KR100563559B1 - Method manufacturing porcelain jade tile and porcelain tile glaze - Google Patents

Abstract

The present invention relates to a method for producing a ceramic jade tile and a ceramic tile glaze, the present invention relates to 72 to 87% by weight frit, 5 to 10% by weight of kaolin, 7 to 15% by weight of glaze composition forming the surface of the tile In order to finely grind jade with high hardness and specific gravity in the ball mill, which is a wet grinder in the grinding process, in the manufacture of raw glaze of ceramic tiles mainly containing 1% to 3% by weight of super anion, jade and kaolin are added first. Only half of the mixture is pulverized first, and then pulverized until it completely passes through the 325 mesh. Then, the remaining raw materials, such as frit, super anion, and water, are added to prepare glaze, and the surface is formed on a molded or primary fired tile. The present invention provides a functional octale product which is treated and calcined at 1050 to 1200 ° C. When the functional ceramic jade tile according to the present invention is installed on the floor or wall of the room, far infrared rays and negative ions are radiated from the glaze layer, which is the surface of the jade tile, which can greatly enhance the health of the user. It removes various germs and prevents its culture, and purifies various odors and surrounding air to make indoor environment more comfortable and beautiful.

Description

Ceramic jade tile manufacturing method and ceramic tile glaze {METHOD MANUFACTURING PORCELAIN JADE TILE AND PORCELAIN TILE GLAZE}

The present invention relates to a method for producing a ceramic jade tile and a ceramic tile glaze, and more particularly, to prepare a ceramic jade tile glaze containing jade and super anion, and to surface-treat the ceramic jade tile glaze on a building tile By producing functional ceramic jade tile, it utilizes far-infrared radiation, antibacterial and deodorizing effect emitted from jade that is beneficial to human body, and negative ions generated from super anions can improve the environment of polluting and maintain the balance of human health. In order to make the most of the effect, the glaze is manufactured by applying a process of completely wet pulverization of jade having high hardness and specific gravity, and after the surface treatment with the glaze, it is calcined to produce a small amount of high unit price jade. Pottery to provide jade tiles that can be distributed evenly on the tile surface to increase functional effects The present invention relates to a nitric jade tile manufacturing method and a ceramic tile glaze.

In the case of a general ceramic tile, the ceramic glaze composition is composed of 94% by weight of frit and 6% by weight of kaolin in a weight ratio, which are blended and pulverized in a ball mill at the same time, and then fired by surface treatment on a molded dry or primary fired tile.

Patent No. 10-0382777 discloses a method of forming and calcining a composition of an jade tile together with jade, and Utility Model No. 20-0274078 discloses jade stones, jade particles, and jade powder as a binder. Tiles composed mainly of jade formed by mixing are described, and Utility Model No. 20-0184902 describes a decorative and visual jade stone interior tile by processing an jade stone plate.

The prior art emits far-infrared rays after construction, but there is a problem in that it is possible to simultaneously obtain an antibacterial and deodorizing effect that is excellent for environmental purification on the anion and tile surfaces beneficial to the human body.

The present invention has been made to solve the above problems and defects as described above, to prepare a ceramic jade tile glaze containing jade and super anion, and to surface-treated the ceramic jade tile glaze on a building tile functional ceramic By producing nitrous jade tile, it uses far-infrared rays, antibacterial and deodorizing effect emitted from jade, which is beneficial to human body, and negative ions generated from super anion improve the polluted environment and maintain the balance of human health. The purpose is to provide a ceramic jade tile manufacturing method and ceramic tile glaze that can be used to the maximum.

In order to achieve the above object, the present invention provides kaolin for crushing jade with high hardness and specific gravity in order to increase the function of the product in the process of grinding the glaze composition composed of frit, kaolin, jade and super anion. And pulverized in a ball mill to allow uniform passage of all 325 mesh, and then pottery prepared by blending the remaining raw materials with surface-treated with a well-dispersed glaze and firing to increase the beneficial functions to the human body. It provides a method for producing nitric jade tile and ceramic tile glaze.

