KR100809607B1 - Processing mothod and processing equipment for excretions of animals - Google Patents

Processing mothod and processing equipment for excretions of animals Download PDF

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KR100809607B1
KR100809607B1 KR1020060088345A KR20060088345A KR100809607B1 KR 100809607 B1 KR100809607 B1 KR 100809607B1 KR 1020060088345 A KR1020060088345 A KR 1020060088345A KR 20060088345 A KR20060088345 A KR 20060088345A KR 100809607 B1 KR100809607 B1 KR 100809607B1
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methane
acid fermentation
sludge
treatment
treated water
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유대환
김장규
김현철
음영진
윤용준
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주식회사 부강테크
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • C02F11/04Anaerobic treatment; Production of methane by such processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C02F11/128Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using batch processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/20Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/20Sludge processing

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
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Abstract

A method and an apparatus for treating livestock excretion are provided to purify the livestock excretion and collect resources efficiently, by performing a pretreatment process, an adjustment process, a methane fermentation process, a temperature decrease process, and a bath reaction process, and three treatment processes on the livestock excretion. A pretreatment process is performed by removing adulterant and sediment from livestock excretion(S210). An adjustment process is performed by homogenizing the flow rate and concentration of the livestock excretion passed by the pretreatment process(S220). An acid fermentation process is performed by converting the homogenized livestock excretion into dissolvable organic matter through acid fermentation and performing solid-liquid separation through precipitation(S230). A methane fermentation process is performed by recovering methane gas and precipitating sludge from the dissolvable organic matter through methane fermentation(S240). A temperature decrease process is performed by decreasing the temperature of the treated water, which is generated during the methane fermentation process, to a temperature suitable for aerobic treatment, 30‹C(S250). A batch reaction process is performed by removing residual organic matter and nutrient salt and precipitating sludge from the treated water, which is generated during the temperature decrease process(S260). A refinement process is performed by removing carbon dioxide, hydrogen sulfide, and moisture from the methane gas generated during the methane fermentation process. A cogeneration process is performed by collecting electricity and waste heat using the refined methane. A dehydration process is performed by dehydrating the sludge generated during the acid fermentation process and the methane fermentation process. A dry process is performed by drying the dehydrated sludge using the waste heat. Further, a third treatment process is performed by removing additionally hardly-degradable organic compounds and nutritive salts remaining after the batch reaction process.

Description

축산분뇨의 처리 방법 및 처리시설{PROCESSING MOTHOD AND PROCESSING EQUIPMENT FOR EXCRETIONS OF ANIMALS}PROCESSING MOTHOD AND PROCESSING EQUIPMENT FOR EXCRETIONS OF ANIMALS}

도1은 종래의 축산분뇨 처리공정의 개략도,1 is a schematic diagram of a conventional livestock waste treatment process,

도2는 본 발명의 축산분뇨 처리공정의 흐름도,2 is a flow chart of the livestock waste treatment process of the present invention,

도3은 본 발명의 축산분뇨 처리시설의 실시예를 보여주는 도면이다.3 is a view showing an embodiment of a livestock waste treatment facility of the present invention.

*** 도면의 주요부분에 대한 부호의 설명 ****** Explanation of symbols for main parts of drawing ***

310;전처리 시설 320;조정조310; pretreatment facility 320; adjustment tank

330;산발효조 331:처리수 우회라인330 acid fermentation tank 331: water bypass line

340;메탄발효조 341;처리수 반송라인340; methane fermentation tank 341; treated water return line

350;열교환기 360;회분식반응조;350; heat exchanger 360; batch reactor;

361;슬러지 반송라인 370;3차처리시설361; Sludge Return Line 370; Tertiary Treatment Facility

380;탈수시설 381;건조시설380; dehydration facility 381; drying facility

390;정제시설 391;발전시설390; Refinery 391; Power Plant

본 발명은 축산분뇨 처리방법에 관한 것으로, 더욱 상세하게는 축산분뇨를 전처리공정, 조정공정, 혐기성공정, 온도저감공정, 고도처리공정, 3차처리공정으로 구성함으로써, 축산분뇨를 효율적으로 정화처리하고 자원을 회수하는 방법에 관한 것이다.The present invention relates to a livestock manure treatment method, more specifically, by the livestock manure consisting of pretreatment step, adjustment step, anaerobic step, temperature reduction step, advanced treatment step, tertiary treatment step, the livestock manure efficiently And recovering resources.

축산분뇨는 고형물, 유기물, 질소의 함량이 높아 처리하기 어려운 폐수로 알려져 있다. 기존의 축산분뇨 처리방법은 도1에 나타낸 바와 같이, 1차로 전처리로서 물리화학적 공정을 통하여 고형물을 제거하고, 2차로 생물학적 고도처리공정을 통하여 잔류 유기물 및 영양염류를 제거하며, 3차로 물리화학적 공정을 통해 잔류하는 오염물질을 제거한다.Livestock manure is known to be difficult to treat due to its high solids, organic matter and nitrogen content. Existing livestock manure treatment method, as shown in Figure 1, as a first pretreatment to remove the solids through the physicochemical process, secondly to remove the residual organic matter and nutrients through the biological advanced treatment process, and to the third physicochemical process Removes any remaining contaminants.

축산폐수와 같이 고농도의 질소를 함유하는 폐수를 처리하여 처리수내의 질소농도를 낮게 유지하기 위해서는 호기성조건에서 질산화가 완료된 후 (후)탈질공정이 필요하게 되는데, 질산화를 위한 호기성조건에서 폐수내의 유기물이 모두 산화되어 버리기 때문에 탈질공정에서 유기물을 효율적으로 이용할 수 없게 되는 문제가 발생하였다. 즉, 후탈질소화는 전단계의 질산화 반응 후 잔존하는 질산화된 질소를 완전히 제거하는 공정으로서 탈질을 위한 유기물을 확보하기 위해 메탄올과 같은을 외부탄소원을 추가적으로 주입해야 하므로 경제적으로 불리한 문제가 있었다.In order to maintain low nitrogen concentration in treated water by treating wastewater containing high concentration of nitrogen like livestock wastewater, after nitrification is completed in aerobic condition, denitrification process is required, and organic matter in wastewater under aerobic condition for nitrification. Since all of them are oxidized, a problem arises in that the organic substance cannot be efficiently used in the denitrification step. In other words, post-denitrification is a process of completely removing the nitrified nitrogen remaining after the nitrification of the previous step, and thus, it is economically disadvantageous to additionally inject an external carbon source such as methanol to secure an organic material for denitrification.

그리고 기존의 호기성공정이 기본이 되는 축산폐수 처리방법은 혐기성처리방법에 비해 슬러지 생성량이 많고, 그 처리에 에너지 소모가 높으며 유용한 자원인 유기물을 효율적으로 회수하지 못하는 단점이 있고 특히 고농도 유기물이 함유된 폐수에 적합하지 않은 문제점이 있었다.In addition, the livestock wastewater treatment method on which the existing aerobic process is based has a disadvantage of producing sludge more than anaerobic treatment method, having high energy consumption and efficiently recovering organic matter, which is a useful resource, and especially containing high concentration organic matter. There was a problem that was not suitable for waste water.

본 발명은 이러한 문제점을 해결하기 위해 축산분뇨의 자원화 가능부분을 최대로 활용하고 안정적인 처리수질을 확보할 수 있는 축산분뇨의 처리방법을 제공하는 것을 목적으로 한다.An object of the present invention is to provide a method for treating livestock manure that can maximize the resources available to the livestock manure in order to solve these problems and ensure a stable treated water quality.

