KR100985669B1 - Insecticide composition - Google Patents

Insecticide composition Download PDF

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KR100985669B1
KR100985669B1 KR1020100010728A KR20100010728A KR100985669B1 KR 100985669 B1 KR100985669 B1 KR 100985669B1 KR 1020100010728 A KR1020100010728 A KR 1020100010728A KR 20100010728 A KR20100010728 A KR 20100010728A KR 100985669 B1 KR100985669 B1 KR 100985669B1
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fatty acid
weight
composition
acid salt
oil
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KR1020100010728A
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Korean (ko)
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강상진
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주식회사동방아그로
주식회사 코씰
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PURPOSE: An insecticidal composition containing morpholine fatty acid salt is provided to ensure prevent pest which parasitizes in crops or fruits. CONSTITUTION: An insecticidal composition 0.1-99.9 weight% of morpholine fatty acid salt as an active ingredient. The composition contains 0.1-99.9% of fatty acid ester, water, ethylene glycol, glycerin, saccharides, alcohols, polyhydric alcohol, polyoxyethylene glycol, polypropylene glycol or N-methylpyrrolidinone. The insecticidal composition contains 70 weight% of morpholine fatty acid salt, 20 weight% of propylene glycol fatty acid ester, D-limonene and 5.0 weight% of propylene glycol.

Description

살충제 조성물{INSECTICIDE COMPOSITION}Insecticide composition {INSECTICIDE COMPOSITION}

본 발명은 살충제에 관계되는 것으로서, 특히 몰포린지방산염을 주제로 하는 친환경성 살충제에 관한 것이다.The present invention relates to pesticides, and more particularly to environmentally friendly insecticides based on morpholine fatty acid salts.

최근 친환경성 농산품이나 과일이 인체에 유리하다는 인식이 많아지면서 농약을 사용하지 않고 재배한 농산품이나 과일이 인기를 끌고 있다. 그러나 실제적으로는 농약을 사용하지 않으면 해충을 방제할 수 없으므로 대부분의 농가에서 판매하는 농산품이 대부분 농약을 사용하여 재배하고 있으며, 이러한 농산물 대부분이 무공해 농산물이라는 이름으로 판매되고 있다. Recently, the growing awareness that environmentally friendly agricultural products or fruits are beneficial to the human body, and agricultural products or fruits grown without using pesticides are becoming popular. However, since pests cannot be controlled without using pesticides, most agricultural products sold by farmers are grown using pesticides, and most of them are sold under the name of pollution-free agricultural products.

농약 중에는 산야에서 생산되는 인체에 무해한 약용식물을 이용한 농약도 개발되어 무공해 농산물 생산에 이용되고 있다. 이러한 산야에서 채취되는 약용 식물로 제조된 농약은 제조과정이 복잡하여 대량 생산이 어렵다는 문제점을 갖고 있다.Among pesticides, pesticides using medicinal plants that are harmless to the human body produced in Sanya have also been developed and used to produce pollution-free agricultural products. Pesticides made from medicinal plants collected from these fields have a problem in that the production process is complicated and mass production is difficult.

현재 감귤 응애나 사과 응애 및 진딧물과 같은 해충을 방제하기 위하여 기계유를 사용하고 있는바, 이러한 기계유를 물에 희석하여 과일에 살포하면 해충의 기문을 막아서 고사시키는 것으로 알려져 있다. Currently, machine oil is used to control pests such as citrus mites, apple mites, and aphids. Diluting such oils in water and spraying them on fruits is known to prevent the death of pests.

본 발명자는 무공해 농산물을 제조하는데 산야에서 채취되는 약용식물을 사용하지 않고 공장에서 대량으로 생산되면서도 인체에 무해한 기존의 제품을 이용한 농약을 개발하기 위하여 연구하는 과정에 몰포린지방산염이 살충효과를 갖고 있음을 알게 되어 본 발명을 완성하게 되었다.The present inventors have a pesticidal effect in the process of research to develop a pesticide using a conventional product that is harmless to the human body while producing in large quantities in a factory without using medicinal plants collected in the field to manufacture pollution-free agricultural products. It was found that the present invention was completed.

