KR101053345B1 - High strength cold rolled steel sheet with excellent surface and hardening properties and its manufacturing method - Google Patents

Abstract

The present invention relates to a cold rolled steel sheet having a high yield strength, a high bake hardening value, a high yield strength after a bake, excellent workability and secondary workability, and excellent surface quality due to no surface defects. .

Cold rolled steel sheet of the present invention by weight, C: 0.0005 ~ 0.004%, Mn: 0.2 ~ 0.8%, P: 0.005 ~ 0.2%, S: 0.003 ~ 0.02%, Al: 0.01 ~ 0.08%, N: 0.004 ~ 0.02 %, Cu: 0.005 ~ 0.2%, the content of Mn, Cu, S is 0.27 * (Mn + Cu) / S: 5 ~ 25, the content of Al, N is 0.25 * Al / N : 1 to 10, and is composed of the remaining Fe and unavoidable impurities, containing at least one precipitate selected from the group consisting of MnS, CuS, (Mn, Cu) S and AlN and the average size of the precipitate is less than 0.2㎛ Is made of.

In the method for manufacturing a cold rolled steel sheet of the present invention, after reheating a steel satisfying the above composition and conditions to a temperature of 1100 ° C. or more, hot rolling is performed at a finish rolling temperature of at least Ar ₃ , and then cooled at a speed of 300 ° C./min or more. After winding at a temperature of 750 ℃ or less, cold rolling and continuous annealing.

Cold Rolled Steel, Hardening Hardening, High Strength, Plastic Anisotropy, Tensile Strength, Elongation

Description

High strength cold rolled steel sheet with excellent surface and hardening properties and its manufacturing method {HIGH STRENGTH COLD ROLLED STEEL SHEET WITH EXCELLENT SURFACE PROPERTIES AND BAKE HARDENABILITY, AND METHOD FOR MANUFACTURING THE SAME}

The present invention relates to a high-strength cold-rolled steel sheet used in materials such as automobiles and a method for manufacturing the same, and more particularly, by adjusting the carbon content to an appropriate amount, controlling the amount of solid solution carbon in grains by controlling the distribution of fine precipitates, thereby providing excellent hardening characteristics. It relates to a high strength cold rolled steel sheet having a and a method of manufacturing the same.

In order to improve the dent resistance, exterior hardening type cold rolled steel sheets are frequently used for exterior materials such as automobiles. The hardened hardened cold rolled steel sheet has a high yield point by allowing an appropriate amount of solid solution carbon to remain in the steel sheet and using solidified heat at the time of coating to fix the dissolvable carbon produced at the time of press forming.

There are Al-Killed steel and IF steel (Interstitial Free Steel).

In the case of Al-Killed steel, which is an annealing material, small amount of solid carbon remains, and it has a hardening hardening capacity of about 10 ~ 20MPa after the baking treatment while securing the aging characteristics. The upper annealing material has disadvantages of low yield strength and low productivity after baking.

IF steel is a type of steel which has improved the formability by completely depositing carbon or nitrogen dissolved in steel by adding Ti and Nb. It is the hard hardening type IF steel that gives the hard hardening characteristic to the IF steel. The baking hardening type IF steel controls the adding amount of Ti or Nb and the adding amount of carbon so that an appropriate amount of carbon remains in the steel to give the baking hardening characteristic. In the case of small-hardening IF steel, in order to employ an appropriate amount of carbon, not only the amount of carbon but also the amount of Ti or Nb added, as well as the amount of S and N reacting with Ti or Nb to form precipitates, must be controlled in a very narrow range. It is difficult to secure stable quality, and when Ti or Nb is added, the recrystallization temperature is increased, so high temperature annealing is required, and expensive alloying elements must be added, thereby degrading economic efficiency.

Korean Patent Laid-Open Publication No. 2006-0115643 discloses a method having an advantage in terms of manufacturing cost by improving the hardening characteristic by using a fine precipitate, but there is a disadvantage in that the steel sheet surface defects occur.

The present invention provides a high strength cold rolled steel sheet and a method of manufacturing the same, which do not add Ti and Nb and have excellent baking hardening properties due to the control of solid solution carbon in the grains by the precipitate and do not cause surface defects.