본 발명은 축산분뇨 내의 유기물을 혐기성 공정을 거쳐 메탄가스를 회수하여 열병합발전을 통해 전기 및 폐열을 생산하며 폐열은 다시 축산분뇨의 처리공정에 이용함을 목적으로 한다.The present invention is to recover the methane gas through the anaerobic process of the organic matter in the livestock manure to produce electricity and waste heat through cogeneration, the waste heat is again used for the treatment process of livestock manure.

또한 축산분뇨로부터 발생하는 슬러지량을 최소화하고 건조를 통하여 안전하고 취급이 용이한 퇴비를 회수함을 목적으로 한다.In addition, it aims to minimize the amount of sludge generated from livestock manure and recover the compost which is safe and easy to handle through drying.

상기와 같은 목적을 달성하기 위하여 본 발명의 축산분뇨 처리방법은, 축산분뇨에 포함된 협잡물 및 침사물질을 제거하는 전처리 공정;상기 전처리 공정에 의해 처리된 상기 축산분뇨의 유량 및 농도를 균질화하는 조정공정;상기 균질화된 입자상태의 측산분뇨 유기물을 산발효조로 유입시켜 산발효를 통해 용존상태로 전환시키고 침전을 통해 고액분리를 수행하는 산발효 공정;상기 산발효공정에서 처리된 용존상태의 유기물로부터 메탄을 회수하는 메탄발효공정;상기 메탄발효공정의 처리수를 온도저감시설로 유입시켜 이어지는 호기성처리에 적정한 온도인 30℃ 이하로 처리수의 온도를 저하시키는 온도저감공정;상기 온도가 저하된 혐기성 처리공정을 통과한 처리수로부터 잔류 유기물 및 영양염류를 제거하는 고도처리공정인 회분식반응공정;및 추가적인 난분해성 유기물 및 질소를 제거하기 위한 3차처리공정;을 포함하는 것을 특징으로 한다.Livestock manure treatment method of the present invention to achieve the above object, the pretreatment step of removing contaminants and sediment contained in the livestock manure; adjusting to homogenize the flow rate and concentration of the livestock manure treated by the pretreatment step An acid fermentation step of converting the homogenized particulate acidic manure organic material in the granular state into an acid fermentation tank, converting it into a dissolved state through acid fermentation, and performing solid-liquid separation through precipitation; from the dissolved organic matter treated in the acid fermentation process A methane fermentation process for recovering methane; a temperature reduction process for introducing the treated water of the methane fermentation process into a temperature reducing facility to lower the temperature of the treated water to 30 ° C. or lower, which is a temperature suitable for subsequent aerobic treatment; A batch reaction process which is a highly treated step of removing residual organic matter and nutrients from the treated water passing through the treatment step; Characterized in that it comprises; I further tertiary treatment process for removing the decomposable organic matter and nitrogen.

또한 본 발명에서는 상기 회분식 반응공정에 필요한 유기물을 공급하여 C/N, C/P를 조정하기 위하여, 상기 산발효공정을 통과한 처리수를 상기 회분식 반응공정으로 일부 우회시키는(by-pass) 산발효공정 처리수 우회공정과, 상기 메탄발효공정의 처리수 일부를 상기 산발효공정으로 반송하여 재처리함으로써 산발효공정의 pH저하를 방지하고 알카리도를 확보하는 메탄발효조 처리수 재처리공정을 더 포함하는 것을 특징으로 한다.In the present invention, in order to supply the organic matter required for the batch reaction step to adjust the C / N, C / P, the acid which partially bypasses the treated water passed through the acid fermentation step to the batch reaction step (by-pass) It further includes a fermentation process bypassed water and a methane fermentation tank treated water reprocessing process to prevent the pH lowering of the acid fermentation process and to ensure alkalinity by returning and partially treating the treated water of the methane fermentation process to the acid fermentation process. Characterized in that.

상기 메탄발효공정을 통하여 생성된 메탄가스에 포함된 이산화탄소, 황화수소, 및 습기를 제거하는 정제공정 및 열병합발전 공정을 더 포함함으로써 상기 정제된 메탄을 이용하여 전기 및 폐열을 회수하는 것을 특징으로 한다. 상기 회수된 폐열은 슬러지 건조공정, 산발효공정 및 메탄발효공정으로 순환시켜서 재사용된다.The method further includes a purification process for removing carbon dioxide, hydrogen sulfide, and moisture contained in the methane gas produced through the methane fermentation process, and a cogeneration process, thereby recovering electricity and waste heat using the purified methane. The recovered waste heat is recycled to the sludge drying process, acid fermentation process and methane fermentation process.

회분식반응공정에서 폐기된 슬러지는 슬러지 생산량을 최소화하고 산발효공정의 암모니아 농도를 희석하여 혐기성 공정의 암모니아 독성을 제거하기 위하여, 상기 조정공정으로 반송하여 재처리된다.The sludge discarded in the batch reaction process is returned to the control process and reprocessed to minimize sludge production and dilute the ammonia concentration in the acid fermentation process to remove ammonia toxicity in the anaerobic process.

또한 상기 산발효공정 및 메탄발효공정을 통하여 발생된 슬러지는 탈수공정;및 상기 폐열을 이용한 건조공정을 통해 퇴비를 생산하여 이용된다.In addition, the sludge generated through the acid fermentation process and the methane fermentation process is used to produce compost through the dehydration process; and the drying process using the waste heat.

도 2에 도시된 바와 같이, 본 발명이 제안하는 축산분뇨 처리방법은 축산분뇨에 포함된 협잡물 및 침사물질을 제거하는 전처리단계(S210)와, 상기 전처리 단계를 거친 축산분뇨를 유량조정조로 유입하여 축산분뇨의 유량 및 농도를 균질화하는 조정단계(S220), 혐기성 처리 공정으로서 1차로 산발효조에서 고형물 형태로 존 재하는 축산분뇨 내의 유기물을 가수분해(hydrolysis) 및 산생성 단계를 거쳐 용존성 유기물로 전환하는 산발효 단계(S230), 2차로 상기 산발효조에서 전환된 용존성 유기물을 메탄발효조에서 메탄발효를 통하여 메탄(CH4)으로 회수하는 메탄발효단계(S240), 상기 혐기성 반응조를 통과한 처리수를 온도저감시설(열교환기)로 유입시켜 이어지는 호기성처리에 적정한 온도(30℃ 이하)로 저하시키는 온도저감단계(S250), 상기 열교환기를 거친 처리수를 회분식 반응조에서 잔류하는 유기물 및 영양염류(질소 및 인)를 제거하는 회분식반응단계(S260), 방류슈질기준이 높을경우 상기 회분식 반응조 후단에 3차처리시설을 도입하여 잔류하는 난분해성 유기물 및 질소, 영양염류를 추가적으로 제거하는 3차처리단계(S270)를 포함한다. 축산분뇨의 처리공정을 자세히 설명하면 다음과 같다.As shown in Figure 2, the livestock manure treatment method proposed by the present invention is a pretreatment step (S210) for removing the contaminants and sediment contained in the livestock manure and the livestock manure through the pretreatment step flows into the flow adjustment tank Adjustment step for homogenizing the flow rate and concentration of livestock manure (S220), as an anaerobic treatment process, the organic matter in the livestock manure, which is present in solid form in an acid fermentation tank, is first converted into a dissolved organic matter through hydrolysis and acid production steps. Acid fermentation step of converting (S230), the methane fermentation step of recovering the dissolved organic matter converted in the acid fermentation tank to methane (CH 4 ) through the methane fermentation in the methane fermentation tank (S240), the treatment passed through the anaerobic reactor A temperature reduction step (S250) for introducing water into a temperature reduction facility (heat exchanger) and lowering the temperature to a temperature (30 ° C. or lower) suitable for subsequent aerobic treatment. Batch reaction step (S260) to remove the residual organic matter and nutrients (nitrogen and phosphorus) in the batch water reactor, if the discharge water quality is high, by introducing a tertiary treatment facility to the rear end of the batch reactor, the remaining hardly decomposable organic matter and Nitrogen, nutrients further comprises a third step (S270). Detailed description of the livestock manure treatment process is as follows.

