KR101144881B1 - 특정 개시제 시스템을 사용함으로써 중합 반응기 생성량을증가시키는 방법 - Google Patents
특정 개시제 시스템을 사용함으로써 중합 반응기 생성량을증가시키는 방법 Download PDFInfo
- Publication number
- KR101144881B1 KR101144881B1 KR1020057020643A KR20057020643A KR101144881B1 KR 101144881 B1 KR101144881 B1 KR 101144881B1 KR 1020057020643 A KR1020057020643 A KR 1020057020643A KR 20057020643 A KR20057020643 A KR 20057020643A KR 101144881 B1 KR101144881 B1 KR 101144881B1
- Authority
- KR
- South Korea
- Prior art keywords
- initiator
- polymerization
- temperature
- amount
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003999 initiator Substances 0.000 title claims abstract description 133
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 118
- 238000000034 method Methods 0.000 claims abstract description 63
- 239000000178 monomer Substances 0.000 claims abstract description 37
- 238000001816 cooling Methods 0.000 claims abstract description 22
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000084 colloidal system Substances 0.000 claims description 20
- 230000001681 protective effect Effects 0.000 claims description 19
- 238000010557 suspension polymerization reaction Methods 0.000 claims description 5
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 abstract description 20
- 150000002978 peroxides Chemical class 0.000 description 33
- 239000000203 mixture Substances 0.000 description 28
- 239000011541 reaction mixture Substances 0.000 description 17
- 239000004372 Polyvinyl alcohol Substances 0.000 description 13
- 229920002451 polyvinyl alcohol Polymers 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000002904 solvent Substances 0.000 description 9
- 239000006185 dispersion Substances 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 230000007062 hydrolysis Effects 0.000 description 7
- 238000006460 hydrolysis reaction Methods 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- 230000000977 initiatory effect Effects 0.000 description 6
- -1 ethylene, propylene, acrylonitrile Chemical class 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000002516 radical scavenger Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 2
- ZACVGCNKGYYQHA-UHFFFAOYSA-N 2-ethylhexoxycarbonyloxy 2-ethylhexyl carbonate Chemical compound CCCCC(CC)COC(=O)OOC(=O)OCC(CC)CCCC ZACVGCNKGYYQHA-UHFFFAOYSA-N 0.000 description 2
- HEEKCUUSDRHGAC-UHFFFAOYSA-N 7,7-dimethyl-2-(2,4,4-trimethylpentyl)octaneperoxoic acid Chemical compound CC(C)(C)CC(C)CC(C(=O)OO)CCCCC(C)(C)C HEEKCUUSDRHGAC-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- JHJSICJSIOGNMW-UHFFFAOYSA-N [2-(2,2-dimethylpropanoylperoxy)-4-methylpentan-2-yl] 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(CC(C)C)OOC(=O)C(C)(C)C JHJSICJSIOGNMW-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- BSVQJWUUZCXSOL-UHFFFAOYSA-N cyclohexylsulfonyl ethaneperoxoate Chemical compound CC(=O)OOS(=O)(=O)C1CCCCC1 BSVQJWUUZCXSOL-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 150000001451 organic peroxides Chemical class 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 239000012966 redox initiator Substances 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- NMOALOSNPWTWRH-UHFFFAOYSA-N tert-butyl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C NMOALOSNPWTWRH-UHFFFAOYSA-N 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- MVELOSYXCOVILT-UHFFFAOYSA-N (4-hydroxy-2-methylpentan-2-yl) 7,7-dimethyloctaneperoxoate Chemical compound CC(O)CC(C)(C)OOC(=O)CCCCCC(C)(C)C MVELOSYXCOVILT-UHFFFAOYSA-N 0.000 description 1