Cold rolled steel sheet of the present invention in weight%, C: 0.0005 ~ 0.004%, Mn: 0.25 ~ 0.8%, P: 0.005 ~ 0.2%, S: 0.003 ~ 0.02%, Al: 0.01 ~ 0.08%, N: 0.004 ~ 0.02 %, Cu: 0.005 ~ 0.2%, the content of Mn, Cu, S is 0.27 * (Mn + Cu) / S: 5 ~ 25, the content of Al, N is 0.25 * Al / N : 1 to 10, and is composed of the remaining Fe and unavoidable impurities, containing at least one precipitate selected from the group consisting of MnS, CuS, (Mn, Cu) S and AlN and the average size of the precipitate is less than 0.2㎛ Is made of.

The method for producing a cold rolled steel sheet of the present invention by weight% C: 0.0005 ~ 0.004%, Mn: 0.25 ~ 0.8%, P: 0.005 ~ 0.2%, S: 0.003 ~ 0.02%, Al: 0.01 ~ 0.08%, N: 0.004 to 0.02%, Cu: 0.005 to 0.2%, the content of Mn, Cu, S is 0.27 * (Mn + Cu) / S: 5 to 25, and the content of Al, N is 0.25 * Al / N: satisfying 1 to 10, reheating the steel composed of the remaining Fe and unavoidable impurities to a temperature of 1100 ° C. or more, and then hot rolling the finishing rolling temperature to an Ar ₃ transformation point or more;

Cooling the hot rolled hot rolled steel sheet as described above at a rate of 300 ° C./min or more and winding the steel sheet at a temperature of 750 ° C. or less; And

Cold rolling and continuous annealing of the hot rolled steel sheet.

The cold rolled steel sheet provided according to the present invention has a higher yield strength than the steel sheet having the same tensile strength, has a high hardening value, and has a high yield strength after baking, and is excellent in workability and secondary work brittleness, and does not cause surface defects. Does not have excellent surface quality.

Hereinafter, the present invention will be described in detail (hereinafter by weight).

The present inventors have discovered the following new facts in the course of research for improving the baking hardening property without adding Ti and Nb. The finer distribution of the precipitates, while controlling the carbon content to an appropriate amount, increases the yield strength after baking in steels with high yield strength. This is based on the study that fine precipitates affect the amount of dissolved carbon in the grains.

As shown in FIG. 1, the finer the precipitates, the smaller the amount of dissolved carbon in the grains. In view of this fact, the present inventors confirmed that the carbon content of the cold rolled steel sheet was in the range of 0.0005 to 0.004% in consideration of the content of solid solution carbon in the grains controlled by the size of the precipitates, thereby achieving excellent bake hardening characteristics. Carbon is precipitated around the precipitates in the finely distributed grains, which do not cause aging at room temperature, but are believed to increase yield strength by dissolving carbon in the coating heat treatment. To this end, the carbon content is in the range of 0.0005 to 0.004%, and can be stably ensured when the average size of precipitates of MnS, CuS, (Mn, Cu) S and AlN is 0.2 μm or less.

Paying attention to these new facts, a study has been made to finely distribute MnS, CuS, (Mn, Cu) S and AlN. As a result, (1) the content of Mn, Cu, S was 0.27 * (Mn + Cu, while the content of Mn was 0.2-0.8%, the content of S 0.003-0.02%, and the content of Cu was 0.005-0.2%. ) / S: It is necessary to adjust to satisfy 5 to 25, (2) while the content of N to 0.004 to 0.02%, the content of Al to 0.01 to 0.08%, the content of Al, N to the following conditions 0.25 * Al / N: By adjusting to satisfy 1 ~ 10, the grain size can be made finer. (3) With this, if the cooling rate is over 300 ℃ / min after hot rolling, MnS, CuS, (Mn The average size of the precipitates of Cu, S and AlN is less than 0.2 µm.

As such, by adjusting the content of carbon and the size of precipitates according to the present invention, the secondary processing brittleness is also excellent while securing the hardening hardening property. When the precipitate becomes fine, an appropriate amount of carbon remains in the grain boundary and the grain boundary is strengthened, thereby preventing brittle fracture caused by the weak grain boundary after processing. Furthermore, the present inventors confirmed that in the distribution of MnS, CuS, and (Mn, Cu) S precipitates, fine precipitates are uniformly distributed as MnS and CuS are more uniform than Mn and Cu composite precipitates, resulting in better processability. . In other words, when the value of 0.27 * (Mn + Cu) / S is in the range of 5 to 20, as the number of single precipitates of MnS and CuS increases, the number of distributions of precipitates increases as the number of single precipitates of (Mn, Cu) S increases. Improves.

