KR102012181B1 - Interior materials containing organic germamium - Google Patents
Interior materials containing organic germamium Download PDFInfo
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- KR102012181B1 KR102012181B1 KR1020190038718A KR20190038718A KR102012181B1 KR 102012181 B1 KR102012181 B1 KR 102012181B1 KR 1020190038718 A KR1020190038718 A KR 1020190038718A KR 20190038718 A KR20190038718 A KR 20190038718A KR 102012181 B1 KR102012181 B1 KR 102012181B1
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- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/40—Compounds containing silicon, titanium or zirconium or other organo-metallic compounds; Organo-clays; Organo-inorganic complexes
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- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
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- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
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- C04B14/30—Oxides other than silica
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- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/34—Metals, e.g. ferro-silicon
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- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/36—Inorganic materials not provided for in groups C04B14/022 and C04B14/04 - C04B14/34
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- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
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- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/26—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/44—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the purpose
- E04C2/52—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the purpose with special adaptations for auxiliary purposes, e.g. serving for locating conduits
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- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
- C04B2103/0097—Anion- and far-infrared-emitting materials
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- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/54—Pigments; Dyes
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- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
- C04B2111/00258—Electromagnetic wave absorbing or shielding materials
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/90—Electrical properties
- C04B2111/94—Electrically conducting materials
Abstract
Description
본 발명은 유기게르마늄이 포함된 건축내장재에 관한 것으로, 보다 상세하게는 석고분말; 유기게르마늄; 황토, 옥돌, 은, 흑운모, 알루미나, 맥반석, 라듐석 및 토르말린 중 선택된 어느 하나 이상의 성분; 전도성 첨가제; 자기파 차폐제; 및 유기게르마늄수를 포함하는 건축내장재에 관한 것이다.The present invention relates to a building interior materials containing organic germanium, more specifically gypsum powder; Organogermanium; One or more components selected from ocher, jade, silver, biotite, alumina, elvan, radiumite and tourmaline; Conductive additives; Magnetic wave shielding agents; And it relates to a building interior materials containing organic germanium water.
일반적으로 건축내장재로는 시멘트 및 석고분에 장력재료인 석면을 혼합하여서 된 석고보드가 주로 사용되어져 왔다.In general, gypsum board made by mixing asbestos, a tension material, with cement and gypsum powder has been mainly used as a building interior material.
상기한 석고보드는 설치에 따른 취급 시 석고분말이 손에 묻거나 가루상태로 비산되어 작업자는 물론 석고보드를 내장재로 쓴 건물에서 생활하는 사람의 호흡기를 통해 폐 등의 장기로 흡입되어져 기관지염 등을 유발시키게 되고, 발암물질인 석면이 시간의 경과로 산화되면서 공기 중으로 비산되어 폐암 등 각종 암을 유발시키게 되는 문제점을 가지고 있다. 또한 철거로 인한 폐기처분 시 수질 및 토양을 오염시키게 되는 단점을 가지고 있다.When the gypsum board is handled according to the installation, the gypsum powder is scattered in the hands or in the form of powder, and it is sucked into the organs such as the lungs through the respiratory organs of the person living in the building where the gypsum board is used as the interior material. Asbestos, which is a carcinogen, is oxidized over time and scattered into the air, causing various cancers such as lung cancer. It also has the disadvantage of polluting the water quality and soil during disposal due to demolition.
상기한 석고보드의 단점을 해결하기 위하여 다양한 형태의 건축내장재가 개발되어 왔다.In order to solve the above-mentioned disadvantages of the gypsum board, various types of building interior materials have been developed.