1. 전처리공정(1. Pretreatment process ( S210S210 ))

전처리로 축산분뇨에 포함된 협잡물 및 침사물질을 제거한다.Pretreatment removes contaminants and sediment contained in livestock manure.

2. 2. 조정공정(Adjustment process S220S220 ))

상기 전처리 단계를 거친 축산분뇨를 유량조정조로 유입하여 유입된 축산분뇨의 유량 및 농도를 균질화한다. The livestock manure that has passed through the pretreatment step is introduced into the flow adjusting tank to homogenize the flow rate and concentration of the livestock manure.

3.혐기성 처리 공정3. Anaerobic treatment process

혐기성 반응처리 공정은 축산폐수내의 유기물을 미생물이 섭취 용이한 유기산으로 전환시켜 최종적으로 메탄으로 회수하기 위한 반응이다.The anaerobic reaction process is a reaction for converting organic matter in livestock wastewater into organic acid, which is easily ingested by microorganisms, and finally recovering it to methane.

혐기성 공정은 다양한 혐기성균(산소를 필요로 하지 않는 미생물에 의한 발 효)에 의해 유기물을 분해하는 공정으로서, 혐기성공정의 유기물 분해단계 및 각 단계에 관계되는 미생물을 나타내면 다음과 같다.Anaerobic process is a process of decomposing organic matter by various anaerobic bacteria (fermentation by microorganisms that do not require oxygen), and the organic decomposition step of the anaerobic process and the microorganisms related to each step are as follows.

혐기성공정의 유기물 분해단계 및 관계되는 미생물Degradation step of organic matter in anaerobic process and related microorganisms 단계step 명칭 designation 관련 미생물 Related Microorganisms 1One SolubilizationSolubilization AcidogenicAcidogenic 22 AcidogenesisAcidogenesis 33 AcetogenesisAcetogenesis AcetogenicAcetogenic 44 MethanogenesisMethanogenesis MethanogenicMethanogenic

고농도 축산폐수를 처리하는 과정에서 혐기적 처리를 하게 되면 첫단계에서 는 가수분해나 용해가 일어나서 고분자화합물이 단위체로 되고, 두번째 단계가 acidogenesis(산생성단계)인데 단순 단위체가 휘발성 지방산(fatty acid)으로 전환되는 과정이며, 세번째 단계는 초산생성단계이고 4번째는 메탄생성단계이다.Anaerobic treatment in the treatment of high concentration livestock wastewater causes the hydrolysis or dissolution to occur in the first stage, and the polymer compound becomes a monomer, and the second stage is acidogenesis, and the simple unit is volatile fatty acid. The third step is acetic acid production and the fourth is methane production.

이러한 반응단계는 크게 산생성단계(Acidogenesis)와 메탄생성단계(Methanogenesis)로 나누기도 하는데, 각 단계에서의 적정 pH는 산생성단계(Acidogenesis)는 6.0~7.0이며 메탄생성단계(Methanogenesis)는 7.0~8.0으로 다르다. 이러한 이유 때문에 각 단계의 최적 효율을 얻기 위하여 본 발명의 혐기성공정은 2상(two phase)으로 구성되며, 제1반응조는 산발효조이고, 제2반응조는 메탄발효조로 운영한다.These reaction stages can be divided into two stages: acid production and methanogenesis. The appropriate pH at each stage is 6.0-7.0 for acid production and 7.0- for methanogenesis. Differs from 8.0. For this reason, the anaerobic process of the present invention consists of two phases in order to obtain the optimum efficiency of each stage, the first reactor is an acid fermentation tank, the second reactor is operated as a methane fermentation tank.

(1)(One) 산발효공정Acid Fermentation Process (( S230S230 ))

상기 균질화된 입자상태의 측산분뇨 유기물을 산발효조로 유입시켜 산발효를 통해 용존상태로 전환시키고 침전을 통해 고액분리를 수행하는 산발효 공정; An acid fermentation process of introducing the homogenized particulate acidic manure organic material into an acid fermentation tank, converting it into a dissolved state through acid fermentation, and performing solid-liquid separation through precipitation;

제1반응조인 산발효조에서는 고형물 형태로 존재하는 축산분뇨 내의 유기물을 가수분해(hydrolysis) 및 산생성 단계를 거쳐 용존상태로 전환시키고 침전을 통해 고액분리를 수행하게 된다. 혐기성공정의 경우 산생성반응조에서는 산(acid)이 주로 생성되기 때문에 산의 형성에 따른 pH저하가 발생하며 과도하게 pH가 저하될 경우 미생물활성이 저하되는 문제가 발생한다. 이를 방지하기 위하여 기존에는 알카리제를 주입하게 되는데 별도의 약품을 구입하여야 하기 때문에 경제적으로 불리한 문제점이 있었다.In the first fermentation tank, the acid fermentation tank converts the organic matter in the livestock manure, which is present in solid form, into a dissolved state through hydrolysis and acid production, and performs solid-liquid separation through precipitation. In the anaerobic process, since acid is mainly produced in the acid production reactor, a pH decrease occurs due to the formation of an acid, and when the pH is excessively reduced, microbial activity decreases. In order to prevent this, there is an economic disadvantage because the conventional injection of an alkaline agent has to purchase a separate drug.

따라서 본 발명에서는 이를 방지하기 위하여 제2반응조인 메탄발효조를 통과한 처리수 일부를 산발효조로 반송시켜 알카리도를 보충하도록 한다.Therefore, in the present invention, to prevent this, a portion of the treated water passing through the methane fermentation tank, which is the second reaction tank, is returned to the acid fermentation tank to supplement the alkalinity.

(2)메탄발효공정((2) methane fermentation process ( S240S240 ))

혐기성 처리공정의 제2반응조인 메탄발효조는 상기 산발효조에서 전환된 용존성 유기물을 메탄발효를 통하여 메탄(CH4)으로 회수한다. 상기 메탄발효를 통하여 생성된 가스는 메탄이 60~70%, 이산화탄소가 30~40%, 기타 황화수소, 습기, 미량기체로 구성되는데, 하수처리수, 하천수, 지하수 등에 KOH를 용해시켜 채운 컬럼(column)을 하부에서 상부로 통과시켜 메탄과 이산화탄소의 용해도차를 이용하여 이산화탄소를 제거하고 탈황 및 습기 제거하는 정제공정을 거친 후, 정제된 메탄가스로부터 열병합발전을 통하여 전기 및 폐열을 회수한다.The methane fermentation tank, the second reaction tank of the anaerobic treatment process, recovers the dissolved organic matter converted from the acid fermentation tank to methane (CH 4 ) through methane fermentation. The gas produced through the methane fermentation is composed of 60 to 70% of methane, 30 to 40% of carbon dioxide, and other hydrogen sulfide, moisture, and trace gases, and a column filled with KOH dissolved in sewage treatment water, river water, and groundwater. ) Is passed from the bottom to the top to remove carbon dioxide using the solubility difference between methane and carbon dioxide, followed by a purification process to remove desulfurization and moisture, and then recover electricity and waste heat from the combined methane gas through cogeneration.

