KR20190040396A - Manufacturing method of composition for ceramics glaze - Google Patents

Manufacturing method of composition for ceramics glaze Download PDF

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Publication number
KR20190040396A
KR20190040396A KR1020170128672A KR20170128672A KR20190040396A KR 20190040396 A KR20190040396 A KR 20190040396A KR 1020170128672 A KR1020170128672 A KR 1020170128672A KR 20170128672 A KR20170128672 A KR 20170128672A KR 20190040396 A KR20190040396 A KR 20190040396A
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glaze
ceramic
mesh
raw material
ceramics
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KR1020170128672A
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Korean (ko)
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김종민
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김종민
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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C23/00—Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
    • B02C23/08—Separating or sorting of material, associated with crushing or disintegrating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
    • B07B1/00—Sieving, screening, sifting, or sorting solid materials using networks, gratings, grids, or the like
    • B07B1/28—Moving screens not otherwise provided for, e.g. swinging, reciprocating, rocking, tilting or wobbling screens

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Food Science & Technology (AREA)
  • Glass Compositions (AREA)

Abstract

The present invention relates to a method for preparing a glaze composition for ceramic. According to the present invention, a crushed glaze raw material for ceramic supplied from a raw material supply company is selected for a glaze composition for ceramic of 200 mesh or more by using a vibration selector. The residual glaze raw material for ceramic of 200 mesh or less is re-crushed by a roll mill to be re-selected by a vibration selector (10). Also, the selected glaze composition for ceramic of 200 mesh or more is packaged by a desired packaging unit for sale, and consumers who purchase the same, stirs the appropriate amount of the glaze composition for ceramic with water every time a glaze is needed for use. Accordingly, the weight and volume can be reduced during distribution, a delivery can be easily performed without concern for leakage, and burden of purchase costs on consumers can be reduced due to reduction in logistical costs. In addition, spatial utilization can be enhanced since concern for freezing is removed while minimizing the volume during storage. Furthermore, financial loss due to a shortened lifetime can be prevented since lifetime shortening caused by transmutation or coagulation does not occur even in case of long storage.

Description

도자기용 유약 조성물의 제조방법{MANUFACTURING METHOD OF COMPOSITION FOR CERAMICS GLAZE}TECHNICAL FIELD [0001] The present invention relates to a glaze composition for ceramics,

본 발명은 도자기의 표면에 도포하여 표면층을 형성하도록 하기 위한 도자기용 유약 조성물의 제조방법에 관한 것이다.The present invention relates to a method for producing a glaze composition for a ceramic to form a surface layer by coating on the surface of a ceramic.

일반적으로 도자기는 소성에 앞서 표면에 유약을 도포하여 광택으로 미려한 외관을 갖도록 하고 또 강도를 강화하며, 매끄러운 표면유지 및 흡수성 차단으로 오염을 방지해주도록 하고 있다.In general, ceramics are coated with glaze on the surface prior to firing so as to have a beautiful appearance with gloss and to strengthen the strength, and to prevent contamination by smooth surface maintenance and water absorption cutoff.

또한 도자기용 유약은 등록특허 10-0387920호 '도자기용 유약의 제조 및 도포방법' 및 등록특허 10-0777031호 '칠보석 석분이 함유된 유약 및 그 제조방법' 등에서와 같이 장석이나 규석, 석회석, 카올린, 백운석 등 원하는 특성에 따른 여러종류의 광물로 이루어진 주성분에 색소로서 산화아연이나 산화주석, 산화코발트, 산화알루미늄 등 여러종류의 금속산화물을 첨가하여 얻은 원재료를 200매쉬 이상의 미립자로 분쇄하여 물에 투입, 교반한 후 윗물을 제거한 현탁액 상태로 이용되는 것으로서, 도자기를 유약에 침전시켜주게 되면 유약이 도자기 외면에 도포되어 건조후 소성시 매끄러운 표면층을 형성하도록 하고 있다.In addition, the glaze for ceramics can be produced by a method such as a method of manufacturing and applying a glaze for ceramics, a method of manufacturing a glaze containing glaze, Kaolin, and dolomite. The raw material is obtained by adding various kinds of metal oxides such as zinc oxide, tin oxide, cobalt oxide, and aluminum oxide as a coloring material to a main component composed of various kinds of minerals according to desired characteristics, When the ceramics are precipitated in the glaze, the glaze is applied to the outer surface of the ceramic to form a smooth surface layer upon drying and firing.