몰포린지방산염은 식품 첨가물로 이미 알려져 있다. 이 몰포린지방산염은 물이나 전착제와 같은 보조 성분으로 희석하여 수확된 과일의 표피에 뿌리면 과일의 표피에 유막층이 형성되어 수분의 증발을 억제하므로 과일의 보존 안전성을 향상시키는 식품 첨가물로 이미 이용되는 약품이며 인체에는 해가 없는 것으로 이미 알려진 약품이다. 그러나 현재까지는 몰포린지방산염이 농약으로 사용되었다는 보고는 없었다. Morpholin fatty acid salts are already known as food additives. This morpholine fatty acid salt is diluted with auxiliary ingredients such as water or electrodeposition agent, and when sprayed on the skin of the harvested fruit, an oil layer is formed on the fruit's epidermis to inhibit evaporation of water, which is already used as a food additive to improve the preservation safety of fruits. It is a medicine that is known to be harmless to the human body. To date, however, there have been no reports of morpholine fatty acid salts used as pesticides.

본 발명은 전술한 바와 같이 종래 식품 첨가물로 알려져 있으나 농약으로 사용된 예가 없는 몰포린지방산염을 이용한 농약 조성물을 제공하는 것이다.The present invention provides a pesticide composition using morpholine fatty acid salts, which are known as conventional food additives but are not used as pesticides.

본 발명의 목적은 대량으로 생산되어 시판되고 있는 몰포린지방산염을 이용하여 인체에 무해하면서도 살충 효과가 우수한 농약 조성물을 제공하는 것이다.It is an object of the present invention to provide a pesticide composition that is harmless to the human body and has excellent insecticidal effect using morpholine fatty acid salt produced in large quantities and commercially available.

전술한 본 발명의 목적은 몰포린지방산염을 함유하는 된 농약 조성물에 의하여 달성된다.The above object of the present invention is achieved by means of agrochemical compositions containing morpholine fatty acid salts.

본 발명은 몰포린지방산염을 주제로 하는 농약 조성물로 구성된다.The present invention consists of a pesticide composition based on morpholine fatty acid salts.

본 발명에 사용되는 몰포린지방산염은 지금까지 과일의 표피에 처리하여 과일의 표피에 유막층이 형성되도록 하여 과일의 표피에서 수분이 증발되는 것을 억제하므로 감귤 표면에 처리하면 수분 증발을 억제함과 동시에 감귤 표면의 광택을 증진시키는 역할을 하여 과일의 보존 안전성 및 광택을 향상시키는 식품 첨가물로 알려져 있을 뿐이고 살충제로 사용된 예는 보고된 바가 없는 화합물이다.The morpholine fatty acid salt used in the present invention is treated to the epidermis of the fruit so that an oil layer is formed on the epidermis of the fruit, thereby inhibiting the evaporation of moisture from the epidermis of the fruit. At the same time, it is only known as a food additive that plays a role in enhancing the glossiness of the citrus surface to improve the preservation safety and glossiness of the fruit, and the examples used as insecticides have not been reported.

본 발명의 조성물은 몰포린지방산염과 기타의 보조 성분으로 조성된다. The composition of the present invention is composed of morpholine fatty acid salts and other auxiliary components.

본 발명에 따르면, 몰포린지방산염은 단독으로 물과 혼합하여 처리할 수도 있다. 그러나 바람직한 조성물은 0.01 내지 99.99중량%의 지방산에스테르, 0 내지 99.99중량%의 오일이나 방향제 및 0.01 내지 99.99중량%의 증량제와 혼합하여 조성물의 형태로 만들고 50배 내지 100,000배의 물로 희석하여 사용한다. 그러나 바람직한 희석 비율은 조성물의 중량을 기준으로 50배 내지 1000배로 희석하여 사용하는 것이다. According to the present invention, morpholine fatty acid salt may be treated by mixing with water alone. However, the preferred composition is mixed with 0.01 to 99.99% by weight of fatty acid ester, 0 to 99.99% by weight of oil or fragrance and 0.01 to 99.99% by weight of extender in the form of a composition and diluted with 50 to 100,000 times of water. However, the preferred dilution ratio is to use 50 to 1000 times dilution based on the weight of the composition.

