KR20150064935A - Refused Derived Fuel Produced by Mixing Chaff Powder and Paper Sludge - Google Patents
Refused Derived Fuel Produced by Mixing Chaff Powder and Paper Sludge Download PDFInfo
- Publication number
- KR20150064935A KR20150064935A KR1020130149876A KR20130149876A KR20150064935A KR 20150064935 A KR20150064935 A KR 20150064935A KR 1020130149876 A KR1020130149876 A KR 1020130149876A KR 20130149876 A KR20130149876 A KR 20130149876A KR 20150064935 A KR20150064935 A KR 20150064935A
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- South Korea
- Prior art keywords
- weight
- parts
- solid fuel
- powder
- paper sludge
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/403—Solid fuels essentially based on materials of non-mineral origin on paper and paper waste
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
- C10L5/445—Agricultural waste, e.g. corn crops, grass clippings, nut shells or oil pressing residues
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/08—Drying or removing water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/32—Molding or moulds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Landscapes
- Chemical & Material Sciences (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
Abstract
The present invention relates to a solid fuel produced by mixing 70 to 80 parts by weight of rice husk powder and 20 to 30 parts by weight of paper sludge.
Description
The present invention relates to a solid fuel produced by mixing rice hull powder with paper sludge, and more particularly, to a solid fuel produced by mixing rice hull powder and paper sludge produced by mixing 70 to 80 parts by weight of rice hull powder and 20 to 30 parts by weight of paper sludge ≪ / RTI >
The rice husk is a large-scale by-product produced in the process of paddy rice production, with about one million tons per year (as of 2011), but most of it is used as compost or used for livestock production. In fact. The reason why the utilization rate of the rice husk as the fuel is low is because the ignition temperature is relatively higher than that of a general solid fuel so that the fire does not stick well but the heat generation amount is lower than those. Therefore, attempts have been made to develop solid fuels having chimneys as the main material but mixing other wastes to increase the calorific value. For example, Korean Patent Application No. 1999-0000202 discloses a method for producing chaff and a method for producing the chaff which is produced by mixing the chaff powder ground with fine particles and the yellow clay powder obtained by removing the quartz and a method for producing the same, On the other hand, since yellow loess does not burn, it plays a role of binder and does not help firepower. Korean Patent Application No. 2012-0041071 also discloses that solidification using rice hull and dyeing sludge is performed by forming 30 to 70% by weight of dyeing sludge, 20 to 60% by weight of rice husks and 5 to 15% by weight of tar, Fuel and a manufacturing method thereof. However, the dyed sludge is originally low in calorie content, and therefore, even if it is mixed with rice hulls to compensate for low calorific value, the rice hull also has a high combustion temperature and low calorific value as described above, There is a problem that the cost increases.
It is necessary to produce solid fuel by using rice husk as a main raw material, which is generated as a byproduct of agriculture every year but is not utilized properly, and to supplement the low calorific value of the rice husk to produce a high calorific solid fuel. Furthermore, it is necessary to develop a solid fuel having a calorific value of 3,000 Kcal / Kg or more, without requiring simple and expensive equipment for producing the solid fuel.
The above problem can be solved by mixing the rice husk powder pulverized at 10 to 100 hours with the paper sludge to produce a solid fuel.
The above problem can be solved by mixing the rice husk powder crushed at 10 to 100 hours with the paper sludge and the char coal powder pulverized at 10 to 100 hours to produce a solid fuel.
The above problem can be solved by mixing the rice husk powder crushed at 10 to 100 hours with the paper sludge and the first hydrate iron sulfate powder or the first iron sulfate powder to prepare a solid fuel.
The above problem can be solved by mixing the rice husk powder pulverized at 10 to 100 hours with paper sludge and waste tire pieces pulverized at 10 to 100 hours to prepare a solid fuel.
The above problem can be solved by mixing the rice husk powder crushed with 10-100 mesh, papermaking sludge, charcoal powder crushed with 10-100 mesh and waste tire piece to produce solid fuel.
