KR100816663B1 - oval briquettes and method of recycle carbide - Google Patents
oval briquettes and method of recycle carbide Download PDFInfo
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- KR100816663B1 KR100816663B1 KR1020030099648A KR20030099648A KR100816663B1 KR 100816663 B1 KR100816663 B1 KR 100816663B1 KR 1020030099648 A KR1020030099648 A KR 1020030099648A KR 20030099648 A KR20030099648 A KR 20030099648A KR 100816663 B1 KR100816663 B1 KR 100816663B1
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/46—Solid fuels essentially based on materials of non-mineral origin on sewage, house, or town refuse
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
- C10L5/34—Other details of the shaped fuels, e.g. briquettes
- C10L5/36—Shape
- C10L5/361—Briquettes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
본 발명은 음식물 쓰레기 탄화물을 이용한 조개탄 조성물 및 제조방법에 관한 것으로서 좀더 상세히는, 공업용 및 산업용의 연소기구에 사용되는 조개탄을 음식물 쓰레기 탄화물과 토상흑연탄을 혼합한 조개탄 조성물 및 제조방법에 관한 것으로, 발열량을 높이면서 불순물이 적은 조개탄을 마련하여 공업용 및 산업용에 용이하고 또한 고가의 코크스 사용을 줄일 수 있으며 또한, 폐기식품을 재활용한 음식물 쓰레기 탄화물을 사용하므로 일상생활에서 배출되는 쓰레기를 적절하게 처리하는 이점이 있는 것이다.The present invention relates to a coal briquette composition and a manufacturing method using a food waste carbide, and more particularly, to a coal briquette composition and a method of manufacturing coal briquettes used in industrial and industrial combustion equipment mixed with food waste carbide and soil graphite. It is easy for industrial and industrial use to reduce the use of expensive coke by raising the calorific value while raising the calorific value, and also using food waste carbide recycled waste foods to properly handle the waste emitted from daily life There is an advantage.
즉, 수분 0.43%, 회분 9.43%, 휘발분 2.33%, 고정탄소 87.81%의 성분으로 발열량 6,910kcal/kg인 토상흑연 45% 와 수분 0.4%, 회분 10.83%, 휘발분 2.01%, 고정탄소 87.16%, 전유황 0.46%의 성분으로 발열량 6,910kcal/kg인 코크스 45%와 수분 4.93%, 회분 53.66%, 휘발분 17.78%, 고정탄소 23.62%, 전유황 0.02%의 성분으로 발열량 3,260kcal/kg인 음식물 쓰레기 탄화물 8% 를 혼합하여 잘게 분쇄하여 접착제 2%를 혼합하여 조개모양으로 성형한 후 건조시켜 완성하는 것을 특징으로 하는 음식물 쓰레기 탄화물을 이용한 조개탄 조성물 및 제조방법.That is, 45% of soil graphite with a calorific value of 6,910 kcal / kg and 0.4% of moisture, 10.83% of ash, 2.01% of volatile matter, 87.16% of total carbon with components of 0.43% moisture, 9.43% ash, 2.33% volatile matter and 87.81% fixed carbon. Food waste carbide with calorific value of 6,910 kcal / kg of coke 45% and moisture 4.93%, ash 53.66%, volatile matter 17.78%, fixed carbon 23.62%, total sulfur 0.02% and calorific value 3,260 kcal / kg Crushed coal composition and manufacturing method using a food waste carbide, characterized in that the mixture is finely pulverized by mixing the mixture 2% by molding and then dried to form a shell shape.
토상흑연, 탄화물, 코크스, 접착제Earth Graphite, Carbide, Coke, Adhesive
Description
본 발명은 음식물 쓰레기 탄화물을 이용한 조개탄 조성물 및 제조방법에 관한 것으로서 좀더 상세히는, 공업용 및 산업용의 연소기구에 사용되는 조개탄을 음식물 쓰레기 탄화물에 토상흑연탄과 코크스를 혼합한 조개탄 조성물 및 제조방법이다.