본 발명의 조성물에 의하여 효과적으로 살충할 수 있는 해충으로는 사과 진딧물, 사과 조팝나무진딧물, 사과 흑진딧물, 사과 깎지벌레류, 사과응애류, 감귤진딧물, 감귤조팝나무진딧물, 감귤 응애류, 감귤깍지벌레류, 배 배명나방, 배진딧물, 배조팝나무 진딧물, 꼬마 배나무이, 배 가루깍지벌레, 고추 진딧물(목화진딧물, 복숭아 흑진딧물), 장미 진딧물, 국화 진딧물, 백합진딧물, 담뱃진딧물, 감자진딧물, 딸기 점박이 응애, 복분자 점박이 응애, 고추 차면지 응애, 수박 점박이 응애, 복숭아 깍지벌레, 복숭아 응애류, 복숭아 흑진딧물, 감 깍지벌레류, 관엽깍지벌레류, 배추 진딧물(복숭아 흑진딧물, 무테두리진딧물) 벼 벼멸구, 벼 혹명나방, 벼 이화명나방, 소나무 솔껍질깍지벌레등이 있으며, 채소, 원예, 화훼의 진딧물, 응애류, 흑진딧물, 깍지벌레류, 조팝나무진딧물, 나방, 나방 유충 및 벼 벼멸구, 벼 혹명나방, 벼 이화명나방, 벼 꼬마배나무이, 벼 벼물바구미, 벼 애멸구 등 벼의 해충에도 적용된다.Insects that can be effectively killed by the composition of the present invention include apple aphids, apple meadowsweet aphids, apple black aphids, apple mole, apple mite, citrus aphids, citrus aphids, citrus mite, citrus worms, Pear pear moth, pear aphid, pear aphid, pear aphid, pear worm, pepper aphid (cotton aphid, peach black aphid), rose aphid, chrysanthemum aphid, lily aphid, tobacco aphid, potato aphid, strawberry spotted mite, Bokbunja spotted mite, red pepper mite, watermelon spotted mite, peach pods, peach mites, peach black aphids, persimmon pods, houseplants, cabbage aphids (peach black aphids, rimless aphids) Moths, rice larvae, pine bark beetles, vegetables, horticulture, aphids of flowers, mites, black aphids, podworms, Pop trees shall apply pest aphid, moth, moth larvae and rice BPH, such as rice hokmyeong moth, rice yihwamyeong moth, rice baenamuyi kid, byeomul rice weevil, rice paddy aemyeolgu.

본 발명의 몰포린지방산염에 사용되는 지방산으로는 다음과 같은 지방산 중에서 선택된 지방산이 있다. 지방산으로는 버터산, 카프로익산, 카프릴릭산, 카프릭산, 라우릴산, 미리스틱산, 팔미틴산, 팔미토레익산, 스테아린산, 오레인산, 리시놀레익산, 바세닉산, 리놀레인산, 알파리놀레닉산, 감마리놀레닉산, 아라키딕산, 가도레익산, 아라치도닉산, EPA, 비헤닉산, 에루식산, DHA, 리노세릭산 중에서 선택된 1종 또는 2 이상의 혼합 지방산이 있다.Fatty acids used in the morpholine fatty acid salts of the present invention include fatty acids selected from the following fatty acids. Fatty acids include butyric acid, caproic acid, caprylic acid, capric acid, lauryl acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, oleic acid, ricinoleic acid, basonic acid, linoleic acid, alphali There is one or two or more mixed fatty acids selected from nolenic acid, gamma-linolenic acid, arachidic acid, gadoleic acid, arachidonic acid, EPA, nonhenic acid, erucic acid, DHA, linoselic acid.

이러한 지방산으로부터 나오는 몰포린지방산염은 2종 이상의 지방산염을 혼합하여 사용할 수도 있다.The morpholine fatty acid salt derived from these fatty acids can also be used in mixture of 2 or more types of fatty acid salts.

그 외에도 천연오일로부터 얻어지는 지방산인 아몬드, 카놀라, 코코아, 코코넛, 옥수수, 면실, 아마, 포도씨, 올리브, 팜, 팜올레인, 팜커널, 땅콩, 홍화, 참기름, 콩기름, 해바라기씨, 호두, 소, 우유(암소, 산양), 대구간기름, 돼지, 모유의 오일로부터 얻어지는 지방산 중에서 선택된 지방산이 이용될 수도 있다. Other fatty acids from almonds, canola, cocoa, coconut, corn, cottonseed, flax, grapeseed, olive, palm, palm olein, palm kernel, peanut, safflower, sesame oil, soybean oil, sunflower seed, walnut, cow, Fatty acids selected from fatty acids obtained from milk (cow, goat), cod liver oil, pig, breast milk may be used.

본 발명의 조성물에 사용되는 지방산에스테르로는 프로필렌글리콜 지방산 에스테르, 글리세린 지방산에스테르, 폴리글리세린 지방산 에스테르, 솔비탄 지방산 에스테르, 폴리옥시에틸렌 솔비탄 지방산에스테르, 폴리솔베이트 20, 폴리솔베이트 40, 폴리솔베이트 60, 폴리솔베이트 80, 자당 지방산 에스테르, 당류 지방산 에스테르 등이 있다.The fatty acid ester used in the composition of the present invention is propylene glycol fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polysorbate 20, polysorbate 40, polysol Bait 60, polysorbate 80, sucrose fatty acid ester, sugar fatty acid ester and the like.