또한 산발효 및 메탄발효 공정을 통하여 발생된 슬러지는 유기물이 안정화된 상태이기 때문에 탈수후 건조를 통하여 퇴비로 활용한다. 건조에 필요한 에너지는 메탄을 이용한 열병합발전에서 회수되는 폐열을 활용한다. 발전기의 냉각수를 통하여 회수되는 폐열의 경우 온도가 100℃이상 되어야 슬러지의 건조에 사용할 수 있는데 이는 슬러지내에 함유된 수분의 경우 흡착수로써 100℃이하에서는 기화되지 않기 때문이다. 이러한 목적을 달성하기 위하여 냉각수의 온도가 100℃이상에서 운영되는 고온냉각방식의 발전기를 적용하고 발전기의 배기가스내의 폐열을 추가적으로 활용한다.In addition, the sludge generated through the acid and methane fermentation process is used as a compost through drying after dehydration because the organic matter is stabilized. The energy required for drying utilizes waste heat recovered from cogeneration with methane. Waste heat recovered through the generator's cooling water can be used to dry the sludge only when the temperature is over 100 ℃, because the water contained in the sludge does not vaporize below 100 ℃ as the adsorbed water. In order to achieve this purpose, a generator of a high temperature cooling method in which the temperature of the cooling water is operated at 100 ° C. or higher is used, and the waste heat in the exhaust gas of the generator is additionally utilized.

열병합발전을 통하여 회수된 폐열은 전술한 바와 같이 슬러지 건조에 사용하며 이후 온도가 약 50~60℃로 저하된다. 이후 혐기성처리공정인 산발효조의 온도를 상승시키 위해 사용되며 온도가 30~40℃정도로 저하되고, 메탄발효조의 온도를 유지하기 위하여 사용된 후 발전기로 순환되어 효율적인 폐열회수 및 냉각수 역할을 수행한다.Waste heat recovered through cogeneration is used for sludge drying as described above, and then the temperature is lowered to about 50-60 ° C. Since it is used to increase the temperature of the acid fermentation tank anaerobic treatment process, the temperature is reduced to about 30 ~ 40 ℃, used to maintain the temperature of the methane fermentation tank and then circulated to the generator to play an efficient waste heat recovery and cooling water.

즉, 우리나라의 경우 동절기에 기온의 저하에 따른 반응조 외벽을 통한 열손실이 발생하고, 반응조의 온도를 유지하기 위한 별도의 보일러설비 및 보일러 가동에 필요한 연료가 소요되어 운영이 난이하고 경제적으로 불리한 문제가 있었으나, 회수된 폐열을 산발효조, 메탄발효조를 가온하여 온도를 유지하는데 재이용할 수 있어 경제적으로 처리시설 운영비용을 절감하는 효과가 있다.That is, in the case of Korea, heat loss occurs through the outer wall of the reactor due to the temperature decrease in winter, and it is difficult and economically disadvantageous to operate a separate boiler facility and fuel required to operate the boiler to maintain the temperature of the reactor. However, the waste heat recovered can be reused to maintain the temperature by heating the acid fermentation tank and the methane fermentation tank, thereby economically reducing the operating cost of the treatment plant.

그리고 상기 메탄발효조를 통과한 처리수는 이 후 고도처리공정을 통하여 정화처리된다.The treated water passing through the methane fermentation tank is then purified through an advanced treatment process.

4.온도저감공정(4. Temperature reduction process S250S250 ))

혐기성공정은 운전온도에 따라서 중온과 고온 소화공정으로 나누어진다. 중온공정은 약 35℃가 최적온도이며, 고온공정은 50℃가 최적온도로 알려져 있다.Anaerobic processes are divided into medium and high temperature digestion processes depending on the operating temperature. In the middle temperature process, about 35 ° C is the optimum temperature, and in the high temperature process, 50 ° C is known as the optimum temperature.

회분식 반응조내의 온도가 40℃를 넘게 되면 미생물활성이 저하되어 질소제거효율이 급격히 저하되는데 본 발명에서 상기 혐기성공정은 중온(35℃ 정도) 또는 고온(55℃정도)으로 운영되므로 회분식 반응조로 유입될 경우 회분식반응조의 온도가 과도하게 상승되어 질산화가 저해될 수 있기 때문에 회분식반응조 전단에 냉각설비를 도입하여 축산폐수의 온도를 30℃이하로 저하시킨다.When the temperature in the batch reactor exceeds 40 ℃ the microbial activity is reduced and the nitrogen removal efficiency is sharply reduced. In the present invention, the anaerobic process is operated at a medium temperature (about 35 ℃) or a high temperature (about 55 ℃) to be introduced into the batch reactor In this case, since the temperature of the batch reactor may be excessively increased and nitrification may be inhibited, a cooling facility is introduced at the front of the batch reactor to reduce the temperature of the livestock wastewater to 30 ° C. or less.

즉, 혐기성 반응조를 통과한 처리수를 온도저감시설(열교환기)로 유입시켜 이어지는 호기성처리에 적정한 온도(30℃ 이하)로 저하시킨다. 냉각설비는 냉각기를 사용할 수도 있고 하수처리장이나 하천이 인근에 있을 경우 열교환기를 이용하여 온도를 저하시킨다.In other words, the treated water that has passed through the anaerobic reactor is introduced into a temperature reduction facility (heat exchanger) to lower the temperature (30 ° C. or lower) suitable for subsequent aerobic treatment. The cooling system may use a cooler, and if the sewage treatment plant or a river is nearby, it uses a heat exchanger to lower the temperature.

5.고도처리공정: 회분식반응공정(5. Advanced treatment process: Batch reaction process ( S260S260 ))

일반적으로 혐기성소화공정의 처리수는 유기물제거는 이루어지지만 질소,인과 같은 영양염류의 제거가 이루어지지 않아 호기성공정에 비해 처리수질이 양호하지 않기 때문에 우리나라 방류수질기준을 만족하기 위해서는 별도의 호기성처리가 필요하다.Generally, the treated water of anaerobic digestion process is organic matter removed, but nutrients such as nitrogen and phosphorus are not removed, so the treated water quality is not good compared to aerobic process. need.

상기 열교환기를 통해 적정한 온도(30℃ 이하)로 저하시킨 혐기성공정을 통과한 처리수는 유기물과 특히 질소의 농도가 높기 때문에 후속되는 회분식 반응조를 이용하여 처리한다. 회분식 반응조에 유입된 처리수는 잔류하는 유기물 및 영양염류(질소 및 인)가 제거된다.The treated water passed through the anaerobic process lowered to an appropriate temperature (30 ° C. or lower) through the heat exchanger is treated with a subsequent batch reactor since the concentration of organic matter and especially nitrogen is high. The treated water introduced into the batch reactor removes residual organic matter and nutrients (nitrogen and phosphorus).

그러나 혐기성공정에서 대부분의 유기물이 제거되기 때문에 C/N비가 0.5정도로 매우 낮아 탈질에 필요한 유기물이 부족하여 질소를 효과적으로 처리할 수 없다.However, since most organics are removed in the anaerobic process, the C / N ratio is very low, such as about 0.5, and thus, there is a shortage of organic matter necessary for denitrification, and thus nitrogen cannot be effectively treated.

고농도의 질소를 함유하는 폐수를 처리하여 처리수내의 질소농도를 낮게 유지하기 위해서는 호기성조건에서 질산화가 완료된 후 탈질공정이 필요하게 되는데, 질산화를 위한 호기성조건에서 폐수내의 유기물이 모두 산화되어 버리기 때문에 탈질공정에서 유기물을 효율적으로 이용할 수 없게 되는 문제가 발생한다. 즉 혐기성소화공정은 영양염류를 제거하기 위한 C/N, C/P를 확보하기 어렵기 때문에 메탄올과 같은 별도의 외부탄소원을 공급해야하는데 약품소요에 따른 운영비용의 상승이 발생한다.In order to maintain the nitrogen concentration in the treated water by treating wastewater containing high concentration of nitrogen, the denitrification process is required after nitrification is completed under aerobic conditions.Denitration is carried out because all organic matter in the wastewater is oxidized under aerobic conditions for nitrification. The problem arises that the organic matter cannot be used efficiently in the process. In other words, the anaerobic digestion process is difficult to secure C / N and C / P to remove nutrients, so it is necessary to supply a separate external carbon source such as methanol.