The present invention relates to a coal briquette composition and a manufacturing method using a food waste carbide, and more particularly, a coal briquette composition and a method of mixing the coal briquettes used in industrial and industrial combustion equipment in the food waste carbide mixed with soil graphite and coke.
일반적으로 조개탄은 고체연료의 일종으로 무연탄을 주원료로 하여 이것에 목탄분말(숯가루)와 콜라이트(coalite) 등을 혼합하고 전분을 점결제로서 첨가하여 조개 모양으로 성형 건조시킨 것으로, 1개는 약 50 g이며 대부분은 가정용으로 그 연소기구는 풍로, 작은 화로 등이다. 목탄분말로만 만들어진 조개탄은 성형목탄이라고 하며 성분은 수분 4 %, 회분 25 %, 휘발분 16 %, 고정탄소 55 %이며, 발열량은 5,800 kca1/kg이다.
In general, the coal briquettes are a kind of solid fuel, and anthracite coal is used as the main raw material, and charcoal powder (charcoal powder) and coalite are mixed and starch is added as a caking additive to form a shell-shaped dried one. It is about 50 g and most of it is for home use. Shell charcoal made only of charcoal powder is called charcoal. Its components are 4% moisture, 25% ash, 16% volatile matter, 55% fixed carbon, and the calorific value is 5,800 kca1 / kg.
그러나, 이러한 조개탄은 발열량이 낮아 가정용의 연소기구인 풍로, 화로, 난로에 사용이 가능하나 공업용 및 산업용으로는 그 사용이 어려워 주로 발열량이 높은 코크스를 사용하였다.
However, the coal briquettes have low calorific value, which can be used in furnaces, braziers, and stoves, which are domestic combustion appliances.
상기 통상적인 코크스(cokes)는 점결탄의 고온건류에 의해서 생기는 다공질 고체연료로서 해탄이라고도 하며, 회색을 띤 흑색이며, 금속성 광택을 지니며 고정탄소가 주성분이며, 회분, 휘발분을 약간 함유하며, 공업분석값은 보통 고정탄소 80∼94%, 회분 6∼18%, 휘발분 0.5∼2%이며, 원소분석값은 탄소 80∼92%, 수소 1∼1.5%, 질소 0.5∼0.9%, 산소 0.4∼0.7%, 황 0.5∼1%, 회분 6∼18%이다. 발열량은 1kg당 6,000∼7,500kcal, 착화온도는 400∼600℃이다.
The conventional cokes (cokes) is a porous solid fuel produced by high-temperature dry distillation of coking coal, also known as debris, grayish black, metallic luster, fixed carbon is the main component, and contains a small amount of ash, volatiles, industrial analysis Values are usually 80 to 94% fixed carbon, 6 to 18% ash, 0.5 to 2% volatile matter, and elemental analysis values are 80 to 92% carbon, 1 to 1.5% hydrogen, 0.5 to 0.9% nitrogen, and 0.4 to 0.7% oxygen. Sulfur 0.5 to 1%, ash 6 to 18%. The calorific value is 6,000-7,500kcal per kg and the ignition temperature is 400-600 ℃.
그러나, 이러한 코크스의 제조법은 분쇄한 석탄을 코크스로 안에 장입하고, 노벽에서 1,200℃의 온도로 가열하면 노벽에 가까운 부분부터 용해하기 시작해서 분해하여 휘발분을 발생한다. 이 용융상태에 있는 층의 온도가 더욱 상승해서 고화하여 코크스가 된다. 가열시간을 늘려서 노 안이 전부 코크스화하는 것을 기다렸다가 물을 뿌려 불을 끈다. 보통 16∼24시간동안 건류하여 제조하므로 발열량은 높으나 가격이 고가라서 원가를 높이는 요인이 발생하였다.
However, such a method of manufacturing coke is charged into the coke oven, and when heated to a temperature of 1,200 ° C. in the furnace wall, it starts to dissolve from the portion close to the furnace wall and decomposes to generate volatile matter. The temperature of the layer in the molten state is further raised to solidify to form coke. Increase the heating time, wait for the furnace to coke, and spray it to extinguish the fire. Normally, it is produced by distilling for 16 to 24 hours, so the calorific value is high but the price is high, causing the cost increase.
