KR100549885B1 - 폴리에틸렌의 제조 방법 - Google Patents

폴리에틸렌의 제조 방법 Download PDF

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Publication number
KR100549885B1
KR100549885B1 KR1020017004463A KR20017004463A KR100549885B1 KR 100549885 B1 KR100549885 B1 KR 100549885B1 KR 1020017004463 A KR1020017004463 A KR 1020017004463A KR 20017004463 A KR20017004463 A KR 20017004463A KR 100549885 B1 KR100549885 B1 KR 100549885B1
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South Korea
Prior art keywords
ziegler
catalyst
ethylene
molar ratio
transition metal
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Expired - Lifetime
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KR1020017004463A
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English (en)
Korean (ko)
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KR20010106509A (ko
Inventor
포드랜달레이
에임즈윌리엄앨버트
둘리케네쓰앨런
반더빌트제프리제임스
원더스앨런조지
Original Assignee
이스트만 케미칼 캄파니
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/602—Component covered by group C08F4/60 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/607—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/609—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6093—Catalysts containing a specific non-metal or metal-free compound organic containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/607—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/609—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6094—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/61—Pretreating the metal or compound covered by group C08F4/60 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/612—Pretreating with metals or metal-containing compounds
    • C08F4/614—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6143—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Emergency Medicine (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Graft Or Block Polymers (AREA)
KR1020017004463A 1999-03-03 1999-03-03 폴리에틸렌의 제조 방법 Expired - Lifetime KR100549885B1 (ko)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1999/004765 WO2000052066A1 (en) 1999-03-03 1999-03-03 Process for producing polyethylene

Publications (2)

Publication Number Publication Date
KR20010106509A KR20010106509A (ko) 2001-11-29
KR100549885B1 true KR100549885B1 (ko) 2006-02-06

Family

ID=22272300

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020017004463A Expired - Lifetime KR100549885B1 (ko) 1999-03-03 1999-03-03 폴리에틸렌의 제조 방법

Country Status (9)

Country Link
EP (1) EP1159311B1 (https=)
JP (1) JP2002538242A (https=)
KR (1) KR100549885B1 (https=)
CN (1) CN1172963C (https=)
AT (1) ATE242274T1 (https=)
BR (1) BR9915578B1 (https=)
CA (1) CA2341880A1 (https=)
DE (1) DE69908657T2 (https=)
WO (1) WO2000052066A1 (https=)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1159314B1 (en) * 1999-03-03 2004-08-04 Eastman Chemical Company Process for producing polyethylene
US6759492B2 (en) * 2001-07-24 2004-07-06 Eastman Chemical Company Process for the polymerization of ethylene and interpolymers thereof
US6828395B1 (en) 2003-10-15 2004-12-07 Univation Technologies, Llc Polymerization process and control of polymer composition properties
US7238756B2 (en) 2003-10-15 2007-07-03 Univation Technologies, Llc Polymerization process and control of polymer composition properties
EP2062924A1 (en) 2007-11-22 2009-05-27 Ineos Europe Limited Process for polymerising ethylene
US20120053305A1 (en) * 2010-08-24 2012-03-01 Equistar Chemicals, Lp Preparation of LLDPE having controlled xylene solubles or hexane extractables

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0655780B2 (ja) * 1984-07-09 1994-07-27 東燃株式会社 オレフイン重合用触媒成分
FR2640273B1 (fr) * 1988-12-14 1992-09-04 Atochem Procede de polymerisation en phase gazeuse de l'ethylene permettant la fabrication de polyethylene lineaire de distribution etroite de masse moleculaire
BR9105561A (pt) * 1990-12-21 1992-09-01 Union Carbide Chem Plastic Catalisador de alta atividade a base de vanadio

Also Published As

Publication number Publication date
DE69908657T2 (de) 2004-03-18
JP2002538242A (ja) 2002-11-12
CA2341880A1 (en) 2000-09-08
WO2000052066A1 (en) 2000-09-08
CN1172963C (zh) 2004-10-27
BR9915578B1 (pt) 2011-11-01
EP1159311B1 (en) 2003-06-04
EP1159311A1 (en) 2001-12-05
CN1357013A (zh) 2002-07-03
KR20010106509A (ko) 2001-11-29
ATE242274T1 (de) 2003-06-15
DE69908657D1 (de) 2003-07-10
BR9915578A (pt) 2001-08-14

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