KR100450437B1 - Multilayer nail-lacquer remover composition which is free from unpleasant smell of solvent, and prevents nails from being damaged by dehydration - Google Patents

Multilayer nail-lacquer remover composition which is free from unpleasant smell of solvent, and prevents nails from being damaged by dehydration Download PDF

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KR100450437B1
KR100450437B1 KR1019960067302A KR19960067302A KR100450437B1 KR 100450437 B1 KR100450437 B1 KR 100450437B1 KR 1019960067302 A KR1019960067302 A KR 1019960067302A KR 19960067302 A KR19960067302 A KR 19960067302A KR 100450437 B1 KR100450437 B1 KR 100450437B1
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multilayer
nail lacquer
low viscosity
composition
nail
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KR1019960067302A
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KR19980048671A (en
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신현종
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주식회사 엘지생활건강
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q3/00—Manicure or pedicure preparations
    • A61Q3/04—Nail coating removers

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
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Abstract

PURPOSE: Provided is a multilayer nail-lacquer remover composition which is free from the unpleasant smell of a solvent, and prevents nails from being damaged by dehydration. The composition is composed of multilayer, and thus has stable appearance having various colors. CONSTITUTION: The multilayer nail-lacquer remover composition is characterized by containing 20-60 wt.% of propylene carbonate, 1-30 wt.% of methoxy ethanol, 1-30 wt.% of low viscosity of silicon oil and 10-50 wt.% of purified water, wherein the low viscosity of silicon oil is low viscosity circular silicon selected from octametha cyclo tetrasiloxane and dodeca methylcyclo hexasiloxane, and dimethyl polysiloxane having a viscosity ranging within 1cSt-10cSt.

Description

다층 네일락카 제거제 조성물Multilayer Nail Lacquer Remover Composition

본 발명은 불쾌한 용제취가 없는 다층 네일락카(multilayer nail lacq-uer 제거제 조성물에 관한 것으로서, 특히 손톱의 탈수 현상에 의한 손상방지와 불쾌한 용제 냄새가 나지 않으며, 다층으로 구성되어 다양한 색상의 아름다운 외관을 지닌 안정한 다층 네일락카 제거제에 조성물에 관한 것이다.The present invention relates to a multilayer nail lacq-uer remover composition that does not have an unpleasant solvent odor, and in particular, prevents damage due to dehydration of nails and does not have an unpleasant solvent smell, and is composed of multiple layers to provide a beautiful appearance of various colors. The composition relates to a stable multilayer nail lacquer remover.

종래의 네일락카 제거액은 네일락카의 주된 필름형성제인 니트로셀룰로오스 및 부착력, 광택을 제공하는 수지류등의 네일락카 주성분을 용해시킬 수 있는 저비점 유기용제인 저급알킬아세테이트, 아세톤등이 그 주성분을 이루고 있으나, 이들은 손톱에 대하여 강한 탈지 및 탈수 현상을 유발하므로 장기간 사용할 경우에는 손톱과 그 주변 피부를 손상시키는 원인이 되었고, 저급 알킬아세테이트(예;부틸아세테이트, 에칠아세테이트), 아세톤의 특이취로 인하여 네일락카 제거액을 사용할때 역겨운 용제취를 발생시켜 불쾌감을 일으키는 것이 일반적인 현상이었다.Conventional nail lacquer removers are composed of nitrocellulose, the main film-forming agent of nail lacquer, and lower alkylacetate, acetone, etc. They cause strong degreasing and dehydration of the nails, which can cause damage to the nails and the surrounding skin when used for a long period of time, and nail lacquer removal due to the peculiar smell of lower alkyl acetates (e.g. butyl acetate, ethyl acetate) and acetone. It was a common phenomenon that discomfort caused by disgusting solvent odor when using.

또한 제품의 외관을 아름답게 보이도록 하기 위한 다층형 네일락카 제거액이 여러 가지로 제안되었는데, 다층형 네일락카 제거액에 관한 종래의 방법 및 기술을 살펴보면 다음과 같다.In addition, a multi-layer nail lacquer removal liquid has been proposed in various ways to make the appearance of the product beautiful. Looking at the conventional methods and techniques related to the multilayer nail lacquer removal liquid are as follows.

