KR100953242B1 - 수성 이액형 폴리우레탄계 - Google Patents
수성 이액형 폴리우레탄계 Download PDFInfo
- Publication number
- KR100953242B1 KR100953242B1 KR1020047015255A KR20047015255A KR100953242B1 KR 100953242 B1 KR100953242 B1 KR 100953242B1 KR 1020047015255 A KR1020047015255 A KR 1020047015255A KR 20047015255 A KR20047015255 A KR 20047015255A KR 100953242 B1 KR100953242 B1 KR 100953242B1
- Authority
- KR
- South Korea
- Prior art keywords
- component
- aqueous
- weight
- polyol
- polyurethane system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/488—Other macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
- C04B41/4884—Polyurethanes; Polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
- C08G18/632—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
- C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
- C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/7806—Nitrogen containing -N-C=0 groups
- C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
- C08G18/7837—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing allophanate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Structural Engineering (AREA)
- Dispersion Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Saccharide Compounds (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2002113229 DE10213229A1 (de) | 2002-03-25 | 2002-03-25 | Wässrige 2K-PUR-Systeme |
| DE10213229.1 | 2002-03-25 | ||
| PCT/EP2003/002531 WO2003080752A1 (de) | 2002-03-25 | 2003-03-12 | Wässrige 2k-pur-systeme |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20040093478A KR20040093478A (ko) | 2004-11-05 |
| KR100953242B1 true KR100953242B1 (ko) | 2010-04-16 |
Family
ID=28050809
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020047015255A Expired - Fee Related KR100953242B1 (ko) | 2002-03-25 | 2003-03-12 | 수성 이액형 폴리우레탄계 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7005470B2 (enExample) |
| EP (1) | EP1490448B1 (enExample) |
| JP (1) | JP4143545B2 (enExample) |
| KR (1) | KR100953242B1 (enExample) |
| CN (1) | CN1328340C (enExample) |
| AT (1) | ATE363523T1 (enExample) |
| AU (1) | AU2003214119A1 (enExample) |
| CA (1) | CA2480062C (enExample) |
| DE (2) | DE10213229A1 (enExample) |
| DK (1) | DK1490448T3 (enExample) |
| ES (1) | ES2286412T3 (enExample) |
| MX (1) | MXPA04009266A (enExample) |
| WO (1) | WO2003080752A1 (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7195820B2 (en) * | 2003-12-09 | 2007-03-27 | Arkema Inc. | Core-shell polymers having hydrophilic shells for improved shell coverage and anti-blocking properties |
| US20060229409A1 (en) * | 2005-04-08 | 2006-10-12 | Ilmenev Pavel E | Method for preparing polyurethane dispersions |
| DE102005020269A1 (de) * | 2005-04-30 | 2006-11-09 | Bayer Materialscience Ag | Bindemittelgemische aus Polyasparaginsäureestern und sulfonatmodifizierten Polyisocyanaten |
| DE102005034344A1 (de) * | 2005-07-22 | 2007-01-25 | Umicore Ag & Co. Kg | Verfahren zur Reaktivierung thermisch gealterter Stickoxid-Speicherkatalysatoren |
| DE102006006100A1 (de) * | 2006-02-10 | 2007-08-16 | Basf Coatings Ag | Wässrige Mehrkomponentensysteme, Verfahren zu ihrer Herstellung und ihre Verwendung |
