JPH06279241A - Hair cosmetic - Google Patents

Hair cosmetic

Info

Publication number
JPH06279241A
JPH06279241A JP5310127A JP31012793A JPH06279241A JP H06279241 A JPH06279241 A JP H06279241A JP 5310127 A JP5310127 A JP 5310127A JP 31012793 A JP31012793 A JP 31012793A JP H06279241 A JPH06279241 A JP H06279241A
Authority
JP
Japan
Prior art keywords
hair cosmetic
silicone
cosmetic composition
hair
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP5310127A
Other languages
Japanese (ja)
Other versions
JP3243356B2 (en
Inventor
Petsushiyu Fuerudeinando
ペッシュ フェルディナンド
Naohisa Go
尚久 呉
Risa Sakuma
梨紗 佐久間
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/03—Liquid compositions with two or more distinct layers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Abstract

PURPOSE:To provide a hair cosmetic containing two kinds of different visually separated phases, immediately mixed to form a homogeneous emulsion when the hair cosmetic is shaked before use, and preferably separated into transparent, different two layers immediately after use. CONSTITUTION:A hair cosmetic contains at least one kind of silicone polyol of the formula (R is 1-18C alkyl; A is ethylene, propylene; C is H, 1-4C alkyl; m, n, z are 2-25; 1 is 1-10) in an amount of 0.05-5wt.%, preferably 0.25-3wt.%, in the whole composition. The ratio of the oil phase to the cosmetic is 15-40wt.%, especially 20-30wt.%, in the whole composition, and the oil composition is preferably a silicone oil, especially high to low volatile aliphatic or cyclic siloxane (e.g. hexamethyldisiloxane), 4-30C linear, branched or cyclic hydrocarbon or their mixture. The hair cosmetic does not require in particular, an emulsifier and a conditioning agent except the compound of the formula and exhibits an excellent two-layer type performance.

Description

【発明の詳細な説明】Detailed Description of the Invention

【０００１】[0001]

【産業上の利用分野】本発明は毛髪化粧料に関し、更に
詳細には、２つの異なる視覚的に分離した相を含有し、
使用前に振とうすることにより直ちに混合され均一なエ
マルションとなり、使用後にはすぐに、好ましくは透明
な、異なる二層に分離する毛髪化粧料に関する。FIELD OF THE INVENTION The present invention relates to hair cosmetics and more particularly to containing two different visually separated phases,
The present invention relates to a hair cosmetic composition that immediately mixes by shaking before use to form a uniform emulsion, and immediately after use, separates into two layers which are preferably transparent and different.

【０００２】[0002]

【従来の技術及び発明が解決しようとする課題】分離し
た二層を含有し、使用前に振とうすることにより直ちに
混合され均一なエマルションとなり、使用後にはすぐに
二層に分離するという性質を有する毛髪化粧料は、その
魅力的な外観により、消費者に好評である。特に、好ま
しくは透明な、２つの相が異なる色である場合には、振
とうすることによってこれらの相が混合され、更に面白
い視覚的な効果が得られる。PRIOR ART AND PROBLEM TO BE SOLVED BY THE INVENTION The property of containing two separated layers is that, by shaking before use, they are immediately mixed to form a uniform emulsion, and immediately after use, they are separated into two layers. The hair cosmetics it has are well received by consumers due to their attractive appearance. Particularly when the two phases, which are preferably transparent, are of different colors, the phases are mixed by shaking to obtain a more interesting visual effect.

【０００３】このような製品を使用する際には、振とう
することによって二層が素早く混合され、乳化によって
均一なエマルションになり、これを毛髪に適用すること
ができ、またその後はすぐに二層に分離するという要件
を満たしていることが重要である。When using such products, the two layers are rapidly mixed by shaking and emulsified into a uniform emulsion which can be applied to the hair and then immediately afterwards. It is important to meet the requirement of layer separation.

