KR101008192B1 - 다수의 필름층을 포함하는 형광 제품 - Google Patents
다수의 필름층을 포함하는 형광 제품 Download PDFInfo
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- KR101008192B1 KR101008192B1 KR1020047017527A KR20047017527A KR101008192B1 KR 101008192 B1 KR101008192 B1 KR 101008192B1 KR 1020047017527 A KR1020047017527 A KR 1020047017527A KR 20047017527 A KR20047017527 A KR 20047017527A KR 101008192 B1 KR101008192 B1 KR 101008192B1
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Images
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Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Laminated Bodies (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Optical Elements Other Than Lenses (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/135,537 | 2002-04-30 | ||
| US10/135,537 US7264880B2 (en) | 2002-04-30 | 2002-04-30 | Fluorescent articles having multiple film layers |
| US10/354,515 US7618709B2 (en) | 2002-04-30 | 2003-01-30 | Fluorescent articles having multiple film layers |
| US10/354,515 | 2003-01-30 | ||
| PCT/US2003/010842 WO2003093007A1 (en) | 2002-04-30 | 2003-04-09 | Fluorescent articles having multiple film layers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20050010777A KR20050010777A (ko) | 2005-01-28 |
| KR101008192B1 true KR101008192B1 (ko) | 2011-01-17 |
Family
ID=33566997
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020047017527A Expired - Lifetime KR101008192B1 (ko) | 2002-04-30 | 2003-04-09 | 다수의 필름층을 포함하는 형광 제품 |
Country Status (10)
| Country | Link |
|---|---|
| EP (2) | EP2620280B1 (enExample) |
| JP (1) | JP4610331B2 (enExample) |
| KR (1) | KR101008192B1 (enExample) |
| CN (1) | CN100542802C (enExample) |
| AU (1) | AU2003224896B2 (enExample) |
| BR (2) | BR0309587A (enExample) |
| CA (1) | CA2480526C (enExample) |
| ES (2) | ES2634117T3 (enExample) |
| MX (1) | MXPA04009520A (enExample) |
| RU (1) | RU2303622C2 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005002072A1 (de) * | 2005-01-14 | 2006-07-20 | Röhm GmbH & Co. KG | Witterungsstabile Folie zur Gelbeinfärbung retroreflektierender Formkörper |
| CA2629944C (en) * | 2005-10-27 | 2016-02-09 | Avery Dennison Corporation | Fluorescent article having multiple layers |
| US7674515B2 (en) * | 2006-10-23 | 2010-03-09 | Avery Dennison Corporation | Fluorescent polycarbonate articles |
| JP5252960B2 (ja) * | 2007-04-02 | 2013-07-31 | キヤノン株式会社 | 縮合環芳香族化合物及びこれを用いた有機発光素子 |
| JP4956313B2 (ja) * | 2007-07-23 | 2012-06-20 | 日本カーバイド工業株式会社 | 内部全反射型キューブコーナー型再帰反射物品 |
| KR100941440B1 (ko) * | 2008-03-31 | 2010-02-11 | 최상석 | 칼라가 제공되는 큐브코너형 재귀반사물 및 그 제조방법 |
| JP5408902B2 (ja) * | 2008-05-15 | 2014-02-05 | キヤノン株式会社 | ジベンゾ[c,g]フルオレン化合物及びそれを使用した有機発光素子 |
| JP5335284B2 (ja) * | 2008-05-22 | 2013-11-06 | キヤノン株式会社 | 縮合多環化合物およびそれを有する有機発光素子 |
| US8322868B2 (en) * | 2009-05-12 | 2012-12-04 | Avery Dennison Corporation | Durable fluorescent articles having multiple film layers |
| US9746591B2 (en) * | 2013-03-12 | 2017-08-29 | Aura Optical Systems, Lp | Multi-layer microprismatic retroreflective sheeting and method of manufacturing the same |
| NL2013295B1 (en) * | 2013-08-02 | 2016-05-18 | Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno | A coating composition comprising a dye and a method to detect moisture in objects. |
