KR101211629B1 - Polymer Concrete Composite and Permeable Block Thereof - Google Patents

Polymer Concrete Composite and Permeable Block Thereof Download PDF

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Publication number
KR101211629B1
KR101211629B1 KR1020110015766A KR20110015766A KR101211629B1 KR 101211629 B1 KR101211629 B1 KR 101211629B1 KR 1020110015766 A KR1020110015766 A KR 1020110015766A KR 20110015766 A KR20110015766 A KR 20110015766A KR 101211629 B1 KR101211629 B1 KR 101211629B1
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South Korea
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weight
parts
filler
polymer concrete
concrete composition
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KR1020110015766A
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Korean (ko)
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KR20120096375A (en
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정중호
이윤수
전철수
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주식회사 네오콘텍
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Dispersion Chemistry (AREA)
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Abstract

The present invention aggregate 70 to 75 parts by weight; 5 to 9 parts by weight of a binder composed of at least one of an unsaturated polyester resin, an epoxy resin, a urethane resin, a methyl methacrylate resin, a thermosetting resin, and a thermoplastic resin; 3 to 15 parts by weight of the first filler; 3 to 15 parts by weight of the second filler, wherein the second filler is relatively coarse than the first filler; And 1 to 20 parts by weight of a heat shield; and a polymer concrete composition comprising a water-permeable block using the same, including water, without using water and using a resin having high light resistance and small temperature sensitivity, By blending, the bonding force is excellent, so that no detachment occurs and the water permeability can be retained for a long time. In addition, by containing the inorganic fine particles having a hollow spherical shape, it has a solar reflection effect and heat insulating properties, it is excellent in mold prevention and antibacterial effect. In addition, the water permeable block prepared using the polymer concrete composition according to the present invention has a high permeability performance, there is an effect that can retain the permeability for a long time. Thus, by installing the water permeable block according to the present invention, such as roads, parks or squares in the city, it is possible to prevent desertification of the city and to maximize the storage and evaporation capacity of the water. In addition, by reducing the surface temperature of the road due to the ceramic hollow fine particles, it is possible to prevent heat island phenomenon, to sterilize various bacteria and to decompose formaldehyde by adding silver ions.

Description

Polymer Concrete Composite and Permeable Block Thereof

The present invention relates to a polymer concrete composition and a water permeation block using the same, and more particularly, to prevent desertification of the city, to maximize the storage and evaporation capacity of water, and to distribute the surface of ceramic hollow fine particles on the surface to reduce the surface temperature. The present invention relates to a polymer concrete composition which reduces heat islands, adds silver ions to sterilize various bacteria and decomposes formaldehyde, and a permeation block using the same.

As water in the ocean and the surface of the water evaporates and falls on the surface in the form of rain or snow, humans have been using their parts to maintain their lives. However, urban flooding and groundwater depletion due to the limited amount of water and increasing urbanization and industrialization due to the increase in population, the infiltration of rainwater is virtually impossible due to the asphalt and concrete pavement of concrete structures, roads or sidewalks. The situation is serious.

1 is a soil coating distribution showing the current state of soil coating in Seoul. As shown in FIG. 1, it can be seen that concrete covers 82% of Seoul land. This shows that in urban areas it is impossible to infiltrate rainwater. Accordingly, acceleration of urban desertification and consequent underground environmental destruction or pollution are emerging as social problems.

As a countermeasure, a permeable concrete pavement and a permeable block pavement are widely used in urban areas, and as a part of them, the construction cost is low and the construction is simple. However, the conventional permeable concrete has a long permeability performance. Since it is not sustainable, it is urgent to develop a product to replace it.

In addition, as the people's living standards are improved due to socio-economic advancement, the demand for safe and comfortable living is increasing. Accordingly, there is an increasing demand for materials for roadways and sidewalks, eco-friendliness, design, functionality, and the like. Therefore, the development of a product to achieve this purpose is required.

Therefore, the present invention was created to solve the above problems, to prevent desertification of the city, to maximize the storage and evaporation capacity of water, and to distribute the ceramic hollow particles on the surface to reduce the surface temperature (Heat Island) The purpose of the present invention is to provide a polymer concrete composition and a water permeation block using the same to reduce the amount, and add silver ions to sterilize various bacteria and decompose formaldehyde.