【０００４】このような製品としては、ドイツ特許出願
第３，６２７，３１３号が知られている。この製品は、
乳化剤として、全組成中に１重量％以下のトリラネース
−４ホスフェート（エチレンオキシド平均４モル付加ラ
ノリンアルコールとリン酸のトリエステル）を含有する
ものである。なお、以下の原料名は、一般名又は米国Ｃ
ＴＦＡ（Ｔｈｅ Ｃｏｓｍｅｔｉｃ，Ｔｏｉｌｅｔｒｙ
ａｎｄ Ｆｒａｇｒａｎｃｅ Ａｓｓｏｃｉａｔｉｏ
ｎ）名を用いた。しかしながら、これらの製品は、毛髪
に充分浸透するような均一なエマルションを形成せず、
また、その後長時間後でも拡散した外観のままで透明な
二層に分離しないなど、前記の要件を満足するものでは
なかった。German Patent Application No. 3,627,313 is known as such a product. This product is
As an emulsifier, the total composition contains 1% by weight or less of trilane-4 phosphate (ethylene oxide average 4 mol addition lanolin alcohol and triester of phosphoric acid). The following raw material names are generic names or US C
TFA (The Cosmetic, Toiletry)
and Fragrance Associatio
n) name was used. However, these products do not form a uniform emulsion that penetrates the hair well,
Further, even after a long period of time thereafter, the above-mentioned requirements are not satisfied such that the diffused appearance remains and the transparent two layers are not separated.

【０００５】ドイツ特許第４，１００，４９０号には、
スキントリートメント用の二層組成物が開示されてい
る。この組成物は、分離した透明な二層が存在し、振と
うにより混合されると均一相を形成し、その後異なる透
明な二層に分離するものであり、乳化剤として、炭素数
１２〜１８のトリグリセリン脂肪酸モノエステルを全組
成物中に０．１〜１．０重量％含有する。このように製
造される組成物は前記の要件を満足するが、毛髪のコン
ディショニング効果を得るためには、トリグリセリン脂
肪酸モノエステル自身ではほとんど効果が得られないた
め、他の特別の成分を、しばしば多量に配合する必要が
あるという欠点があった。しかも、このことは適合性に
ついての問題も生じる。German Patent 4,100,490 describes
A two-layer composition for skin treatment is disclosed. This composition has two separate transparent layers, forms a homogeneous phase when mixed by shaking, and then separates into two different transparent layers. As an emulsifier, it has 12 to 18 carbon atoms. Triglycerin fatty acid monoester is contained in the total composition in an amount of 0.1 to 1.0% by weight. The composition thus produced satisfies the above-mentioned requirements, but in order to obtain a hair conditioning effect, triglycerin fatty acid monoester itself has little effect, and therefore other special ingredients are often added. There was a drawback that it was necessary to mix a large amount. Moreover, this also raises compatibility issues.

【０００６】従って、分離した二層を含有し、振とうす
ることにより一時的に均一なエマルションとなり、その
後すぐに２つの異なる視覚的に分離した相になり、しか
も乳化剤が、それ自体で更にヘアコンディショニング効
果を有するものである組成物が望まれていた。[0006] Thus, it contains two separate layers and is shaken to give a temporarily homogeneous emulsion, which is immediately followed by two different visually separated phases, while the emulsifiers themselves add further to the hair. It has been desired to have a composition that has a conditioning effect.

【０００７】[0007]

【課題を解決するための手段】かかる実情において、本
発明者らは鋭意研究を行った結果、乳化剤として特定の
シリコーンコポリオールを用いれば、上記課題を解決し
た二層型の優れた毛髪化粧料が得られることを見出し、
本発明を完成した。Under such circumstances, as a result of intensive studies by the present inventors, if a specific silicone copolyol is used as an emulsifier, an excellent two-layer type hair cosmetic composition that solves the above-mentioned problems can be obtained. Found that
The present invention has been completed.