대표적인 건축내장재로는 황토, 옥돌, 은 등을 이용한 건축내장재를 예로 들을 수 있다. 이중 황토를 원료로 한 건축내장재는 미네랄이 풍부하고 황토에서 발산되는 원적외선에 의한 성인병 예방 및 건강을 증진시킬 수 있는 장점을 가지고 있다. 그러나 점력 유지에 어려움이 있어 제조공정이 까다로울 뿐만 아니라 제품의 다량 생산에 어려움이 있고, 생산 및 수요의 불균형에 따라 가격이 상승되는 단점을 가지고 있다. 또한, 내구성을 높이기 위한 수단으로 건축내장재에서 황토가 차지하는 비중이 커짐은 물론 두께가 필요 이상으로 두꺼워져 중량이 많이 나가는 단점이 있으며, 디자인이 미려하지 못하다는 단점이 있다.Representative architectural interior materials can be cited as the building interior materials using ocher, jade, silver, and the like. The built-in building materials made of ocher are rich in minerals and have the advantage of preventing the disease and promoting health caused by far infrared rays emitted from the ocher. However, it is difficult to maintain the strength of the manufacturing process is not only difficult, but also difficult to produce a large amount of product, and has the disadvantage that the price is increased due to the imbalance of production and demand. In addition, as a means for increasing durability, the occupancy of the clay in building interior materials increases, as well as the thickness is thicker than necessary, there is a disadvantage that a lot of weight, and the design is not beautiful.
상기와 같은 종래기술의 문제점을 해결하고자, 본 발명은 유기게르마늄을 포함하여 원적외선 및 음이온을 방출하고, 유해 전자파를 차폐하여 인체에 무해하며, 탈취, 항균, 제습 및 곰팡이번식억제 효과가 탁월한 유기게르마늄을 포함하는 건축내장재를 제공하는 것을 목적으로 한다.In order to solve the problems of the prior art as described above, the present invention, including organic germanium, emits far infrared rays and negative ions, harmless to human body by shielding harmful electromagnetic waves, organic germanium excellent in deodorization, antibacterial, dehumidification and mold propagation inhibitory effect To provide a building interior material comprising a.
또한 본 발명은 강력한 항균력과 접착력으로 인해 곰팡이나 변색이 없으며, 난연성, 단열성 및 방음성이 우수하여 주거환경을 월등히 개선할 수 있어 건축내장재로서의 상품성이 우수한 유기게르마늄을 포함하는 건축내장재를 제공하는 것을 목적으로 한다. In addition, the present invention has no mold or discoloration due to the strong antimicrobial and adhesive force, and excellent flame retardancy, heat insulation and soundproofing to improve the living environment to provide a building interior material containing an organic germanium excellent commercial property as building interior materials It is done.
상기 목적을 달성하기 위하여, 본 발명은 석고분말 100중량부에 대하여 유기게르마늄 10~30중량부, 황토, 옥돌, 은, 흑운모, 장석, 알루미나, 맥반석, 라듐석 및 토르말린 중 선택된 어느 하나 이상의 성분 10~50중량부, 니켈, 구리, CNT(carbon nanotube) 및 그라핀 중 선택된 어느 하나 이상의 전도성 첨가제 10~20중량부, 페라이트(ferrite), Ni-Zn 페라이트, FeSiCr계 및 FeSiAl계 중 선택되는 어느 하나 이상의 자기파 차폐제 1~20중량부, 및 유기게르마늄수 50~80중량부를 포함하는 유기게르마늄을 포함하는 건축내장재를 제공한다.In order to achieve the above object, the present invention is 10 to 30 parts by weight of organic germanium, ocher, octane, silver, biotite, feldspar, alumina, ganban stone, radiumite and tourmaline with respect to 100 parts by weight of
본 발명의 건축내장재는 유기게르마늄을 포함하여 원적외선 및 음이온 방출 효과가 뛰어나고, 유해 전자파를 차폐하여 인체에 무해하며, 탈취, 항균, 제습 및 곰팡이번식억제 효과가 탁월하다. 또한 강력한 항균력과 접착력으로 인해 곰팡이나 변색이 없으며, 난연성, 단열성 및 방음성이 우수하여 주거환경을 월등히 개선할 수 있어 건축내장재로서의 상품성이 우수하다. Building interior materials of the present invention, including organic germanium is excellent in the far infrared and anion emission effect, harmless to the human body by shielding harmful electromagnetic waves, excellent deodorization, antibacterial, dehumidification and mold propagation inhibitory effect. In addition, there is no mold or discoloration due to strong antibacterial activity and adhesiveness, and it is excellent in flame retardancy, heat insulation and sound insulation, and can improve the residential environment.
도 1은 본 발명의 일실시예에 따라 제조한 유기게르마늄 분말의 원적외선 방사능 측정결과를 나타낸 그래프이다.1 is a graph showing the far-infrared radiation measurement results of the organic germanium powder prepared according to an embodiment of the present invention.