따라서 유약의 사용량이 많은 생활도자기제조업체의 경우 자체적으로 유약 제조시설을 갖추고 필요시 유약을 직접제조하여 사용하고 있으나, 유약의 사용량이 적고 또 작업공간이 부족한 소규모 도예공방이나 도예가들의 경우 유약전문 제조업체로부터 유약을 구입하여 사용하고 있다.In the case of pottery manufacturers, which have a lot of use of glaze, they have their own glaze manufacturing facilities and manufacture glazes themselves if necessary. However, in case of small-scale pottery workshops or pottery companies that use less glaze and lack working space, Glaze is purchased and used.

그러나 도자기유약전문 제조업체의 경우 도자기용 유약 원재료 납품업체로부터 공급받는 분쇄된 광물 및 금속산화물들은 전체적으로 고르게 분쇄되지 않아 재분쇄를 요하게 되므로 이제껏 납품업체로부터 납품받은 도자기용 유약 원재료를 세라믹볼을 갖는 볼밀기에 분쇄 및 교반에 필요한 물과 함께 투입하여 세라믹볼에 의해 재분쇄되게 하면서 물에 의해 교반되게 하여 현탁액상태의 완전한 유약을 제조하고 또 이러한 제조공정상의 어려움으로 인한 생산성 향상을 위하여 대량을 제조한 후 약 20ℓ들이 일반합성수지용기에 담아서 유통시켜 주도록 함으로서, 제품의 중량 및 누수 등으로 인하여 배송시 많은 어려움이 따르게 됨은 물론 부피가 크고 무게가 무거워 물류비용이 추가 소요되는 만큼 수요자들의 구입비용부담이 가중되고, 보관시에는 동절기 결빙방지를 위하여는 실내의 넓은 공간을 필요로 하므로 공간활용률이 떨어지게 되며, 제조후 시간이 지날수록 원재료가 물과 반응하거나 또는 침전된 원재료가 응고되어 수명을 다하게 되므로 장기간 보관이 불가능할 뿐 아니라 제때에 사용하지 못할 경우 폐기처분하여야 하므로 금전적 손실이 더해지는 등의 많은 문제점들이 있는 것이다.However, in the case of a manufacturer specialized in ceramic glaze, the ground minerals and metal oxides supplied from suppliers of ceramic glaze raw materials are not uniformly crushed and require re-grinding. Therefore, the raw materials for ceramic glaze that have been supplied from the suppliers, With water required for grinding and stirring and then re-pulverized by a ceramic ball while being stirred with water to prepare a complete glaze in a suspension state. In order to improve the productivity due to the difficulty of such a manufacturing process, It is difficult to deliver the product because of the weight and leakage of the product due to the weight of the product and the cost of the logistics is increased due to the heavy weight and heavy weight, When stored In order to prevent freezing in winter, space utilization rate is decreased because it requires a large space in the room. As the time passes after manufacturing, the raw material reacts with water, or the precipitated raw material coagulates, If you can not use it on time, you have to dispose of it, so there are many problems such as adding financial loss.

등록특허 10-0387920호 '도자기용 유약의 제조 및 도포방법'Patent No. 10-0387920 'Manufacturing and application method of ceramic glaze' 등록특허 10-0777031호 '칠보석 석분이 함유된 유약 및 그 제조방법'Registered Patent No. 10-0777031 'Glaze containing gem stone powder and method for manufacturing the same'

본 발명의 목적은 분말상태로 공급하여 사용에 앞서 간단히 물과 혼합하여 사용할 수 있도록 한 도자기용 유약 조성물의 제조방법을 제공하는데 있다.It is an object of the present invention to provide a method for manufacturing a glaze composition for a pottery which is supplied in a powder state and which can be mixed with water simply before use.