본 발명은 상술한 종래의 문제점을 해결하기 위한 것으로서, 위와같이 공업 용 및 산업용의 연소기구에 사용가능케 함유수분이 80% 이상이고 탄수화물과 소채류가 주성분인 폐기식품을 주성분으로 한 음식물 쓰레기 탄화물과 화강암, 섬록암, 유문암, 편마암 등 속에 맥 또는 렌즈 모양을 이루고 산출되어 접촉변질작용에 의하여 석탄에서 변성하여 탄층과 수반되는 토상흑연을 혼합한 조개탄을 발명한 것인데,The present invention has been made to solve the above-mentioned problems, food waste carbide and granite mainly composed of waste food containing 80% or more of water and carbohydrates and vegetables are the main component, which can be used in industrial and industrial combustion equipment as described above It was invented in the form of veins or lenticulars in diorite, rhyolite, gneiss, and the like, and modified into coal by contact transformation to mix coal beds and accompanying soil graphite.
이를 더욱 상세히 설명하면 다음과 같다.
This will be described in more detail as follows.
먼저 본 발명의 이해력을 높이기 위해 토상흑연과 음식물 쓰레기 탄화물에 대해 설명하겠습니다.
First, in order to improve the understanding of the present invention, we will explain the soil graphite and food waste carbide.
먼저 토상흑연에 대해 설명하자면 토상흑연은 흑연의 일종으로서 흑연은 석묵이라고도 하며 거의 순수한 탄소로 이루어지며 다이아몬드와 동질이상이며, 인상, 편상의 결정을 이루지만, 대부분은 괴상, 토상으로 때로는 콩 모양인 경우도 있다. 굳기 1 이하, 비중 1.9∼2.3으로 연하며 지방 모양의 감촉이 있고, 편상의 것은 휜다. 흑색으로 불투명하고 금속광택을 가지며, 조흔색은 흑색이다. 모양에 따라 인상흑연과 토상흑연으로 나누어 진다.
First of all, earth graphite is a kind of graphite, which is also called graphite, which is composed of almost pure carbon, is homogeneous with diamond, and forms crystals of impression and flake. In some cases. Hardness less than 1, specific gravity 1.9-2.3, fat-like texture, flaky ones are thin. It is opaque in black and has a metallic luster, and streaks are black. According to the shape, it is divided into impression graphite and soil graphite.
상기 인상흑연은 결정편암이나 편마암과 함께 산출되며, 흔히 그것에 수반되는 석회암 속에 산재한다. 토상흑연은 화강암, 섬록암, 유문암, 편마암 등 속에 맥 또는 렌즈 모양을 이루고 산출되며, 접촉변질작용에 의하여 석탄에서 변성하여 탄층과 수반하여 산출되며 흑연은 전기의 양도체이며, 연필심, 도가니, 전기로, 아크 등의 전극 등에 사용되며 활마재로도 사용된다.
The impression graphite is produced with crystalline schist or gneiss and is often scattered in the limestone that accompanies it. Soil graphite is produced in the shape of veins or lenses in granite, diorite, rhyolite, gneiss, etc., and it is converted from coal by contact metamorphism to be accompanied with coal seams. Graphite is a good conductor of electricity, pencil lead, crucible, electric furnace, It is used for electrodes such as arc, and also used as a lubricant.
그리고, 음식물 쓰레기 탄화물에 대해 설명하자면 수분이 80%이상이고 탄수화물과 소채류가 주성분인 폐기식품을 5 ~ 15mm로 파쇄하여 알갱이 상태로 만들어 알갱이 상태의 재료에 톱밥 또는 건조 폐기식품인 부 재료를 5 ~20% 혼가, 건조시켜 함유수분을 20 ~ 25%인 과립상으로 제조하고 과랍상의 재료를 연소용 탄화물의 형태와 크기로 성형하고, 탄화물의 형태로 성형한 재료를 함유 수분 10 ~ 15%로 건조시킨 다음 건조 고형재료를 건류 탄화시켜 건조시킨 것이다.