이하 본 발명을 상세히 설명한다. Hereinafter, the present invention will be described in detail.
본 발명의 건축내장재는 석고분말에 유기게르마늄과 황토, 옥돌, 은, 흑운모, 장석, 알루미나, 맥반석, 라듐석 및 토르말린 중 선택된 어느 하나 이상의 성분, 전도성 첨가제, 자기파 차폐제 및 유기게르마늄수를 포함한다.The building interior materials of the present invention include organic germanium, ocher, jade, silver, biotite, feldspar, alumina, ganban stone, radiumite and tourmaline in gypsum powder, conductive additives, magnetic wave shielding agents and organic germanium water. .
상기 석고분말은 건축용 자재로 널리 사용되는 통상의 석고분말로서 물을 이용해 경화되어 매우 높은 강도를 나타낸다.The gypsum powder is a conventional gypsum powder widely used as a building material and is cured using water to exhibit very high strength.
일반적으로 게르마늄은 인체와 유사한 반도체성 원소로서, 일본의 아사이 박사는 게르마늄이 우리 몸에 산소를 놀랍도록 풍부하게 해주는 기적의 원소이자 감마 인터페론(암, 바이러스 등의 병원체 증식억제)을 생성케 하는 경이적인 물질임을 밝혀냈다.In general, germanium is a semiconducting element similar to the human body, and Dr. Asai of Japan is a phenomenal element that makes germanium a surprisingly rich source of oxygen and a wonder that causes gamma interferon (inhibiting the growth of pathogens such as cancer and viruses). It turned out to be a substance.
특히, 본 발명에서는 게르마늄과 세레늄, 세륨, 마그네슘, 칼륨 등 인체에 유익한 성분이 포함되어 있는 지하수로부터 추출해 낸 유기게르마늄을 건축내장재에 사용함으로써 기존 게르마늄들과 대비하여 원적외선 및 음이온 방출 효과를 극대화하고, 독소제거, 면역, 항균효과 등을 더욱 높이고자 하였다. Particularly, in the present invention, by using organic germanium extracted from groundwater containing components beneficial to the human body such as germanium, selenium, cerium, magnesium, potassium, and the like in building interior materials, the effect of releasing far infrared rays and anions is maximized in comparison with conventional germaniums, Toxin removal, immunity, and antimicrobial effect was further enhanced.
구체적으로, 상기 유기게르마늄은 게르마늄이 함유된 지하수를 500~1,000℃에서 5~7시간 가열한 다음 2~3회 건조기를 통해 수분을 증발시켜 게르마늄 분말을 추출하고, 상기 추출된 게르마늄 분말을 1~3시간 정도 살균기에서 살균처리하여 최종 유기게르마늄 분말을 제조할 수 있다. Specifically, the organic germanium is heated for 5 to 7 hours at 500 ~ 1,000 ℃ groundwater containing germanium and then evaporated the water through a dryer 2-3 times to extract the germanium powder, the extracted
상기 유기게르마늄은 석고분말 100중량부에 대하여 10~30중량부로 포함되는 것이 바람직하며, 그 함량이 상기 범위를 벗어날 경우에는 본 발명자가 목적하는 만큼의 원적외선 및 음이온 방출 효과를 얻을 수 없게 된다.The organic germanium is preferably contained in 10 to 30 parts by weight with respect to 100 parts by weight of gypsum powder, when the content is out of the above range it is not possible to obtain the far-infrared and anion emission effect as the inventors intended.
또한 상기 황토, 옥돌, 은, 흑운모, 장석, 알루미나, 맥반석, 라듐석 및 토르말린 중 선택된 어느 하나 이상의 성분은 유기게르마늄과 함께 사용되어 원적외선 및 음이온의 방출에 시너지 효과를 낼 수 있게 된다. 뿐만 아니라, 상기 성분들은 항균, 제습, 탈취, 방열, 곰팡이 번식 억제 효과를 가져 건축내장재의 상품성을 향상시킬 수 있다. In addition, any one or more components selected from ocher, jade, silver, biotite, feldspar, alumina, elvan, radiumite and tourmaline may be used together with organic germanium to produce a synergistic effect on the emission of far infrared rays and anions. In addition, the components have an antibacterial, dehumidification, deodorization, heat dissipation, mold growth inhibitory effect can improve the commerciality of the building interior materials.