- HXDFVLSNQZTNEL-UHFFFAOYSA-N 2,2-dimethylpropanoyl hexaneperoxoate Chemical compound CCCCCC(=O)OOC(=O)C(C)(C)C HXDFVLSNQZTNEL-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- RAWISQFSQWIXCW-UHFFFAOYSA-N 2-methylbutan-2-yl 2,2-dimethyloctaneperoxoate Chemical compound CCCCCCC(C)(C)C(=O)OOC(C)(C)CC RAWISQFSQWIXCW-UHFFFAOYSA-N 0.000 description 1
- AQKYLAIZOGOPAW-UHFFFAOYSA-N 2-methylbutan-2-yl 2,2-dimethylpropaneperoxoate Chemical compound CCC(C)(C)OOC(=O)C(C)(C)C AQKYLAIZOGOPAW-UHFFFAOYSA-N 0.000 description 1
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical group CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- SLKKSLOWRYKYDZ-UHFFFAOYSA-N CC(=C)C(=O)OOOC(=O)C(C)(C)C Chemical compound CC(=C)C(=O)OOOC(=O)C(C)(C)C SLKKSLOWRYKYDZ-UHFFFAOYSA-N 0.000 description 1
- 229920005682 EO-PO block copolymer Polymers 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- 101100409194 Rattus norvegicus Ppargc1b gene Proteins 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 239000004147 Sorbitan trioleate Substances 0.000 description 1
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- CVFDGOLLFYUDSK-UHFFFAOYSA-N bis[(2-methylpropan-2-yl)oxy] ethanediperoxoate Chemical compound CC(C)(C)OOOC(=O)C(=O)OOOC(C)(C)C CVFDGOLLFYUDSK-UHFFFAOYSA-N 0.000 description 1
- NSGQRLUGQNBHLD-UHFFFAOYSA-N butan-2-yl butan-2-yloxycarbonyloxy carbonate Chemical compound CCC(C)OC(=O)OOC(=O)OC(C)CC NSGQRLUGQNBHLD-UHFFFAOYSA-N 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000012674 dispersion polymerization Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- UPWGQKDVAURUGE-UHFFFAOYSA-N glycerine monooleate Natural products CCCCCCCCC=CCCCCCCCC(=O)OC(CO)CO UPWGQKDVAURUGE-UHFFFAOYSA-N 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- VNJISVYSDHJQFR-UHFFFAOYSA-N tert-butyl 4,4-dimethylpentaneperoxoate Chemical compound CC(C)(C)CCC(=O)OOC(C)(C)C VNJISVYSDHJQFR-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
- C08F4/38—Mixtures of peroxy-compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Polymerization Catalysts (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03076390 | 2003-05-01 | ||
| EP03076390.8 | 2003-05-01 | ||
| PCT/EP2004/004500 WO2004096871A1 (en) | 2003-05-01 | 2004-04-27 | Increased polymerization reactor output by using a specific initiator system |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20060015564A KR20060015564A (ko) | 2006-02-17 |
| KR101144881B1 true KR101144881B1 (ko) | 2012-05-14 |
Family
ID=33395907
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020057020643A Expired - Lifetime KR101144881B1 (ko) | 2003-05-01 | 2004-04-27 | 특정 개시제 시스템을 사용함으로써 중합 반응기 생성량을증가시키는 방법 |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US8283431B2 (enExample) |
| EP (1) | EP1618137B1 (enExample) |
| JP (1) | JP4896709B2 (enExample) |
| KR (1) | KR101144881B1 (enExample) |
| CN (1) | CN100347203C (enExample) |
| AT (1) | ATE398143T1 (enExample) |
| AU (1) | AU2004234056B2 (enExample) |
| BR (1) | BRPI0409857B1 (enExample) |
| CA (1) | CA2524135C (enExample) |
| DE (1) | DE602004014359D1 (enExample) |
| ES (1) | ES2307011T3 (enExample) |
| MX (1) | MXPA05011727A (enExample) |
| MY (1) | MY136934A (enExample) |
| NO (1) | NO333033B1 (enExample) |
| PL (1) | PL1618137T3 (enExample) |
| RU (1) | RU2349603C2 (enExample) |
| SA (1) | SA04250201B1 (enExample) |
| TW (2) | TW200424217A (enExample) |
| WO (1) | WO2004096871A1 (enExample) |
| ZA (1) | ZA200509705B (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7173095B2 (en) † | 2003-06-20 | 2007-02-06 | Akzo Nobel N. V. | Polymerization process involving the dosing initiators |