본 발명에 사용되는 오일 또는 가향제들은 천연에서 얻을 수 있는 것으로서, 가향제로는 천연에서 얻어지는 것으로서 허브계는 라벤더, 로즈마리, 유칼립투스, 카모마일과 같은 허브계 가향제, 과일과 시트러스 계열로는 오렌지, 유자, 베르가못, 알로에, 그린피치, 복숭아, 레몬, 스쿼시, 애플, 모과오일 또는 향이 사용된다. 자연 또는 꽃 계열로서는 뮤게, 후리지아, 아카시아, 머스크, 앰버, 솔(pine), 헤이즐럿, 리모넨(D-limonene), 편백유등이 사용되며, 오일로는 아몬드 오일, 카놀라 오일, 코코아 오일, 코코넛 오일, 옥수수 기름, 면실유, 아마유, 포도씨유, 올리브 오일, 팜유, 팜올레인유, 팜커널유, 땅콩기름, 홍화유, 참기름, 콩기름, 해바라기씨유, 호두기름, 소기름, 우유(암소, 산양), 대구간기름, 돼지기름, 모유 등이 사용된다.The oils or flavoring agents used in the present invention can be obtained in nature, and as a flavoring agent is obtained in nature, the herb-based herb flavors such as lavender, rosemary, eucalyptus, chamomile, orange and citron as fruit and citrus-based Bergamot, aloe, green pitch, peach, lemon, squash, apple, quince oil or fragrance are used. As the natural or floral family, muge, freesia, acacia, musk, amber, pine, haislot, d-limonene, cypress oil, etc. are used, and almond oil, canola oil, cocoa oil, coconut oil, Corn oil, cottonseed oil, linseed oil, grapeseed oil, olive oil, palm oil, palm olein oil, palm kernel oil, peanut oil, safflower oil, sesame oil, soybean oil, sunflower seed oil, walnut oil, beef oil, milk (cow, goat), cod Oil, pork oil and breast milk are used.

본 발명에 사용되는 증량제로는 물, 에틸렌글리콜, 프로필렌글리콜, 글리세린, 당류, 알콜류, 다가알콜, 폴리옥시에틸렌 글리콜, 폴리프로필렌글리콜, N-메칠피롤리디논 등이 있다.Extenders used in the present invention include water, ethylene glycol, propylene glycol, glycerin, sugars, alcohols, polyhydric alcohols, polyoxyethylene glycol, polypropylene glycol, N-methylpyrrolidinone and the like.

본 발명에 의하면 농작물이나 과수에 기생하는 해충들이 효과적으로 제거된다.According to the present invention, pests parasitic in crops or fruit trees are effectively removed.

이하 본 발명을 구체적으로 설명하기 위하여 실시예를 기재한다.Hereinafter, examples will be described in order to describe the present invention in detail.

실시예 1Example 1

본 발명의 성분들을 다음과 같이 배합하여 본 발명의 조성물을 얻고 250배 및 500배의 물로 희석하여 감귤 조팝나무진딧물에 대하여 다발생기 경엽 처리를 하고 1 일후, 3 일후, 7 일후 및 14일 후에 방제가를 판단하고, 대조용으로 기계유 유제를 100배의 물로 희석하여 동일한 방법으로 처리하여 얻은 방제가와 비교하였다. 시험결과는 표 1에 기재한다.Compounds of the present invention were formulated as follows to obtain a composition of the present invention and diluted with 250 and 500 times water and treated with multi-generative foliage on citrus zodiac aphids and control after 1 day, 3 days, 7 days and 14 days. The value was judged and compared with the control value obtained by diluting the machine oil emulsion with 100 times water as a control for the same method. The test results are shown in Table 1.