특히, 상기 성분들 중 맥반석, 황토 등은 열을 가하면 원적외선을 다량 방사하여 건축내장재로 사용할 때 난방 시 효과적으로 원적외선을 방출할 수 있으며, 라듐석은 열과 관계없이 자연적으로 미량의 방사능을 발생시키고, 은, 흑운모, 장석, 토르말린은 음이온을 발생시키므로 본 발명의 건축내장재는 다양한 조건에서 원적외선 뿐 아니라 음이온과 방사능을 발생시켜 인체에 유익한 효과를 낼 수 있다. In particular, among the above components, elvan, loess and the like can radiate a large amount of far-infrared radiation when heated, and can effectively emit far-infrared radiation when used as a building interior material, radiumite naturally generates a small amount of radioactivity regardless of heat, silver, Biotite, feldspar, tourmaline generates anion, so the building interior material of the present invention can produce a beneficial effect on the human body by generating anion and radioactivity as well as far infrared under various conditions.
상기 황토, 옥돌, 은, 흑운모, 장석, 알루미나, 맥반석, 라듐석, 토르말린 등은 1 종 이상 선택하여 본 발명의 건축내장재에 포함될 수 있으나, 바람직하게는 상기 성분들 중 맥반석, 황토/라듐석/은, 흑운모, 장석, 토르말린의 세 그룹에서 1종 이상씩을 포함하는 것이 더욱 좋다.The ocher, jade, silver, biotite, feldspar, alumina, elvan, radiumite, tourmaline, etc. may be included in the building interior materials of the present invention by selecting one or more, preferably, among the above components, elvan, ocher / radium / It is better to include at least one of three groups of silver, biotite, feldspar, and tourmaline.
상기 성분들은 석고분말 100중량부에 대하여 10~50중량부로 포함되는 것이 바람직하며, 그 함량이 상기 범위를 벗어날 경우에는 원적외선 및 음이온 방출의 시너지 효과가 미비하게 되며, 본 발명이 목적하는 건축내장재로서의 효과를 얻기 어려울 수 있다.The components are preferably contained in 10 to 50 parts by weight based on 100 parts by weight of gypsum powder, when the content is out of the above range, the synergistic effect of far-infrared and anion emission is insignificant, and as the building interior material It can be difficult to get the effect.
상기 전도성 첨가제로는 니켈, 구리, CNT(carbon nanotube), 그라핀 등이 사용될 수 있으며, 250메쉬 이하 크기의 구형 또는 랜덤 형상의 분말을 사용할 수 있다. 상기 전도성 첨가제는 석고분말 100중량부에 대하여 10~20중량부로 포함되는 것이 바람직하다.Nickel, copper, carbon nanotube (CNT), graphene, or the like may be used as the conductive additive, and spherical or random shaped powder having a size of 250 mesh or less may be used. The conductive additive is preferably included in 10 to 20 parts by weight based on 100 parts by weight of gypsum powder.
상기 자기파 차폐제로는 페라이트(ferrite), Ni-Zn 페라이트, FeSiCr계, FeSiAl계 등이 사용될 수 있으며, 석고분말 100중량부에 대하여 1~20중량부로 포함되는 것이 바람직하다.Ferrite (ferrite), Ni-Zn ferrite, FeSiCr-based, FeSiAl-based and the like may be used as the magnetic wave shielding agent, it is preferably included in 1 to 20 parts by weight based on 100 parts by weight of gypsum powder.
상기 유기게르마늄수는 전술한 바와 같이 추출된 유기게르마늄 분말과 정제수를 혼합한 것으로, 정제수 대비 1~25중량% 정도의 유기게르마늄 분말을 균일하게 혼합하여 사용할 수 있다.The organic germanium water is a mixture of the organic germanium powder and purified water extracted as described above, can be used by uniformly mixing the organic germanium powder of about 1 to 25% by weight compared to the purified water.
상기와 같은 성분으로 이루어지는 본 발명의 건축내장재는 천연석과 같은 느낌을 주면서 빛에 의해 다채로운 색상을 발현토록 하기 위하여 발광입자를 추가로 포함할 수도 있다.The building interior material of the present invention composed of the above components may further include light emitting particles in order to express a variety of colors by light while giving a feeling like natural stone.