이러한 문제를 해결하기 위해 질소제거를 위하여 회분식 반응공정에 필요한 유기물은 상기 산발효공정의 처리수 일부를 회분식반응조로 우회(by-pass)시킴으로써, 회분식 반응조로 유입되는 축산폐수의 C/N비가 질소제거에 적합한 3~4정도가 되도록 한다.In order to solve this problem, organic matters necessary for the batch reaction process for nitrogen removal are bypassed by a part of the treated water of the acid fermentation process to the batch reaction tank, so that the C / N ratio of the livestock wastewater flowing into the batch reaction tank is nitrogen. Make it 3 to 4 suitable for removal.

회분식 반응조는 무산소 및 호기를 반복하는 교호방식으로 운영되며 호기시 질산화가 무산소시 탈질을 유도한다. 통상적으로 폐수를 정화하는 데에는 폐수 내의 NH3-N(암모니아성 질소)를 NO3-N(질산성질소)로 질산화 하는 질산화공정(호기성 공정)과, NO3-N(질산성질소)를 N2(질소가스)로 탈질시키는 탈질공정(혐기성 공정 또는 무산소 공정)이 수행된다. 무산소조건시 탈질에 필요한 유기물은 산발효조의 유출수를 우회(by-pass)시켜 유입시킴으로써 필요한 유기물을 확보할 수 있도록 한다. 유출수 유입은 무산소조건에서 주입하며 호기조건에서는 주입을 중단하여 질산화가 원활히 진해되도록 한다.The batch reactor is operated in an alternating manner in which anoxic and aerobic cycles are repeated, and nitrification at aerobic induction leads to denitrification at anoxic. In general, wastewater purification includes nitrification (aerobic process) of nitrifying NH 3 -N (ammonia nitrogen) into NO 3 -N (nitrogen nitrogen) in the waste water, and NO 3 -N (nitrogen nitrogen). A denitrification step (anaerobic step or anoxic step) is carried out to denitrate with 2 (nitrogen gas). Organic matter necessary for denitrification under anoxic conditions can be obtained by bypassing the effluent from the acid fermentation tank to obtain necessary organic matter. The inflow of effluent is injected under anoxic conditions and the injection is stopped under aerobic conditions so that nitrification is smoothed.

한편 회분식 반응조에서 폐기된 슬러지는 침전공정후 일정량씩 반송하여 유량조정조로 유입시킨 후 다시 혐기성반응조로 주입해서 탄소원을 회수함으로써 발생되는 슬러지의 양을 최소화하게 된다. 또한 축산분뇨내에는 다량의 암모니아성 질소가 존재하기 때문에 혐기성반응조내에서 암모니아독성을 발생시켜 미생물의 활성을 저하시킬 수 있는데, 질소가 제거된 슬러지를 반송함으로써 유입수내의 질소농도를 저하시킬 수 있어 이러한 독성문제를 해결한다.On the other hand, the sludge discarded in the batch reactor is returned to the flow control tank by a predetermined amount after the precipitation process, and then injected into the anaerobic reactor to minimize the amount of sludge generated by recovering the carbon source. In addition, since a large amount of ammonia nitrogen is present in the livestock manure, ammonia toxicity can be generated in the anaerobic reactor to reduce the activity of microorganisms.By returning sludge from which nitrogen is removed, nitrogen concentration in the influent can be reduced. Solve the toxicity problem.

6. 3차처리공정(6. Tertiary treatment process S270S270 ))

방류수질이 엄격할 경우 상기 회분식 반응조 후단에 3차처리공정을 도입하여 잔류하는 난분해성 유기물 및 질소, 영양염류를 추가적으로 제거한다. 3차처리시설은 가압온존부상, 생물막공정으로 구성되나 동일한 효율을 나타내는 그 외의 기술도 적용이 가능하다.If the discharged water is strict, a third treatment process is introduced at the rear of the batch reactor to further remove residual hardly decomposable organic matter, nitrogen and nutrients. The tertiary treatment facility consists of a pressurized temperature flotation and a biofilm process, but other techniques showing the same efficiency are applicable.

본 발명에 따른 공정은 축산분뇨의 처리 및 자원화에 적합하나 고농도 유기물 및 질소를 함유한 기타의 하폐수에 적용되어도 동일한 효과를 발휘한다.The process according to the invention is suitable for the treatment and recycling of livestock manure but has the same effect when applied to other wastewater containing high concentrations of organic matter and nitrogen.

이하에서는 본 발명의 축산분뇨 처리방법에 의한 자원의 회수에 대하여 설명한다.Hereinafter, the recovery of resources by the livestock waste treatment method of the present invention will be described.

전기 생성Electricity generation

메탄발효공정(S340)을 통하여 생성된 메탄가스에 포함된 이산화탄소, 황화수소, 및 습기를 제거하여 정제하고 상기 정제된 메탄가스를 열병합발전을 통하여 전기 및 폐열을 회수한다.Carbon dioxide, hydrogen sulfide, and moisture contained in methane gas produced through the methane fermentation process (S340) are removed and purified, and the purified methane gas is recovered electricity and waste heat through cogeneration.

폐열 회수Waste heat recovery

상기 회수된 폐열은 폐열순환라인을 통해 전술한 바와 같이 혐기성처리공정에서 발생한 슬러지를 건조하는 건조공정, 산발효공정 및 메탄발효공정의 온도를 올리도록 순환시켜 재이용된다.The recovered waste heat is recycled through the waste heat circulation line to increase the temperature of the drying process, acid fermentation process and methane fermentation process to dry the sludge generated in the anaerobic treatment process.

슬러지Sludge

상기 산발효공정 및 메탄발효공정을 통하여 발생된 슬러지는 탈수시설 및 폐열을 이용하여 건조하는 건조시설을 거쳐서 건조된 후 퇴비로 이용된다.The sludge generated through the acid fermentation process and the methane fermentation process is dried through a dehydration facility and a drying facility that is dried using waste heat, and then used as compost.

한편 회분식 반응조에서 폐기된 슬러지는 침전공정후 일정량씩 반송하여 유량조정조로 유입시킨 후 다시 혐기성반응조로 주입해서 탄소원을 회수함으로써 발생되는 슬러지의 양을 최소화하게 된다.On the other hand, the sludge discarded in the batch reactor is returned to the flow control tank by a predetermined amount after the precipitation process, and then injected into the anaerobic reactor to minimize the amount of sludge generated by recovering the carbon source.

도 3은 도 2 와 같은 공정을 수행하는 축산분뇨 처리시설에 관한 도면이다.도 3 에 도시된 축산분뇨 처리시설은, 전처리 시설(310), 조정조(320), 산발효조(330) 메탄발효조(340), 열교환기(350), 회분식반응조(360), 회분식 반응조(370), 처리수 우회라인(331), 처리수 반송라인(341), 슬러지 반송라인(361), 탈수시설(380), 건조시설(381), 정제시설(390), 발전시설(391)을 포함한다.3 is a view of a livestock waste treatment facility performing the same process as in FIG. 2. The livestock waste treatment facility shown in FIG. 3 includes a pretreatment facility 310, an adjustment tank 320, an acid fermentation tank 330, and a methane fermentation tank ( 340, heat exchanger 350, batch reactor 360, batch reactor 370, treated water bypass line 331, treated water return line 341, sludge conveyance line 361, dewatering facility 380, It includes a drying facility 381, a purification facility 390, and a power generation facility 391.

