KR100615512B1 - Composition for preventing advertising material from sticking to something and production method of street furniture using thereof - Google Patents
Composition for preventing advertising material from sticking to something and production method of street furniture using thereof Download PDFInfo
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- KR100615512B1 KR100615512B1 KR1020050084135A KR20050084135A KR100615512B1 KR 100615512 B1 KR100615512 B1 KR 100615512B1 KR 1020050084135 A KR1020050084135 A KR 1020050084135A KR 20050084135 A KR20050084135 A KR 20050084135A KR 100615512 B1 KR100615512 B1 KR 100615512B1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/80—Processes for incorporating ingredients
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- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Road Signs Or Road Markings (AREA)
- Paints Or Removers (AREA)
Abstract
본 발명은 광고물 부착 방지용 조성물 및 이것을 이용한 광고물 부착 방지용 도로시설 구조물의 제조방법에 관한 것이다.The present invention relates to a composition for preventing ad attachment and a method for manufacturing a road facility structure for preventing ad attachment using the same.
이를 위해 본 발명은 평균중합도가 20 ~ 60인 저중합도 실리콘 수지 50 ~ 60중량%와 평균중합도가 150 ~ 200인 고중합도 실리콘 수지 40 ~ 50중량%를 혼합하여 제조된 이형실리콘수지와 용제인 톨루엔을 상온에서 2:3의 중량비로 혼합한 1차 합성용제를 제조한 후, 상기 제조된 1차 합성용제 80 ~ 90중량%를 스티렌계 아크릴 에멀젼수지 10 ~ 20중량%와 혼합교반하여 2차 합성용제를 제조하고, 상기 2차 합성용제 40 ~ 50중량%와 백시멘트 45 ~ 50중량% 및 칼슘 5중량%를 24 ~ 48시간 겔화시켜 반죽된 혼합물을 제조하고, 상기 혼합물 100중량부에 대하여 재활용 안료 0.001 ~ 2중량부, 경화제 0.001 ~ 0.05중량부를 첨가하여 제조되는 것을 특징으로 한다.To this end, the present invention is a release silicone resin and a toluene solvent prepared by mixing 50 to 60% by weight of a low polymerization silicone resin having an average degree of polymerization of 20 to 60 and 40 to 50% by weight of a high polymerization silicone resin having an average degree of polymerization of 150 to 200. After preparing a primary synthetic solvent mixed in a weight ratio of 2: 3 at room temperature, 80 to 90% by weight of the prepared primary synthetic solvent was mixed and stirred with 10 to 20% by weight of a styrene-based acrylic emulsion resin for secondary synthesis A solvent was prepared, and the mixture was gelled for 40 to 50% by weight of the secondary synthetic solvent, 45 to 50% by weight of cement and 5% by weight of calcium for 24 to 48 hours to prepare a kneaded mixture, and recycled to 100 parts by weight of the mixture. It is prepared by adding 0.001 to 2 parts by weight of a pigment and 0.001 to 0.05 parts by weight of a curing agent.
또한, 도로시설 구조물의 제조공정 중에는 상기에서 제조된 조성물을 제작되는 도로시설 구조물의 외표면에 도포하는 공정을 포함하는 것을 특징으로 한다.In addition, the manufacturing process of the road facility structure is characterized in that it comprises a step of applying the composition prepared above to the outer surface of the road facility structure to be manufactured.
이형실리콘수지, 톨루엔, 스티렌계 아크릴 에멀젼수지, 재활용 안료Release silicone resin, toluene, styrene acrylic emulsion resin, recycled pigment
Description
본 발명은 광고물 부착방지용 도로시설 구조물의 제조방법에 관한 것으로, 보다 상세하게는 실리콘화합물을 이용한 불법광고물 부착방지제를 구성하여 도로시설 구조물 즉 가로등, 신호등, 전신주 빛 배전반 제조시 도포시켜 완성된 제품을 도로에 초기부터 설치하는 광고물 부착방지용 도로시설 구조물의 제조방법에 관한 것이다.The present invention relates to a method for manufacturing a road facility structure for preventing the adhesion of advertisements, and more particularly, by constructing an anti-adhesive agent for preventing illegal advertisements using a silicone compound, it is completed by coating the road facility structure, ie, a street lamp, a traffic light, and a telephone pole light switchboard. The present invention relates to a method for manufacturing a road facility structure for preventing the attachment of advertisements from the beginning.