감귤 조팝나무진딧물 시험결과Citrus Maple Aphid Test Results
시험물질
Test substance

희석배수
Dilution factor

방제가(%)
Control price (%)
비고
Remarks
1일후
1 day later
3일후
3 days later
7일후
7 days later
14일후
14 days later



다발생기
경엽처리
(5/27)



Multigenerator
Foliage treatment
(5/27)


본 발명의
조성물

Of the present invention
Composition
250배
250x

90.9
90.9
89.6
89.6
80.0
80.0
78.2
78.2
500배
500 times

71.0
71.0
52.0
52.0
44.5
44.5
38.3
38.3
기계유유제
Machine emulsion
100배
100 times

60.3
60.3
86.2
86.2
62.5
62.5
66.2
66.2

실시예 2Example 2

실시예 1과 동일한 방법으로 본 발명의 조성물을 얻고 감귤 응애에 대하여 한 잎당 23마리의 응애가 발생하였을 때 경엽 처리하고 5일 후, 10일 후, 15일 후, 20일 후에 방제가를 판단하였다. 시험결과는 표 2에 기재한다.When the composition of the present invention was obtained in the same manner as in Example 1 and 23 mites per leaf were generated for the citrus mites, the leaves were treated after 5 days, 10 days, 15 days, and 20 days. . The test results are shown in Table 2.

감귤 귤응애 시험결과Citrus tangerine mite test results
시험물질
Test substance

희석배수
Dilution factor
방제가(%)
Control price (%)
비고
Remarks
5일후
5 days later
10일후
10 days later
14일후
14 days later
20일후
20 days later


한잎당2-3마리 발생 시경엽처리
(7/9)


Foliage treatment when 2-3 leaves per leaf
(7/9)

본 발명의
조성물

Of the present invention
Composition

250배
250x

83.8
83.8
80.5
80.5
78.4
78.4
75.6
75.6
500배
500 times

66.4
66.4
34.5
34.5
44.1
44.1
25.6
25.6
기계유유제
Machine emulsion

100배
100 times
81.1
81.1
78.4
78.4
76.0
76.0
73.3
73.3

실시예 3Example 3

실시예 1과 동일한 방법으로 본 발명의 조성물을 얻고 실시예 2와 동일한 방법으로 방제가를 평가하였다. 대조용 약제로는 선초를 1000배의 물로 희석하여 사용하였다. 시험결과는 표 3에 기재한다.The composition of the present invention was obtained in the same manner as in Example 1, and the control value was evaluated in the same manner as in Example 2. As a control drug, vinegar was diluted with 1000 times of water. The test results are shown in Table 3.

사과 사과응애 시험결과Apple apple mite test results
시험물질
Test substance

희석배수
Dilution factor
방제가(%)
Control price (%)
비고
Remarks
5일후
5 days later
10일후
10 days later
15일후
15 days later
20일후
20 days later


한 잎당 2-3마리
발생시
경엽처리
(7/16)


2-3 per leaf
At occurrence
Foliage treatment
(7/16)

본 발명의
조성물

Of the present invention
Composition
250배
250x

84.9
84.9
75.2
75.2
74.5
74.5
84.0
84.0
500배
500 times

71.6
71.6
62.6
62.6
61.0
61.0
58.7
58.7
선초
Seoncho

1000배
1000 times
96.2
96.2
85.6
85.6
68.6
68.6
73.4
73.4

실시예 4Example 4

실시예 1과 동일한 방법으로 제조된 본 발명의 조성물을 동일한 방법으로 사과조팝나무에 처리하여 방제가를 판단하였다, 대조용 약제로는 푸른꿈을 1000배의 물로 희석하여 사용하였다. 시험 결과는 표 4에 기재한다.The composition of the present invention prepared in the same manner as in Example 1 was treated with apple cider in the same way to determine the control value, the control agent was used by diluting blue dream with 1000 times water. The test results are shown in Table 4.

사과 조팝나무 진딧물 시험결과Apple Maple Aphid Test Results
시험물질
Test substance

희석배수
Dilution factor
방제가(%)
Control price (%)
비고
Remarks
1일후
1 day later
3일후
3 days later
7일후
7 days later
14일후
14 days later



다발생기
경엽처리
(6/1)



Multigenerator
Foliage treatment
(6/1)

본 발명의
조성물

Of the present invention
Composition
250배
250x

91.2
91.2
95.2
95.2
89.2
89.2
85.9
85.9
500배
500 times

70.6
70.6
88.0
88.0
90.9
90.9
45.2
45.2
푸른꿈
Blue dream
1000배
1000 times

85.9
85.9
85.4
85.4
87.1
87.1
81.1
81.1

상기 시험결과에 의하면 감귤 조팝나무진딧물에 대한 약제방제 효과시험을 실시한 결과, 250배로 희석한 본 발명의 조성물은 처리 후 1일에서 3일까지 90% 정도의 방제 효과를 보여 발생초기 처리 시 높은 방제가를 기대할 수 있는 것으로 판단된다.According to the test results of the drug control effect test for citrus meadow aphid, the composition of the present invention diluted 250-fold shows a control effect of about 90% from 1 day to 3 days after treatment, high control during the initial treatment We believe that we can expect price hikes.