The above problem can be solved by mixing the rice husk powder crushed at 10 to 100 hours with the first hydrate iron sulfate powder or the first iron sulfate powder and the waste tire piece to prepare a solid fuel.
It is possible to recycle wastes by manufacturing solid fuel by mixing paper sludge which is generated and abandoned in large quantities when producing chaff and paper as much as agricultural by-products every year, and it is possible to solve the problem of garbage that has been raised as a social problem .
The present invention relates to a solid fuel produced by mixing 70 to 80 parts by weight of rice husk powder and 20 to 30 parts by weight of paper sludge. Hereinafter, the present invention will be described in detail.
The main material of the present invention is rice husk. However, in the present invention, in order to lower the ignition temperature of the rice husk which has a higher ignition temperature than other solid fuels and does not easily catch fire, the husks are dried to a moisture content of 5 to 10%, and the dried rice husk is pulverized to 10 to 100 mesh After being powdered, it was used as the main raw material of solid fuel. Thus, by finely grinding the rice husks, the ignition temperature can be greatly reduced. The characteristics of the rice hull used as a main material in the present invention are as follows.
In the present invention, 70 to 80 parts by weight of rice husk powder, which has been dried to a moisture content of 5 to 10% and then pulverized to 10 to 100 mesh, was blended.
Paper sludge is discharged in the form of a cake with a mixture of 70 ~ 80% by weight of water and 20 ~ 30% by weight of organic matter in the final process of paper making and discharged together with wastewater. It is decomposed by microorganisms into a fine powder phase. However, since the moisture content is 70 to 80% as described above, the powder is aggregated and becomes like a dead body.
In Korea, about 6.5 million tons of paper sludge is generated annually (as of 2004), and the disposal of such paper sludge is becoming a big problem. Paper sludge has been treated by incineration and landfill. However, the government has prohibited the dumping of paper sludge in the sea and announced the principles of land treatment through recycling. Thus, recycling technology of paper sludge is being tried.
Paper sludge is classified as a low carbon-based fuel because it contains 20 to 30% by weight of organic matter and has a calorific value of 1,000 kcal / kg or more by itself. Therefore, when paper solid sludge is mixed with rice hull powder to produce solid fuel, paper sludge can be used without discarding, and the heating value of solid fuel can be increased. The properties of paper sludge are as follows.
As shown in the above table, paper sludge has a very high moisture content of 70 ~ 80%. Therefore, it is dehydrated to a moisture content of 30 ~ 40% by using a dehydrator commonly used in industry and then mixed with rice husk powder.
When the paper sludge is dewatered and mixed with the rice hull powder, the rice hull powder absorbs the moisture of the paper sludge, thereby lowering the overall moisture content, and the moisture content of the rice hull powder and the paper sludge mixture becomes 20 to 25%.
On the other hand, paper sludge has its own binder component in addition to calorie, so it is well-solidified when an appropriate amount of water is present. Therefore, if rice husk powder and paper sludge with 30 ~ 40% moisture content are mixed and formed, they can be solidified even if no binder is added, so that solid fuel having a moisture content of 20 ~ 25% can be produced. The volume of the solid fuel is not particularly limited. For example, it is appropriate that the length and the length are 40 to 70 mm and the height is 20 to 60 mm.
In the present invention, 20 to 30 parts by weight of paper sludge having a moisture content of 30 to 40% was compounded to prepare a solid fuel.
The properties of the solid fuel thus prepared and the produced fuel are as follows.
Therefore, the present invention relates to a method for producing a sludge-containing sludge, which comprises drying 70 to 80 parts by weight of rice husk powder pulverized to 10 to 100 mesh, and 20 to 30 parts by weight of paper sludge having a moisture content of 30 to 40% 20 to 25%, and then molding the solid fuel.
The solid fuel produced as described above can be sufficiently used as fuel, but paper sludge is discharged together with wastewater and recovered at the wastewater treatment plant, so that it is highly odorous. Even when mixed with rice husk powder, the odor does not disappear, The odor is discharged even during use as a process or fuel. Therefore, charcoal was blended to remove odor from solid fuel.
