KR100987902B1 - 불활성 가스 발포 폴리우레탄 발포체에 사용하기 위한난연성 실리콘 계면활성제 - Google Patents
불활성 가스 발포 폴리우레탄 발포체에 사용하기 위한난연성 실리콘 계면활성제 Download PDFInfo
- Publication number
- KR100987902B1 KR100987902B1 KR1020047017254A KR20047017254A KR100987902B1 KR 100987902 B1 KR100987902 B1 KR 100987902B1 KR 1020047017254 A KR1020047017254 A KR 1020047017254A KR 20047017254 A KR20047017254 A KR 20047017254A KR 100987902 B1 KR100987902 B1 KR 100987902B1
- Authority
- KR
- South Korea
- Prior art keywords
- delete delete
- polyether
- surfactant
- foam
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 90
- 229920005830 Polyurethane Foam Polymers 0.000 title claims abstract description 31
- 239000011496 polyurethane foam Substances 0.000 title claims abstract description 31
- 229920001296 polysiloxane Polymers 0.000 title claims abstract description 30
- 239000011261 inert gas Substances 0.000 title claims abstract description 18
- 239000003063 flame retardant Substances 0.000 title claims description 24
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 23
- 239000000203 mixture Substances 0.000 claims abstract description 62
- 229920000570 polyether Polymers 0.000 claims abstract description 58
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 46
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 16
- 239000003054 catalyst Substances 0.000 claims abstract description 13
- 238000005187 foaming Methods 0.000 claims abstract description 9
- 229920005862 polyol Polymers 0.000 claims abstract description 9
- 150000003077 polyols Chemical class 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 6
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 6
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 6
- 238000002360 preparation method Methods 0.000 claims abstract description 4
- 239000006260 foam Substances 0.000 claims description 87
- 238000004519 manufacturing process Methods 0.000 claims description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 4
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 claims 2
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 2
- 239000001569 carbon dioxide Substances 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 abstract description 11
- 125000002947 alkylene group Chemical group 0.000 abstract description 9
- 125000003118 aryl group Chemical group 0.000 abstract description 7
- 229920000233 poly(alkylene oxides) Polymers 0.000 abstract description 6
- 125000002877 alkyl aryl group Chemical group 0.000 abstract description 4
- 125000003710 aryl alkyl group Chemical group 0.000 abstract description 3
- 239000001257 hydrogen Substances 0.000 abstract description 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 3
- 239000007789 gas Substances 0.000 description 19
- 210000004027 cell Anatomy 0.000 description 18
- 238000005516 engineering process Methods 0.000 description 11
- 239000004604 Blowing Agent Substances 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 9
- 238000009472 formulation Methods 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- -1 polysiloxane chain Polymers 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000011020 pilot scale process Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 1
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 1
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical compound CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 235000013929 Psidium pyriferum Nutrition 0.000 description 1
- 244000236580 Psidium pyriferum Species 0.000 description 1
- 229910018540 Si C Inorganic materials 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000005910 alkyl carbonate group Chemical group 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010959 commercial synthesis reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 210000000497 foam cell Anatomy 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/61—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/30—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by mixing gases into liquid compositions or plastisols, e.g. frothing with air