| KR101359595B1 (ko) | 2006-03-24 | 2014-02-07 | 아크조 노벨 엔.브이. | 비닐 클로라이드 (코)폴리머의 연속 제조 방법 |
| BRPI0709144B1 (pt) * | 2006-03-24 | 2018-03-13 | Akzo Nobel Chemicals International B.V. | Processo de polimerização |
| EP1852418A1 (en) | 2006-04-27 | 2007-11-07 | Arkema France | Process for synthesizing selected organic peroxides |
| EP1849804A1 (en) * | 2006-04-27 | 2007-10-31 | Arkema France | Process of free-radical polymerization or crosslinking in the presence of an organic peroxide by an ex situ process |
| KR100899985B1 (ko) * | 2006-06-12 | 2009-05-28 | 주식회사 엘지화학 | 현탁 중합에 의한 염화 비닐계 중합체의 제조 방법 |
| KR100983702B1 (ko) * | 2006-08-22 | 2010-09-24 | 주식회사 엘지화학 | 가공성이 우수한 염화비닐계 중합체의 제조방법 |
| DE102008008421B4 (de) | 2008-02-09 | 2014-06-26 | Celanese Emulsions Gmbh | Verfahren zur Herstellung von Polymerdispersionen, die damit enthaltenen Dispersionen und deren Verwendung |
| EP2462114B1 (en) | 2009-08-06 | 2014-03-12 | Akzo Nobel Chemicals International B.V. | Storage stable and safe peroxide emulsions with a high active oxygen content |
| AR081664A1 (es) | 2010-06-30 | 2012-10-10 | Akzo Nobel Chemicals Int Bv | Proceso de polimerizacion con formacion in-situ del iniciador |
| EP3708591A1 (de) | 2019-03-15 | 2020-09-16 | Hilti Aktiengesellschaft | Beschleuniger-kombination |
| CN111718439A (zh) * | 2020-06-19 | 2020-09-29 | 宁波南大光电材料有限公司 | 甲基丙烯酸树脂及其制备方法和应用 |
| CN120435503A (zh) | 2022-12-20 | 2025-08-05 | 伊诺韦恩欧洲有限公司 | 使用引发剂和活性控制剂的混合物在水性悬浮液中制备pvc的方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4727110A (en) | 1984-04-19 | 1988-02-23 | Union Carbide Corporation | Process for the polymerization of shear-stable water-in-oil emulsions |
| JPH0782304A (ja) * | 1993-09-13 | 1995-03-28 | Shin Etsu Chem Co Ltd | 塩化ビニル系重合体の製造方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3451985A (en) | 1964-03-26 | 1969-06-24 | Monsanto Co | Method of polymerizing vinyl monomers |
| US3778422A (en) * | 1971-05-17 | 1973-12-11 | Tenneco Chem | Process for the production of vinyl halide polymers |
| DE3029211A1 (de) * | 1980-08-01 | 1982-03-18 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von polymerisaten des vinylchlorids |
| EP0096365A1 (en) * | 1982-06-07 | 1983-12-21 | Air Products And Chemicals, Inc. | Shortened reaction cycle times in vinyl chloride-propylene copolymerization |
| JP3326956B2 (ja) * | 1994-04-05 | 2002-09-24 | 三菱化学株式会社 | 塩化ビニル系重合体の製造方法 |
| JP3388528B2 (ja) * | 1994-12-15 | 2003-03-24 | 信越化学工業株式会社 | ビニル系重合体の製造方法 |
| JPH09157308A (ja) * | 1995-07-05 | 1997-06-17 | Shin Etsu Chem Co Ltd | 塩化ビニル系重合体の製造方法 |
| RU2155775C2 (ru) * | 1998-06-22 | 2000-09-10 | ОАО "Капролактам" | Способ суспензионной полимеризации винилхлорида |
| PL200423B1 (pl) * | 1998-09-21 | 2009-01-30 | Akzo Nobel Nv | Sposób (ko)polimeryzacji chlorku winylu i (ko)polimer chlorku winylu |
| US6274690B1 (en) * | 1999-08-11 | 2001-08-14 | Shin-Etsu Chemical Co., Ltd. | Preparation of vinyl chloride polymer |
| CA2470817C (en) * | 2001-12-21 | 2011-03-15 | Akzo Nobel Nv | Addition of organic initiators during the pressure drop in vinyl chloride monomer polymerization reactions |
| UA77245C2 (uk) * | 2001-12-21 | 2006-11-15 | Акцо Нобель Н.В. | Спосіб полімеризації суміші, яка містить вінілхлоридний мономер |
| PL371628A1 (en) * | 2002-04-12 | 2005-06-27 | Akzo Nobel N.V. | Co-metering of organic initiators and protective colloids during polymerization reactions |
-
2003
- 2003-06-10 TW TW092115675A patent/TW200424217A/zh unknown
-
2004
- 2004-04-27 PL PL04729652T patent/PL1618137T3/pl unknown
- 2004-04-27 EP EP04729652A patent/EP1618137B1/en not_active Expired - Lifetime
