CA2480526C - Fluorescent articles having multiple film layers - Google Patents
Fluorescent articles having multiple film layers Download PDFInfo
- Publication number
- CA2480526C CA2480526C CA2480526A CA2480526A CA2480526C CA 2480526 C CA2480526 C CA 2480526C CA 2480526 A CA2480526 A CA 2480526A CA 2480526 A CA2480526 A CA 2480526A CA 2480526 C CA2480526 C CA 2480526C
- Authority
- CA
- Canada
- Prior art keywords
- article
- fluorescent
- film
- accordance
- overlayer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 claims abstract description 14
- 229920000642 polymer Polymers 0.000 claims description 113
- 239000011159 matrix material Substances 0.000 claims description 88
- 239000007850 fluorescent dye Substances 0.000 claims description 80
- 239000000975 dye Substances 0.000 claims description 75
- 229920000515 polycarbonate Polymers 0.000 claims description 74
- 239000004417 polycarbonate Substances 0.000 claims description 74
- 239000004925 Acrylic resin Substances 0.000 claims description 30
- 229920000178 Acrylic resin Polymers 0.000 claims description 30
- 239000006096 absorbing agent Substances 0.000 claims description 30
- -1 combinations thereof Polymers 0.000 claims description 30
- 229920001230 polyarylate Polymers 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 19
- 238000012216 screening Methods 0.000 claims description 19
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 claims description 18
- UJVBZCCNLAAMOV-UHFFFAOYSA-N 2h-1,2-benzothiazine Chemical class C1=CC=C2C=CNSC2=C1 UJVBZCCNLAAMOV-UHFFFAOYSA-N 0.000 claims description 17
- VVZRKVYGKNFTRR-UHFFFAOYSA-N 12h-benzo[a]xanthene Chemical class C1=CC=CC2=C3CC4=CC=CC=C4OC3=CC=C21 VVZRKVYGKNFTRR-UHFFFAOYSA-N 0.000 claims description 13
- 238000010276 construction Methods 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 11
- 229920001577 copolymer Polymers 0.000 claims description 10
- 238000009472 formulation Methods 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 10
- 229920005989 resin Polymers 0.000 claims description 10
- 239000004800 polyvinyl chloride Substances 0.000 claims description 9
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 8
- 239000004431 polycarbonate resin Substances 0.000 claims description 7
- 229920005668 polycarbonate resin Polymers 0.000 claims description 7
- 239000002952 polymeric resin Substances 0.000 claims description 6
- 229920003002 synthetic resin Polymers 0.000 claims description 6
- 239000004793 Polystyrene Substances 0.000 claims description 5
- 239000004611 light stabiliser Substances 0.000 claims description 5
- 229920002223 polystyrene Polymers 0.000 claims description 5
- 230000002452 interceptive effect Effects 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 210000000988 bone and bone Anatomy 0.000 claims description 2
- 125000002080 perylenyl group Chemical class C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 claims description 2
- 230000008707 rearrangement Effects 0.000 claims description 2
- 150000005075 thioxanthenes Chemical class 0.000 claims description 2
- XOFYZVNMUHMLCC-ZPOLXVRWSA-N prednisone Chemical compound O=C1C=C[C@]2(C)[C@H]3C(=O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 XOFYZVNMUHMLCC-ZPOLXVRWSA-N 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 1
- 239000003086 colorant Substances 0.000 abstract description 29
- 239000010408 film Substances 0.000 description 201
- 239000010410 layer Substances 0.000 description 106
- 239000004926 polymethyl methacrylate Substances 0.000 description 64
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 59
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 30
- 239000002356 single layer Substances 0.000 description 17
- 238000002156 mixing Methods 0.000 description 13
- 229920000058 polyacrylate Polymers 0.000 description 11
- 239000000654 additive Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 238000013459 approach Methods 0.000 description 9
- 238000005562 fading Methods 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 229920006353 Acrylite® Polymers 0.000 description 7
- 230000032683 aging Effects 0.000 description 7