전처리 시설(310)은 처리될 축산폐수가 유입되어 협잡물 및 침사물질을 제거되는 시설이며, 협잡물 처리기 등으로 구성된다. 전처리시설(310)을 거친 축산분뇨는 조정조(320)로 유입되고, 조정조(320)는 유량 및 농도를 조절하는 수조로서 유입된 축산분뇨의 유량 및 농도를 균질화한다. 균질화된 축산분뇨는 혐기성처리를 의해 혐기성반응조로 유입된다. The pretreatment facility 310 is a facility in which livestock wastewater to be treated is introduced to remove contaminants and sediment, and is composed of a contaminant treatment unit and the like. Livestock manure that has passed through the pretreatment facility 310 is introduced into the adjustment tank 320, the adjustment tank 320 homogenizes the flow rate and concentration of the livestock manure as the water tank to control the flow rate and concentration. Homogenized livestock manure is introduced into the anaerobic reactor by anaerobic treatment.

혐기성공정은 다양한 혐기성균(산소를 필요로 하지 않는 미생물에 의한 발효)에 의해 유기물을 분해하는 공정으로서, 혐기성반응조는 제1반응조인 산발효조(330)와 제2반응조인 메탄발효조(340)로 순차적으로 구성된다.Anaerobic process is a process of decomposing organic matter by various anaerobic bacteria (fermentation by microorganisms that do not require oxygen), anaerobic reaction tank to the first reaction tank acid fermentation tank 330 and the second reaction tank methane fermentation tank (340) It is constructed sequentially.

산발효조(330)는 고형물 형태로 존재하는 축산분뇨 내의 유기물을 가수분해(hydrolysis) 및 산생성 단계를 거쳐 용존성 유기물로 전환시킨다. 무교반으로 운전되는 산발효조(330)로 유입된 축산분뇨는 산발효를 거치면서 고형물이 침전되고 일정시간 누적된다.The acid fermentation tank 330 converts the organic matter in the livestock manure present in the solid form into a dissolved organic material through hydrolysis and acid production steps. The livestock manure introduced into the acid fermentation tank 330 which is operated in an unstirred state is subjected to acid fermentation, and solids are precipitated and accumulated for a predetermined time.

고형물이 걸러진 산발효조(330)를 통과한 처리수는 메탄발효조(340)로 유입된다. 메탄발효조(340)는 상기 산발효조(330)에서 전환된 용존성 유기물을 메탄발효시킨다. 상기 메탄발효를 통하여 생성된 가스는 메탄이 60~70%, 이산화탄소가 30~40%, 기타 황화수소, 습기, 미량기체로 구성되는데, 하수처리수, 하천수, 지하수 등에 KOH를 용해시켜 채운 컬럼(column)을 하부에서 상부로 통과시켜 메탄과 이산화탄소의 용해도차를 이용하여 이산화탄소를 제거하고 탈황 및 습기 제거하는 정제시설(390)을 거친 후, 발전시설(391)에서 정제된 메탄가스로부터 열병합발전을 통하여 전기 및 폐열을 회수한다. 상기 열병합발전시설에서는 100℃ 이상의 폐열을 얻기 위해 고온냉각방식의 발전기를 사용한다.The treated water that has passed through the acid fermentation tank 330 in which the solids are filtered is introduced into the methane fermentation tank 340. Methane fermentation tank 340 methane fermentation of the dissolved organic matter converted in the acid fermentation tank 330. The gas produced through the methane fermentation is composed of 60 to 70% of methane, 30 to 40% of carbon dioxide, and other hydrogen sulfide, moisture, and trace gases, and a column filled with KOH dissolved in sewage treatment water, river water, and groundwater. ) Through a purification plant 390 to remove carbon dioxide and remove desulfurization and moisture by using a solubility difference between methane and carbon dioxide from the bottom to the top, and then through cogeneration from methane gas purified in the power plant 391. Recover electricity and waste heat. In the cogeneration plant, a high temperature cooling generator is used to obtain waste heat of 100 ° C. or higher.

또한 산발효 및 메탄발효 공정을 통하여 발생된 슬러지는 유기물이 안정화된 상태이기 때문에 탈수시설과 건조시설을 차례로 거쳐서 퇴비로 생성된다. 상기 건조시설에서 필요한 에너지는 상기 메탄을 이용한 열병합발전에서 회수되는 폐열을 활용한다. In addition, the sludge generated through the acid fermentation and methane fermentation process is produced as a compost through the dehydration and drying facilities in order to stabilize the organic matter. Energy required in the drying facility utilizes waste heat recovered from cogeneration with methane.

한편, 혐기성공정의 경우 산생성반응조에서는 산(acid)이 주로 생성되기 때문에 산의 형성에 따른 pH저하가 발생하며 과도하게 pH가 저하될 경우 미생물활성이 저하되는 문제가 발생한다. 이를 방지하기 위하여 본 발명에서는 메탄발효조를 통과한 처리수를 산발효조로 유입시키는 처리수 반송라인(341)을 추가로 설치함으로써 알카리도를 보충한다.On the other hand, in the anaerobic process, since acid is mainly produced in the acid production reaction tank, a pH decrease occurs due to the formation of an acid, and when the pH is excessively reduced, microbial activity decreases. In order to prevent this, the present invention supplements the alkalinity by providing a treated water return line 341 for introducing the treated water passing through the methane fermentation tank into the acid fermenting tank.

상기 메탄발효조를 통과한 처리수는 온도를 저감시키기 위해 온도저감시설(열교환기)로 유입되고, 열교환기(350)는 유입된 처리수를 이어지는 호기성처리에 적정한 온도(30℃ 이하)로 저하시킨다. 상기 열교환기(350)를 통해 적정한 온도(30℃ 이하)로 냉각된 처리수는 유기물과 특히 질소의 농도가 높기 때문에 고도처리를 위해 회분식 반응조(360)로 유입된다.The treated water passing through the methane fermentation tank is introduced into a temperature reducing facility (heat exchanger) to reduce the temperature, and the heat exchanger 350 reduces the introduced treated water to a temperature (30 ° C. or lower) suitable for subsequent aerobic treatment. . The treated water cooled to an appropriate temperature (below 30 ° C.) through the heat exchanger 350 is introduced into the batch reactor 360 for the advanced treatment because the concentration of organic matter and especially nitrogen is high.

회분식 반응조(360)는 고도처리시설로서 무산소 및 호기를 반복하는 교호방식으로 운영되며 호기시 질산화가 무산소시 탈질을 유도하여 잔류하는 유기물 및 영양염류(질소 및 인)를 제거한다. 고농도의 질소를 함유하는 폐수를 처리하여 처리수내의 질소농도를 낮게 유지하기 위해서는 호기성조건에서 질산화가 완료된 후 탈질공정이 필요하게 되는데, 질산화를 위한 호기성조건에서 폐수내의 유기물이 모두 산화되어 버리기 때문에 탈질공정에서 유기물을 효율적으로 이용할 수 없게 되는 문제가 발생한다. 이러한 문제를 해결하기 위해 무산소조건시 탈질에 필요한 유기물은 산발효조의 처리수를 메탄발효조를 거치지 않도록 열교환기로 유입되도록 연결된 처리수 우회라인(331)을 추가로 설치함으로써 해결한다. 즉, 열교환기에서 냉각된 산발효조 처리수 일부는 열교환기를 거쳐 냉각된 후 회분식 반응조(360)로 우회되어 축산폐수의 C/N비가 질소제거에 적합한 3~4정도가 되도록 한다.Batch reactor 360 is an advanced treatment facility and operates in an alternating manner of anoxic and aerobic repetition and removes organic matter and nutrients (nitrogen and phosphorus) by nitrification upon aerobic induction of denitrification. In order to maintain the nitrogen concentration in the treated water by treating wastewater containing high concentration of nitrogen, denitrification process is required after nitrification is completed under aerobic conditions. The problem arises that the organic matter cannot be used efficiently in the process. In order to solve this problem, organic matter necessary for denitrification in anoxic conditions is solved by additionally installing a treatment water bypass line 331 connected to the heat exchanger so that the treated water of the acid fermentation tank does not go through the methane fermentation tank. That is, some of the acid fermentation tank treated water cooled in the heat exchanger is cooled through the heat exchanger and then bypassed to the batch reactor 360 so that the C / N ratio of the livestock wastewater is about 3 to 4 suitable for nitrogen removal.

