KR100777031B1 - the glaze and the manufacturing method using stone powder of conglomerate with seven color - Google Patents
the glaze and the manufacturing method using stone powder of conglomerate with seven color Download PDFInfo
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- KR100777031B1 KR100777031B1 KR1020040095502A KR20040095502A KR100777031B1 KR 100777031 B1 KR100777031 B1 KR 100777031B1 KR 1020040095502 A KR1020040095502 A KR 1020040095502A KR 20040095502 A KR20040095502 A KR 20040095502A KR 100777031 B1 KR100777031 B1 KR 100777031B1
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
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- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
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- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/02—Pretreated ingredients
- C03C1/022—Purification of silica sand or other minerals
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
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Abstract
본 발명은 칠보석 석분이 함유된 유약 및 그 제조 방법에 관한 것으로, 인체에 유익한 칠보석 석분과 물을 일정 비율로 교반한 유약을 제작하여, 이를 시유한 도자기류를 제작함에 따라, 그 표면에서 원적외선 및 음이온을 다량 방사하고, 탈취기능과 항균효과 및 항곰팡이 기능을 가지는 것이다.The present invention relates to a glaze containing chilseok stone powder and a method for manufacturing the same, and to produce a glaze stirred in a certain ratio of the chilseok stone powder and water beneficial to the human body, by producing a porcelain with the same, on the surface It emits a large amount of far infrared rays and anions, and has deodorizing function, antibacterial effect and antifungal function.
본 발명의 대략적인 공정을 살펴보면, 먼저, 채취된 칠보석을 분쇄하는 칠보석 1차 분쇄 공정(S1), 분쇄된 칠보석 석분에 포함된 철분을 분리해내는 철분 제거 공정(S2), 철분이 제거된 칠보석 석분을 다시 미세하게 분쇄하는 칠보석 2차 분쇄 공정(S3), 상기 공정을 거친 칠보석 석분과 물을 일정 비율로 배합하는 칠보석 석분 및 물 배합 공정(S4), 배합된 칠보석 석분 및 물을 잘 저어주는 교반 공정(S5), 일정 시간을 두어 내용물을 침전시키는 침전 공정(S6), 그 침전물 두고 윗물을 제거하는 윗물 제거 공정(S7)으로 칠보석 석분이 함유된 현탁액의 유약이 제조된다. Looking at the approximate process of the present invention, first, the first preliminary grinding process (S1) for crushing the collected seven stones, iron removal step (S2) for separating the iron contained in the crushed seven stones, iron is Cloisonne stone secondary grinding process (S3) for finely crushing the removed stone stone powder (S3), Cloisonne stone powder and water compounding process (S4), which is a compounding of the coarse stone stone and water subjected to the process at a predetermined ratio, Stirring process (S5), which stirs the gemstone powder and water well, the precipitation process (S6) that precipitates the contents for a certain time, and the water removal process (S7) which removes the supernatant from the precipitate. Glazes are prepared.
이와 같이, 칠보석이 함유된 유약은, 도자기류를 제조하는데 있어서, 초벌구이를 한 소지에 시유하고, 재벌구이하여 도자기류를 제작함에 따라, 그 표면에서 원적외선 및 음이온을 다량방사하며, 항곰팡이, 탈취기능, 항균효과 등의 기능을 가지고, 또한, 인위적인 화학성분이 아니므로 인체에 무해하고, 소성 후에는 그 고 유의 색을 가지므로 외관이 미려한 특징이 있다.Thus, glaze containing chilboseok, in the manufacture of porcelain, lubricated with a piece of first roasted, and pottery roasted to produce porcelain, thus emitting a large amount of far infrared rays and anions on the surface, antifungal, It has deodorizing function, antibacterial effect, etc., and it is not an artificial chemical ingredient, so it is harmless to human body, and after firing, it has its own color, so it has a beautiful appearance.
칠보석, 유약, 원적외선, 기, 도자기, 음이온Tanabata, Glaze, Far Infrared, Flag, Ceramic, Anion
Description
도 1은 본 발명에 따른 공정도.1 is a process chart according to the present invention.
