KR20030071053A - A manufacturing method of material for no scribbling and sticking advertisement - Google Patents
A manufacturing method of material for no scribbling and sticking advertisement Download PDFInfo
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- KR20030071053A KR20030071053A KR1020020010578A KR20020010578A KR20030071053A KR 20030071053 A KR20030071053 A KR 20030071053A KR 1020020010578 A KR1020020010578 A KR 1020020010578A KR 20020010578 A KR20020010578 A KR 20020010578A KR 20030071053 A KR20030071053 A KR 20030071053A
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F19/00—Advertising or display means not otherwise provided for
- G09F19/22—Advertising or display means on roads, walls or similar surfaces, e.g. illuminated
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F2003/023—Adhesive
- G09F2003/0247—Non-strippable anti-stick coatings
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F2003/0255—Forms or constructions laminated
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- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Description
본 발명은 벽보물 부착 및 낙서 방지체의 제조방법에 관한 것으로, 좀 더 상세하게는 불법적으로 부착되는 스티커를 비롯한 부착물을 간편하고 용이하게 제거할 수 있을 뿐만 아니라 어린아이들의 낙서로 부터 보호할 수 있는 광고물 부착 및 낙서 방지체의 제조방법에 관한 것이다.The present invention relates to a method of manufacturing wall treasures and graffiti preventive body, more specifically can be easily and easily remove the attachments, including stickers that are illegally attached as well as protect from the graffiti of children. The present invention relates to a method for manufacturing affixed advertisements and preventing graffiti.
일반적으로 도로 시설물 등의 보호 및 보존을 위하여 다양한 색의 도료가 도포되어 있으나 최근 각종 벽보물 등의 부착으로 인하여 외관의 손상은 물론 시설물의 경관을 해하는 경우가 빈번하게 발생하고 있다.In general, various colors of paint are applied for the protection and preservation of road facilities. Recently, due to the attachment of various wall coverings, damage to the exterior as well as the scenery of the facilities have frequently occurred.
실질적으로 도심의 가로벽이나 건물의 벽, 시멘트 담, 공원의 울타리, 게시판, 전신주 등에는 벽보 부착물들이 장소에 구애됨이 없이 무분별하게 부착되어 있어 쾌적한 도시의 환경을 해하는 공해요인으로 대두되고 있으며, 이를 관리하는 정부기관에서는 부착된 벽보물의 제거에 상당한 예산을 낭비하고 있는 실정이다.Practically, wall attachments are attached indiscriminately to city walls, building walls, cement fences, park fences, bulletin boards, telephone poles, etc. Government agencies that manage this waste a considerable amount of money to remove the attached wall coverings.
또한 시설물 등에 기부착되어 있는 부착물 등을 제거하기 위하여 많은 경비와 인원이 동원되어야 함은 물론, 실질적으로는 부착물 등이 여러겹으로 다양한 접착성 물질에 의해 부착되어 있는 실정이므로 수작업에 의한 제거가 용이하지 않다는 문제점이 있었다.In addition, a lot of expenses and personnel must be mobilized to remove the deposits attached to the facilities, etc. In addition, since the attachments are actually attached by various adhesive materials in multiple layers, it is easy to remove them by hand. There was a problem that not.
따라서 금속제 도구 등을 사용하여 완전히 제거하여도 제거 작업후에는 시설물 등의 표면에 도구의 사용에 의한 손상이 그대로 남아있어 미관상 불쾌감을 초래할 뿐만 아니라 부분별한 재부착 행위가 단속을 피하여 반복됨으로 해서 부착물의 제거작업과 부착행위가 계속 이루어지고 있는 바, 이에 대한 대책이 시급히 요구되고 있다.Therefore, even if it is completely removed using a metal tool, the damage caused by the use of the tool remains on the surface of the facility after the removal work, resulting in aesthetic unpleasantness, and the partial reattachment is repeated to avoid crackdown. The removal and attachment of the continuation has been continuously carried out, and countermeasures are urgently required.