Charcoal is a carbon lump material composed of 85% carbon, 10% water and 3% minerals (calcium, potassium, magnesium, iron, etc.). Charcoal burns the wood while burning the oxygen, and then burns the ash with the ash, and burns out. In this way, charcoal has a lot of porosity (as a result, it has a surface area of several hundreds of m 2 per 1 g of char surface area) and adsorbs and purifies odor inducing substances, organic substances in water, inorganic substances, .
In addition, charcoal is strong enough to be used not only as food for cooking from ancient times but also as a fuel when iron is separated from iron ore. Therefore, when the charcoal is powdered and mixed with the solid fuel, odor can be removed and the thermal power of the solid fuel can be greatly increased.
Accordingly, as a second embodiment of the present invention, 70 to 80 parts by weight of rice hull powder pulverized to 10 to 100 mesh and dried to a moisture content of 5 to 10% and 20 to 30 parts by weight of paper sludge having a moisture content of 30 to 40% And 10 to 20 parts by weight of charcoal powder pulverized to 10 to 100 mesh with respect to 100 parts by weight of the solid fuel produced by mixing the powders.
As a third embodiment of the present invention, a first hydrate iron sulfate (FeSO4 · HO) powder or a first iron sulfate (FeSO4) powder having a low cost instead of char is added to the solid fuel to remove odor of paper sludge. That is, since the first hydrate iron sulfate powder and the first iron sulfate powder are excellent in the ability to adsorb odors and remove odors, they are dried to a moisture content of 5-10% And 20 to 30 parts by weight of a paper sludge having a water content of 30 to 40%, based on 100 parts by weight of a solid fuel prepared by blending 10 to 20 parts by weight of a first hydrate iron sulfate powder or a first iron sulfate powder Providing a solid fuel that is characterized.
As a fourth embodiment of the invention, a method for further increasing the calorific value of the solid fuel produced by mixing the rice hull powder and the paper sludge is a method in which a mixture of the rice husk powder and paper sludge is pulverized into a waste tire piece .
With the rapid increase in the number of cars, waste tires have been a social issue for a long time in Korea. In the meantime, the number of automobile waste tires has increased by more than four times the number of automobiles that have been increased. Therefore, the number of waste tires has also increased greatly. However, only about 50 ~ 60% of these waste tires are recycled and the rest are secretly processed by illegal incineration and illegal landfill Causing environmental pollution. However, if the tire is burned in its entirety, the environmental pollution problem may arise. However, the waste tire piece that is pulverized by 10 ~ 100 mesh and the iron core is removed is a renewable energy source classified as solid fuel.
Therefore, in the present invention, it is preferable that 70 to 80 parts by weight of the rice husk powder, which is dried to have a moisture content of 5 to 10% and pulverized to 10 to 100 mesh, and 20 to 30 parts by weight of paper sludge having a moisture content of 30 to 40% And 10 to 20 parts by weight of a piece of waste tire obtained by crushing 10 to 100 meshes to 100 parts by weight of fuel and from which an iron core has been removed, followed by molding.
As a fifth embodiment of the present invention, a solid fuel can be produced by further adding charcoal powder and waste tire pieces. That is, 5 to 20 parts by weight of charcoal powder pulverized to 10 to 100 mesh with respect to 100 parts by weight of solid fuel produced by mixing rice hull powder and paper sludge, pulverized to 10 to 100 mesh, The solid fuel can be remarkably increased in the amount of the solid fuel and the odor of the paper sludge can be removed.
Accordingly, the present invention relates to a method for producing a solid product, which comprises drying 70 to 80 parts by weight of rice hull powder pulverized to 10 to 100 mesh and drying 20 to 30% of water content, and 20 to 30 parts by weight of paper sludge having a moisture content of 30 to 40% 5 to 20 parts by weight of charcoal powder pulverized to 10 to 100 mesh with respect to 100 parts by weight of fuel and 5 to 20 parts by weight of pulverized tire tire pieces with 10 to 100 mesh and iron core removed are blended and then pelletized It provides solid fuel.