An object of the present invention as described above is 70 to 75 parts by weight of aggregate; 5 to 9 parts by weight of a binder composed of at least one of an unsaturated polyester resin, an epoxy resin, a urethane resin, a methyl methacrylate resin, a thermosetting resin, and a thermoplastic resin; 3 to 15 parts by weight of the first filler; 3 to 15 parts by weight of the second filler, wherein the second filler is relatively coarse than the first filler; And 1 to 20 parts by weight of the heat shield; it can be achieved by the polymer concrete composition comprising a.

At this time, the aggregate is at least one of crushed stone, cobbles, silica sand and artificial lightweight aggregate having a particle size of 13 mm or less.

Further, the first filler is at least one of heavy calcium carbonate, stone powder, slag, cement, fly ash and paper ash having a particle diameter of 1 μm to 30 μm, and the second filler is fine silica having a particle diameter of 20 μm to 40 μm. .

In addition, the heat shield is an inorganic fine particle which is at least one of an aluminosilicate ceramic and a silica alumina ceramic having a hollow spherical form.

In addition, the polymer concrete composition further comprises 0.5 parts by weight to 5 parts by weight of the curing agent.

Further, 4 to 5 parts by weight of the silver ion antibacterial agent of the total weight of the binder is further included.

As another category, the object of the present invention can be achieved by a permeable block using the polymer concrete composition described above.

According to the present invention, by using a resin having a high light resistance, a low temperature sensitivity, and blending each composition according to the present invention, the bonding strength is excellent, so that no detachment occurs and the water permeability can be retained for a long time.

In addition, by containing the inorganic fine particles having a hollow spherical shape, it has a solar reflection effect and heat insulating properties, it is excellent in mold prevention and antibacterial effect.

In addition, natural amino acids, including silver ion antimicrobial agents, decompose formaldehyde, which is a skin allergen, and silver ions have an effect of obtaining high bactericidal power against most bacteria such as pneumococci, Escherichia coli, and Staphylococcus aureus.

In addition, the permeable block prepared using the polymer concrete composition according to the present invention has a high permeability performance, there is an effect that can retain the permeability for a long time. Thus, by installing the water permeable block according to the present invention, such as roads, parks or squares in the city, it is possible to prevent desertification of the city and to maximize the storage and evaporation capacity of the water. In addition, there is an effect that can prevent the heat island phenomenon by reducing the surface temperature of the road due to the ceramic hollow fine particles.

The following drawings, which are attached in this specification, illustrate preferred embodiments of the present invention, and together with the detailed description thereof, serve to further understand the technical spirit of the present invention. It should not be interpreted.
1 is a soil coating distribution chart showing the status of soil coating in Seoul,

Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.

Polymer Concrete Composition

The polymer concrete composition according to the invention comprises an aggregate, a binder, a first filler, a second filler and a heat shield.

The aggregate according to the present invention is a crushed stone, steel gravel, silica sand and the like having a particle size of 13mm or less, in some cases using artificial lightweight aggregate, and includes 70 to 75 parts by weight of the total weight of the polymer concrete composition. At this time, the aggregate should be used to dry completely, the higher the strength of the aggregate, the higher the overall strength of the polymer concrete composition.

The binder (Binder) according to the present invention contains 5 to 9 parts by weight of the total weight of the polymer concrete composition. At this time, as the type of binder, an unsaturated polyester (UP) resin, an epoxy resin, a urethane resin, a methyl methacrylate (MMA) resin, a thermosetting resin, and a thermoplastic resin alone Use or mix. Preferably, unsaturated polyester resin and methyl methacrylate resin are used, or unsaturated polyester resin and methyl methacrylate resin are mixed and used. If the binder is less than 5 parts by weight, there is a problem in that the strength decreases significantly. If the binder is more than 9 parts by weight, there is a problem in that the water permeability is lowered due to a pore blocking phenomenon.

The first filler and the second filler according to the present invention are used for increasing the binder, improving workability, improving strength and durability, and the second filler uses a relatively coarse filler as compared to the first filler.

Here, the first filler using at least any one of fine calcium carbonate, stone powder, slag, cement, fly ash and paper ash having a fine powder with a particle diameter of 1 to 30 ㎛, 3 to 15 weight of the total weight of the polymer concrete composition Addition is included. Although the first filler made of such a fine powder is inexpensive and has good physical properties, it is preferable not to exceed 15 parts by weight based on the total weight of the polymer concrete composition because of the problem that the strength is lowered when it is used a lot. If the first filler is less than 3 parts by weight, there is no meaning as a filler. If the first filler is more than 15 parts by weight, the workability is lowered and the amount of the binder is increased to increase the cost.