-
- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04W—WIRELESS COMMUNICATION NETWORKS
- H04W68/00—User notification, e.g. alerting and paging, for incoming communication, change of service or the like
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
-
- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04W—WIRELESS COMMUNICATION NETWORKS
- H04W64/00—Locating users or terminals or network equipment for network management purposes, e.g. mobility management
- H04W64/006—Locating users or terminals or network equipment for network management purposes, e.g. mobility management with additional information processing, e.g. for direction or speed determination
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Computer Networks & Wireless Communication (AREA)
- Signal Processing (AREA)
- Polyurethanes Or Polyureas (AREA)
- Fireproofing Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/133,266 | 2002-04-26 | ||
| US10/133,266 US6653359B2 (en) | 2002-04-26 | 2002-04-26 | Fire retardant silicone surfactants for use in inert gas blown polyurethane foams |
| PCT/US2003/011257 WO2003091320A1 (en) | 2002-04-26 | 2003-04-01 | Fire retardant silicone surfactants for use in inert gas blown polyurethane foams |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020097019172A Division KR20090111347A (ko) | 2002-04-26 | 2003-04-01 | 불활성 가스 발포 폴리우레탄 발포체에 사용하기 위한 난연성 실리콘 계면활성제 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20050006193A KR20050006193A (ko) | 2005-01-15 |
| KR100987902B1 true KR100987902B1 (ko) | 2010-10-13 |
Family
ID=29248955
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020047017254A Expired - Lifetime KR100987902B1 (ko) | 2002-04-26 | 2003-04-01 | 불활성 가스 발포 폴리우레탄 발포체에 사용하기 위한난연성 실리콘 계면활성제 |
| KR1020097019172A Withdrawn KR20090111347A (ko) | 2002-04-26 | 2003-04-01 | 불활성 가스 발포 폴리우레탄 발포체에 사용하기 위한 난연성 실리콘 계면활성제 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020097019172A Withdrawn KR20090111347A (ko) | 2002-04-26 | 2003-04-01 | 불활성 가스 발포 폴리우레탄 발포체에 사용하기 위한 난연성 실리콘 계면활성제 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6653359B2 (enExample) |
| EP (1) | EP1501889B1 (enExample) |
| JP (1) | JP4297791B2 (enExample) |
| KR (2) | KR100987902B1 (enExample) |
| CN (1) | CN100341927C (enExample) |
| AU (1) | AU2003221901A1 (enExample) |
| BR (1) | BR0309794B1 (enExample) |
| WO (1) | WO2003091320A1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008000266A1 (de) | 2008-02-11 | 2009-08-13 | Evonik Goldschmidt Gmbh | Die Erfindung betrifft die Verwendung von Schaumstabilisatoren, die auf Basis nachwachsender Rohstoffe hergestellt werden, zur Herstellung von Polyurethanschäumen |
| US8044109B2 (en) * | 2008-04-03 | 2011-10-25 | Momentive Performance Materials Inc. | Polyurethane foams containing silicone surfactants |
| US7718750B2 (en) * | 2008-05-27 | 2010-05-18 | Siltech Llc | Multi alkoxylated silicone surfactants |
| DE102008043343A1 (de) | 2008-10-31 | 2010-05-06 | Evonik Goldschmidt Gmbh | Silikonpolyetherblock-Copolymere mit definierter Polydispersität im Polyoxyalkylenteil und deren Verwendung als Stabilisatoren zur Herstellung von Polyurethanschäumen |
| US9587068B2 (en) | 2009-05-11 | 2017-03-07 | Momentive Performance Materials Inc. | Silicone surfactant for use in polyurethane foams prepared using vegetable oil based polyols |
| CN101696280B (zh) * | 2009-10-23 | 2011-07-20 | 河南科达节能环保有限公司 | 一种无氟聚氨酯发泡成型工艺 |
| DE102010063241A1 (de) * | 2010-12-16 | 2012-06-21 | Evonik Goldschmidt Gmbh | Siliconstabilisatoren für Polyurethan- oder Polyisocyanurat-Hartschaumstoffe |