【０００８】すなわち、本発明は、一般式（１）That is, the present invention is based on the general formula (1)

【０００９】[0009]

【化２】 [Chemical 2]

【００１０】（式中、Ｒは炭素数１〜１８のアルキル基
を示し、Ａはエチレン基又はプロピレン基を示し、Ｘは
水素原子又は炭素数１〜４のアルキル基を示し、ｍ、ｎ
及びｚはそれぞれ２〜２５の数を示し、ｌは１〜１０の
数を示す）で表わされるシリコーンコポリオールの少な
くとも１種を全組成中に０．０５〜５重量％含有し、使
用前には異なる二層に分離し、振とうすることにより混
合されて短時間に均一なエマルションを形成し、その後
二層に分離する毛髪化粧料を提供するものである。(In the formula, R represents an alkyl group having 1 to 18 carbon atoms, A represents an ethylene group or a propylene group, X represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and m, n
And z each represent a number of 2 to 25, and 1 represents a number of 1 to 10), and 0.05 to 5% by weight is contained in the total composition of at least one silicone copolyol. Provides a hair cosmetic composition that separates into two different layers, is mixed by shaking to form a uniform emulsion in a short time, and then separates into two layers.

【００１１】一般式（１）で表わされるシリコーンコポ
リオールの好ましいものとしては、例えばダウコーニン
グ社、ゴールドシュミット社、ユニオンカーバイド社、
信越化学工業社等から市販されているジメチコーンコポ
リオールが挙げられ、これらは式（１）中、ｍが５〜１
５、ｎが３〜７、ｌが２又は３、ｚが１０〜１５の数を
示すものである。また、Ｘは水素原子、エチル基、メチ
ル基、ｎ−プロピル基、イソプロピル基、ｎ−ブチル基
を示す。Ｒとしては、メチル基、ラウリル基、セチル基
が好ましい。Preferred examples of the silicone copolyol represented by the general formula (1) include, for example, Dow Corning, Goldschmidt, Union Carbide,
Examples include dimethicone copolyols commercially available from Shin-Etsu Chemical Co., Ltd., and these have m of 5 to 1 in the formula (1).
5, n is 3 to 7, 1 is 2 or 3, and z is a number of 10 to 15. X represents a hydrogen atom, an ethyl group, a methyl group, an n-propyl group, an isopropyl group, or an n-butyl group. R is preferably a methyl group, a lauryl group or a cetyl group.

【００１２】このようなシリコーンコポリオールとして
は、Ａｂｉｌ Ｂ ８８４２、Ｂ８８４３、Ｂ ８８４
７、Ｂ ８８５１、Ｂ ８８５２、Ｂ ８８６３、Ｂ
８８７３、Ｂ ８８１８３、Ｂ ８８１８４（以上、ゴ
ールドシュミット社製）、Ｄｏｗ Ｃｏｒｎｉｎｇ １
９０、１９３、Ｑ２−５２２０ポリエーテル（以上、ダ
ウコーニング社製）、信越 ＫＦ ３５１Ａ、ＫＦ ３
５２Ａ、ＫＦ ３５３Ａ、ＫＦ ３５４Ａ、ＫＦ ３５
５Ａ、ＫＦ ６１５Ａ、ＫＦ ６２５Ａ、ＫＦ ９４５
Ａ（以上、信越化学工業社製）、Ｓｉｌｗｅｔ（ユニオ
ンカーバイド社製）などの市販品を用いることができ
る。Examples of such silicone copolyols include Abil B8842, B8843, and B884.
7, B 8851, B 8852, B 8863, B
8873, B 88183, B 88184 (all manufactured by Gold Schmidt), Dow Corning 1
90, 193, Q2-5220 polyether (all manufactured by Dow Corning), Shin-Etsu KF 351A, KF 3
52A, KF 353A, KF 354A, KF 35
5A, KF 615A, KF 625A, KF 945
Commercial products such as A (above, manufactured by Shin-Etsu Chemical Co., Ltd.) and Silwet (manufactured by Union Carbide) can be used.

【００１３】これらのシリコーンコポリオールは、１種
又は２種以上を組合わせて用いることができ、全組成中
に０．０５〜５重量％、好ましくは０．２５〜３重量％
配合される。０．０５重量％未満では、振とうにより速
やかに乳化せず、５重量％を超えると静止による速やか
な二層分離を得ることができない。These silicone copolyols may be used either individually or in combination of two or more, and are contained in an amount of 0.05 to 5% by weight, preferably 0.25 to 3% by weight, based on the total composition.
Be compounded. If it is less than 0.05% by weight, the emulsion will not be rapidly emulsified by shaking, and if it exceeds 5% by weight, rapid two-phase separation due to stationary cannot be obtained.