감귤 귤응애에서는, 250배로 희석한 본 발명의 조성물은 처리 5일, 10일 후 까지는 80% 이상, 15일, 20일 후에는 70%이상의 방제 효과가 나타나는 것으로 확인되었으며, 대조약제인 기계유유제와 비교하였을 때 유사한 효과가 나타나 친환경제제로서 실용성이 있는 것으로 판단된다.In citrus tangerine mite, the composition of the present invention diluted by 250-fold was found to have a control effect of 80% or more after 5 days, 10 days, and 70% or more after 15 days, 20 days, and compared with a mechanical emulsion, a control drug. Similar effects appeared when it is considered to be practical as an eco-friendly formulation.

사과 사과응애에 대한 시험결과에 의하면, 250배로 희석한 본 발명의 조성물은 처리 초기인 5일 후에서 가장 높은 방제가를 나타냈기 때문에 발생초기 처리 시 85% 정도의 방제가를 기대할 수 있는 것으로 판단된다.According to the test results of apple apple mite, the composition of the present invention diluted 250-fold showed the highest control value after 5 days of the initial treatment, so it can be expected that about 85% of the control value can be expected during the initial treatment. do.

사과 조팝나무진딧물에 대한 약제방제 효과시험을 실시한 결과, 250배로 희석한 본 발명의 조성물은 대조약제인 푸른꿈과 유사한 방제 효과가 나타나서 실용성이 있는 것으로 나타났다.
As a result of the drug control effect test on apple meadowsweet aphid, the composition of the present invention diluted 250-fold appeared to have a control effect similar to that of the control drug blue dream, showing its utility.

실시예 5Example 5

실시예 1의 조성물을 500배 및 50배의 물로 희석하여 딸기 하우스에서 채집한 점박이 응애(Tetranychus urticae)에 대하여 실시하였다. 실험은 전북 익산시 여산면 딸기하우스에서 채집한 점박이 응애 성충을 처리구당 30마리씩 접종하였으며 동일한 실험을 두 차례 실시하고 3회 반복 실시하였다.The composition of Example 1 was diluted with 500 times and 50 times water to carry out the Tetranychus urticae collected in the strawberry house. The experiment was conducted to inoculate 30 adult spotted mites from the strawberry house in Yeosan-myeon, Yeosan-myeon, Iksan-si, per treatment. The same experiment was repeated twice and repeated three times.

시험방법 및 평가에 대하여는 다음에 기재한다.Test methods and evaluations are described below.

1. 시험방법1. Test Method

시험구 배치 및 방법Test Arrangement and Method
구 분
division

배치법
Placement
처리수
Treated water
반복수
Iterations
총주수
Total shares
구당주수
Gudang stock
총소요주수
Total demand
약 효
Medicinal effect

완전임의
Full random
5
5
3
3
15
15
1Pot
1Pot
15Pot
15Pot

공시약제 및 처리내용 Disclosure and Treatment

시험약제

Test drug

주성분함량(%)

Main ingredient content (%)

약 효
Medicinal effect
희석배수
Dilution factor
처리시기 및 방법
When and how to process
본 발명의 조성물(1차)

본 발명의 조성물(1차)
Composition of the present invention (primary)

Composition of the present invention (primary)

500배

500배
500 times

500 times
접종후 경엽처리(4/10)

접종후 1일간격2회 경엽처리(4/10,11)
Foliage treatment after inoculation (4/10)

Twice a day after inoculation, foliage treatment (4 / 10,11)
본 발명의 조성물(2차)

본 발명의 조성물(2차)
Composition of the present invention (secondary)

Composition of the present invention (secondary)

500배

500배
500 times

500 times
접종후 경엽처리(4/10)

접종후 1일간격2회 경엽처리(4/10.11)
Foliage treatment after inoculation (4/10)

Twice a day after inoculation, foliage treatment (4 / 10.11)
무처리
No treatment


-
-
-
-

2. 시험결과 2. Test result

가. 약효시험end. Drug test

점박이응애 성충에 대한 약제방제 효과(1일차)Drug Control Effects on Spotted Mites (Day 1)

시험약제

Test drug


주성분함량(%)

Main ingredient content (%)


희석배수

Dilution factor

생충율(%)
% Viability

방제가(%)

Control price (%)

평 균
Average
본 발명의 조성물
(1차)