| WO2008148763A1 (en) * | 2007-06-05 | 2008-12-11 | Akzo Nobel Coatings International B.V. | Peelable temporary coating |
| US20090298989A1 (en) * | 2008-05-28 | 2009-12-03 | Funston Sr Randall A | 2K Waterborne Polyurethane Coating System and Methods Thereof |
| BRPI0912919B1 (pt) * | 2008-08-22 | 2019-04-24 | Dow Global Technologies Llc | Composição bicomponente e método para ligar dois ou mais substratos entre si |
| JP5415339B2 (ja) * | 2010-03-31 | 2014-02-12 | 旭化成ケミカルズ株式会社 | 架橋性水性樹脂組成物 |
| CN102212286B (zh) * | 2011-04-25 | 2013-06-19 | 上海应用技术学院 | 一种陶瓷示温涂层用牢度增强剂及其制备方法 |
| CN102558827B (zh) * | 2011-12-26 | 2016-06-15 | 上海金力泰化工股份有限公司 | 聚脲树脂组合物、其制备方法及其在汽车金属闪光漆中的应用 |
| WO2013157479A1 (ja) * | 2012-04-18 | 2013-10-24 | Dic株式会社 | 水性樹脂組成物、水性塗料及び該水性塗料の硬化塗膜を有する物品 |
| JP6165419B2 (ja) * | 2012-05-29 | 2017-07-19 | 旭化成株式会社 | 水系2成分型コーティング組成物、インキ組成物、及び接着剤組成物、並びにその使用方法 |
| EP2986681B1 (en) * | 2013-06-21 | 2019-08-21 | Dow Global Technologies LLC | An aqueous coating composition |
| CN103756605A (zh) * | 2013-12-27 | 2014-04-30 | 中科院广州化灌工程有限公司 | 一种低温快固乙烯基树脂堵漏材料及其制备方法与应用 |
| CN104877107A (zh) * | 2014-02-28 | 2015-09-02 | 拜耳材料科技(中国)有限公司 | 水性双组分聚氨酯涂料体系 |
| DE102014209183A1 (de) * | 2014-05-15 | 2015-11-19 | Evonik Degussa Gmbh | Reaktive Zusammensetzung aus einer Uretdiongruppen haltigen Dispersion und Polyaminen |
| JP2015045003A (ja) * | 2014-09-30 | 2015-03-12 | 理想科学工業株式会社 | インクジェット用インクセット及びインクジェット記録方法 |
| CN108473650A (zh) * | 2015-12-15 | 2018-08-31 | 巴斯夫欧洲公司 | 用于胶粘剂化合物的聚合物水分散体 |
| GB201609160D0 (en) * | 2016-05-25 | 2016-07-06 | Croda Europ Ltd | Polymeric coating compositions |
| KR102842826B1 (ko) | 2019-10-29 | 2025-08-06 | 다우 글로벌 테크놀로지스 엘엘씨 | 2-성분 폴리우레탄 조성물 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100230027B1 (ko) * | 1991-09-10 | 1999-11-15 | 빌프리더 하이더 | 코팅제, 그의 제조 방법 및 코팅 제조를 위한 그의 용도 |
| WO2000037522A1 (de) * | 1998-12-18 | 2000-06-29 | Bayer Aktiengesellschaft | Wässrige 2k-pur-systeme mit erhöhter schlagzähigkeit und guten beständigkeitseigenschaften, ein verfahren zu deren herstellung und deren verwendung |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3829587A1 (de) | 1988-09-01 | 1990-03-15 | Bayer Ag | Beschichtungsmittel, ein verfahren zu ihrer herstellung und die verwendung von ausgewaehlten zweikomponenten-polyurethansystemen als bindemittel fuer derartige beschichtungsmittel |
| DE4101696A1 (de) | 1991-01-22 | 1992-07-23 | Bayer Ag | Verwendung von zweikomponenten-systemen zur herstellung von einbrennbeschichtungen |
| DE4109477A1 (de) * | 1991-03-22 | 1992-09-24 | Henkel Kgaa | Fuer reaktivsysteme geeignete polymerdispersionen |
| DE4206044A1 (de) | 1992-02-27 | 1993-09-02 | Bayer Ag | Beschichtungsmittel, ein verfahren zu ihrer herstellung und ihre verwendung |
| DE19528939A1 (de) | 1995-08-07 | 1997-02-13 | Bayer Ag | Wäßrige, vernetzbare Bindemitteldispersionen mit niedrigem Lösemittelgehalt |
| DE19728411C2 (de) | 1997-07-03 | 2001-09-27 | Basf Coatings Ag | Polyurethanharz, Verfahren zu seiner Herstellung und seine Verwendung in wäßrigen Zweikomponenten-Klarlacken |
| CA2306120A1 (en) * | 1997-10-29 | 1999-05-06 | Mario Pschaidt | Aqueous polyurethane dispersions and coatings prepared therefrom |