Hereinafter, the composition range of the present invention will be described in detail.

The content of carbon (C) is 0.0005 to 0.004%. In the present invention, while the amount of carbon dissolved in the grains is reduced by the fine precipitates, the amount of hardening of the baking is reduced by that much. That is, as the total carbon content in the steel sheet increases, the content of carbon segregating around the grain boundaries or precipitates where grain hardening properties are more effective than in the grains increases. Considering this, the carbon content is set to 0.0005 to 0.004%. If the content of C is less than 0.0005%, the amount of hardening of baking in steel is small, and if the content of C is more than 0.004%, the moldability decreases rapidly.

The content of manganese (Mn) is 0.2 to 0.8%. Mn is known as an element that precipitates solid solution sulfur in steel as MnS to prevent hot shortness caused by solid solution sulfur. In the present invention, when the content of manganese and sulfur is appropriate, very fine MnS is precipitated, and carbon is precipitated around the precipitate, and the precipitated carbon is dissolved in the coating baking treatment to improve yield strength. The content of manganese is limited to 0.2 to 0.8%. If the content of Mn is less than 0.2%, the amount of S remaining in solid solution increases, so the amount of FeS generated during reheating increases, which increases the probability of surface defects. When the content of manganese is 0.2% or more to achieve the above effects, there is no surface defects. When the content of manganese exceeds 0.8%, the content of manganese is high and coarse MnS precipitates are generated, which results in poor hardening characteristics.

The content of phosphorus (P) is 0.005 to 0.2%. Phosphorus is an element having a high solid solution strengthening effect and a small decrease in the r value (plastic anisotropy index), which guarantees high strength in steels for controlling precipitates according to the present invention. When the content of phosphorus is more than 0.005% to secure the strength, but exceeds 0.2% ductility is reduced.

The content of sulfur (S) is 0.003 to 0.02%. If the content of sulfur is less than 0.003%, not only the amount of MnS, CuS, (Mn, Cu) S precipitates are small, but the precipitates are very coarse in size, so that the hardening hardening property is not good. When the content of sulfur exceeds 0.02%, the content of solute is high, so the ductility and moldability are greatly lowered, and there is a problem of red brittleness.

The content of aluminum (Al) is 0.01 to 0.08%. Aluminum is an element added as a deoxidizer, but in the present invention, nitrogen is added in steel to prevent formability deterioration due to solid nitrogen. If the content of aluminum is less than 0.01%, the amount of solid solution is high, so that the moldability is not good. If the content of aluminum is more than 0.08%, the amount of aluminum is present in the solid solution state, the ductility is reduced.

The content of nitrogen (N) is made 0.004 to 0.02%. Nitrogen serves to refine the grains by causing the AlN precipitate to precipitate in the steel. If the content of nitrogen is less than 0.004%, the number of AlN precipitates is small and the effect of miniaturization is small. If the content of nitrogen exceeds 0.02%, the amount of Al added to precipitate solid solution N is too high, which may cause other defects and the number of AlN precipitates. As the size increases, the size increases at the same time, so there is no meaning to add more, so the upper limit is made 0.02%.

The content of copper (Cu) is 0.005 to 0.2%. Copper forms precipitates of less than 0.2㎛ when the ratio of Cu and S content and the cooling rate before winding in the hot rolling process is appropriate, and carbon precipitates around the precipitates, and the precipitated carbon is dissolved and yielded during the coating baking process. Add 0.005-0.2% based on the study of increasing strength. If the content of copper is 0.005% or more, it can be finely precipitated, and if it exceeds 0.2%, it is coarse precipitated, resulting in poor aging characteristics.

Cold rolled steel sheet of the present invention may further include molybdenum (Mo). The content of Mo is preferably 0.01 to 0.2%. Mo is added as an element to increase the plastic anisotropy index, the content of the plastic anisotropy index becomes larger when the content is 0.01% or more, and when the content exceeds 0.2%, the plastic anisotropy index does not increase any more and has a disadvantage of causing hot brittleness.