【００１４】本発明の毛髪化粧料において、油相の割合
は全組成中に約１５〜４０重量％、特に約２０〜３０重
量％、更に約２０重量％であるのが好ましい。この油相
は天然又は合成油のあらゆるものを含んでいてもよく、
かかる油相成分としては、例えば前記ドイツ特許第４，
１００，４９０号に記載されているものなどが挙げられ
る。In the hair cosmetic composition of the present invention, the proportion of the oil phase in the total composition is preferably about 15 to 40% by weight, particularly about 20 to 30% by weight, and more preferably about 20% by weight. This oil phase may contain any of the natural or synthetic oils,
Examples of such oil phase components include the above-mentioned German Patent No. 4,
The thing described in 100,490 is mentioned.

【００１５】油相成分としては、公知の種々のシリコー
ン油、特に高〜低揮発性脂肪族又は環状シロキサンが好
ましい。好ましいシロキサンとしては、例えばヘキサメ
チルジシロキサンが挙げられ、特にこれを単独又はポリ
フェニルメチルシロキサン等の環状シロキサンと混合し
たものが好ましい。また、例えばオクタ−、デカ−又は
ドデカメチルシクロヘキサシロキサン等の、一般名「シ
クロメチコーン」として知られている、ポリジメチルシ
クロシロキサンも好ましい。これらの揮発性シリコーン
を用いる場合には、密閉可能なエアゾール容器又はスプ
レー容器を用いるのが好ましい。As the oil phase component, various known silicone oils, particularly high to low volatility aliphatic or cyclic siloxanes are preferable. Examples of preferable siloxanes include hexamethyldisiloxane, and it is particularly preferable to use hexamethyldisiloxane alone or in a mixture with cyclic siloxane such as polyphenylmethylsiloxane. Also preferred are polydimethylcyclosiloxanes known under the generic name "cyclomethicone", such as octa-, deca- or dodecamethylcyclohexasiloxane. When using these volatile silicones, it is preferable to use an aerosol container or a spray container that can be sealed.

【００１６】更に、油相成分として好ましいものとして
は、炭素数約４〜３０の直鎖、分岐鎖又は環状の炭化水
素、またこれらと前記シリコーン油との混合物が挙げら
れる。これらの場合には、脂肪族アルコールも好まし
く、例えば炭素数８〜２２の脂肪族アルコール、そのエ
ステル、更に長鎖脂肪酸の例えばエチル又はイソプロピ
ルアルコール等の低級アルコールのエステルなどが挙げ
られる。Further, preferable examples of the oil phase component include linear, branched or cyclic hydrocarbons having about 4 to 30 carbon atoms, and a mixture of these with the above silicone oil. In these cases, an aliphatic alcohol is also preferable, and examples thereof include an aliphatic alcohol having 8 to 22 carbon atoms, an ester thereof, and a lower alcohol ester of a long chain fatty acid such as ethyl or isopropyl alcohol.

【００１７】本発明の毛髪化粧料において、油相成分と
して好ましく用いられる天然油脂としては、当該分野で
公知のものが挙げられ、例えば“化粧品の基礎及び処
方”（Ｋ．Ｓｃｈｒａｄｅｒ，第２版，１９８９年，Ｈ
ｕｔｈｉｇ Ｂｕｃｈｖｅｒｌａｇ，ハイデルベルク）
第３２４〜３４１頁に記載されているものなどが挙げら
れる。In the hair cosmetic composition of the present invention, natural fats and oils preferably used as an oil phase component include those known in the art, for example, "Basic and formulation of cosmetics" (K. Schrader, 2nd edition, 1989, H
(Uthig Buchverlag, Heidelberg)
Examples thereof include those described on pages 324 to 341.