상기 발광입자로는 블랙나이트 무기안료를 사용할 수 있으며, 예를 들어 Y203+S+Eu, ZnS+Au, ZnS+Au+Cu+Al2O3 등의 블랙나이트 무기안료를 사용할 수 있다. 특히, 자외선을 받으면 Y203+S+Eu 원료는 적색을 발하고, ZnS+Au 원료는 청색을 발하며, ZnS+Au+Cu+Al2O3 원료는 녹색을 발하는 안료로, 목적하는 바에 따라 그 사용이나 혼합비를 적절히 조절할 수 있음은 물론이다.As the light emitting particles, black knight inorganic pigments may be used. For example, black knight inorganic pigments such as Y 2 0 3 + S + Eu, ZnS + Au, ZnS + Au + Cu + Al 2 O 3 may be used. . In particular, Y 2 0 3 + S + Eu raw material emits red color, ZnS + Au raw material emits blue color, and ZnS + Au + Cu + Al 2 O 3 raw material emits green color. Of course, the use and the mixing ratio can be properly adjusted.
또한 본 발명의 건축내장재는 당업계에서 사용되는 통상의 수성도료나 향료 등을 추가하여 다양한 색상을 발현하거나, 향기를 내도록 할 수도 있음은 물론이다.In addition, the building interior material of the present invention may be added to the usual water-based paints or flavors used in the art to express a variety of colors, or to give a fragrance of course.
이하에서는 실시예를 들어 본 발명에 관하여 더욱 상세하게 설명할 것이나. 이들 실시예는 단지 설명의 목적을 위한 것으로 본 발명의 보호 범위를 제한하고자 하는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to Examples. These examples are for illustrative purposes only and are not intended to limit the protection scope of the present invention.
제조예 1. 유기게르마늄 분말 추출Preparation Example 1 Extraction of Organic Germanium Powder
불소 1.5㎎/ℓ, 아연 1.6㎎/ℓ, 망간 13.4㎎/ℓ, 황산이온1,320㎎/ℓ, 게르마늄1,000㎎/ℓ, 셀레늄 0.042㎎/ℓ을 함유하는 지하수를 700℃에서 6시간 동안 가열하였다. 이어서 2~3회 건조기를 통해 수붐함량 1중량% 이하로 건조시켜 게르마늄 분말을 추출하였다. 그 다음 상기 게르마늄 분말을 2시간 동안 살균기에서 살균시켜 최종 유기게르마늄 분말 3㎎/ℓ을 수득하였다. Groundwater containing 1.5 mg / l fluorine, 1.6 mg / l zinc, 13.4 mg / l manganese, 1,320 mg / l sulfate, 1,000 mg / l germanium, and 0.042 mg / l selenium was heated at 700 ° C. for 6 hours. Then, the germanium powder was extracted by drying to a water boom content of 1 wt% or less through a dryer 2-3 times. The germanium powder was then sterilized for 2 hours in a sterilizer to obtain 3 mg / l of the final organic germanium powder.
상기 수득한 유기게르마늄 분말의 원적외선 방사율을 측정하여 도 1 및 하기 표 1에 나타내었다. 원적외선 방사율은 KFIA-FI-1005법에 의거하여 FT-IR Spectrophotometer를 이용하여 BLACK BODY 대비 방사율과 방사에너지로 측정하였다. Far-infrared emissivity of the obtained organic germanium powder was measured and shown in FIG. 1 and Table 1 below. Far-infrared emissivity was measured by FT-IR Spectrophotometer with emissivity and radiant energy compared to BLACK BODY based on KFIA-FI-1005 method.
도 1 및 상기 표 1에 나타낸 바와 같이, 본 발명에 따라 제조한 유기게르마늄 분말은 원적외선 방사율 0.923㎛, 방사에너지가 3.526ㅧ102W/㎡ㅇ㎛(37℃)로 원적외선 방사효과가 우수함을 알 수 있었다.As shown in FIG. 1 and Table 1, the organic germanium powder prepared according to the present invention has a far-infrared emissivity of 0.923 μm and a radiant energy of 3.526 × 10 2 W / m 2 μm (37 ° C.). Could.
