it is formed by adding a natural component including jeju citrus oil to a mixture of 20 to 35% by weight of the useful microbial stock solution and 65 to 80% by weight aqueous solution of lacquer.

The citrus oil fermented extract exhibits effects of preventing discoloration and discoloration of clothes, bactericidal action, fabric softening, skin protection, etc. in the strong acidic liquid cleaning, and provides a bactericidal effect in the present invention.

In the present invention, the useful microbial stock solution and the lacquer aqueous solution are the same as those described in the herbal fermentation product.

In addition, in the citrus oil fermented extract, the natural ingredients are organic sulfur sugar: 100-200 g, sun salt: 50-150 g, Jeju citrus oil: 50-100 g, plums Concentrate: 50-100g, Cheonnyeoncho powder: 50-100g, dermis powder: 50-100g, green tea powder: 5-30g, kelp powder: 5-30g, rice bran: 5-30g, camellia oil: 5-30g or soy powder: 5 Characterized in that it comprises one or more components selected from ˜30g.

The natural component is fed to the main microorganisms, such as surviving in the useful microbial stock solution has the effect of promoting the growth of the microorganism to enhance the fermentation ability and sterilization of the microorganism.

In one embodiment of the present invention, the method for preparing the citrus oil fermented extract consists of the following steps.

(1) preparing an EM lacquer aqueous solution by mixing 20 to 35 wt% of an effective organisms (EM) stock solution and 65 to 80 wt% of an aqueous solution of lacquer water.

(2) 100 to 200 g of organic sulfur sugar, 50 to 150 g of natural salt, 50 to 100 g of Jeju citrus oil, 50 to 100 g of plum concentrate, 50 to 100 g of cheonnyeoncho powder, 50 to 100 g of dermis powder, 5 to 30 g of green tea powder Mixing natural ingredients containing at least one component from 5-30 g of kelp powder, 5-30 g of rice bran, 5-30 g of camellia oil, and 5-30 g of soybean powder

(3) the step of fermenting low temperature fermentation for 2 to 3 months at 15 ~ 20 ℃ EM aqueous solution mixed with the natural ingredients

(4) filtering the EM lacquer aqueous solution mixed with the low temperature matured natural ingredients using a bag filter

(5) filtering the herbal extract using a micro filter

(6) adjusting the acidity to pH 3 ~ 4 by adding lactic acid for food additives to the filtered herbal extracts and

(7) low-temperature vacuum distillation of the herbal extracts with the acidity adjusted using a low-temperature vacuum distillation apparatus at a medium vacuum state of 10 ^-3 to 1 Torr and a temperature of 55 to 65 ° C.

Specifically, the step of (3) the optimum temperature and fermentation ripening period is about 17 ~ 18 ℃ and about 2 months. In the step (4), the bag filter used for the purpose of removing impurities is preferably a 10 μm bag filter. In the step (5), the micro filter can remove impurities using a 0.2 μm filtering equipment. The description of other steps will be omitted because they have been described above or technically inferred by those skilled in the art.

Finally, the Jeju citrus oil mixture, characterized in that formed by mixing 90 to 99% by weight of Jeju citrus oil and 1 to 3% by weight of the useful microbial stock solution.

The citrus citrus oil mixture provides antimicrobial, antiseptic, fiber softening and fragrance effects to the strongly acidic laundry liquid detergent.

When the useful microbial stock solution and the citrus oil are mixed, yeasts and lactic acid bacteria of the useful microbial stock solution are fermented to produce a weakly acidic substance having antioxidant power.

In one embodiment of the present invention, the second material, preferably when the strong acid detergent, lactic acid and citric acid are mixed in the same ratio may be characterized in that the acidity is formed to pH 4.5 or less to show acidity. . More preferably, the first material may have an acidity of ph 2.5 or less, and may have a strongly acidic property. This is to increase the derusting effect of the second material.

In addition, in one embodiment of the present invention, the second material is obtained by mixing the useful microbial stock solution and the lactic acid, and then filtering the mixed solution formed by the mixing using a micro filter of 100 μm or less. Can be. This is to remove impurities and the like that may be generated by the mixing.

The second material formed as described above is capable of providing an excellent function in removing rust and scale by mixing the strong acid detergent having excellent effects in scale, oil-water separation, and the like with lactic acid and citric acid, and the strong acid detergent Excitation sterilization function, oil and water separation function and washing function are imparted to the coating additive.

Hereinafter, the coating additive obtained by mixing the first substance and the second substance will be described.

The film additive formed by mixing the first material and the second material is 75 to 90% by weight of the first material, 10 to 25% by weight of the second material is added, the first material And the second material is formed by stirring and mixing.

In one embodiment of the present invention, the coating additive obtained by the mixing of the first material and the second material, preferably, when mixed as described above may be characterized in that the acidity is formed to pH 4.5 or less to show acidity have. More preferably, the film additive obtained by mixing the first material and the second material may be characterized by having an acidity of ph 2.5 or less and having a strongly acidic property.

In addition, in one embodiment of the present invention, the film additive obtained by mixing the first material and the second material, after the first material and the second material is mixed, using a micro filter of 100 ㎛ or less It is characterized by the thing obtained by filtering a liquid mixture. This is to remove impurities and the like that may be generated by the mixing.