한편 회분식 반응조(360)에는 슬러지를 조정조로 일정량씩 반송시키도록 슬러지 반송라인(361)이 추가로 설치되어 있다. 슬러지는 침전공정후 일정량씩 반송라인(361)을 통해 조정조(320)로 유입되고 다시 혐기성반응조로 유입됨으로써 탄소원이 회수된다. 또한 축산분뇨내에는 다량의 암모니아성 질소가 존재하고 이는 혐기성반응조내에서 암모니아독성을 발생시켜 미생물의 활성을 저하시킬 수 있는데, 질소가 제거된 슬러지를 반송함으로써 혐기성반응조로 유입되는 유입수 내의 질소농도를 저하시킴으로써 이러한 독성문제를 해결하는 효과가 있다.On the other hand, the sludge conveying line 361 is further installed in the batch reactor 360 so as to convey the sludge by a fixed amount by the adjusting tank. The sludge is introduced into the adjustment tank 320 through the conveying line 361 by a predetermined amount after the precipitation process, and is returned to the anaerobic reaction tank to recover the carbon source. In addition, a large amount of ammonia nitrogen is present in the livestock manure, which may cause ammonia toxicity in the anaerobic reactor, thereby reducing the activity of microorganisms. Lowering it has the effect of solving this toxicity problem.

방류수질이 엄격할 경우에는 상기 회분식반응조(360) 후단에 3차처리시설(370)을 도입하여 잔류하는 난분해성 유기물 및 질소, 영양염류를 추가적으로 제거한다. 3차처리시설(370)은 가압온존부상, 생물막공정으로 구성되나 동일한 효율을 나타내는 그 외의 기술도 적용이 가능하다.If the discharge water is strict, the third treatment facility 370 is introduced to the rear of the batch reactor 360 to further remove the remaining hardly decomposable organic matter, nitrogen, and nutrients. The tertiary treatment facility 370 is composed of a pressurized temperature flotation and a biofilm process, but other techniques showing the same efficiency may be applied.

본 발명은 축산분뇨내의 유기물을 메탄으로 회수하고 생산된 메탄을 활용하여 열병합발전을 통해 전기를 생산하여 처리공정을 운영하는데 소요되는 전기를 충당하며 회수된 폐열은 슬러지 건조, 산발효조, 메탄발효조 온도유지에 이용할 수 있다.The present invention recovers the organic matter in the livestock manure as methane and uses the produced methane to produce electricity through cogeneration to cover the electricity required to operate the treatment process and the recovered waste heat is sludge drying, acid fermentation tank, methane fermentation tank temperature It can be used for maintenance.

본 발명은 축산분뇨를 효율적이고 경제적으로 처리/재활용 할 수 있으며, 발생되는 슬러지량을 최소화하고 건조를 통하여 안전하고 취급이 용이한 퇴비를 확보 할 수 있다.The present invention can be efficiently and economically treated / recycled livestock manure, minimize the amount of sludge generated and secure a safe and easy compost through drying.

또한 혐기성공정 후 영양염류를 제거하기 위하여 별도의 외부탄소원 공급이 필요없고 운영에 필요한 약품소요량을 최소화 할 수 있어 경제성을 확보할 수 있다.In addition, to remove nutrients after the anaerobic process, it is not necessary to supply a separate external carbon source, and it can secure economical efficiency by minimizing the chemical requirement required for operation.

본 발명은 축산분뇨의 자원화 가능부분을 최대로 활용하고 추가적인 처리공정의 도입으로 안정적인 처리수질을 확보할 수 있기 때문에 자원회수 및 환경보호를 동시에 달성할 수 있다.The present invention can achieve the resource recovery and environmental protection at the same time because it can make the most of the resources available part of the livestock manure and ensure the stable treatment water quality by the introduction of additional treatment process.

이상에서는 본 발명의 바람직한 실시예에 대해 설명하였으나 당해 기술분야에서 통상의 지식을 가진 자라면 본원 발명의 요지를 벗어남이 없이 다양한 변형실시가 가능할 것이며, 이러한 변형실시는 본원발명의 보호범위에 속하는 것으로서 본원발명의 보호범위는 특허청구범위에 기재된 바에 따라 해석되어야 할 것이다.In the above description of the preferred embodiment of the present invention, those skilled in the art will be able to perform various modifications without departing from the gist of the present invention, and such modifications are within the protection scope of the present invention. The protection scope of the present invention should be construed as described in the claims.

Claims (13)