| JPWO2020022063A1 (ja) * | 2018-07-23 | 2021-08-05 | 三菱ケミカル株式会社 | 再帰反射シート用アクリル樹脂フィルムおよび再帰反射シート |
| EP4010743A1 (en) | 2019-08-05 | 2022-06-15 | Avery Dennison Corporation | Retroreflective films comprising fluorescent dyes |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2300596A (en) * | 1995-05-10 | 1996-11-13 | Portals Ltd | Fluorescent security feature for cheques and banknotes |
| KR19990063719A (ko) * | 1995-09-29 | 1999-07-26 | 스프레이그 로버트 월터 | 형광 염료 배합물 |
| KR20000048695A (ko) * | 1996-09-30 | 2000-07-25 | 스프레이그 로버트 월터 | 형광성 레전드를 갖는 재귀반사 그래픽 물품과 그 제조 방법 |
| JP2001174809A (ja) * | 1999-12-15 | 2001-06-29 | Asahi Kasei Corp | 面状偏光発光体 |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2407680A (en) | 1945-03-02 | 1946-09-17 | Minnesota Mining & Mfg | Reflex light reflector |
| US3190178A (en) | 1961-06-29 | 1965-06-22 | Minnesota Mining & Mfg | Reflex-reflecting sheeting |
| US3810804A (en) | 1970-09-29 | 1974-05-14 | Rowland Dev Corp | Method of making retroreflective material |
| US3684348A (en) | 1970-09-29 | 1972-08-15 | Rowland Dev Corp | Retroreflective material |
| US4486363A (en) | 1982-09-30 | 1984-12-04 | Amerace Corporation | Method and apparatus for embossing a precision optical pattern in a resinous sheet |
| US4601861A (en) | 1982-09-30 | 1986-07-22 | Amerace Corporation | Methods and apparatus for embossing a precision optical pattern in a resinous sheet or laminate |
| US4588258A (en) | 1983-09-12 | 1986-05-13 | Minnesota Mining And Manufacturing Company | Cube-corner retroreflective articles having wide angularity in multiple viewing planes |
| GB2189800B (en) * | 1986-04-07 | 1990-03-14 | Michael Anthony West | Marking of articles |
| US4775219A (en) | 1986-11-21 | 1988-10-04 | Minnesota Mining & Manufacturing Company | Cube-corner retroreflective articles having tailored divergence profiles |
| JP2844339B2 (ja) * | 1988-07-05 | 1999-01-06 | 日本カーバイド工業株式会社 | 蛍光発色シート |
| CA2026161A1 (en) * | 1990-06-25 | 1991-12-26 | Thomas C. Dipietro | Fluorescent pigments |
| ZA918849B (en) | 1990-12-06 | 1992-08-26 | Minnesota Mining & Mfg | Articles exhibiting durable fluorescence |
| US5213872A (en) | 1991-04-19 | 1993-05-25 | Stimsonite Corporation | Preprinted retroreflective highway sign and method for making the sign |
| RU2063057C1 (ru) * | 1993-07-08 | 1996-06-27 | Обособленное научно-исследовательское подразделение по солнечной и точной оптике при Научно-производственном объединении "Астрофизика" | Световозвращающий экран (варианты) и способ его изготовления (варианты) |
| WO1996017012A1 (en) | 1994-11-28 | 1996-06-06 | Minnesota Mining And Manufacturing Company | Articles exhibiting durable colour and/or fluorescent properties |
| JP3127198B2 (ja) * | 1995-03-01 | 2001-01-22 | 森井 壽▲ひろ▼ | 有彩色残光性複合体および有彩色残光性物品 |
| US5672643A (en) * | 1995-09-29 | 1997-09-30 | Minnesota Mining And Manufacturing Company | Fluorescent dye blends |
| US5920429A (en) | 1995-09-29 | 1999-07-06 | Minnesota Mining And Manufacturing Company | Fluorescent dye blends |
| RU2131136C1 (ru) * | 1996-10-24 | 1999-05-27 | Лариса Аркадьевна Молохина | Световозвращающий материал |
| US6110566A (en) | 1997-10-23 | 2000-08-29 | 3M Innovative Properties Company | Stabilization of fluorescent dyes in vinyl articles using hindered amine light stabilizers |