따라서 본 발명은 상기와 같은 문제점을 해결하기 위하여 구성된 것으로, 스티커와 같은 벽보물의 접착성을 피착제에 대하여 원천적으로 부착이 이루어지지 않으며, 벽보물의 제거가 용이하게 이루어지도록 하여, 불법 광고물의 제거작업으로 인한 인력과 시간 및 경비를 절감할 수 있으며, 아이들의 낙서로 부터 시설물을 보호할 수 있는 광고물 부착 및 낙서 방지체의 제조방법을 제공함으로서 달성될 수 있다.Therefore, the present invention is configured to solve the above problems, the adhesion of the wall coverings such as stickers is not made to adhere to the adherent at the source, and to facilitate the removal of the wall coverings, removal of illegal advertisements It can reduce the manpower and time and expenses due to, and can be achieved by providing a method of manufacturing advertising attachments and anti-graffiti to protect the facility from children's graffiti.
상기와 같은 목적을 달성하기 위하여 본 발명은,The present invention to achieve the above object,
평균 중합도가 20 ~ 60인 실리콘과 평균 중합도가 150 ~ 200인 실리콘이 50 ~ 60 : 40 ~ 50으로 혼합된 합성수지 100중량부에 대하여 300 내지 400중량부의 용매를 혼합한 조성물을 각종 도로 시설물과 같은 피착체에 소정의 두께로 도포하고 경화시킴으로서 이루어지는 것을 특징으로 하는 광고물 부착 및 낙서 방지체의 제조방법을 제공함으로서 달성될 수 있다.A composition in which 300 to 400 parts by weight of a solvent is mixed with 100 parts by weight of a silicone resin having an average polymerization degree of 20 to 60 and a silicone having an average degree of polymerization of 150 to 200 is mixed at 50 to 60:40 to 50 It can be achieved by providing a method for producing an advertisement attachment and graffiti prevention body, characterized in that by applying to the adherend to a predetermined thickness and cured.
이하에서는 본 발명에 대해서 좀 더 구체적으로 설명하기로 한다.Hereinafter, the present invention will be described in more detail.
본 발명의 광고물 부착 및 낙서 방지체를 제조하기 위하여 먼저 평균 중합도가 20 ~ 60인 실리콘과 평균 중합도가 150 ~ 200인 실리콘이 50 ~ 60 : 40 ~ 50으로 혼합된 합성수지를 용매에 혼합하게 된다.In order to prepare the advertisement adhering and anti-scribing material of the present invention, first, the silicone having a mean polymerization degree of 20 to 60 and the silicone having an average degree of polymerization of 150 to 200 are mixed in a solvent with a synthetic resin of 50 to 60: 40 to 50. .
상기 사용되는 실리콘은 건축물이나 시설물의 실링이나 방수 및 미관을 위해 일반적으로 사용되는 건축재료로서, 경화 후에는 부드럽고 질기며, 매우 미끈한 표면이 유지될 뿐만 아니라 이형성을 가지고 있기 때문에 스티커와 같은 벽보 부착물의 접착성을 떨어뜨리게 된다.The silicone used is a building material generally used for sealing or waterproofing and aesthetics of a building or facility, and after curing, it is soft and tough, and a very smooth surface is not only maintained but also has releasability. The adhesive will be degraded.
이와 같은 실리콘 합성수지는 평균 중합도가 20 ~ 60인 실리콘과 평균 중합도가 150 ~ 200인 실리콘을 혼합하여 사용하게 되면 더 좋은 효과를 가져오게 된다.Such silicone synthetic resins have a better effect when a mixture of silicon having an average degree of polymerization of 20 to 60 and silicon having an average degree of polymerization of 150 to 200 is used.
즉, 저중합도와 고중합도의 실리콘 수지를 일정비율로 혼합하여 사용하게 되면, 중합도에 따른 용해도의 차이에 의하여 상대적으로 고중합도의 실리콘 수지는 용해도가 낮기 때문에 경화시 표면이 미끈해지지 않고 울퉁불퉁한 표면을 형성시키게 된다.That is, when a low polymerization rate and a high polymerization degree silicone resin are mixed at a constant ratio, the high polymerization degree silicone resin has a low solubility due to the difference in solubility according to the degree of polymerization, so that the surface is not slippery when hardened. Will form.