More specifically, the method for preparing a ceramic jade tile according to the present invention includes a primary raw material mixing step of combining jade, kaolin, and water, a primary wet grinding step of wet grinding the blended raw material, and the pulverized raw material. A secondary raw material blending step of combining frit, super anion, and water, and a secondary wet grinding step of wetly grinding the distributed raw material to prepare a ceramic jade tile glaze, and to form the ceramic jade tile glaze. And a surface treatment step of surface treatment on the dried or primary fired tile, and a firing step of firing at 1050 to 1200 ° C.

The first wet grinding step is pulverized so as to pass all the management standard 325 mesh, and in the second wet grinding step, the control standard 325 mesh is pulverized to 1 to 2% by weight or less.

The ceramic jade tile glaze of the present invention is composed of 72 to 87% by weight of frit, 5 to 10% by weight of kaolin, 7 to 15% by weight of jade, and 1 to 3% by weight of super anion.

When jade is added to the glaze composition, the hardness and specific gravity are high, which makes it harder to grind than ordinary glaze raw materials. Therefore, precipitation occurs during storage or surface treatment of glaze. Therefore, uniform surface treatment is not possible. Therefore, jade must be completely ground to prevent precipitation. Therefore, jade, kaolin, and water must be ground first. The amount of jade is well dispersed to produce a homogeneous functional tile.

However, when the high hardness jade is pulverized like other raw materials for general glaze manufacturing, the alkali component of some of the glaze raw materials is eluted in water, affecting the surface of the product, resulting in oil cracking, pinholes, boiling, It deteriorates the quality due to discoloration.

In this quantitative composition of the ceramic jade tile glaze of this outbreak

If the frit is blended at less than 72% by weight, it is difficult to achieve the specific gravity of the glaze required by the tile quality, resulting in poor quality and low production.When it is more than 87% by weight, it is difficult to wet grind and the unit price increases. If less than it may cause precipitation of the glaze and difficult to control the viscosity, and if it exceeds 10% by weight, the fluidity of the glaze is reduced and the color of the surface is reduced, 7 to 15% by weight of jade, 1 to 3% by weight of super anion . In addition, the jade and the super anion may be added as much as possible, but when added in an excessive amount, there is a factor of an increase in unit cost.

The jade used in the present invention contains calcium and magnesium as components necessary for the human body, and the composition is composed of Mg ₆ (OH) ₈ Si ₄ O ₁₀ . The cells that make up are also made of magnesium, the same wave waves coming out of the jade and human cells are called waves.

In addition, jade removes heat from the body and comforts the body and prevents obesity, and when it is eaten, it is described that the trash is discharged to the outside of the body. It is effective in the digestive system by removing the heat of gastric juice. It is effective for bronchial asthma, fever and stuffy chest. It is good for anemia, quenches thirst, and smoothes the function of the lungs. It is said that it is beneficial for health because it is said to help the vocal cords, good for throat, affect hair, nourish the intestines, and especially reduce neurological diseases such as stress.

Super anions emit 31,000 anions per 1cc, and the effect on the human body is the purification of blood, that is, the anion increases the ionization rate of calcium, sodium, potassium, etc. It cleanses the blood and raises the ionization rate of calcium and sodium in the serum by generating substances such as androphine and enkepyrin, which not only cleanses blood, recovers fatigue, recovers stamina, but also restores the cells in the area of strong pain. It can be activated to relieve pain. It also purifies the blood through the exchange of electrical substances in cell membranes. X-rays, R-rays, ionizing radiation, and ultraviolet rays emitted from various electronics and electrical appliances, including TVs and PCs, have high energy. It causes the formation of cations in the liver, and if the number of cations increases, diseases such as asthma, bronchitis, headache, visual impairment, low back pain, stiff shoulder, nervousness, tension, dysmenorrhea, lethargy, depression, dermatitis, birth defects, etc. May cause

Negative ions, however, are negatively charged air elements that neutralize harmful cations, clear blood, promote nerve stabilization, fatigue recovery, food intake, and cell activation. It has the effect of increasing resistance, autonomic nervous system control, air purification, sterilization.