상기한 목적달성을 위한 본 발명 도자기용 유약 조성물의 제조방법은 원재료 공급업체로부터 공급받은 분쇄된 도자기용 유약 원재료를 진동선별기를 이용하여 200메쉬 이상의 도자기용 유약 조성물을 선별하고, 선별후 남은 200메쉬 이하의 도자기용 유약 원재료는 롤밀기로 재분쇄하여 진동선별기로 재선별한 다음 선별된 200메쉬 이상의 도자기용 유약 조성물을 원하는 포장단위로 포장하여 판매를 하게 되면 이를 구입한 수요자들이 유약의 필요시마다 적당량의 도자기용 유약 조성물을 물로 교반하여 현탁액상태로 사용하도록 함을 특징으로 한다.In order to accomplish the above object, the present invention provides a method for manufacturing a glaze composition for ceramics, which comprises: grinding a raw material of glaze for a powdered ceramics supplied from a raw material supplier, selecting a glaze composition for a ceramics of 200 mesh or more using a vibration discriminator, The following glaze raw materials for ceramics are re-pulverized by roll milling and re-screened by a vibration sorter. When the glaze composition for a ceramics having 200 mesh or more is packed in a desired packing unit for sale, The glaze composition for a pottery of the present invention is used in a suspension state by stirring with water.

본 발명을 통하여 얻게 되는 도자기용 유약 조성물은 200메쉬 이상의 분말상태로서, 수분 없이 분말상태로 유통시켜서 이를 구입한 수요자들이 유약의 매 필요시마다 적당량을 물과 교반하여 사용하도록 함으로서, 유통시 중량 및 부피를 줄일 수 있고 또 누수에 대한 염려가 없어 배송이 용이하게 이루어질 수가 있게 됨은 물론 물류비용 절감으로 수요자들의 구입비용부담을 줄여줄 수가 있고, 보관시에는 부피를 최소화하면서 결빙에 대한 염려를 없애줄 수가 있어 공간활용률을 높여줄 수 있으며, 오랜 보관시에도 변질이나 응고 등에 의한 수명단축우려가 없어 수명단축으로 인한 금전적 손실을 방지해줄 수가 있게 되는 등의 효과가 있는 것이다.The glaze composition for a pottery obtained through the present invention is a powder having a size of 200 mesh or more and is circulated in the state of powder without moisture so that a consumer who purchases the glaze can use an appropriate amount of glaze each time it is stirred, It is possible to reduce the cost of purchasing by reducing the cost of logistics. In addition, it is possible to reduce the burden of freezing while minimizing the volume during storage. It is possible to increase the utilization rate of the space and to prevent the loss of life due to shortening of life time because there is no possibility of shortening the life time due to deterioration or solidification even in long storage.

도 1 : 본 발명에 이용되는 진동선별기의 정면구성도
도 2 : 본 발명에 이용되는 진동선별기의 일부단면구성도1 is a front view of a vibration separator used in the present invention;
2 is a partial cross-sectional view of a vibration isolator used in the present invention;

이하 본 발명의 바람직한 실시예를 첨부한 도면에 의거 상세히 설명하기로 하며, 다만 도면들 중 동일한 구성요소들은 가능한 동일부호로 기재하고, 관련된 공지기술이나 기능에 대한 구체적인 설명은 본 발명의 요지가 모호해지지 않도록 하기 위하여 생략하기로 한다.DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings, wherein like reference numerals are used to designate like elements in the drawings, It will be omitted for the sake of clarity.