The cold rolled steel sheet of the present invention may further include silicon (Si). The content of Si is preferably 0.02 to 0.6%. Si is a solid solution strengthening element of steel, which has lower elongation reduction rate compared with other elements, and has excellent powdering properties when plating, but when it is added in excess of 0.6%, the amount of red scale is large, and the pickling property deteriorates rapidly. As the surface defects increased, the upper limit was set to 0.6%, and the lower limit was set to 0.02% because the strengthening effect and the powdering property were not improved when added below 0.02%.

The remainder is composed of Fe and other unavoidable impurities.

The content of Mn, Cu and S satisfies 0.27 * (Mn + Cu) / S: 5-25.

S is combined with Mn and Cu to be precipitated as MnS, CuS, (Mn, Cu) S, and the precipitates vary depending on the amount of Mn, Cu, and S added, resulting in hardening hardening properties, secondary processing brittleness, and plastic anisotropy index. This affects the in-plane anisotropy index. Therefore, effective precipitates are obtained when 0.27 * (Mn + Cu) / S is 5 or more, and when it exceeds 25, the precipitates are coarse, and the characteristics of the hardening hardening property, plastic anisotropy index, and in-plane anisotropy index are deteriorated.

In addition, the content of Al and N satisfies 0.52 * Al / N: 1-10.

N binds to Al and precipitates as AlN, which affects the hardening hardening properties, secondary processing properties, and plastic anisotropy index depending on the content of Al and N. Therefore, effective precipitates are obtained when 0.52 * Al / N is 1 or more, and when it exceeds 10, solid solution N remains, and the plastic anisotropy index is not good, and the hardening hardening property is too large, and the aging characteristics are not good.

The present invention includes one or more precipitates selected from the group consisting of MnS, CuS, (Mn, Cu) S and AlN in addition to the above component range, and the average size of the precipitates is 0.2 μm or less. In the present invention, the size of MnS, CuS, (Mn, Cu) S and AlN precipitates directly affects the hardening characteristics, secondary processing brittleness, plastic anisotropy index, and in-plane anisotropy index, and the average size of these precipitates is 0.2 When it exceeds micrometer, especially the baking hardening characteristic is not good, secondary work brittleness, plastic anisotropy index, and in-plane anisotropy index become bad.

Hereinafter, the manufacturing method of the cold rolled steel sheet of this invention is demonstrated in detail.

The present invention is characterized by satisfying the average size of MnS, CuS, (Mn, Cu) S and AlN precipitates in a cold rolled steel sheet through hot rolling and cold rolling of steels satisfying the composition. The average size of these precipitates in the cold rolled steel sheet is affected by the conditions of addition amount, manufacturing process such as reheating temperature, winding temperature, etc., and especially by the cooling rate after hot rolling.

First, the steel satisfying the composition is reheated and hot rolled. As for reheating temperature, 1100 degreeC or more is preferable. This is because when the reheating temperature is lower than 1100 ° C., the reheating temperature is low so that the coarse CuS generated during continuous casting is not completely dissolved, and thus many coarse precipitates remain after hot rolling.

Finish rolling temperature of the hot rolling is carried out in more than Ar ₃ transformation temperature. If the finish rolling temperature is less than the Ar ₃ transformation temperature, not only the workability is degraded due to the formation of the rolled grain, but also the ductility is greatly reduced.

After the hot rolling, the cooling rate before winding is set at 300 ° C / min or more. Even if 0.27 * (Mn + Cu) / S satisfies 5 to 25 according to the present invention, if the cooling rate is less than 300 ° C./min, the average size of precipitates exceeds 0.2 μm. That is, as the cooling rate increases, a large number of nuclei are generated and the precipitate becomes fine. The faster the cooling rate, the finer the precipitate becomes, so it is not necessary to limit the upper limit of the cooling rate. However, if the cooling rate exceeds 1000 ° C / min, the effect of refining the precipitate no longer increases, so the cooling rate is 300 ~ 1000 ° C / min. It is more preferable to set it as.

Although winding is performed after the said cooling, winding temperature is made into 750 degreeC or less. If the coiling temperature exceeds 750 ° C., precipitates grow too coarsely, resulting in poor baking hardening. It is more preferable to wind up in the temperature range of 550-750 degreeC.