최근 가로등, 전신주, 신호등 및 배전반 등에 광고물이 무분별하게 불법으로 도시미관을 해칠 뿐만 아니라 이러한 부착물들을 제거하기 위한 별도의 인력을 필요로 하여 경제적으로도 많은 손실을 초래하였다.In recent years, advertisements, such as street lamps, telephone poles, traffic lights, and switchboards, indiscriminately illegally harm the city's aesthetics, and require a separate manpower to remove these attachments, resulting in economic losses.
그러나, 종래에는 상기와 같은 불법광고 부착물의 부착을 방지하기 위해 도로에 설치된 도로 시설물에 이형효과를 얻기 위한 이형제를 비롯하여 침상모양의 돌출형태를 가진 보호판 등을 도포 또는 부착함으로써 광고물 부착을 방지하였지만, 기설치된 도로 시설물에 이형제 또는 보호판을 도포 또는 부착하는 것은 많은 인력이 소요되는 문제점이 있고, 또한 그에 따른 경제적인 손실도 감수하여야 하지만 이형제 또는 보호판의 설치상태가 오래도록 유지되지 못한다는 문제점도 발생된다. 그래서 실질적으로 불법광고 부착물의 부착상태를 사실상 방치하고 있다가 일정한 시간이 지나면 다시 인력을 투입하여 불법광고 부착물을 제거하는 등 부착과 제거가 반복되는 악순환이 지속되고 있는 실정이다. However, in the past, to prevent the attachment of illegal advertisement attachments, the attachment of the advertisements was prevented by applying or attaching a release plate for obtaining a release effect to the road facilities installed on the road, and a protective plate having a needle-like protrusion. In addition, applying or attaching a release agent or protection plate to an existing road facility requires a lot of manpower, and also requires economic loss, but also causes a problem that the installation state of the release agent or protection plate is not maintained for a long time. . Thus, the vicious cycle in which the attachment and removal of the illegal advertisement attachments is repeated, such as the fact that the attachment state of the illegal advertisement attachments is actually left unattended, and after a certain time, the manpower is input again to remove the illegal advertisement attachments.
본 발명은 상기와 같은 문제점을 해결하기 위하여 안출된 것으로서, 이형효과가 우수한 광고물 부착방지용 조성물을 제조하고, 도로시설 구조물 즉 가로등 지주, 전신주, 신호등 지주 및 배전반의 제조단계에 상기 광고물 부착방지용 조성물을 도포시켜 완성된 제품들을 도로에 초기설치하여 시공비용의 중복을 절감시키고, 불법광고 부착물이 부착되더라도 곧바로 떨어지도록 하여 도시미관의 손상을 방지하며, 더불어 부착물의 제거로 인한 인력투입을 없애 경제적인 손실을 최소화할 수 있는 광고물 부착방지용 도로시설 구조물 제조방법을 제공하는 데 있다.The present invention has been made in order to solve the above problems, to prepare a composition for preventing ad attachments excellent in the release effect, and to prevent the ad attachment in the manufacturing step of the road facility structure, namely street lamp posts, telephone poles, traffic light posts and switchboards. Applying the composition to the initial installation of the finished product on the road to reduce the duplication of construction costs, to prevent the damage of the urban aesthetics by dropping immediately even if the illegal advertising attachments attached, and eliminates the manpower input by removing the attachments It is to provide a method for manufacturing a road facility structure for preventing the adhesion of advertising to minimize the loss of phosphorus.