본 발명은 칠보석 석분이 함유된 유약 및 그 제조 방법에 관한 것으로, 인체에 유익한 칠보석 석분과 물을 일정 비율로 교반한 유약을 제작하여, 이를 시유한 도자기류를 제작함에 따라, 그 표면에서 원적외선 및 음이온을 다량 방사하고, 탈취기능과 항균효과 및 항곰팡이 기능을 가지는 것이다.The present invention relates to a glaze containing chilseok stone powder and a method for manufacturing the same, and to produce a glaze stirred in a certain ratio of the chilseok stone powder and water beneficial to the human body, by producing a porcelain with the same, on the surface It emits a large amount of far infrared rays and anions, and has deodorizing function, antibacterial effect and antifungal function.
일반적으로 도자기류를 제작하는데 있어서, 유약을 시유하는 것은, 표면에 광택을 주어 제품을 아름답게 하는 것 외에도 강도를 더하고, 표면을 반질반질하게 하여 더러워지는 것을 방지하는 데 있으며, 또한, 흡수성을 없애어 물이나 화학약품에 대한 저항성을 증가시켜 실용성을 향상시킨다.In general, in the manufacture of ceramics, the application of glaze is not only to luster the surface to make the product beautiful, but also to increase the strength, to make the surface semi-finished, and to prevent it from becoming dirty. Improves practicality by increasing resistance to water and chemicals.
통상 사용되는 유약은 소나무, 싸리나무, 볏짚과 같은 화본 과식물(禾本科植物)의 재를 이용하거나, 장석, 석회석, 규석으로 구성되는 유약을 제조하여 쓰며, 최근에는 특수 성분을 포함하는 유약이 개발되었는데, 이를 살펴보면, 먼저, 국내등록특허공보 제 446477호에 개시된 바와 같이, 수금으로 코팅된 도자기류의 제조방법을 제시하고 있으며, 국내공개특허공보 10-2002-0066789에 개시된 바와 같이, 옥을 주성분으로 하는 유약을 사용한 도자기의 제조방법을 제시하고 있으나, 이는 그 유약의 재료가 되는 각 수금 코팅재 및 옥분말을 제조하는 공정이 용이하지 않고, 사용되는 재료가 고가이어서 원가가 상승하는 문제점이 있었다.Commonly used glazes are made of ash from native plants such as pine, birches and rice straws, or they are used to manufacture glazes composed of feldspar, limestone and silica. Recently, glazes containing special ingredients are used. It was developed, looking at this, first, as disclosed in Korean Patent Publication No. 446477, suggests a method of manufacturing ceramics coated with a harp, as disclosed in Korean Patent Publication No. 10-2002-0066789, Although a method of manufacturing ceramics using glaze as a main ingredient is proposed, this is not easy to manufacture each collection coating material and jade powder, which is the material of the glaze, and there is a problem that the cost of the material is high because the material used is expensive. .
따라서 본 발명은 상기의 문제를 해결하고자, 채취된 칠보석을 1차 분쇄한 칠보석 석분에 함유된 철분을 제거하고, 300메쉬 이상으로 미세하게 2차 분쇄한 칠보석 석분을 물과 같은 비율로 배합·교반하며, 이를 침전시켜 그 윗물을 제거한 현탁액의 침전물로 형성된 유약을 제공하여, 이를 시유한 도자기류를 제작함에 따라, 그 표면에서 원적외선 및 음이온을 방사하고, 항균효과, 탈취기능, 항곰팡이의 기능을 가지도록 하는데 그 목적이 있다.
Therefore, in order to solve the above problem, the present invention removes the iron contained in the first crushed chilseok stone powder, and the second crushed chilseok stone powder finely crushed more than 300 mesh at the same ratio as water It provides a glaze formed of a precipitate of a suspension which is mixed and stirred, and precipitated to remove the supernatant thereof. As a result of the manufacture of porcelains using this, it radiates far infrared rays and anions on its surface, and has antibacterial effect, deodorizing function, and antifungal effect. Its purpose is to have a function.