When the functional ceramic jade tile prepared by the present invention is applied to the floor or wall of the room, far infrared rays and anions are radiated from the glaze layer, which is the surface of the jade tile, to obtain a health promoting effect of the user, and to prevent various bacteria by antibacterial and deodorizing action. It removes and purifies the surrounding air, thereby improving the indoor environment.

Hereinafter, the ceramic jade tile manufacturing method and the ceramic tile glaze according to the present invention will be described in more detail with reference to Examples.

The ceramic jade tile production method according to the present invention comprises a primary raw material mixing step of combining jade, kaolin, water, the first wet grinding step of wet grinding the blended raw materials, and the frit to the pulverized raw material, A secondary raw material blending step of combining super anion and water, and a secondary wet grinding step of wetly grinding the distributed raw material to produce a ceramic jade tile glaze, and the ceramic jade tile glaze is molded or dried. It is intended to produce a functional octaile product, including a surface treatment step of surface treatment on the secondary fired tile and a firing step of firing at 1050 to 1200 ° C.

The wet grinding is performed using a conventional ball mill, and in the first wet grinding step, pulverizes to pass the entire management standard 325 mesh, and in the second wet grinding step, the grinding standard is pulverized to 1 to 2% by weight of the control standard 325 mesh. Manufactures quality jade tile glazes.

Ceramic pottery glaze according to the present invention prepared by the above process is composed of 72 to 87% by weight of frit, 5 to 10% by weight of kaolin, 7 to 15% by weight of jade, 1 to 3% by weight of super anion.

The glaze prepared by the above process is stored in an appropriate place and used as necessary.The ceramic octane glaze is surface-treated on a mold dried or primary fired tile and calcined at 1050-1200 ° C. to produce a functional octale product. Manufacture.

When jade is added to the glaze composition, the hardness and specific gravity are high, which makes it harder to grind than ordinary glaze raw materials. Therefore, precipitation occurs during storage or surface treatment of glaze. Therefore, uniform surface treatment is not possible. Therefore, jade must be completely ground to prevent precipitation. Therefore, jade, kaolin, and water must be ground first. The amount of jade is well dispersed to produce a homogeneous functional tile.

The super anion is manufactured by Environment Korea Co., Ltd. It is preferable to use an anion generating material KN-100 as a compound of Ce, La, Nd, Th and PO ₄ containing monazite, but other products can also be used. .

The components of the jade powder used in the ceramic jade tile glaze are as follows.

Ingredients of jade powder

Exam analysis item Test analysis result Test Analysis Method SiO 42.1 KSL 4007-2001 device analysis (KP-OES) Al ₂ O ₃ 0.94 CaO 0.08 MgO 42.4 K2O 0.48 Na ₂ O 0.38 Fe ₂ O ₃ 0.37 Heat loss 9.7

For reference, the analysis is an analysis result of the Korea Institute of Industrial Technology, KP-OES used in the analysis is OPTIMA 3300DV of PERKIN-ELMER.

When explaining the embodiment of the ceramic jade tile manufacturing method according to the present invention in detail compared with the conventional comparative example as follows.

According to the present invention, the ceramic jade tile glaze according to the present invention is primarily a combination of jade, kaolin, and water, followed by wet milling, followed by wet blending of frits, super anions, and water in the milled raw material by secondary blending. It is manufactured.

The surface treatment method used in the embodiment of the present invention was sprayed oil, the specific gravity of the glaze was 1.70, the weight of the glaze was 40g to 200X250mm tile. In addition, glazes were made for each embodiment, and surface-treated on a completely dried tile or a first calcined tile, and then fired at 1080 ° C. to 1175 ° C. in a continuous roller kiln to produce a product.