제조예 2. 유기게르마늄수 제조Preparation Example 2 Preparation of Organic Germanium Water
상기 제조예 1에서 제조한 유기게르마늄 분말을 정제수 대비 10중량%로 첨가하고 균일하게 혼합하여 유기게르마늄수를 제조하였다.The organic germanium powder prepared in Preparation Example 1 was added in an amount of 10 wt% based on the purified water and uniformly mixed to prepare an organic germanium water.
실시예 1. 유기게르마늄 포함 건축내장재 제조Example 1 Preparation of Building Interior Materials Including Organic Germanium
석고분말 100중량부에 상기 제조예 1에서 제조한 유기게르마늄 분말 20중량부, 황토 8중량부, 라듐석 5중량부 및 토르말린 7중량부, 230메쉬의 구형의 니켈 분말 10중량부, 페라이트 5중량부, 및 유기게르마늄수 70중량부를 혼합하였다. 상기 혼합물을 몰드에 투입한 후 완전건조시켜 유기게르마늄 포함 건축내장재를 제조하였다. 20 parts by weight of the organic germanium powder prepared in Preparation Example 1, 100 parts by weight of gypsum powder, 8 parts by weight of ocher, 5 parts by weight of radiumite and 7 parts by weight of tourmaline, 10 parts by weight of spherical nickel powder of 230 mesh and 5 parts of ferrite. Parts and 70 parts by weight of organic germanium water were mixed. The mixture was put in a mold and then completely dried to prepare an organic germanium-containing building interior material.
실시예 2. 유기게르마늄 포함 건축내장재 제조Example 2. Fabrication of Building Interior Materials Containing Organic Germanium
석고분말 100중량부에 상기 제조예 1에서 제조한 유기게르마늄 분말 30중량부, 맥반석 5중량부, 라듐석 10중량부 및 흑운모 8중량부, 230메쉬의 구형의 니켈 분말 10중량부, 페라이트 5중량부, 및 유기게르마늄수 80중량부를 혼합한 것을 제외하고는 상기 실시예 1과 동일하게 실시하였다. 30 parts by weight of gypsum powder, 30 parts by weight of the organic germanium powder prepared in Preparation Example 1, 5 parts by weight of ganbanite, 10 parts by weight of radiumite and 8 parts by weight of biotite, 10 parts by weight of spherical nickel powder of 230 mesh, and 5 parts of ferrite. The same procedure as in Example 1 was carried out except that 80 parts by weight of parts and 80 parts by weight of organic germanium were mixed.
실시예 3. 유기게르마늄 포함 건축내장재 제조Example 3 Fabrication of Architectural Interior Materials Containing Organic Germanium
석고분말 100중량부에 상기 제조예 1에서 제조한 유기게르마늄 분말 25중량부, 맥반석 4중량부와 황토 5중량부, 라듐석 7중량부 및 은 6중량부와 토르말린 5중량부, 210메쉬의 랜덤형상의 구리 분말 10중량부, Ni-Zn 페라이트 8중량부, 및 유기게르마늄수 80중량부를 혼합한 것을 제외하고는 상기 실시예 1과 동일하게 실시하였다. 25 parts by weight of the organic germanium powder prepared in Preparation Example 1, 100 parts by weight of gypsum powder, 4 parts by weight of ganbanite and 5 parts by weight of ocher, 7 parts by weight of radiumite, 6 parts by weight of silver and 5 parts by weight of tourmaline, and a random of 210 mesh The same procedure as in Example 1 was carried out except that 10 parts by weight of the copper powder having a shape, 8 parts by weight of Ni-Zn ferrite, and 80 parts by weight of organic germanium were mixed.
실시예 4. 유기게르마늄 포함 건축내장재 제조Example 4 Fabrication of Architectural Interior Materials Containing Organic Germanium
석고분말 100중량부에 상기 제조예 1에서 제조한 유기게르마늄 분말 20중량부, 황토 8중량부, 라듐석 5중량부 및 토르말린 7중량부, 230메쉬의 구형의 니켈 분말 10중량부, 페라이트 5중량부, 블랙나이트 무기안료로 ZnS+Au 5중량부 및 유기게르마늄수 70중량부를 혼합한 것을 제외하고는 상기 실시예 1과 동일하게 실시하였다. 20 parts by weight of the organic germanium powder prepared in Preparation Example 1, 100 parts by weight of gypsum powder, 8 parts by weight of ocher, 5 parts by weight of radiumite and 7 parts by weight of tourmaline, 10 parts by weight of spherical nickel powder of 230 mesh and 5 parts of ferrite. In the same manner as in Example 1, except that 5 parts by weight of ZnS + Au and 70 parts by weight of organic germanium were mixed with the black knight inorganic pigment.