【００１８】水相の割合は、油相の割合に依存すること
は明らかであり、両相の合計が１００重量％となる。水
相には、前記シリコーンコポリオールのほか、通常の毛
髪化粧料に用いられる成分、例えば水、保湿剤、アルコ
ール類、ビタミン類、植物抽出物、紫外線吸収剤、血行
促進剤、抗炎症剤、香料等、更に、生理学的に許容され
る酸、所望のpHに調整するための緩衝剤などが配合され
る。It is clear that the proportion of the aqueous phase depends on the proportion of the oil phase, the sum of both phases being 100% by weight. In the water phase, in addition to the silicone copolyol, components used in ordinary hair cosmetics, such as water, moisturizers, alcohols, vitamins, plant extracts, ultraviolet absorbers, blood circulation promoters, anti-inflammatory agents, A fragrance, a physiologically acceptable acid, a buffering agent for adjusting to a desired pH, and the like are further added.

【００１９】本発明の毛髪化粧料には、更に視覚的な変
化をもたせるために、染料を配合することができ、油相
には油溶性の染料を、水相には水溶性の染料を使用する
ことができる。好ましい染料としては、ドイツ化粧品規
則（Ｄｅｕｔｓｃｈｅ Ｋｏｓｍｅｔｉｋｖｅｒｏｒｄ
ｎｕｎｇ）のＡｎｎｅｘIII に記載されている、化粧品
に許容される染料などが挙げられる。A dye may be added to the hair cosmetic composition of the present invention in order to make a further visual change. An oil-soluble dye is used in the oil phase and a water-soluble dye is used in the water phase. can do. The preferred dyestuffs are the German Cosmetics Regulations (Deutsche Kosmetikverord).
and the dyes acceptable for cosmetics described in Annex III of Nung).

【００２０】本発明の毛髪化粧料は、ヘアリンス等のヘ
アコンディショニング剤とする場合には、更にヘアコン
ディショニング成分を１相又は両相に添加することがで
きる。ヘアコンディショニング成分としては、公知のも
の、例えば前記Ｓｃｈｒａｄｅｒの文献の第７２２〜７
７１頁に記載されているものなどが挙げられる。また、
毛髪にハリ・コシを持たせるためには、ナフタレンスル
ホン酸塩、例えば２−ナフタレンスルホン酸のアルカリ
金属塩等を全組成中に０．１〜１０重量％、特に０．５
〜５重量％配合するのが好ましい。When the hair cosmetic composition of the present invention is used as a hair conditioning agent such as hair rinse, a hair conditioning component can be further added to one phase or both phases. Known hair conditioning components, such as those described in Schrader, 722-7.
Examples include those described on page 71. Also,
In order to give the hair firmness and elasticity, a naphthalene sulfonate, for example, an alkali metal salt of 2-naphthalene sulfonic acid is contained in the total composition in an amount of 0.1 to 10% by weight, particularly 0.5.
It is preferable to blend 5 to 5% by weight.

【００２１】本発明の毛髪化粧料は、２５℃における粘
度が１０００mPa・sec2(cSt) 以下であるのが好まし
い。The hair cosmetic composition of the present invention preferably has a viscosity at 25 ° C. of 1000 mPa · sec 2 (cSt) or less.

【００２２】[0022]

【発明の効果】本発明の毛髪化粧料は、乳化剤としてシ
リコーンコポリオール（１）を使用することにより、２
つの異なる視覚的に分離した相を含み、使用前に振とう
することにより直ちに混合され均一なエマルションとな
り、その後すぐに透明な二層に分離するものである。そ
して、前記乳化剤以外に特に乳化剤やコンディショニン
グ剤を用いる必要がなく、前記二層型の優れた性能が得
られ、しかもコンディショニング効果も良好である。EFFECTS OF THE INVENTION The hair cosmetic composition of the present invention contains 2 by using the silicone copolyol (1) as an emulsifier.
It contains three different visually separated phases, which are shaken before use to immediately mix into a uniform emulsion, which immediately separates into two clear layers. Further, it is not necessary to use an emulsifier or a conditioning agent other than the emulsifier, the excellent performance of the two-layer type is obtained, and the conditioning effect is also good.

【００２３】[0023]

【実施例】次に実施例を挙げて本発明を更に説明する。EXAMPLES The present invention will be further described with reference to examples.