상기의 목적을 달성하기 위하여, 본 발명에 따른 광고물 부착 방지용 조성물은 가로등 지주, 신호등 지주, 전신주, 배전반 등에 도포되어 광고물이 부착되는 것을 방지하는 조성물에 있어서, 평균중합도가 20 ~ 60인 저중합도 실리콘 수지 50 ~ 60중량%와 평균중합도가 150 ~ 200인 고중합도 실리콘 수지 40 ~ 50중량%를 혼합하여 제조된 이형실리콘수지와 용제인 톨루엔을 상온에서 2:3의 중량비로 혼합한 1차 합성용제를 제조한 후, 상기 제조된 1차 합성용제 80 ~ 90중량%를 스티렌계 아크릴 에멀젼수지 10 ~ 20중량%와 혼합교반하여 2차 합성용제를 제조하고, 상기 2차 합성용제 40 ~ 50중량%와 백시멘트 45 ~ 50중량% 및 칼슘 5중량%를 24 ~ 48시간 겔화시켜 반죽된 혼합물을 제조하고, 상기 혼합물 100중량부에 대하여 재활용 안료 0.001 ~ 2중량부와 경화제 0.001 ~ 0.05중량부를 첨가하여 제조되는 것을 특징으로 한다.In order to achieve the above object, the composition for preventing ad attachment according to the present invention is applied to street light props, traffic light props, telephone poles, switchboards, etc. to prevent the ad attachments, low average polymerization degree of 20 to 60 Primary polysilicon resin prepared by mixing 50 to 60% by weight of a polymerization degree silicone resin and 40 to 50% by weight of a high polymerization degree silicone resin having an average degree of polymerization of 150 to 200 was mixed with a toluene solvent at room temperature in a weight ratio of 2: 3. After the preparation of the synthetic solvent, 80-90 wt% of the prepared primary synthetic solvent was mixed and stirred with 10-20 wt% of the styrene-based acrylic emulsion resin to prepare a secondary synthetic solvent, and the secondary synthetic solvent 40-50 To prepare a kneaded mixture by gelling 24% to 50% by weight and 45% by weight of cement and 5% by weight of calcium for 24 to 48 hours, 0.001 to 2 parts by weight of recycled pigment and 0.001 to 0.05 parts by weight of a curing agent based on 100 parts by weight of the mixture.Is added characterized in that the manufacturing.
또한, 본 발명에 따른 광고물 부착 방지용 도로시설 구조물의 제조방법은 가로등 지주, 신호등 지주, 전신주, 배전반 등과 같은 도로시설 구조물의 제조방법에 있어서, 상기 도로시설 구조물의 제조공정 중에는 상기에서 제조된 광고물 부착 방지용 조성물을 제작되는 도로시설 구조물의 외표면에 도포하는 공정을 포함하는 것을 특징으로 한다.In addition, the method of manufacturing a road facility structure for preventing advertisements according to the present invention is a method of manufacturing a road facility structure, such as street lamp posts, traffic light posts, telephone poles, switchboards, etc., during the manufacturing process of the road facility structure advertising It characterized in that it comprises a step of applying a composition for preventing water adhesion to the outer surface of the road facility structure to be manufactured.
이하, 본 발명에 따른 광고물 부착 방지용 조성물 및 이것을 이용한 광고물 부착 방지용 도로시설 구조물의 제조방법을 상세히 설명하면 다음과 같다.Hereinafter, a composition for preventing ad attachment according to the present invention and a method for manufacturing an ad attachment prevention road facility structure using the same will be described in detail.
먼저, 광고물 부착 방지용 조성물의 제조방법에 대하여 설명한다.First, the manufacturing method of the composition for preventing ad adhesion is demonstrated.
평균중합도가 20 ~ 60인 저중합도 실리콘 수지 50 ~ 60중량%와 평균중합도가 150 ~ 200인 고중합도 실리콘 수지 40 ~ 50중량%를 혼합하여 이형실리콘수지를 제조한다. 이렇게 저중합도의 실리콘 수지와 고중합도의 실리콘 수지를 혼합하는 이유는 중합도에 따른 용해도의 차이에 의하여 상대적으로 고중합도의 실리콘 수지는 용해도가 낮기 때문에 경화시 표면이 미끈해지지 않고 울퉁불퉁한 표면을 형성하기 때문이다.A release silicone resin is prepared by mixing 50 to 60 wt% of a low polymerization silicone resin having an average degree of polymerization of 20 to 60 and 40 to 50 wt% of a high polymerization silicone resin having an average degree of polymerization of 150 to 200. The reason for mixing the low-polymerization silicone resin with the high-polymerization silicone resin is that the high-polymerization silicone resin has low solubility due to the difference in solubility according to the degree of polymerization, so that the surface does not become slippery when hardened to form an uneven surface. Because.
이와같이 울퉁불퉁하게 형성된 표면은 실리콘의 이형성에 의하여 부착물(광고물)의 접착성이 떨어지게 되고, 또한 광고물의 접착면적이 최소화되고, 광고물과 표면사이로 물의 침투가 용이하게 되어 바람이나 빗물에 의해 쉽게 광고물이 떨어지게 되는 효과를 갖게 된다.The uneven surface formed as described above is inferior in adhesiveness due to the release of silicone, and the adhesion area of the advertisement is minimized, and water is easily penetrated between the advertisement and the surface. It will have the effect of falling water.