In addition, the food waste carbide is described as crushing the waste food containing more than 80% of water and carbohydrates and vegetables as 5 ~ 15mm into granules to make granules of the sawdust or dry waste foods 5 ~ 20% Honga and dried to prepare the water content into granules of 20 to 25% granules, and the excess material is molded into the shape and size of the burning carbide, dried into 10 to 15% moisture containing the material formed in the form of carbide The dried solid material is dried and carbonized and dried.
본 발명의 목적을 달성하기 위한 조개탄의 조성물로는 수분 0.43%, 회분 9.43%, 휘발분 2.33%, 고정탄소 87.81%의 성분으로 발열량 6,910kcal/kg인 토상흑연 45%와 수분 0.4%, 회분 10.83%, 휘발분 2.01%, 고정탄소 87.16%, 전유황 0.46%의 성분으로 발열량 6,910kcal/kg인 코크스 45%와 수분 4.93%, 회분 53.66%, 휘발분 17.78%, 고정탄소 23.62%, 전유황 0.02%의 성분으로 발열량 3,260kcal/kg인 음식물 쓰레기 탄화물 8% 와 접착제 2%를 혼합한 것이다.
Composition of the briquettes for achieving the object of the present invention is 453% soil graphite and 0.4% moisture, 10.83% ash with a calorific value of 6,910 kcal / kg as a component of 0.43% moisture, 9.43% ash, 2.33% volatile matter, 87.81% fixed carbon. , Volatile matter 2.01%, fixed carbon 87.16%, total sulfur 0.46%, coke 45% with calorific value 6,910kcal / kg, water 4.93%, ash 53.66%, volatile matter 17.78%, fixed carbon 23.62%, total sulfur 0.02% As a result, 8% of food waste carbide having a calorific value of 3,260 kcal / kg and 2% of adhesive were mixed.
또한, 본 발명의 목적을 달성하기 위한 조개탄의 제조방법으로는 수분 0.43%, 회분 9.43%, 휘발분 2.33%, 고정탄소 87.81%의 성분으로 발열량 6,910kcal/kg인 토상흑연 45% 와 수분 0.4%, 회분 10.83%, 휘발분 2.01%, 고정탄소 87.16%, 전유황 0.46%의 성분으로 발열량 6,910kcal/kg인 코크스 45%와 수분 4.93%, 회분 53.66%, 휘발분 17.78%, 고정탄소 23.62%, 전유황 0.02%의 성분으로 발열량 3,260kcal/kg인 음식물 쓰레기 탄화물 8%를 혼합하여 잘게 분쇄하여 접착제 2%를 혼합하여 조개모양으로 성형한 후 건조시켜 완성하는 것이다.In addition, as a method for producing briquettes for achieving the object of the present invention, 45% of earth graphite and 0.4% of moisture having a calorific value of 6,910 kcal / kg, with a component of 0.43% water, 9.43% ash, 2.33% volatile matter, and 87.81% fixed carbon. 10.83% of ash, 2.01% of volatile matter, 87.16% of fixed carbon, 0.46% of total sulfur, coke 45% with a calorific value of 6,910 kcal / kg, water 4.93%, ash 53.66%, volatile matter 17.78%, fixed carbon 23.62%, total sulfur 0.02 8% of food waste carbide with a calorific value of 3,260kcal / kg is mixed with finely pulverized, 2% of adhesive is mixed, molded into shells and dried.
상기 토상흑연의 성분은 제 1표와 같다.The components of the soil graphite are as shown in the first table.
[제 1표][Table 1]
상기 코크스의 성분은 제 2표와 같다. The components of the coke are as shown in the second table.
[제 3표][Table 3]
상기 음식물 쓰레기 탄화물의 성분은 제 3표와 같다.The components of the food waste carbide are shown in Table 3.
[제 3표][Table 3]
상기 접착제는 전분이나 옥수수가루 및 밀가구 또는 당분으로 사용하여도 무방하다.
The adhesive may be used as starch, corn flour, wheat flour or sugar.