As a sixth embodiment of the present invention, a solid fuel can be produced by further adding a first hydrate iron sulfate powder or a first iron sulfate powder and a waste tire piece. That is, 5 to 20 parts by weight of the first hydrate iron sulfate powder or the first iron sulfate powder was pulverized into 10 to 100 mesh and 100 parts by weight of the solid tire fuel produced by mixing the rice husk powder and the paper sludge, To 20 parts by weight of the solid fuel to produce solid fuel, the amount of heat of the solid fuel can be dramatically increased, and the odor of the paper sludge can be removed.
Accordingly, the present invention relates to a method for producing a solid product, which comprises drying 70 to 80 parts by weight of rice hull powder pulverized to 10 to 100 mesh and drying 20 to 30% of water content, and 20 to 30 parts by weight of paper sludge having a moisture content of 30 to 40% 5 to 20 parts by weight of a first hydrate of iron sulfate powder or first iron sulfate powder and 10 to 100 parts by weight of a first hydrate of iron powder and 5 to 20 parts by weight of a waste tire piece from which an iron core has been removed are blended and then pelletized Providing a solid fuel that is characterized.
Claims (6)
Charcoal powder pulverized into 10 to 100 mesh was mixed with 100 parts by weight of solid fuel
And 10 to 20 parts by weight of the solid fuel
Wherein the solid fuel is prepared by adding 10 to 20 parts by weight of a first hydrate of iron sulfate or a first iron sulfate powder to 100 parts by weight of the solid fuel,
And 10 to 20 parts by weight of a piece of waste tire pulverized to 10 to 100 mesh is added to 100 parts by weight of the solid fuel and then molded.
5 to 20 parts by weight of charcoal powder pulverized to 10 to 100 mesh with respect to 100 parts by weight of the solid fuel, 5 to 20 parts by weight of pulverized waste tire pieces having been pulverized to 10 to 100 mesh, Solid fuel
5 to 20 parts by weight of the first hydrate of iron sulfate powder or the first iron sulfate powder and 10 to 100 parts by weight of the first hydrate iron powder and 5 to 20 parts by weight of the waste tire piece from which the iron core has been removed are added to 100 parts by weight of the solid fuel, ≪ RTI ID = 0.0 > solid fuel
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020130149876A KR101530552B1 (en) | 2013-12-04 | 2013-12-04 | Refused Derived Fuel Produced by Mixing Chaff Powder and Paper Sludge |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020130149876A KR101530552B1 (en) | 2013-12-04 | 2013-12-04 | Refused Derived Fuel Produced by Mixing Chaff Powder and Paper Sludge |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20150064935A true KR20150064935A (en) | 2015-06-12 |
| KR101530552B1 KR101530552B1 (en) | 2015-06-26 |
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| Application Number | Title | Priority Date | Filing Date |
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| KR1020130149876A KR101530552B1 (en) | 2013-12-04 | 2013-12-04 | Refused Derived Fuel Produced by Mixing Chaff Powder and Paper Sludge |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102000924B1 (en) | 2018-11-08 | 2019-07-17 | 주식회사 다인피에스피 | Eco-friendly compost comprising paper sludge, coffee grounds and steel slag powder for supplement of carbon source and mineral elements |
| KR102101357B1 (en) | 2019-07-12 | 2020-04-17 | (주)피엔피컴퍼니 | Eco-friendly organic and inorganic hybrid compost comprising paper sludge, brewers grain and steel slag powder for supplement of carbon source, amino acid and mineral elements |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR940003907B1 (en) * | 1991-02-12 | 1994-05-09 | 구선희 | Method of making solid fuel |
| KR101006011B1 (en) * | 2008-09-04 | 2011-01-05 | 김원두 | pellet |
| KR101296011B1 (en) * | 2011-11-14 | 2013-08-12 | 박수철 | Fuel pellets using sludge |
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| Publication number | Publication date |
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| KR101530552B1 (en) | 2015-06-26 |
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