이와 같이 울퉁불퉁하게 형성된 표면은 실리콘의 이형성에 의하여 부착물의 접착성이 떨어지게 되고, 또한 피착체와 접착면적을 최소화되어 있고, 방지체와 광고물 사이에 물의 침투가 용이하게 일어나게 되어 바람이나 빗물에 의해서 쉽게 떨어지게 된다는 효과를 가져오게 된다.The uneven surface formed as described above is inferior in adhesiveness due to the release of silicon, and also minimizes the adherend and the adhesion area, and easily penetrates water between the preventer and the advertisements, caused by wind or rainwater. The effect is that it will fall easily.
상기와 같은 실리콘 혼합수지는 평균 중합도가 20 ~ 60인 실리콘과 평균 중합도가 150 ~ 200인 실리콘을 50 ~ 60 : 40 ~ 50의 비율로 혼합하는 것이 가장 바람직한 효과를 가져오게 된다.As described above, the silicone mixture resin has a most preferable effect of mixing a silicon having an average degree of polymerization of 20 to 60 and a silicon having an average degree of polymerization of 150 to 200 at a ratio of 50 to 60:40 to 50.
이는 혼합된 실리콘 수지 전체량에 대하여 평균 중합도가 20 ~ 60인 실리콘의 양이 감소하게 되면, 용매에 용해시 점도가 너무 높아지기 때문에 균일한 혼합이 어렵고 작업성이 좋지 못하며, 반대로 평균 중합도가 20 ~ 60인 실리콘 수지의 양이 증가하게 되면, 점도가 너무 낮아지게 되어 경화속도가 느리고 도포시 용액이 흘러내리게 되어 균일한 도포층을 형성시키기 어렵기 때문이다.When the amount of silicone having an average degree of polymerization of 20 to 60 is reduced with respect to the total amount of the mixed silicone resin, the viscosity is too high when dissolved in a solvent, so that uniform mixing is difficult and workability is not good. When the amount of the silicone resin of 60 is increased, the viscosity becomes too low, the curing speed is slow, and the solution flows down during application, it is difficult to form a uniform coating layer.
상기와 같이 혼합된 실리콘 수지를 용매와 혼합하게 되는데, 사용되는 용매로는 아세트산에틸 등의 에스테르류, 케톤류, 에탄올 등의 알코올류, 톨루엔이 사용될 수 있으며, 희석제로서 나프타를 소량 첨가하여 사용하게 된다.The silicone resin mixed as described above is mixed with a solvent. As the solvent used, esters such as ethyl acetate, ketones, alcohols such as ethanol, and toluene may be used, and a small amount of naphtha is added as a diluent. .
이 때 혼합된 실리콘 합성수지 100중량부에 대하여 300 내지 400중량부의 용매를 혼합한 조성하는 것이 바람직한데, 이와 같은 배율이 혼합 실리콘 수지의 결착성 및 도포효율면에서 가장 효과적이기 때문이다.At this time, it is preferable to mix 300 to 400 parts by weight of the solvent with respect to 100 parts by weight of the mixed silicone synthetic resin, since this ratio is most effective in terms of binding properties and coating efficiency of the mixed silicone resin.
만약 혼합 실리콘 수지 100중량부에 대하여 용매를 300중량부 미만으로 첨가하게 되면, 실리콘 수지 용액의 농도가 낮아지게 되어, 도포후 도포층이 쉽게 벗겨지거나 쉽게 손상되기 때문에 소정의 효과를 얻기 위해서는 수회 반복하여 덧칠을 해야만 하는 문제점이 있고, 용매를 400중량부 초과하여 첨가하게 되면, 수지 용액의 농도가 너무 진해서 도포작업성이 나쁘고 혼합공정중에 기포가 발생하게 되어 피착체와의 결합력이 떨어지게 된다는 문제점이 발생하게 된다.If the solvent is added to less than 300 parts by weight with respect to 100 parts by weight of the mixed silicone resin, the concentration of the silicone resin solution is lowered, and the coating layer is easily peeled off or easily damaged after application, and thus repeated several times. There is a problem that must be repainted, and when the solvent is added in excess of 400 parts by weight, the concentration of the resin solution is too thick, the coating workability is bad and bubbles are generated during the mixing process, and the bonding strength with the adherend is reduced. Will occur.