In the second filler according to the present invention, it is preferable to use fine silica sand having a particle diameter of 20 μm to 40 μm, and more preferably # 8 yarn sand. This second filler comprises from 3 to 15 parts by weight of the total weight of the polymer concrete composition. If the second filler is less than 3 parts by weight, there is no meaning as a filler, and if the second filler is more than 15 parts by weight, the amount of the binder is increased to increase the cost.

Heat shielding material (ceramic hollow particles) according to the present invention is to improve the heat shielding and thermal insulation effect, alumina silicate (Alumino Siliccate) having a hollow spherical shape and a hollow spherical shape having a solar firing effect and heat insulation in the form of bubbles ) Inorganic fine particles such as ceramics and silica alumina ceramics are used alone or in combination. Such heat shield includes 1 to 20 parts by weight of the total weight of the polymer concrete composition. As a preferred heat shield, the present invention uses an insuladd commercialized with an aluminosilicate system. In the present invention, the insulation is used, but any material can be used as long as it has a heat shielding function. If the heat shield is less than 1 part by weight, there is no heat shielding effect. If the heat shield is more than 20 parts by weight, the amount of the binder is increased to increase the unit cost. In particular, the binder is not significantly different in use of 15 parts by weight or more, it is preferable to use 6 parts by weight to 12 parts by weight as appropriate capacity.

The polymer concrete composition according to the present invention may further comprise a small amount of curing agent depending on the use. In this case, the hardener may include 0.5 parts by weight to 5 parts by weight of the total weight of the polymer concrete composition.

In addition, the polymer concrete composition according to the present invention may contain 4 parts by weight to 5 parts by weight of silver ion antibacterial agent based on the total weight of the binder for the antibacterial effect. In this case, the silver ion antimicrobial agent may be contained in a liquid paste or powder state. In this case, it is preferable to use an organic solution-based silver amino acid as the silver ion antimicrobial agent to be used. As such, when the silver ion antimicrobial agent is further included, natural amino acids decompose formaldehyde, which is a skin allergen, and further sterilize pneumococci, Escherichia coli, and Staphylococcus aureus.

One preferred embodiment of the polymer concrete composition comprising the above-described composition is made of a combination as shown in Table 1 below.

division Binders 1st filler
(Calcium Carbonate)
2nd filler
(# 8 Hoshi Sasa)
Heat shield
(Insulin)
aggregate
(Gyusa 1)
system
weight 60 60 88 20 772 1000 percentage 6.0% 6.0% 8.8% 2.0% 77.2% 100%

Depending on the use aspect, 0.5 parts by weight to 5 parts by weight of the curing agent and 4 parts by weight to 5 parts by weight of the total weight of the silver ion antimicrobial agent may be further included.

<Pitching block manufacturing method>

The permeable block according to the present invention is manufactured using the above-described polymer concrete composition, the production method is as follows.

First, the mold is assembled so as to correspond to the shape and size of the permeable block to be manufactured to produce the block.

Next, the release agent is evenly applied to the inside of the assembled mold to facilitate demolding of the polymer concrete. If the release agent is excessively used, problems may occur during curing of the polymer concrete, and the excessively applied portion of the release agent is removed using a dry cloth.

Next, the polymer concrete is blended. At this time, the polymer concrete is mixed at the same mixing ratio as described above and mixed through a mixer. The polymer concrete mixing process will be described in more detail as follows.

Weigh the aggregates into the mixer, mix the hardener in the binder and pour into the aggregates for 3 minutes. At this time, the mixing of the binder is preferably carried out for 1 minute or more so as to completely knead the curing agent.

Next, the blended polymer concrete composition is filled into a mold using a scoop. At this time, the polymer concrete composition is compacted by filling the top of the mold about 1 cm convex.

Next, the upper surface is pressed to smooth the surface to finish the surface.

Next, the permeation block is cured using the polymer concrete composition filled in the mold and stored so that no external force is applied at room temperature.

Finally, when the curing of the polymer concrete composition is completed, the permeation block is demolded from the mold to manufacture the permeation block.

<Installation method of pitcher block>

The installation method of the pitcher block according to the present invention is as follows.

First of all, the installation space is determined, and in order to secure the space for installing the permeation block by digging in consideration of the height of the ground after installation.