In addition, as a result of testing only the glaze composition of the functional octale produced according to the present invention, jade is good to use a lot within 15g, but because the price is expensive, use it at a minimum, and also use super anion within 1g to reduce the cost A visible result was obtained.

The analysis according to the test is the result of the Korea Far Infrared Applied Evaluation Institute of Korea Far Infrared Council.

Example (Invention)

division Component (wt%) Kaolin 5 Fried (OD3780) 83 jade 10 Super anion 2

Test Analysis Result of Example

  Test Analysis Items  Test analysis result  Test Analysis Method Far infrared ray emission amount 5-20 0.931 Instrument Analysis (KF1A-F1-1042) Anion Release ION / cc 620 Charge particle measurement Antimicrobial reduction rate 24 hours later 96.10% by weight Escherichia coli, Pseudomonas aeruginosa test (KF1A-F1-1003) Deodorization Rate 2 hours later 89.20% by weight Ammonia (KF1A-F1-1004)

Comparative example (conventional tile)

division Component (wt%) Kaolin 6 Fried (OD3780) 94 jade Super anion

Test Analysis Result of Comparative Example

  Test Analysis Items  Test analysis result  Test Analysis Method Far infrared ray emission amount 5-20 0.898 Instrument Analysis (KF1A-F1-1042) Anion Release ION / cc 157 Charge particle measurement Antimicrobial reduction rate 24 hours later 36% by weight Escherichia coli, Pseudomonas aeruginosa test (KF1A-F1-1003) Deodorization Rate 2 hours later 25% by weight Ammonia (KF1A-F1-1004)

As a result of the comparison of the above analysis, it was confirmed that the tile according to the present invention improves the effect of far-infrared rays, anions, antibacterial and deodorizing functions than the conventional tiles.

Functional magnetic jade tile according to the present invention as described above can be far-infrared and negative ions are radiated from the glaze layer that is the surface of the jade tile when installed on the floor or wall of the room can have a great effect on the health of the user, antibacterial, The deodorizing action removes various germs and prevents their culture, and cleans up various odors and the air around them to make the indoor environment more comfortable and beautiful.                     

Functional ceramic jade tile according to the present invention as described above can be far-infrared and negative ions are radiated from the glaze layer that is the surface of the jade tile when installed on the floor or wall of the room can have a great effect on the health of the user, antibacterial By deodorizing action, it removes various germs and prevents its cultivation, and also cleans various odors and the surrounding air and has the advantage and effect to make indoor environment more comfortable and beautiful living environment.

Claims (4)

A primary raw material blending step of combining jade, kaolin, and water, a primary wet grinding step of wet grinding the blended raw materials, and a secondary raw material blending of frit, super anion, and water to the ground raw materials. And a second wet grinding step of wetly grinding the distributed raw material to prepare a ceramic jade tile glaze, and surface treatment step of surface-treating the ceramic jade tile glaze on a molded dried or primary fired tile. And a firing step of firing at 1050 to 1200 ° C. to produce a functional octale product. The method of claim 1, wherein in the first wet milling step, pulverization is passed through the entire control standard 325 mesh, and in the second wet milling step, the grinding standard is controlled so that the residual amount of the control standard 325 mesh 1 to 2% by weight or less. Ceramic jade tile manufacturing method characterized in that the manufacturing. The ceramic pottery glaze of claim 1, wherein the ceramic jade tile glaze is composed of 72 to 87 wt% of frit, 5 to 10 wt% of kaolin, 7 to 15 wt% of jade, and 1 to 3 wt% of super anion. Nitric jade tile manufacturing method. A ceramic jade tile which is manufactured by the ceramic jade tile manufacturing method according to any one of claims 1 to 3, wherein the ceramic jade tile glaze is coated on a surface thereof.