일본공개특허 소 57-122013호에서는 유충을 지닌 2층형 네일락카 제거액이 제안되었으나, 유상을 분산시키기 위해서는 격렬한 교반조건이 필요하며, 상시 제거액을 정치시켜 둘 경우 곧 2층으로 분리되므로 사용시에 계속 흔들어 이들을 혼합시켜야 하는 단점이 있었으며, 일본공개특허 평 1-143818호에서는 아세톤과 액상유 및 산화티탄, 마이카, 산화철, 타올린등의 분체를 사용한 2층형 네일락카 제거액이 기술되어 있으나, 장시간 경과시에는 비중이 큰 마이카와 산화티탄등이 침전되어 아름다운 외관을 유지하기 어려웠다.In Japanese Laid-Open Patent Publication No. 57-122013, a two-layer nail lacquer removal liquid having larvae has been proposed, but vigorous stirring conditions are required to disperse the oil phase. There is a disadvantage in that they must be mixed, Japanese Patent Laid-Open No. 1-143818 describes a two-layer nail lacquer removal liquid using acetone and liquid oil and powders such as titanium oxide, mica, iron oxide, and taolin, but after a long time It was difficult to maintain a beautiful appearance due to the precipitation of mica and titanium oxide, which have a high specific gravity.

또한 상기 일본공개특허 소 57-122013호 및 평 1-143818호의 경우에는 2층형으로 분리되므로써 색상표현면에서 제한을 받을 뿐아니라 외관상 미적표현이 단조로운 한계가 있었다.In addition, the Japanese Patent Application Laid-Open Nos. 57-122013 and 1-143818 have two limitations in color expression as well as aesthetic limitations in appearance.

이외에도 일본공개특허 평 1-160908호에서는 아세톤, 정제수, 탄산프로필렌, 비점이 300℃이상인 액상유 탄화수소 용제를 함유하는 3상형 네일락카 제거액이 제안되었다.In addition, Japanese Patent Laid-Open No. 1-160908 proposes a three-phase nail lacquer removal liquid containing acetone, purified water, propylene carbonate, and a liquid oil hydrocarbon solvent having a boiling point of 300 ° C or higher.

그러나 상기 발명은 액상유를 주성분으로 하는 상층과 탄산프로필렌, 탄화수소용제 아세톤으로 이루어진 중층 및 물과 아세톤으로 구성된 하층의 3상형 네일락카 조성물임을 주장하고 있으나, 탄산프로필렌은 그 비중이 1.2이상으로서 하층을 구성하고 있는 수상성분보다 무겁기 때문에 중간상으로 존재하는 것이 불가능하며, 탄화수소용제 또한 중간층의 구성성분으로 사용된 아세톤과 탄산프로필렌에 대한 용해성이 상층성분인 액상유에 대해서 보다 나쁘므로 용해도와 비중차에 의해 상분리가 이루어지는 층상구성원리상으로 볼때 상기 발명은 상층과 하층의 2층상으로구성될 수밖에 없으므로, 안정한 3층 분리 형태를 유지하기 어렵다.However, the present invention claims to be a three-phase nail lacquer composition composed of a liquid oil-based upper layer, a middle layer composed of propylene carbonate, a hydrocarbon solvent acetone, and a lower layer composed of water and acetone. It is impossible to exist in the intermediate phase because it is heavier than the aqueous phase component, and the solubility of acetone and propylene carbonate used as a constituent of the intermediate layer is worse than that of the liquid oil which is the upper layer component. In view of the layered composition principle, the present invention cannot but consist of two layers of upper and lower layers, and thus it is difficult to maintain a stable three-layer separation form.

이상에서 기술한 선행기술 발명들에서는 한결같이 아세톤등의 휘발성이 강한 용제들을 사용하고 있으므로, 네일락카 제거제를 사용할때 불쾌한 용제취를 발생시킬 수밖에 없었다.In the above-described prior art inventions, since volatile solvents such as acetone are consistently used, there is no choice but to produce an unpleasant solvent odor when the nail lacquer remover is used.

이에 본 발명자는 상술한 선행기술의 문제점들을 해소하기 위해 수많은 연구와 실험을 거듭한 결과 정제수, 탄산프로필렌, 메톡시에탄올 및 저점도 실리콘 오일을 조합사용하므로써, 불쾌한 용제취가 나지 않으며 우수한 외관미를 지닌 안정한 다층 네일락카 제거제 조성물을 개발하게 되었다.Accordingly, the present inventors have conducted numerous studies and experiments to solve the above-mentioned problems of the prior art, and by using a combination of purified water, propylene carbonate, methoxy ethanol and low viscosity silicone oil, there is no unpleasant solvent smell and excellent appearance beauty. A stable multilayer nail lacquer remover composition has been developed.