- LEVFXWNQQSSNAC-UHFFFAOYSA-N 2-(4,6-diphenyl-1,3,5-triazin-2-yl)-5-hexoxyphenol Chemical compound OC1=CC(OCCCCCC)=CC=C1C1=NC(C=2C=CC=CC=2)=NC(C=2C=CC=CC=2)=N1 LEVFXWNQQSSNAC-UHFFFAOYSA-N 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 230000005540 biological transmission Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- SWZOQAGVRGQLDV-UHFFFAOYSA-N 4-[2-(4-hydroxy-2,2,6,6-tetramethylpiperidin-1-yl)ethoxy]-4-oxobutanoic acid Chemical compound CC1(C)CC(O)CC(C)(C)N1CCOC(=O)CCC(O)=O SWZOQAGVRGQLDV-UHFFFAOYSA-N 0.000 description 5
- 238000004049 embossing Methods 0.000 description 5
- 239000001046 green dye Substances 0.000 description 5
- 239000004005 microsphere Substances 0.000 description 5
- OLFNXLXEGXRUOI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-phenylpropan-2-yl)phenol Chemical compound C=1C(N2N=C3C=CC=CC3=N2)=C(O)C(C(C)(C)C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=CC=C1 OLFNXLXEGXRUOI-UHFFFAOYSA-N 0.000 description 4
- PQJUJGAVDBINPI-UHFFFAOYSA-N 9H-thioxanthene Chemical compound C1=CC=C2CC3=CC=CC=C3SC2=C1 PQJUJGAVDBINPI-UHFFFAOYSA-N 0.000 description 4
- 239000011324 bead Substances 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 229920001109 fluorescent polymer Polymers 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 125000001841 imino group Chemical group [H]N=* 0.000 description 4
- 230000003993 interaction Effects 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 229910052724 xenon Inorganic materials 0.000 description 4
- 239000004429 Calibre Substances 0.000 description 3
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 description 3
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 3
- 229920006397 acrylic thermoplastic Polymers 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000012965 benzophenone Substances 0.000 description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
- 239000012964 benzotriazole Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 230000001747 exhibiting effect Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical class C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 description 3
- 229920006289 polycarbonate film Polymers 0.000 description 3
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 3
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 3
- 235000005881 Calendula officinalis Nutrition 0.000 description 2
- 241000736851 Tagetes Species 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 230000001413 cellular effect Effects 0.000 description 2
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 2
- 239000003623 enhancer Substances 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000001048 orange dye Substances 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 230000011664 signaling Effects 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- MXAPNMOBJKFMFC-UHFFFAOYSA-N (6,6-dihydroxycyclohexa-2,4-dien-1-yl)-(2,4-dihydroxyphenyl)methanone Chemical compound OC1=CC(O)=CC=C1C(=O)C1C(O)(O)C=CC=C1 MXAPNMOBJKFMFC-UHFFFAOYSA-N 0.000 description 1
- STEYNUVPFMIUOY-UHFFFAOYSA-N 4-Hydroxy-1-(2-hydroxyethyl)-2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CC(O)CC(C)(C)N1CCO STEYNUVPFMIUOY-UHFFFAOYSA-N 0.000 description 1
- MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 description 1
- 108010043121 Green Fluorescent Proteins Proteins 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- 239000004610 Internal Lubricant Substances 0.000 description 1
- 229920004061 Makrolon® 3108 Polymers 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920005372 Plexiglas® Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000013036 UV Light Stabilizer Substances 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N benzo-alpha-pyrone Natural products C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 1
- XJHABGPPCLHLLV-UHFFFAOYSA-N benzo[de]isoquinoline-1,3-dione Chemical class C1=CC(C(=O)NC2=O)=C3C2=CC=CC3=C1 XJHABGPPCLHLLV-UHFFFAOYSA-N 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- SODJJEXAWOSSON-UHFFFAOYSA-N bis(2-hydroxy-4-methoxyphenyl)methanone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=C(OC)C=C1O SODJJEXAWOSSON-UHFFFAOYSA-N 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 235000001671 coumarin Nutrition 0.000 description 1
- 125000000332 coumarinyl group Chemical class O1C(=O)C(=CC2=CC=CC=C12)* 0.000 description 1