또한, 상기와 같이 이형실리콘수지는 평균중합도가 20 ~ 60인 저중합도 실리콘 수지 50 ~ 60중량%와 평균중합도가 150 ~ 200인 고중합도 실리콘 수지 40 ~ 50중량%를 혼합하는 것이 가장 바람직한 효과를 갖게 된다. 이는 혼합된 실리콘 수지 전체량에 대하여 평균 중합도가 20 ~ 60인 실리콘 수지의 양이 상기의 범위보다 감소하게 되면, 용매에 용해시 점도가 너무 높아지기 때문에 균일한 혼합이 어렵고, 작업성이 좋지 못하며, 반대로 평균 중합도가 20 ~ 60인 실리콘 수지의 양이 상기의 범위보다 증가하게 되면 점도가 너무 낮아지게 되어 경화속도가 느려지게 되고, 도포시 용액이 흘러내리게 되어 균일한 도포층을 형성시키기 어렵기 때문이다.In addition, as described above, the release silicone resin has the most preferable effect of mixing 50 to 60% by weight of a low polymerization degree silicone resin having an average polymerization degree of 20 to 60 and 40 to 50% by weight of a high polymerization degree silicone resin having an average degree of polymerization of 150 to 200. Will have If the amount of the silicone resin having an average polymerization degree of 20 to 60 with respect to the total amount of the mixed silicone resin is less than the above range, since the viscosity is too high when dissolved in a solvent, uniform mixing is difficult and workability is not good, On the contrary, if the amount of the silicone resin having an average degree of polymerization of 20 to 60 is higher than the above range, the viscosity becomes too low and the curing speed becomes slow, and the solution flows down during application, making it difficult to form a uniform coating layer. to be.
이렇게 이형실리콘수지가 생성되면 용제인 톨루엔 2 : 3의 중량비로 상온에서 혼합하여 1차 합성용제를 제조한다.When the release silicone resin is produced as described above, a primary synthetic solvent is prepared by mixing at room temperature in a weight ratio of toluene 2: 3 as a solvent.
그런다음, 상기 제조된 1차 합성용제 80 ~ 90중량%에 스티렌계 아크릴 에멀젼수지를 10 ~ 20중량%를 혼합교반하여 2차 합성용제를 제조한다.
상기 스티렌계 아크릴 에멀젼수지(BASF사의 D623)는 아크릴 모노머를 중합반응시켜 생성되는 고분자의 총징으로 높은 점성을 통해 증강된 접착력을 갖는 유백색 또는 투명한 액체이다. 수분 증발에 의해 아크릴 폴리머의 미분자가 결합하여 무색 투명한 필름(층)을 형성하며, 광택성, 내수성, 안료 환화성, 내노화성, 견뢰도 및 내후성이 우수하다.Then, the secondary synthetic solvent is prepared by mixing and stirring 10 to 20 wt% of the styrene-based acrylic emulsion resin with 80 to 90 wt% of the prepared primary synthetic solvent.
The styrene-based acrylic emulsion resin (BASF's D623) is a milky white or transparent liquid having enhanced adhesion through high viscosity as a total polymer produced by polymerizing an acrylic monomer. By evaporation of water, fine molecules of the acrylic polymer combine to form a colorless transparent film (layer), and are excellent in gloss, water resistance, pigment cyclization, aging resistance, fastness and weather resistance.
그리고, 상기 제조된 2차 합성용제 40 ~ 50중량%와 백시멘트 45 ~ 50중량% 및 칼슘 5중량%를 혼합하여 24 ~ 48시간 동안 교반하여 겔화시킨다.Then, 40 to 50% by weight of the prepared secondary synthetic solvent, 45 to 50% by weight of cement and 5% by weight of calcium are mixed and stirred for 24 to 48 hours to gel.
상기 혼합비는 수차례의 실험을 통하여 조성물 제조시 용매와 용제를 대략 1 : 1로 하였을 때 최적의 부착방지 효과를 얻을 수 있고, 그 제조비용의 경제적인 측면도 고려되어 정해진 비율이다.The mixing ratio is obtained by taking several experiments to obtain an optimum anti-sticking effect when the solvent and the solvent is approximately 1: 1, the ratio is determined in consideration of the economic aspect of the manufacturing cost.