본 발명은 탄산프로필렌, 메톡시에탄올, 저점도실리콘오일 및 정제수를 함유하여 불쾌한 용제취가 나지 않고 안정한 3층 분리형태로 이루어짐을 특징으로 하는 다층네일락카 제거제 조성물에 관한 것이다.The present invention relates to a multilayer nail lacquer remover composition comprising propylene carbonate, methoxy ethanol, low viscosity silicone oil, and purified water, and having a stable three-layer separation form without an unpleasant solvent odor.

본 발명에 따른 네일락카 제거제 조성물은 정제수 10-50중량%, 탄산프로필렌 20-60중량%, 메톡시에탄올 1-30중량%, 저점도 실리콘오일 1-30중량%를 함유한다.The nail lacquer remover composition according to the present invention contains 10-50% by weight of purified water, 20-60% by weight of propylene carbonate, 1-30% by weight of methoxyethanol, and 1-30% by weight of low viscosity silicone oil.

본 발명에 따른 다층 네일락카 제거제 조성물은 주성분으로서 탄산프로필렌을 20-70중량% 함유하게 되는데, 이때 탄산프로필렌의 사용량이 20중량% 미만인 경우에는 네일락카 제거액의 주목적인 네일락카 제거효과가 나빠지게 되며, 70중량%를 초과하는 경우에는 만족스러운 마일드감을 얻지 못한다.The multilayer nail lacquer remover composition according to the present invention contains 20-70% by weight of propylene carbonate as a main component, and when the amount of propylene carbonate is less than 20% by weight, the main effect of removing nail lacquer is worse. If it exceeds 70% by weight, a satisfactory mild feeling is not obtained.

본 발명의 다층 네일락카 제거제 조성물에서 메톡시에탄올은 1-30중량%를 사용한다. 메톡시에탄올을 1중량% 미만으로 사용할 경우에는 네일락카 제거 효과가 떨어지며, 30중량%를 초과시에는 탄산프로필렌상과 정제수 상의 용해성이 좋아지므로 안정한 다층 구조를 얻을 수 없게 된다.In the multilayer nail lacquer remover composition of the present invention, methoxyethanol is used in an amount of 1-30% by weight. When methoxy ethanol is used in less than 1% by weight, the nail lacquer removal effect is inferior, and when it exceeds 30% by weight, the solubility in the propylene carbonate phase and the purified water is improved, so that a stable multilayer structure cannot be obtained.

또한 본 발명 조성물의 상층 구성성분인 저점도 실리콘오일은 저점도 환상 실리콘과 저점도 디메칠폴리실록산을 사용할 수 있는데, 저점도 환상실리콘은 옥타메칠사이클로테트라실록산, 도데카메칠사이클로 헥사실록산등을 사용할 수 있고, 저점도 디메칠폴리실록산은 1센티스톡스-10센티스톡스를 사용 가능한데, 10센티스톡스 이상의 디메칠폴리실록산은 네일락카 제거시 손톱에 두꺼운 오일막을 형성하므로 좋지 못하다.In addition, the low-viscosity silicone oil, which is an upper constituent of the composition of the present invention, may use low-viscosity cyclic silicone and low-viscosity dimethylpolysiloxane, and the low-viscosity cyclic silicone may use octamethylcyclotetrasiloxane, dodecamethylcyclo hexasiloxane, and the like. In addition, the low viscosity dimethylpolysiloxane may use 1 centistox-10 centistox, but dimethylpolysiloxane of 10 centistox or more is not good because it forms a thick oil film on the nail when removing the nail lacquer.

본 발명 조성물에서 저점도 실리콘오일은 1-30중량%를 사용할 수 있다. 저점도 실리콘오일을 1중량% 이하 사용시에는 안정한 상층구조 및 손톱 보호효과를 나타내기가 어렵고, 30중량% 이상 사용하는 경우에는 네일락카 제거효과를 떨어뜨릴 수 있으므로 바람직하지 못하다.Low viscosity silicone oil in the composition of the present invention may be used 1-30% by weight. When using a low viscosity silicone oil of less than 1% by weight it is difficult to exhibit a stable upper layer structure and nail protection effect, when using more than 30% by weight is not preferable because it can reduce the nail lacquer removal effect.

본 발명 조성물에서 사용되는 정제수는 네일락카 제거효과, 균형있는 층상 구성을 위해 10-50 중량% 함유하는 것이 좋다.Purified water used in the composition of the present invention is preferably contained 10-50% by weight for the nail lacquer removal effect, a balanced layer composition.

이외에도 본 발명 조성물은 필요에 따라 글리세린, 프로필렌글리콜등의 보습제 및 향료와 색소를 첨가하므로써 향취, 외관을 더욱 좋게 할 수 있다.In addition, the composition of the present invention can further improve the fragrance and appearance by adding moisturizers such as glycerin and propylene glycol, flavoring agents and pigments as necessary.