| DE102011003148A1 (de) * | 2011-01-26 | 2012-07-26 | Evonik Goldschmidt Gmbh | Verwendung von Silikonpolyetherblock-Copolymere mit hochmolekularen nicht endverkappten Polyetherresten als Stabilisatoren zur Herstellung von Polyuretherschäumen niedriger Dichte |
| DE102011003150A1 (de) * | 2011-01-26 | 2012-07-26 | Evonik Goldschmidt Gmbh | Silikonpolyetherblock-Copolymere mit hochmolekularen Polyetherresten und deren Verwendung als Stabilisatoren zur Herstellung von Polyurethanschäumen |
| DE102011109540A1 (de) | 2011-08-03 | 2013-02-07 | Evonik Goldschmidt Gmbh | Alkylcarbonat endverschlossene Polyethersilioxane und Verfahren zu deren Herstellung |
| DE102011109547A1 (de) * | 2011-08-03 | 2013-02-07 | Evonik Goldschmidt Gmbh | Polysiloxanpolyether-Copolymere mit Carbonatgruppenhaltigen (Polyether-)Resten und deren Verwendung als Stabilisatorne zur Herstellung von Polyurethanschäumen |
| CN106146778B (zh) * | 2015-04-10 | 2020-11-17 | 莫门蒂夫性能材料股份有限公司 | 用于制备火焰层压聚氨酯泡沫的组合物和方法 |
| EP3307801B1 (en) * | 2015-06-11 | 2021-05-26 | Momentive Performance Materials Inc. | Silicone surfactant for use in polyurethane foams prepared with polyether carbonate polyols |
| US12617891B2 (en) | 2021-07-28 | 2026-05-05 | Momentive Performance Materials Inc. | Flexible foams comprising additives for improving hardness |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5525640A (en) * | 1995-09-13 | 1996-06-11 | Osi Specialties, Inc. | Silicone surfactants for use in inert gas blown polyurethane foams |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4814409A (en) | 1986-12-31 | 1989-03-21 | Union Carbide Corporation | Polysiloxane-polyoxyalkylene terpolymers for polyurethane foam manufacture |
| US4855329A (en) | 1987-08-31 | 1989-08-08 | Union Carbide Corporation | Polysiloxane-polyoxyalkylene terpolymers for polyurethane foam manufacture |
| US5145879A (en) | 1990-12-31 | 1992-09-08 | Union Carbide Chemicals & Plastics Technology Corporation | Surfactants for manufacture of urethane foams |
| US5665287A (en) | 1993-07-14 | 1997-09-09 | Foaming Technologies Cardio Bv | Froth process for continous manufacture of polyurethane foam slab-stocks |
| TW261577B (enExample) | 1993-07-14 | 1995-11-01 | Krypton Internat Sa | |
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-
2002
- 2002-04-26 US US10/133,266 patent/US6653359B2/en not_active Expired - Lifetime
-
2003
- 2003-04-01 WO PCT/US2003/011257 patent/WO2003091320A1/en not_active Ceased
- 2003-04-01 KR KR1020047017254A patent/KR100987902B1/ko not_active Expired - Lifetime
- 2003-04-01 JP JP2003587872A patent/JP4297791B2/ja not_active Expired - Lifetime
- 2003-04-01 KR KR1020097019172A patent/KR20090111347A/ko not_active Withdrawn
- 2003-04-01 AU AU2003221901A patent/AU2003221901A1/en not_active Abandoned
- 2003-04-01 CN CNB038150115A patent/CN100341927C/zh not_active Expired - Lifetime
- 2003-04-01 EP EP03718360.5A patent/EP1501889B1/en not_active Expired - Lifetime
- 2003-04-01 BR BRPI0309794-3A patent/BR0309794B1/pt active IP Right Grant
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5525640A (en) * | 1995-09-13 | 1996-06-11 | Osi Specialties, Inc. | Silicone surfactants for use in inert gas blown polyurethane foams |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2003221901A1 (en) | 2003-11-10 |
| EP1501889B1 (en) | 2013-07-24 |
| KR20050006193A (ko) | 2005-01-15 |
| JP2005523965A (ja) | 2005-08-11 |
| CN1662587A (zh) | 2005-08-31 |
| EP1501889A1 (en) | 2005-02-02 |
| JP4297791B2 (ja) | 2009-07-15 |
| US6653359B2 (en) | 2003-11-25 |
| BR0309794A (pt) | 2005-02-22 |
| WO2003091320A1 (en) | 2003-11-06 |
| BR0309794B1 (pt) | 2014-02-11 |
| CN100341927C (zh) | 2007-10-10 |
| US20030203984A1 (en) | 2003-10-30 |
| KR20090111347A (ko) | 2009-10-26 |
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