상기와 같은 과정이 끝난 후 혼합용액을 도심의 가로벽이나 건물의 벽, 시멘트 담, 공원의 울타리, 게시판, 전신주 등과 같은 피착체에 먼지나 오물질을 제거하여 깨끗하게 한 다음에 도포함으로서 이루어지게 된다.After the above process is completed, the mixed solution is cleaned by removing dust or dirt on adherends such as horizontal walls of buildings, walls of buildings, cement walls, park fences, bulletin boards, and telephone poles. .
이러한 방법으로 형성된 부착방지제 도포층은 투명도가 높아 피착체의 도료층에 형성된 색깔을 변형 또는 훼손시키지 않으면서 벽보물의 부착을 방지할 수 있으며, 따라서 종래의 벽보물 제거작업으로 인한 인력과 시간 및 경비를 절감할 수 있을 뿐만 아니라 어린아이들의 낙서로 부터 보호할 수 있다는 것이다.The anti-sticking agent coating layer formed in this way has high transparency and can prevent the adhesion of the wall coverings without deforming or damaging the color formed on the coating layer of the adherend. Therefore, manpower, time, and expense due to the conventional wall removing work Not only can it save money, but it also protects children from doodles.
이하 실시예에 의하여 본 발명을 더욱 자세하게 설명하기는 하나, 하기의 실시예는 본 발명의 예시일 뿐, 본 발명이 하기의 실시예에 의하여 제한되는 것은 아니다.Although the present invention will be described in more detail with reference to the following examples, the following examples are merely illustrative of the present invention, and the present invention is not limited by the following examples.
<실시예 1><Example 1>
평균 중합도가 50인 실리콘과 평균 중합도가 200인 실리콘을 30 : 70으로 혼합한 합성수지 100중량부를 톨루엔 300 중량부와 균일하게 혼합하고, 상기 혼합용액을 일반적인 도료가 도포되어 있는 피착제에 로울링하여 소정의 두께로 도포하고 경화시킨 것을 실시예 1로 하였다.100 parts by weight of a synthetic resin obtained by mixing a silicone having an average degree of polymerization of 50 and a silicone having an average degree of polymerization of 30:70 was uniformly mixed with 300 parts by weight of toluene, and the mixed solution was rolled onto a coating material coated with a general coating material. What applied and hardened | cured to predetermined thickness was set to Example 1.
상기 실시예 1에 대한 이형성을 측정하기 위하여 상면에 5×10㎝의 스카치테잎을 부착시킨 후, 소정의 세기를 갖는 대형 선풍기를 이용하여 바람을 불어주면서 분무기를 이용하여 물을 분사시킨 다음 그 결과를 측정하였다.In order to measure the releasability of Example 1, after attaching a scotch tape of 5 × 10 cm to the upper surface, water was sprayed using a sprayer while blowing air using a large fan having a predetermined intensity. Was measured.
상기 실시예 1의 실험결과 부착되어 있던 스카치테잎이 분무기로 20회를 분사하였을 때 박리되는 것을 알 수 있었다. 이 경우 제조과정에서 고중합도의 실리콘의 양이 저중합도의 실리콘의 양에 비하여 상대적으로 많기 때문에 용매에 혼합시 수지가 균일하게 혼합되지 않게 되어 작업성이 좋지 않다는 문제점도 발생하였다.As a result of the experiment of Example 1, it was found that the scotch tape attached was peeled off when sprayed 20 times with an atomizer. In this case, since the amount of the high polymerization degree of silicone is relatively higher than the amount of the low degree of polymerization, the resin is not uniformly mixed when mixed in a solvent, resulting in poor workability.
<실시예 2><Example 2>
평균 중합도가 50인 실리콘과 평균 중합도가 200인 실리콘을 50 : 50으로 혼합한 합성수지 100중량부를 톨루엔 300 중량부와 균일하게 혼합하고, 상기 혼합용액을 일반적인 도료가 도포되어 있는 피착제에 로울링하여 소정의 두께로 도포하고 경화시킨 것을 실시예 2로 하였다.100 parts by weight of a synthetic resin obtained by mixing 50:50 of silicon having an average degree of polymerization of 50 and 50% by weight of silicon is uniformly mixed with 300 parts by weight of toluene, and the mixed solution is rolled onto a coating material coated with a general coating material. What applied and hardened | cured to predetermined thickness was set to Example 2.