- 239000013039 cover film Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012939 laminating adhesive Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- ORECYURYFJYPKY-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine;2,4,6-trichloro-1,3,5-triazine;2,4,4-trimethylpentan-2-amine Chemical compound CC(C)(C)CC(C)(C)N.ClC1=NC(Cl)=NC(Cl)=N1.C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 ORECYURYFJYPKY-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 238000005382 thermal cycling Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 150000003736 xenon Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
- B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/122—Reflex reflectors cube corner, trihedral or triple reflector type
- G02B5/124—Reflex reflectors cube corner, trihedral or triple reflector type plural reflecting elements forming part of a unitary plate or sheet
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/126—Reflex reflectors including curved refracting surface
- G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/422—Luminescent, fluorescent, phosphorescent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2590/00—Signboards, advertising panels, road signs
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31507—Of polycarbonate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Laminated Bodies (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Optical Elements Other Than Lenses (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/135,537 | 2002-04-30 | ||
| US10/135,537 US7264880B2 (en) | 2002-04-30 | 2002-04-30 | Fluorescent articles having multiple film layers |
| US10/354,515 US7618709B2 (en) | 2002-04-30 | 2003-01-30 | Fluorescent articles having multiple film layers |
| US10/354,515 | 2003-01-30 | ||
| PCT/US2003/010842 WO2003093007A1 (en) | 2002-04-30 | 2003-04-09 | Fluorescent articles having multiple film layers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2480526A1 CA2480526A1 (en) | 2003-11-13 |
| CA2480526C true CA2480526C (en) | 2010-10-05 |
Family
ID=33566997
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2480526A Expired - Lifetime CA2480526C (en) | 2002-04-30 | 2003-04-09 | Fluorescent articles having multiple film layers |
Country Status (10)
| Country | Link |
|---|---|
| EP (2) | EP2620280B1 (enExample) |
| JP (1) | JP4610331B2 (enExample) |
| KR (1) | KR101008192B1 (enExample) |
| CN (1) | CN100542802C (enExample) |
| AU (1) | AU2003224896B2 (enExample) |
| BR (2) | BR0309587A (enExample) |
| CA (1) | CA2480526C (enExample) |
| ES (2) | ES2634117T3 (enExample) |
| MX (1) | MXPA04009520A (enExample) |
| RU (1) | RU2303622C2 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005002072A1 (de) * | 2005-01-14 | 2006-07-20 | Röhm GmbH & Co. KG | Witterungsstabile Folie zur Gelbeinfärbung retroreflektierender Formkörper |
| CA2629944C (en) * | 2005-10-27 | 2016-02-09 | Avery Dennison Corporation | Fluorescent article having multiple layers |
| US7674515B2 (en) * | 2006-10-23 | 2010-03-09 | Avery Dennison Corporation | Fluorescent polycarbonate articles |
| JP5252960B2 (ja) * | 2007-04-02 | 2013-07-31 | キヤノン株式会社 | 縮合環芳香族化合物及びこれを用いた有機発光素子 |
| JP4956313B2 (ja) * | 2007-07-23 | 2012-06-20 | 日本カーバイド工業株式会社 | 内部全反射型キューブコーナー型再帰反射物品 |
| KR100941440B1 (ko) * | 2008-03-31 | 2010-02-11 | 최상석 | 칼라가 제공되는 큐브코너형 재귀반사물 및 그 제조방법 |
| JP5408902B2 (ja) * | 2008-05-15 | 2014-02-05 | キヤノン株式会社 | ジベンゾ［ｃ，ｇ］フルオレン化合物及びそれを使用した有機発光素子 |
| JP5335284B2 (ja) * | 2008-05-22 | 2013-11-06 | キヤノン株式会社 | 縮合多環化合物およびそれを有する有機発光素子 |
| US8322868B2 (en) * | 2009-05-12 | 2012-12-04 | Avery Dennison Corporation | Durable fluorescent articles having multiple film layers |
| US9746591B2 (en) * | 2013-03-12 | 2017-08-29 | Aura Optical Systems, Lp | Multi-layer microprismatic retroreflective sheeting and method of manufacturing the same |
| NL2013295B1 (en) * | 2013-08-02 | 2016-05-18 | Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno | A coating composition comprising a dye and a method to detect moisture in objects. |
| JPWO2020022063A1 (ja) * | 2018-07-23 | 2021-08-05 | 三菱ケミカル株式会社 | 再帰反射シート用アクリル樹脂フィルムおよび再帰反射シート |
| EP4010743A1 (en) | 2019-08-05 | 2022-06-15 | Avery Dennison Corporation | Retroreflective films comprising fluorescent dyes |