본 발명은 원재료 공급업체로부터 공급받은 분쇄된 도자기용 유약 원재료를 진동선별기(10)에 투입하여 200메쉬 이상의 도자기용 유약 조성물을 선별하고, 선별후 남은 200메쉬 이하의 도자기용 유약 원재료는 롤밀기로 재분쇄한 후 진동선별기(10)로 재선별하여 200메쉬 이상의 도자기용 유약 조성물을 선별하며, 선별된 200메쉬 이상의 도자기용 유약 조성물은 원하는 포장단위로 포장하여 유통시켜 주도록 하여 이를 구입한 수요자들이 유약의 매 필요시마다 적당량을 물로 교반하여 사용하도록 한다.The present invention relates to a method for selecting a glaze composition for ceramics having a diameter of 200 mesh or more by inputting a pulverized raw material for glaze for ceramics supplied from a raw material supplier into a vibration discriminating device 10, After re-grinding, it is re-screened with a vibration screening machine (10) to select glaze compositions for ceramics having a size of 200 mesh or more. The glaze composition for a ceramics having a screen size of 200 mesh or more is packaged in a desired packaging unit, If necessary, use an appropriate amount of water with stirring.

이때 본 발명에서 원재료 공급업체로부터 공급받는 분쇄된 도자기용 유약 원재료는 장석이나 규석, 석회석, 카올린, 백운석 등과 같은 여러종류의 광물로 이루어진 주재료 및 색소로서 산화아연이나 산화주석, 산화코발트, 산화알루미늄 등과 같은 여러종류의 금속산화물로 이루어진 부재료로서, 이들은 단순히 종류별 각기 별도로 공급받아서 얻고자 하는 유약의 특성이나 색상 등에 따라 주재료와 부재료를 선택하여 각기 적정배합비율로 배합되므로 이용되는 주재료와 부재료의 종류 및 배합비율 등에 대하여는 구체적인 설명을 생략하기로 한다.At this time, the ground raw material of the glaze for ceramics supplied from the raw material supplier in the present invention is a main material and coloring matter of various kinds of minerals such as feldspar, limestone, kaolin, dolomite, etc. and zinc oxide, tin oxide, It is mixed with various kinds of metal oxides, and they are mixed with each other in proper mixing ratio by selecting the main material and the sub-materials according to the characteristics and color of the glaze to be obtained by separately supplying them separately. Therefore, The detailed description of the ratio and the like will be omitted.

도 1 및 도 2는 본 발명에 이용되는 진동선별기를 나타낸 것으로서, 본 발명에 이용되는 진동선별기(10)는 받침틀(12) 상부에 진동체(14)와 복수의 압축스프링(16)을 이용하여 선별케이스(18)를 연결설치하고, 상기 선별케이스(18)의 내부가 200메쉬의 스크린(20)으로 구획되고 또 구획된 상부공간부(22)와 하부공간부(24)는 각각 배출관(26)(28)을 갖는 본체(30) 및 본체(30) 상부에 분리가능케 결합되고 또 상부에 공급관(32)을 갖는 뚜껑(34)으로 이루어져 원재료 공급업체로부터 공급받은 도자기용 유약 원재료로부터 200메쉬 이상의 도자기용 유약 조성물을 선별해 주게 된다.1 and 2 show a vibration discriminator used in the present invention. The vibration discriminator 10 used in the present invention is a vibration discriminator 10 used in the present invention in which a vibrating body 14 and a plurality of compression springs 16 are used above a support frame 12 The upper case 22 and the lower case 24 are partitioned by a screen 20 of 200 mesh and the divided space is partitioned by a discharge pipe 26, And a lid 34 detachably connected to the upper portion of the main body 30 and having a supply pipe 32 at an upper portion of the main body 30. The main body 30 is made of ceramics having a thickness of 200 mesh or more from the glaze raw material for ceramics, The glaze composition is selected.