| WO1999048961A2 (en) | 1998-01-21 | 1999-09-30 | Reflexite Corporation | Extended life fluorescence polyvinyl chloride sheeting |
| JP3430094B2 (ja) * | 1998-12-10 | 2003-07-28 | 日産自動車株式会社 | 塗装構造 |
| WO2000047407A1 (en) | 1999-02-12 | 2000-08-17 | Reflexite Corporation | Extended life fluorescence polyvinyl chloride sheeting |
| JP2001092393A (ja) * | 1999-09-24 | 2001-04-06 | Shiina:Kk | 発光シート |
| US20050003975A1 (en) * | 2003-06-18 | 2005-01-06 | Browne Yvonne Bridget | Blooming soap bars |
| DE10332650A1 (de) * | 2003-07-18 | 2005-02-10 | Kronos International, Inc. | Verfahren zur Oberflächenbehandlung eines Titandioxid-Pigments |
-
2003
- 2003-04-09 KR KR1020047017527A patent/KR101008192B1/ko not_active Expired - Lifetime
- 2003-04-09 BR BRPI0309587-8A patent/BR0309587A/pt active IP Right Grant
- 2003-04-09 EP EP13164767.9A patent/EP2620280B1/en not_active Expired - Lifetime
- 2003-04-09 EP EP03721589.4A patent/EP1507658B1/en not_active Expired - Lifetime
- 2003-04-09 CN CNB03809634XA patent/CN100542802C/zh not_active Expired - Lifetime
- 2003-04-09 CA CA2480526A patent/CA2480526C/en not_active Expired - Lifetime
- 2003-04-09 MX MXPA04009520A patent/MXPA04009520A/es unknown
- 2003-04-09 ES ES03721589.4T patent/ES2634117T3/es not_active Expired - Lifetime
- 2003-04-09 JP JP2004501163A patent/JP4610331B2/ja not_active Expired - Lifetime
- 2003-04-09 AU AU2003224896A patent/AU2003224896B2/en not_active Expired
- 2003-04-09 BR BRPI0309587-8A patent/BRPI0309587B1/pt unknown
- 2003-04-09 RU RU2004134737/04A patent/RU2303622C2/ru active
- 2003-04-09 ES ES13164767T patent/ES2739190T3/es not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2300596A (en) * | 1995-05-10 | 1996-11-13 | Portals Ltd | Fluorescent security feature for cheques and banknotes |
| KR19990063719A (ko) * | 1995-09-29 | 1999-07-26 | 스프레이그 로버트 월터 | 형광 염료 배합물 |
| KR20000048695A (ko) * | 1996-09-30 | 2000-07-25 | 스프레이그 로버트 월터 | 형광성 레전드를 갖는 재귀반사 그래픽 물품과 그 제조 방법 |
| JP2001174809A (ja) * | 1999-12-15 | 2001-06-29 | Asahi Kasei Corp | 面状偏光発光体 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2620280B1 (en) | 2019-05-15 |
| JP4610331B2 (ja) | 2011-01-12 |
| MXPA04009520A (es) | 2005-01-25 |
| CA2480526C (en) | 2010-10-05 |
| BR0309587A (pt) | 2007-03-06 |
| KR20050010777A (ko) | 2005-01-28 |
| RU2004134737A (ru) | 2005-04-20 |
| ES2634117T3 (es) | 2017-09-26 |
| CN100542802C (zh) | 2009-09-23 |
| CA2480526A1 (en) | 2003-11-13 |
| EP2620280A1 (en) | 2013-07-31 |
| EP1507658B1 (en) | 2017-05-17 |
| BRPI0309587B1 (pt) | 2019-10-08 |
| CN1649731A (zh) | 2005-08-03 |
| EP1507658A1 (en) | 2005-02-23 |
| RU2303622C2 (ru) | 2007-07-27 |
| ES2739190T3 (es) | 2020-01-29 |
| AU2003224896A1 (en) | 2003-11-17 |
| JP2005528249A (ja) | 2005-09-22 |
| AU2003224896B2 (en) | 2009-01-15 |
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| KR100972524B1 (ko) | 다층 필름을 포함하는 형광 제품 | |
| KR101008192B1 (ko) | 다수의 필름층을 포함하는 형광 제품 | |
| US7618709B2 (en) | Fluorescent articles having multiple film layers | |
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| US8034436B2 (en) | Fluorescent article having multiple layers |
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