본 발명은 칠보석 석분이 함유된 유약 및 그 제조 방법에 관한 것으로, 인체 에 유익한 칠보석 석분과 물을 일정 비율로 교반한 유약을 제작하여, 이를 시유한 도자기류를 제작함에 따라, 그 표면에서 원적외선 및 음이온을 다량 방사하고, 탈취기능과 항균효과 및 항곰팡이 기능을 가지는 것이다.The present invention relates to a glaze containing chilseok stone powder and a method for manufacturing the same, and to produce a glaze stirred by a certain ratio of chilseok stone powder and water beneficial to the human body, by producing a porcelain, which is applied to the surface, on its surface It emits a large amount of far infrared rays and anions, and has deodorizing function, antibacterial effect and antifungal function.
본 발명의 대략적인 공정을 살펴보면, 먼저, 채취된 칠보석을 분쇄하는 칠보석 1차 분쇄 공정(S1), 분쇄된 칠보석 석분에 포함된 철분을 분리해내는 철분 제거 공정(S2), 철분이 제거된 칠보석 석분을 다시 미세하게 분쇄하는 칠보석 2차 분쇄 공정(S3), 상기 공정을 거친 칠보석 석분과 물을 일정 비율로 배합하는 칠보석 석분 및 물 배합 공정(S4), 배합된 칠보석 석분 및 물을 잘 저어주는 교반 공정(S5), 일정 시간을 두어 내용물을 침전시키는 침전 공정(S6), 그 침전물 두고 윗물을 제거하는 윗물 제거 공정(S7)으로 칠보석 석분이 함유된 현탁액의 유약이 제조된다. Looking at the approximate process of the present invention, first, the first preliminary grinding process (S1) for crushing the collected seven stones, iron removal step (S2) for separating the iron contained in the crushed seven stones, iron is Cloisonne stone secondary grinding process (S3) for finely crushing the removed stone stone powder (S3), Cloisonne stone powder and water compounding process (S4), which is a compounding of the coarse stone stone and water subjected to the process at a predetermined ratio, Stirring process (S5), which stirs the gemstone powder and water well, the precipitation process (S6) that precipitates the contents for a certain time, and the water removal process (S7) which removes the supernatant from the precipitate. Glazes are prepared.
상기의 제조 방법을 도1에 도시된 공정도를 참조하여 상세히 설명하면, 첫 번째 공정인 칠보석 1차 분쇄 공정(S1)은 칠보석을 1차로 분쇄하는 공정으로, 이는 경상북도 영양 일월산에서 채석한 칠보석을 마찰드럼식이나 회전분마기에 넣고, 고속 분마 처리하여, 100∼300 메쉬(mesh)까지 1차 분쇄하는 것이다.Referring to the manufacturing method described above in detail with reference to the process diagram shown in Figure 1, the first process, the first crushed chilboseok crushing (S1) is a process to crush the chilboseok first, which is quarried in Gyeongsangbuk-do nutrition Ilwolsan The jewel is placed in a friction drum or rotary powder, subjected to high-speed powdering, and ground first to 100 to 300 mesh.
다음 철분 제거 공정(S2)은 상기 1차 분쇄한 칠보석 석분에 존재하는 철분을 분리해 내는 것으로, 이는 분쇄된 칠보석 석분을 컨베이어 벨트 또는 회전 드럼에 두고, 강한 자력선을 투과하여 철분을 제거하거나, 탈철기를 칠보석 석분에 넣어 전기를 가해 휘저어 함유된 철분을 분리해 낸다The following iron removal process (S2) is to separate the iron present in the primary crushed chilseok stone powder, which is to place the crushed chilseok stone powder on a conveyor belt or a rotating drum, and remove the iron by penetrating a strong magnetic line , Put the decarbizer into the chilseok stone powder, apply electricity and stir to remove the iron content
그리고 칠보석 2차 분쇄 공정(S3)은 철분을 제거한 칠보석 석분을 한번 더 미세하게 분쇄하는 것으로, 유약으로 사용하는 칠보석 석분은 300메쉬 이상의 고운 입자로 형성하여, 제작된 도자기류의 표면을 매끄럽게 한다. The second crushing step of the crushed gemstone (S3) is to finely crush the crushed stone of the crushed stone once more, and the crushed stone of the crushed stone used as a glaze is formed of fine particles of 300 mesh or more, thereby forming the surface of the manufactured ceramics. Smooth it out.