즉, 진동선별기(10)의 선별케이스(18)가 갖는 뚜껑(34)의 공급관(32)을 통하여 본체(30) 내 상부공간부(22)에 원재료 공급업체로부터 공급받은 분쇄된 도자기용 유약 원재료를 투입한 후 진동체(14)를 작동시켜서 선별케이스(18)를 진동시켜주게 되면 상부공간부(22) 내 도자기용 유약 원재료의 선별작업이 시작되어 200메쉬 이상의 도자기용 유약 조성물은 스크린(20)을 통과하여 하부공간부(24)에 낙하하며, 이러한 선별작업으로 상부공간부(22) 내에 잔류한 200메쉬 이하의 도자기용 유약 원재료와 스크린(20)을 통과하여 하부공간부(24) 내에 낙하한 200메쉬 이상의 도자기용 유약 조성물은 각각 별도의 배출관(26)(28)으로 배출되어 수집통에 수집된다.That is to say, the powdered glaze raw material supplied from the raw material supplier to the upper hollow portion 22 in the main body 30 through the supply pipe 32 of the lid 34 of the discriminating case 18 of the vibration discriminating device 10 When the oscillating body 14 is operated to vibrate the screening case 18, the screening operation of the glaze raw materials for the ceramics in the upper hollow portion 22 begins. And falls into the lower space portion 24 by such a sorting operation. The glaze raw material for 200 g of the glaze for use in ceramics having a size of 200 mesh or less remaining in the upper hollow portion 22 passes through the screen 20 and falls into the lower space portion 24 The glaze composition for a ceramics having a mesh or more is discharged into separate discharge pipes 26 and 28 and collected in a collection container.

또한 진동선별기(10)를 이용한 선별후 남은 200메쉬 이하의 도자기용 유약 원재료를 재분쇄하는 롤밀기는 회전비를 달리하는 한쌍의 분쇄롤러로 이루어진 일반적인 것으로서, 더 이상의 구체적인 설명은 생략하기로 하며, 이러한 롤밀기로 재분쇄된 도자기용 유약 원재료는 진동선별기(10)를 이용하여 200메쉬 이상의 도자기용 유약 조성물을 재선별한다.Further, the roll mill for re-grinding the glaze raw material for 200 g of ceramic or less remaining after screening using the vibration discriminating device 10 is generally made of a pair of grinding rollers having different rotation ratios, The glaze raw materials for ceramics re-pulverized by roll milling are re-screened for 200 glaze or higher glaze compositions for ceramics using a vibration discriminator (10).

그리고 진동선별기(10)를 통하여 선별된 200메쉬 이상의 도자기용 유약 조성물은 원하는 포장단위로 포장하여 유통시켜 주도록 하며, 이를 구입한 수요자들은 유약의 필요시 적당량의 도자기용 유약 조성물을 물로 간단히 교반하여 사용하면 된다.The glaze composition for the ceramics having a mesh size of 200 mesh or more selected through the vibration discriminating device 10 is packaged and packaged in a desired packing unit. The consumer who purchases the glaze composition can easily mix an appropriate amount of the glaze composition for ceramics with water .

따라서 본 발명을 통하여 얻게 되는 200메쉬 이상의 도자기용 유약 조성물은 물과 교반되지 않은 분말상태로서, 가볍고 또 부피가 작을 뿐 아니라 누수 우려를 없애줌에 따라 배송이 용이하게 이루어질 수가 있게 됨은 물론 물류비용 절감으로 수요자들의 구입비용부담을 줄여줄 수가 있게 된다.Therefore, the glaze composition for a ceramic of 200 mesh or more obtained through the present invention is in powder form not stirred with water, and is light and small in volume. Moreover, since it prevents leakage, it can be easily delivered, It can reduce the cost of purchasing the customers.

그리고 보관시에는 부피가 작고 또 결빙우려를 없애줌에 따라 공간활용률을 높여줄 수가 있고 또 오랜 보관시에도 변질이나 응고 등에 의한 수명단축우려가 전혀 없어 수명단축으로 인한 금전적 손실을 방지해줄 수가 있게 된다.In addition, it is possible to increase the utilization rate of the space by reducing the volume and the fear of freezing at the time of storage, and at the time of long storage, there is no fear of shortening the life due to deterioration or solidification, thereby preventing the financial loss due to the shortening of life.