Next, after leveling the ground surface using silica sand, and secure the place to install the pitcher block.

Next, install a pitcher block to be spaced apart a certain interval. At this time, each pitcher block is installed to be spaced apart at the same interval. However, the permeation block may be installed without being spaced apart from each other, or may be installed at different intervals in consideration of the use mode and installation environment.

Next, the installation of the permeation block is completed by filling silica sand between each permeation block and removing excess silica sand on the block surface.

As described above, those skilled in the art will understand that the present invention may be embodied in other specific forms without departing from the spirit or essential characteristics thereof. It is therefore to be understood that the above-described embodiments are to be considered in all respects as illustrative and not restrictive. The scope of the present invention is defined by the appended claims rather than the detailed description and all changes or modifications derived from the meaning and scope of the claims and their equivalents should be construed as being included within the scope of the present invention.

Claims (7)

70 to 75 parts by weight of aggregate;
5 to 9 parts by weight of a binder composed of at least one of an unsaturated polyester resin, an epoxy resin, a urethane resin, a methyl methacrylate resin, a thermosetting resin, and a thermoplastic resin;
3 to 15 parts by weight of the first filler;
3 to 15 parts by weight of the second filler is relatively thicker than the first filler; And
1 to 20 parts by weight of the heat shield; the polymer concrete composition comprising a.
The method of claim 1,
The aggregate is a polymer concrete composition, characterized in that the particle size is at least any one of crushed stone, steel gravel, silica and artificial light aggregate of 13mm or less.
The method of claim 1,
The first filler is at least one of heavy calcium carbonate, stone powder, slag, cement, fly ash and paper ash having a particle diameter of 1㎛ 30㎛,
The second filler is a polymer concrete composition, characterized in that the fine silica having a particle diameter of 20㎛ to 40㎛.
The method of claim 1,
The heat shield is a polymer concrete composition, characterized in that the inorganic fine particles of at least one of aluminosilicate ceramic and silica alumina ceramic having a hollow spherical shape.
The method of claim 1,
The polymer concrete composition further comprises 0.5 parts by weight to 5 parts by weight of a curing agent.
The method of claim 1,
4 to 5 parts by weight of the silver ion antimicrobial agent of the total weight of the binder further comprises a polymer concrete composition.
Permeable block using the polymer concrete composition according to any one of claims 1 to 5.
KR1020110015766A 2011-02-22 2011-02-22 Polymer Concrete Composite and Permeable Block Thereof KR101211629B1 (en)

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KR101211629B1 true KR101211629B1 (en) 2012-12-13

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KR101838586B1 (en) * 2017-03-21 2018-03-14 청호환경개발주식회사 Infiltration Sidewalk Block System Including Clearance Block
KR102348646B1 (en) 2021-05-31 2022-01-12 흥덕산업 주식회사 Organic-inorganic hybrid antibacterial concrete block with surface layer using acryl resin and antibacterial artificial aggregate and the manufacturing method thereof
KR102425765B1 (en) 2022-01-27 2022-07-28 주식회사 정우콘크리트 Sidewalk and road block with non-slip and antibacterial for pedestrian safty of peopoe who are weak in walking

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DE102015112524A1 (en) 2015-07-30 2017-02-02 Halla Visteon Climate Control Corporation Method for voltage balancing of capacitors connected in series
JP6914682B2 (en) * 2017-03-17 2021-08-04 東洋工業株式会社 Laying block
CN108892410B (en) * 2018-09-25 2020-12-25 福建三凯建筑材料有限公司 Concrete cementing material
KR102477171B1 (en) * 2021-09-17 2022-12-12 김종순 Mortar composition with thermal insulation performance
KR102477174B1 (en) * 2021-09-17 2022-12-12 김종순 Paint composition with thermal insulation performance

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101838586B1 (en) * 2017-03-21 2018-03-14 청호환경개발주식회사 Infiltration Sidewalk Block System Including Clearance Block
KR102348646B1 (en) 2021-05-31 2022-01-12 흥덕산업 주식회사 Organic-inorganic hybrid antibacterial concrete block with surface layer using acryl resin and antibacterial artificial aggregate and the manufacturing method thereof
KR102425765B1 (en) 2022-01-27 2022-07-28 주식회사 정우콘크리트 Sidewalk and road block with non-slip and antibacterial for pedestrian safty of peopoe who are weak in walking

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