다음으로 칠보석 석분 및 물 배합 공정(S4)은 상기 칠보석 석분과 물을 적정한 비율로 배합하는 공정으로, 칠보석 석분 50%와 물 50%의 부피비로 배합하며, 다음, 교반 공정(S5)은 상기 배합된 칠보석 석분 및 물이 잘 섞이도록 저어주는 공정이다.Next, the chilseok stone powder and water mixing step (S4) is a step of mixing the chilseok stone powder and water in an appropriate ratio, it is blended in a volume ratio of 50% of the stone of chilseok stone powder and 50% of water, and then stirring step (S5) Is a step of stirring the mixed chilseok stone powder and water well.
또한, 침전 공정(S6)은 상기 잘 교반된 혼합물을 일정시간 두어 그 내용물을 침전시켜, 맑은 물과 침전물이 분리되도록 하는 것이고, 마지막으로, 윗물 제거 공정(S7)은 침전된 내용물을 두고, 윗물을 제거하는 공정이며, 이와 같은 공정으로 남는 침전물로 현탁액의 유약을 완성한다.In addition, the precipitation step (S6) is to leave the well stirred mixture for a certain time to precipitate the contents, so that the clear water and sediment is separated, and finally, the upper water removal process (S7) puts the precipitated contents, the upper water This step is to remove the glaze of the suspension with the remaining precipitate.
상기와 같이 제조된 현탁액의 유약의 사용 방법은, 통상 도자기류를 제작하는 공정에서 이용하는 방법과 같이, 성형·건조된 소지를 850℃ 내외의 가마에서 초벌구이 후에, 유약을 시유하며, 이는 1280℃ 내외의 가마에서 재벌구이를 통해 도자기류를 제작할 수 있다.The use method of the glaze of the suspension prepared as described above, as in the method used in the process of producing ceramics, usually after glazing in the kiln around 850 ℃, the oil glaze, which is around 1280 ℃ In pottery's kiln, you can make pottery by baking chaebol.
한편, 상기 사용되는 칠보석을 간단히 설명하면, 이는 경상북도 영양 일원산에서 채석된 것을 사용하는데, 이 칠보석은 중생대 경상계 누군층으로 구성된 역암(conglomerate)으로, 퇴적암류, 화산암류, 변성암류 등으로 구성되어 있고, 그 광물은 주로 석영, 장석, 방해석, 녹니석 등으로 이루어져 있으며, 그 색상은 흑색, 적색, 홍색, 갈색, 담회색, 녹색 등의 다양한 색상을 띄고, 이 칠보석은 기를 증진시키는 효과가 옥의 약 250배, 게르마늄의 약 150배에 달한다고 알려져 있다.On the other hand, the chilboseok used briefly described, which is used in the Gyeongsangbuk-do antelope Ionwonsan, which is a conglomerate consisting of a mesozoic Gyeongsang nouveau, sedimentary rocks, volcanic rocks, metamorphic rocks, etc. Its minerals are mainly composed of quartz, feldspar, calcite, chlorite, etc., and its color is black, red, red, brown, light gray, green, and various colors. It is known that the effect is about 250 times that of jade and about 150 times that of germanium.