상기 실시예 2에 대한 이형성 측정은 실시예 1과 동일한 방법으로 실시하였다.The releasability measurement for Example 2 was carried out in the same manner as in Example 1.
상기 실시예 2의 실험결과, 부착되어 있던 스카치테잎이 분무기로 5회를 분사하였을 때 박리되는 것을 알 수 있었다. 이는 부착방지제의 표면이 울퉁불퉁하여 스카치테잎의 접착층과 부착방지제 사이로 물의 침투가 용이하게 일어나 접착성을 떨어뜨렸기 때문이다. 또한 제조과정에 있어서도 고중합도와 저중합도의 수지가 균일하게 혼합될 수 있는 점도가 유지되어 작업성이 좋으며, 피착체에 도포과정에 있어서도 균일한 두께의 도포층을 형성시킬 수 있었다.As a result of the experiment of Example 2, it was found that the adhered Scotch tape was peeled off when sprayed five times with an atomizer. This is because the surface of the anti-sticking agent is uneven, so water penetrates easily between the adhesive layer of the scotch tape and the anti-sticking agent, thereby reducing the adhesiveness. In addition, even during the manufacturing process, the viscosity of the high-polymerization and the low-polymerization resin can be uniformly mixed to maintain the workability, and the coating layer having a uniform thickness can be formed on the adherend.
<실시예 3><Example 3>
평균 중합도가 50인 실리콘과 평균 중합도가 200인 실리콘을 70 : 30으로 혼합한 합성수지 100중량부를 톨루엔 300 중량부와 균일하게 혼합하고, 상기 혼합용액을 일반적인 도료가 도포되어 있는 피착체에 로울링하여 소정의 두께로 도포하고경화시킨 것을 실시예 3으로 하였다.100 parts by weight of a synthetic resin obtained by mixing 70:30 of silicon having an average degree of polymerization and silicon having an average degree of polymerization of 200: was uniformly mixed with 300 parts by weight of toluene, and the mixed solution was rolled onto an adherend coated with a general coating material. It was set as Example 3 what apply | coated to the predetermined thickness and hardened | cured.
상기 실시예 3에 대한 이형성 측정은 실시예 1과 동일한 방법으로 실시하였다.The releasability measurement for Example 3 was carried out in the same manner as in Example 1.
상기 실시예 3의 실험결과 부착되어 있던 스카치테잎이 분무기로 30회를 분사하였을 때 박리되는 것을 알 수 있었다. 이 경우 고중합도의 실리콘의 양이 저중합도의 실리콘의 양에 비하여 상대적으로 적기 때문에 점도가 낮아 도포중에 흘러내려 균일한 도포층을 형성하기가 어렵다는 문제점도 발생하였다.As a result of the experiment of Example 3, it was found that the scotch tape attached was peeled off when sprayed 30 times with an atomizer. In this case, since the amount of silicon having a high degree of polymerization is relatively small compared to the amount of silicon having a low degree of polymerization, a problem arises in that it is difficult to form a uniform coating layer due to low viscosity and low flow rate during application.
<실시예 4><Example 4>
평균 중합도가 50인 실리콘과 평균 중합도가 200인 실리콘을 50 : 50으로 혼합한 합성수지 100중량부를 톨루엔 200 중량부와 균일하게 혼합하고, 상기 혼합용액을 일반적인 도료가 도포되어 있는 피착체에 로울링하여 소정의 두께로 도포하고 경화시킨 것을 실시예 4로 하였다.100 parts by weight of a synthetic resin obtained by mixing 50:50 of silicon having an average degree of polymerization and silicon having an average degree of polymerization of 50:50 was uniformly mixed with 200 parts by weight of toluene, and the mixed solution was rolled onto an adherend coated with a general coating material. What applied and hardened | cured to predetermined thickness was set to Example 4.
상기 실시예 4에 대한 이형성 측정은 실시예 1과 동일한 방법을 사용하였다.The releasability measurement for Example 4 was the same as in Example 1.