상기와 같이 구성된 본 발명은 토상흑연과 코크스를 음식물 쓰레기 탄화물과 혼합하여 잘게 분쇄하여 접착제와 재혼합하여 조개탄을 완성하는 것으로, 상기 토상흑연의 성분중 큰 비중을 차지하고 있는 고정탄소 87.81%의 성분으로 인해 발열량을 높일수 있으며 또한, 전유황의 성분이 낮아 공업용과 산업용에 사용시 불순물 을 적게하여 높은 발열량을 얻을 수 있어 공업용 및 산업용에도 용이하게 작용한다.
The present invention configured as described above is mixed with ground garbage and coke with food waste carbide, finely pulverized and remixed with an adhesive to complete shellfish, due to the component of the fixed carbon 87.81% occupying a large proportion of the components of the soil graphite The calorific value can be increased, and the low sulfur content makes it possible to obtain high calorific value by reducing impurities when used for industrial and industrial purposes.
따라서, 본 발명은 상기한 바와 같이 재활용의 음식물 쓰레기 탄화물과 토상흑연을 혼합하여 발열량을 높이면서 불순물이 적은 조개탄을 마련하여 공업용 및 산업용에 용이하고 또한, 폐기식품을 재활용한 음식물 쓰레기 탄화물을 사용하므로 일상생활에서 배출되는 쓰레기를 적절하게 처리하므로 매립과 소각의 처리로인한 매립면적을 많이 차지하게 되고 또한, 유해중금속과 매연으로 인해 심한 공해를 유발하여 토양의 오염과 자연환경을 줄일 수 있는 이점이 있는 것이다.Therefore, the present invention uses the food waste carbide, which is easy for industrial and industrial use, by recycling the waste food waste carbide and the earth graphite, and preparing the pulverized coal with less impurities while increasing the calorific value. Since it properly handles the wastes emitted from daily life, it takes up a lot of landfill area due to landfill and incineration, and also has the advantage of reducing the pollution of the soil and the natural environment by causing severe pollution due to harmful heavy metals and soot. It is.
Claims (2)
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| Application Number | Priority Date | Filing Date | Title |
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| KR1020030099648A KR100816663B1 (en) | 2003-12-30 | 2003-12-30 | oval briquettes and method of recycle carbide |
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| KR1020030099648A KR100816663B1 (en) | 2003-12-30 | 2003-12-30 | oval briquettes and method of recycle carbide |
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| Publication Number | Publication Date |
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| KR20050070300A KR20050070300A (en) | 2005-07-07 |
| KR100816663B1 true KR100816663B1 (en) | 2008-03-26 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5725393A (en) | 1980-07-23 | 1982-02-10 | Iwano Kouyu Kk | Production of solid fuel |
| JPS5770193A (en) | 1980-10-20 | 1982-04-30 | Matsushita Electric Ind Co Ltd | Solid fuel |
| KR880014114A (en) * | 1987-05-27 | 1988-12-22 | 김창호 | Steel making charcoal |
| JPH1060464A (en) | 1996-08-21 | 1998-03-03 | Shinagawa Fuel Co Ltd | Formed charcoal and its production |
| JP2001329281A (en) | 2000-05-22 | 2001-11-27 | Seki Shoten:Kk | Solid fuel and process for preparing it |
-
2003
- 2003-12-30 KR KR1020030099648A patent/KR100816663B1/en not_active IP Right Cessation
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5725393A (en) | 1980-07-23 | 1982-02-10 | Iwano Kouyu Kk | Production of solid fuel |
| JPS5770193A (en) | 1980-10-20 | 1982-04-30 | Matsushita Electric Ind Co Ltd | Solid fuel |
| KR880014114A (en) * | 1987-05-27 | 1988-12-22 | 김창호 | Steel making charcoal |
| JPH1060464A (en) | 1996-08-21 | 1998-03-03 | Shinagawa Fuel Co Ltd | Formed charcoal and its production |
| JP2001329281A (en) | 2000-05-22 | 2001-11-27 | Seki Shoten:Kk | Solid fuel and process for preparing it |
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| KR20050070300A (en) | 2005-07-07 |
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