또한, 한국건자재시험 연구원의 원적외선응용평가센터에서 평가한 시험성적을, 하기의 표1과 표2 및 표3을 참조하여 살펴보면, 이는 원적외선 방사율이 0.92, 음이온의 발산이 20에 달하고, 암모니아를 이용한 탈취 시험에서 보인 바와 같이, 시간이 경과함에 따라, 시료 농도가 시료를 넣지 않은 것에 비해 급격히 떨어져, 탈취율이 증가됨을 알 수 있다. In addition, the test results evaluated by the Korea Institute of Building Materials Testing and Evaluation Center for Far-Infrared Application, referring to Table 1, Table 2 and Table 3 below, have a far-infrared emissivity of 0.92, anion divergence of 20, and using ammonia As shown in the deodorization test, it can be seen that as time passes, the sample concentration drops sharply compared to the absence of the sample, and the deodorization rate is increased.
비고) 본 시험은 의뢰자의 요구에 의하여 40℃에서 시험하였으며,Note) This test was conducted at 40 ℃ according to the request of the sponsor.
FT-IR Spectrometer를 이용한 BLACK BODY 대비 추정결과 임. 끝.Estimated results compared to black body using FT-IR spectrometer. End.
비고) 1) 시험방법 : KICM-FIR-1012Remarks) 1) Test Method: KICM-FIR-1012
2) 시험편 : 40×40×10 (㎜) 2) Test piece: 40 × 40 × 10 (㎜)
3) 전하 입자 측정 장치를 이용하여, 실내온도 22℃, 습도 41%, 대기 중 음이온수 15cc 조건에서 시험하였으며, 측정대상돌에서 방출되는 음이온을 측정하여 단위체적당 ION 수로 표시한 결과 임. 끝. 3) Using the charged particle measuring device, the test was conducted under the condition of room temperature 22 ℃, humidity 41%, and 15cc of anion water in the air. The anion released from the target stone was measured and expressed as the number of IONs per unit volume. End.
(주) (1) Blank : 시료를 넣지 않은 상태에서 측정한 것임.(Note) (1) Blank: Measured without sample.
(2) 시험편 : 40×40×10(㎜). 끝. (2) Test piece: 40 x 40 x 10 (mm). End.
1) 시험 방법 : KICM-FIR-10041) Test Method: KICM-FIR-1004
2) 시험가스명 : 암모니아2) Test gas name: Ammonia
3) 가스농도 측정 : 가스검지관3) Gas concentration measurement: Gas detector tube
따라서, 상기 칠보석 석분이 함유된 유약을 시유하여 제작된 도자기류는, 그 표면에서 다량의 원적외선 및 음이온을 방사하고, 탈취기능, 항균효과, 항곰팡이의 기능을 가지며, 인위적인 화학 성분의 안료를 사용하지 않아 인체에 무해하고, 칠보석 석분 유약의 사용으로 고유의 색상을 가지므로 외관이 미려한 특징이 있다.Therefore, the ceramics produced by lacquer containing the seventh stone stone powder radiates a large amount of far-infrared rays and anions on the surface thereof, and has a deodorizing function, an antibacterial effect, an antifungal function, and a pigment of an artificial chemical component. It is harmless to human body because it is not used, and it has a unique color because of its unique color by the use of chilseok stone powder glaze.
이와 같이 본 발명은, 채취된 칠보석을 1차 분쇄한 칠보석 석분에 함유된 철분을 제거하고, 300메쉬 이상으로 미세하게 2차 분쇄한 칠보석 석분을 물과 같은 비율로 배합·교반하며, 이를 침전시켜 그 윗물을 제거한 현탁액의 침전물로 형성된 유약을 제공하여, 이를 시유한 도자기류를 제작함에 따라, 그 표면에서 원적외선 및 음이온을 방사하고, 항균효과, 탈취기능, 항곰팡이의 기능 등의 가지는 효과가 있다.As described above, the present invention removes the iron contained in the pre-crushed chil-stone stone powder, and mixes and stirs the chil-stone stone powder finely secondary-crushed to 300 mesh or more in the same ratio as water, It precipitates and provides a glaze formed from the precipitate of the suspension from which the supernatant is removed. As the porcelain is produced using this, it emits far infrared rays and anions on its surface, and has antibacterial effect, deodorizing function, and antifungal function. It works.
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