본 발명의 조성물
(1차, 1일간격2회)
Compositions of the Invention
(Primary)

Compositions of the Invention
(1st, 2 times daily)

500배


500배
500 times


500 times
43.3


40.0
43.3


40.0
56.7


60.0
56.7


60.0
본 발명의 조성물
(2차)

본 발명의 조성물
(2차, 1일간격2회)
Compositions of the Invention
(Secondary)

Compositions of the Invention
(2nd, 2 times a day)

500배


500배
500 times


500 times
56.7


53.3
56.7


53.3
43.3


46.7
43.3


46.7

무처리
No treatment

-
-
100.0
100.0
-
-

점박이응애 성충에 대한 약제방제 효과(2일차)Drug Control Effects on Spotted Mites (Day 2)

시험약제

Test drug


주성분함량(%)

Main ingredient content (%)


희석배수

Dilution factor

생충율(%)
% Viability

방제가(%)

Control price (%)

평 균
Average
본 발명의
조성물(1차)

본 발명의 조성물
(1차, 1일간격2회)
Of the present invention
Composition (primary)

Compositions of the Invention
(1st, 2 times daily)

500배


500배
500 times


500 times
20.0


10.0
20.0


10.0
80.0


90.0
80.0


90.0
본 발명의 조성물
(2차)

본 발명의 조성물
(2차, 1일간격2회)
Compositions of the Invention
(Secondary)

Compositions of the Invention
(2nd, 2 times a day)

500배


500배
500 times


500 times
26.7


30.0
26.7


30.0
73.3


70.0
73.3


70.0

무처리
No treatment

-
-
100.0
100.0
-
-

점박이응애 성충에 대한 약제방제 효과(4일차)Effect of Pharmaceutical Control on Spotted Mites (Day 4)

시험약제

Test drug


주성분함량(%)

Main ingredient content (%)


희석배수

Dilution factor

생충율(%)
% Viability

방제가(%)

Control price (%)

평 균
Average
본 발명의 조성
물(1차)

본 발명의 조성물
(1차, 1일간격2회)
Composition of the Invention
Water (primary)

Compositions of the Invention
(1st, 2 times daily)

500배


500배
500 times


500 times
10.0


3.3
10.0


3.3
90.0


92.7
90.0


92.7
본 발명의 조성물
(2차)

본 발명의 조성물
(2차, 1일간격2회)
Compositions of the Invention
(Secondary)

Compositions of the Invention
(2nd, 2 times a day)

500배


500배
500 times


500 times
16.7


6.7
16.7


6.7
83.3


93.3
83.3


93.3

무처리
No treatment

-
-
100.0
100.0
-
-

점박이응액 성충에 대한 약제방제 효과(5일차)Effect of Drug Control on Adults of Spotted Coagulation (Day 5)

시험약제

Test drug


주성분함량(%)

Main ingredient content (%)


희석배수

Dilution factor

생충율(%)
% Viability

방제가(%)

Control price (%)

평 균
Average
본 발명의 조성물
(1차)

본 발명의 조성물
(1차, 1일간격2회)
Compositions of the Invention
(Primary)

Compositions of the Invention
(1st, 2 times daily)

500배


500배
500 times


500 times
10.0


3.3
10.0


3.3
90.0


92.7
90.0


92.7
본 발명의 조성물
(2차)

본 발명의 조성물
(2차, 1일간격2회)
Compositions of the Invention
(Secondary)

Compositions of the Invention
(2nd, 2 times a day)

500배


500배
500 times


500 times
16.7


6.7
16.7


6.7
83.3


93.3
83.3


93.3

무처리
No treatment

-
-
100.0
100.0
-
-

점박이응애 성충에 대한 약제방제 효과(8일차)Effect of Pharmaceutical Control on Spotted Mites (Day 8)

시험약제

Test drug


주성분함량(%)

Main ingredient content (%)


희석배수

Dilution factor

생충율(%)
% Viability

방제가(%)

Control price (%)

평 균
Average
본 발명의 조성물
(1차)

본 발명의 조성물
(1차, 1일간격2회)
Compositions of the Invention
(Primary)

Compositions of the Invention
(1st, 2 times daily)

500배


500배
500 times


500 times
6.7


3.3
6.7


3.3
92.8


96.5
92.8


96.5
본 발명의 조성물
(2차)

본 발명의 조성물
(2차, 1일간격2회)
Compositions of the Invention
(Secondary)

Compositions of the Invention
(2nd, 2 times a day)