실시예 5. 유기게르마늄 포함 건축내장재 제조Example 5 Fabrication of Architectural Interior Materials Containing Organic Germanium
석고분말 100중량부에 상기 제조예 1에서 제조한 유기게르마늄 분말 20중량부, 황토 8중량부, 라듐석 5중량부 및 토르말린 7중량부, 230메쉬의 구형의 니켈 분말 10중량부, 페라이트 5중량부, 블랙나이트 무기안료로 ZnS+Au 5중량부, 수성도료 3중량부, 향료 3중량부 및 유기게르마늄수 75중량부를 혼합한 것을 제외하고는 상기 실시예 1과 동일하게 실시하였다. 20 parts by weight of the organic germanium powder prepared in Preparation Example 1, 100 parts by weight of gypsum powder, 8 parts by weight of ocher, 5 parts by weight of radiumite and 7 parts by weight of tourmaline, 10 parts by weight of spherical nickel powder of 230 mesh and 5 parts of ferrite. In the same manner as in Example 1, except that 5 parts by weight of ZnS + Au, 3 parts by weight of aqueous paint, 3 parts by weight of fragrance, and 75 parts by weight of organic germanium were mixed as an inorganic pigment.
상기 실시예 1에서 제조한 건축내장재를 이용하여 방사선량을 측정하고, 그 결과를 하기 표 2에 나타내었다. 방사선량은 KFIA-FI-1108법에 의거하여 방사선량 측정장치를 이용하여 실내온도 22℃, 습도 45%의 조건에서 시험하였으며, 측정대상물에서 방사되는 방사선량을 측정하여 시간당 방사선의 선량으로 표시하였다.The radiation dose was measured using the building interior materials prepared in Example 1, and the results are shown in Table 2 below. The radiation dose was tested under the condition of room temperature 22 ℃ and humidity 45% by using the radiation dose measuring device according to KFIA-FI-1108 method, and the radiation dose emitted from the measured object was measured and expressed as the dose of radiation per hour. .
상기 표 2에 나타낸 바와 같이, 본 발명에 따란 유기게르마늄 포함 건축내장재는 실내온도 22℃, 습도 45%의 조건에서 방사선량이 시간당 0.01μSv으로 원적외선 방사율이 우수함을 확인할 수 있었다. As shown in Table 2, it can be confirmed that the organic interior structure containing organic germanium according to the present invention has excellent far-infrared emissivity at 0.01 μSv per hour at room temperature of 22 ° C. and humidity of 45%.
특히, 본 발명의 건축내장재는 유기게르마늄 분말과 함께 황토, 옥돌, 은, 흑운모, 장석, 알루미나, 맥반석, 라듐석 및 토르말린 중 선택된 1종 이상의 성분을 함께 사용함으로서 유기게르마늄 분말을 단독으로 사용할 때와 대비하여 현저히 향상된 원적외선 및 음이온 방사 효과를 볼 수 있다. In particular, the building interior materials of the present invention by using an organic germanium powder alone by using at least one selected from the group consisting of ocher, jade, silver, biotite, feldspar, alumina, ganban stone, radiumite and tourmaline together with the organic germanium powder In contrast, the effect of far-infrared and anion radiation can be significantly improved.
상기와 같이 원적외선 방사율이 우수한 유기게르마늄 분말을 포함하는 본 발명의 건축내장재는 원적외선 및 음이온 방출 효과가 뛰어나고, 유해 전자파를 차폐하여 인체에 무해하며, 탈취, 항균, 제습 및 곰팡이번식억제 효과가 탁월하여 주거환경을 월등히 개선할 수 있으며, 건축내장재로서의 상품성이 우수할 것임을 예측할 수 있었다.Building interior materials of the present invention comprising an organic germanium powder having excellent far-infrared emissivity as described above is excellent in far-infrared and anion emission effect, harmless to the human body by shielding harmful electromagnetic waves, excellent deodorization, antibacterial, dehumidification and mold propagation inhibitory effect The residential environment could be greatly improved, and the merchandise as building interior materials would be excellent.