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| US2407680A (en) | 1945-03-02 | 1946-09-17 | Minnesota Mining & Mfg | Reflex light reflector |
| US3190178A (en) | 1961-06-29 | 1965-06-22 | Minnesota Mining & Mfg | Reflex-reflecting sheeting |
| US3810804A (en) | 1970-09-29 | 1974-05-14 | Rowland Dev Corp | Method of making retroreflective material |
| US3684348A (en) | 1970-09-29 | 1972-08-15 | Rowland Dev Corp | Retroreflective material |
| US4486363A (en) | 1982-09-30 | 1984-12-04 | Amerace Corporation | Method and apparatus for embossing a precision optical pattern in a resinous sheet |
| US4601861A (en) | 1982-09-30 | 1986-07-22 | Amerace Corporation | Methods and apparatus for embossing a precision optical pattern in a resinous sheet or laminate |
| US4588258A (en) | 1983-09-12 | 1986-05-13 | Minnesota Mining And Manufacturing Company | Cube-corner retroreflective articles having wide angularity in multiple viewing planes |
| GB2189800B (en) * | 1986-04-07 | 1990-03-14 | Michael Anthony West | Marking of articles |
| US4775219A (en) | 1986-11-21 | 1988-10-04 | Minnesota Mining & Manufacturing Company | Cube-corner retroreflective articles having tailored divergence profiles |
| JP2844339B2 (ja) * | 1988-07-05 | 1999-01-06 | 日本カーバイド工業株式会社 | 蛍光発色シート |
| CA2026161A1 (en) * | 1990-06-25 | 1991-12-26 | Thomas C. Dipietro | Fluorescent pigments |
| ZA918849B (en) | 1990-12-06 | 1992-08-26 | Minnesota Mining & Mfg | Articles exhibiting durable fluorescence |
| US5213872A (en) | 1991-04-19 | 1993-05-25 | Stimsonite Corporation | Preprinted retroreflective highway sign and method for making the sign |
| RU2063057C1 (ru) * | 1993-07-08 | 1996-06-27 | Обособленное научно-исследовательское подразделение по солнечной и точной оптике при Научно-производственном объединении "Астрофизика" | Световозвращающий экран (варианты) и способ его изготовления (варианты) |
| WO1996017012A1 (en) | 1994-11-28 | 1996-06-06 | Minnesota Mining And Manufacturing Company | Articles exhibiting durable colour and/or fluorescent properties |
| JP3127198B2 (ja) * | 1995-03-01 | 2001-01-22 | 森井 壽▲ひろ▼ | 有彩色残光性複合体および有彩色残光性物品 |
| GB2300596B (en) * | 1995-05-10 | 1998-11-04 | Portals Ltd | Composite material having fluorescent features |
| US5672643A (en) * | 1995-09-29 | 1997-09-30 | Minnesota Mining And Manufacturing Company | Fluorescent dye blends |
| US5674622A (en) * | 1995-09-29 | 1997-10-07 | Minnesota Mining And Manufacturing Company | Fluorescent dye blends |
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-
2003
- 2003-04-09 KR KR1020047017527A patent/KR101008192B1/ko not_active Expired - Lifetime
- 2003-04-09 BR BRPI0309587-8A patent/BR0309587A/pt active IP Right Grant
- 2003-04-09 EP EP13164767.9A patent/EP2620280B1/en not_active Expired - Lifetime
- 2003-04-09 EP EP03721589.4A patent/EP1507658B1/en not_active Expired - Lifetime
- 2003-04-09 CN CNB03809634XA patent/CN100542802C/zh not_active Expired - Lifetime
- 2003-04-09 CA CA2480526A patent/CA2480526C/en not_active Expired - Lifetime
- 2003-04-09 MX MXPA04009520A patent/MXPA04009520A/es unknown
- 2003-04-09 ES ES03721589.4T patent/ES2634117T3/es not_active Expired - Lifetime
- 2003-04-09 JP JP2004501163A patent/JP4610331B2/ja not_active Expired - Lifetime
- 2003-04-09 AU AU2003224896A patent/AU2003224896B2/en not_active Expired
- 2003-04-09 BR BRPI0309587-8A patent/BRPI0309587B1/pt unknown
- 2003-04-09 RU RU2004134737/04A patent/RU2303622C2/ru active
- 2003-04-09 ES ES13164767T patent/ES2739190T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP2620280B1 (en) | 2019-05-15 |
| JP4610331B2 (ja) | 2011-01-12 |
| MXPA04009520A (es) | 2005-01-25 |
| BR0309587A (pt) | 2007-03-06 |
| KR20050010777A (ko) | 2005-01-28 |
| RU2004134737A (ru) | 2005-04-20 |
| ES2634117T3 (es) | 2017-09-26 |
| CN100542802C (zh) | 2009-09-23 |
| CA2480526A1 (en) | 2003-11-13 |
| EP2620280A1 (en) | 2013-07-31 |
| EP1507658B1 (en) | 2017-05-17 |
| BRPI0309587B1 (pt) | 2019-10-08 |
| CN1649731A (zh) | 2005-08-03 |
| EP1507658A1 (en) | 2005-02-23 |
| RU2303622C2 (ru) | 2007-07-27 |
| ES2739190T3 (es) | 2020-01-29 |
| AU2003224896A1 (en) | 2003-11-17 |
| KR101008192B1 (ko) | 2011-01-17 |
| JP2005528249A (ja) | 2005-09-22 |
| AU2003224896B2 (en) | 2009-01-15 |
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