【００２４】実施例１ 透明な油相Ａと透明な水相Ｂを含む下記組成のヘアコン
ディショニング剤を製造した。Example 1 A hair conditioning agent having the following composition containing a transparent oil phase A and a transparent aqueous phase B was prepared.

【００２５】[0025]

【表１】 油相Ａ： （重量％） ジメチコーン（ＤＣ ２００，０．２５cSt(25℃) ） ２０．０ シクロメチコーン（ＤＣ ３４４） ５．０ 水相Ｂ： グリセリン ５．０ ２−ナフタレンスルホン酸ナトリウム ３．０ ジメチコーンコポリオールメチルエーテル （信越 ＫＦ ３５１Ａ） ０．５ アラントイン ０．２ 水 バランス[Table 1] Oil phase A: (wt%) Dimethicone (DC 200, 0.25 cSt (25 ° C)) 20.0 Cyclomethicone (DC 344) 5.0 Aqueous phase B: Glycerin 5.0 2-naphthalene sulfone Sodium acid salt 3.0 Dimethicone copolyol methyl ether (Shin-Etsu KF 351A) 0.5 Allantoin 0.2 Water balance

【００２６】得られたコンディショニング剤は２つの異
なる透明な完全に分離した相を含み、これを振とうする
と均一なエマルションが得られた。このエマルションを
毛髪に適用すると、均一に広がり、すぐに浸透してコン
ディショニング効果を得ることができた。また、振とう
後１０分以内にエマルションは完全に分離した透明な二
層にもどった。The resulting conditioning agent contained two different clear, completely separated phases which were shaken to give a homogeneous emulsion. When this emulsion was applied to the hair, it spread evenly and quickly penetrated to obtain a conditioning effect. Also, within 10 minutes after shaking, the emulsion returned to a completely separated and transparent two layer.

【００２７】実施例２ 下記組成の透明な油相Ａと透明な水相Ｂより、ヘアコン
ディショニング剤を製造した。使用前に振とうして二層
を混合すると、直ちに均一になり、これをシャンプーし
た髪に適用すると、良好な光沢と豊かな感触とボリュー
ムが得られた。また、振とう後１０分以内に、エマルシ
ョンは分離した透明な二層にもどった。Example 2 A hair conditioning agent was produced from a transparent oil phase A and a transparent aqueous phase B having the following compositions. When the two layers were shaken and mixed before use, they immediately became homogeneous and when applied to shampooed hair, they gave good gloss and a rich feel and volume. Also, within 10 minutes after shaking, the emulsion returned to a separate and transparent bilayer.

【００２８】[0028]

【表２】 油相Ａ： （重量％） シクロメチコーン（ＤＣ ３４４） ５．０ ジメチコーン（ＤＣ ２００；０．６５cSt ） ５．０ フェニルトリメチコーン（ＤＣ ５５６） １．０ イソドデカン １０．０ 油相Ｂ： ジメチコーンコポリオールブチルエーテル （信越 ＫＦ ３５２Ａ） ０．５ エタノール ５．０ ０．２Ｍ クエン酸水溶液 ３．９ 緑茶エキス １．０ Ｄ−パンテノール ０．５ 水 バランスOil Phase A: (wt%) Cyclomethicone (DC 344) 5.0 Dimethicone (DC 200; 0.65 cSt) 5.0 Phenyltrimethicone (DC 556) 1.0 Isododecane 10.0 Oil Phase B: Dimethicone copolyol butyl ether (Shin-Etsu KF 352A) 0.5 Ethanol 5.0 0.2M Citric acid aqueous solution 3.9 Green tea extract 1.0 D-Panthenol 0.5 Water balance

【００２９】実施例３ 実施例２と同様に、２つの異なる色の相を含むヘアコン
ディショニング剤を製造した。得られたコンディショニ
ング剤は混合すると１つの均一な相になり、使用後は再
び完全に分離した。Example 3 A hair conditioning agent containing two different hues was prepared as in Example 2. The resulting conditioning agent mixes into one homogeneous phase which is completely separated again after use.