Cold rolling is performed after winding, but cold rolling is performed at a reduction ratio of 30% or more. If the cold reduction rate is less than 30%, since the annealing recrystallization nucleation amount is small, the crystal grains grow too large during annealing, and the strength and formability are lowered by coarsening of the annealing recrystallization grains.

After cold rolling, continuous annealing is performed. Temperature during continuous annealing plays an important role in determining the material of cold rolled steel sheet. In the present invention, the continuous annealing is preferably carried out at a temperature range of 500 ~ 900 ℃. If the continuous annealing temperature is less than 500 ° C., recrystallization is not completed and the target ductility value cannot be secured. If the continuous annealing temperature is higher than 900 ° C., there is a problem that the strength decreases due to coarsening of the recrystallized grains.

The continuous annealing time keeps the recrystallization complete. If it is about 10 seconds or more, the recrystallization is completed. More preferably, it is within the range of 10 second-30 minutes.

Hereinafter, the present invention will be described in more detail with reference to the following examples.

(Example)

The steel slabs having the component ranges shown in Table 1 were reheated at 1200 ° C., hot finished rolled, cooled at a rate of 600 ° C./min, and wound up at 650 ° C. The hot finish rolling temperature at this time was 910 degreeC which is more than Ar3 transformation point, and continuous annealing was performed by heating at 700 degreeC for 40 second at the speed of 10 degreeC / sec.

Table 2 shows the mechanical properties of the cold rolled steel sheet thus obtained. In order to investigate the mechanical properties of the cold rolled steel sheet was processed into a standard specimen according to ASTM E-8 standard, the specimen using a tensile tester (INSTRON, Model 6025)

Yield strength, tensile strength, elongation and plastic anisotropy index (r _m value) were measured. Where r _m = (r ₀ + 2r ₄₅ + r ₉₀ ) / 4. The quench hardening property was measured by applying 2% strain to the specimen and heat-treating at 170 ° C for 20 minutes, then measuring the yield yield of the specimen and subtracting the original yield strength value from the measured yield strength value to the quench hardening index (BH). It is shown. In addition, in order to determine the secondary brittleness, the transition temperature (Ductile Brittle Transition Temperature, DBTT) was measured, and the surface defects were visually checked.

River
Composition range (% by weight) 0.27 * (Mn + Cu) / S 0.52 * Al / N C Mn P S Cu Al N Etc Inventive Steel 1 0.0033 0.25 0.009 0.009 0.06 0.036 0.0062 - 9.30 3.02 Inventive Steel 2 0.0016 0.36 0.03 0.008 0.09 0.046 0.0083 - 15.19 2.88 Invention Steel 3 0.0027 0.49 0.059 0.012 0.11 0.052 0.0075 - 13.50 3.61 Inventive Steel 4 0.001 0.71 0.096 0.007 0.09 0.063 0.0122 - 30.86 2.69 Inventive Steel 5 0.0014 0.65 0.081 0.011 0.11 0.042 0.0093 Mo: 0.04 18.65 2.35 Comparative Steel 1 0.0014 0.06 0.047 0.014 0.09 0.036 0.0074 - 2.89 2.53 Comparative Steel 2 0.0063 0.12 0.045 0.021 0.11 0.033 0.0063 - 2.96 2.72 Comparative Steel 3 0.0028 0.4 0.07 0.01 0 0.04 0.0016 Ti: 0.022 10.80 13.00 Comparative Steel 4 0.0028 0.4 0.07 0.01 0 0.04 0.0016 Ti: 0.022 10.80 13.00

River Yield strength
(MPa) The tensile strength
(MPa) Elongation
(%) Plastic Anisotropy Index (r _m ) Secondary processing
Brittle
(DBTT- ℃) Sobu Hardening Index
(MPa) Surface Defects Average size of precipitate
(Μm) Inventive Steel 1 192 302 48 1.72 -40 52 No occurrence 0.07 Inventive Steel 2 220 352 41 1.71 -50 47 No occurrence 0.09 Invention Steel 3 259 399 39 1.69 -40 46 No occurrence 0.11 Inventive Steel 4 311 462 32 1.58 -30 39 No occurrence 0.15 Inventive Steel 5 309 461 32 1.63 -40 43 No occurrence 0.16 Comparative Steel 1 193 346 39 1.72 -40 32 Occur 0.07 Comparative Steel 2 228 359 35 1.43 -50 71 Occur 0.09 Comparative Steel 3 279 402 31 1.39 -10 39 No occurrence 0.38 Comparative Steel 4 202 345 40 1.83 0 32 No occurrence 0.38

Inventive steels 1 to 5 in Tables 1 and 2 are precipitates having a size of 0.2 μm or less, high strength, a hardening characteristic of 30 MPa or more, excellent workability, and no surface defects.