상기와 같이 2차 합성용제, 백시멘트 및 칼슘을 혼합하여 겔화시키는 도중 또는 겔화시킨 다음 원하는 색상을 얻기 위하여 안료, 바람직하게는 재활용 안료를 상기 혼합물 100중량부에 대하여 재활용 안료 0.001 ~ 2중량부를 혼합하여 교반한다.
상기 안료는 무기질 안료인 이산화티탄(titanium dioxide), 산화철적(Iron oxide red) 또는 산화철황(Iron oxide yellow), 산화크롬(Chromium oxide), 산화아연(Zinc oxide), 재활용 안료 중 선택되는 안료를 이용하여 백색, 적색, 황색, 녹색 및 청색 등과 같이 다양한 색을 표현할 수 있다.
또한, 상기 재활용 안료는 페라이트계 철의 제조공정에서 발생되는 산화철을 다시 재활용하여 안료로 적용하는 것이다. 산화철은 무기질 안료로서 유기질 안료와 비교하여 기상변화에 대한 내후성이 우수하고, 색상변화가 적어 유기질 안료보다 선호되는 안료이다.As described above, in order to obtain a desired color during or after gelation by mixing the secondary synthetic solvent, the back cement and the calcium, the pigment, preferably the recycled pigment, is mixed with 0.001 to 2 parts by weight of the recycled pigment with respect to 100 parts by weight of the mixture. And stir.
The pigment is a pigment selected from among inorganic pigments such as titanium dioxide (iron dioxide), iron oxide (Iron oxide red) or iron oxide (Iron oxide yellow), chromium oxide (Chromium oxide), zinc oxide (Zinc oxide), recycled pigments It can be used to express various colors such as white, red, yellow, green and blue.
In addition, the recycled pigment is to reuse the iron oxide generated in the manufacturing process of ferritic iron to be applied as a pigment. Iron oxide is an inorganic pigment, which is superior to organic pigments because of its excellent weather resistance against gas phase changes and less color change, and thus is preferred to organic pigments.
이렇게 원하는 색상을 얻은 혼합물은 사용하기 직전에 상기 혼합물 100중량부에 대하여 0.001중량부에서 최고 0.05중량부까지 경화제를 넣음으로써 광고물 부착 방지용 조성물이 완성된다.The mixture obtained the desired color is added with a curing agent from 0.001 parts by weight up to 0.05 parts by weight with respect to 100 parts by weight of the mixture just before use to complete the composition for preventing ad attachment.
다음으로, 광고물 부착 방지용 조성물을 이용한 광고물 부착 방지용 도로시설 구조물의 제조방법에 대하여 설명하면 다음과 같다.Next, the manufacturing method of the ad installation prevention road facility structure using the composition for preventing the ad attachment is described as follows.
본 발명에서 실시되는 도로시설 구조물의 제조방법은 가로등 지주, 신호등 지주, 전주, 배전반 등을 제조하는 방법에 관한 것으로서, 본 발명의 요지는 가로등 지주, 신호등 지주, 전주, 배전반 등과 같은 도로시설 구조물을 제조할 때 상기에서 제조된 광고물 부착 방지용 조성물을 상기 도로시설 구조물이 도로에 설치된 다음에 도포되는 것이 아니라 제조단계에서 상기 광고물 부착 방지용 조성물이 도포되어 도로시설 구조물이 완성되고, 이를 도로에 설치하여 작업성과 경제성을 향상시키는 것이다.The method for manufacturing a road facility structure according to the present invention relates to a method for manufacturing a street lamp post, a traffic light post, a pole, a switchboard, and the like. The gist of the present invention provides a road facility structure such as a street lamp post, a traffic light post, a pole, a switchboard, and the like. At the time of manufacture, the composition for preventing ad attachments prepared above is not applied after the road facility structure is installed on the road, but the composition for preventing ad attachment is applied at the manufacturing stage to complete the road facility structure and install it on the road. To improve workability and economics.
그럼, 상기 도로시설 구조물의 제조에 대해 가로등 지주의 예를 들어 설명한 다. Then, an example of a street lamp post is described with respect to the manufacture of the road facility structure.
가로등 지주를 비롯하여 대부분의 도로시설 구조물은 다이케스팅 주조 방법으로 제조된다.Most road structures, including street lamp posts, are manufactured by die casting casting.