본 발명의 불쾌한 용제취가 없는 다층 네일락카 제거제 조성물의 층상 구조는 아래의 그림 1과 같다.The layered structure of the multilayer nail lacquer remover composition without the unpleasant solvent smell of the present invention is shown in Figure 1 below.

그림 1Pic 1

본 발명 조성물은 상기의 그림 1과 같이 상층에는 손톱보호효과가 우수한 저점도 실리콘오일로 구성되어 있고, 중층에는 정제수, 하층에는 비중이 높은 탄산프로필렌으로 구성되며 하층과 중층에는 정제수와 탄산프로필렌에 대하여 용해성이 우수한 메톡시에탄올이 용해되어 있다.The composition of the present invention is composed of a low viscosity silicone oil having excellent nail protection effect in the upper layer, as shown in Figure 1 above, consisting of purified water in the middle layer and propylene carbonate having a high specific gravity in the lower layer, and purified water and propylene in the lower and middle layers. Methoxyethanol excellent in solubility is dissolved.

본 발명 조성물에서 쓰이는 탄산프로필렌과 메톡시에탄올은 불쾌한 용제취가 나지 않으며 네일락카 제거 효과가 우수한 성분이다. 본 발명 조성물은 그림1과 같이 안정한 3층 구조를 취하므로 각 층에 색상을 부여할 수 있어 아름다운 외관미를 부여할 수 있다.Propylene carbonate and methoxy ethanol used in the composition of the present invention do not have an unpleasant solvent odor and is an excellent component for removing nail lacquer. Since the composition of the present invention has a stable three-layer structure as shown in Fig. 1, color can be given to each layer, thereby giving a beautiful appearance.

이하, 본 발명을 실시예에 의거하여 구체적으로 설명하지만, 본 발명의 기술적 범위가 이들로 제한되는 것은 아니다.Hereinafter, although this invention is demonstrated concretely based on an Example, the technical scope of this invention is not limited to these.

실시예 1-4 및 비교예 1-3Example 1-4 and Comparative Example 1-3

표1에 나타낸 바에 따라 1-13의 성분을 평량하여 균일하게 교반시켜 실시예 1-4 및 비교예 1-3의 네일락카 제거제 조성물을 제조하였다.As shown in Table 1, the components of 1-13 were weighed and uniformly stirred to prepare the nail lacca remover compositions of Examples 1-4 and Comparative Examples 1-3.

표1.Table 1.

[품질평가][Quality evaluation]

상기 실시예와 비교예에 따라 제조된 네일락카 제거제 조성물을 다음과 같은 방법으로 품질평가를 실시하였다.Quality evaluation of the nail lacquer remover composition prepared according to the Examples and Comparative Examples was carried out in the following manner.

네일락카 제거액을 사용해 본 경험이 있는 20대에서 40대 여성 30명을 대상으로 실시예 및 비교예에서 제조된 네일락카제거제를 사용하게 한다음, 제품의 외관미, 네일락카 제거효과, 사용시 불쾌한 용제취 발생정도, 보습효과등을 다음의기준으로 평가 하였다.30 people in their 20s to 40s who have experience using nail lacquer removal liquids should use the nail lacquer remover prepared in Examples and Comparative Examples, and then the appearance of the product, nail lacquer removal effect, and unpleasant solvents when using Odor incidence and moisturizing effects were evaluated based on the following criteria.

(양호하다고 평가한 사람수/불량하다고 평가한 사람수)(Number of people who considered good / number of people who evaluated poor)

상기 품질평가 결과는 하기표 2에 나타내었다.The quality evaluation results are shown in Table 2 below.

표 2.Table 2.

상기 표2의 결과에서 나타난 바와 같이 본 발명 조성물(실시예 1-4 은 기존의 단일상 네일락카 제거제(비교예1) 및 다층상 네일락카 제거제 (비교예2-3 에 비하여 외관미, 네일락카 제거효과, 보습효과, 불쾌한 용제취 정도등 전반적인 면에서 우수한 효과를 나타내었다.As shown in the results of Table 2, the composition of the present invention (Example 1-4 is a conventional single-phase nail lacquer remover (Comparative Example 1) and multi-layer nail lacquer remover (Comparative Example 2-3 appearance beauty, nail lacquer) It showed excellent effect in overall aspects such as removal effect, moisturizing effect and unpleasant solvent odor.