Comparative steel 1, however, had an average size of precipitates of 0.2 μm or less, high strength, and had a quench hardening characteristic of 30 MPa or more, but had a low Mn content and a low 0.27 * (Mn + Cu) / S value, resulting in surface defects. Comparative steel 2 has a high carbon content and a low elongation and plastic anisotropy index, which is highly likely to cause breakage during molding, and a surface defect occurs due to a low Mn content.

Comparative steel 3 has a higher yield strength than that of the inventive steel in the same tensile strength class, a very low elongation and plastic anisotropy index, and is likely to break during molding. In the case of Ti-added IF steel, it is difficult to secure formability at the same annealing temperature due to the high recrystallization temperature, and it is very disadvantageous in terms of cost because of annealing at a higher temperature. Comparative steel 4 is composed of the same components as Comparative steel 3 and is annealed at a higher temperature of 830 ° C. The yield strength is lower and the quench hardening value is lower than that of the same tensile strength. In addition, due to the high temperature of Ductile Brittle Transition Temperature (DBTT), which is known as the secondary work brittleness evaluation scale, fracture may occur after molding processing in extreme regions.

1 is a graph showing the change in the amount of solid solution carbon in the grain with respect to the size of the precipitate.

Claims (6)

In weight%, C: 0.0005-0.004%, Mn: 0.25-0.8%, P: 0.005-0.2%, S: 0.003-0.02%, Al: 0.01-0.08%, N: 0.004-0.02%, Cu: 0.005- 0.2%, the content of Mn, Cu, S is 0.27 * (Mn + Cu) / S: 5 to 25, and the content of Al, N is 0.25 * Al / N: 1 to 10 It is composed of the remaining Fe and unavoidable impurities, and comprises at least one precipitate selected from the group consisting of MnS, CuS, (Mn, Cu) S and AlN and the surface characteristics characterized in that the average size of the precipitate is 0.2㎛ or less And high strength cold rolled steel sheet having excellent hardening properties. The high strength cold rolled steel sheet having excellent surface and baking hardening characteristics according to claim 1, wherein the composition further comprises one or two types of Mo: 0.01 to 0.2% and Si: 0.02 to 0.6%. In weight%, C: 0.0005-0.004%, Mn: 0.25-0.8%, P: 0.005-0.2%, S: 0.003-0.02%, Al: 0.01-0.08%, N: 0.004-0.02%, Cu: 0.005- 0.2%, the content of Mn, Cu, S is 0.27 * (Mn + Cu) / S: 5 to 25, and the content of Al, N is 0.25 * Al / N: 1 to 10 And reheating the steel composed of the remaining Fe and unavoidable impurities to a temperature of 1100 ° C. or higher and then hot rolling the finishing rolling temperature to an Ar ₃ transformation point or more; Cooling the hot rolled hot rolled steel sheet as described above at a rate of 300 ° C./min or more and winding at a temperature of 750 ° C. or less; And Cold rolling and continuously annealing the hot rolled steel sheet; Method for producing a high strength cold rolled steel sheet excellent in surface properties and baking hardening properties, characterized in that consisting of. The method of manufacturing a high strength cold rolled steel sheet having excellent surface properties and hardening hardening properties, characterized in that the composition further comprises one or two types of Mo: 0.01 to 0.2% and Si: 0.02 to 0.6%. . The method for producing a high strength cold rolled steel sheet having excellent surface properties and hardening hardening characteristics according to claim 3 or 4, wherein the cold rolling is performed at a rolling reduction of 30% or more. The method of claim 3 or 4, wherein the continuous annealing is performed for 10 seconds or more in a temperature range of 500 to 900 ° C.

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