500배


500배
500 times


500 times
10.0

3.3
10.0

3.3
89.3


96.5
89.3


96.5

무처리
No treatment

-
-
93.3
93.3
-
-

Claims (8)

몰포린지방산염을 유효성분으로 함유하고 해충의 표피에 처리하여 해충의 기문을 폐쇄하여 해충을 박멸하는 살충제 조성물.An insecticide composition containing morpholine fatty acid salt as an active ingredient and treating the epidermis of the pest to close the gate of the pest and thereby exterminate the pest. 제1항에서, 몰포린지방산염이 전체 조성물의 중량을 기준으로 0.1 내지 99.9중량% 함유되고 살충제용 첨가제로서 지방산 에스테르, 물, 에틸렌글리콜, 글리세린, 당류, 알콜류, 다가알콜, 폴리옥시에틸렌 글리콜, 폴리프로필렌글리콜, N-메칠피롤리디논 중 하나 또는 둘 이상을 포함하는 살충제용 첨가제가 0.1 내지 99.9% 함유되었음을 특징으로 하는 살충제 조성물.The method according to claim 1, wherein the morpholine fatty acid salt is contained 0.1 to 99.9% by weight based on the weight of the total composition and as a pesticide additive, fatty acid esters, water, ethylene glycol, glycerin, sugars, alcohols, polyhydric alcohols, polyoxyethylene glycol, A pesticide composition comprising 0.1 to 99.9% of an insecticide additive containing one or two or more of polypropylene glycol and N-methylpyrrolidinone. 제1항에서, 이 조성물이 몰포린지방산염 70중량%, 프로필렌글리콜 지방산에스테르 20중량%, D-리모넨 5.0중량% 및 프로필렌글리콜 5.0중량%로 조성되었음을 특징으로 하는 살충제 조성물.The insecticide composition according to claim 1, wherein the composition is composed of 70% by weight of morpholine fatty acid salt, 20% by weight of propylene glycol fatty acid ester, 5.0% by weight of D-limonene and 5.0% by weight of propylene glycol. 삭제delete 삭제delete 삭제delete 삭제delete 몰포린지방산염을 유효성분으로 함유하는 살충제 조성물을 5 내지 1000배의 물로 희석하고 해충이 기생하는 농작물에 살포하여 해충의 기문을 폐쇄하여 해충을 박멸하는 농작물 해충 방제 방법.A pest control method for diminishing pests by diluting the insecticide composition containing morpholine fatty acid salt as an active ingredient with 5 to 1000 times of water and spraying on the pests parasitic parasites to close the gate of the pests.
KR1020100010728A 2010-02-05 2010-02-05 Insecticide composition KR100985669B1 (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101815877B1 (en) * 2015-08-24 2018-01-08 경남과학기술대학교 산학협력단 Mixed solution for foliar fertilization
US20190208778A1 (en) * 2012-06-28 2019-07-11 Envance Technologies, Llc Insect repellent surface composition
KR20220072636A (en) * 2020-11-25 2022-06-02 농업회사법인투엠바이오주식회사 Composition for controlling pest comprising Neem seed extract, Cinnamomum cassia extract and Citronella oil as effective component and uses thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02200604A (en) * 1988-11-23 1990-08-08 Roussel Uclaf New insect pest-exterminating agent composition containing pyrethrinoid and bactericide
KR920000229A (en) * 1990-06-13 1992-01-29 프랑소와 크레띠앙 Methods of treating leaf fungicides and bactericidal compositions for carrying out the method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02200604A (en) * 1988-11-23 1990-08-08 Roussel Uclaf New insect pest-exterminating agent composition containing pyrethrinoid and bactericide
KR920000229A (en) * 1990-06-13 1992-01-29 프랑소와 크레띠앙 Methods of treating leaf fungicides and bactericidal compositions for carrying out the method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20190208778A1 (en) * 2012-06-28 2019-07-11 Envance Technologies, Llc Insect repellent surface composition
KR101815877B1 (en) * 2015-08-24 2018-01-08 경남과학기술대학교 산학협력단 Mixed solution for foliar fertilization
KR20220072636A (en) * 2020-11-25 2022-06-02 농업회사법인투엠바이오주식회사 Composition for controlling pest comprising Neem seed extract, Cinnamomum cassia extract and Citronella oil as effective component and uses thereof
KR102488343B1 (en) 2020-11-25 2023-01-13 농업회사법인투엠바이오주식회사 Composition for controlling pest comprising Neem seed extract, Cinnamomum cassia extract and Citronella oil as effective component and uses thereof

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