- 2004-04-27 DE DE602004014359T patent/DE602004014359D1/de not_active Expired - Lifetime
- 2004-04-27 AT AT04729652T patent/ATE398143T1/de not_active IP Right Cessation
- 2004-04-27 AU AU2004234056A patent/AU2004234056B2/en not_active Ceased
- 2004-04-27 MX MXPA05011727A patent/MXPA05011727A/es active IP Right Grant
- 2004-04-27 ES ES04729652T patent/ES2307011T3/es not_active Expired - Lifetime
- 2004-04-27 CN CNB2004800117908A patent/CN100347203C/zh not_active Expired - Lifetime
- 2004-04-27 KR KR1020057020643A patent/KR101144881B1/ko not_active Expired - Lifetime
- 2004-04-27 BR BRPI0409857-9A patent/BRPI0409857B1/pt not_active IP Right Cessation
- 2004-04-27 RU RU2005137324/04A patent/RU2349603C2/ru active
- 2004-04-27 CA CA2524135A patent/CA2524135C/en not_active Expired - Fee Related
- 2004-04-27 US US10/553,971 patent/US8283431B2/en active Active
- 2004-04-27 JP JP2006505306A patent/JP4896709B2/ja not_active Expired - Lifetime
- 2004-04-27 WO PCT/EP2004/004500 patent/WO2004096871A1/en not_active Ceased
- 2004-04-30 MY MYPI20041652A patent/MY136934A/en unknown
- 2004-05-03 TW TW093112405A patent/TWI346668B/zh not_active IP Right Cessation
- 2004-07-03 SA SA04250201A patent/SA04250201B1/ar unknown
-
2005
- 2005-11-30 NO NO20055661A patent/NO333033B1/no not_active IP Right Cessation
- 2005-11-30 ZA ZA200509705A patent/ZA200509705B/en unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4727110A (en) | 1984-04-19 | 1988-02-23 | Union Carbide Corporation | Process for the polymerization of shear-stable water-in-oil emulsions |
| JPH0782304A (ja) * | 1993-09-13 | 1995-03-28 | Shin Etsu Chem Co Ltd | 塩化ビニル系重合体の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| NO333033B1 (no) | 2013-02-18 |
| CA2524135A1 (en) | 2004-11-11 |
| TWI346668B (en) | 2011-08-11 |
| MXPA05011727A (es) | 2006-01-23 |
| RU2349603C2 (ru) | 2009-03-20 |
| BRPI0409857B1 (pt) | 2014-12-02 |
| CA2524135C (en) | 2012-07-24 |
| US8283431B2 (en) | 2012-10-09 |
| EP1618137B1 (en) | 2008-06-11 |
| PL1618137T3 (pl) | 2008-11-28 |
| TW200500380A (en) | 2005-01-01 |
| CN1780861A (zh) | 2006-05-31 |
| JP4896709B2 (ja) | 2012-03-14 |
| WO2004096871A1 (en) | 2004-11-11 |
| ATE398143T1 (de) | 2008-07-15 |
| DE602004014359D1 (de) | 2008-07-24 |
| TW200424217A (en) | 2004-11-16 |
| AU2004234056A1 (en) | 2004-11-11 |
| BRPI0409857A (pt) | 2006-05-16 |
| RU2005137324A (ru) | 2006-05-27 |
| JP2006525389A (ja) | 2006-11-09 |
| MY136934A (en) | 2008-11-28 |
| CN100347203C (zh) | 2007-11-07 |
| ES2307011T3 (es) | 2008-11-16 |
| AU2004234056B2 (en) | 2008-10-02 |
| NO20055661L (no) | 2005-11-30 |
| ZA200509705B (en) | 2006-12-27 |
| SA04250201B1 (ar) | 2009-02-07 |
| KR20060015564A (ko) | 2006-02-17 |
| US20060149014A1 (en) | 2006-07-06 |
| EP1618137A1 (en) | 2006-01-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US8367784B2 (en) | Continuous dosing of extremely fast initiators during polymerization reactions | |
| KR101144881B1 (ko) | 특정 개시제 시스템을 사용함으로써 중합 반응기 생성량을증가시키는 방법 | |
| JP2012052134A (ja) | 重合反応中の非常に速い開始剤の連続的配量 | |
| RU2295540C2 (ru) | Совместное введение органических инициаторов и защитных коллоидов в ходе проведения реакций полимеризации | |
| EP1375529A1 (en) | Addition of organic initiators during a pressure drop in vinyl chloride monomer polymerization reactions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
Patent event date: 20051031 Patent event code: PA01051R01D Comment text: International Patent Application |
|
| PG1501 | Laying open of application | ||
| A201 | Request for examination | ||
| AMND | Amendment | ||
| PA0201 | Request for examination |