다이케스팅 주조방법이란 금형을 사용하여 용해된 재료를 주조기에서 압력을 주입하여 주물형체로 성형하는 방법을 말하는데, 보통 주석, 아연, 마그네슘, 알루미늄, 동 등의 합금재료를 사용하고, 생산성이 대단히 좋으며, 다량의 부품을 동시에 작업할 수 있는 장점이 있다. 또한, 제품의 크기나 중량의 실질적인 제한이 없어서 복잡하고 다양한 형상의 제품을 생산하는데 적합하다.The die casting casting method is a method of molding a molten material into a cast body by injecting pressure from a casting machine. Usually, alloy materials such as tin, zinc, magnesium, aluminum, and copper are used, and productivity is very good. The advantage is that a large number of parts can be worked at the same time. In addition, there is no practical limitation on the size or weight of the product, which makes it suitable for producing products of complex and various shapes.
통상적인 방법은 상기와 같이 제조되는 제품을 조건에 맞게 후가공하고, 각종 부품을 조립한 다음 품질 검사를 한 후 제품을 포장하여 출하하게 된다.The conventional method is to post-process the product to be manufactured as described above, assembling various parts and then quality inspection and then package and ship the product.
하지만, 본 발명은 상기와 같이 도로시설 구조물을 제조하는 단계 중 각종 부품을 조립하기 전 단계 또는 품질 검사 단계 또는 제품 포장 단계 전에 상기에서 제조된 광고물 부착 방지용 조성물을 구조물에 도포하여 제품을 완성하는 것이다.However, the present invention is to complete the product by applying the composition for preventing the adhesion of the advertisement prepared in the above step before assembling the various components or the quality inspection step or product packaging step of manufacturing the road facility structure as described above will be.
이때 광고물 부착 방지용 조성물이 도포하는 위치는 각 구조물마다 다르겠지만 통상 구조물이 설치되었을 때 사람들의 시선 및 부착 가능위치를 감안하여 도포하는 것이 바람직할 것이다.At this time, the position to be applied to the composition for preventing the adhesion of advertisements will vary for each structure, but when the structure is installed, it would be preferable to apply in consideration of the eyes of the people and the attachable position.
좀더 구체적으로 실시예를 통해 본 발명을 설명한다.More specifically, the present invention will be described through examples.
제 1 단계 : 광고물 부착 방지용 조성물을 제조하는 단계First step: preparing a composition for preventing ad attachment
평균중합도가 20 ~ 60이 되는 저중합도 실리콘 수지(Dow Corning사의 QP8-5314 저중합도 제품 사용) 500g과 평균중합도가 150 ~ 200인 고중합도 실리콘 수지(Dow Corning사의 QP8-5314 고중합도 제품 사용) 500g을 혼합하여 교반기에서 분당회전수 30rpm의 속도로 1시간정도 교반 혼합하여 이형실리콘수지를 제조한다.500 g of low-polymerization silicone resins with average polymerization degrees of 20 to 60 (using Dow Corning's QP8-5314 low-polymerization products) and 500-g of high-polymerization silicone resins with average polymerization degrees of 150 to 200 (using Dow Corning's QP8-5314 high polymerization products) To prepare a release silicone resin by mixing and stirring for about 1 hour at a speed of 30rpm per minute in a stirrer.
상기 제조된 이형실리콘수지 400g에 용제인 톨루엔 600g을 혼합교반하여 1차 합성용제를 제조한 후, 상기 1차 합성용제 900g에 스티렌계 아크릴 에멀젼수지(BASF사의 D623 사용)를 20g 혼합하여 교반기에서 20 ~ 30rpm의 속도로 30분정도 교반하여 2차 합성용제를 제조한다. 완성된 2차 합성용제 420g과 백시멘트 420g, 칼슘 20g을 혼합하여 교반기에서 분당 회전수 30rpm의 속도로 30분 교반 후 상온의 밀폐용기에서 48시간동안 겔화시켜 반죽된 혼합물을 얻은 다음 재활용 안료 15g을 첨가혼합하고 요구되는 칼라를 표현하여 광고물 부착 방지제를 제조한다.To prepare a primary synthetic solvent by mixing and stirring toluene 600g solvent to 400g of the release silicone resin prepared above, 20g of styrene-based acrylic emulsion resin (using D623 of BASF) is mixed with 900g of the primary synthetic solvent 20 in a stirrer To prepare a secondary synthetic solvent by stirring for about 30 minutes at a speed of ~ 30rpm. 420 g of the finished secondary synthetic solvent was mixed with 420 g of white cement and 20 g of calcium, stirred for 30 minutes at a speed of 30 rpm in a stirrer, and gelled for 48 hours in a sealed container at room temperature to obtain a kneaded mixture. The admixture and the required color are expressed to prepare an ad attachment inhibitor.