축산분뇨에 포함된 협잡물 및 침사물질을 제거하는 전처리 공정;A pretreatment step of removing the impurities and sediment contained in the livestock manure; 상기 전처리공정을 통과한 상기 축산분뇨를 유량조정조에서 유량 및 농도를 균질화하는 조정공정;An adjusting step of homogenizing the flow rate and the concentration in the livestock manure that has passed the pretreatment step in a flow adjusting tank; 상기 균질화된 입자상태의 축산분뇨 유기물을 산발효조로 유입시켜 산발효를 통해 용존상태로 전환시키고 침전을 통해 고액분리를 수행하는 산발효 공정;An acid fermentation process of introducing the homogenized particulate livestock manure organic matter into an acid fermentation tank, converting it into a dissolved state through acid fermentation, and performing solid-liquid separation through precipitation; 상기 산발효공정을 통과한 용존상태의 유기물을 메탄발효조로 유입시켜 메탄발효를 통해 메탄가스를 회수하고 슬러지를 침전시키는 메탄발효공정;A methane fermentation step of recovering methane gas through methane fermentation and introducing sludge into the methane fermentation tank by dissolving the organic matter passed through the acid fermentation process; 상기 메탄발효공정을 통과한 처리수를 온도저감시설로 유입시켜 이어지는 호기성처리에 적정한 온도인 30℃ 이하로 처리수의 온도를 저하시키는 온도저감공정;A temperature reduction step of lowering the temperature of the treated water to 30 ° C. or lower, which is a temperature suitable for aerobic treatment by introducing the treated water that has passed through the methane fermentation process into a temperature reducing facility; 상기 온도가 저하된 혐기성 처리공정을 통과한 처리수로부터 잔류 유기물 및 영양염류를 제거하고 슬러지를 침전시키는 고도처리공정인 회분식반응공정;A batch reaction step which is a highly treated step of removing residual organic matter and nutrients from the treated water passing through the anaerobic treatment step in which the temperature is lowered and settling sludge; 상기 메탄발효공정을 통하여 생성된 메탄가스에 포함된 이산화탄소, 황화수소, 및 습기를 제거하는 정제공정;A purification step of removing carbon dioxide, hydrogen sulfide, and moisture contained in the methane gas produced through the methane fermentation process; 상기 정제된 메탄을 이용하여 전기 및 폐열을 회수하는 열병합발전 공정;A cogeneration process for recovering electricity and waste heat using the purified methane; 상기 산발효공정 및 상기 메탄발효공정을 통하여 발생된 슬러지를 탈수시설을 통하여 탈수시키는 탈수공정; 및A dehydration step of dewatering the sludge generated through the acid fermentation process and the methane fermentation process through a dehydration facility; And 상기 탈수된 슬러지를 상기 폐열을 이용하여 건조하는 건조공정을 포함하는 것을 특징으로 하는 축산분뇨의 처리방법.And a drying step of drying the dewatered sludge using the waste heat. 제1항에 있어서,The method of claim 1, 상기 회분식반응공정 후 잔류하는 난분해성 유기물 및 영양염류를 추가적으로 제거하기 위한 3차 처리공정을 더 포함하는 것을 특징으로 하는 축산분뇨의 처리방법.Livestock manure treatment method characterized in that it further comprises a third treatment step for additionally removing the hardly decomposable organic matter and nutrients remaining after the batch reaction process. 제1항에 있어서,The method of claim 1, 상기 회분식 반응공정에 필요한 유기물을 공급하여 C/N, C/P를 조정하기 위하여, 상기 산발효공정을 통과한 처리수를 상기 회분식 반응공정으로 일부 우회시키는(by-pass) 산발효공정 처리수 우회공정을 더 포함하는 것을 특징으로 하는 축산분뇨의 처리방법.Acid fermentation process treated water which partially bypasses the treated water that has passed the acid fermentation process to the batch reaction process in order to adjust C / N and C / P by supplying the organic substance necessary for the batch reaction process. Livestock manure treatment method further comprising a bypass step. 제1항에 있어서,The method of claim 1, 상기 메탄발효공정의 처리수 일부를 상기 산발효공정으로 반송하여 재처리함으로써 산발효공정의 pH저하를 방지하고 알카리도를 확보하기 위한 메탄발효조 처리수 재처리공정을 더 포함하는 것을 특징으로 하는 축산분뇨의 처리방법.Livestock manure, characterized in that the methane fermentation tank treated water reprocessing step to prevent the pH lowering of the acid fermentation process and to ensure alkalinity by returning a portion of the treated water of the methane fermentation process to the acid fermentation process Treatment method. 제1항에 있어서,The method of claim 1, 슬러지 생산량을 최소화하고 산발효공정의 암모니아 농도를 희석하여 혐기성 공정의 암모니아 독성을 제거하기 위하여, 상기 회분식반응공정에서 폐기된 슬러지를 상기 조정공정으로 반송하여 재처리하는 슬러지 재처리공정을 더 포함하는 것을 특징으로 하는 축산분뇨의 처리방법.In order to minimize sludge production and dilute the ammonia concentration in the acid fermentation process to remove the ammonia toxicity of the anaerobic process, the sludge reprocessing step of returning the sludge discarded in the batch reaction process to the adjustment process is further included. Livestock manure treatment method characterized in that. 삭제delete 제1항에 있어서,The method of claim 1, 상기 회수된 폐열을 상기 산발효공정 및 상기 메탄발효공정으로 순환시켜서 사용하는 폐열회수공정을 추가로 포함하는 것을 특징으로 하는 축산분뇨의 처리방법.And a waste heat recovery step of circulating the recovered waste heat into the acid fermentation step and the methane fermentation step. 삭제delete 축산분뇨에 포함된 협잡물 및 침사물질을 제거하는 전처리 공정을 수행하는 전처리 시설;A pretreatment facility for carrying out a pretreatment process for removing contaminants and sediment contained in the livestock manure; 상기 전처리 공정에 의해 처리된 상기 축산분뇨의 유량 및 농도를 균질화하는 조정조;An adjusting tank for homogenizing the flow rate and concentration of the livestock manure treated by the pretreatment step; 상기 입자상태의 측산분뇨 유기물을 용존상태로 전환시키는 산발효공정을 수행하는 산발효조;An acid fermentation tank for performing an acid fermentation process for converting the particulate acidic manure organic matter in a dissolved state into a dissolved state; 상기 산발효공정에서 처리된 용존상태의 유기물로부터 메탄발효를 통해 메탄가스를 회수하고 슬러지를 침전시키는 메탄발효 공정을 수행하는 메탄발효조;A methane fermentation tank performing a methane fermentation process for recovering methane gas from methane fermentation and precipitating sludge from the dissolved organic matter treated in the acid fermentation process; 상기 메탄발효공정의 처리수를 온도저감시설로 유입시켜 이어지는 호기성처리에 적정한 온도인 30℃ 이하로 처리수의 온도를 저하시키는 온도저감시설;A temperature reduction facility for introducing the treated water of the methane fermentation process into a temperature reduction facility to lower the temperature of the treated water to 30 ° C. or less, which is a temperature suitable for subsequent aerobic treatment; 상기 온도가 저하된 혐기성 처리공정의 처리수로부터 잔류 유기물 및 영양염류를 제거하는 회분식 반응공정을 수행하는 회분식반응조;A batch reactor for performing a batch reaction step of removing residual organic matter and nutrients from the treated water of the anaerobic treatment step in which the temperature is lowered; 추가적인 난분해성 유기물 및 질소를 제거하기 위한 3차 처리시설;Tertiary treatment facilities to remove additional hardly degradable organics and nitrogen; 상기 메탄발효조에서 변환된 메탄가스에 포함된 이산화탄소, 황화수소, 및 습기를 제거하는 정제시설; 및A purification facility for removing carbon dioxide, hydrogen sulfide, and moisture contained in methane gas converted in the methane fermentation tank; And 상기 정제된 메탄가스를 이용하여 전기 및 폐열을 회수하는 열병합발전시설;을 포함하는 것을 특징으로 하는 축산분뇨의 처리시설.Livestock manure treatment facility comprising a; cogeneration plant for recovering electricity and waste heat using the purified methane gas. 제9항에 있어서,The method of claim 9, 상기 회분식 반응공정에 필요한 유기물을 공급하여 C/N, C/P를 조정하기 위하여, 상기 산발효조를 통과한 처리수를 상기 회분식 반응조로 일부 우회시키는(by-pass) 처리수 우회라인;A treatment water bypass line for partially bypassing the treated water passing through the acid fermentation tank to the batch reaction tank in order to control C / N and C / P by supplying organic materials necessary for the batch reaction process; 상기 산발효조의 pH저하를 방지하고 알카리도 확보를 위하여, 상기 메탄발효조를 통과한 처리수 일부를 상기 산발효조로 반송하는 처리수 반송라인;및Treated water return line for conveying a portion of the treated water passed through the methane fermentation tank to the acid fermentation tank in order to prevent the pH lowering of the acid fermentation tank and ensure alkalinity; And 슬러지 생산량을 최소화하고 상기 산발효조의 암모니아 농도를 희석함으로써 독성을 제거하기 위하여, 상기 회분식반응조에서 폐기된 슬러지를 상기 산발효조로 반송하여 재처리하는 슬러지 반송라인;을 더 포함하는 것을 특징으로 하는 축산분뇨 처리시설.A sludge conveying line for returning sludge discarded in the batch reactor to the acid fermentation tank for reprocessing in order to minimize sludge production and to remove toxicity by diluting the ammonia concentration of the acid fermentation tank. Manure processing facility. 삭제delete 제9항에 있어서,The method of claim 9, 상기 열병합발전시설은 100℃이상의 폐열을 얻기 위해 고온냉각방식의 발전기를 사용하는 것을 특징으로 하는 축산분뇨 처리시설.The cogeneration plant is a livestock waste treatment facility, characterized in that using a high-temperature cooling generator to obtain waste heat of 100 ℃ or more. 제9항에 있어서,The method of claim 9, 상기 산발효조와 상기 메탄발효조로부터 폐기된 슬러지에서 물을 제거하는 탈수시설; A dehydration system for removing water from the sludge discarded from the acid fermentation tank and the methane fermentation tank; 상기 탈수된 슬러지를 상기 폐열을 이용하여 건조하는 건조시설을 더 포함하는 것을 특징으로 하는 축산분뇨 처리시설.Livestock waste treatment plant further comprises a drying facility for drying the dewatered sludge using the waste heat.
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