Patent event code: PA02012R01D Patent event date: 20090326 Comment text: Request for Examination of Application |
|
| E902 | Notification of reason for refusal | ||
| PE0902 | Notice of grounds for rejection |
Comment text: Notification of reason for refusal Patent event date: 20110315 Patent event code: PE09021S01D |
|
| AMND | Amendment | ||
| E601 | Decision to refuse application | ||
| PE0601 | Decision on rejection of patent |
Patent event date: 20111123 Comment text: Decision to Refuse Application Patent event code: PE06012S01D Patent event date: 20110315 Comment text: Notification of reason for refusal Patent event code: PE06011S01I |
|
| AMND | Amendment | ||
| J201 | Request for trial against refusal decision | ||
| PJ0201 | Trial against decision of rejection |
Patent event date: 20111222 Comment text: Request for Trial against Decision on Refusal Patent event code: PJ02012R01D Patent event date: 20111123 Comment text: Decision to Refuse Application Patent event code: PJ02011S01I Appeal kind category: Appeal against decision to decline refusal Decision date: 20120223 Appeal identifier: 2011101010072 Request date: 20111222 |
|
| PB0901 | Examination by re-examination before a trial |
Comment text: Amendment to Specification, etc. Patent event date: 20111222 Patent event code: PB09011R02I Comment text: Request for Trial against Decision on Refusal Patent event date: 20111222 Patent event code: PB09011R01I Comment text: Amendment to Specification, etc. Patent event date: 20110516 Patent event code: PB09011R02I Comment text: Amendment to Specification, etc. Patent event date: 20090326 Patent event code: PB09011R02I |
|
| B701 | Decision to grant | ||
| PB0701 | Decision of registration after re-examination before a trial |
Patent event date: 20120223 Comment text: Decision to Grant Registration Patent event code: PB07012S01D Patent event date: 20120201 Comment text: Transfer of Trial File for Re-examination before a Trial Patent event code: PB07011S01I |
|
| GRNT | Written decision to grant | ||
| PR0701 | Registration of establishment |
Comment text: Registration of Establishment Patent event date: 20120503 Patent event code: PR07011E01D |
|
| PR1002 | Payment of registration fee |
Payment date: 20120503 End annual number: 3 Start annual number: 1 |
|
| PG1601 | Publication of registration | ||
| FPAY | Annual fee payment |
Payment date: 20150424 Year of fee payment: 4 |
|
| PR1001 | Payment of annual fee |
Payment date: 20150424 Start annual number: 4 End annual number: 4 |
|
| FPAY | Annual fee payment |
Payment date: 20160422 Year of fee payment: 5 |
|
| PR1001 | Payment of annual fee |
Payment date: 20160422 Start annual number: 5 End annual number: 5 |
|
| FPAY | Annual fee payment |
Payment date: 20170424 Year of fee payment: 6 |
|
| PR1001 | Payment of annual fee |
Payment date: 20170424 Start annual number: 6 End annual number: 6 |
|
| FPAY | Annual fee payment |
Payment date: 20180424 Year of fee payment: 7 |
|
| PR1001 | Payment of annual fee |
Payment date: 20180424 Start annual number: 7 End annual number: 7 |
|
| FPAY | Annual fee payment |
Payment date: 20190423 Year of fee payment: 8 |
|
| PR1001 | Payment of annual fee |
Payment date: 20190423 Start annual number: 8 End annual number: 8 |
|
| PR1001 | Payment of annual fee |
Payment date: 20200428 Start annual number: 9 End annual number: 9 |
|
| PR1001 | Payment of annual fee |
Payment date: 20210504 Start annual number: 10 End annual number: 10 |
|
| PC1801 | Expiration of term |
Termination date: 20241027 Termination category: Expiration of duration |