제 2 단계 : 도로시설 구조물을 제조하는 단계Second step: manufacturing the road facility structure
다이케스팅 주조방법을 사용하여 가로등 지주을 생산한다. 그리고, 표면을 여건에 맞게 표면을 처리하고, 각종 부품 들을 조립한다.Produce street lamp post using die casting casting method. Then, the surface is treated according to the conditions, and various parts are assembled.
그런다음 상기 제 1단계에서 제조된 광고물 부착 방지용 조성물에 경화제를 첨가하고 교반한 다음 구조물에 도포한다.Then, the curing agent is added to the composition for preventing ad attachment prepared in the first step, stirred and then applied to the structure.
이때 광고물 부착 방지용 조성물을 도포하는 방법은 가압식 스프레이 건을 활용하여 스프레이로 도포하고, 붓, 롤러등을 활용하여 미도포된 부분을 도포하는 방법과, 용기를 제작하여 광고물 부착 방지용 조성물을 담은 후 일정한 간격으로 2 ~ 3회 정도 도로시설 구조물을 담궈서 도포하는 방법 중 하나를 이용한다. 이때는 도로시설 구조물을 3분정도 담궜다가 빼내어 가사, 경화 시켜 도로시설 구조물의 제조를 완성한다.At this time, the method of applying the composition for preventing the adhesion of the advertisement is applied by spraying using a pressure spray gun, and the method of applying the uncoated portion by using a brush, a roller, etc., and a container containing the composition for preventing the adhesion of the advertisement. Then use one of the methods of immersing and applying the road facility structure 2-3 times at regular intervals. At this time, immerse the road construction structure for 3 minutes, remove it, and then harden it to complete the manufacture of the road construction structure.
다음 표1은 상기 실시예에 따른 실험결과와 품질기준을 나타내었다.Table 1 shows the experimental results and the quality standards according to the embodiment.
상기 표1의 결과 본 발명에 사용된 광고물 부착 방지제는 광고물 부착 방지제 품질기준을 상위하는 것으로 나타났다.As a result of Table 1, the ad attachment inhibitor used in the present invention was found to be higher than the ad attachment inhibitor quality standards.
상기에서 본 바와 같이, 본 발명은 광고물 부착 방지용 조성물을 제조하여 도로시설 구조물(가로등 지주, 신호등 지주, 전신주, 배전반 등) 제조단계에서 사익 조성물을 도포시켜 제품을 완성시키고, 완성된 제품들을 도로에 설치함으로써, 시공비용의 중복을 절감하고, 불법광고물의 부착을 방지하여 도시미관의 손상을 방지하며, 부착물의 제거에 드는 인력 및 경제적 손실을 최소화하는 효과가 있다.As seen from the above, the present invention is to prepare a composition for preventing the ad attachments to finish the product by applying the sound composition in the manufacturing step of the road facility structure (street lamp, traffic light pole, telephone pole, switchboard, etc.), the finished products road By installing in, it is possible to reduce the duplication of construction costs, to prevent the attachment of illegal advertisements to prevent damage to the urban aesthetics, and to minimize the labor and economic losses in removing the attachments.
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20020089664A (en) * | 2001-05-24 | 2002-11-30 | 김학봉 | Adhesion preventive matter |
KR20030071053A (en) * | 2002-02-27 | 2003-09-03 | 성장경 | A manufacturing method of material for no scribbling and sticking advertisement |
KR20030092349A (en) * | 2002-05-29 | 2003-12-06 | (주)에취앤제이코퍼레이션 | A composite of a silicone coating material |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
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KR20030071053A (en) * | 2002-02-27 | 2003-09-03 | 성장경 | A manufacturing method of material for no scribbling and sticking advertisement |
KR20030092349A (en) * | 2002-05-29 | 2003-12-06 | (주)에취앤제이코퍼레이션 | A composite of a silicone coating material |
Cited By (1)
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KR101046536B1 (en) | 2008-04-16 | 2011-07-05 | 주식회사 프레코 | Anti-adhesion composition for spray |
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