비록 본 발명이 상기에 언급된 바람직한 실시예로서 설명되었으나, 발명의 요지와 범위로부터 벗어남이 없이 다양한 수정이나 변형을 하는 것이 가능하다. 또한 첨부된 청구 범위는 본 발명의 요지에 속하는 이러한 수정이나 변형을 포함한다.Although the present invention has been described as the preferred embodiment mentioned above, it is possible to make various modifications or variations without departing from the spirit and scope of the invention. The appended claims also cover such modifications and variations as fall within the spirit of the invention.
Claims (3)
유기게르마늄 10~30중량부,
황토, 옥돌, 은, 흑운모, 장석, 알루미나, 맥반석, 라듐석 및 토르말린 중 선택된 어느 하나 이상의 성분 10~50중량부,
CNT(carbon nanotube) 및 그라핀 중 선택된 어느 하나 이상의 전도성 첨가제 10~20중량부,
페라이트(ferrite), Ni-Zn 페라이트, FeSiCr계 및 FeSiAl계 중 선택되는 어느 하나 이상의 자기파 차폐제 1~20중량부, 및
유기게르마늄수 50~80중량부를 포함하며;
상기 유기게르마늄은 게르마늄이 함유된 지하수를 500~1,000℃에서 5~7시간 가열한 후 수분을 증발시키는 단계, 및 상기 가열 및 증발을 거쳐 추출한 게르마늄 분말을 살균처리하는 단계로 제조되고;
발광입자로 Y203+S+Eu, ZnS+Au 및 ZnS+Au+Cu+Al2O3 중 선택된 어느 하나 이상의 블랙나이트 무기안료 1~10중량부를 추가로 포함하고;
상기 전도성 첨가제로는 250메쉬 이하 크기의 구형으로 형성되고, 상기 전도성 첨가제는 석고분말 100중량부에 대하여 10~20중량부로 포함 조성되며;
상기 자기파 차폐제로는 석고분말 100중량부에 대하여 1~20중량부로 포함조성되고;
상기 유기게르마늄수는 유기게르마늄 분말과 정제수를 혼합조성하되, 정제수 대비 1~25중량% 정도의 유기게르마늄 분말을 균일하게 혼합 조성하며;
천연석과 같은 느낌을 주면서 빛에 의해 다채로운 색상을 발현토록 하기 위하여 발광입자를 포함하고;
건축내장재는 향기를 내도록 향료를 포함한 것을 특징으로 하는 유기게르마늄이 포함된 건축내장재.
About 100 parts by weight of gypsum powder
10-30 parts by weight of organic germanium,
10-50 parts by weight of any one or more components selected from ocher, jade, silver, biotite, feldspar, alumina, elvan, radiumite and tourmaline,
10 to 20 parts by weight of any one or more conductive additives selected from carbon nanotubes (CNT) and graphene,
1 to 20 parts by weight of at least one magnetic wave shielding agent selected from ferrite, Ni-Zn ferrite, FeSiCr and FeSiAl, and
50-80 parts by weight of organic germanium water;
The organic germanium is prepared by heating groundwater containing germanium at 500 to 1,000 ° C. for 5 to 7 hours and then evaporating water, and sterilizing the germanium powder extracted through the heating and evaporation;
It further comprises 1 to 10 parts by weight of any one or more black knight inorganic pigments selected from Y 2 0 3 + S + Eu, ZnS + Au and ZnS + Au + Cu + Al 2 O 3 as light emitting particles;
The conductive additive is formed into a sphere having a size of 250 mesh or less, the conductive additive is composed of 10 to 20 parts by weight based on 100 parts by weight of gypsum powder;
The magnetic wave shielding agent is included in an amount of 1 to 20 parts by weight based on 100 parts by weight of gypsum powder;
The organic germanium water is mixed with the organic germanium powder and purified water, but uniformly mixes about 1 to 25% by weight of the organic germanium powder compared to the purified water;
It includes light-emitting particles to express a colorful color by light while giving a feeling like natural stone;
Architectural interior materials include organic germanium, characterized in that it contains a fragrance to give a fragrance.
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| CN110818374A (en) * | 2019-11-19 | 2020-02-21 | 湖北工业大学 | Graphene gypsum-based electromagnetic shielding composite material doped with wet-milled steel slag and preparation method thereof |
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