이상에서 설명한 바와 같이 본 발명은 그 권리범위는 전술한 실시예 및 첨부된 도면에 의해 한정되는 것은 아니고, 본 발명의 기술적 사상을 벗어나지 않는 범위 내에서 여러가지 치환, 변형 및 변경이 가능하며, 이는 본 발명이 속하는 기술범야에서 통상의 지식을 가진 자에게 있어서는 자명한 것이다.As described above, the present invention is not limited to the above-described embodiments and the accompanying drawings, and various changes, modifications and variations can be made without departing from the technical spirit of the present invention. It is obvious to those having ordinary skill in the art that the invention belongs.

(10)--진동선별기 (12)--받침틀
(14)--진동체 (16)--압축스프링
(18)--선별케이스 (20)--스크린
(22)--상부공간부 (24)--하부공간부
(26)(28)--배출관 (30)--본체
(32)--공급관 (34)--뚜껑(10) - Vibrating sorting machine (12) - Supporting table
(14) - oscillating body (16) - compression spring
(18) - sorting case (20) - screen
(22) - the upper hollow portion (24) - the lower space portion
(26) (28) - discharge pipe (30) - body
(32) - a supply line (34) - a lid

Claims (1)

원재료 공급업체로부터 공급받은 분쇄된 도자기용 유약 원재료를 진동선별기(10)에 투입하여 200메쉬 이상의 도자기용 유약 조성물을 선별하고, 선별후 남은 200메쉬 이하의 도자기용 유약 원재료는 롤밀기로 재분쇄한 후 진동선별기(10)로 재선별하여 200메쉬 이상의 도자기용 유약 조성물을 선별하며, 선별된 200메쉬 이상의 도자기용 유약 조성물은 원하는 포장단위로 포장하여 유통시켜 주도록 함을 특징으로 하는 도자기유약 조성물의 제조방법.The powdered glaze raw material for the ceramics which is supplied from the raw material supplier is put into the vibration discriminating device 10 to select the glaze composition for the ceramics having a size of 200 mesh or more and the remaining glaze raw material for the ceramics less than 200 mesh remaining after the screening is re- And then selected by a post-vibration discriminator (10) to select glaze compositions for ceramics having a size of 200 mesh or more. The glaze composition for a ceramics having a size of 200 mesh or more is packed and distributed in a desired packaging unit. Way.
KR1020170128672A 2017-10-10 2017-10-10 Manufacturing method of composition for ceramics glaze KR20190040396A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102354671B1 (en) 2021-05-21 2022-01-21 백승민 Low gloss ceramic glaze composition with excellent abrasion resistance and texture, and its manufacturing method
CN117227040A (en) * 2023-11-10 2023-12-15 四川益涵新材料科技有限公司 Feeding device for PE film production

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100387920B1 (en) 2000-08-22 2003-06-18 김대진 The method of preparing and application for chinaware glaze
KR100777031B1 (en) 2004-11-20 2007-11-28 권기송 the glaze and the manufacturing method using stone powder of conglomerate with seven color

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100387920B1 (en) 2000-08-22 2003-06-18 김대진 The method of preparing and application for chinaware glaze
KR100777031B1 (en) 2004-11-20 2007-11-28 권기송 the glaze and the manufacturing method using stone powder of conglomerate with seven color

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102354671B1 (en) 2021-05-21 2022-01-21 백승민 Low gloss ceramic glaze composition with excellent abrasion resistance and texture, and its manufacturing method
CN117227040A (en) * 2023-11-10 2023-12-15 四川益涵新材料科技有限公司 Feeding device for PE film production
CN117227040B (en) * 2023-11-10 2024-01-23 四川益涵新材料科技有限公司 Feeding device for PE film production

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