| US6017998A (en) * | 1998-06-17 | 2000-01-25 | H.B. Fuller Licensing & Financing,Inc. | Stable aqueous polyurethane dispersions |
| DE19858732A1 (de) * | 1998-12-18 | 2000-06-21 | Bayer Ag | Wäßrige 2 K-PUR-Systeme mit erhöhter Schlagzähigkeit, hohen Beständigkeitseigenschaften und guten optischen Eigenschaften, ein Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE19929784A1 (de) | 1999-06-29 | 2001-01-04 | Bayer Ag | Bindemittelkombination für wäßrige Beschichtungen |
| DE10006539A1 (de) * | 2000-02-15 | 2001-08-16 | Conica Technik Ag Schaffhausen | Verwendung von wässrigen Polyurethan-Dispersionen in Formulierungen für rissüberbrückende Beschichtungssysteme |
| DE10043433A1 (de) | 2000-09-04 | 2002-03-21 | Bayer Ag | Wäßrige 2-K-PUR-Systeme |
| WO2002031021A1 (en) * | 2000-10-10 | 2002-04-18 | Polymer Coating Technologies Of Singapore Pte Ltd. | Low voc polyol alkyd dispersion and polyurethane dispersions |
-
2002
- 2002-03-25 DE DE2002113229 patent/DE10213229A1/de not_active Withdrawn
-
2003
- 2003-03-12 AU AU2003214119A patent/AU2003214119A1/en not_active Abandoned
- 2003-03-12 DK DK03709776T patent/DK1490448T3/da active
- 2003-03-12 KR KR1020047015255A patent/KR100953242B1/ko not_active Expired - Fee Related
- 2003-03-12 AT AT03709776T patent/ATE363523T1/de not_active IP Right Cessation
- 2003-03-12 DE DE50307374T patent/DE50307374D1/de not_active Expired - Lifetime
- 2003-03-12 ES ES03709776T patent/ES2286412T3/es not_active Expired - Lifetime
- 2003-03-12 MX MXPA04009266A patent/MXPA04009266A/es active IP Right Grant
- 2003-03-12 CN CNB03811951XA patent/CN1328340C/zh not_active Expired - Lifetime
- 2003-03-12 CA CA 2480062 patent/CA2480062C/en not_active Expired - Fee Related
- 2003-03-12 EP EP03709776A patent/EP1490448B1/de not_active Expired - Lifetime
- 2003-03-12 JP JP2003578487A patent/JP4143545B2/ja not_active Expired - Lifetime
- 2003-03-12 WO PCT/EP2003/002531 patent/WO2003080752A1/de not_active Ceased
- 2003-03-21 US US10/393,588 patent/US7005470B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100230027B1 (ko) * | 1991-09-10 | 1999-11-15 | 빌프리더 하이더 | 코팅제, 그의 제조 방법 및 코팅 제조를 위한 그의 용도 |
| WO2000037522A1 (de) * | 1998-12-18 | 2000-06-29 | Bayer Aktiengesellschaft | Wässrige 2k-pur-systeme mit erhöhter schlagzähigkeit und guten beständigkeitseigenschaften, ein verfahren zu deren herstellung und deren verwendung |
Also Published As
| Publication number | Publication date |
|---|---|
| US20030187134A1 (en) | 2003-10-02 |
| WO2003080752A1 (de) | 2003-10-02 |
| EP1490448B1 (de) | 2007-05-30 |
| JP2005520914A (ja) | 2005-07-14 |
| ATE363523T1 (de) | 2007-06-15 |
| ES2286412T3 (es) | 2007-12-01 |
| DE50307374D1 (de) | 2007-07-12 |
| AU2003214119A1 (en) | 2003-10-08 |
| JP4143545B2 (ja) | 2008-09-03 |
| EP1490448A1 (de) | 2004-12-29 |
| US7005470B2 (en) | 2006-02-28 |
| MXPA04009266A (es) | 2005-05-17 |
| DE10213229A1 (de) | 2003-10-16 |
| CA2480062A1 (en) | 2003-10-02 |
| DK1490448T3 (da) | 2007-09-10 |
| KR20040093478A (ko) | 2004-11-05 |
| CN1328340C (zh) | 2007-07-25 |
| CA2480062C (en) | 2011-08-09 |
| CN1656186A (zh) | 2005-08-17 |
| HK1081582A1 (zh) | 2006-05-19 |
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