비교예 1(단층형 네일락카 제거제)의 경우 네일락카 제거효과는 우수하지만 외관미가 좋지 않고, 불쾌한 용제취가 심하며, 비교예 2(일본공개특허 평 1-143818호)는 층간의 불균형 및 비중이 큰 분체가 첨가됨으로 인해 외관미가 좋지 못하고, 냄새 발생이 심하다.In the case of Comparative Example 1 (single layer nail lacquer remover), the nail lacquer removal effect is excellent, but the appearance is not good, the unpleasant solvent smell is severe, and Comparative Example 2 (Japanese Patent Laid-Open No. 1-143818) has an unbalance and specific gravity between layers. Due to the addition of large powder, the appearance is not good, and the smell is severe.

또한 비교에 3(대한민국 특허출원 제 90-11240호)에서는 외관미 보습효과는 비교적 우수한 물성을 나타내었으나, 초산부틸에칠 및 아세톤의 냄새취 발생에 있어서 다소 열등하였다.In comparison 3 (Korean Patent Application No. 90-11240), the moisturizing effect of appearance was relatively excellent, but was slightly inferior in the occurrence of odor of butyl ethyl acetate and acetone.

반면에 실시예 1-4의 다층 네일락카 제거제는 안정한 3층 구조를 취하여 우수한 외관미를 지니고, 용제의 냄새취가 거의 나지 않아 사용시 전혀 불쾌감이 없고 저점도 실리콘오일에 의해 보습효과가 뛰어나므로 네일락카 제거제로서 갖추어야 할 모든면에서 우수한, 불쾌한 용제취가 없는 다층 네일락카 제거제 조성물임을 알 수 있다.On the other hand, the multi-layered nail lacquer remover of Example 1-4 has a stable three-layer structure, has an excellent appearance beauty, almost no smell of the solvent, so there is no discomfort when using and excellent moisturizing effect by low viscosity silicone oil It can be seen that it is a multilayer nail lacquer remover composition which is excellent in all respects as a lacquer remover and has no unpleasant solvent odor.

Claims (2)

탄산프로필렌 20-60중량%, 메톡시에탄올 1-30중량%, 저점도 실리콘 오일 1-30중량% 및 정제수 10-50중량%를 함유하여, 불쾌한 용제취가 나지 않고 안정한 3층 분리형태로 이루어짐을 특징으로 하는 다층 네일락카 제거제 조성물.20-60% by weight of propylene carbonate, 1-30% by weight of methoxyethanol, 1-30% by weight of low-viscosity silicone oil, and 10-50% by weight of purified water. Multilayer nail lacquer remover composition, characterized in that. 제 1항에 있어서, 저점도 실리콘 오일이 옥타메칠 사이클로 테트라실록산 및 도데카 메칠사이클로 헥사실록산 중에서 선택된 저점도 환상 실리콘과 1센티스톡스-10센티스톡스 범위의 저점도 디메칠 폴리실록산으로 구성됨을 특징으로 하는 다층 네일락카 제거제 조성물.The low viscosity silicone oil according to claim 1, characterized in that the low viscosity silicone oil consists of low viscosity cyclic silicone selected from octamethylcyclo tetrasiloxane and dodeca methylcyclo hexasiloxane and low viscosity dimethyl polysiloxane in the range of 1 centistox-10 centistox. Multilayer nail lacquer remover composition.
KR1019960067302A 1996-12-18 1996-12-18 Multilayer nail-lacquer remover composition which is free from unpleasant smell of solvent, and prevents nails from being damaged by dehydration KR100450437B1 (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR880013548A (en) * 1987-05-08 1988-12-21 허신구 Multi-layer nail lacquer remover
JPH01216911A (en) * 1988-02-25 1989-08-30 Nikkei New Bijinesu Kk Enamel-remover for manicure
JPH01242515A (en) * 1988-03-22 1989-09-27 Suhama Kagaku Kk Nail lacquer remover
WO1996014823A1 (en) * 1994-11-16 1996-05-23 Kao Corporation Enamel remover
US5543085A (en) * 1995-03-24 1996-08-06 Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. Thickened nail polish remover

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR880013548A (en) * 1987-05-08 1988-12-21 허신구 Multi-layer nail lacquer remover
JPH01216911A (en) * 1988-02-25 1989-08-30 Nikkei New Bijinesu Kk Enamel-remover for manicure
JPH01242515A (en) * 1988-03-22 1989-09-27 Suhama Kagaku Kk Nail lacquer remover
WO1996014823A1 (en) * 1994-11-16 1996-05-23 Kao Corporation Enamel remover
US5543085A (en) * 1995-03-24 1996-08-06 Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. Thickened nail polish remover

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