상기 실시예 4의 실험결과 부착되어 있던 스카치테잎이 분무기로 20회를 분사하였을 때 박리되는 것을 알 수 있었다. 이 경우 혼합용액의 농도가 너무 낮기 때문에 도포후 부착방지층의 두께가 너무 얇아 쉽게 박리되어 떨어져나간다는 문제점도 발생하였다.As a result of the experiment of Example 4, it was found that the scotch tape attached was peeled off when sprayed 20 times with an atomizer. In this case, since the concentration of the mixed solution is too low, the thickness of the anti-stick layer after coating is too thin to easily peel off and fall off.
<실시예 5>Example 5
평균 중합도가 50인 실리콘과 평균 중합도가 200인 실리콘을 50 : 50으로 혼합한 합성수지 100중량부를 톨루엔 600 중량부와 균일하게 혼합하고, 상기 혼합용액을 일반적인 도료가 도포되어 있는 피착체에 로울링하여 소정의 두께로 도포하고 경화시킨 것을 실시예 5로 하였다.100 parts by weight of a synthetic resin obtained by mixing 50:50 of silicon having an average degree of polymerization and silicon having an average degree of polymerization of 50:50 was uniformly mixed with 600 parts by weight of toluene, and the mixed solution was rolled onto an adherend coated with a general coating material. What was apply | coated and hardened | cured to predetermined thickness was set to Example 5.
상기 실시예 5에 대한 이형성 측정은 실시예 1과 동일한 방법으로 실시하였다.The releasability measurement for Example 5 was performed in the same manner as in Example 1.
상기 실시예 5의 실험결과 부착되어 있던 스카치테잎이 분무기로 10회를 분사하였을 때 박리되는 것을 알 수 있었다. 이 경우 혼합용액의 농도가 너무 높기 때문에 도포시 작업성이 좋지 않고, 실리콘 혼합수지를 용매에 혼합시 기포가 발생하게 되어 피착제와의 결합력이 좋지 않다는 문제점도 발생하였다.As a result of the experiment of Example 5, it was found that the scotch tape attached was peeled off when sprayed 10 times with an atomizer. In this case, since the concentration of the mixed solution is too high, workability is not good at the time of application, and bubbles are generated when the silicone mixed resin is mixed in the solvent, thereby causing a problem in that the adhesion to the adherend is not good.
상술한 바와 같이 본 발명의 벽보물 부착 방지체의 제조방법은 스티커와 같은 벽보 부착물의 접착제층에 대하여 피착체의 접촉면적을 최소화하여 접착성을 떨어뜨려 벽보물의 제거가 용이하게 이루어짐은 물론 제거작업으로 인한 인력과 시간 및 경비를 절감할 수 있을 뿐만 아니라 어린아이들의 낙서로 부터 시설물을 보호할 수 있다는 효과를 가져오는 것이다.As described above, the method of manufacturing the wall attachment preventing member according to the present invention reduces the adhesiveness by minimizing the contact area of the adherend with respect to the adhesive layer of the wall attachment such as a sticker, thereby making it easy to remove the wall covering, as well as the removing operation. It not only saves manpower, time and money, but also protects the facilities from the graffiti of young children.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20020057835A (en) * | 2002-03-20 | 2002-07-12 | 서기열 | Special Coating Method for Preventing Adherence of Ground Equipment Enclosures |
| KR100615512B1 (en) * | 2005-09-09 | 2006-08-28 | 주식회사 한백 이앤이 | Composition for preventing advertising material from sticking to something and production method of street furniture using thereof |
| KR100619187B1 (en) * | 2005-07-25 | 2006-09-06 | 코스모스티이에스 (주) | Manufacturing method of anti adhesive sheet |
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| KR20010087777A (en) * | 2001-04-19 | 2001-09-26 | 이정헌 | Coating Compositions for proofing adhesion of stickers |
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| JPS6378975A (en) * | 1986-09-22 | 1988-04-09 | 江頭 正 | Paper patch preventing method in building such as utility pole |
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| KR20020057835A (en) * | 2002-03-20 | 2002-07-12 | 서기열 | Special Coating Method for Preventing Adherence of Ground Equipment Enclosures |
| KR100619187B1 (en) * | 2005-07-25 | 2006-09-06 | 코스모스티이에스 (주) | Manufacturing method of anti adhesive sheet |
| KR100615512B1 (en) * | 2005-09-09 | 2006-08-28 | 주식회사 한백 이앤이 | Composition for preventing advertising material from sticking to something and production method of street furniture using thereof |
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