【００３０】[0030]

【表３】 油相Ａ： （重量％） Ｃ12〜Ｃ14パラフィン混合物 ２０．００ 油溶性青色染料 ０．０１ 水相Ｂ： ジメチコーンコポリオール（信越 ＫＦ ３５３Ａ） ０．７５ パンテノール ０．５０ エタノール １０．００ 水 バランスOil phase A: (wt%) C 12 to C 14 paraffin mixture 20.00 Oil soluble blue dye 0.01 Water phase B: Dimethicone copolyol (Shin-Etsu KF 353A) 0.75 Panthenol 0.50 Ethanol 10.00 Water balance

Claims (6)

【特許請求の範囲】[Claims] 【請求項１】 一般式（１） 【化１】 （式中、Ｒは炭素数１〜１８のアルキル基を示し、Ａは
エチレン基又はプロピレン基を示し、Ｘは水素原子又は
炭素数１〜４のアルキル基を示し、ｍ、ｎ及びｚはそれ
ぞれ２〜２５の数を示し、ｌは１〜１０の数を示す）で
表わされるシリコーンコポリオールの少なくとも１種を
全組成中に０．０５〜５重量％含有し、使用前には異な
る二層に分離し、振とうすることにより混合されて短時
間に均一なエマルションを形成し、その後二層に分離す
る毛髪化粧料。1. A compound represented by the general formula (1): (In the formula, R represents an alkyl group having 1 to 18 carbon atoms, A represents an ethylene group or a propylene group, X represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and m, n and z are respectively 2 to 25, wherein 1 represents a number of 1 to 10) and at least one silicone copolyol represented by the formula: A hair cosmetic composition that is separated into two layers and mixed by shaking to form a uniform emulsion in a short time, and then separated into two layers. 【請求項２】 一般式（１）で表わされるシリコーンコ
ポリオールを全組成中に０．２５〜３重量％含有する請
求項１記載の毛髪化粧料。2. The hair cosmetic composition according to claim 1, which contains 0.25 to 3% by weight of the total composition of the silicone copolyol represented by the general formula (1). 【請求項３】 一般式（１）中、ｍが５〜１５の数を示
し、ｎが３〜７の数を示し、ｌが２又は３を示し、ｚが
１０〜１５の数を示すシリコーンコポリオールを含有す
る請求項１又は２記載の毛髪化粧料。3. A silicone represented by the general formula (1), wherein m represents a number of 5 to 15, n represents a number of 3 to 7, l represents 2 or 3, and z represents a number of 10 to 15. The hair cosmetic composition according to claim 1 or 2, which contains a copolyol. 【請求項４】 一般式（１）中、Ｒがメチル基、ラウリ
ル基又はセチル基を示すシリコーンコポリオールを含有
する請求項１〜３のいずれかの項記載の毛髪化粧料。4. The hair cosmetic composition according to claim 1, which contains a silicone copolyol in which R represents a methyl group, a lauryl group or a cetyl group in the general formula (1). 【請求項５】 油相の主要部分が、少なくとも１種のシ
リコーン油である請求項１〜４のいずれかの項記載の毛
髪化粧料。5. The hair cosmetic composition according to claim 1, wherein the main part of the oil phase is at least one silicone oil. 【請求項６】 油相の主要部分が、シリコーン油と炭素
数４〜３０の炭化水素との混合物である請求項１〜４の
いずれかの項記載の毛髪化粧料。6. The hair cosmetic composition according to claim 1, wherein the major part of the oil phase is a mixture of silicone oil and a hydrocarbon having 4 to 30 carbon atoms.
JP31012793A 1992-12-11 1993-12-10 Hair cosmetics Expired - Fee Related JP3243356B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE9216886U DE9216886U1 (en) 1992-12-11 1992-12-11 Cosmetic products
DE4241799:6 1992-12-11
DE4241799A DE4241799C1 (en) 1992-12-11 1992-12-11 New cosmetic agent, e.g., for treatment of hair and skin - made in two separate phases and contg. a silicone-co-poly:ol cpd.

Publications (2)

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JPH06279241A true JPH06279241A (en) 1994-10-04
JP3243356B2 JP3243356B2 (en) 2002-01-07

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DE (2) DE9216886U1 (en)

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JP3243356B2 (en) 2002-01-07
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