The film additive obtained by mixing the first substance and the second substance has all the properties of the first substance and the second substance, which are vaporized, to increase the rust resistance and adhesion of the painted surface, and react with the metal and the paint. Intermediate blocking prevents aging of the coating film and has excellent properties in removing rust and scale. It also additionally gives the surface of the material a sterilization function, oil water separation function and cleaning function.

[Example 1]

Hereinafter, a method of coating pretreatment using a coating additive obtained by mixing the first substance and the second substance will be described.

In the pretreatment of the surface of a small amount of metal material, the surface cleaning process (degreasing and washing step and degreasing and washing step) is performed in the same manner as in the conventional art. In this process, the degreasing step is generally performed by using a physical mechanical method for a small amount of coating and a chemical method of washing a metal surface with an acidic solution for a large amount of coating.

When the surface cleaning process is completed, the chemical conversion coating process, which is a next step, is performed. In the chemical conversion coating, the coating treatment agent of the present invention is first applied to the metal surface by spraying two or three times. At this time, the metal surface is working in the dry state as possible.

Next, the coating material is sprayed to dry the metal material in order to remove moisture from the applied metal surface. In one embodiment of the present invention, the drying method may be hot air drying to dry using hot air at a temperature of 120 ℃ or less. In another embodiment, a method of natural drying without using a separate device is also possible. The drying may proceed in about 15 minutes.

As described above, the method for forming a film on the surface of a material such as a metal by using the present invention includes the steps of surface cleaning, chemical conversion treatment and drying, thereby providing surface cleaning, chemical conversion treatment, post treatment and There is no need for complex multi-steps, such as cleaning and drying processes. In addition, the chemical conversion treatment process does not need to go through a washing step, which is an essential step for washing a highly toxic substance as in the prior art, so that the harmful substances are discharged to reduce the risk of water pollution and are simpler than before. There is an advantage that the film can be treated.

Although the present invention has been shown and described with reference to the preferred embodiment as described above, the scope of the present invention is not limited to the above-described embodiment and should be interpreted by the appended claims. In addition, various modifications and improvements within the equivalent range by those skilled in the art using the basic concept of the present invention also fall within the scope of the present invention.

Claims (8)

delete delete And a second material formed by mixing 45 to 65% by weight of a strong acidic laundry liquid detergent, 20 to 30% by weight of lactic acid, and 15 to 35% by weight of citric acid.
The strong acid laundry liquid cleaner,
Vegetable surfactant 64 to 85% by weight, herbal fermented processed product 4 to 15% by weight, citrus oil fermented extract 5-15% by weight and Jeju citrus oil mixture 0.5 to 6% by weight of the mixture,
The herbal fermented processed product,
It is formed by adding a herbal component to the mixture formed by the mixture of 10 to 25% by weight of the useful microbial stock solution, 60 to 85% by weight aqueous solution of lacquer water, 5 to 15% by weight of citric acid,
The citrus oil fermented extract,
It is formed by adding a natural citrus oil component to a mixture of 20 to 35% by weight of the useful microbial stock solution and 65 to 80% by weight aqueous solution of lacquer water,
Jeju citrus oil mixture,
90 to 99% by weight of Jeju citrus oil and 1 to 10% by weight of the useful microbial stock solution is formed by a coating agent.
The method according to claim 3,
The second material is,
A coating agent obtained by filtering the liquid mixture of the strongly acidic laundry liquid detergent, the lactic acid, and the citric acid using a micro filter of 100 µm or less.
75 to 90% by weight of the first material and 10 to 25% by weight of the second material are formed by stirring and mixing,
The first material is,
It is formed by stirring and mixing 80-90 weight% of microorganism stock solution and 10-20 weight% of lactic acid,
The second material is,
It is formed by mixing 45 to 65% by weight of a strong acidic laundry liquid detergent, 20 to 30% by weight of lactic acid and 15 to 35% by weight of citric acid,
The strong acid laundry liquid cleaner,
Vegetable surfactant 64 to 85% by weight, herbal fermented processed product 4 to 15% by weight, citrus oil fermented extract 5-15% by weight and Jeju citrus oil mixture 0.5 to 6% by weight of the mixture,
The herbal fermented processed product,
It is formed by adding a herbal component to the mixture formed by the mixture of 10 to 25% by weight of the useful microbial stock solution, 60 to 85% by weight aqueous solution of lacquer water, 5 to 15% by weight citric acid,
The citrus oil fermented extract,
It is formed by adding a natural citrus oil component to a mixture of 20 to 35% by weight of the useful microbial stock solution and 65 to 80% by weight aqueous solution of lacquer water,
Jeju citrus oil mixture,
90 to 99% by weight of Jeju citrus oil and 1 to 10% by weight of the useful microbial stock solution is formed by a coating agent.
The method according to claim 5,
The coating agent obtained by filtering the mixture formed by the stirring mixture of the said 1st material or the said 2nd material using a microfilter of 100 micrometers or less.
The method according to claim 3 or 5,
The herbal component,
An encapsulation agent comprising at least one component selected from gold, ointment, gold and silver, peony, fruit, gamgu, green tea, quince, dermis or millennia.
The method according to claim 3 or 5,
The natural ingredient,
An organic yellow sugar, sun salt, citrus oil, Jeju concentrate, cheonnyeoncho powder, dermis powder, green tea powder, kelp powder, rice bran, camellia oil or soybean powder coating agent comprising at least one component selected from.